Patent Description:
Membranes are widely used for the separation of gases and liquids, including for example, separating acid gases, such as CO<NUM> and H<NUM>S from natural gas, and the removal of O<NUM> from air. Gas transport through such membranes is commonly modeled by the sorption-diffusion mechanism. Polymeric membranes have been well studied and are widely available for gaseous separations due to easy process-ability and low cost. CMS membranes, however, have been shown to have attractive separation performance properties exceeding that of polymeric membranes.

CMS membranes are typically produced through thermal pyrolysis of polymer precursors. For example, it is known that defect-free hollow fiber CMS membranes can be produced by pyrolyzing cellulose hollow fibers (<NPL>)). In addition, many other polymers have been used to produce CMS membranes in fiber and dense film form, among which polyimides have been favored. Polyimides have a high glass transition temperature, are easy to process, and have one of the highest separation performance among other polymeric membranes, even prior to pyrolysis.

Polyimide hollow fibers have been pyrolyzed to form CMS membranes under vacuum such as described by <CIT>. <CIT> also discloses a method of using CMS membranes to separate CO<NUM> from a methane stream containing <NUM>% CO<NUM>, at <NUM> psia and <NUM>, with a selectivity of approximately <NUM>, a selectivity that is much higher than typical commercial polymeric membranes. Other patents that describe processes for producing carbon membranes (both asymmetric hollow "filamentary" and flat sheets), and applications for gas separation, include, for example, <CIT>, and <CIT>.

To improve the separation properties of CMS membranes formed from polyimides research has focused primarily on a particular polyimide used and the conditions used to carbonize the particular polyimide. For example, Steel and Koros performed a detailed investigation of the impact of pyrolysis temperature, thermal soak time, and polymer composition on the performance of carbon membranes. ) Membranes were produced in an air atmosphere at <NUM> Hg pressure. The results showed that increases in both temperature and thermal soak time increased the selectivity but decreased permeance for CO<NUM>/CH<NUM> separation. In addition, Steel et al showed that a precursor polymer with a tightly packed structure tends to lead to a CMS membrane having higher selectivity compared with less compact precursor polymers.

The impact of pyrolysis atmosphere has been researched. Suda and Haraya disclosed the formation of CMS membranes under different environments. ) CMS dense films were prepared from polyimide Kapton® at <NUM> in either argon or in vacuum. According to their gas separation properties, the results of an O<NUM>/N<NUM> separation were almost the same between <NUM> membranes formed under the different atmospheres. Suda and Haraya did not disclose the effects of atmosphere on CO<NUM> separation from natural gas, nor disclose how separation properties vary with ability and low cost. Similarly, Geiszler and Koros disclosed the results of CMS fibers produced from pyrolysis of fluorinated polyimide in helium and argon for both O<NUM>/N<NUM> and H<NUM>/N<NUM> separations. That paper disclosed a slightly higher selectivity with vacuum pyrolysis than the purged pyrolysis processes. In addition, Geiszler and Koros showed that the flow rate of the purge gases impacted performance. In <CIT>, the effect of using atmospheres having small amounts of oxygen in the pyrolysis atmosphere was described.

Limited research has been done on changing the chemistry of the polyimide such as incorporating metals that may have an affinity for particular gas molecules of interest (e.g., ethylene and propylene). Filler particles (clusters) of silver particles have been mixed in carbon membranes formed from P84 <NUM>,<NUM>'-<NUM>,<NUM>'-Benzophenone tetracarboxylic dianhydride (BTDA)-toluene diisocyanate/methylene diisocyanate (BTDA-TDI/MDI) copolyimide to separate He, CO<NUM>, O<NUM> and N<NUM>, has been described by<NPL>. Filler particles of alumina and silver were loaded into a carbonized phenolic resin for separating C<NUM>H<NUM>, C<NUM>H<NUM>, H, He, N<NUM>, CO<NUM> and O<NUM> as described by <NPL>. Particular metals such as silver and copper have been incorporated into sulfonated polymers such as sulfonated poly(phenylene oxide) in which metals were formed upon carbonization of the sulfonated polymer to separate H, He, N<NUM>, CO<NUM> and O<NUM>, but the residual sulfur may be potentially poisonous as described by <NPL>. Likewise, silver was incorporated into carbonized blends of a P84 copolyimide and a sulfonated poly (ether ether ketone) for the separation of He, N<NUM>, CO<NUM> and O<NUM>.

