Patent Description:
Polyester polyols are prepared by polycondensation of dibasic organic carboxylic acids, carboxylic anhydrides and polyhydric alcohols, and their relative molecular masses are generally less than <NUM>. Dibasic acids include phthalic acid or phthalic anhydride or its esters, adipic acid, halogenated phthalic acid and so on, and polyhydric alcohols include ethylene glycol, propylene glycol, diethylene glycol, trimethylolpropane, pentaerythritol and so on. The polyester polyols are generally classified based on carboxylic acids, and usually comprise following species: adipic acid polyester polyols, alkyd polyester polyols, caprolactone polyester polyols and acrylic polyester polyols. The methods for preparing polyester polyols include vacuum dehydration method and high temperature nitrogen dehydration method. Vacuum dehydration method refers to that, under vacuum conditions, using acetate as a catalyst, dibasic acid and dihydric alcohol undergo polycondensation reaction to synthesize a certain molecular mass of polyester polyol. High temperature nitrogen dehydration method refers to synthesizing polyester polyol at high temperature under the protection of nitrogen.

Traditional polyester polyols are produced from organic acids, anhydrides or organic acid esters as raw materials, which have poor heat resistance and the initial decomposition temperature is generally lower than <NUM> (see <CIT>; <NPL>. ), and are difficult to apply in fields requiring high heat resistance. <CIT> discloses the preparation method of copolymer ether ester comprising ester exchange or esterification reaction, and fasculation reaction. The product has excellent comprehensive performance, and the thermal decomposition temperature is <NUM>-<NUM>.

According to one aspect of the present application, a method for preparing polyester polyol is provided, and the polyester polyol prepared by the method has higher heat resistance.

The polyester polyol polymer of the present application is a new type of polyester polyol polymer obtained by transesterification of inorganic oxyacid ester and polyhydric alcohols as raw materials as indicated in the annexed claims. In contrast, the traditional polyester polyol is prepared by dehydration esterification reaction of organic acid and polyhydric alcohols as raw materials.

The method for preparing polyester polyol is characterized in that it comprises performing transesterification of raw materials containing inorganic oxyacid ester and polyhydric alcohol to obtain the polyester polyol.

Optionally, the inorganic oxyacid ester is at least one of compounds having a chemical formula shown in Formula I and Formula II:.

wherein, M is a metal element or a non-metal element that does not include P, R<NUM> and R<NUM> are independently selected from at least one of C<NUM> to C<NUM> alkyl groups, n<NUM> =<NUM>~<NUM>, n<NUM> =<NUM>~<NUM>.

Optionally, n<NUM> =<NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, or <NUM>.

Optionally, M comprises at least one of B, Si, Ge, P, Al, Ti, Fe, Sn, V, Ga, Zr, Cr, Sb and W.

Optionally, M is B, Si, Ge, P, Al, Ti, Fe, Sn, V, Ga, Zr, Cr, Sb or W.

Optionally, in the Formula I, R<NUM> and R<NUM> are independently selected from at least one of C<NUM>to C<NUM> alkyl groups.

Optionally, the inorganic oxyacid ester comprises at least one of trimethyl borate, triethyl borate, tripropyl borate, tributyl borate, tri-n-hexyl borate, triisooctyl borate, trioctyl borate, tetramethoxysilane, tetraethyl orthosilicate, tetrapropyl silicate, tetrabutyl silicate, ethyl orthogermanate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, tri-n-pentyl phosphate, trihexyl phosphate, aluminium ethoxide, aluminum isopropoxide, aluminum n-butoxide, aluminum tert-butoxide, tetraethyl titanate, tetraisopropyl titanate, tetrabutyl titanate, tetrahexyl titanate, tetraisooctyl titanate, tetrabutyl ferrite, tetrabutyl stannate, butyl orthovanadate, gallium ethoxide, tetra-n-propyl zirconate, tetrabutyl zirconate, tert-butyl chromate, ethyl antimonite, butyl antimonate, tungsten ethoxide and tungsten isopropoxide.

