Patent Description:
Along with the progress and development of the petroleum industry, the target strata for oil and gas exploration and exploitation have been gradually shifted from the middle and shallow strata to the deep and ultra-deep strata. Based on the results of the Fourth Resource Evaluation, the oil and gas resources in deep and ultra-deep strata in China have reached <NUM> billion tons of oil equivalents, which accounts for about <NUM>% of the total oil and gas resources, and the corresponding exploration and development potential is enormous. However, both the deep and ultra-deep reservoir strata face the problems of heterogeneous control of the reservoir strata, wherein the heterogeneous control problems of the deep reservoir strata (≥<NUM>,<NUM>) have been substantially resolved, the ultra-deep reservoir strata (<NUM>,<NUM>-<NUM>,<NUM>) are generally exposed to more harsh reservoir conditions such as ultra-high temperature (≥<NUM>), high salinity (≥<NUM>×<NUM><NUM>mg/L), low permeability (≤ 50mD), the heterogeneous profile control of reservoir strata faces with increased difficulty, resulting in the fluid channeling after injecting with water or gas. Therefore, controlling heterogeneity of reservoir strata and achieving the balanced displacement are essential measures for increasing production of the ultra-deep reservoir, an efficient profile control system is the core. The existing profile control systems, such as the polymer gel system, the foam system, the polymeric microspheres and the inorganic precipitation system, have significant effects in the profile control of shallow to deep reservoir, but the application of aforementioned systems to the profile control of ultra-deep reservoir strata remains confront with numerous challenges, for instance, the polymer gel system is prone to suffer from dehydration and instability under the conditions of high temperature and high salinity, the foam system can hardly be injected and exhibits a short period of validity, the polymeric microspheres have limited resistance to high temperature and high salinity although the microspheres can be easily migrated to deep parts of the stratum; by contrast, the inorganic precipitation system is resistant to high temperature and high salinity, but the system has a short migration distance and is prone to cause plugging at the near-borehole area. Therefore, it is urgent to invent a heterogeneity control agent for ultra-deep reservoir having the desirable properties of "high temperature resistance, high salinity resistance, injectability, and long distance migration". In <CIT> a kind of simple function group polyethex amine modification graphene oxide and its applications in epoxy resin composite material is disclosed. Further, in <CIT> application of modified nano graphene oxide as a chemical agent for improving the recovery ratio of a low-permeability reservoir is disclosed.

It is an object of the present disclosure to overcome the problems in the prior art with respect to insufficient control on the heterogeneity of the high temperature and high salinity reservoir strata, for example, the existing profile control agents "have poor performances in high temperature resistance, high salinity resistance, migration distance and profile controllability", and provide salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system, preparation method thereof and application method thereof in profile control of ultra-deep reservoir, the modified graphite oxide nanoparticles have self-coalescence effect under the conditions of high temperature and high salinity, and are applicable in the high temperature and high salinity reservoir strata, thereby achieving the heterogeneity profile control of the high temperature and high salinity reservoir strata.

In order to achieve the above objects, a first aspect of the present disclosure provides a salinity-induced self- coalescence modified graphite oxide nanoparticles for ultra-deep reservoir comprising graphite oxide nanoparticles and a monofunctional polyether amine covalently grafted to the surface of the graphite oxide nanoparticles through amide bonds, the monofunctional polyether amine has a structural formula shown by Formula (I);
<CHM>.

A second aspect of the present disclosure provides a method of preparing the aforementioned modified graphite oxide nanoparticles including:.

In a third aspect, the present disclosure provides a salinity-induced self-coalescence modified graphite oxide nanoparticles for ultra-deep reservoir profile control system comprising <NUM>-1wt% of graphite oxide nanoparticles; the graphite oxide nanoparticles which comprises the modified graphite oxide nanoparticles according to the present disclosure.

In a fourth aspect, the present disclosure provides a method of using the salinity-induced self-coalescence modified graphite oxide nanoparticles for ultra-deep reservoir profile control system into ultra-deep reservoir stratum including:.

Due to the above-described technical scheme, the modified graphite oxide nanoparticles of the present disclosure and the polyether amine molecular chain segments which have been covalently grafted to the surface of the graphite oxide nanoparticles generate an steric hindrance effect, such that the modified graphite oxide nanoparticles have desirable dispersion stability in deionized water or fresh water as well as small nanometer scale particle size.

