Patent ID: 8017197

Claim:
A plasma processing method for forming a fluorine-containing carbon film on a surface of a substrate by using a plasma processing apparatus including a processing chamber in which a mounting table is provided; a disc-shaped planar antenna member disposed at an upper portion of the processing chamber to face the mounting table, a plurality of slots for radiating a microwave being circumferentially formed in the planar antenna member; a dielectric plate disposed under the planar antenna member, the dielectric plate transmitting the microwave radiated from the planar antenna member; and a conductive gas supply member disposed between the dielectric plate and the mounting table to divide the inside of the processing chamber into an upper plasma generation space and a lower processing space, the gas supply member made of aluminum or an aluminum alloy including an aluminum fluoride passivation film thereon and having a plurality of through-holes and a plurality of gas supply openings, the plasma generation space and the processing space communicating with each other through the through-holes, wherein the method comprises the steps of: (a) mounting the substrate on the mounting table in the processing chamber; (b) forming a fluorine-containing carbon film of a predetermined thickness on the surface of the substrate on the mounting table, including: (b1) supplying a rare gas into the plasma generation space, (b2) supplying a film forming gas, which is a compound gas containing carbon and fluorine, into the processing space through the gas supply openings of the gas supply member, and (b3) activating the rare gas and the film forming gas by radiating the microwave from the planar antenna member to deposit active species generated from the film forming gas; (c) unloading the substrate on which the film is formed out of the processing chamber; (d) after the step (c), by supplying a cleaning gas containing oxygen and hydrogen into the processing chamber and radiating the microwave from the planar antenna member to activate the cleaning gas, cleaning inner surfaces of the processing chamber including a bottom surface of the dielectric plate and the gas supply member with oxygen active species and hydrogen active species generated from the cleaning gas wherein during the cleaning at least a portion of the aluminum fluoride passivation film is removed from a surface of the gas supply member made of aluminum or aluminum alloy, thereby exposing a surface of the aluminum or aluminum alloy; and (e) after the step (d), by supplying a gaseous mixture of an oxygen-containing gas and a rare gas into the processing chamber and radiating the microwave from the planar antenna member to activate the gaseous mixture, oxidizing the exposed aluminum or aluminum alloy surface of the gas supply member with oxygen radicals generated from the gaseous mixture, wherein an oxide film having a high adhesivity is formed on the surface of the gas supply member by the oxidizing step (e).