Patent ID: 8871177

Claim:
A microporous crystalline metallophosphate material having a three-dimensional framework of EO 2 − and PO 2 + and at least one of [M 2+ O 2 ] 2− and SiO 2 tetrahedral units and an empirical composition in the as synthesized and anhydrous basis expressed by an empirical formula of: R r M 2+ m EP x Si y O z where M is at least one framework cation of +2 valence selected from the group consisting of alkaline earth and transition metals, “m” is the mole ratio of M to E and varies from 0 to about 1.0, R is an organoammonium cation selected from the group consisting of ethyltrimethylammonium (ETMA + ), choline, diethyldimethylammonium (DEDMA + ), trimethylpropylammonium, tetramethylammonium (TMA + ) tetraethylammonium (TEA + ), tetrapropylammonium (TPA + ) cations, and mixtures thereof, “r” is the mole ratio of R to E and has a value of about 0.1 to about 2, E is a trivalent element selected from the group consisting of aluminum, gallium, iron, boron and mixtures thereof, “x” is the mole ratio of P to E and has a value of 0.5 to about 2.0, “y” is the mole ratio of Si to E and varies from 0 to about 1.0, “m”+“y”≧0.1, and “z” is the mole ratio of O to (Al+E) and has a value determined by the equation: z =(2 ·m+r+ 3+5 ·x+ 4 ·y )/2 and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table A: TABLE A 2Θ d(Å) I/I 0 % 7.69-7.48 11.48-11.81 w 9.15-8.88 9.66-9.95 m-vs 12.55-12.25 7.05-7.22 m 13.30-13.07 6.65-6.77 w-s 14.90-14.51 5.94-6.10 w 16.13-15.87 5.49-5.58 m 16.75-16.37 5.29-5.41 w 18.28-18.02 4.85-4.92 m 19.94-19.41 4.45-4.57 w-m 20.88-20.64 4.25-4.30 m-vs 21.34-20.79 4.16-4.27 m 22.67-22.26 3.92-3.99 m-vs 23.08-22.78 3.85-3.90 w-s 25.28-24.78 3.52-3.59 w 26.11-25.43 3.41-3.50 s-vs 26.67-26.35 3.34-3.38 w-m 28.40-27.86 3.14-3.20 w 29.36-28.78 3.04-3.10 w-m 30.92-30.27 2.89-2.95 w-m 31.36-30.92 2.85-2.89 w-m 32.29-31.70 2.77-2.82 m 35.60-35.02 2.52-2.56 w-m 36.50-35.45 2.46-2.53 w 42.40-41.58 2.13-2.17 w-m 43.69-42.61 2.07-2.12 w 49.21-48.65 1.85-1.87 w 50.98-49.79 1.79-1.83 w-m 55.30-54.23 1.66-1.69 w-m.