Patent Description:
Traditionally, items produced with unsaturated polyester or epoxy vinyl ester have the problem of static charge build-up on the surface thereof, due to the high surface resistance and mass resistance they have, with resistance values at <NUM> of above <NUM><NUM> Ω·m. The build-up of charges causes harmful effects such as electric shocks on people, materials, fuels and electronic systems, among others. In general, the build-up of electric charges takes place in these materials when they are subjected to friction, for example by people passing by or even by the effects of the wind which contains dust and sand particles. This effect limits the uses of materials produced with the aforementioned thermostable resins.

The solutions proposed to prevent this charge build-up effect are classified into three groups:
Addition of molecules to the resin that become part of the polymer, providing greater electric conductivity to the items produced with the same. The patent <CIT> proposes the use of a maleimide containing a quaternary amine group and an anion bonded to said chemical group. This type of solution has the disadvantage that the mechanical characteristics of the material worsen in comparison to composites to which additives have not been added to the polymer in order to achieve greater electric conductivity since the polymerisation of the anti-static additive, derived from maleimide, is different to that of the reactive solvent typically used in unsaturated polyesters and epoxy vinyl ester resins.

It is well-known in scientific literature that electric conductivity in ionic conductors depends on the concentration and mobility of the cation and the anion. In this case, the cation derived from the maleimide loses its mobility due to the polymerisation reaction, under the effect thereof as an anti-static additive (see for example <NPL> and <NPL>).

The patent <CIT> proposes the use of sulphonation reactions of the surface of unsaturated polyester textile fibres with sulphurous derivatives. This type of material has a weak anti-static effect due to the low reactivity of the sulphurous derivatives with the unsaturated polyesters and the stability thereof over time is very short due to the fact that the effect only takes place on the surface of the textile fibres and is quickly lost.

The patent <CIT> presents the use of quaternary ammonium salts of the R1R2R3R4N* type and an R<NUM>SO<NUM> type anion, R1, R2, R3 and R4 being hydrogen or a saturated alkyl group with <NUM> to <NUM> carbons. These types of salt cause only small increases in electric conductivity in the material, but they especially produce a large deterioration of the mechanical characteristics of the pieces that contain them.

These salts on their own, among others, have a recognised effect of increasing the viscosity when they are added on the unsaturated polyester or epoxy vinyl ester resins as stated in the patents <CIT> and <CIT>.

It is also known that the quaternary ammonium salts produce modifications in the polymerisation of unsaturated polyester systems, since they affect the activators.

The direct addition of ionic, organic and inorganic salts on the resin also produces the accumulation thereof on points of the finished final piece due to the fact that these salts are not completely soluble in the resins and these points in turn create areas with worse mechanical characteristics and areas dyed with different colours that make the pieces produced invalid for the uses for which they were intended.

Addition of carbon-based conductive solids, for example lampblack or acetylene black, as described in the applications <CIT>, <CIT>), <CIT>, <CIT> or <CIT>. These solutions have two disadvantages: due to the fact that the materials derived from carbon act as free radical scavengers, mechanical properties are lost during the polymerisation reaction of the thermostable resins; and mainly due to the fact that the carbon-based materials are black, this limits the chromatic possibilities of the articles produced.

Addition of conductive solids based on metals, conductive metal oxides or silicon carbide in the form of powder or granules as described in the patents <CIT> and <CIT> or in the form of metal fibres or threads as described in <CIT> and <CIT>. These solutions have a new disadvantage: due to the large size of the added solids, large amounts of the same must be added to the final material in order to reduce the electrical resistance. In turn, this high requirement of conductive solids significantly modifies the final properties of the product obtained and notably limits the chromatic possibilities thereof since the same are visible.

<CIT> discloses clay/organic chemical compositions which consist of an organic chemical-smectite clay intercalate that has been ion-exchanged and reacted with one or more quaternary ammonium compounds having particularly long hydrocarbon chains in their structure, such as bis[(<NUM>-hydroxyethyl)]stearyl ammonium chloride (M2HES) or dimethyldihydrogenated tallow ammonium chloride (2M2HT). It is therein disclosed that those intercalates are particularly useful for producing nanocomposites of improved structural strength, but the technical problem of reducing static charges and/or electric dissipation in unsaturated polyester resins and epoxy vinyl ester resins has not been therein considered, let alone addressed.

Therefore, there is still the need in the state of the art to provide a formulation or additive that enables anti-static objects and materials and/or that dissipate electric charge built-up in unsaturated polyester resins and epoxy vinyl ester resins that have not lost mechanical properties or chromatic possibilities.

The object of the present invention is to produce an additive or formulation according to claim <NUM> which is based on two components, an ionic salt with specific characteristics and an encapsulant/dispersant of said ionic salt. The use of this second compound has the purpose of preventing the loss of mechanical properties and chromatic possibilities and improving the dispersion of the ionic slat.

Once the additive or formulation is prepared, it is added on unsaturated polyester and epoxy vinyl ester resins during the production process thereof and provides the same with anti-static and electric charge dissipation characteristics for the objects produced that contain this formulation.

The additive or formulation can be used in processes for producing agglomerated stone, sheet moulding composite (SMC) material, bulk moulding composite (BMC) material and/or gel coat, thus enabling panels, blocks, tiles, planes or structures of this type to be obtained, which can be dyed in any colour range, with optimal mechanical performance. The pieces produced can be used in construction, decoration, furniture and construction of transport equipment.

