Patent Description:
An organic solar cell has gained more and more attention due to its low price, light weight, good bending property, large area printing and other advantages. In recent years, with unremitting efforts of scientists, the photoelectric conversion efficiency of the organic solar cell has exceeded <NUM>% and gradually approaches a commercialization threshold. In comparison, the stability property of the current organic solar cell device is far from satisfying application demands.

Considerable research results show that during the working, the organic solar cell can generate a phenomenon of rapid attenuation, called "burn-in loss", in the beginning <NUM> hours. This process generally occurs in the initial working period of the device. Although it lasts for <NUM> hours, the properties of the device are attenuated by <NUM>-<NUM>%, thereby seriously influencing the stability and service life of the device. Such the process is considered as attenuation of the properties of the device caused by failure in the organic photoactive layer. Thus, improvement of the stability property of the photoactive layer is an important method for improving the stability of the organic solar cell device. At present, the method for improving the stability of the photoactive layer structure is performed mainly through design synthesis of a donor material and development and use of a non-fullerene material, and there are few appropriate manners which do not affect the efficiency of the device and can improve the stability of the device on the premise that the material in the active layer is not changed. <CIT> describes an additive for improving the light stability of a conjugated polymer, a method for preparing the same and an organic photovoltaic cell containing the same. <CIT> describes that the additive can be used for an organic photovoltaic (OPV) cell device and can also be usefully used for an organic optoelectronic device using a conductive polymer, such as an organic photodiode (OPD), an organic thin0film transistor (OTFT), an organic light-emitting diode (OLED), etc..

The main objective of the disclosure is to provide an organic photoactive layer composite ink and a preparation method thereof to overcome the shortages of the prior art.

Another main objective of the disclosure is to provide an organic solar cell prepared by utilizing the organic photoactive layer composite ink and a preparation method thereof.

In order to achieve the aforementioned objectives, the present invention provides an organic photoactive layer composite ink as defined in claims <NUM> to <NUM>, a preparation method of the organic photoactive layer composite ink as defined in claim <NUM>, an organic photoactive layer composite film as defined in claims <NUM> to <NUM>, a preparation method of the organic photoactive layer composite film as defined in claims <NUM> to <NUM>, an organic solar cell as defined in claim <NUM>, and a preparation method of the organic solar cell as defined in claim <NUM>.

Compared with the prior art, the disclosure has the advantages:.

Reference numbers: <NUM>-top electrode, <NUM>-top electrode interface modification layer, <NUM>-organic photoactive layer, <NUM>-bottom electrode interface modification layer, <NUM>-bottom electrode, and <NUM>-bottom electrode base.

In view of the shortages of the prior art, the present inventor provides the technical solution of the disclosure via long-term research and significant practice. Next, this technical solution, its implementation process and principle and the like will be further explained and illustrated.

In claim <NUM>, preferably, C1~C20 alkyl includes, but is not limited to methyl, ethyl, propyl and butyl.

The electron donor material refers to a semiconductor material whose molecule can give electrons in an organic solar cell photoactive layer under the condition of light excitation so as to achieve charge separation. In some embodiments, the electron donor material comprises a conjugated polymer electron donor material and/or a conjugated small organic molecule electron donor material.

Preferably, the conjugated polymer electron donor material comprises any one or a combination of two or more of poly(<NUM>-hexylthiophene), PTB7, PTB7-Th (<NPL>), PffBT4T-2OD (<NPL>, <NUM>) and structure variants thereof, but is not limited thereto.

Preferably, the conjugated small organic molecule electron donor material comprises a micromolecule based on benzodithiophene (BDT) as a core and a micromolecule based on oligothiophene as a core.

For example, preferably, the conjugated small organic molecule electron donor material comprises DR3TSBDT (<NPL>. ), <NPL>) and structure variants thereof.

