Patent ID: 7524905

Claim:
A process for preparing a copolymer comprising contacting at least one acyclic aliphatic olefin monomer, at least one nitrogen containing vinyl monomer, wherein the at least one nitrogen containing vinyl monomer is according to Formula (I) and a catalyst composition comprising a metal center, M, complexed with at least one ligand, wherein the at least one ligand has a structure according to Formula (III) wherein R 19 is selected from —C═C, and —C(O)—C═C; wherein R 20 and R 21 are independently selected from H, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a biphenyl group, a carboxylate group, a carboxyalkyl group, a carboxyarylalkyl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, an alkoxycarbonyl group, and derivatives thereof; and, wherein R 20 and R 21 may optionally be combined to form a cyclic or multi-cyclic structure; wherein M is selected from Ni and Pd; wherein R 1 -R 14 are independently selected from a hydrogen; a halogen; and, a substituent selected from C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, aryl, arylalkyl, alkylaryl, phenyl, biphenyl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl, C 1 -C 20 alkylsulfinyl and silyl; wherein at least one of R 1 , R 5 , R 6 and R 10 is a 2,6-R 16 R 17 -phenyl, where R 16 and R 17 are independently selected from hydrogen, halogen, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, aryl, arylalkyl, alkylaryl, phenyl, biphenyl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl, C 1 -C 20 alkylsulfinyl and silyl; wherein at least one of R 1 , R 5 , R 6 and R 10 is 2,6-dimethoxyphenyl; wherein R 15 is selected from —SO 3 , —PO 3 , —AsO 3 , and —C(CF 3 ) 2 O; wherein the copolymer comprises 1 to 99.9 mol % acyclic aliphatic olefin monomer units; with the proviso that R 20 and R 21 are not both H and with the proviso that the at least one nitrogen containing vinyl monomer is not N-vinylimidazole.