The profile control system constructed using the modified graphite oxide nanoparticles of the present disclosure exhibits excellent stability under the conditions of high temperature and low salinity, thus the modified graphite oxide nanoparticles can follow the profile control system and deeply access the strata; the modified graphite oxide nanoparticles in the profile control system are thermodynamically unstable under the environment of high temperature and high salinity, the thermal motion of the modified graphite oxide nanoparticles is accelerated under the environment of high temperatures and high salinity, increase the probability of collisions between the modified graphite oxide nanoparticles, further compress the diffusion electric double layer on the surface of the modified graphite oxide nanoparticles by using the ions (e.g., Na+, Ca<NUM>+, Mg<NUM>+) in salinity water of the strata, resulting in decreased electrostatic repulsive force and increased attractive forces between the modified graphite oxide nanoparticles, thereby causing the salinity-induced self-coalescence phenomenon, which increases the particle size from nanometer scale to micrometer scale, exhibits a large coalescence multiple (greater than <NUM> times) and a characteristic of high strength after coalescence.

When the profile control system of the present disclosure is used in the high temperature and high salinity reservoir (e.g., ultra-deep reservoir strata), it is capable of producing the effects of "high temperature resistance, high salinity resistance, injectability, long distance migration and profile controllability", and induces the modified graphite oxide nanoparticles profile control system to coalescence from the nanometer scale to micrometer scale by taking advantage of the high temperature and high salinity environment of the reservoir strata, can control heterogeneity of the high temperature and high salinity reservoir (e.g., ultra-deep reservoir strata), and impose an effective control on the water channeling /gas channeling passage or crack system, thereby improving heterogeneity of the ultra-deep reservoir strata and resulting in substantially enhanced oil and gas recovery.

The salinity-induced self-coalescence modified graphite oxide nanoparticles for ultra-deep reservoir profile control system constructed with the modified graphite oxide nanoparticles have many advantages, such as wide raw material source, simple preparation process, high yield, stable product properties, facilitating industrial production of the product in the present disclosure, and the profile control system requires a simple on-site formulation and injection process, and has a flexible operation arrangement, and facilitates implementation of the oil fields.

The ultra-deep reservoir strata refer to the reservoir strata having a burial depth larger than <NUM>,<NUM> meters (e.g., <NUM>,<NUM>-<NUM>,<NUM> meters).

The conditions of high temperature and high salinity refer to the conditions consisting of a temperature ≥ <NUM>, and a salinity ≥ <NUM>×<NUM><NUM> mg/L.

A first aspect of the present disclosure provides an ultra-deep reservoir salinity-induced self-coalescence modified graphite oxide nanoparticles comprising graphite oxide nanoparticles and a monofunctional polyether amine covalently grafted to the surface of the graphite oxide nanoparticles through amide bonds, the monofunctional polyether amine has a structural formula shown by Formula (I);
<CHM>.

According to a preferred embodiment of the present disclosure, R<NUM> may be one of methyl, ethyl, propyl and butyl, R<NUM> is preferably CH<NUM>.

According to a preferred embodiment of the present disclosure, R<NUM> may be at least one of hydrogen, methyl, ethyl, propyl and butyl, R<NUM> is preferably H and/or CH<NUM>.

According to a preferred embodiment of the present disclosure, n is <NUM>, <NUM>, <NUM> or <NUM>.

In the present disclosure, the modified graphite oxide nanoparticles may have a wide selectable range of average particle size. According to a preferred embodiment of the present disclosure, the modified graphite oxide nanoparticles have an average lamellar size of <NUM>-<NUM>, preferably <NUM>-<NUM>.

In the present disclosure, the modified graphite oxide nanoparticles may have a wide selectable range of thickness. According to a preferred embodiment of the present disclosure, the modified graphite oxide nanoparticles have an average lamellar thickness of <NUM>-<NUM>, preferably <NUM>-<NUM>.

The grafting ratio of the monofunctional polyether amine can be selected from a wide range in the present disclosure. According to a preferred embodiment of the present disclosure, the monofunctional polyether amine has a grafting ratio of <NUM>-40wt%, based on a total weight of the modified graphite oxide nanoparticles.

According to a preferred embodiment of the present disclosure, the modified graphite oxide nanoparticles have at least one structure shown in Formulae (II), (III), (IV) and (V);
<CHM>
<CHM>
<CHM>
<CHM>.

