Patent Description:
Transparent polymer films are widely used as core materials in the fields of optical, transparent and flexible displays, and in particular have come to replace glass in the display industry due to the light weight, ease of processing and flexibility thereof. However, since transparent polymer films have disadvantages of low surface hardness and abrasion resistance compared to glass, coating techniques for improving the abrasion resistance of polymer films arise as an important issue.

The materials used for polymer films broadly include organic materials, inorganic materials and hybrid organic-inorganic materials. Thereamong, organic materials have advantages of flexibility and moldability due to the inherent characteristics of organic substances, but have the disadvantage of low surface hardness, whereas inorganic materials have the advantages of high surface hardness and transparency, but have the disadvantages of poor flexibility and moldability. For this reason, hybrid organic-inorganic materials having the advantages of both materials are receiving attention at present, and active research thereon is underway. However, it is not possible at present to realize the advantages of both types of materials.

In addition, the most important requirements in order for surface-coated polymer films to be appropriate for use in optical applications are that coating agents should have excellent adhesivity to the films and should be free from curling and rainbow phenomena. Therefore, finding coating materials that are capable of exhibiting all of these advantages has arisen as a key issue for technological development.

There are several patent documents that disclose coating compositions relating to polymer films. For example, <CIT> discloses a high-hardness hard coating film composition including an ultraviolet-ray-curable polyurethane acrylate oligomer, and <CIT> discloses a vinyl oligosiloxane hybrid composition including a metal catalyst. The former case can minimize the curling phenomenon and prevent the rainbow phenomenon, which is caused by optical interference. The latter case is reported as a composition having an inorganic network structure that can accomplish a low shrinkage rate and excellent optical properties and heat resistance.

Meanwhile, <CIT> discloses a high-hardness siloxane resin composition containing a cyclic epoxy group, a method for preparing the same, and an optical film including a cured product thereof. This patent suggests that the technical level of the hard coating has improved such that a high hardness of <NUM> is able to be achieved. However, despite achieving such a high-hardness coating, the patent entails concerns about weather resistance due to the use of a single monomer and a cationic initiator, which is also a great obstacle to processing in mass production, such as a roll-to-roll process, has a limitation in that curling occurs, which may cause problems associated with durability of a subsequently provided product, and is inapplicable to flexible displays due to the excessive hardness, and thus decreased flexibility, thereof.

As such, coating materials still have limitations in that drawbacks in terms of hardness and permeability are inevitable when highlighting the advantages of organic materials, and the drawback associated with flexibility cannot be completely overcome when highlighting the advantages of inorganic materials. In particular, organic materials are suitable for surface coating of polymer films due to the advantageous flexibility thereof. However, when the surface hardness of the coating layer is improved by forming a dense network between the molecules, increased shrinkage may result in curling and cracking, which causes the coating layer to peel off due to the deteriorated adhesivity. Therefore, for wider use of polymer films, there is urgent need for techniques capable of preventing deterioration in the flexibility of films due to the coating while increasing the surface hardness thereof. <CIT> discloses a siloxane coating composition based on methyltriethoxysilane, methacryloxypropyl trimethoxysilane, and glycidoxypropyl trimethoxysilane. Its Example <NUM> also includes dimethyldimethoxysilane.

Therefore, the present disclosure has been made in view of the above problems, and it is one object of the present disclosure to provide a resin composition for coating which has a surface hardness of at least <NUM> as well as excellent flexibility and curling property. It is another object of the present disclosure to provide a coating film including a cured product of the resin composition as a coating layer.

In accordance with a first aspect of the present disclosure to solve the technical problems, provided is a resin composition for coating comprising a siloxane resin obtained through a chemical bond of compounds comprising: an alkoxysilane represented by the following Formula <NUM>; and at least one alkoxysilane selected from an alkoxysilane represented by the following Formula <NUM> and an alkoxysilane represented by the following Formula <NUM>, as well as a diol represented by Formula <NUM> shown below:.

