Patent ID: 8580896

Claim:
A process for preparing a fluorine-containing polymer comprising a first step for preparing a dispersion comprising fluorine-containing emulsified particles (A) having ionic functional groups where a fluorine-containing monomer mixture (i) is polymerized by using a water soluble radical polymerization initiator (a) without addition of an emulsifying agent, and a second step for preparing a fluorine-containing polymer (B) having a small amount of ionic functional groups where fluorine-containing monomers (ii) are emulsion-polymerized by using a radical polymerization initiator (b) in the presence of said fluorine-containing emulsified particles (A) having ionic functional groups without addition of an emulsifying agent, and a step for reducing an amount of the water soluble radical polymerization initiator (a) remaining in a polymerization system after completion of the first step which comprises decomposing a polymerization initiator by treatment with activated carbon or decomposing a polymerization initiator by increasing temperature, said process being characterized in that: (1) the fluorine-containing monomer mixture (i) used in the first step is a monomer mixture comprising a perhalo ethylenic monomer and a nonperhalo ethylenic monomer, (2) the fluorine-containing emulsified particles (A) having ionic functional groups prepared in the first step are used in an amount of from 0.01 to 5.0% by mass based on the fluorine-containing polymer (B) to be prepared in the second step, (3) an amount of the water soluble radical polymerization initiator (a) used in the first step is from 1.3 to 1,000% by mass based on the fluorine-containing emulsified particles (A) having ionic functional groups to be prepared in the first step, and (4) an emulsifying agent is not added through the first step and the second step, wherein the radical polymerization initiator (b) used in the second step is a water soluble radical polymerization initiator (b1).