The unsaturated polyester resins are polymers with respect to which there is extensive knowledge on the state of the art. They are made up of polyester chains formed by glycols and/or polyols esterified with dicarboxylic or polycarboxylic acids or anhydrides.

The preferred glycol is propylene glycol, but others such as ethylene glycol, diethylene glycol, neopentyl glycol, and other diols or polyols known in the state of the art can be used.

The unsaturated polycarboxylic acids can be maleic acid, fumaric acid, maleic anhydride or others and mixtures of these compounds.

Furthermore, in the production of unsaturated polyester resins, wherein said production of unsaturated polyester resins is not encompassed by the wording of the claims but is considered as useful for understanding the invention, other polycarboxylic acids are added, such as phthalic anhydride, isophthalic acid, itaconic acid, dicarboxylic cyclohexane acid, terephthalic acid, adipic acid, sebacic acid, azelaic acid and glutaric acid, and any other acid according to the state of the art.

The total amount of acid or anhydride varies depending on the characteristics required of the formed unsaturated polyester.

Dicyclopentadiene can be added to the resins. The report by<NPL>) describes the modification of polyesters with dicyclopentadiene. Once the resin has been formed, it is diluted in a reactive diluent in proportions that range between <NUM> and <NUM>% and can be: styrene, methyl methacrylate, butyl methacrylate, other methacrylates, acrylates, vinyl toluene, para-methylstyrene, divinylbenzene, diallyl phthalate, vinyl derivatives including mixtures thereof and other diluents known in the state of the art.

Furthermore, other additives are incorporated such as suitable curing agents, low profile additives, accelerating agents and the like.

Normally, strengthening agents are added for the final use, such as fibreglass and inert additives such as quartz, cristobalite, aluminium trihydroxide, glass, metal loads, wood loads, calcium carbonate, sand or clay, among others. When necessary, desirable or convenient, pigments, demoulding agents, plasticizers and the like are also conventionally used. The manner in which these polyester resin compositions are made is well known in the state of the art.

Epoxy vinyl ester resins are polymers with respect to which there is extensive knowledge on the state of the art.

These can be different types of polymer chains such as epoxy bisphenol A, epoxy bisphenol F or novolacs. All or some of the epoxy groups of the polymer react with an agent that introduces an ester group and an unsaturation at least at each end of the chain, methacrylic acid being preferred for this function and other unsaturated monocarboxylic acids can be used such as acrylic acid and crotonic acid.

Once the resin has been formed, it is diluted in a reactive diluent in proportions that range between <NUM> and <NUM>% and can be: styrene, methyl methacrylate, butyl methacrylate, other methacrylates, acrylates, vinyl toluene, para-methylstyrene, divinylbenzene, diallyl phthalate, vinyl derivatives including mixtures thereof and other diluents known in the state of the art.

Normally, strengthening agents are added for the final use, such as fibreglass and inert additives and loads such as quartz, cristobalite, aluminium trihydroxide, glass, metal loads, wood loads and inorganic loads such as calcium carbonate, sand or clay, among others. When necessary, desirable or convenient, pigments, demoulding agents, plasticizers and the like are also conventionally used.

This invention can also be applied to resins of the previous modified types, for example with isocyanates or to mixtures thereof that are well known in the state of the art.

The mixtures obtained based on unsaturated polyester or epoxy vinyl ester or the modifications thereof, are worked in several ways:
Agglomerated stone, which enables the production of panels, blocks or tiles, are composite materials formed by resins and additives to which mineral loads are added.

The inorganic load used can comprise, for example, a mixture of crushed materials with a grain size that ranges between several centimetres to very few microns and can have one or several materials. The materials can be, among others, quartz, marble, dolomite, silica, crystal, mirror, cristobalite, granite, feldspar, basalt, glass, various sands and mixtures thereof. The inorganic load is either obtained commercially or by selecting and crushing the inorganic starting materials until the desired grain size and mixing them in the proportions suitable for obtaining an optimal packaging of the material and a final appearance that is appropriate for the use for which it is required.

The resin formulated with the previously homogenised components and additives thereof is mixed with the mineral load.

The formed mass is treated by the processes applied in the state of the art and is deposited on moulds that are open on two faces.

Vibro-compression under vacuum is carried out on the mixture.

The formed materials move to a thermal heating stage in specific ovens.

Once the mass has been hardened by means of heat application, the item obtained is subjected to a series of processes that comprise cooling the product obtained and carrying out mechanical treatments such as calibration, polishing and cutting according to the desired final dimensions of the pieces that are to be used. The shapes are mainly flat but other, more complex shapes can be obtained.

Sheets produced of the sheet moulding composite (SMC) material or bulk moulding composite (BMC) material, are materials obtained from the unsaturated polyester or epoxy vinyl ester resins described above and which are produced by means of a homogeneous mixture of glass fibre, mineral loads and thermostable unsaturated polyester or epoxy vinyl ester resin, with the addition of coupling agents, cross-linking activators, pigments and produced by high pressure compression, heating and demoulding.

Various mineral loads are added to the resins in the form of powder with a fine grain size such as aluminium trihydroxide, quartz, silica, pigments, and they are mixed.