<Formula <NUM>>     R<NUM>nSi(OR<NUM>)<NUM>-n.

wherein R<NUM> is a C1-C3 linear, branched or cyclic alkylene group substituted with epoxy or acryl, R<NUM> is a C1-C8 linear, branched or cyclic alkyl group, and n is an integer of <NUM> to <NUM>,.

<Formula <NUM>>     R<NUM>Si(OR<NUM>)<NUM>.

wherein R<NUM> and R<NUM> each independently represent a C1 to C4 linear or branched alkyl group, and.

<Formula <NUM>>     R<NUM><NUM>Si(OR<NUM>)<NUM>.

wherein R<NUM> and R<NUM> each independently represent a C1 to C4 linear or branched alkyl group.

In the first aspect, the at least one alkoxysilane selected from the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM> may be present in a molar ratio (%) of <NUM> to <NUM> moles with respect to the total of <NUM> moles of the alkoxysilane represented by the following Formula <NUM>.

In this case, the siloxane resin may be obtained through a chemical bond of compounds including both the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM>, and the molar ratio of the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM> may be <NUM>:<NUM> to <NUM>:<NUM>.

The siloxane resin is obtained through a chemical bond of compounds further including a diol represented by the following Formula <NUM>:.

wherein n is an integer of <NUM> to <NUM>.

In this case, the diol may be present in a molar ratio (%) of <NUM> to <NUM> moles with respect to the total of <NUM> moles of the alkoxysilane represented by Formula <NUM>.

The alkoxysilane represented by Formula <NUM> may include at least one selected from <NUM>-glycidoxypropyl trimethoxysilane, <NUM>-glycidoxypropyl triethoxysilane, <NUM>-glycidoxypropyl tripropoxysilane, <NUM>-methacryloxypropyl trimethoxysilane, <NUM>-methacryloxypropyl triethoxysilane, <NUM>-acryloxypropyl trimethoxysilane, <NUM>-acryloxypropyl triethoxysilane, <NUM>-acryloxypropyl tripropoxysilane, <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltrimethoxysilane, <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltriethoxysilane and <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltripropoxysilane.

The siloxane resin according to the first aspect may have a weight average molecular weight of <NUM>,<NUM> to <NUM>,<NUM> and a molecular weight distribution of <NUM> to <NUM>.

The resin composition for coating according to the first aspect may further include at least one additive selected from the group consisting of an organic solvent, a photoinitiator, a thermal initiator, an antioxidant, a leveling agent and a coating aid.

In accordance with a second aspect of the present disclosure, there is provided a coating film including a base film and a coating layer formed on at least one surface of the base film using the resin composition for coating according to the first aspect.

In this case, the coating film according to the second aspect may have a surface hardness in the direction in which the coating layer is formed, measured in accordance with ASTM D3363, of <NUM> or more.

In addition, the coating film according to the second aspect may have a distance (curl) from a bottom to an edge of the film, of <NUM> or less and a radius of curvature, measured using a radial mode of a bending tester (JIRBT-<NUM>-<NUM>), of <NUM> or less, based on a coating thickness of <NUM> to <NUM>, which means that the coating film has an excellent curling property and flexibility.

The present disclosure is capable of ensuring surface hardness and scratch resistance through the dense crosslinking of a siloxane network formed from an alkoxysilane containing epoxy or acryl, and is capable of securing flexibility of the molecular bond and thus curling property and flexibility during curing by introducing dialkoxysilane having a silane D structure and trialkoxysilane having a silane T structure.

In one aspect, the present disclosure is directed to a resin composition for coating including a siloxane resin obtained by a chemical bond of compounds including alkoxysilane containing epoxy or acryl and trialkoxysilane having a silane T structure and dialkoxysilane having a silane D structure.