The electron acceptor material refers to a semiconductor material whose molecule can receive electrons in an organic solar cell photoactive layer under the condition of light excitation so as to achieve charge separation. In some embodiments, the electron acceptor material comprises any one or a combination of two or more of a fullerene electron acceptor material, a fullerene derivative electron acceptor material and a non-fullerene electron acceptor material, but is not limited thereto.

Preferably, the fullerene electron acceptor material and the fullerene derivative electron acceptor material comprise any one or a combination of two or more of [<NUM>,<NUM>]-phenyl-C<NUM>-methyl butyrate (PC<NUM>BM), PC<NUM>BM (<NPL>), Bis-PC<NUM>BM (<NPL>. ) and IC<NUM>BA (<NPL>. ), but is not limited thereto.

Preferably, the non-fullerene electron acceptor material comprises an organic conjugated electron acceptor material.

More preferably, the organic conjugated electron acceptor material comprises any one or a combination of two or more of a perylene diimide (PDI) derivative, a naphthdiimide (NDI) derivative, an indacene derivative, a fluorene derivative, a benzothiadiazole (BT) derivative and a subphthalocyanine (SubPc) derivative, but is not limited thereto.

Another aspect of an embodiment of the disclosure provides a preparation method of the aforementioned organic photoactive layer composite ink, comprising: dissolving an organic amine compound, an electron acceptor material and an electron donor material into an organic solvent, and uniformly mixing to obtain the organic photoactive layer composite ink.

Another aspect of an embodiment of the disclosure also provides an organic photoactive layer composite film formed by the aforementioned organic photoactive layer composite ink.

In some embodiments, the organic photoactive layer composite film comprises a complex formed by combination of any one or a combination of two or more of poly(<NUM>-hexylthiophene), PTB7, PTB7-Th, PffBT4T-2OD and structure variants thereof as an electron donor material, any one or a combination of two or more of [<NUM>,<NUM>]-phenyl-C<NUM>-methyl butyrate, PC<NUM>BM, Bis-PC<NUM>BM and IC<NUM>BA as an electron acceptor material, and an organic amine compound having a structure as shown in any one of Formulas (<NUM>), (<NUM>), (<NUM>-<NUM>) and (<NUM>-<NUM>).

Preferably, the thickness of the organic photoactive layer composite film is <NUM>~<NUM>, preferably, <NUM>~<NUM>, and especially preferably, <NUM>~<NUM>.

Further, an embodiment of the disclosure also provides a preparation method of aforementioned the organic photoactive layer composite film, comprising: performing film formation treatment on the organic photoactive layer composite ink to form the organic photoactive layer composite film.

Preferably, the film formation treatment manner comprises at least one of a dropping film process, a spin-coating film formation process, a spray-coating film formation process, an ink-jet printing film formation process, a silk-screen printing film formation process, a blade coating film formation process and a wire bar coating process.

In some particular embodiments, the preparation method comprises: applying the organic photoactive layer composite ink to a substrate by at least selecting any one of coating and printing manners to construct and form the organic photoactive layer composite film.

Preferably, the coating manner comprises any one of spin coating, blade coating and spray coating.

Preferably, the film formation treatment also comprises: performing thermal treatment and/or solvent annealing treatment on the organic photoactive layer composite film.

Preferably, the organic photoactive layer composite film is subjected to thermal treatment at a temperature of <NUM>~<NUM> for <NUM>~<NUM>.

Preferably, a solvent for the solvent annealing treatment comprises any one or a combination of two or more of methylbenzene, dimethylformamide, tetrahydrofuran, chloroform, o-dichlorobenzene and chlorobenzene, but is not limited thereto.

Further, the time for the solvent annealing treatment is <NUM>~<NUM>.

Another aspect of an embodiment of the disclosure also provides application of the aforementioned organic photoactive layer composite ink or organic photoactive layer composite film in preparation of an organic solar cell.

