Patent ID: 8277939

Claim:
An article of manufacture comprising (i) at least one glass substrate having a thickness of 5 to 500 micrometers and (ii) a coating layer on at least a portion of at least one side of the glass substrate wherein the coating layer comprises a cured silicone resin composition selected from: (I) a hydrosilylation cured silicone resin composition which is a cured product of a silicone composition comprising: (A) a silicone resin having the formula: (R 1 R 2 2 SiO 1/2 ) w (R 2 2 SiO 2/2 ) x (R 1 SiO 3/2 ) y (SiO 4/2 ) z wherein R 1 is a C 1 to C 10 hydrocarbyl group or a C 1 to C 10 halogen-substituted hydrocarbyl group, both free of aliphatic unsaturation, R 2 is R 1 or an alkenyl group, w has a value of from 0 to 0.8, x has a value of from 0 to 0.6, y has a value of from 0 to 0.99, z has a value of from 0 to 0.35, the sum of y+z is 0.2 to 0.99, and the sum of w+x is 0.01 to 0.80 with the proviso that silicone resin (A) contains at least two silicon-bonded alkenyl groups per molecule; (B) a organohydrogensilane or organohydrogensiloxane containing at least two silicon bonded hydrogen atoms per molecule; (C) a hydrosilylation catalyst selected from complexes of chloroplatinic acid and vinyl-containing organosiloxanes, a supported hydrosilylation catalyst comprising a solid support having a platinum group metal on the surface thereof, or a microencapsulated platinum group metal-containing catalyst comprising a platinum group metal encapsulated in a thermoplastic resin; and optionally a hydrosilylation catalyst inhibitor; or (II) a free radical cured silicone resin composition which is a cured product of a silicone composition comprising: (A 2 ) a free radical curable silicone resin having the formula (R 1 R 9 2 SiO 1/2 ) w (R 9 2 SiO 2/2 ) x (R 1 SiO 3/2 ) y (SiO 4/2 ) z wherein R 1 is a C 1 to C 10 hydrocarbyl group or a C 1 to C 10 halogen-substituted hydrocarbyl group, both free of aliphatic unsaturation, R 9 is R 1 , alkenyl, or alkynyl, w has a value of from 0 to 0.8, x has a value of from 0 to 0.6, y has a value of from 0 to 0.99, z has a value of from 0 to 0.35, the sum of y+z is 0.2 to 0.99, and the sum of w+x is 0.01 to 0.80, with the proviso that silicone resin (A 2 ) has an average of at least two silicon-alkenyl groups or at least two silicon-bonded alkynyl groups per molecule; (B 2 ) a crosslinking agent which is an unsaturated compound having a molecular weight of less than 500 selected from (i) at least one organosilicon compound having at least one silicon-bonded alkenyl group per molecule, (ii) at least one organic compound having at least one aliphatic carbon-carbon double bond per molecule, or (iii) mixtures comprising (i) and (ii); (C 2 ) a free radical photoinitiator or an organic peroxide.