It would be desirable to provide a CMS membrane and method to make the CMS membrane to improve the separation of particular gases such as ethane from ethylene and propylene from propane. In particular, it would be desirable to provide such a CMS membrane that avoids one or more of the problems of the prior art such as one described above (e.g., sulfur poisoning).

A first aspect of the invention is a carbon molecular sieve membrane as defined in claim <NUM>. When referring to group of transition metal groups, the group being referred to is IUPAC new notation (periodic table) as per<NPL>).

A second aspect is a process for separating a gas molecule from a feed gas comprised of the gas molecule and at least one other gas molecule as defined in the respective independent claim.

A third aspect of the invention is a method of making a carbon molecular sieve membrane as defined in the respective independent claim.

Herein is further described a carbon molecular sieve module comprising a sealable enclosure comprised of: a plurality of carbon molecular sieve membranes, comprising at least one carbon molecular sieve membrane of the first aspect, contained within the sealable enclosure; an inlet for introducing a gas feed comprised of at least two differing gas molecules; a first outlet for permitting egress of a permeate gas stream; and a second outlet for egress of a retentate gas stream.

The gas separation method is particularly useful for separating gas molecules in gas feeds that have very similar molecular sizes such as ethane/ethylene and propane/propylene. It may also be used to separate gases from atmospheric air such as oxygen or separating gases (e.g., methane) in natural gas feeds.

<FIG> shows the X-ray absorption near edge structure (XANES) results for the valence state of Fe present in the Examples of the invention and reference materials showing, metallic Fe-Fe bonds and Fe+<NUM> valence.

The polyimide precursor polymer is a polyimide copolymer comprising <NUM>,<NUM>-diaminobenzoic acid (DABA) useful for making CMS membranes that does not contain sulfur and in which a transition metal is added. The polyimide contains <NUM>,<NUM>-diaminobenzoic acid (DABA) that allows for the incorporation of the transition metal into the polyimide structure ionically. The polyimide may be a conventional or fluorinated polyimide. Desirable polyimides typically contain at least two different moieties selected from <NUM>,<NUM>,<NUM>-trimethyl-<NUM>,<NUM>-phenylene diamine (DAM), oxydianaline (ODA), dimethyl-<NUM>,<NUM>-diaminodiphenyl-thiophene-<NUM>,<NUM>'-dioxide (DDBT), <NUM>,<NUM>-diaminobenzoic acid (DABA), <NUM>,<NUM>,<NUM>-tetramethyl-<NUM>,<NUM>-phenylene diamine (durene), meta-phenylenediamine (m-PDA), <NUM>,<NUM>-diaminotolune (<NUM>,<NUM>-DAT), tetramethylmethylenedianaline (TMMDA), <NUM>,<NUM>'-[<NUM>,<NUM>,<NUM>-trifluoro-<NUM>-(trifluoromethyl)ethylidene]-<NUM>,<NUM>-isobenzofurandion (6FDA), <NUM>,<NUM>',<NUM>,<NUM>'-biphenyl tetracarboxylic dianhydride (BPDA), pyromellitic dianhydride (PMDA), <NUM>,<NUM>,<NUM>,<NUM>-naphthalene tetracarboxylic dianhydride (NTDA), and benzophenone tetracarboxylic dianhydride (BTDA), with two or more of 6FDA, BPDA and DAM being preferred.

