Patent ID: 8609195

Claim:
A process for the demulsifying cleaning of metallic surfaces contaminated with a contaminant that is an oil, with at least one further non-polar organic compound, with a fat, with a soap, with particulate dirt or with at least one anionic organic compound, using an aqueous, alkaline, surfactant-containing bath, wherein the bath becomes contaminated with the oil, with the at least one further non-polar organic compound, with the fat, with the soap, with the particulate dirt or with the at least one anionic organic compound during cleaning of the metallic surfaces, wherein the bath contains an demulsifying surfactant that is selected from non-ionic surfactants based on ethoxylated alkyl alcohols with an end group cap that is an isopropyl group or an isobutyl group and ethoxylated-propoxylated alkyl alcohols with an end group cap that is an isopropyl group or an isobutyl group and this is added to the bath, wherein the bath further comprises a cationic organic compound and this is added to the bath, and wherein the bath is kept in a demulsifying state even during increasing contamination with at least one anionic organic compound, wherein the content of the demulsifying surfactant in the bath ranges from 0.1 to 10 g/l, and wherein through the choice of the demulsifying surfactant, the content of the demulsifying surfactants and the mixture of the demulsifying surfactant, a specific radius of curvature of oil droplets as the predominant possible radius of curvature in baths via the coverage of the oil droplets the radius of curvature is adjusted so that the oil in a moved bath is still not quite emulsified and so that an oil-containing phase has therefore still not accumulated or not yet accumulated markedly on the surface of the bath, but however spontaneously deposits in a quiescent bath and accumulates on the surface of the bath as an oil-containing phase.