Patent Description:
The enamel layer of the tooth is naturally an opaque white or slightly off-white colour. However, this enamel layer can become stained or discoloured. Many products we consume have a negative impact on our teeth and mouth. Many substances can stain or reduce the whiteness of one's teeth, in particular, certain foods, tobacco products, and fluids such as tea and coffee. These staining and discolouring substances are often able to permeate the enamel layer. This problem occurs gradually over many years, but imparts a noticeable discoloration of the enamel of one's teeth.

Consumers have always had a strong desire for healthy and white teeth. Benefit agents such as optical agents and antimicrobial agents are commonly incorporated in oral care products to provide benefits such as whitening and better oral hygiene. Many oral care products, however, do not provide sufficient benefit agents deposition on teeth. The benefit agents are simply rinsed away during daily oral hygiene routine like tooth brushing and therefore provide little or no benefits.

Therefore, there is continuing need for an oral care composition which delivers improved deposition of benefit agents on teeth to maximize the effectiveness of such benefit agents.

<CIT> (<NUM> Innovative Properties Company) discloses a composition comprising from <NUM> wt% to <NUM> wt% total of arginine, glycine, or a combination thereof based on the total weight of the composition; and from <NUM> wt% to <NUM> wt% total of one or more surfactants, based on the total weight of the composition, of Formula I: HOCH<NUM>-(CHOH)n-CH<NUM>NR<NUM>R<NUM> (I) wherein R<NUM> and R2 are independently selected from the group consisting of a hydrogen atom, an alkyl group, C(O)R<NUM>, and SO2R<NUM>; with R<NUM> and R<NUM> being independently selected from the group consisting of an alkyl group, an aryl group, and an aralkyl group; wherein n is an integer from about <NUM> to about <NUM>.

<CIT> discloses an oral care composition comprising an orally acceptable vehicle and one or more surfactants. The one or more surfactants may include an N-alkyl-N-acylglucamine.

<CIT>discloses compositions that include from <NUM>. 1wt% to 8wt% of one or more compounds of formula based on the total weight of the composition HOCH<NUM>-(CHOH)n-CH<NUM>NR<NUM>R<NUM> wherein R<NUM> and R2 are independently selected from the group consisting of a hydrogen atom, an alkyl group, C(O)R<NUM>, and SO<NUM>R<NUM>; with R<NUM> and R<NUM> being independently selected from the group consisting of an alkyl group, an aryl group, and an aralkyl group; wherein n is an integer from about <NUM> to about <NUM>; from 5wt% to 95wt% of one or more plant based oils based on the total weight of the composition; from 5wt% to 80wt% water based on the total weight of the composition and from <NUM>. 01wt% to 1wt% of one or more nonionic aromatic phenolic preservatives based on the total weight of the composition wherein the composition has a pH from <NUM> to <NUM>, the composition is an emulsion, and the composition is edible.

In a first aspect, the present invention is directed to an oral care composition comprising:.

wherein the deposition polymer comprises xanthan gum, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, γ-polyglutamic acid, heparin sodium salt, a copolymer of methyl vinyl ether and maleic anhydride, polyacrylic acid, polystyrene sulfonate, deoxyribonucleic acids, poly(allylamine), locust bean gum, guar gum, polyglycolic acid, polylactic acid, poly(glycolic-co-lactic acid), chitosan, humic acid, phytate acid, derivatives or mixtures thereof.

In a second aspect, the present invention is directed to a packaged oral care product comprising the oral care composition of the first aspect of this invention.

In a third aspect, the present invention is directed to a method of whitening teeth and/or improving the oral hygiene of an individual comprising the steps of applying the composition of any embodiment of the first aspect to at least one surface of the teeth of the individual.

All amounts are by weight of the final oral care composition, unless otherwise specified. It should be noted that in specifying any ranges of values, any particular upper value can be associated with any particular lower value.

The oral care composition of the invention comprises a deposition polymer. The term "deposition polymer", as used herein, means a polymer which aids deposition of benefit agents from the continuous phase of the composition onto the surface of teeth during use of the composition. Use of the composition in the context of this invention typically involves application of the composition to the oral cavity, followed by brushing and/or rinsing. The deposition polymer enhances the deposition of the benefit agents onto the surfaces of teeth and thereby enhances the performance of the composition. Suitable deposition polymers for use in the invention may be naturally or synthetically-derived.