According to a preferred embodiment of the present disclosure, in Formulae (II), (III), (IV) and (V), R is each independently H and/or CH<NUM>; n is each independently <NUM>, <NUM>, <NUM> or <NUM>.

According to a preferred embodiment of the present disclosure, the modified graphite oxide nanoparticles have the structure shown by Formula (II).

In the present disclosure, the objects of the present disclosure can be achieved as long as the features of the modified graphite oxide nanoparticles have the characteristics of the present disclosure, and the method of preparing the modified graphite oxide nanoparticles is not particularly defined therein. In a second aspect, the present disclosure provides a method of preparing the aforementioned modified graphite oxide nanoparticles including:.

According to a preferred embodiment of the present disclosure, the method of preparing the aforementioned modified graphite oxide nanoparticles including:.

In accordance with a preferred embodiment of the present disclosure, the material I is <NUM>-ethyl-(<NUM>-dimethylaminopropyl) carbodiimide hydrochloride.

In accordance with a preferred embodiment of the present disclosure, the material II is N-hydroxysuccinimide.

According to a preferred embodiment of the present disclosure, the dosage ratio of the graphite oxide nanoparticles to the monofunctional polyether amine is (<NUM>-<NUM>): (<NUM>-<NUM>).

According to a preferred embodiment of the present disclosure, the dosage ratio of the graphite oxide nanoparticles to the material I is (<NUM>-<NUM>): (<NUM>-<NUM>).

According to a preferred embodiment of the present disclosure, the dosage ratio of the graphite oxide nanoparticles to the material II is (<NUM>-<NUM>): (<NUM>-<NUM>).

The reaction conditions in step (<NUM>) of the present disclosure may be selected from a wide range, and the reaction time may be adjusted appropriately according to the reaction temperature. According to a preferred embodiment of the present disclosure, the reaction conditions comprise: a reaction temperature of <NUM>-<NUM>, preferably <NUM>-<NUM>; and a reaction time of <NUM>-<NUM>, preferably <NUM>-<NUM>.

In step (<NUM>) of the present disclosure, the condensed reflux reaction is performed by adding the monofunctional polyether amine into the active graphite oxide nanoparticles dispersion liquid in step (<NUM>).

In the present disclosure, the process of dispersing graphite oxide nanoparticles in a solvent can be implemented by means of the conventional dispersion methods in the art, such as stirring, ultrasonic dispersion. According to a preferred embodiment of the present disclosure, ultrasonic dispersion is used, it is preferable that the ultrasonic power is within a range of <NUM>-390W, preferably within a range of <NUM>-350W; and the ultrasonic dispersion time is within a range of <NUM>-<NUM> minutes, preferably <NUM> minutes.

In the present disclosure, the dispersion of <NUM>-ethyl- (<NUM>-dimethylaminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide into the dispersion of graphite oxide nanoparticles can be achieved by means of the conventional dispersion methods in the art, such as stirring, ultrasonic dispersion.

The modes and conditions of filtering, washing and drying in the present disclosure are not particularly limited in the present disclosure, may be modes and conditions of filtering, washing and drying conventionally used in the art; for example, the filtering may be performed using a polytetrafluoroethylene membrane having a pore size of <NUM>-<NUM>, for instance, the filtering may be performed using a polytetrafluoroethylene membrane having a pore size of <NUM>; for example, a washing solvent may be any one selected from the group consisting of anhydrous methanol, anhydrous ethanol, or a combination thereof; the number of washing may be from <NUM> to <NUM> times, preferably from <NUM> to <NUM> times; and the drying mode may be any one of freeze drying or vacuum drying; the drying time may be <NUM>-<NUM>, preferably <NUM>-<NUM>.

The present disclosure does not impose particular requirements on the protective gas, for example, it may be one or more selected from the group consisting of nitrogen gas, helium gas and argon gas, preferably nitrogen gas.

The ratio of the graphite oxide nanoparticles to the solvent can be selected from a wide range of the present disclosure. In accordance with a preferred embodiment of the present disclosure, the ratio of the graphite oxide nanoparticles to the solvent is <NUM>: <NUM>-<NUM>,<NUM>.

According to a preferred embodiment of the present disclosure, the graphite oxide nanoparticles has an average lamellar size of <NUM>-<NUM>; preferably <NUM>-<NUM>.

