Patent ID: 7312363

Claim:
A process for reacting epoxides with an initiator compound in the presence of a double metal cyanide compound as a catalyst, said process having a shortened induction period and comprising at least the stages (1) and (2): (1) activating the double metal cyanide compounds by adding the epoxide to a mixture of double metal cyanide compound and initiator compound at an internal reactor pressure of less than 200 mbar, (2) polymerizing an epoxide in the presence of a double metal cyanide compound activated according to stage (1), wherein at least 5% of the total amount of epoxide used in the process is added at an internal reactor pressure of less than 200 mbar, the initiator compound is chosen from organic dicarboxylic acids, aliphatic and aromatic diamines having from 1 to 4 carbon atoms in the alkyl radical, ammonia, and octanol, nonanol, decanol, undecanol, dodecanol, tridecanol, tetradecanol, pentadecanol, iso-octanol, iso-nonanol, iso-decanol, iso-undecanol, iso-dodecanol, iso-tridecanol, iso-tetradecanol, iso-pentadecanol or mixtures of C 13 - to C 15 -alcohols, and after activation of the double metal cyanide compound according to stage (1) the internal pressure is increased to pressures of 1 bar or higher.