The deposition polymers for use in the invention include, xanthan gum, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, γ-polyglutamic acid, heparin sodium salt, a copolymer of methyl vinyl ether and maleic anhydride, polyacrylic acid, polystyrene sulfonate, deoxyribonucleic acids, poly(allylamine), locust bean gum, guar gum, polyglycolic acid, polylactic acid, poly(glycolic-co-lactic acid), chitosan, humic acid, phytate acid, derivatives or mixtures thereof. Preferably the deposition polymer comprises xanthan gum, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, γ-polyglutamic acid, phytate acid, derivatives or mixtures thereof.

It is preferred that the deposition polymer is xanthan gum and/or its derivatives.

Xanthan gum is an extracellular polysaccharide secreted by the microorganism Xanthomonas campestris. It is a linear (<NUM>, <NUM>)-linked β-D-glucose backbone (as in cellulose) with a trisaccharide side chain on every other glucose at C-<NUM>. This side chain comprises a glucuronic acid residue linked (<NUM>, <NUM>) to a terminal mannose unit and (<NUM>, <NUM>) to a second mannose that connects to the backbone. Approximately <NUM>% of the terminal mannose residues are pyruvated and the non-terminal residue usually carries an acetyl group at C-<NUM>.

The structure of xanthan gum is given below:
<CHM>.

Wherein n ranges from <NUM> to <NUM>,<NUM>, preferably from <NUM> to <NUM>,<NUM>, more preferably from <NUM> to <NUM>,<NUM>, most preferably from <NUM>,<NUM> to <NUM>,<NUM>.

The xanthan gum derivatives can be prepared by etherification, esterification, acetalation, amidation or oxidation of non-derivatized xanthan gum. Preferred xanthan gum derivatives are prepared by reacting non-derivatized gum with quaternary ammonium compounds in an amount equal to or greater than the stoichiometric amount required for complete derivatization. The quaternary ammonium compounds are preferably having a single alkyl or alkenyl substituent containing from <NUM> to <NUM> carbon atoms, and/or two alkyl or alkenyl substituents of <NUM> to <NUM> carbon atoms per substituent. Most preferably, the quaternary ammonium compound is alkyl dimethylbenzylammonium chloride with an alkyl group containing from <NUM> to <NUM> carbon atoms.

The oral care composition comprises the deposition polymer in an amount of from <NUM> to <NUM>%, preferably from <NUM> to <NUM>%, more preferably from <NUM> to <NUM>% and most preferably from <NUM> to <NUM>%, based on total weight of the oral care composition and including all ranges subsumed therein.

The polyhydroxy fatty acid amide surfactant suitable for use the invention is a non-ionic surfactant represented by the general formula (I):
<CHM>
wherein R<NUM> is a C<NUM>-C<NUM> alkyl group or hydroxy-substituted C<NUM>-C<NUM> alkyl groups; R<NUM> is a linear or branched, saturated or unsaturated hydrocarbon chain having <NUM> to <NUM> carbon atoms.

R<NUM> is preferably a C<NUM>-C<NUM> alkyl group, more preferably is a methyl group.

R<NUM> is preferably an alkyl group, an alkenyl group, an aryl group, or an aralkyl group having <NUM> to <NUM> carbon atoms, more preferably <NUM> to <NUM> carbon atoms and most preferably <NUM> to <NUM> carbon atoms.

It is preferred that R<NUM> is a methyl group and R<NUM> is an alkyl group having <NUM> to <NUM> carbon atoms, more preferably <NUM> to <NUM> carbon atoms, and most preferably <NUM> to <NUM> carbon atoms.

Preferably, the polyhydroxy fatty acid amide surfactant comprises at least <NUM>% by weight of a polyhydroxy fatty acid amide with R<NUM> being a methyl group and R<NUM> being a C<NUM> alkyl group, more preferably from <NUM> to <NUM>%, more preferably still from <NUM> to <NUM>% and most preferably from <NUM> to <NUM>%, based on total weight of the polyhydroxy fatty acid amide.

It is particularly preferred that the surfactant is polyhydroxy fatty acid amide with R<NUM> being a methyl group and R<NUM> being a C<NUM> alkyl group.

The composition of the present invention may additionally have small fractions of polyhydroxy fatty acid amide having short hydrocarbon chains, in particular wherein R<NUM> is a C<NUM>-C<NUM>, C<NUM>, C<NUM>, C<NUM>, C<NUM>, C<NUM> alkyl group or an C<NUM>, C<NUM>, C<NUM>, C<NUM>, C<NUM>, C<NUM>, C<NUM> alkenyl group.