An exemplary polyimide, not according to the invention , designated as 6FDA/BPDA-DAM, may be synthesized via thermal or chemical processes from a combination of three monomers: DAM; 6FDA, and BPDA, each commercially available for example from Sigma-Aldrich Corporation. Formula <NUM> below shows a representative structure for 6FDA/BPDA-DAM, with a potential for adjusting the ratio between X and Y to tune polymer properties. As used in examples below, a <NUM>:<NUM> ratio of component X and component Y may also abbreviated as 6FDA/BPDA(<NUM>:<NUM>)-DAM. <CHM>
<CHM>.

Another exemplary polyimide, not according to the invention , designated as 6FDA-DAM lacks BPDA such that Y equals zero in Formula <NUM> above. Formula <NUM> below shows a representative structure for this polyimide.

A particularly useful polyimide for ionically incorporating a transition metal is <NUM>,<NUM>'-hexafluoroisopropylidene diphthalic anhydride (6FDA),<NUM>,<NUM>,<NUM>-trimethyl-<NUM>,<NUM>-phenylenediamine (DAM) and <NUM>,<NUM>-diaminobenzoic acid (DABA) as shown below in Formula <NUM>, and which may be abbreviated as 6FDA-DAM:DABA (<NUM>:<NUM>):
<CHM>.

To realize a CMS membrane of the invention, a transition metal is incorporated into the precursor polymer to form a transition metal bearing precursor polymer. The incorporation may be by any useful method whereby the transition metal may be incorporated into the polyimide. It is desirable that the transition metal is incorporated in the polyimide on a fine scale. The transition metal may be incorporated by physical mixing or blending. For example, the polymer and a transition metal salt may be dissolved in a solvent, mixed and the solvent removed. In a particular embodiment a transition metal salt and a polyimide precursor having polar moieties are dissolved in a solvent and upon removal of the solvent with or without further heating, the salt decomposes and the transition metal ionically cross-links the polyimide polymer through the polar moieties. An example of such incorporation is illustrated as follows:
<CHM>.

Transition metals may also be incorporated during the polyimide synthesis process. For example, a transition metal salt is added to a solution of polyamic acid having polar moieties, and the mixture is cast into a film. As the film is thermally cured at high temperature, the polyamic acid converts to polyimide and the metal ions react with the polar moieties to form an ionomer.

Incorporating the transition metal may also be achieved by infusing. For example, the metal may be incorporated into a solid polymer precursor by infusing a metal compound dissolved in a solvent (e.g., water, ethanol, methanol, hexane, HCF<NUM>, and supercritical CO<NUM>). An example of a metal compound useful to infuse or incorporate during the synthesis of the polyimide, other than those previously mentioned, is a metallocene such as ferrocene.

The transition metal salt may be any salt useful for incorporating into the polyimide, but typically is an organic salt such as a transition metal acetylacetonate, metal acetate, or metal chloride. Mixtures of differing salts as well as differing transition metals may be used.

The transition metal is iron (Fe) and is present in the CMS membrane at a valence state greater than <NUM> and less than <NUM> as determined by X-ray absorption near edge structure (XANES).

The amount of transition metal in the CMS membrane is from <NUM>% to <NUM>% by weight of the CMS membrane. Desirably, the amount of transition metal is at least about <NUM>%, <NUM>%, or <NUM>% to <NUM>%, <NUM>% or <NUM>% by weight of the CMS membrane.

In forming the CMS membranes, the polyimides incorporating the transition metal are formed into hollow fiber membranes or film membranes. These as formed membranes (i.e., not yet pyrolyzed) are substantially defect-free. "Defect-free" means that selectivity of a gas pair, typically oxygen (O<NUM>) and nitrogen (N<NUM>), through a hollow fiber membrane or film membrane is at least <NUM> percent of the selectivity for the same gas pair through a dense film prepared from the same composition as that used to make the polymeric precursor hollow fiber membrane. By way of illustration, a 6FDA/BPDA(<NUM>:<NUM>)-DAM polymer has an intrinsic O<NUM>/N<NUM> selectivity (also known as "dense film selectivity") of <NUM>.