For sheet moulding composite (SMC) materials, the material is laminated between plastic sheets. Once the sheets are formed, they can be stored for subsequent use.

For bulk moulding composite (BMC) materials, the material is inserted in the mould from a mass.

In order to obtain the final material, the sheets or mass are inserted into a press that works at high pressure and subjects the material to heating. The mould can have different shapes.

The resin polymerises and hardens due to the effect of the temperature and pieces of SMC or BMC materials are obtained.

Gel coats are obtained by means of the homogeneous mixture of mineral loads, and thermostable unsaturated polyester or epoxy vinyl ester resin, with the addition of coupling agents, polymerisation activators, pigments, thickeners and others and produced by mould deposition. These are coatings of <NUM> to <NUM> thick of unsaturated polyester or epoxy vinyl ester resin that are applied in one or several layers on the surface of a mould and that serve as a superficial protective surface of the main body of the piece that is mainly produced from new in unsaturated polyester or epoxy vinyl ester applied by casting on the layer of gel coat.

The gel coat is deposited on the mould by painting with a brush, roller or by spray gun, among others.

A gel coat contains a base resin, preferably with good performance for resisting the use that the piece will be given in different types of environments, a reactive diluent, mainly styrene, silica fume, precipitated silica or a mixture of both to adjust the rheology of the product and pigments when the surface of the product needs to be dyed. The gel coat is polymerised by a system formed by peroxides and cobalt or amine accelerators.

In addition, the gel coat normally contains inorganic loads. The most commonly used loads are precipitated calcium carbonate and micronized talc. The self-extinguishing gel coat can be prepared with alumina trihydrate.

In order to facilitate the handling of the gel coat, it is used by mixing with solvents that are classified in two categories:
The first includes non-copolymerisable viscosity reducers, which serve to reduce the viscosity of the gel coat for gun application. They must have the main characteristic of an extremely fast evaporation level, preferably that completely evaporate before the gel coat reaches the surface of the mould. Acetone is generally used for this purpose. Approximately <NUM> to <NUM>% acetone reduces the viscosity of the gel coat to provide values compatible with spray gun application.

The second category includes copolymerisable solvents, which form an integral part of the cured gel coat.

Other components of the gel coat are polymerisation inhibiting agents that generally contain the resin in order to facilitate the preservation thereof before use and active substances, such as UV protectors.

The formulation presented can also be used in other production methods applicable to unsaturated polyester and epoxy vinyl ester resins, such as mass mould deposition, contact moulding, simultaneous spray moulding, vacuum moulding, compression moulding, filament winding, pultrusion and the various modifications thereof that are widely known in the state of the art.

All these different materials thus produced are very bad electrical conductors and when they are subjected to friction by different materials (shoe soles, dust in the wind, etc.) they have a strong tendency to become electrically charged, finally resulting in the production of electric shocks on materials and people causing unpleasant effects to accidents related to fires and explosions. This effect limits or prevents the use of these materials in floors, facades or panels in transport equipment, etc..

In the present invention, a formulation according to claim <NUM>, which is free of conductive polymers, metals, carbon-based conductive materials, such as lampblack, carbon fibres, graphite, graphene or carbon nanotubes is obtained, which provides an anti-static and/or electric charge dissipation effect in the application thereof in thermostable unsaturated polyester resins or in thermostable epoxy vinyl ester resins and wherein the presence of two components is necessary so that the first component can disperse in the polymer matrix thus preventing the loss of mechanical and aesthetic properties, also preventing the formation of agglomerates or the reaction with the components of the resin, the purpose of which is to increase the electrical conductivity of the materials described above and prevent the build-up of electric charges on the surface thereof without losing the mechanical properties and chromatic possibilities.

The formulation of the present invention has two components which are:
The active substance, which will enable the mobility of the ions on the surface and/or the interior of the material and, therefore, the mobility of electric charges, giving rise to the conductive and electric charge dissipation effect.

A system that supports said active substance and enables the addition to the composites described above, such that the presence of this active substance and the long-term effect thereof is maintained, the thickening effect is prevented and preventing the active substance from interfering in the polymerisation reactions during the production of the pieces. It also prevents the loss of mechanical properties and the loss of chromatic possibilities, since it is not a black or coloured additive and does not create patches and accumulations due to the low solubility of the ionic salt in the polymer matrix.

The active substance, first component, is a salt formed by a cation and an anion, wherein the cation is a compound based on the cation N,N,N-trialkyl-alkyl-ol-ammonium, as it is or derivatised on the OH group, as expressed in the following chemical formula:
<CHM>
wherein R<NUM>, R<NUM> and R<NUM> can be -CH<NUM>, -CH<NUM>CH<NUM>, -CH<NUM>CH<NUM>CH<NUM> or - CH<NUM>CH<NUM>CH<NUM>CH<NUM>;.

The anion of said salt is inorganic or organic, and is selected from: chloride, fluoride, bromide, iodide, perchlorate, sulphate, hydrogen sulphate, nitrate, nitrite, dihydrogen phosphate, hydrogen phosphate, phosphate, borate, carbonate, hydrogen carbonate, sulphocyanide, tetrafluoroborate, hexafluorophosphate, dicyanamide, sulfamate, acetate, propionate, butanoate, formate, oxalate, lactate, glycolate, benzoate, salicylate, citrate, tartrate, p-toluenesulfonate, xylenesulfonate, <NUM>-ethylhexyl sulfate, octanesulfonate, methanesulfonate, ethanesulfonate, propanesulfonate, methosulfate (methyl sulfate), ethosulfate (ethyl sulfate), alkyl phosphates, aryl phosphates or saccharinate.