According to a preferred embodiment of the present disclosure, the graphite oxide nanoparticles have an average lamellar thickness of <NUM>-<NUM>, preferably <NUM>-<NUM>.

In accordance with a preferred embodiment of the present disclosure, the monofunctional polyether amine has a number average molecular weight of <NUM>-<NUM>,<NUM>/mol.

The solvent is not specifically defined in the present disclosure. According to a preferred embodiment of the present disclosure, the solvent is at least one of water, methanol and ethanol.

A third aspect of the present disclosure provides a salinity-induced self-coalescence profile control system comprising <NUM>-1wt% of graphite oxide nanoparticles which comprises the modified graphite oxide nanoparticles according to the present disclosure. The profile control system constructed using the modified graphite oxide nanoparticles of the present disclosure have excellent stability under the conditions of high temperature and low salinity, thus the modified graphite oxide nanoparticles can follow the profile control system and deeply access the strata; the modified graphite oxide nanoparticles in the profile control system are thermodynamically unstable under the environment of high temperature and high salinity, the thermal motion of the modified graphite oxide nanoparticles is accelerated under the environment of high temperatures and high salinity, increase the probability of collisions between the modified graphite oxide nanoparticles, further compress the diffusion electric double layer on the surface of the modified graphite oxide nanoparticles by using the ions (e.g., Na+, Ca<NUM>+, Mg<NUM>+ and so on) in salinity water of the strata, resulting in decreased electrostatic repulsive force and increased attractive forces between the modified graphite oxide nanoparticles, and salinity-induced self-coalescence phenomenon, which increases the particle size from nanometer scale to micrometer scale, exhibits a large coalescence multiple (greater than <NUM> times) and a characteristic of high strength after coalescence.

According to a preferred embodiment of the present disclosure, the profile control system further comprises a dispersant, preferably in an amount of <NUM>-2wt%.

According to a preferred embodiment of the present disclosure, the profile control system further comprises water, preferably in an amount of <NUM>-<NUM>.

In the present disclosure, the water is at least one selected from the group consisting of deionized water, fresh water and tap water.

The present disclosure does not impose specific definition on the kinds of dispersant, the conventional dispersants in the art can be used in conjunction with the modified graphite oxide nanoparticles. According to a preferred embodiment of the present disclosure, the dispersant is at least one selected from the group consisting of sodium dodecylbenzene sulphonate, sodium lauryl sulphate and a substance having the structure shown by Formula (VI), preferably the substance having the structure shown by Formula (VI):
<CHM>
wherein n is an integer from <NUM> to <NUM>.

The method of preparing the profile control system is not particularly defined in the present disclosure, provided that the ingredients of the profile control system are blended and dispersed uniformly. According to a preferred embodiment of the present disclosure, the present disclosure provides a method of preparing the profile control system including:.

According to a preferred embodiment of the present disclosure, the dispersant in step (i) is used in a mass fraction of <NUM>-<NUM>%, preferably <NUM>-<NUM>%; and the stirring dispersion time is <NUM>-<NUM> minutes, preferably <NUM> minutes.

According to a preferred embodiment of the present disclosure, the modified graphite oxide nanoparticles in step (ii) is used in a mass fraction of <NUM>-<NUM>%, preferably <NUM>-<NUM>%; the ultrasonic power is within a range of <NUM>-390W, preferably 325W; the ultrasonic dispersion time is within a range of <NUM>-<NUM> minutes, preferably <NUM> minutes; the standing time is <NUM>-<NUM> hours, preferably <NUM>-<NUM> hours.

In a fourth aspect, the present disclosure provides a method of using the ultra-deep reservoir salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system including:.

In the present disclosure, the low salinity water refers to oil field reinjection water with a total salinity less than <NUM>,<NUM>/L.

The present disclosure will be described below in detail with reference to examples.

In the following examples, the graphite oxide nanoparticles, the monofunctional polyether amine (with a number average molecular weight of <NUM>/mol, <NUM>,<NUM>/mol, <NUM>,<NUM>/mol, <NUM>,<NUM>/mol), <NUM>-ethyl- (<NUM>-dimethylaminopropyl) carbodiimide hydrochloride (EDC·HCl), the N-hydroxysuccinimide (NHS) and the dispersant sodium methylene bisnaphthalene sulfonate (NNO) are commercially available.

