Patent Description:
At present drinks, food, or bottled products are available in different types of containers, such as glass, plastic or PET bottles, plasticized recipients, as well as metal cans, etc., whereby during processing and bottling it is necessary to transport the empty and/or full containers from one place to another, during the different stages of the industrial process to which they are submitted, using conveyor chains generally made of stainless steel or plastic, which provokes a constant friction between the conveyor chains and the containers, between the components of the conveyor chains, as well as the mutual collision among the containers during transportation.

A result of uncontrolled friction, or of an insufficient lubrication of the settings of the conveyor chains, may be a series of unfavorable situations, such as the containers tipping over or obstructing the passage (even though the conveyor chains continue operation), or otherwise, provoke more noise and discontinuity in the feeding or supply of containers to the following stages in the process, for example in the filling or labeling stages. Therefore, these situations may lead to a low performance in the stages of the process, provoking an accelerated wear of the conveyor chains and force the capacity of the motors, all the former because of an inappropriate lubrication.

Conventional solutions to the need for controlling friction in such situations includes the use of a concentrated lubricant (often soap-based or fatty amine) diluted with water to form an aqueous dilute lubricant solution (i.e., dilution ratios of <NUM>: <NUM> to <NUM>:<NUM>), and copious amounts of aqueous dilute lubricant solutions are typically applied to the conveyor or containers using spray or pumping equipment. These lubricant solutions permit highspeed operation of the conveyor and limit marring of the containers or labels, but also have some disadvantages. First, dilute aqueous lubricants typically require use of large amounts of water on the conveying line, which must then be disposed of or recycled, and which causes an unduly wet environment near the conveyor line. Second, some aqueous lubricants can promote the growth of microbes. Third, by requiring dilution of the concentrated lubricant dilution errors can occur, leading to variations and errors in concentration of the aqueous dilute lubricant solution. Finally, by requiring water from the plant, variations in the water can have negative side effects on the dilute lubrication solution.

When an aqueous dilute lubricant solution is used, it is typically applied at least half of the time the conveyor is running, and usually it is applied continuously. By running the aqueous dilute lubricant solution continuously, more lubricant is used than is necessary, and the lubricant concentrate drums have to be switched out more often than necessary.

"Dry lubes" have been described as solutions to these disadvantages of dilute aqueous lubricants and have been referred to a lubricant composition with less than <NUM>% water that was applied to a container or conveyor without dilution. However, this application typically required special dispensing equipment and nozzles and energized nozzles in particular. Energized nozzles refer to nozzles where the lubricant stream is broken into a spray of fine droplets by the use of energy, which may include high pressures, compressed air, or sonication to deliver the lubricant. Silicone materials have been the most popular "dry lube. " However, silicone is primarily effective at lubricating plastics such as PET bottles, and has been observed to be less effective at lubricating on glass or metal containers, particularly on a metal surface. If a plant is running more than one type of container on a line, the conveyor lubricant will have to be switched before the new type of container can be run. Alternatively, if a plant is running different types of containers on different lines, the plant will have to stock more than one type of conveyor lubricant. Both scenarios are time consuming and inefficient for the plant.

<CIT> discloses a lubricant for conveyor chains, the lubricant consists of a mixture of a quantity of fatty acid, a quantity of amine, a quantity of polyglycol, and a quantity of hydrocarbon. The lubricant uses a direct application, without dilution, and forms a layer or film of lubricant on the surface of the conveyor chain so that the application is discontinued, in long intervals between the applications.

It is against this background that the present invention has been made.

An object of the invention is to provide a dry lubricant suitable for various materials as well as suitable for maintaining lubrication in dirty zones of an application.

A further object of the invention is to provide a "universal" lubricant that may be used with a variety of container and conveyor materials.

Other objects, advantages and features of the present invention will become apparent from the following specification taken in conjunction with the accompanying drawings.

An advantage of the invention is a total dry or semi-dry application of lubricant maintaining a coefficient of friction below about <NUM> while being suitable on various surfaces of containers along with metal (stainless steel) and plastic conveyors. It is a further advantage of the present invention that lubrication is provided in dirty zones of application, such as where spillage has occurred and before washing. It is a still further advantage of the present invention that water consumption is reduced or eliminated.