These active salts are known in scientific literature and can be commercially obtained or prepared by, for example, using the following methods:
In the case of the acid derivatives by cation reaction, the -OR<NUM> of which is -OH with acid anhydrides, for example, as indicated in <CIT> or other methods as indicated in <CIT>.

In turn, the different anions can be introduced into the salt based on a given salt with chloride anion with a silver derivative of the anion to be obtained in a suitable solvent, <NPL> or <CIT>. Similarly, based on the initial salt with chloride anion, it can be treated by an alkali hydroxide in an alcohol solvent and adding to the result the acid of the new anion that is intended to be obtained in the final salt, as indicated in <CIT>.

Different salts can also be prepared with different anions by reaction of the hydroxide of the cation that is obtained by reaction of the ethylene oxide with trimethylamine, triethylamine or tributylamine or other amines in water or aqueous solvents and subsequently neutralising with the acid corresponding to the anion that is intended to be obtained in the final salt, for example, as indicated in <CIT>, <CIT> or <CIT>.

As has been noted, the direct addition of the salt on the resin also produces thickening, negative modifications in the polymerisation reaction, poor dispersion and appearance of agglomerates, which entails the loss of mechanical properties, appearance of patches and loss of chromatic possibilities.

In order to prevent the thickening effect of the resin, achieve a homogeneous distribution over the piece produced and prevent the loss of mechanical and decorative properties, the salt must be encapsulated or predispersed before it is added to the resin.

The second component is a support with high surface area that encapsulates or serves as a solid dispersing agent for the previous anion-cation group (salt), wherein the support is comprised among the following: sodium aluminosilicate, precipitated silica, silica fume, sepiolite, attapulgite, stevensite-kerolite, bentonites, ball clay, kaolinite, kaolin, metakaolin, halloysite, zeolites, TiO<NUM>, alumina (Al<NUM>O<NUM>), boehmite, aluminium trihydroxide, magnesium hydroxide, magnesium oxide, calcium carbonate, magnesium carbonate, calcium carbonate and magnesium and/or the mixtures thereof.

Preferably, the support that encapsulatesor serves as a solid dispersing agent must have the following characteristics and is comprised among: precipitated silica with a specific surface area (BET) between <NUM> and <NUM><NUM>/gr, silica fume <NUM>-<NUM><NUM>/gr, sodium aluminosilicate (<NUM> to <NUM><NUM>/gr), sepiolite <NUM>-<NUM>, attapulgite <NUM>-<NUM>, stevensite-kerolite <NUM>-<NUM>, bentonites <NUM>-<NUM>, ball clay, kaolinite <NUM>-<NUM>, kaolin <NUM>-<NUM>, metakaolin <NUM>-<NUM>, halloysite, zeolite <NUM>-<NUM>, TiO<NUM> <NUM>-<NUM>, alumina <NUM>-<NUM>, boehmite <NUM>-<NUM>, aluminium trihydroxide <NUM>-<NUM>, magnesium hydroxide <NUM>-<NUM>, magnesium oxide <NUM>-<NUM>, calcium carbonate <NUM>-<NUM>, magnesium carbonate <NUM>-<NUM>, calcium carbonate and magnesium <NUM>-<NUM> and/or the mixtures thereof.

The support and interaction process between the two components is carried out in a dry medium, by means of intimate homogenisation of the salt used and the encapsulant due to the effect of mechanical action. The encapsulating effect is achieved when the active salt is distributed homogeneously over the surface of the encapsulant or in the inside thereof, being adsorbed by the material. For this purpose, among other forms, it can be achieved by means of the interaction of the components in a rapid mixer.

Alternatively, the encapsulation can be carried out by means of: a) simultaneous moulding of the salt and the encapsulating agent, b) by dissolving the salt in a suitable solvent, deposition thereof on the encapsulant and finally removal the solvent by distillation, evaporation, filtration or by other methods, the final result of which is a homogeneous distribution of the salt over the surface and/or the interior of the encapsulant.

The encapsulant provides its effect when the ionic compound is supported by the same and the preferable amount of the compound is of <NUM>% to <NUM>% by mass. Depending on the type of encapsulant used, the harmful effects on chromatic characteristics, appearance and mechanical properties of the final material appear as the proportion of ionic compound compared to encapsulant is increased. More preferably, the proportion of ionic compound in the formulation is between <NUM> and <NUM>% and even more preferably between <NUM> and <NUM>%.

The formulation formed by two components is added to the composite material by the same means, systems and at the same time as any other load or pigment is added. It can also be mixed with any inorganic load that is previously added to the material. If necessary, the formulation can be added on the mixture of liquid components of the resin.

The proportions of the formulation based on the <NUM> compounds to be added on the unsaturated polyester or epoxy vinyl ester are preferably established in proportion to the amount of liquid resin used and range between <NUM>% and <NUM>%, preferably between <NUM> and <NUM>% and more preferably between <NUM> and <NUM>% of formulation per unit of resin. This proportion depends on the level of electric conductivity that is to be obtained in the final material.