Referring to <FIG>, an embodiment of the disclosure also provides an organic solar cell, comprising a top electrode <NUM>, a top electrode interface modification layer <NUM>, an organic photoactive layer <NUM>, a bottom electrode interface modification layer <NUM>, a bottom electrode <NUM> and a bottom electrode base <NUM> which are arranged in turn along a setting direction, and the organic photoactive layer <NUM> comprises the aforementioned organic photoactive layer composite film.

The disclosure also provides a laminated organic solar cell whose front junction and/or rear junction cells contain the above organic solar cell.

Further, an embodiment of the disclosure also provides a preparation method of the aforementioned solar cell, comprising:.

Further, in the aforementioned step (<NUM>), the bottom electrode base is washed before the bottom electrode is formed on the bottom electrode base.

In some embodiments, the step (<NUM>) comprises: performing thermal treatment and/or solvent annealing treatment on the organic photoactive layer composite film, and then preparing a top electrode interface modification layer on the organic photoactive layer composite film.

Preferably, a solvent for the solvent annealing treatment comprises any one or a combination of two or more of methylbenzene, dimethylformamide (DMF), tetrahydrofuran, chloroform, o-dichlorobenzene and chlorobenzene, but is not limited thereto.

Further, the time of the solvent annealing treatment is <NUM>~<NUM>.

Further, any step prior to the step (<NUM>) also comprises: preparing the organic photoactive layer composite ink.

In some particular embodiments, the preparation method particularly comprises the following steps:.

In order to make the purposes, technical solutions and advantages of the disclosure more clear, the technical solutions of the disclosure will be further described in detail in combination with embodiments and drawings below. If not especially stated, the methods in the following embodiments are all conventional methods in the art.

Comparative example <NUM>: preparation of an inverted polymer organic solar cell based on poly(<NUM>-hexylthiophene) (P3HT):[<NUM>,<NUM>]-phenyl-C<NUM>-methyl butyrate (PC<NUM>BM) as an organic photoactive layer.

First, a substrate consisting of a transparent substrate and an indium tin oxide (ITO) transparent conducting cathode sequentially undergoes ultrasonic washing with a washing agent, deionized water, acetone and isopropanol, with each step for <NUM>. After being dried with nitrogen, the washed substrate is treated for <NUM> using a UVO ozone washing machine. A ZnO cathode buffer layer is prepared on the treated substrate. ZnO acetone solution is spin coated on the substrate by using a spin coating method, the rotation speed of a spin coater is 2000rpm/s, and spin coating time is <NUM>. Then, annealing is carried out for <NUM> at <NUM>. An organic photoactive layer is prepared on the cathode buffer layer by using the spin coating method. This organic photoactive layer is prepared by dissolving an electron donor material P3HT and an electron acceptor material PC<NUM>BM into o-dichlorobenzene in a mass percent of <NUM>:<NUM> to be mixed. The organic photoactive layer is prepared in a glove box by using the spin coating method, with the rotation speed of 600rpm/s, time of <NUM> and a thickness of about <NUM>. After spin-coating film formation, solvent annealing is carried out for <NUM> in a watch glass with a cover, and then the substrate is put on a heating plate and undergoes thermal annealing for <NUM> at <NUM>. Subsequently, the substrate is brought into a vacuum coating machine, anode buffer layer molybdenum oxide (MoO<NUM>) (a thickness is <NUM>, and an evaporation rate is <NUM>-<NUM>Å/s) and metal anode Al (a thickness is <NUM>, and an evaporation rate is <NUM>Å/s) are sequentially deposited on the organic photoactive layer. The prepared solar cell is measured under standard conditions (AM1. <NUM>, <NUM> mW/cm<NUM>), and current density-voltage curve data is collected using a Keithley <NUM> digital source table.

