Patent ID: 7057063

Claim:
An unsaturated carboxylic ester compound derived from the reaction of (a) an oxetane compound containing at least two oxetanyl groups with (b) an unsaturated monocarboxylic acid and having at least two discrete structures represented by the following general formula (1): wherein R 1 represents a hydrogen atom or an alkyl group of 2 to 6 carbon atoms, R 2 represents a hydrogen atom or a methyl group, and R 3 and R 4 independently represent a hydrogen atom, wherein said oxetane compound (a) is selected from the group consisting of a bisoxetane compound represented by the following general formula (2) and a polyfunctional oxetane compound represented by the following general formula (3), and said unsaturated monocarboxylic acid (b) is selected from the group consisting of acrylic acid and methacrylic acid, wherein, R 1 represents a hydrogen atom or an alkyl group of 2 to 6 carbon atoms, and R 5 represents a bivalent group selected from the group consisting of linear or branched saturated hydrocarbons of 2 to 12 carbon atoms, linear or branched unsaturated hydrocarbons of 2 to 12 carbon atoms, aromatic hydrocarbons represented by the following formulas (A), (B), (C), (D), and (E): wherein R 6 represents a hydrogen atom, an alkyl group of 1 to 12 carbon atoms, an aryl group, or an aralkyl group, R 7 represents —O—, —S—, —CH 2 —, —NH—, —SO 2 —, —CH(CH 3 )—, —C(CH 3 ) 2 —, or —C(CF 3 ) 2 —, and R 8 represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, linear or cyclic alkylene groups containing a carbonyl group and represented by the following formulas (F) and (G): wherein n represents an integer of 1 to 12 , and aromatic hydrocarbons containing a carbonyl group and represented by the following formulas (H) and (I): wherein, m represents the number of functional groups bonded to a residue R 9 and an integer of not less than three, R 1 represents a hydrogen atom or an alkyl group of 2 to 6 carbon atoms, and R 9 represents a residue of an etherified product with oxetane and either one of a novolak resin residue, a poly(p-hydroxy styrene) residue, a calixarene residue, a residue of a silicone resin, a branched alkylene group represented by the following 10 formula (J), (K) or (L): or an aromatic hydrocarbon represented by the following formula (M), (N) or (P): wherein R 10 represents a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, or an aryl group.