In an embodiment, the present invention provides a dry lubricant composition according to claims <NUM> to <NUM>.

In an embodiment, the present invention provides a method of lubricating a surface according to claims <NUM> to <NUM>.

Various embodiments of the present invention will be described in detail with reference to the drawings, wherein like reference numerals represent like parts throughout the several views. Figures represented herein are presented for exemplary illustration of the invention.

As used in this specification and the appended claims, the singular forms "a," "an" and "the" can include plural referents unless the content clearly indicates otherwise. Further, all units, prefixes, and symbols may be denoted in its SI accepted form.

So that the present invention may be more readily understood, certain terms are first defined. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which embodiments of the invention pertain. In describing and claiming the embodiments of the present invention, the following terminology will be used in accordance with the definitions set out below.

The term "about," as used herein, refers to variation in the numerical quantity that can occur, for example, through typical measuring and liquid handling procedures used for making concentrates or use solutions in the real world; through inadvertent error in these procedures; through differences in the manufacture, source, or purity of the ingredients used to make the compositions or carry out the methods; and the like.

The term "hard surface" refers to a solid, substantially non-flexible surface such as a counter top, tile, floor, wall, panel, window, plumbing fixture, kitchen and bathroom furniture, appliance, engine, circuit board, and dish. Hard surfaces may include for example, health care surfaces and food processing surfaces.

As used herein, the term "polymer" generally includes, but is not limited to, homopolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, and higher "x"mers, further including their derivatives, combinations, and blends thereof. Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible isomeric configurations of the molecule, including, but are not limited to isotactic, syndiotactic and random symmetries, and combinations thereof. Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible geometrical configurations of the molecule.

For the purpose of this patent application, successful microbial reduction is achieved when the microbial populations are reduced by at least about <NUM>%, or by significantly more than is achieved by a wash with water. Larger reductions in microbial population provide greater levels of protection. Differentiation of antimicrobial "-cidal" or "-static" activity, the definitions which describe the degree of efficacy, and the official laboratory protocols for measuring this efficacy are considerations for understanding the relevance of antimicrobial agents and compositions. Antimicrobial compositions can affect two kinds of microbial cell damage. The first is a lethal, irreversible action resulting in complete microbial cell destruction or incapacitation. The second type of cell damage is reversible, such that if the organism is rendered free of the agent, it can again multiply. The former is termed microbiocidal and the later, microbistatic. A sanitizer and a disinfectant are, by definition, agents which provide antimicrobial or microbiocidal activity. In contrast, a preservative is generally described as an inhibitor or microbistatic composition.

As used herein, the term "substantially free" refers to compositions completely lacking the component or having such a small amount of the component that the component does not affect the performance of the composition. The component may be present as an impurity or as a contaminant and shall be less than <NUM> wt-%. In another embodiment, the amount of the component is less than <NUM> wt-% and in yet another embodiment, the amount of component is less than <NUM> wt-%. The dry lubricant is substantially free of water.

As used herein, the term "waters" includes food process or transport waters. Food process or transport waters include produce transport waters (e.g., as found in flumes, pipe transports, cutters, slicers, blanchers, retort systems, washers, and the like), belt sprays for food transport lines, boot and hand-wash dip-pans, third-sink rinse waters, and the like. Waters also include domestic and recreational waters such as pools, spas, recreational flumes and water slides, fountains, and the like.

The terms "water soluble" and "water dispersible" as used herein, means that the polymer is soluble or dispersible in water in the inventive compositions. In general, the polymer should be soluble or dispersible at <NUM> at a concentration of <NUM>% by weight of the water solution and/or water carrier, preferably at <NUM>%, more preferably at <NUM>% and most preferably at <NUM>%.

The methods, and compositions of the present invention may comprise, consist essentially of, or consist of the components and ingredients of the present invention as well as other ingredients described herein. As used herein, "consisting essentially of" means that the methods, and compositions may include additional steps, components or ingredients, but only if the additional steps, components or ingredients do not materially alter the basic and novel characteristics of the claimed methods, systems, apparatuses, and compositions.