One example of a polyhydroxy fatty acid amide surfactant suitable for use in this invention is sunfloweroyl methyl glucamide commercially available as GlucoPure® Sense from Clariant International Ltd.

The oral care composition typically comprises the polyhydroxy fatty acid amide in an amount of from <NUM> to <NUM>% by weight of the composition, more preferably from <NUM> to <NUM>% and most preferably from <NUM> to <NUM>%, based on total weight of the oral care composition and including all ranges subsumed therein.

Benefit agent, as used herein, means an active typically delivered to human teeth and/or the oral cavity including the gums to enhance or improve a characteristic of those dental tissues. The only limitation with respect to the benefit agent that may be used in this invention is that the same is suitable for use in the mouth.

Typically benefit agent includes, for example, optical agents, biomineralization agents, adsorbing agents, antimicrobial agents, gum health agents, desensitizing agents, anti-calculus agents, freshness agents or mixtures thereof. Preferably the benefit agent is selected from optical agents, antimicrobial agents and mixtures thereof.

Optical agents may be selected from one or more of whitening agents and pearlescent agents. When the optical agent is a whitening agent, it is preferable that the whitening agent is a dye or a pigment or a combination of the two. The pigment according to the invention is a shade/material which is insoluble in the relevant medium, at the relevant temperature. This is in contrast to dyes which are soluble. The term "relevant medium", as used herein, refers to human saliva, the liquid medium in which the composition is used, at the temperature of the oral cavity during brushing of the teeth, i.e. up to <NUM>. The relevant medium may also be water and the relevant temperature to be <NUM>. Preferred pigment or dye for use in the present invention is violet or blue having a hue angle, h, in the CIELAB system of from <NUM> to <NUM> degrees, preferably from <NUM> to <NUM> degrees. When the whitening agent is a pigment, it is preferable that the pigment is violet or blue selected from one or more of those listed in the Colour Index International as pigment blue <NUM> through to pigment blue <NUM> and pigment violet <NUM> through to pigment violet <NUM>. Other suitable pigments are pigment ultramarine blue and ultramarine violet. While the preferred pigment is blue or violet, the same effect may be achieved through mixing pigments outside of this hue angle range. For example, such a hue angle may also be obtained by mixing a red and green-blue pigment to yield a blue or violet shaded pigment. It is particularly preferred that the pigment is a blue pigment. A preferred class of blue pigments suitable for use in the invention are organic blue pigments such as phthalocyanine blue pigments. It is especially preferred that the pigment is phthalocyanine blue pigment selected from alpha copper phthalocyanines Pigment Blue <NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM> and mixtures thereof, more preferably Pigment Blue <NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM> and mixtures thereof. Most preferably the pigment is Pigment Blue <NUM>:<NUM>. A commercially available example is Cosmenyl Blue A4R from Clariant. When the whitening agent is a dye, it is preferable that the dye is a blue dye, more preferably FD&C Blue <NUM>, Patent Blue V or Gardenia Blue.

In another preferred embodiment, the whitening agent is a particulate whitening agent having a refractive index of from <NUM> to <NUM>. The refractive index is quoted at a temperature of <NUM> and a wavelength of <NUM>. Suitable materials to provide such a high refractive index are metal compounds and preferred are compounds where the metal is selected from zinc (Zn), titanium (Ti), zirconium (Zr) or a mixture thereof. Preferably, the metal compound is (or at least comprises) a metal oxide such as titanium dioxide (TiO<NUM>), zinc oxide (ZnO), zirconium dioxide (ZrO<NUM>) or a mixture thereof. Preferably, the particulate whitening agent is a composite particle. The term "Composite particle", as used herein, means a particle comprising a first component core and a second component coating wherein the core and coating are composed of different materials. The composite particle comprises a first component core and a second component coating. Particularly suitable core materials are metal compounds and preferred are compounds where the metal is selected from zinc (Zn), titanium (Ti), zirconium (Zr) or a mixture thereof. Preferably, the metal compound is (or at least comprises) a metal oxide such as titanium dioxide (TiO<NUM>), zinc oxide (ZnO), zirconium dioxide (ZrO<NUM>) or a mixture thereof. The second component coating comprises material suitable to adhere to tooth enamel, dentin or both. Typically the coating material comprises the element calcium, and optionally, other metals like potassium, sodium, aluminium, magnesium as well as mixtures thereof whereby such optional metals are provided as, for example, sulphates, lactates, oxides, carbonates or silicates. Optionally, the coating material may be aluminium oxide or silica. In a preferred embodiment, the second component coating can comprise, for example, calcium phosphate, calcium gluconate, calcium oxide, calcium lactate, calcium carbonate, calcium hydroxide, calcium sulphate, calcium carboxymethyl cellulose, calcium alginate, calcium salts of citric acid, calcium silicate, mixture thereof or the like. Calcium silicate is particularly preferred. In an especially preferred embodiment, the particulate whitening agent is titanium dioxide coated with calcium silicate.