The molar ratio of the inorganic oxyacid ester to the polyhydric alcohol satisfies: inorganic oxyacid ester: polyhydric alcohol = (<NUM>~<NUM>) n<NUM>/x; wherein x is the number of moles of alkoxyl groups contained in each mole of inorganic oxyacid ester, and n<NUM> is the number of moles of hydroxyl groups contained in each mole of polyhydric alcohol.

Optionally, the upper limit of the molar ratio of the inorganic oxyacid ester to the polyol is <NUM>. 85n<NUM>/x, <NUM>. 9n<NUM>/x, <NUM>. 95n<NUM>/x, 1n <NUM>/x, <NUM>. 05n<NUM>/x, <NUM>. 1n<NUM>/x, <NUM>. 15n<NUM>/x or <NUM>. 2n<NUM>/x, and the lower limit thereof is <NUM>. 8n<NUM>/x, <NUM>. 85n<NUM>/x, <NUM>. 9n<NUM>/x, <NUM>. 95n<NUM>/x, 1n<NUM>/x, <NUM>. 05n<NUM>/x, <NUM>. 1n<NUM>/x or <NUM>. 15n<NUM>/x; wherein, x is the number of moles of alkoxy groups contained in each mole of the inorganic oxyacid ester, and n<NUM> is the number of moles of hydroxyl groups contained in each mole of the polyhydric alcohol.

Optionally, the number of hydroxyl groups in the polyhydric alcohol is not less than two.

Optionally, the polyhydric alcohol comprises at least one of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, <NUM>,<NUM>-propanediol, <NUM>,<NUM>-propanediol, <NUM>,<NUM>-butylene glycol, <NUM>,<NUM>-hexanediol, polyethylene glycol <NUM>, polyethylene glycol <NUM>, polyethylene glycol <NUM>, polyethylene glycol <NUM>, <NUM>,<NUM>-cyclohexanediol, <NUM>,<NUM>-cyclohexane dimethanol, terephthalyl alcohol, glycerin, trimethylolpropane, pentaerythritol, xylitol and sorbitol.

Optionally, the formula of the polyhydric alcohol is R<NUM>-(OH)x, wherein x≥<NUM>.

Optionally, the molar ratio of the inorganic oxyacid ester to the polyhydric alcohol satisfies: (<NUM>~<NUM>) n/x; wherein, x is the number of moles of alkoxy groups contained in each mole of the inorganic oxyacid ester, and n is the number of moles of hydroxyl groups contained in each mole of the polyhydric alcohol.

Optionally, the transesterification is carried out in the presence of a transesterification catalyst.

Optionally, the amount of the transesterification catalyst is in a range from <NUM>. 1wt% to 5wt% of the inorganic oxyacid ester.

Optionally, the upper limit of amount of the transesterification catalyst is <NUM>. 2wt%, <NUM>. 5wt%, <NUM>. 8wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt%, <NUM>. 5wt% or <NUM>. 0wt% of the inorganic oxyacid ester, and the lower limit thereof is <NUM>. 1wt%, <NUM>. 2wt%, <NUM>. 5wt%, <NUM>. 8wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt%, <NUM>. 5wt%, <NUM>. 0wt% or <NUM>. 5wt% of the inorganic oxyacid ester.

Optionally, the transesterification catalyst is at least one of acidic catalyst and basic catalyst.

Optionally, the acidic catalyst includes at least one of alcohol-soluble acid, solid acid, aluminum alkoxide, aluminum phenoxide, tetrabutyl stannate, titanium alkoxide, zirconium alkoxide, ethyl antimonite and butyl antimonite; and the basic catalyst includes at least one of alcohol-soluble base and solid base.

Optionally, the alcohol-soluble acid is an acid that is easily soluble in alcohol.

Optionally, the alcohol-soluble base is a base that is easily soluble in alcohol.

Optionally, the alcohol-soluble acid includes sulfuric acid, sulfonic acid and the like.

Optionally, the alcohol-soluble base includes NaOH, KOH, NaOCH<NUM>, organic base and the like.