Conventional procedures to make the polyimide hollow fibers or films may be used. For example, coextrusion procedures including such as a dry-jet wet spinning process (in which an air gap exists between the tip of the spinneret and the coagulation or quench bath) or a wet spinning process (with zero air-gap distance) may be used to make the hollow fibers and solution casting may be used to make the films.

The particular heating rates, final pyrolysis temperatures, cooling rates and combinations of them are somewhat dependent on the particular polyimide, transition metal used and desired separations to be performed. Nevertheless, generally, it has been found particularly for separating olefins (e.g., ethylene and propylene) from their paraffin analogs, that it is desirable to heat to the maximum pyrolysis temperature and hold at that temperature such that the transition metal tends to have an average valence state closer to its maximum as given in the periodic table in the <NPL>) as determined by XANES. Generally, this tends to mean that is it is desirable to heat rapidly, hold for short times at lower maximum pyrolysis temperatures.

Generally, the maximum or final pyrolysis temperature to carbonize the transition metal containing polyimide may be anywhere from <NUM> to <NUM>, but preferably is from about <NUM> to <NUM> or <NUM>. The heating rate may be any suitable such as <NUM>/minute to <NUM>/minute, but desirably is from about <NUM>/minute or <NUM>/minute to <NUM>/minute, or <NUM>/minute. The amount of time at the final pyrolysis temperature is desirably from as short time practicable in view of the heating rate, e.g., several seconds or one minute to about <NUM> minutes. In an embodiment, the hold time at the final pyrolysis temperature is from <NUM> minutes to <NUM> minutes. Longer times tend not to be necessary and may negatively affect the desired combination of permeance and selectivity. Likewise, the cooling rate may be any suitable method such as merely passively cooling the furnace (by shutting the power off), but it may be desirable to cool rapidly or accelerate the cooling by a heat removal method.

Exemplary heat removal methods include: flowing a gas directly over the carbon molecular sieve membrane within the furnace; flowing a gas through the carbon molecular sieve membrane within the furnace; removing the furnace insulation; flowing a liquid over at least a portion of the furnace or flowing a gas over at least a portion of the furnace. Any one or combination of heat removal methods may be used, with it being desirable to have the cooling rate as high as possible at least from the final pyrolysis temperature to about <NUM> or to room temperature. Generally, the average cooling rate from the final pyrolysis temperature to <NUM> is at least about <NUM>, <NUM> or <NUM>/minute. The average heating rate is the temperature difference between the final pyrolysis temperature and <NUM> and the total time it takes to reach <NUM>. The cooling rate from <NUM> to room temperature may be any practicable with faster being desirable merely for productivity sake.

It is understood that all temperatures, heating rates and cooling rates are those as measured in the furnace and not the actual CMS membranes being formed. The actual temperature of the CMS membranes being formed may vary somewhat due to temperature lag due to thermal mass within the furnace, particular furnace used and the like and is readily determinable by one skilled in the art.

Any suitable supporting means for holding the CMS membranes may be used during the pyrolysis including sandwiching between two metallic wire meshes or using a stainless steel mesh plate in combination with stainless steel wires and as described by <CIT> at col. <NUM>, line <NUM> to col. <NUM>, line <NUM>. A quartz plate may be desirably used when supporting a dense film as opposed to a hollow fiber.

The transition metal containing polyimide may be carbonized under various inert gas purge or vacuum conditions, preferably under inert gas purge conditions, for the vacuum pyrolysis, preferably at low pressures (e.g. less than <NUM> millibar). In one embodiment the pyrolysis utilizes a controlled purge gas atmosphere during pyrolysis in which low levels of oxygen are present in an inert gas. By way of example, an inert gas such as argon is used as the purge gas atmosphere. Other suitable inert gases include, but are not limited to, nitrogen, helium, or any combinations thereof. By using any suitable method such as a valve, the inert gas containing a specific concentration of oxygen may be introduced into the pyrolysis atmosphere. For example, the amount of oxygen in the purge atmosphere may be less than about <NUM> ppm (parts per million) O<NUM>/Ar. Alternatively, the amount of oxygen in the purge atmosphere may be less than <NUM> ppm O<NUM>/Ar. Embodiments include pyrolysis atmospheres with about <NUM> ppm, <NUM> ppm, or <NUM> ppm O<NUM>/Ar.

