Patent ID: 7211704

Claim:
A process for preparing p-dichlorobenzene by nuclear chlorination of benzene and/or chlorobenzene as starting material with chlorine molecules, which comprises chlorinating the starting material using aluminum chloride in an amount of 0.1–3 millimols per mol of said starting material and phenothiazine represented by the following formula(I) in an amount of 0.1–0.9 mols per mol of aluminum chloride so that a chlorination degree is in a range of 1.2–2.5: wherein t is an integer of 0–4; u is an integer of 0–4; A is a halocarbonyl group; a group represented by CH x X 1 y CO—, wherein X 1 is a chlorine atom or a bromine atom, x is an integer of 0–2, and y is an integer of 1–3; a group represented by CF 3 (CF 2 ) n CO—,where n is an integer of 0–2; or a group represented by the following formula(II): wherein X 2 is a halogen atom, an alkyl group having 1–4 carbon atoms, an alkoxy group having 1–4 carbon atoms, a nitro group or a cyano group; a is an integer of 0–5; a plurality of X 2 is identical or different respectively when a is 2 or more; and b is an integer of 0–5, but (a+b) is an integer of 5 or less.