Patent ID: 7196030

Claim:
A process for the preparation of at least one alkoxylate comprising: bringing into contact an alkylene oxide mixture comprising ethylene oxide with at least one starter compound in the presence of at least one double-metal cyanide compound of the formula 1: M 1 a [M 2 (CN) b (A) c ] d ·fM 1 g X n ·h(H2O)·eL·kP. wherein M 1 is a metal ion selected from the group consisting of Zn 2+ , Fe 3+ , Co 3+ , Ni 2+ , Mn 2+ , Co 2+ , Sn 2+ , Pb 2+ , Mo 4+ , Mo 6+ , Al 3+ , V 4+ , V 5+ , Sr 2+ , W 4+ , W 6+ , Cr 2+ , Cr 3+ , Cd 2+ , Hg 2+ , Pd 2+ , Pt 2+ , V 2+ , Mgt + , Ca 2+ , Ba 2+ , Cu 2+ , La 3+ , Ce 3+ , Ce 4+ , Eu 3+ , Ti 3+ , Ti 4+ , Ag + , Rh 2+ , Rh 3+ , Ru 2+ , and Ru 3+ ; M 2 is a metal ion selected from the group consisting of Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Mn 2+ , Mn 3+ , V 4+ , V 5+ , Cr 2+ , Cr 3+ , Rh 3+ , Ru 2+ , and Ir 3+ ; A and X, independently of one another, are anions, each of which is selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, hydrogensulfate, phosphate, dihydrogenphosphate, hydrogenphosphate or and hydrogencarbonate; L is a water-miscible lagand selected from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, polyesters, polycarbonate, ureas, amides, primary, secondary and tertiary amines, ligands with pyridine nitrogen, nitriles, sulfides, phosphides, phosphates, phosphines, phosphonates and phosphates; k is a fraction or an integer, wherein the value of k is greater than or equal to zero; P is at least one organic additive selected from the group consisting of polyethers, polyesters, polycarbonates, polyalkylene glycol sorbitan esters, polyalkylene glycol glycidyl ethers, polyacrylamide, poly(acrylamide-co-acrylic acid), polyacrylic acid, poly(acrylamide-co-maleic acid), polyacrylonitrile, polyalkyl acrylates, polyalkyl methacrylates, polyvinyl methyl ether, polyvinyl ethyl ether, polyvinyl acetate, polyvinyl alcohol, poly-N-vinylpyrrolidone, poly(N-vinylpyrrolidone-co-acrylic acid), polyvinyl methyl ketone, poly(4-vinylphenol), poly(acrylic acid-co-styrene), oxazoline polymers, polyalkyleneimines, maleic acid and maleic anhydride copolymers, hydroxyethylcellulose, polyacetates, ionic surface-active and interface-active compounds, bile acid or salts thereof, esters or amides, carboxylic esters of polyhydric alcohols, and glycosides; a, b, c, d, g and n are chosen such that the electroneutrality of the compound I is ensured; e is the number of ligand molecules, wherein e is a fraction or an integer, and wherein the value of e is greater than or equal to 0; and each of f and h, independently of one another, is a fraction or an integer wherein each off and h, independently of each other, has a value greater than or equal to 0; wherein, during the induction phase, the sum of the inert gas partial pressure and the ethylene oxide partial pressure is 1.5 bar to 6.0 bar; and wherein the starter compound is a Guerbet alcohol.