The structure of the organic solar cell prepared in this comparative example is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM/MoO<NUM>/Al (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in comparative example <NUM>, and other specific device property parameters are listed in Table <NUM>. It can be seen from experimental results that the photoelectric conversion efficiency of a P3HT:PC<NUM>BM cell having a standard structure is <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and piperazine into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, and the contents of piperazine are respectively 1wt%, 3wt%, 5wt%, 7wt% and 10wt% of the total masses of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM: piperazine/Al (<NUM>), wherein, the structure of piperazine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device property parameters are listed in Table <NUM>. It can be seen from experimental results that when the doping amount of piperazine is <NUM>-<NUM>%, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is <NUM>% to the greatest extent. When the doping amount ranges from <NUM>% to <NUM>%, the properties of the device are all higher than or equal to those of the device without doping of piperazine, illustrating the doping range of piperazine is extremely wide.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and N,N'-dimethyl ethylenediamine into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, and the content of N,N'-dimethyl ethylenediamine is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:N,N'-dimethyl ethylenediamine/MoO<NUM>/Al (<NUM>), wherein, the structure of N,N'-dimethyl ethylenediamine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device property parameters are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of N,N'-dimethyl ethylenediamine is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material PTB7-Th, an electron acceptor material PC<NUM>BM and piperazine (different concentrations) into chlorobenzene (added with DIO having a volume ratio of <NUM>%) to be mixed, wherein, the mass percent of PTB7-Th to PC<NUM>BM is <NUM>:<NUM>, the concentration of PTB7-Th is <NUM>/mL, and the content of piperazine is <NUM>-<NUM>. 2wt% of the total mass of PTB7-Th and PC<NUM>BM. The organic photoactive layer is prepared in a glove box by using a spin coating method, with a rotation speed of 1000rpm/s, time of <NUM> and a thickness of about <NUM>. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/IP3HT:PTB7-Th:PC<NUM>BM:piperazine/MoO<NUM>/Al (<NUM>), wherein, the chemical structure of PTB7-Th is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of a <NUM>. 15wt% piperazine-doped organic solar cell prepared in embodiment <NUM>. It can be seen from experimental results that after <NUM>. 15wt% of piperazine is doped, the photoelectric conversion efficiency of the organic solar cell is <NUM>%.

First, a substrate consisting of a transparent substrate and an indium tin oxide (ITO) transparent conducting cathode sequentially undergoes ultrasonic washing with a washing agent, deionized water, acetone and isopropanol, with each step for <NUM>. After being dried with nitrogen, the washed substrate is treated for <NUM> using a UVO ozone washing machine. A PEDOT:PSS anode buffer layer is prepared on the treated substrate. The organic photoactive layer is prepared on the anode buffer layer by using a spin coating method. This organic photoactive layer is prepared by dissolving an electron donor material COOP-4HT-BDT, an electron acceptor material PC<NUM>BM and piperazne into chloroform to be mixed, wherein, in the mass percent of COOP-4HT-BDT to PC<NUM>BM is <NUM>:<NUM>, the concentration of COOP-4HT-BDT is <NUM>/mL, and the content of piperazine is <NUM>. 1wt% of the total mass of COOP-4HT-BDT and PC<NUM>BM. An organic photoactive layer is prepared in a glove box by using the spin coating method, with the rotation speed of 2500rpm/s, time of <NUM> and a thickness of about <NUM>. Then, the substrate is brought into a vacuum coating machine, and cathode buffer layer lithium fluoride (LiF) (a thickness is <NUM>, and an evaporation rate is <NUM>Å/s) and metal cathode Al (a thickness is <NUM>, and an evaporation rate is <NUM>Å/s) are sequentially deposited on the organic photoactive layer. The prepared organic solar cell is measured under standard conditions (AM1. <NUM>, <NUM> mW/cm<NUM>), and current density-voltage curve data is collected using a Keithley <NUM> digital source table.

