Patent ID: 6838579

Claim:
A process for obtaining anhydrous or substantially anhydrous formic acid, in which i) methyl formate is subjected to hydrolysis, ii) methanol and excess methyl formate are distilled off from the resultant hydrolysis mixture, iii) the bottom product from distillation (ii), comprising formic acid and water, is extracted in a liquid—liquid extraction with an extractant which principally takes up the formic acid, and the extractant employed here is a carboxamide of the general formula I where the radicals R 1 and R 2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R 1 and R 2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R 3 is hydrogen or a C 1 -C 4 -alkyl group, iv) the resultant extract phase, comprising formic acid, extractant and some water, is subjected to distillation, v) the top product obtained in this distillation, which comprises water and some of the formic acid, is fed back into the lower part of the distillation device in step ii), vi) the bottom product from distillation step iv), which comprises predominantly extractant and formic acid, is separated by distillation into anhydrous or substantially anhydrous formic acid and the extractant, and vii) the extractant leaving step vi) is fed back into the process, which comprises removing a sub-stream of the extractant employed from the process and feeding it to the distillation device provided for carrying out step ii), with the corresponding feed point for the sub-stream of the extractant in the distillation device being above the feed point of the hydrolysis mixture and below the removal point of methanol.