The modified graphite oxide nanoparticles had an average lamellar size of <NUM> and an average lamellar size of <NUM>, and had a structure shown by Formula (II), wherein n=<NUM> and R was methyl; the monofunctional polyether amine had a grafting ratio of 38wt%, based on a total weight of the modified graphite oxide nanoparticles.

The infrared spectrum graph of the modified graphite oxide nanoparticles was illustrated in <FIG>, which demonstrated that the monofunctional polyether amine was successfully grated on the graphite oxide nanoparticles.

The macro-scopic morphology of the modified graphite oxide nanoparticles was illustrated in <FIG>, which showed a black powdery solid.

The modified graphite oxide nanoparticles had an average lamellar size of <NUM> and an average lamellar size of <NUM>, and had a structure shown by Formula (II), wherein n=<NUM> and R was H; the monofunctional polyether amine had a grafting ratio of 31wt%, based on a total weight of the modified graphite oxide nanoparticles.

The modified graphite oxide nanoparticles had an average lamellar size of <NUM> and an average lamellar size of <NUM>, and had a structure shown by Formula (II), wherein n=<NUM> and R was methyl; the monofunctional polyether amine had a grafting ratio of 33wt%, based on a total weight of the modified graphite oxide nanoparticles.

The modified graphite oxide nanoparticles had an average lamellar size of <NUM> and an average lamellar size of <NUM>, and had a structure shown by Formula (II), wherein n=<NUM> and R was H; the monofunctional polyether amine had a grafting ratio of 29wt%, based on a total weight of the modified graphite oxide nanoparticles.

The ultra-deep reservoir salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system was added with salt (with the salinity shown in Table <NUM>), and uniformly stirred, and sealed in an ampoule and subjected to continuous oscillation under a certain temperature, and particle size variation of the modified graphite oxide nanoparticles was shown in Table <NUM>.

According to the results shown in Table <NUM>, the profile control system of the present disclosure exhibited excellent stability under the conditions of high temperature and low salinity, thus the profile control system was able to migrate to deep parts of the stratum; the particle size of the modified graphite oxide nanoparticles was shifted from nanometer scale to the micrometer scale under an induction of the environment of high temperature and high salinity, and the modified graphite oxide nanoparticles profile control system had a salinity-induced self-coalescence effect. Therefore, the profile control system of the present disclosure was induced by the environment of high temperature and high salinity during the percolation process, and gradually implemented the self-coalescence phenomenon, such that the preferential percolation channels were effectively controlled.

The macro-scopic morphology of the profile control system before and after aging process under the simulated reservoir conditions was shown in <FIG>, which illustrated that the profile control system experienced an obvious salinity-induced self-coalescence phenomenon.

The modified graphite oxide nanoparticles were prepared according to the method of Example <NUM>, except that the modified graphite oxide nanoparticles in use were the modified graphite oxide nanoparticles prepared in Example <NUM>, the remaining conditions were identical with those of Example <NUM>. The test conditions were same as those in Example <NUM>, the test results were illustrated in Table <NUM>.

According to the results shown in Table <NUM>, the profile control system of the present disclosure exhibited excellent stability under the conditions of high temperature and low salinity, thus the profile control system was able to migrate to deep parts of the stratum; the particle size of the modified graphite oxide nanoparticles was shifted from nanometer scale to micrometer scale under an induction of the environment of high temperature and high salinity, and the modified graphite oxide nanoparticles profile control system had a salinity-induced self-coalescence effect. Therefore, the profile control system of the present disclosure was induced by the environment of high temperature and high salinity during the percolation process, and gradually implemented the self-coalescence phenomenon, such that the preferential percolation channels were effectively controlled.

The modified graphite oxide nanoparticles were prepared according to the method of Example <NUM>, except that the dispersant was <NUM> of sodium dodecylbenzene sulfonate, the remaining conditions were identical with those of Example <NUM>. The test results were illustrated in Table <NUM>.

According to the results shown in Table <NUM>, as compared with Example <NUM>, when the dispersant of the profile control system of the present disclosure was replaced with sodium dodecylbenzene sulfonate, the particle size of the modified graphite oxide nanoparticles remained relatively stable under the conditions of high temperature and low salinity, and the phenomenon of increased particle size was not significant; however, under the induction of high temperature and high salinity environment, the speed of shifting the particle size of the modified graphite oxide nanoparticles from the nanometer scale to the micrometer scale was faster, which was not beneficial to the migration of the profile control system to the deeper part of the stratum.

