Patent ID: 8288492

Claim:
An oligomer consisting of: A) 40 to 90 mole percent copolymerized units of tetrafluoroethylene; B) 10 to 60 mole percent copolymerized units of perfluoro(methyl vinyl ether); C) 0 to 10 mole percent copolymerized units of hexafluoropropylene; D) 0 to 10 mole percent copolymerized units of a perfluoro vinyl ether of formula CF 2 â•CFO(R fâ€² O) n (R fâ€³ O) m R f , where R fâ€² and R fâ€³ are different linear or branched perfluoroalkylene groups of 2-6 carbon atoms, m and n are independently 0-10, and R f is a perfluoroalkyl group of 1-6 carbon atoms; and E) 0 to 10 mole percent copolymerized units of a functional fluorovinyl ether selected from the group consisting of a functional fluorovinyl ether selected from the group consisting of i) propanoic acid, 3-[1-[difluoro[(1,2,2-trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro-, methyl ester; ii) ethanesulfonyl fluoride, 2-[1-[difluoro[(1,2,2-trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoro-; iii) 1-propanol, 3-[1-[difluoro[(trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro-; iv) propanenitrile, 3-[1-[difluoro[(1,2,2-trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro-; v) hexanenitrile, 2,2,3,3,4,4,5,5,6,6-decafluoro-6-[(1,2,2-trifluoroethenyl)oxy]-; vi) propanenitrile, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-[(trifluoroethenyl)oxy]propoxy]-; vii) propanamide, 3-[1-[difluoro[(1,2,2-trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro-; viii) 1-propanol, 3-[1-[difluoro[(trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro-, dihydrogen phosphate; and ix) propanoic acid, 3-[1-[difluoro[(trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-2,2,3,3-tetrafluoro- wherein said oligomer has a number average molecular weight of 1500 to 5000 g/mole, a molecular weight distribution less than 1.5, and wherein said oligomer has a â€”CF 2 H functional group at each chain end.