Encapsulation preparation of a salt of (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in precipitated sodium aluminosilicate <NUM>%.

<NUM> gr of sodium aluminosilicate is used, preferably it must have a composition of <NUM> to <NUM> (SiO<NUM>), <NUM> to <NUM> (Al<NUM>O<NUM>), <NUM> to <NUM> (Na<NUM>O) and surface BET surface <NUM> to <NUM><NUM>/gr, for this example we use <NUM>(SiO<NUM>)·Al<NUM>O<NUM>·<NUM>(Na<NUM>O) BET <NUM><NUM>/gr fine powder obtained by precipitation. <NUM> gr of the salt, choline chloride, powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Preparation as in example <NUM>, wherein the ratio is <NUM>%-<NUM>%.

<NUM> gr of sodium aluminosilicate is used, <NUM>(SiO<NUM>)·Al<NUM>O<NUM>·<NUM>(Na<NUM>O) BET <NUM><NUM>/gr fine powder obtained by precipitation. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation of a salt of (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is bromide (choline bromide) at <NUM>% in sepiolite.

<NUM> gr of sepiolite is used, BET <NUM><NUM>/gr fine powder obtained by grinding in humid medium. <NUM> gr of choline bromide powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in attapulgite.

<NUM> gr of attapulgite is used, BET <NUM><NUM>/gr fine powder obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in halloysite.

<NUM> gr of halloysite is used, BET <NUM><NUM>/gr fine powder obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is formate (choline formate) at <NUM>% in stevensite-kerolite.

<NUM> gr of stevensite-kerolite is used, BET <NUM><NUM>/gr fine powder obtained by grinding in dry medium. <NUM> gr of choline formate in powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is acetate (choline acetate) at <NUM>% in activated sodium bentonite.

<NUM> gr of activated sodium bentonite is used in fine powder obtained by activation in liquid medium, dried and ground in dry medium. <NUM> gr of choline acetate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is acetate (choline acetate) at <NUM>% in calcium bentonite.

<NUM> gr of calcium bentonite is used in fine powder obtained by grinding in dry medium. <NUM> gr of choline acetate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is methanesulfonate (choline methanesulfonate) at <NUM>% in ball clay.

<NUM> gr of ball clay is used in fine powder obtained by grinding in dry medium. <NUM> gr of choline methanesulfonate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in kaolin.

<NUM> gr of micronised kaolin is used in fine powder obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in metakaolin.

<NUM> gr of micronised metakaolin is used in fine powder obtained by thermally treating kaolin and grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in zeolite A.

<NUM> gr of micronised zeolite A is used in fine powder obtained by precipitation and grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in aluminium oxide (alumina).

<NUM> gr of aluminium oxide (alumina) is used in fine powder less than <NUM> obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in boehmite.

<NUM> gr of boehmite is used in fine powder less than <NUM> obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in aluminium trihydroxide.

<NUM> gr of aluminium trihydroxide is used in fine powder less than <NUM> obtained by grinding in dry medium. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation N,N,N-trialkyl-alkyl-stearoyl-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> according to the general formula of the compounds of the present invention is stearoyl and the anion is chloride (stearoyl choline chloride) at <NUM>% in calcium carbonate.

<NUM> gr of calcium carbonate is used in fine powder less than <NUM> obtained by grinding. <NUM> gr of stearoyl choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is bromide (choline bromide) at <NUM>% in sodium aluminosilicate and halloysite.

<NUM> gr of sodium aluminosilicate is used, BET <NUM><NUM>/gr. <NUM> gr of halloysite in fine powder is added. <NUM> gr of choline bromide powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in precipitated silica <NUM> BET m<NUM>/gr.

<NUM> gr of precipitated silica BET <NUM><NUM>/gr is used. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in titanium dioxide (TiO<NUM>).

<NUM> gr of titanium dioxide (TiO<NUM>) with a size of less than <NUM> is used. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in magnesium hydroxide (Mg(OH)<NUM>) with an average particle size of <NUM>.

<NUM> gr of <NUM> magnesium hydroxide (Mg(OH)<NUM>) is used. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is bromide (choline bromide) at <NUM>% in magnesium hydroxide.

<NUM> gr of magnesium hydroxide is used. <NUM> gr of choline bromide powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is ethyl sulfate (choline ethyl sulfate) at <NUM>% in magnesium hydroxide.

<NUM> gr of magnesium hydroxide is used. <NUM> gr of choline ethyl sulfate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is methyl sulfate (choline methyl sulfate) at <NUM>% in zeolite A.

<NUM> gr of zeolite A is used. <NUM> gr of choline methyl sulfate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is tetrafluoroborate (choline tetrafluoroborate) at <NUM>% in calcium carbonate.

<NUM> gr of calcium carbonate is used. <NUM> gr of choline tetrafluoroborate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is acetate (choline acetate) at <NUM>% in calcium carbonate.