Exemplary ranges of the lubricant compositions according to the invention are shown in Table <NUM> in weight percentage of the concentrate dry lubricant compositions.

The dry lubricant compositions have a pH from about <NUM> to <NUM>, or preferably from about <NUM> to <NUM>.

The dry lubricant compositions have a viscosity (sp3 <NUM> rmp (cps)) from <NUM> to about <NUM>, preferably from about <NUM> to about <NUM>, preferably from about <NUM> to about <NUM>.

The compositions form oil in water dispersions when exposed to water or another solvent as a result of the lipophilic mineral oil or component and the emulsifiers employed, making the compositions "water-miscible", that is, the compositions should they be combined with water would be sufficiently water-soluble or water-dispersible so that a stable solution, emulsion or suspension is formed. The desired use level will vary according to the particular conveyor or container application, and according to the type of mineral oil, fatty acids, and other compounds employed. This is a beneficial property as the dry lubricant compositions can be easily removed from the conveyor surface by cleaning with a water-based cleaning composition, as opposed to traditional mineral oil compositions which are not readily removed using water-based cleaning compositions. In an aspect, it is sufficiently soluble or dispersible in water so that the coating can be removed from the container or conveyor using conventional aqueous cleaners, without the need for high pressure, mechanical abrasion or the use of aggressive cleaning chemicals. However, the dry lubricant excluding water from the formulations is not so water-soluble that it runs off the conveyor when it encounters water or spilled beverage normally present during the bottling process.

The dry lubricant compositions are provided as concentrate compositions or may be diluted to form ready to use compositions for semi-dry applications of use. In general, a concentrate refers to a composition that is not (or not yet diluted) with water or other solvent to provide a use solution that contacts an object to provide the desired lubrication, cleaning, or the like. The dry lubricant composition that contacts the articles or surfaces to be lubricated can be referred to as a concentrate or a use composition (or use solution) dependent upon the formulation employed in methods according to the invention. It should be understood that the concentration of the active components in the dry lubricant composition will vary depending on whether the composition is provided as a concentrate or as a diluted composition, such as for a semi-dry application of use.

In a preferred aspect, the dry lubricant is applied for use in an undiluted formulation. The dry lubricant composition is substantially-free of water. Preferably, the dry lubricant composition is has less than <NUM> wt-% of water, or less than <NUM> wt-% of water. In another embodiment, the amount of water is less than <NUM> wt-% and in yet another embodiment, the amount of water is less than <NUM> wt-%. The amount of water referred to herein includes any added water to the dry lubricant formulation, and preferably any water of addition from the components of the formulation as well.

A desirable dilution of the dry lubricant according to the invention to provide a semi-dry application provides an oil in water dispersion, the concentration of which may vary from about <NUM>% to about <NUM>%, preferably from about <NUM>% to about <NUM>%, or more preferably from about <NUM>% to about <NUM>%, and more preferably about <NUM>%. In an aspect of the invention, water is employed as a solvent to form a ready-to-use formulation for use in a semi-dry application and one skilled in the art will ascertain that performance considerations of a particular application of use for the lubricator will impact the concentration. Exemplary dilution ranges for diluted applications of the dry lubricant are from about <NUM>:<NUM> to <NUM>:<NUM>, beneficially allowing an extremely high dilution (which is distinct from conventional lubricants, such as disclosed in <CIT>). For such applications of use employing a diluted lubricant composition (or a ready-to-use formulation) a flow meter is preferably installed to quantify or dose water of dilution.

Beneficially, the dry lubricant compositions exhibit a decrease in COF after the composition is applied to the conveyor (or containers) and remains dries on the conveyor (or containers). In an embodiment, the present compositions maintain effective lubrication after the composition is applied to the conveyor and remains dry on the conveyor. The invention provides a lubricant coating that reduces the coefficient of friction of coated conveyor parts and containers and thereby facilitates movement of containers along a conveyor line. In an embodiment the lubricant maintains a coefficient of friction below about <NUM>, below about <NUM>, below about <NUM>, below about <NUM>, and preferably below about <NUM>.