The application method of the profile control system was described by taking the dimensions of rock core as an example and the plugging ratio as an evaluation index. It was common practice in the field to inject a profile control system by using a rock core having a relatively high permeability; when the plugging ratio was higher than <NUM>%, it was deemed that the rock core realized an effective control, such that the permeability of aforementioned rock core was reduced, the reservoir stratum tended to be homogenized; the higher was the plugging ratio, the better was the homogenization effect of the reservoir stratum.

The specification of a rock core was as follows: the length was <NUM>, the diameter was <NUM>, the pore volume was <NUM>, and the permeability was 20mD; the temperature was <NUM>, the salinity of simulated water was <NUM>×<NUM><NUM>mg/L, the salinity ingredients were composed of NaCl in an amount of <NUM>×<NUM><NUM>mg/L, CaCl<NUM> in an amount of <NUM>×<NUM><NUM>mg/L and MgCl<NUM> in an amount of <NUM>×<NUM><NUM>mg/L, and the specific steps were as follows:.

After the four steps were finished, the water flooding was performed until the pressure was stable, the pressure change of each stage was recorded, the calculated plugging ratio was <NUM>%. It demonstrated that the ultra-deep reservoir salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system of the Example can effectively control the preferential percolation channels.

After the four steps were finished, the water flooding was performed until the pressure was stable, the pressure change of each stage was recorded, the calculated plugging ratio was <NUM>%. It demonstrated that the salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system of the Example can effectively control the preferential percolation channels.

After the four steps were finished, the water flooding was performed until the pressure was stable, the pressure change of each stage was recorded, the calculated plugging ratio was <NUM>%. It demonstrated that the salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system of the Example can effectively regulate and control the preferential percolation channels.

The application method of a profile control system was performed according to the method in Example <NUM>, except that the profile control system prepared in Example <NUM> was injected in the step (b), the remaining conditions were identical with those of Example <NUM>. After the four steps were finished, the water flooding was performed until the pressure was stable, the pressure change of each stage was recorded, the calculated plugging ratio was <NUM>%. It demonstrated that the ultra-deep reservoir salinity-induced self-coalescence modified graphite oxide nanoparticles profile control system of the Example can effectively control the preferential percolation channels.

The application method of a profile control system was performed according to the method in Example <NUM>, except that in step (ii), <NUM> of the modified graphite oxide nanoparticles (having an average particle diameter of <NUM> and a thickness of <NUM>) was added into the dispersion liquid in step (i) under a temperature condition of <NUM>, and subjected to an ultrasonic dispersion for <NUM> minutes to obtain the graphite oxide nanoparticles profile control system. The test conditions were the same as in those in Example <NUM>, and the test results were shown in Table <NUM>.

According to the results shown in Table <NUM>, the profile control system prepared from graphite oxide nanoparticles in use may perform self-coalescence under the conditions of high temperature and low salinity, and cannot migrate to the deep part of the stratum, and the effects of "high temperature resistance, high salinity resistance, injectability, long distance migration and profile controllability" cannot be achieved.

The application method of a profile control system was performed according to the method in Example <NUM>, except that in step (b) main slug: the salinity-induced self-coalescence profile control system prepared in Comparative Example <NUM> was injected, the injection amount was <NUM> times of the stratum pore volume;
After the four steps were finished, the water flooding was performed until the pressure was stable, the pressure change of each stage was recorded, the calculated plugging ratio was <NUM>%.

Claim 1:
A salinity-induced self-coalescence modified graphite oxide nanoparticles particles for ultra-deep reservoir comprising a graphite oxide nanoparticles and a monofunctional polyether amine covalently grafted to the surface of the graphite oxide nanoparticles through amide bonds, the monofunctional polyether amine has a structural formula shown by Formula (I);
<CHM>
wherein R<NUM> is one selected from C<NUM>-C<NUM> alkyl; R<NUM> is H or one of the C<NUM>-C<NUM> alkyl;
n is an integer from <NUM> to <NUM>;
wherein the monofunctional polyether amine has a grafting ratio of <NUM>-40wt%, based on a total weight of the modified graphite oxide nanoparticles;
wherein the modified graphite oxide nanoparticles have an average lamellar size of <NUM>-<NUM>;
the modified graphite oxide nanoparticles have an average lamellar thickness of <NUM>-<NUM>.