Patent ID: 7834104

Claim:
A process of producing a urethane resin removable pressure-sensitive adhesive having an adhesive force exceeding 15 N/25 mm and not higher than 50 N/25 mm, which process comprises: (1) reacting a polyol selected from the group consisting of polyoxyalkylene polyols, polyester polyols, polyoxytetramethylene glycol, and polycarbonate polyols and mixtures thereof, with one or more polyisocyanate compounds selected from the group consisting of aliphatic polyisocyanates, alicyclic polyisocyanates, and polyisocyanates having an aromatic ring and having isocyanate groups not directly bonded to the aromatic ring, in such a proportion that isocyanate groups are present in excess to thereby obtain an isocyanate-group-terminated prepolymer, (2) subsequently reacting the isocyanate-group-terminated prepolymer with a chain extender in an amount in such excess of the isocyanate groups of the isocyanate-group-terminated prepolymer that the urethane resin produced has residual hydroxyl groups and a number-average molecular weight of 10,000 to 300,000, and (3) further reacting the resultant polymer with a chain terminator having a group reactive with an isocyanate group in an amount of 1-2 moles per 1 mole of the terminal isocyanate groups remaining after the chain extension reaction; wherein at least 50% by mole of the chain extender comprises a polyfunctional compound (X) having a molecular weight of 500 and lower and three or more functional groups reactive with an isocyanate group; wherein two of the functional groups of the polyfunctional compound (X) are primary hydroxyl groups and the remaining functional group(s) is secondary hydroxyl or tertiary hydroxyl group(s); and wherein the chain terminator is selected from the group consisting of (a) a compound having only one functional group reactive with an isocyanate group, and (b) a compound having one highly reactive functional group reactive with an isocyanate group and one or two less reactive functional groups, wherein the polyfunctional compound (X) is at least one member selected from the group consisting of compounds represented by chemical formula (1) and compounds represented by chemical formula (2): wherein R1 in chemical formula (1) represents a hydrogen atom or a methyl group and R2 therein represents a methyl group or an ethyl group; and n in chemical formula (2) represents any of 0, 1, and 2.