Patent ID: 7880028

Claim:
A process for the continuous production of 3-pentenenitrile, comprising: (a) continuously introducing feed comprising hydrogen cyanide, 1,3-butadiene, and a catalyst precursor composition to a reaction zone, wherein the molar ratio of the hydrogen cyanide in the feed to the 1,3-butadiene in the feed is in the range of about 0.90:1.00 to about 1.04:1.00, and wherein the catalyst precursor composition comprises a zero-valent nickel and at least one multidentate phosphorus-containing ligand selected from the group consisting of a phosphite, a phosphonite, a phosphinite, a phosphine, and a mixed phosphorus-containing ligand or a combination of such members; (b) displacing a product mixture from the reaction zone by the feed which is continuously introduced into the reaction zone; and (c) maintaining a residence time in the reaction zone sufficient to convert about 95% or more of the hydrogen cyanide and to produce the product mixture, wherein the product mixture comprises 3-pentenenitrile and 2-methyl-3-butenenitrile, and wherein the 2-methyl-3-butenenitrile concentration is maintained below about 15 weight percent of the total mass of the product mixture.