Optionally, the transesterification catalyst is: a basic catalyst including bases that are easily soluble in alcohol (such as NaOH, KOH, NaOCH<NUM>, organic bases and so on) and various solid base catalysts; and an acidic catalyst including acids that are easily soluble in alcohol (such as sulfuric acid, sulfonic acid and so on) and various solid acidic catalysts, aluminum alkoxide, aluminum phenoxide, tetrabutyl stannate, titanium alkoxide, zirconium alkoxide, ethyl antimonite, butyl antimonite and so on. And the amount of the transesterification catalyst is in a range from <NUM>. 1wt% to 5wt% of the inorganic oxyacid ester.

Optionally, the conditions for the transesterification are: a reaction temperature ranges from <NUM> to °C, and a reaction time ranges from <NUM> to10 hours in an inactive atmosphere.

Optionally, the inactive atmosphere includes at least one of nitrogen and inert gas atmosphere.

Optionally, the inactive atmosphere is nitrogen atmosphere.

Optionally, the transesterification is carried out under stirring condition.

Optionally, the upper limit of the reaction temperature is <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM> or <NUM>, and the lower limit thereof is <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM> or <NUM>.

Optionally, the upper limit of the reaction time is <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours or <NUM> hours, and the lower limit thereof is <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours or <NUM> hours.

Optionally, the conversion rate of the transesterification ranges from <NUM>% to <NUM>%.

Optionally, the conditions for the transesterification further comprise performing vacuum distillation thereafter.

Optionally, the conditions of the vacuum distillation comprise: a vacuum degree ranges from <NUM> to 5kPa, a vacuum distillation temperature ranges from <NUM> to <NUM>, and a vacuum distillation time ranges from <NUM> to <NUM> hours.

Optionally, in the vacuum distillation process, the upper limit of the vacuum degree is <NUM>. 02kPa, <NUM>. 05kPa, <NUM>. 1kPa, <NUM>. 5kPa, 1kPa, 2kPa, 3kPa, 4kPa, <NUM>. 5kPa or 5kPa, and the lower limit thereof is <NUM>. 01kPa, <NUM>. 02kPa, <NUM> kPa, <NUM>. 1kPa, <NUM>. 5kPa, 1kPa, 2kPa, 3kPa, 4kPa or <NUM>.

Optionally, in the vacuum distillation process, the upper limit of the vacuum distillation temperature is <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>,<NUM> or <NUM>, and the lower limit thereof is <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM> or <NUM>.

Optionally, in the vacuum distillation process, the upper limit of the vacuum distillation time is <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours or <NUM> hours, and the lower limit thereof is <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours, <NUM> hours or <NUM> hours.

Optionally, the conversion rate of the transesterification is greater than <NUM>%.

As a specific embodiment, the method comprises:.

Optionally, the initial decomposition temperature of the polyester polyol is higher than <NUM>.

Optionally, the initial decomposition temperature of the polyester polyol reaches <NUM>.

In the present application, "C<NUM>~C<NUM>" and the like all refer to the number of carbon atoms contained in the alkyl group.

In the present application, "alkyl" is a group formed by the loss of any hydrogen atom on the molecule of an alkane compound.

In the present application, the "initial decomposition temperature" refers to the temperature at which the polyester polyol has an obvious weight loss peak through thermogravimetric analysis.

The beneficial effects that the present application can achieve comprise:.

The present application will be described in detail below with reference to the examples, but the present application is not limited to these examples.

Unless otherwise specified, the raw materials in the examples of the present application are all commercially available.

The analysis methods in the examples of the present application are as follows.

Thermogravimetric analysis is conducted by TA Q-<NUM> thermogravimetric analyzer produced by TA Instruments. The nitrogen flow rate is <NUM>/min, and the temperature is increased to <NUM> at a temperature rise rate of <NUM>/min.

The conversion rate of the transesterification in the examples of the present application is calculated as follows: according to the number of moles n of the by-product alcohols distilled out during the reaction, the number of groups participating in the transesterification is determined to be n, and the total number of moles of esters in the reaction raw materials is m, and then the conversion rate of the transesterification is n/xm. x depends on the number of alkoxy groups connected to the central atom in the esters.

