Patent ID: 8686208

Claim:
A process for making styrene comprising: providing a C 1 source to a reactor comprising a catalyst; and reacting toluene with the C 1 source in the presence of the catalyst to form a product stream comprising ethylbenzene and styrene; wherein the C 1 source is selected from the group consisting of methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, dimethyl ether, and combinations thereof; wherein the catalyst comprises a nitrogen-substituted zeolite formed through contacting of a zeolite with a nitrogen containing material that subjects the zeolite to the substitution of oxygen with nitrogen within the structure of the zeolite; wherein the zeolite is selected from the group consisting of faujasites; wherein the nitrogen containing material is selected from the group consisting of ammonia, an alkyl amine, and any combinations thereof; wherein the catalyst further comprises at least one promoter in an amount ranging from 0.1 wt % to 5 wt % based on the total weight of the catalyst, the promoter selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and any combinations thereof.