<NUM> gr of calcium carbonate is used. <NUM> gr of choline acetate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is lactate (choline lactate) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of choline lactate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is <NUM>-1λ6,<NUM>-benzisothiazol-<NUM>,<NUM>,<NUM>-thionate (choline saccharinate) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of choline saccharinate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation N,N,N-trialkyl-alkyl acetyl-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> according to the general formula of the compounds of the present invention is OC(=O)CH3 and the anion is chloride (acetylcholine chloride) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of acetylcholine chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl(n)-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride at <NUM>% in precipitated sodium aluminosilicate.

<NUM> gr of sodium aluminosilicate <NUM>(SiO<NUM>)·Al<NUM>O<NUM>·<NUM>(Na<NUM>O) BET <NUM><NUM>/gr fine powder obtained by precipitation is used. <NUM> gr of the salt powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride at <NUM>% in precipitated sodium aluminosilicate.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is bromide (choline bromide) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of choline bromide powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation N,N,N- trialkyl-acetyl alkyl-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> according to the general formula of the compounds of the present invention is OC(=O)CH3 and the anion is ethyl sulfate (acetylcholine ethyl sulfate) at <NUM>% in halloysite.

<NUM> gr of halloysite is used. <NUM> gr of acetylcholine ethyl sulfate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation N,N,N-trialkyl-<NUM>-ethylhexanoyl alkyl ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> according to the general formula of the compounds of the present invention is <NUM>-ethylhexanoyl and the anion is ethyl sulfate (<NUM>-ethylhexanoyl choline ethyl sulfate) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of <NUM>-ethylhexanoyl choline ethyl sulfate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl(n)-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride (choline chloride) at <NUM>% in precipitated silica.

<NUM> gr of precipitated silica is used. <NUM> gr of choline chloride powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Encapsulation preparation (R<NUM>)N,N,N-trialkyl-alkyl(n)-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is ethyl sulfate (choline ethyl sulfate) at <NUM>% in halloysite.

<NUM> gr of halloysite is used. <NUM> gr of choline ethyl sulfate powder is added. It is encapsulated by mixing at high revolutions in a rapid turbo-mixer at <NUM> rpm for <NUM> minutes.

Agglomerated stone-type material, without anti-static additive, an example which we take as comparative reference <NUM> (i.e., comparative example not according to the claimed invention, but useful for understanding the invention).

Homogeneous mass produced from <NUM> of materials with the following composition expressed in percentage by weight:
Load formed by: micronised cristobalite <NUM>%, crushed quartz <NUM>% and titanium dioxide pigment <NUM>%.

Agglomerant resin <NUM>% formed by orthophthalic unsaturated polyester resin with: trimethoxysilyl propyl methacrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

The additives are added on the resin and are mixed and dispersed therein. The loads are mixed. The resin, with the additives thereof, is added on the load mixture and are homogenised in a planetary mixer. The mass is arranged on a mould, in the lower part of which kraft paper has been placed. It is pressed by means of vibro-compression and vacuum for <NUM> minutes. The mould is taken to an oven at a temperature of <NUM> for <NUM> minutes until the resin has polymerised. It is left to cool at room temperature and two days later it is demoulded, cut, polished and the thickness is calibrated.

Electric conductivity and resistance to bending tests are carried out with the following result:.

Agglomerated stone-type material, with anti-static additive tetramethylammonium methyl sulfate (ACROS Organics), an example which we take as reference JPS63110242A (i.e., comparative example not according to the claimed invention, but useful for understanding the invention).

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this being tetramethylammonium methyl sulfate.

Agglomerant <NUM>% formed by orthophthalic unsaturated polyester resin with: trimethoxysilyl propyl methacrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

The additives are added on the resin and are mixed and dispersed therein. The loads and anti-static additive are mixed. The resin, with the additives thereof, is added on the load and anti-static additive mixture and they are homogenised in a planetary mixer. The mass is arranged on a mould, in the lower part of which kraft paper has been placed. It is pressed by means of vibro-compression and vacuum for <NUM> minutes. The mould is taken to an oven at a temperature of <NUM> for <NUM> minutes until the resin has polymerised. It is left to cool at room temperature and two days later it is demoulded, cut, polished and the thickness is calibrated.

Only a slight anti-static effect is produced, resistance to bending is lost, which means that the material is not valid for use as tiles, work tops, tables and other construction materials, dark patches appearing on the surface which make the chromatic possibilities of the material unusable.

Agglomerated stone-type material, with anti-static additive choline chloride, an example which we take as comparative reference (i.e., comparative example not according to the claimed invention, but useful for understanding the invention).

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this being pure choline chloride.

Electric conductivity that is useful for the application of the material on floors or walls is achieved, but the mechanical characteristics and chromatic possibilities are lost.

Agglomerated stone-type material, with anti-static additive choline bromide, an example which we take as comparative reference (i.e., comparative example not according to the claimed invention, but useful for understanding the invention).

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this being pure choline bromide.

Electric conductivity is limited and the mechanical properties and chromatic possibilities are lost, which means the material loses its possibilities of use.

Agglomerated stone-type material, with anti-static additive choline chloride encapsulated in sodium aluminosilicate according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being choline chloride <NUM>% in sodium aluminosilicate <NUM>% according to EXAMPLE <NUM>.

Agglomerated stone-type material, with anti-static additive choline bromide encapsulated in sepiolite according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being choline bromide <NUM>% in sepiolite <NUM>% according to EXAMPLE <NUM>.

