Patent ID: 7314962

Claim:
A process for making at least one alkylated aromatic compound of the Formula: wherein: a) Q 1 is H, —CH 3 , —C 2 H 5 , or CH 3 —CH—CH 3 ; b) Q 2 is H, —CH 3 or —C 2 H 5 ; and c) Q 3 is —C 2 H 5 or C 3 to C 18 straight chain alkyl group having therein a single CH group, the carbon atom of which is bonded to the aromatic compound; by a process comprising: (1) reacting a C 2 to C 18 straight-chain monoolefin with an aromatic compound of the Formula: wherein Q 1 and Q 2 are as defined above; in an ionic liquid of the Formula: wherein: (i) Z is —(CH 2 ) n —, wherein n is an integer from 2 to 12; (ii) R 2 , R 3 and R 4 taken independently are H, —CH 3 , —CH 2 CH 3 or C 3 to C 6 straight-chain or branched monovalent alkyl; and (iii) A − is an anion selected from the group consisting of [BF 4 ] − , [PF 6 ] − , [SbF 6 ] − , [CH 3 CO 2 ] − , [HSO 4 ] − , [CF 3 SO 3 ] − , [HCF 2 CF 2 SO 3 ] − , [CF 3 HFCCF 2 SO 3 ] − , [HCClFCF 2 SO 3 ] − , [(CF 3 SO 2 ) 2 N] − , [AlCl 4 ] − , [CF 3 CO 2 ] − , [NO 3 ] − , [SO 4 ] 2 − , Cl − , Br − , I − , and F − ; in the presence of an acid catalyst that is soluble in the ionic liquid, at a temperature between about 25 degrees C. and about 200 degrees C., and a pressure between atmospheric pressure and that pressure required to maintain the reactants in a liquid state, wherein at the start of the reaction the aromatic compound is in molar excess relative to the monoolefin, to form a reaction product that comprises an organic phase that contains the at least one alkyl aromatic compound and an ionic liquid phase that contains the acid catalyst, and (2) separating the organic phase comprising the at least one alkylated aromatic compound from the ionic liquid phase.