More specifically, the alkoxysilane containing epoxy or acryl may be represented by the following Formula <NUM>, and more preferably includes at least one selected from <NUM>-glycidoxypropyl trimethoxysilane, <NUM>-glycidoxypropyl triethoxysilane, <NUM>-glycidoxypropyl tripropoxysilane, <NUM>-methacryloxypropyl trimethoxysilane, <NUM>-methacryloxypropyl triethoxysilane, <NUM>-acryloxypropyl trimethoxysilane, <NUM>-acryloxypropyl triethoxysilane, <NUM>-acryloxypropyl tripropoxysilane, <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltrimethoxysilane, <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltriethoxysilane and <NUM>-(<NUM>,<NUM>-epoxycyclohexyl)ethyltripropoxysilane.

wherein R<NUM> is a C1-C3 linear, branched or cyclic alkylene group substituted with epoxy or acryl, R<NUM> is a C1-C8 linear, branched or cyclic alkyl group, and n is an integer of <NUM> to <NUM>.

When the siloxane resin is synthesized using the silane compound alone, high surface hardness can be secured, but there is a limitation on securing flexibility, since the bonding structure is formed only through dense siloxane crosslinking. Accordingly, by polymerizing a siloxane resin from compounds including at least one alkoxysilane selected from alkoxysilane represented by the following Formula <NUM> and alkoxysilane represented by the following Formula <NUM> as well as the alkoxysilane represented by Formula <NUM>, the present disclosure is capable of securing flexibility of the molecular bond and thus imparting excellent flexibility to the cured product of the resin composition.

That is, Formulas <NUM> and <NUM> show a trialkoxysilane having a silane T structure and a dialkoxysilane having a silane D structure, respectively, and contain an alkyl group that does not correspond to the polymerization functional group of the silane, thus securing the intermolecular space and thereby improving flexibility and curling properties.

The at least one alkoxysilane selected from the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM> in the present disclosure is present in a molar ratio (%) of <NUM> to <NUM> moles, preferably <NUM> to <NUM> moles, based on the total of <NUM> moles of the alkoxysilane represented by Formula <NUM>, because high surface hardness can be secured and flexibility can be improved. When the molar ratio is lower than the predetermined range, the surface hardness of the cured product may be further increased due to the increased content of the alkoxysilane represented by Formula <NUM>, but flexibility may be deteriorated. When the molar ratio exceeds the predetermined range, a certain level of surface hardness may be not obtained due to excessive flexibility.

In this case, in order to improve the bending property while maintaining a hardness of <NUM> or more, in the present disclosure, the siloxane resin may be advantageously obtained by a chemical bond of compounds including both the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM>.

The molar ratio of the alkoxysilane represented by Formula <NUM> and the alkoxysilane represented by Formula <NUM> may be <NUM>:<NUM> to <NUM>:<NUM>, preferably <NUM>:<NUM> to <NUM>:<NUM>, and more preferably <NUM>:<NUM> to <NUM>:<NUM>, because hardness can be maintained. When the molar ratio of the silane compound represented by Formula <NUM> is less than the predetermined range, the bending property may be poor compared to when the molar ratio of the silane compound represented by Formula <NUM> falls within the predetermined range.

Meanwhile, in the present disclosure, in order to improve flexibility, a diol represented by the following Formula <NUM> is incorporated in the polymerization of the siloxane resin. Through adding the diol, a linear diol structure is introduced into the polymer chain of the siloxane resin, so that the flexibility of the cured product can be further improved.

In the present disclosure, the diol may be present in a molar ratio (%) of <NUM> to <NUM> moles, preferably <NUM> to <NUM> moles, and more preferably <NUM> to <NUM> moles with respect to the total of <NUM> moles of the alkoxysilane. When the molar ratio of the diol exceeds the predetermined range, the polymerization rate may be slowed down due to the problem of the diol residue, and conversely, when the molar ratio does not reach the predetermined range, the addition of the diol may be meaningless due to the small increase in flexibility.

In the present disclosure, the synthesis of the siloxane resin may be carried out at room temperature, but may alternatively be carried out while performing stirring at <NUM> to <NUM> for <NUM> to <NUM> hours. The catalyst for conducting the reaction may be an acid catalyst such as hydrochloric acid, acetic acid, hydrogen fluoride, nitric acid, sulfuric acid or iodic acid, a base catalyst such as ammonia, potassium hydroxide, sodium hydroxide, barium hydroxide or imidazole, and an ion exchange resin such as Amberite. These catalysts may be used alone or in combination. In this case, the amount of the catalyst may be about <NUM> parts to about <NUM> parts by weight, based on <NUM> parts by weight of the siloxane resin, but is not particularly limited thereto. When the reaction is conducted, water or alcohol is produced as a byproduct. When removing this water or alcohol, the reverse reaction can be suppressed and the forward reaction can be performed more quickly, so that control of the reaction rate is possible through this principle. After completion of the reaction, the byproduct can be removed by heating under reduced pressure.

