Patent ID: 7513916

Claim:
An agent for the simultaneous lightening and coloring of keratin fibers, comprising at least one oxidizing agent and at least one azodye of the general formula (I); wherein X is selected from the group consisting of oxygen, sulfur, N—R3 and C—R4; Y is selected from the group consisting of C—R5, nitrogen, N—R6, sulfur and oxygen; Z is C—R7 or nitrogen; wherein the heterocycle of the formula (I) comprises from two to three heteroatoms, wherein the heterocycle comprises at most one sulfur atom or one oxygen atom; n is an integer from 1 to 6; R1 is selected from the group consisting of hydrogen, a saturated or unsaturated (C 1 -C 12 )-alkyl group, a (C 1 -C 12 )-alkyl group substituted by a halogen atom, a hydroxy-(C 2 -C 12 )-alkyl group, an amino-(C 1 -C 12 )-alkyl group, a substituted or unsubstituted phenyl group and a substituted or unsubstituted benzyl group; R2, R4, R5, and R7 may be identical or different and, independently of one another, are selected from the group consisting of hydrogen, a halogen atom, a saturated or unsaturated (C 1 -C 12 )-alkyl group, a (C 1 -C 12 )-alkyl group substituted by a halogen atom, a hydroxyl group, a hydroxy-(C 1 -C 12 )-alkyl group, a (C 1 -C 12 )-alkoxy group, a (C 1 -C 12 )-thioalkyl group, a cyano group, a nitro group, an amino group, a (C 1 -C 12 )-alkylamino group, a (C 1 -C 12 )-dialkylamino group, a carboxylic acid group, a C(O)O—(C 1 -C 12 )-alkyl group, a substituted or unsubstituted C(O)O-phenyl group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group and a substituted or unsubstituted heteroaryl group; or if Y and Z are C—R5 and C—R7, the radical groups R5 and R7, together with the remaining molecule, can form a heterocyclic or carbocyclic, saturated or unsaturated, substituted or unsubstituted ring system; or if X and Y are C—R4 and C—R5, the radical groups R4 and R5, together with the remaining molecule, can form a heterocyclic or carbocyclic, saturated or unsaturated, substituted or unsubstituted ring system; R3 and R6 may be identical or different and, independently of one another, are selected from the group consisting of a saturated or unsaturated (C 1 -C 12 )-alkyl group, a (C 1 -C 12 )-alkyl group substituted by a halogen atom (F, Cl, Br, I), a hydroxy-(C 2 -C 12 )-alkyl group, an amino-(C 1 -C 12 )-alkyl group, a substituted or unsubstituted phenyl group and a substituted or unsubstituted benzyl group; Q+ represents an aromatic or non aromatic, substituted or unsubstituted 4- to 6-membered heterocyclic quaternary ammonium group, which may contain other heteroatoms selected from the group consisting of nitrogen, sulfur and oxygen, wherein the cationic heterocycle comprises at most three heteroatoms, where the heterocycle comprises at most one sulfur atom or oxygen atom; or the radical group R1, together with Q+, can form a 5 or 6-membered unsaturated heterocyclic, substituted or unsubstituted cationic ring system; the anion An- is an organic or inorganic acid anion.