Patent ID: 8282715

Claim:
Apparatus useful for treating gaseous carbon dioxide that contains SOx and NOx, comprising (A) an activated carbon reactor system adapted to receive a gaseous feed stream of carbon dioxide such as flue gas that also comprises NOx and sulfur dioxide and that is at a pressure of at least 1.5 bar, and the activated carbon reactor system comprising at least one bed of activated carbon for adsorbing SO 2 and NO from said feed stream and converting adsorbed sulfur dioxide to sulfur trioxide and converting adsorbed NO to nitrogen dioxide, and thereby forming SO 2 -depleted NOx-depleted carbon dioxide, wherein sulfur trioxide and nitrogen dioxide adsorbed on said bed can be washed therefrom with water; (B) a subambient-temperature recovery system coupled to said activated carbon reactor system to receive therefrom SO 2 -depleted NOx-depleted carbon dioxide and to treat said SO 2 -depleted NOx-depleted carbon dioxide, employing refrigeration provided by expansion of at least one liquid carbon dioxide product stream formed in said recovery system, to produce at least one gaseous carbon dioxide product stream and at least one gaseous carbon dioxide-containing vent stream; (C) a carbon dioxide separation system coupled to said subambient-temperature recovery system to receive therefrom a gaseous carbon dioxide-containing vent stream and to separate said vent stream into a carbon dioxide-rich stream and a carbon dioxide-depleted stream by pressure swing adsorption or by physical or chemical absorption; and wherein said carbon dioxide separation system is coupled to said feed stream to recycle said carbon dioxide-rich stream to feed stream.