The siloxane resin of the present disclosure thus synthesized may have a weight average molecular weight of <NUM>,<NUM> to <NUM>,<NUM> and a polydispersion index (PDI) of <NUM> to <NUM>. The molecular weight (Mw) and polydispersion index (PDI) correspond to the weight average molecular weight (Mw) and the number average molecular weight (Mn) determined for polystyrene through gel permeation chromatography (GPC, Waters Alliance, Model: e2695). The polymer to be measured was dissolved at a concentration of <NUM>% in tetrahydrofuran and was injected in an amount of <NUM>µl into GPC. The mobile phase of GPC was tetrahydrofuran and was fed at a flow rate of <NUM>/min, and analysis was conducted at <NUM>. The column used herein was purchased from Waters Styragel HR3, and two columns were connected in series. The detector herein used was an RI detector (Waters Alliance, <NUM>) and measurement was conducted at <NUM>. At this time, the molecular weight distribution (PDI) was calculated by dividing the measured weight average molecular weight by the number average molecular weight.

Meanwhile, in addition to the siloxane resin, the resin composition for coating may further include, as another component, at least one additive selected from the group consisting of an organic solvent, a photoinitiator, a thermal initiator, an antioxidant, a leveling agent and a coating aid. In this case, it is possible to provide a resin composition for coating suitable for various applications by controlling the kind and content of the additive that is used. In the present disclosure, a resin composition for coating capable of exhibiting improved hardness, abrasion resistance, flexibility and curling resistance is preferably provided.

The initiator according to the present disclosure is, for example, a photopolymerization initiator such as an organometallic salt and a photopolymerization initiator such as amine and imidazole. In this case, the amount of the initiator that is added is preferably about <NUM> to <NUM> parts by weight based on <NUM> parts by weight of the total amount of the siloxane resin. When the content of the initiator is less than <NUM> parts by weight, the curing time of the coating layer required to obtain sufficient hardness is lengthened and efficiency is thus deteriorated. When the content of the initiator is more than <NUM> parts by weight, the yellowness of the coating layer may be increased, thus making it difficult to obtain a transparent coating layer.

Also, the organic solvent may include, but is not limited to, at least one selected from the group consisting of: ketones such as acetone, methyl ethyl ketone, methyl butyl ketone and cyclohexanone; cellosolves such as methyl cellosolve and butyl cellosolve; ethers such as ethyl ether and dioxane; alcohols such as isobutyl alcohol, isopropyl alcohol, butanol and methanol; halogenated hydrocarbons such as dichloromethane, chloroform and trichloroethylene; and hydrocarbons such as normal hexane, benzene and toluene. In particular, since the viscosity of the siloxane resin can be controlled by controlling the amount of the organic solvent that is added, the amount of the organic solvent can be suitably controlled in order to further improve workability or to control the thickness of the coating film.

Further, the present disclosure may provide a cured product having high hardness obtained by forming the resin composition for coating using a method such as coating, casting or molding, followed by photopolymerization or thermal polymerization. In particular, the present disclosure is directed to a coating film including a base film and a coating layer laminated on at least one surface of the base film and including a cured product of the resin composition for coating as a coating layer.

The coating film may have a surface hardness in the direction in which the coating layer is formed, measured in accordance with ASTM D3363, of at least <NUM>, the coating film may have a distance (curl) from the bottom to the edge of the film, of <NUM> or less, based on a coating thickness of <NUM> to <NUM>, and the coating film may have a radius of curvature, measured using a radial mode of a bending tester (JIRBT-<NUM>-<NUM>), of <NUM> or less, based on a coating thickness of <NUM> to <NUM> pm. This means that the resin composition has sufficient hardness as well as excellent curl characteristics and flexibility. Particularly, because various desirable conditions are satisfied, hardness of <NUM> or more can be secured, and the curl and the radius of curvature may be <NUM> or less and <NUM> or less, respectively, based on a coating thickness of <NUM>, which means that physical properties can be further improved.

