Patent ID: 8484839

Claim:
A process comprising: conformably laminating an uncured formable asymmetric thermoset film to a circuitized dielectric core to form a laminated circuitized dielectric core comprising an uncured laminated asymmetric thermoset film, the asymmetric thermoset film having a first film surface and a second film surface, the surfaces being parallel to one another and separated by an interior, the film comprising an uncured thermoset resin composition with one or more fillers dispersed therewithin, the one or more fillers having a total concentration of 15% to 75% by weight based on the total combined weight of the thermoset resin composition and fillers when cured, excluding solvents and volatiles, wherein in the interior the concentration of the one or more fillers exhibits a continuous gradient; each the one or more fillers having an average particle size in the range of 0.01 to 5 μm; the second surface being in conforming contact with the circuitized dielectric core layer; thermally curing the uncured laminated asymmetric thermoset film to form a cured laminated circuitized dielectric core; introducing vias, through-holes, and semi-through holes in the laminated circuitized dielectric core; roughening the exposed surfaces in the laminated circuitized dielectric core with chemical desmearing agents; adheringly applying a metallic layer to the first surface of the asymmetric film; covering at least a portion of the exposed metallic layer with a photoresist surface; imagewise exposing the photoresist surface, and developing the photoresist to form a pattern upon the imagewise exposed photoresist coating; increasing the thickness of the exposed metallic layer using means such as electrolytic deposition; removing the residual photoresist surface; and etching the patterned surface to remove unwanted conductive material to produce a pattern of discrete conductive pathways thereupon.