Patent ID: 7910744

Claim:
A method for the manufacture of substituted phosphanes, phosphane oxides, phosphane sulfides, or phosphane selenides corresponding to one of the formulae P(R x )(Ar 3-x ) or EP(R x )(Ar 3-x ) or P(R)(R′)(Ar) or EP(R)(R′)(Ar), wherein x equals 0, 1 or 2; E corresponds to oxygen, sulfur or selenium; R and R′ are selected from the group consisting of: an aryl group (phenyl, polycondensed aromatic group, heterocyclic aromatic group, substituted phenyl group, substituted polycondensed aromatic group, or substituted heterocyclic aromatic group), an olefinic group (open-chain or cyclic, with or without functional groups), or an alkyl group (open-chain or cyclic, with or without functional groups); Ar corresponds to an aryl group substituted in ortho, meta, or para position, wherein the same or different aryl groups can be arranged in combination in one compound, with the following substituents: 3(5)-pyrazolyl group, 3-pyrazolyl group substituted in position 1, 3(5)-pyrazolyl group substituted in position 4 and/or 5,3-pyrazolyl group substituted in position 4 and/or 5 as well as in position 1,3-pyrazolyl group substituted in position 4 and/or 5 as well as in position 2, also N-oxide, 1,2-substituted 3-pyrazolium group, 1,2-substituted 3-pyrazolium group substituted in position 4 and/or 5, also N-oxide, each with different anions, 4-pyrimidinyl group, pyrimidine group substituted in position 2 and/or 5 and/or 6, also N-oxide or N,N′-dioxide, wherein the 4-(2-diphenylphosphino-1-naphthyl)-2-R-chinazolines (with R═H, methyl, phenyl, benzyl, i-propyl, t-butyl) and the P-oxides of these compounds are excluded, 4-pyrimidinium group substituted in position 1 or 3, also N-oxide or N,N′-dioxide, or position 2 and/or 5 and/or 6 and in position 1 or 3 substituted 4-pyrimidinium group, also N-oxide or N,N′-dioxide, each with different anions, 4-pyrimidinium group substituted in position 1 and 3, dication, also N-oxide or N,N′-dioxide, 4-pyrimidinium group substituted in position 2 and/or 5 and/or 6 and in position 1 and 3, dication, also N-oxide or N,N′-dioxide, each with different anions; a 1-oxa-3-di(alkyl or aryl)aminoprop-2-enyl group, 1-oxa-3-di(alkyl or aryl)aminoprop-2-enyl group substituted in 2 and/or 3 position, and; a 1,3-dioxapropyl group, a 1,3-dioxapropyl group substituted in 2 and/or 3 position, wherein the phosphane oxides and phosphane sulfides of these compounds, in which the carbon atom of the 1-carbonyl group is substituted with a 1-hydroxy-3-oxocyclohex-1-en-2-yl group, are excluded, wherein in selenide compounds, the following anions can occur: F −1 , Cl −1 , B- 1 , I −1 , OH −1 , SO 4 −2 , HSO 4 −1 , H x PO 4 −1(3−x) (with x=0, 1 or 2), CO 3 −2 or HCO 3 −1 ; the method is comprising introducing pyrazol or pyrimidine groups, respectively, on aromatic groups for the phosphanes, phosphane oxides, phosphane sulfides or phosphane selenides, step-by-step, starting from acetyl groups, according to the following sequence: wherein R is as defined above.