In another preferred embodiment, the optical agent is a pearlescent agent. The term "pearlescent", as used herein, means an agent in the form of particles which reflects and partially transmits the incident light. Suitable pearlescent agent for use in the present invention includes mica, bismuth oxychloride or mixtures thereof. Preferably the pearlescent agent is formed by coating one or more metal oxide layers onto natural or synthetic mica flakes. Examples of suitable mica include, for example, muscovite, phlogopite, fluorophlogopite, biotite or mixtures thereof. Examples of suitable metal oxides include, for example, TiO<NUM>, Fe<NUM>O<NUM>, TiFe<NUM>O<NUM>, Fe<NUM>O<NUM>, Cr<NUM>O<NUM>, Al<NUM>O<NUM>, SiO<NUM>, ZrO<NUM>, ZnO, SnO<NUM>, CoO, Co<NUM>O<NUM>, VO<NUM>, V<NUM>O<NUM>, Sn(Sb)O<NUM>, titanium suboxides or mixtures thereof. One example of a preferred pearlescent agent is mica coated with TiO<NUM>.

Antimicrobial agents may be selected from one or more of metal compounds where the metal is selected from zinc, copper, silver or a mixture thereof, triclosan, triclosan monophosphate, triclocarban, curcumin, quaternary ammonium compounds, bisbiguanides and long chain tertiary amines, preferably zinc compounds including zinc oxide, zinc chloride, zinc acetate, zinc ascorbate, zinc sulphate, zinc nitrate, zinc citrate, zinc lactate, zinc peroxide, zinc fluoride, zinc ammonium sulfate, zinc bromide, zinc iodide, zinc gluconate, zinc tartarate, zinc succinate, zinc formate, zinc phenol sulfonate, zinc salicylate, zinc glycerophosphate or a mixture thereof. Zinc citrate is particularly preferred.

It is preferred that the benefit agent is an optical agent selected from pigments, dyes, mica, mica coated with TiO<NUM>, titanium dioxide, titanium dioxide coated with calcium silicate and mixtures thereof. More preferably the benefit agent is a phthalocyanine blue pigment is selected from alpha copper phthalocyanines Pigment Blue <NUM>, Pigment Blue <NUM>:<NUM>, Pigment Blue <NUM>:<NUM> and mixtures thereof. Pigment Blue <NUM>:<NUM> is particularly preferred.

It is also preferred that the benefit agent is zinc compounds selected from zinc oxide, zinc chloride, zinc acetate, zinc ascorbate, zinc sulphate, zinc nitrate, zinc citrate, zinc lactate, zinc peroxide, zinc fluoride, zinc ammonium sulfate, zinc bromide, zinc iodide, zinc gluconate, zinc tartarate, zinc succinate, zinc formate, zinc phenol sulfonate, zinc salicylate, zinc glycerophosphate and mixtures thereof. Zinc citrate is particularly preferred.

The oral care composition of the present invention may comprise a single benefit agent or a mixture of two or more benefit agents. Typically, the benefit agent is present in an amount from <NUM> to <NUM>%, and more preferably, from <NUM> to <NUM>%, and most preferably from <NUM> to <NUM>% by total weight of the oral care composition and including all ranges subsumed therein.

When the benefit agent is a pigment, the pigment is preferably present at a level of from <NUM> to <NUM>% by weight of the oral care composition, more preferably from <NUM> to <NUM>%, most preferably from <NUM> to <NUM>%, based on total weight of the oral care composition and including all ranges subsumed therein.

Preferably, the oral care composition has a pH from <NUM> to <NUM>, more preferably from <NUM> to <NUM>, and most preferably from <NUM> to <NUM>. The pH of oral care composition is measured when <NUM> parts by weight of the composition is uniformly dispersed and/or dissolved in <NUM> parts by weight pure water at <NUM>. In particular, the pH may be measured by manually mixing <NUM> oral care composition with <NUM> water for <NUM>, then immediately testing the pH with indicator or a pH meter.