According to an embodiment of the present application, the polyester polyol polymer and the method for preparing the same are characterized in that the method includes the following steps:.

Optionally , the formula of the inorganic oxyacid ester in step a) is M(OR)n, wherein M is B, Si, Ge, P, Al, Ti, Fe, Sn, V, Ga, Zr, Cr, Sb, W; R is any one of "C<NUM> to C<NUM>" alkyl groups; and the inorganic oxyacid ester comprises at least one of trimethyl borate, triethyl borate, tripropyl borate, tributyl borate, tri-n-hexyl borate, triisooctyl borate, trioctyl borate, tetramethoxysilane, tetraethyl orthosilicate, tetrapropyl silicate, tetrabutyl silicate, ethyl orthogermanate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, tri-n-pentyl phosphate, trihexyl phosphate, aluminium ethoxide, aluminum isopropoxide, aluminum n-butoxide, aluminum tert-butoxide, tetraethyl titanate, tetraisopropyl titanate, tetrabutyl titanate, tetrahexyl titanate, tetraisooctyl titanate, tetrabutyl ferrite, tetrabutyl stannate, butyl orthovanadate, gallium ethoxide, tetra-n-propyl zirconate, tetrabutyl zirconate, tert-butyl chromate, ethyl antimonite, butyl antimonate, tungsten ethoxide and tungsten isopropoxide.

Optionally, the formula of the polyhydric alcohol in step a) is R-(OH)x, wherein x ≥ <NUM>; the polyhydric alcohol comprises at least one of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, <NUM>,<NUM>-propanediol, <NUM>,<NUM>-propanediol, <NUM>,<NUM>-butylene glycol, <NUM>,<NUM>-hexanediol, polyethylene glycol <NUM>, polyethylene glycol <NUM>, polyethylene glycol <NUM>, polyethylene glycol <NUM>, <NUM>,<NUM>-cyclohexanediol, <NUM>,<NUM>-cyclohexane dimethanol, terephthalyl alcohol, glycerin, trimethylolpropane, pentaerythritol, xylitol and sorbitol.

Optionally, in the step a), the molar ratio of the inorganic oxyacid ester to the polyhydric alcohol satisfies: M(OR)n/R-(OH) x = (<NUM>~<NUM>)x/n.

Optionally, the transesterification catalyst used in the step a) is: a basic catalyst including bases that are easily soluble in alcohol (such as NaOH, KOH, NaOCH<NUM>, organic bases and so on) and various solid base catalysts; and an acidic catalyst including acids that are easily soluble in alcohol (such as sulfuric acid, sulfonic acid and so on) and various solid acidic catalysts, aluminum alkoxide, aluminum phenoxide, tetrabutyl stannate, titanium alkoxide, zirconium alkoxide, ethyl antimonite, butyl antimonite and so on; and the amount of the transesterification catalyst is in a range from <NUM>. 1wt% to 5wt% of the inorganic oxyacid ester.

Optionally, the step a) is carried out under nitrogen protection, the reaction temperature thereof ranges from <NUM> to180 °C, and the reaction time thereof ranges from <NUM> to <NUM> hours.

Optionally, the conversion rate of the transesterification in step a) ranges from <NUM>% to <NUM>%.

Optionally, the step b) is carried out under vacuum distillation conditions, and the vacuum degree thereof ranges from <NUM> to 5kPa.

Optionally, in step b), the reaction temperature ranges from <NUM> to <NUM>, and the reaction time ranges from <NUM> to <NUM> hours.

Optionally, the conversion rate of the transesterification in step b) is greater than <NUM>%.

