Patent ID: 8871178

Claim:
A family of microporous crystalline metallophosphate materials having a three-dimensional framework of EO 2 − , PO 2 + and at least one of [M 2+ O 2 ] 2− tetrahedral units and an empirical composition in the as synthesized and anhydrous basis expressed by an empirical formula of: R r M 2+ m EP x Si y O z where M is at least one framework divalent cation selected from the group consisting of alkaline earth and transition metals, “m” is the mole ratio of M to E and varies from 0 to about 1.0, R is an organoammonium cation selected from the group of choline, tetrametylammonium (TMA + ), ethyltrimethylammonium (ETMA + ), diethyldimethylammonium (DEDMA + ), methyltriethylammonium (MTEA + ), trimethylpropylammonium, dimethyldiethanolammonium, tetraethylammonium (TEA + ), tetrapropylammonium (TPA + ) and mixtures thereof, “r” is the mole ratio of R to E and has a value of about 0.1 to about 2, E is an trivalent element selected from the group consisting of aluminum, gallium, iron, boron and mixtures thereof, “x” is the mole ratio of P to E and has a value of 0.5 to about 2.0, “y” is the mole ratio of Si to E and varies from 0 to about 1.0, “m”+“y”≧0.1, and “z” is the mole ratio of O to E and has a value determined by the equation: z =(2 ·m+r+ 3+5· x+ 4 ·y )/2 and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table A: TABLE A 2Θ d (Å) I/I 0 % 7.85-7.36 11.25-12.00 w 10.49-10.11 8.43-8.74 m-vs 13.40-13.03 6.60-6.79 w-m 15.40-15.13 5.75-5.85 w 17.00-16.56 5.21-5.35 m-s 19.41-18.87 4.57-4.70 w-m 20.49-20.03 4.33-4.43 w 21.09-20.35 4.21-4.36 w-m 21.66-21.24 4.10-4.18 m-vs 22.43-21.98 3.96-4.04 m-vs 23.14-22.78 3.84-3.90 w-m 26.11-25.58 3.41-3.48 w 26.91-26.35 3.31-3.38 w-m 29.16-28.68 3.06-3.11 m-s 31.94-31.36 2.80-2.85 m 35.02-34.33 2.56-2.61 w-m 35.74-35.16 2.51-2.55 w 42.61-41.99 2.12-2.15 w 48.93-48.10 1.86-1.89 w 49.50-48.65 1.84-1.87 w 50.98-50.37 1.79-1.81 w 54.94-54.23 1.67-1.69 w.