Patent ID: 8802353

Claim:
An amorphous film produced by using a radiation-sensitive composition containing 1 to 80% by weight of a solid component and 20 to 99% by weight of a solvent, wherein the solid component has an absorptivity coefficient at a wavelength of 248 nm of 40 L/(cm·g) or more, and wherein the radiation sensitive composition contains a compound B which satisfies the following requirements of: (a) having a structure derived from a polyphenol compound A by introducing an acid-dissociating group to at least one phenolic hydroxyl group of the polyphenol compound A which is synthesized by a condensation between a di- to tetrafunctional aromatic ketone or aromatic aldehyde each having 5 to 36 carbon atoms with a compound having 1 to 3 phenolic hydroxyl groups and 6 to 15 carbon atoms, and (b) having a molecular weight of 400 to 2000, and wherein a total content of the compound B and a solubilizer C is 50 to 99.999% by weight of a total weight of the solid component; wherein the compound B is represented by the following formula 1: wherein each R 1 is an acid-dissociating group selected from the group consisting of substituted methyl groups, 1-substituted ethyl groups, 1-substituted n-propyl groups, 1-branched alkyl groups, silyl groups, acyl groups, 1-substituted alkoxymethyl groups, cyclic ether groups and alkoxycarbonyl groups, and two or more R 1 may be the same or different; wherein each R 2A is a group selected from the group consisting of halogen atom, alkyl group, cycloalkyl group, aryl group, aralkyl group, alkoxy group, aryloxy group, alkenyl group, acyl group, alkoxycarbonyl group, alkyloyloxy group, aryloyloxy group, cyano group, and nitro group, and two or more R 2A may be the same or different; wherein each of R 3 and R 7 is a hydrogen atom or alkyl group having 1 to 6 carbon atoms; wherein R 4A is a divalent group having 10 to 28 carbon atoms which includes a biphenyl structure, terphenyl structure, naphthalene structure, phenanthrene structure, or pyrene structure, or R 4A together with R 3 and R 7 optionally represents a tetravalent group having 10 to 28 carbon atoms which includes a fluorine structure or benzophenone structure; and wherein each of k0, j0, m0, and n0 is an integer of 0 to 3, each of k1, j1, m1, and n1 is an integer of 0 to 3; and each of k2, j2, m2, and n2 is an integer of 0 to 4, satisfying 1≦k0+k1+k2≦5, 1<j0+j1+j2<5, 1<m0+m1+m2<5, 1<n0+n1+n2<5, 1<k1+j1+m1+n1<12, 1<k0+k1<3, 1<j0+j1<3, 1<m0+m1<3, and 1<n0+n1<3.