<NUM> <NUM>,<NUM>-propanediol, <NUM> tetraethyl orthosilicate and <NUM> tetramethoxysilane are added to a three-necked flask which is connected to a distillation device. <NUM> concentrated sulfuric acid as catalyst is added dropwise in the three-necked flask under stirring condition. The temperature is heated up to <NUM> under nitrogen protection, and the reaction time is <NUM> hours. During this process, a large amount of methanol and ethanol are distilled out, and the conversion rate of the transesterification reaction is <NUM>%. Then a vacuum device is connected to distillation device and the transesterification continues under vacuum distillation conditions, wherein the vacuum degree of the reaction system was controlled to be 1kPa and the temperature was raised to <NUM>. After reacting for <NUM> hour, the transesterification is stopped. After the temperature is naturally cooled to be room temperature, the resulting sample is taken, and the conversion rate of the transesterification is <NUM>%.

<NUM> ethylene glycol and <NUM> aluminum ethoxide are added to a three-necked flask which is connected to a distillation device, wherein the aluminum ethoxide is used not only as an inorganic oxyacid salt raw material, but also as a transesterification catalyst. The temperature is heated up to <NUM> under nitrogen protection and stirring condition, and the reaction time is <NUM> hours. During this process, a large amount of ethanol is distilled out, and the conversion rate of the transesterification reaction is <NUM>%. Then a vacuum device is connected to distillation device and the transesterification continues under vacuum distillation conditions, wherein the vacuum degree of the reaction system was controlled to be <NUM>. 1kPa and the temperature was raised to <NUM>. After reacting for <NUM> hour, the transesterification is stopped. After the temperature is naturally cooled to be room temperature, the resulting sample is taken, and the conversion rate of the transesterification is <NUM>%.

<NUM> terephthalyl alcohol and <NUM> tripropyl borate are added to a three-necked flask which is connected to a distillation device. <NUM> tetrabutyl titanate as catalyst is added dropwise in the three-necked flask under stirring condition. The temperature is heated up to <NUM> under nitrogen protection, and the reaction time is <NUM> hours. During this process, a large amount of propanol is distilled out, and the conversion rate of the transesterification reaction is <NUM>%. Then a vacuum device is connected to distillation device and the transesterification continues under vacuum distillation conditions, wherein the vacuum degree of the reaction system was controlled to be 1kPa and the temperature was raised to <NUM>. After reacting for <NUM> hour, the transesterification is stopped. After the temperature is naturally cooled to be room temperature, the resulting sample is taken, and the conversion rate of the transesterification is <NUM>%.

The specific raw materials, amounts thereof and reaction conditions different from Example <NUM> are shown in Table <NUM> below, and the other procedures are the same as those in Example <NUM>.

The polyester polyol prepared in Example <NUM> to Example <NUM> are subjected to thermogravimetric analysis respectively, results of which are typically shown in <FIG> shows the thermal analysis curve of the polyester polyol prepared in Example <NUM>. It can be seen from the figure that the initial decomposition temperature of the polyester polyol prepared in Example <NUM> is <NUM>.

<FIG> shows the thermal analysis curve of the polyester polyol prepared in Example <NUM>. It can be seen from the figure that the initial decomposition temperature of the polyester polyol prepared in Example <NUM> is <NUM>.

The results of the polyester polyol prepared in other examples are similar to the above, and the initial decomposition temperature of the polyester polyol is higher than <NUM>.

Claim 1:
A method for preparing polyester polyol comprising following steps:
a) mixing inorganic oxyacid ester, polyhydric alcohol as raw materials and transesterification catalyst, and then performing the transesterification under stirring conditions and in an inactive protection atmosphere, wherein the reaction temperature ranges from <NUM> to <NUM>, and the reaction time ranges from <NUM> to <NUM> hours;
b) after the reaction in step a), performing vacuum distillation during which the vacuum degree ranges from <NUM> to 5kPa, the reaction temperature ranges from <NUM> to <NUM>, and the reaction time ranges from <NUM> to <NUM> hours;
wherein a molar ratio of inorganic oxyacid ester, polyhydric alcohol and transesterification catalyst satisfies: inorganic oxyacid ester: polyhydric alcohol = (<NUM>~<NUM>)n<NUM>/x,
wherein x is the number of moles of alkoxyl groups contained in each mole of inorganic oxyacid ester, and n<NUM> is the number of moles of hydroxyl groups contained in each mole of polyhydric alcohol.