The oral care composition may comprise other surfactants in addition to the polyhydroxy fatty acid amide. Suitable surfactants include anionic surfactants, such as the sodium, magnesium, ammonium or ethanolamine salts of C<NUM> to C<NUM> alkyl sulphates (for example sodium lauryl sulphate), C<NUM> to C<NUM> alkyl sulphosuccinates (for example dioctyl sodium sulphosuccinate), C<NUM> to C<NUM> alkyl sulphoacetates (such as sodium lauryl sulphoacetate), C<NUM> to C<NUM> alkyl sarcosinates (such as sodium lauryl sarcosinate), C<NUM> to C<NUM> alkyl phosphates (which can optionally comprise up to <NUM> ethylene oxide and/or propylene oxide units) and sulphated monoglycerides. Other suitable surfactants include non-ionic surfactants, such as polyethoxylated fatty acid sorbitan esters, ethoxylated fatty acids, esters of polyethylene glycol, ethoxylates of fatty acid monoglycerides and diglycerides, and ethylene oxide/propylene oxide block polymers. Other suitable surfactants include amphoteric surfactants, such as betaines or sulphobetaines. Mixtures of any of the above described materials may also be used. More preferably the surfactant comprises or is an anionic surfactant. The preferred anionic surfactants are sodium lauryl sulphate and/or sodium dodecylbenzene sulfonate. Most preferably the surfactant is sodium lauryl sulphate, sodium coco sulfate, cocamidopropyl betaine, sodium methyl cocoyl taurate or mixtures thereof.

When the oral care composition comprises surfactants in addition to the polyhydroxy fatty acid amide, the surfactant is typically present at a level from <NUM> to <NUM>% by weight of the composition, more preferably from <NUM> to <NUM>% and most preferably from <NUM> to <NUM>%, based on total weight of the oral care composition and including all ranges subsumed therein.

The oral care composition of the present invention may comprise a physiologically acceptable carrier. Water is the most common carrier for this invention. The carrier may further comprise at least thickener, humectant or a combination thereof.

Thickener may be used in this invention in addition to the deposition polymer which is included in the oral care composition and is limited only to the extent that the same may be added to a composition suitable for use in the mouth. Illustrative examples of the types of thickeners that may be used in this invention include, sodium carboxymethyl cellulose (SCMC), hydroxyl ethyl cellulose, methyl cellulose, ethyl cellulose, silica based thickeners including silica aerogels, magnesium aluminum silicate (e.g., Veegum) and mixtures thereof.

Sodium carboxymethyl cellulose is typically preferred. The copolymer which is included in the composition can also behave as a thickener.

In an especially preferred embodiment, the sodium carboxymethyl cellulose (SCMC) used is SCMC <NUM>. It has been described as a sodium salt of a cellulose derivative with carboxymethyl groups bound to hydroxy groups of glucopyranose backbone monomers and identified via <NPL>. The same is available from suppliers like Alfa Chem.

Thickener typically makes up from <NUM> to about <NUM>%, more preferably from <NUM> to <NUM>%, and most preferably, from <NUM> to <NUM>% by weight of the oral care composition, based on total weight of the composition and including all ranges subsumed therein.

Suitable humectants are preferably used in the oral care composition of the present invention and they include, for example, glycerin, sorbitol, propylene glycol, dipropylene glycol, diglycerol, triacetin, mineral oil, polyethylene glycol (preferably, PEG-<NUM>), alkane diols like butane diol and hexanediol, ethanol, pentylene glycol, or a mixture thereof. Glycerin, polyethylene glycol, sorbitol or mixtures thereof are the preferred humectants.

The carrier is typically present at a level of from <NUM> to <NUM>% by weight of the oral care composition, more preferably <NUM> to <NUM>%, and most preferably from <NUM> to <NUM>% by weight of the composition, based on total weight of the composition and including all ranges subsumed therein.

The oral care composition of the present invention may contain a variety of other ingredients in addition to the benefit agent that is included in the composition, which are common in the art to enhance physical properties and performance. These ingredients include preservatives, pH-adjusting agents, sweetening agents, particulate abrasive materials, buffers and salts to buffer the pH and ionic strength of the compositions, and mixtures thereof. Such ingredients typically and collectively make-up less than <NUM>% by weight of the composition, and preferably, from <NUM> to <NUM>% by weight, and most preferably, from <NUM> to <NUM>% by weight of the composition, including all ranges subsumed therein.

