Patent ID: 8420407

Claim:
A growth method of Fe3N comprising: growing Fe 3 N in a metal organic chemical vapor deposition (MOCVD) system comprising the following process: 1) heat treating a sapphire substrate at 1000-1100° C. and then pumping in ammonia into the MOCVD system to perform surface nitridation on the sapphire substrate at 1000-1100° C., controlling a flux of the ammonia at 500-700 sccm, such that a V/III ratio which denotes mole ratio of nitrogen and gallium is 500-50000; 2) pumping in a carrier gas of N 2 , an ammonia gas and an organic gallium source, and growing a 5-50 nm low temperature GaN buffer on the sapphire substrate which has been treated by the process in step 1), wherein the organic gallium source is trimethyl gallium with a flux of 1-50 sccm; 3) after growing the low temperature GaN buffer, raising the MOCVD system temperature to 1000-1150° C., and then continuing to grow the GaN buffer for 10 minutes to get a GaN supporting layer of 50 nm; 4) after growing the GaN supporting layer, pumping in FeCp 2 as a Fe source at a flux of the Fe source is 50-200 sccm to grow the Fe 3 N, wherein a growth time of the Fe 3 N is 5-3600 s; and 5) controlling the pressure of the MOCVD system to be at 0.1-2 atmospheric pressure.