In the present disclosure, when the resin composition for coating is polymerized, the amount of light suitable for photopolymerization may be not less than <NUM> mJ/cm<NUM> and not more than <NUM>,<NUM> mJ/cm<NUM>, and heat treatment may be performed at a temperature not lower than <NUM> and not higher than about <NUM> so as to obtain a uniform surface. The temperature suitable for photopolymerization is not lower than <NUM> and not higher than <NUM>, but is not limited thereto.

Hereinafter, the present disclosure will be described in more detail with reference to the following Examples. The examples are only provided only for better understanding of the present disclosure, and should not be construed as limiting the scope of the present disclosure.

Among the compounds used in Examples and Comparative Examples of the present disclosure, KBM-<NUM> is an alkoxysilane represented by Formula <NUM> of R<NUM>nSi(OR<NUM>)<NUM>-n, wherein R<NUM> is a glycidoxypropylene group, R<NUM> is a methyl group, and n is <NUM>, and KBM-<NUM> is an alkoxysilane represented by Formula <NUM> of R<NUM>nSi(OR<NUM>)<NUM>-n wherein R<NUM> is a methylacryloxypropylene group, R<NUM> is a methyl group, and n is <NUM>.

In addition, TEMS (methyltrimethoxysilane) is an alkoxysilane represented by Formula <NUM> of R<NUM>Si(OR<NUM>)<NUM> wherein R<NUM> is a methyl group and R<NUM> is an ethyl group, and DMDMMS (dimethoxydimethylsilane) is an alkoxysilane represented by Formula <NUM> of R<NUM><NUM>Si(OR<NUM>)<NUM> wherein R<NUM> is a methyl group and R<NUM> is a methyl group. In addition, TEOS (tetraethoxysilane) used in comparative examples is an alkoxysilane represented by the formula Si(OR<NUM>)<NUM> wherein R<NUM> is an ethyl group.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>.

Next, <NUM> parts by weight of IRGACURE <NUM> (BASF Corporation), which is a photoinitiator, with respect to <NUM> parts by weight of the siloxane resin, was added to the siloxane resin diluted in the solvent to finally obtain a resin composition for coating.

This composition was coated on the polyimide surface using a bar, dried at <NUM> for <NUM> minutes and then exposed to an ultraviolet lamp having a wavelength of <NUM> for <NUM> seconds to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), DMDMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM> and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), DMDMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, and a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, and a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), DMDMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), DMDMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM>.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), DMDMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM>.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), DMDMS (Sigma-Aldrich Corporation), and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), DMDMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM>: <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

The process was performed in the same manner as in Example <NUM>, except that KBM-<NUM> (Shin-Etsu Chemical Co. ), TEMS (Sigma-Aldrich Corporation), DMDMS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol).

The process was performed in the same manner as in Example <NUM>, except that KBM-<NUM> (Shin-Etsu Chemical Co. ), DMDMS (Sigma-Aldrich Corporation), ethylene glycol (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol : <NUM> mol).

KBM-<NUM> (Shin-Etsu Chemical Co. ) and distilled water were mixed at a ratio of <NUM> : <NUM> (<NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