The oral care composition of this invention can be used in a method of benefiting teeth of an individual comprising the steps of applying the composition to at least one surface of the teeth of an individual. In particular, the oral care composition of this invention can be used in a method of whitening teeth and/or improving oral hygiene of an individual comprising the steps of applying the composition to at least one surface of the teeth of the individual. Preferably, the method is non-therapeutic. The oral care composition of this invention may additionally or alternatively be used for whitening teeth and/or improving oral hygiene of an individual and/or used in the manufacture of a medicament for whitening teeth and/or improving oral hygiene of an individual. Preferably, the use is non-therapeutic.

Typically, the composition will be packaged. In toothpaste or gel form, the composition may be packaged in a conventional plastic laminate, metal tube or a single compartment dispenser. The same may be applied to dental surfaces by any physical means, such as a toothbrush, fingertip or by an applicator directly to the sensitive area. In liquid mouthwash form the composition may be packaged in a bottle, sachet or other convenient container.

The oral care composition of the invention is preferably a toothpastes or gel. When the oral care composition is a toothpaste or gel, the same typically has a viscosity from about <NUM>,<NUM> to <NUM>,<NUM> centipoise, and preferably, from <NUM>,<NUM> to <NUM>,<NUM> centipoise, and most preferably, from <NUM>,<NUM> to <NUM>,<NUM> centipoise, taken at room temperature (<NUM>) with a Brookfield Viscometer, Spindle No.<NUM>/<NUM> and at a speed of <NUM> rpm for <NUM> minute.

The composition can be effective even when used in an individual's daily oral hygiene routine. For example, the composition may be brushed onto the teeth and/or be rinsed around the inside of the mouth of the individual. The composition may, for example, be contacted with the teeth for a time period of one second to <NUM> hours. More preferably from <NUM> to <NUM> hours, more preferably still from <NUM> to <NUM> hour and most preferably from <NUM> to <NUM> minutes. The composition may be used daily, for example for use by an individual once, twice or three times per day.

The following examples are provided to facilitate an understanding of the present invention. The examples are not provided to limit the scope of the claims.

This example demonstrated the deposition of pigments. All ingredients are expressed by weight percent of the total formulation, and as level of active ingredient.

To evaluate the deposition of pigments, the following in vitro test was carried out. The colour difference expressed as the CIELAB delta E (ΔE) value was calculated based on L*, a*, b* values measured using DigiEye (VeriVide, England) with the following formula: <MAT>.

Hydroxyapatite (HAP) discs were used as substrates. The baseline L*, a*, b* of the HAP discs was measured by DigiEye (VeriVide, England). Four HAP discs were used for each sample. The HAP discs were soaked in de-ionized (DI) water for <NUM> hour before they were immersed in different samples for <NUM> hours. Thereafter the HAP discs were rinsed with <NUM> DI water and shaken by hand gently for <NUM> times. The residual water on HAP discs was absorbed with tissue. After this step the L*, a*, b* values of each HAP disc were remeasured based on which the delta E (ΔE) from baseline were calculated and statistically analyzed.

The results are summarized in table <NUM>. The higher the average ΔE value the more deposition of the pigment.

Claim 1:
An oral care composition comprising:
(a) from <NUM> to <NUM>% by weight of a deposition polymer;
(b) a polyhydroxy fatty acid amide surfactant of formula (I):
<CHM>
wherein R<NUM> is a C<NUM>-C<NUM> alkyl group or hydroxy-substituted C<NUM>-C<NUM> alkyl groups;
R<NUM> is a linear or branched, saturated or unsaturated hydrocarbon chain having <NUM> to <NUM> carbon atoms; and
(c) a benefit agent selected from optical agents, antimicrobial agents and mixtures thereof;
wherein the deposition polymer comprises xanthan gum, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, γ-polyglutamic acid, heparin sodium salt, a copolymer of methyl vinyl ether and maleic anhydride, polyacrylic acid, polystyrene sulfonate, deoxyribonucleic acids, poly(allylamine), locust bean gum, guar gum, polyglycolic acid, polylactic acid, poly(glycolic-co-lactic acid), chitosan, humic acid, phytate acid, derivatives or mixtures thereof.