The gas permeation properties of a membrane can be determined by gas permeation experiments. Two intrinsic properties have utility in evaluating separation performance of a membrane material: its "permeability," a measure of the membrane's intrinsic productivity; and its "selectivity," a measure of the membrane's separation efficiency. One typically determines "permeability" in Barrer (<NUM> Barrer=<NUM>-<NUM> [cm<NUM> (STP) cm]/[cm<NUM> s cmHg], calculated as the flux (ni) divided by the partial pressure difference between the membrane upstream and downstream (Δpi), and multiplied by the thickness of the membrane (l).

Another term, "permeance," is defined herein as productivity of asymmetric hollow fiber membranes and is typically measured in Gas Permeation Units (GPU) (<NUM> GPU=<NUM>-<NUM> [cm<NUM> (STP)]/[cm<NUM> s cmHg]), determined by dividing permeability by effective membrane separation layer thickness.

Finally, "selectivity" is defined herein as the ability of one gas's permeability through the membrane or permeance relative to the same property of another gas. It is measured as a unitless ratio.

In a particular embodiment, the CMS membrane produced by the method enables a carbon hollow fiber CMS membrane that has a permeance of at least <NUM> GPU for a target gas molecule (permeate) and a selectivity of at least <NUM> and a stability such that said permeance and selectivity varies less than <NUM>% after being continuously separating a feed gas comprised of a retentate gas molecule and permeate gas molecule for <NUM> days. Desirably, the permeance and selectivity varies less than <NUM>%, <NUM>% or <NUM>% after continuously separating a feed gas comprised of a retentate and permeate gas molecule pair for <NUM>, <NUM> or <NUM> days. In particular embodiments the permeate/retentate gas molecule pairs may be ethylene/ethane, propylene/propane, butylene/butane, methane/carbon dioxide, methane/water, oxygen/nitrogen, and methane/hydrogen sulfide. Illustratively, the feed gas generally is comprised of at least <NUM>% the permeate gas molecule (e.g., ethylene or propylene) and <NUM>% of retentate gas molecule (e.g., ethane or propane).

In a particular embodiment the CMS membrane produced has a permeance of at least <NUM> GPU for propylene (permeate) and a selectivity of at least <NUM> propylene/propane. Desirably, in this embodiment the permeance is at least <NUM>, <NUM> or even <NUM> GPU for propylene. Likewise, in this embodiment the selectivity is at least <NUM>, <NUM> or even <NUM> for propylene/propane. In another particular embodiment, the CMS membrane produced has a permeance of at least <NUM> GPU for ethylene (permeate) and a selectivity of at least <NUM> ethylene/ethane. Desirably, in this embodiment the permeance is at least <NUM>, <NUM> or even <NUM> GPU for ethylene. Likewise, in this embodiment the selectivity is at least <NUM>, <NUM> or even <NUM> for ethylene/ethane. In a further embodiment, the CMS membrane produced has a permeance of at least <NUM> GPU for butylene (permeate) and a selectivity of at least <NUM> for butylene/butane. Desirably, in this embodiment the permeance is at least <NUM>, <NUM> or even <NUM> GPU for butylene. Likewise, in this embodiment the selectivity is at least <NUM>, <NUM> or even <NUM> for butylene/butane.

The CMS membranes are particularly suitable for separating gases that are similar in sizes such as described above and involve flowing a gas feed containing a desired gas molecule and at least one other gas molecule through the CMS membrane. The flowing results in a first stream have an increased concentration of the desired gas molecule and second stream having an increased concentration of the other gas molecule. The process may be utilized to separate any of the aforementioned gas pairs and in particular is suitable for separating ethylene and ethane or propylene and propylene. Likewise, the process exhibits the same stability as it relates to permeance and selectivity over time as described above. When practicing the process, the CMS membrane is desirably fabricated into a module comprising a sealable enclosure comprised of a plurality of carbon molecular sieve membranes that is comprised of at least one carbon molecular sieve membrane produced by the method of the invention that are contained within the sealable enclosure. The sealable enclosure having an inlet for introducing a gas feed comprised of at least two differing gas molecules; a first outlet for permitting egress of a permeate gas stream; and a second outlet for egress of a retentate gas stream.