KBM-<NUM> (Shin-Etsu Chemical Co. ), TEOS (Sigma-Aldrich Corporation) and distilled water were mixed at a ratio of <NUM> : <NUM> : <NUM> (<NUM> mol : <NUM> mol : <NUM> mol), the resulting mixture was injected into a <NUM>,<NUM> double-jacket reactor, a sodium hydroxide solution (NaOH <NUM> in H<NUM>O <NUM>) was added as a catalyst, and the mixture was stirred at <NUM> RPM with a mechanical stirrer at <NUM> for <NUM> hours using a thermostat. Then, the resulting mixture was diluted with <NUM>-butanone to realize a solid content of <NUM> wt%, and was then filtered through a <NUM> Teflon filter to obtain a siloxane resin. The molecular weight of the resin was measured using GPC, and the result showed that the resin had a number average molecular weight of <NUM>,<NUM>, a weight average molecular weight of <NUM>,<NUM>, and a polydispersity index (PDI, Mw/Mn) of <NUM>. Next, a resin composition for coating was prepared in the same manner as in Example <NUM>, and a polyimide film was coated therewith to prepare a coating film with a thickness of <NUM> pm.

The physical properties of the prepared coating films of Examples and Comparative examples were evaluated in accordance with the following methods, and the results are shown in Table <NUM> below.

As can be seen from Table <NUM>, Comparative Examples <NUM> to <NUM>, in which an alkoxysilane having a T structure or an alkoxysilane having a D-structure is not used for the synthesis of a siloxane resin, have a radius of curvature (R) higher than <NUM>, thus exhibiting significantly lowered flexibility or considerably low curling properties compared to Examples <NUM> to <NUM>.

In particular, when comparing Comparative Example <NUM> using KBM-<NUM> including an epoxy reactive group with Example <NUM> using KBM-<NUM> in the same amount, it can be seen that Example <NUM> containing an alkoxysilane having a D structure exhibits improved hardness, curling property, and bending property compared to Comparative Example <NUM>.

In addition, when comparing Comparative Example <NUM> using KBM-<NUM>, containing an acrylic reactive group, with Examples <NUM>, <NUM>, <NUM>, <NUM> and <NUM>, containing an alkoxysilane or diol, it can be seen that Examples <NUM>, <NUM>, <NUM>, <NUM> and <NUM> have better pencil hardness, curling property, scratch resistance and flexibility.

In addition, among Examples, Examples <NUM>, <NUM>, <NUM> and <NUM>, containing an alkoxysilane having a D structure, have better flexibility than Examples <NUM>, <NUM>, <NUM> and <NUM>, containing an alkoxysilane having a T structure.

In addition, among Examples, Examples <NUM>, <NUM>, <NUM> and <NUM> using KBM-<NUM> containing an epoxy reactive group have better curl and bending properties than Examples <NUM>, <NUM>, <NUM> and <NUM> using KBM-<NUM> containing an acrylic reactive group.

In addition, among Examples, Examples <NUM> to <NUM> and <NUM> containing a diol have a better bending property than Examples containing no diol.

As can be seen from Examples described above, the resin composition for coating according to the present disclosure is capable of securing flexibility of the molecular bond and thus maximizing curling property and flexibility during curing without deterioration in surface hardness by introducing dialkoxysilane, having a silane D structure, and trialkoxysilane, having a silane T structure, into the synthesis of the siloxane resin.

Claim 1:
A resin composition for coating comprising a siloxane resin obtained through a chemical bond of compounds comprising:
an alkoxysilane represented by the following Formula <NUM>;
at least one alkoxysilane selected from an alkoxysilane represented by the following Formula <NUM> and an alkoxysilane represented by the following Formula <NUM>: and
a diol represented by the following Formula <NUM>:

        <Formula <NUM>>     R<NUM>nSi(OR<NUM>)<NUM>-n

wherein R<NUM> is a C1-C3 linear, branched or cyclic alkylene group substituted with epoxy or acryl, R<NUM> is a C1-C8 linear, branched or cyclic alkyl group, and n is an integer of <NUM> to <NUM>,

        <Formula <NUM>>     R<NUM>Si(OR<NUM>)<NUM>

wherein R<NUM> and R<NUM> each independently represent a C1 to C4 linear or branched alkyl group,

        <Formula <NUM>>     R<NUM><NUM>Si(OR<NUM>)<NUM>

wherein R<NUM> and R<NUM> each independently represent a C1 to C4 linear or branched alkyl group, and

        [Formula <NUM>]     HO(CH<NUM>)nOH

wherein n is an integer of <NUM> to <NUM>.