The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/PEDOT:PSS/COOP-4HT-BDT:PC<NUM>BM:piperazine/LiF/Al (<NUM>), wherein, the structure of COOP-4HT-BDT is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device property parameters are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of piperazine is doped, the photoelectric conversion efficiency of the organic solar cell is <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material PTB7-Th, an electron acceptor material SBF-PDI<NUM> and piperazine into chloroform (added with chloronaphthalene having a volume ratio of <NUM>%) to be mixed, wherein, the mass percent of PTB7-Th to SBF-PDI<NUM> is <NUM>:<NUM>, the concentration of PTB7-Th is <NUM>/mL, the content of piperazine is <NUM>. 1wt% of the total mass of PTB7-Th and SBF-PDI<NUM>. The organic photoactive layer is prepared in a glove box by using a spin coating method, with a rotation speed of 2000rpm/s, time of <NUM> and a thickness of about <NUM>. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/PTB7-Th:SBF-PDI<NUM>:piperazine/MoO<NUM>/Al (<NUM>), wherein, the structure of PTB7-Th is seen in Formula (<NUM>).

As shown in <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after <NUM>. 1wt% of piperazine is doped, the photoelectric conversion efficiency of the organic solar cell is <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and polyetherimide into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, the content of polyetherimide is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:polyetherimide/MoO<NUM>/Al (<NUM>), wherein, the structure of polyetherimide is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of polyetherimide is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and <NUM>,<NUM>-diazabicyclo [<NUM>. <NUM>] octane into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, and the content of <NUM>,<NUM>-diazabicyclo [<NUM>. <NUM>] octane is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:<NUM>,<NUM>-diazabicyclo [<NUM>. <NUM>] octane/MoO<NUM>/Al (<NUM>), wherein, the structure of <NUM>,<NUM>-diazabicyclo [<NUM>. <NUM>] octane is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of <NUM>,<NUM>-diazabicyclo [<NUM>. <NUM>] octane is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and N,N'-diphenylethanediamine into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, the content of N,N'-diphenylethanediamine is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:N,N'-diphenylethanediamine/MoO<NUM>/Al (<NUM>), wherein, the structure of N,N'-diphenylethanediamine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of N,N'-diphenylethanediamine is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and <NUM>,<NUM>-dimethylpiperazine into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, the content of <NUM>,<NUM>-dimethylpiperazine is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:<NUM>,<NUM>-dimethylpiperazine/MoO<NUM>/Al (<NUM>), wherein, the structure of <NUM>,<NUM>-dimethylpiperazine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of <NUM>,<NUM>-dimethylpiperazine is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and <NUM>-(<NUM>-pyridyl) piperazine into trimethylbenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, the content of <NUM>-(<NUM>-pyridyl) piperazine is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:<NUM>-(<NUM>-pyridyl) piperazine/MoO<NUM>/Al (<NUM>), wherein, the structure of <NUM>-(<NUM>-pyridyl) piperazine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of <NUM>-(<NUM>-pyridyl) piperazine is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and pentaethylene hexaamine into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, and the content of pentaethylene hexaamine is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM:pentaethylene hexaamine/MoO<NUM>/Al (<NUM>), wherein, the structure of pentaethylene hexaamine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of pentaethylene hexaamine is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material PffBT4T-2OD, an electron acceptor material PC<NUM>BM and N,N'-diphenylethanediamine (Formula <NUM>) into trimethylbenzene and <NUM>-phenyl naphthalene to be mixed, wherein, the mass percent of PffBT4T-2OD to PC<NUM>BM is <NUM>:<NUM>, the content of N,N'-diphenylethanediamine is 1wt% of the total mass of PffBT4T-2OD and PC<NUM>BM. The volume ratio of <NUM>-phenyl naphthalene to trimethylbenzene is <NUM>:<NUM>. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/PffBT4T-2OD:PC<NUM>BM:N,N'-diphenylethanediamine/MoO<NUM>/Al (<NUM>), wherein, the structure of PffBT4T-2OD is seen in Formula (<NUM>) and the structure of N,N'-diphenylethanediamine is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of N,N'-diphenylethanediamine is doped, the photoelectric conversion efficiency of the device is <NUM>%.