The CMS membranes were made using 6FDA-DAM:DABA (<NUM>:<NUM>) polymer. The 6FDA-DAM:DABA was acquired from Akron Polymer Systems, Inc. , Akron , OH. The polymer was dried under vacuum at <NUM> overnight to remove moisture. The dried polymer was dissolved in tetrahydrofuran (THF) in a <NUM> vial (vial A) to form a <NUM> to <NUM> wt% polymer solution. Iron(II) acetylacetonate (Sigma-Aldrich, St. Louis, MO) was dissolved in THF in a <NUM> vial (vial B) to form a Fe-containing solution. The two solutions were filtered with <NUM> micron PTFE filters respectively, and the Fe-containing solution in vial B was added to vial A to form the Fe-containing polymer dope for casting. The compositions of the solutions are shown in Table <NUM>.

Dense films were prepared by casting the mixed solution into a Teflon casting dish inside a glove bag at room temperature to allow for a slow evaporation rate. After at least <NUM> days, the vitrified films were removed from the bag and dried in a vacuum oven at <NUM> for <NUM> hours to remove residual solvent. The dried films having a thickness of about <NUM> micron were then cut into <NUM> inch diameter discs that were then pyrolyzed as described below.

The discs were pyrolyzed to form the CMS membranes by placing the discs on a slotted quartz plate with spacing between each disc. The combination of the discs and quartz plate were placed into a quartz tube of a tube furnace. The films were pyrolyzed under an inert gas (argon flowing at a rate of <NUM> standard cubic centimeters per minute (sccm)). Prior to pyrolyzing the furnace was purged with inert gas to remove oxygen for a minimum of ten hours to reduce the oxygen level to less than <NUM> ppm. The films were heated at a ramp rate and held at the maximum soak temperature as shown in Table <NUM> to form the final CMS membranes. The formed CMS membranes were all cooled passively (furnace shut off with the same inert gas flow maintained until the furnace was cooled to about room temperature, ~<NUM>-<NUM> hours.

After cooling, the CMS membranes were masked in a dense film permeation cell by using impermeable aluminum tape and five minute epoxy (<NUM>™ Scotch-Weld™ Epoxy Adhesive DP110). The permeation cell was then placed in a constant-volume permeation system, and the system was stabilized at <NUM>. For each permeation test, the entire system was evacuated for <NUM> hours. After evacuation, the upstream was pressurized with feed gas at about <NUM> pounds per square inch absolute pressure (psia) while the downstream was kept at vacuum. The pressure rise in a constant, known downstream volume was monitored by a pressure transducer and recorded over time by LabVIEW (National Instruments, Austin, TX) until a steady state was achieved.

Examples <NUM> through <NUM> were evaluated for multiple-component olefins/paraffins mixture separation. The multicomponent feed contained <NUM> mol% ethylene, <NUM> mol% ethane, <NUM> mol% propylene, and <NUM> mol% propane. The separation characteristics of the CMS membranes of Examples <NUM> through <NUM> for the multicomponent feed are shown in Table <NUM>. Example <NUM> and Comparative Example <NUM> were also tested for pure gas permeation, and their permeation characteristics and selectivity are shown in Table <NUM>.