Several comparative examples are carried out with additions of <NUM>% of anti-static additive with respect to the total of the mass and equivalent to <NUM>% with respect to the agglomerant, prepared in different encapsulants in a ratio of <NUM>% of the salt indicated and <NUM>% of encapsulant.

The form of preparation is identical to that set forth above in example F and the results are presented below:.

Agglomerated stone-type material, with anti-static additive choline bromide encapsulated in precipitated silica according to EXAMPLE <NUM>.

Homogeneous mass produced from <NUM> of materials with the following composition expressed in percentage by weight:
Load formed by: ground quartz <NUM>%, crushed quartz <NUM>% and titanium dioxide pigment <NUM>%.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being choline bromide <NUM>% in precipitated silica <NUM>% according to EXAMPLE <NUM>.

Homogeneous mass produced from <NUM> of materials with the following composition expressed in percentage by weight:
Load formed by: ground quartz <NUM>%, crushed quartz <NUM>% and titanium dioxide pigment <NUM>% of the total.

Agglomerant <NUM>% of the total formed by orthophthalic unsaturated polyester resin with: trimethoxysilyl propyl acrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

Agglomerated stone-type material, with anti-static additive acetylcholine ethyl sulfate encapsulated in halloysite according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being acetylcholine ethyl sulfate <NUM>% in halloysite <NUM>% according to EXAMPLE <NUM>.

Agglomerant <NUM>% of the total, formed by epoxy vinyl ester resin with: trimethoxysilyl propyl methacrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

The additives are added on the resin and are mixed and dispersed therein to form the agglomerant. The loads and anti-static additive are mixed. The resin, with the additives thereof, is added on the load and anti-static additive mixture and they are homogenised in a planetary mixer. The mass is arranged on a mould, in the lower part of which kraft paper has been placed. It is pressed by means of vibro-compression and vacuum for <NUM> minutes. The mould is taken to an oven at a temperature of <NUM> for <NUM> minutes until the resin has polymerised. It is left to cool at room temperature and two days later it is demoulded, cut, polished and the thickness is calibrated.

Agglomerated stone-type material, with anti-static additive <NUM>-ethylhexanoyl choline ethyl sulfate encapsulated in precipitated silica according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being acetylcholine ethyl sulfate <NUM>% in precipitated silica <NUM>% according to EXAMPLE <NUM>.

Agglomerant <NUM>% of the total, formed by unsaturated polyester resin in diluent, <NUM>% styrene and <NUM>% butyl methacrylate with: trimethoxysilyl propyl methacrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

Agglomerated stone-type material, with anti-static additive choline chlorine encapsulated in precipitated silica according to EXAMPLE <NUM>.

Homogeneous mass produced from <NUM> of materials with the following composition expressed in percentage by weight:
Load formed by: ground albite-type feldspar <NUM>%, crushed quartz <NUM>% and titanium dioxide pigment <NUM>%.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being choline chloride <NUM>% in precipitated silica <NUM>% according to EXAMPLE <NUM>.

Agglomerant <NUM>% of the total, formed by dicyclopentadiene unsaturated polyester resin with: trimethoxysilyl propyl methacrylate (<NUM>% with respect to the resin), cumyl hydroperoxide (<NUM>% with respect to the resin).

Agglomerated stone-type material, with anti-static additive (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride encapsulated in sepiolite according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride, at <NUM>% in sepiolite <NUM>% according to EXAMPLE <NUM>.

Agglomerated stone-type material, with anti-static additive (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride at <NUM>% encapsulated in sepiolite according to EXAMPLE <NUM>.

Anti-static additive <NUM>% with respect to the total and equivalent to <NUM>% with respect to the agglomerant, this encapsulant being (R<NUM>)N,N,N-trialkyl-alkyl-ol-ammonium wherein R<NUM>, R<NUM>, R<NUM> are CH<NUM>CH<NUM>CH<NUM>; n = <NUM> and OR<NUM> is OH and the anion is chloride, at <NUM>% in sepiolite <NUM>% according to EXAMPLE <NUM>.

Gel coat-type material, with anti-static additive choline chloride without encapsulation. Homogeneous mass produced in an amount of <NUM> in total, with the following composition expressed in percentage by weight and added in the following order:.

As the components are added in the order indicated in the table above, the mass that forms is stirred at <NUM> rpm with a cowles stirrer. After component <NUM> is added, stirring continues for <NUM> mins until the material forms. Lastly, component <NUM>, the peroxide activator, is added and stirred for <NUM> mins.

The material is deposited on a silicone mould and a thickness of <NUM> is obtained. When it has polymerised and <NUM> days have passed, the surface resistance is measured.

Gel coat-type material, with anti-static additive choline chloride encapsulated in halloysite according to EXAMPLE <NUM>.

Homogeneous mass produced in an amount of <NUM> in total, with the following composition expressed in percentage by weight and added in the following order:.

The material is deposited on a silicone mould in a thickness of <NUM>. When it has polymerised and <NUM> days have passed, the surface resistance is measured.

The material is deposited on a silicone mould in a layer that is <NUM> thick. When it has polymerised and <NUM> days have passed, the surface resistance is measured.

Gel coat-type material, with anti-static additive choline chloride encapsulated in sodium aluminosilicate according to EXAMPLE <NUM>.

