Patent ID: 7847046

Claim:
A polymeric ophthalmic or otorhinolaryngological device material comprising a) a monofunctional acrylate or methacrylate monomer of formula [1]; b) a difunctional acrylate or methacrylate cross-linking monomer of formula [2], and c) a phenylene-siloxane macromer of formula [3a] or [3b]: wherein: B═O(CH 2 ) n , NH(CH 2 ) n , or NCH 3 (CH 2 ) n ; R 1 , R 2 , R 3 independently ═H, CH 3 , CH 2 CH 3 , or CH 2 OH; X, X′ independently ═O(CH 2 ) n , NH(CH 2 ) n , NCH 3 (CH 2 ) n , O(CH 2 ) n C 6 H 4 , O(CH 2 CH 2 O) n CH 2 , O(CH 2 CH 2 CH 2 O) n CH 2 , O(CH 2 CH 2 CH 2 CH 2 O) n CH 2 , or nothing; J=(CH 2 ) a , O(CH 2 CH 2 O) b , O, or nothing, provided that if X and X′=nothing, then J≠nothing; J′, J″ independently ═(CH 2 ) a or nothing, provided that if X and X′=nothing, then J′, J″≠nothing; n=0-12; Y═C 6 H 5 , (CH 2 ) m H, or O(CH 2 ) m C 6 H 5 ; Z, Z′ independently ═C(=O) or OCH 2 C 6 H 4 ; m=0-12; a=1-12; b=1-24; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 independently =(CH 2 ) b H, CH═CH 2 , CH═C(CH 3 ), CH 2 CH═CH 2 , CH 2 CH═CHCH 3 , CH(CH 3 ) 2 , CH 2 CH(CH 3 ) 2 , O(CH 2 ) m C 6 H 5 , O(CH 2 ) m C 6 H 4 (OH)C(O)C 6 H 5 , CH 2 CH 2 CH 2 NH 2 , CH 2 CH 2 CH 2 NHCH 3 , CH 2 CH 2 CH 2 N(CH 3 ) 2 , CH 2 CH 2 CH 2 NHCH 2 CH 2 NH 2 , CH 2 CH(CH 3 )CH 2 NHCH 2 CH 2 NH 2 , (CH 2 ) a OC(O)C(R 1 )═CH 2 , (CH 2 ) b SH, CH 2 CH 2 CH 2 OCH 2 (O)CH 2 , CH(CH 3 )NHCH 2 CH 3 , CH(CH 3 )N(CH 3 )CH 2 CH 3 , CH(CH 3 )N(CH 2 CH 3 ) 2 , cyclopentyl, cyclohexyl, CH 2 CH 2 CN, CH 2 CH 2 CH 2 CN, CH 2 CH 2 CH(CH 3 )CN, CH 2 Cl, CH 2 CH 2 Cl, CH 2 CH 2 CH 2 Cl, CH 2 CH 2 C 6 H 4 CH 2 Cl, CH 2 Si(CH 3 ) 3 , CH 2 Si(CH 2 CH 3 ) 3 , CH 2 CH 2 CF 3 , CH 2 NCO, CH 2 NHC 6 H 5 , C 6 F 5 , phenyl, or naphthyl, each optionally substituted with C 1 -C 12 alkyl, C 1 -C 12 alkoxy, C 1 -C 12 cycloalkyl, C 1 -C 12 cycloalkoxy, NO 2 , OH, CN, NCO, NH 2 , F, Br, Cl, I, or (CH 2 CH 2 O) b H; R 10 =phenyl, biphenyl, diphenylether, or naphthyl, each optionally substituted with C 1 -C 12 alkyl, C 1 -C 12 alkoxy, C 1 -C 12 cycloalkyl, C 1 -C 12 cycloalkoxy, NO 2 , OH, CN, NCO, NH 2 , F, Br, Cl, I, or (CH 2 CH 2 O) b H; and w=3-120.