A preparation method is seen in comparative example <NUM>. This organic photoactive layer is prepared by dissolving an electron donor material P3HT, an electron acceptor material PC<NUM>BM and <NUM>,<NUM>-DIHYDRO-PHENAZINE into o-dichlorobenzene to be mixed, wherein, the mass percent of P3HT to PC<NUM>BM is <NUM>:<NUM>, the content of <NUM>,<NUM>-DIHYDRO-PHENAZINE is 1wt% of the total mass of P3HT and PC<NUM>BM. The structure of the organic solar cell prepared in this embodiment is as follows: transparent substrate/ITO/ZnO/P3HT:PC<NUM>BM: <NUM>,<NUM>-DIHYDRO-PHENAZINE/MoO<NUM>/Al (<NUM>), wherein, the structure of <NUM>,<NUM>-DIHYDRO-PHENAZINE is seen in Formula (<NUM>).

Referring to <FIG>, it is a current density-voltage curve graph of an organic solar cell prepared in embodiment <NUM>, and other specific device properties are listed in Table <NUM>. It can be seen from experimental results that after 1wt% of <NUM>,<NUM>-DIHYDRO-PHENAZINE is doped, the voltage and current of the organic solar cell are both increased, and the photoelectric conversion efficiency of the final device is improved from original <NUM>% to <NUM>%.

Embodiment <NUM>: the inverted P3HT:PC<NUM>BM device in comparative example <NUM> and the <NUM>% piperazine-doped P3HT:PC<NUM>BM device in embodiment <NUM> are simultaneously subjected to an attenuation test using a solar cell service life test system. During the test, the light intensities of the two devices are consistent, and the two devices are both tested under the condition of additional <NUM>% load. Since the devices are persistently illuminated, the temperatures of the surfaces of the devices during the test are <NUM>-<NUM>.

<FIG> are curve graphs of changes in properties of the inverted P3HT:PC<NUM>BM device in comparative example <NUM> and the <NUM>% piperazine-doped P3HT:PC<NUM>BM device in embodiment <NUM> during attenuation over time. It can be seen from <FIG> that various parameters of the device without doping of piperazine are attenuated along with the extension of time, leading to rapid attenuation of the properties during this. When the test proceeds to <NUM>, the properties of the device have been attenuated to initial <NUM>%. However, the voltage and current of the piperazine-doped device are barely attenuated along with the extension of time, and a filling factor rises, finally leading to slight rising of the properties of the device. When the test proceeds to <NUM>, the properties of the device are still barely attenuated.

Claim 1:
An organic photoactive layer composite ink, comprising an electron donor material, an electron acceptor material and an organic solvent, also comprising an organic amine compound, wherein, in the organic photoactive layer composite ink, the mass of the organic amine compound is <NUM>.01wt%~10wt% of the total mass of the electron donor material and the electron acceptor material; in the organic photoactive layer composite ink, the mass ratio of the electron donor material to the electron acceptor material is <NUM>:<NUM>~<NUM>:<NUM>, and the concentration of the electron donor material or the electron acceptor material is <NUM>~<NUM>/mL,
wherein the organic amine compound comprises an organic amine compound having a structure as shown in Formula (<NUM>):
<CHM>
wherein R<NUM>, R<NUM>, R<NUM> and R<NUM> comprise hydrogen, substituted or unsubstituted C1~C20 alkyl, C1~C20 heteroalkyl, or a five or six membered cyclic structure formed by connecting any two substitution units in R<NUM>, R<NUM>, R<NUM> and R<NUM>, or the organic amine compound is selected from one of the following structures:
<CHM>
<CHM>
or
wherein the organic amine compound is selected from piperazine derivatives having a structure as shown in any one of Formulas (<NUM>)-(<NUM>):
<CHM>
<CHM>
wherein R<NUM> comprises hydrogen, substituted or unsubstituted C1~C20 alkyl, or C1~C20 heteroalkyl, or the organic amine compound is selected from one of the following structures:
<CHM>
<CHM>
<CHM>
preferably wherein the organic amine compound is piperazine.