The material is deposited on a silicone mould to obtain a layer that is <NUM> thick. When it has polymerised and <NUM> days have passed, the surface resistance is measured.

Material produced by Bulk Moulding Composite (BMC) technique, with addition of choline ethyl sulfate without encapsulation.

First, the resin formed by three components is prepared: unsaturated polyester diluted in styrene <NUM>%, low profile polyvinyl acetate additive diluted in styrene <NUM>% and styrene <NUM>% to obtain <NUM> of material. The unsaturated polyester is a diluted orthophthalic resin containing <NUM>% styrene. The low profile additive is a polyvinyl acetate solution containing <NUM>% styrene, which are mixed in a tank with a cowles blade at <NUM> rpm for <NUM> mins.

<NUM> is produced in which for every <NUM> parts of the previous mixture the following are added in parts:.

The material is mixed in a kneader for <NUM> mins. The cut glass fibre is added and it is mixed for <NUM>. The material is moulded for <NUM> mins at <NUM> and <NUM> MPa of pressure. Pieces that are <NUM> x <NUM> and <NUM> thick are obtained.

Material produced by Bulk Moulding Composite (BMC) technique, with addition of choline ethyl sulfate at <NUM>% encapsulated in halloysite according to example <NUM>.

First, the resin formed by three components is prepared: unsaturated polyester diluted in styrene <NUM>%, low profile polyvinyl acetate additive diluted in styrene <NUM>% and styrene <NUM>% to obtain <NUM> of material. The unsaturated polyester is a diluted orthophthalic resin containing <NUM>% of styrene. The low profile additive is a polyvinyl acetate solution containing <NUM>% of styrene, which are mixed in a tank with a cowles blade at <NUM> rpm for <NUM> mins.

Material produced by Sheet Moulding Composite (SMC) technique, with addition of choline ethyl sulfate without encapsulation.

The components of the resin are prepared in an amount of <NUM> in the following addition order in a mixer:.

Components <NUM> to <NUM> are mixed in a mixer with a cowles blade at <NUM> rpm for <NUM> mins. The material is deposited on a polyethylene film and spread. The cut glass fibre is added. A top sealing film is placed and it is passed through a double roller. The material formed is left to mature for <NUM> weeks. The material is moulded for <NUM> mins at <NUM> and <NUM>/cm<NUM> of pressure. Pieces that are <NUM> x <NUM> and <NUM> thick are obtained.

Material produced by Sheet Moulding Composite (SMC) technique, with addition of choline ethyl sulfate encapsulated in halloysite according to EXAMPLE <NUM>.

Claim 1:
A formulation free of conductive polymers, metals, carbon-based conductive materials, such as lampblack, carbon fibres, graphite, graphene or carbon nanotubes, which provides an anti-static and/or electric charge dissipation effect in the application thereof in thermostable unsaturated polyester resins or in thermostable epoxy vinyl ester resins and wherein the presence of two components is necessary so that the first component can disperse in the polymer matrix thus preventing the loss of mechanical and aesthetic properties, also preventing the formation of agglomerates or the reaction with the components of the resin, this formulation being characterised in that it comprises:
a. First component: a compound based on the cation such as N,N,N-trialkyl-alkyl-ol-ammonium or derivatised on the OH group, and an anion A, as expressed in the following chemical formula:
<CHM>
R<NUM>, R<NUM> and R<NUM> = -CH<NUM>, -CH<NUM>CH<NUM>, -CH<NUM>CH<NUM>CH<NUM> or -CH<NUM>CH<NUM>CH<NUM>CH<NUM> n = <NUM>, <NUM> or <NUM>
OR<NUM> = hydroxyl, formyl, acetyl, propanoyl, butanoyl, hexanoyl, octanoyl, <NUM>-ethylhexanoyl, decanoyl, dodecanoyl, tetradecanoyl, hexadecanoyl, stearoyl, oleoyl or benzoyl
The anion, A, is selected from: chloride, fluoride, bromide, iodide, perchlorate, sulphate, hydrogen sulphate, nitrate, nitrite, dihydrogen phosphate, hydrogen phosphate, phosphate, borate, carbonate, hydrogen carbonate, sulphocyanide, tetrafluoroborate, hexafluorophosphate, dicyanamide, sulfamate, acetate, propionate, butanoate, formate, oxalate, lactate, glycolate, benzoate, salicylate, citrate, tartrate, p-toluenesulfonate, xylenesulfonate, <NUM>-ethylhexyl sulfate, octanesulfonate, methanesulfonate, ethanesulfonate, propanesulfonate, methosulfate (methyl sulfate), ethosulfate (ethyl sulfate), alkyl phosphates, aryl phosphates or saccharinate
b. Second component: a support that encapsulates or serves as a solid dispersing agent for the previous anion-cation group (salt) comprised among the following: sodium aluminosilicate, precipitated silica, silica fume, sepiolite, attapulgite, stevensite-kerolite, bentonite, ball clay, kaolinite, kaolin, metakaolin, halloysite, zeolites, TiO<NUM>, alumina (Al<NUM>O<NUM>), boehmite, aluminium trihydroxide, magnesium hydroxide, magnesium oxide, calcium carbonate, magnesium carbonate, calcium and magnesium carbonate and/or the mixtures thereof.