A pressure decay sorption system was used to measure sorption properties of CMS membranes. The CMS membranes were crushed into small pieces between two pieces of weighing paper and wrapped with aluminum foil securely. The samples were loaded into the sample cell chamber, and the sorption cell was then placed in an oil bath with a heating circulator to maintain uniform temperature at <NUM>. The entire system was evacuated for <NUM> hours before testing. For the measurement at each pressure level, the reservoir cell chamber was filled with feed gas and equilibrated for <NUM> to <NUM> minutes. The valve between the reservoir and the sample cell was then opened carefully to introduce gas into the sample cell. The pressure in both the reservoir and sample cell was monitored by a pressure transducer and recorded over time by LabVIEW (National Instruments, Austin, TX) until the pressure became constant. The amount of sorbed gas was calculated based on a mole balance. Gas uptake was plotted against equilibrium pressure and the data was fitted using a Langmuir model to obtain sorption isotherms. The sorption results of ethane and ethylene are shown in Table <NUM>.

For CMS membranes of Examples <NUM>,<NUM>, <NUM> and <NUM> as well as for the iron foil and iron acetylacetonate, X-ray absorption near edge structure (XANES) was performed to determine the valence state of the Fe, with the Fe foil representing a zero or metallic Fe-Fe bond and the iron acetylacetonate representing an Fe+<NUM> valence. The Fe K-edge XANES spectra were collected at Argonne National Laboratory, Lemont, IL in transmission mode at room temperature. The results are shown in <FIG>, where it can be seen that the faster lower temperature pyrolysis conditions results in an average Fe bonding state that is closer to Fe+<NUM>.

Comparative Example CMS membranes <NUM> and <NUM> were prepared and tested in the same manner as Examples <NUM> through <NUM>, except that the casting solution did not contain the iron(II) acetylacetonate. The particular heating conditions to form these CMS membranes are shown in Table <NUM>. The separation characteristics of these CMS membranes for the multicomponent feed are shown in Table <NUM>. Comparative Example <NUM> was also tested for pure gas permeation, and its separation characteristics are shown in Table <NUM>.

The results in Table <NUM> show that metal-containing CMS membranes (i.e., Examples <NUM> and <NUM>) pyrolyzed with a lower temperature and at a faster heating rate show C<NUM>H<NUM>/C<NUM>H<NUM> sorption selectivity that is enhanced compared to CMS membranes pyrolyzed at a higher temperature and slower heating rate (Comparative Examples <NUM>, <NUM> and <NUM>). The sorption data also show that Examples <NUM> and <NUM> have improved sorption selectivity compared to membranes without iron (Comparative Examples <NUM> and <NUM>).

The separation characteristics for the multicomponent feed in Table <NUM> also show that Examples <NUM>, <NUM> and <NUM> each have a C<NUM>H<NUM>/C<NUM>H<NUM> selectivity that is much higher than the C<NUM>H<NUM>/C<NUM>H<NUM> selectivity of Comparative Examples <NUM> and <NUM>. Likewise the pure gas permeation characteristics shown in Table <NUM> show that the metal-containing CMS membrane (Example <NUM>) has a much higher C<NUM>H<NUM>/C<NUM>H<NUM> selectivity of <NUM> than Comparative <NUM>'s C<NUM>H<NUM>/C<NUM>H<NUM> selectivity of <NUM> in which both were made using the same heating rate and temperature. From XANES results shown in <FIG>, iron in the metal-containing CMS membranes of the Examples have a higher valence state (Fe<NUM>+, Fe<NUM>+, or between Fe<NUM>+ and Fe<NUM>+) when the films are pyrolyzed at a lower temperature and at a faster heating rate. That is, Examples <NUM> and <NUM> have the most desirable permeation and separation characteristics, which correspond to a higher iron valence state as compared to Examples <NUM>, <NUM> and <NUM>.

Claim 1:
A carbon molecular sieve membrane formed from a precursor polymer that is a polyimide copolymer comprising <NUM>,<NUM>-diaminobenzoic acid (DABA), said carbon molecular sieve membrane comprising, carbon, a transition metal and in the absence of sulfur, wherein the transition metal is Fe and the average valence state is greater than <NUM> and less than <NUM> as determined by X-ray absorption near edge structure (XANES), wherein the transition metal is present in the CMS membrane in an amount of from <NUM>% to <NUM>% by weight of the CMS membrane.