Patent ID: 7960445

Claim:
A composition of matter comprising the structure: wherein A is a polyether or polyester polyol backbone, comprising the structure: Wherein R is H or which may be further substituted by R to extend the polyol backbone up to six total alcohol groups per each polymeric structure, and where R 2′ is: (i) an alkylene (meth)acrylate terminated urethane containing linkage; or (ii) an alkylenealkoxysilyl terminated linkage; where R 3 , R 7 and R 11 may be the same or different and are each H or C 1-6 alkyl; R 4 , R 8 and R 12 may be the same or different and are each alkylene C 1-6 , W is free valency or x is 1 to 40, q is 0.1 to 1, s is 0.1 to 1, and t is 0.1 to 1, where q, s and t together are no more than 3; R 1 is a carbamoyl containing linkage or a hydrocarbon diradical joined to A through a carbamoyl linkage; and R 2 is a member selected from the group consisting of: (A) (i) an alkylene (meth)acrylate terminated urethane containing linkage; and (ii) an alkylene alkoxysilyl terminated linkage; or (iii) an alkylene alkoxysilyl terminated urea containing linkage, provided that greater than one of group (i) and at least one of group (ii) or (iii) are present; or (B) (i) a photocurable portion comprising a urethane or carbamate linkage terminated with a (meth)acryloxyalkyl group; (ii) a moisture curable portion terminated with a polyalkoxysilyl group; and (iii) a moisture curable portion comprising a urea linkage terminated with an alkylpolyalkoxysilyl group, provided that there are present: (a) at least two photocuring portions and at least one moisture curing portion; or (b) at least two moisture curing portions from the same group and at least one photocuring portion, and n is >2 up to 6.