As a further benefit, the dry lubricant compositions are compatible with non-refillable PET bottles and/or barrier bottles, such as those used with carbonated soft drinks as determined using a PET Stress Crack Test. In a further embodiment, the dry lubricant compositions are compatible with refillable PET bottles useful for carbonated soft drinks as determined using a PET Stress Crack Test for refillable bottles. For example, the dry lubricant compositions result in a grade in such a test of A or B. In an example, the present composition can result in a grade in such a test of A.

The lubricant compositions include a dissolvent that can be one or more mineral oils or hydrocarbons. In an alternative, the dissolvent can be a mineral oil or hydrocarbon as well an aliphatic such as benzene, or a mixture of these. Saturated aliphatic hydrocarbon can be linear or ramified, there may be, for example, alkanes of the general formula CnH2n+<NUM> such as heptane, octane, nonane, decanes, pentadecanes, alkenes of the general formula CnH2n such as ethane, propene, butane, pentene, and alkynes of the general formula CnH2n-<NUM> such as ethyne, propine, butane, pentene.

In an aspect, preferred aliphatic hydrocarbons include mineral oils of high purity, such as for example white mineral oils. In an aspect, preferred benzene hydrocarbons include for example, those of the general formula CnH2n-<NUM> such as benzene, toluene, xylenes, and isomers.

The compositions include from about <NUM> wt-% - <NUM> wt-% mineral oil, and more preferably from about <NUM> wt-% - <NUM> wt-% mineral oil.

Beneficially, the mineral oil or hydrocarbon base ingredient or dissolvent of the dry lubricant compositions replaces the need for water and/or polylakylglycol base components for the lubricant compositions as are used in many lubricant compositions. See for example <CIT> employing a hydrophilic material (silicon emulsion and glycerol) material up to <NUM> wt-% of the lubricant, <CIT> employing a polylalkylglycol material up to <NUM> wt-% of the lubricant, and <CIT> employing a polylalkylene-glycol material up to <NUM> wt-% of the lubricant. Beneficially, the replacement of the hydrophilic materials with the mineral oil or hydrocarbon base ingredient provides improved lubrication, including in areas with rinsing and product spillage.

The lubricant compositions include a fatty acid component. The fatty acid is one or more fatty acids to increase the lubricity of the lubricant and beneficially enables the compositions to be used in containers of varied materials such as metal, glass, plasticized bottles, etc. The fatty acid consists of an alkyd chain with a terminal carboxylic group, being the simplest configuration the completely saturated lineal chain. Fatty acids are classified in fatty acids of short, medium, and long chains, and through their saturation grade in saturated and unsaturated, the latter divided in turn in mono-unsaturated fatty acids and polyunsaturated acids.

In an aspect, the fatty acids have a lineal chain of <NUM> to <NUM> carbon atoms, whether saturated, unsaturated, or substituted. Exemplary saturated fatty acids include for example, the caprylic acid of <NUM> carbon atoms, the capric acid of <NUM> carbon atoms, the undecylic acid of <NUM> carbon atoms, the lauric acid of <NUM> carbon atoms, the tridecyl acid of <NUM> carbon atoms, the myristic acid of <NUM> carbon atoms, the palmitic acid of <NUM> carbon atoms, the stearic acid of <NUM> carbon atoms; among the mono-unsaturated fatty acids there may, for example, the lauroleic acid of <NUM> carbon atoms, the myristoleic acid of <NUM> carbon atoms, the palmitoleic acid of <NUM> carbon atoms, and preferably the oleic acid of <NUM> carbon atoms; among the polyunsaturated fatty acids there may be, for example, the linoleic acid (de-unsaturated) of <NUM> carbon atoms and the linolenic acid (tri-unsaturated) of <NUM> carbon atoms, and among the substituted fatty acids there may be, for example, the ricinoleic acid of <NUM> carbon atoms substituted by hydroxide.

In an aspect, mixed fatty acids, such as the derivatives from greases and oils may be used in the lubricant composition of this invention, as for example, the fatty acid from coconut oil, or the fatty acid from liquid resin.

In an aspect, the compositions include from about <NUM> wt-% - <NUM> wt-% fatty acid, from about <NUM> wt-% - <NUM> wt-% fatty acid, from about <NUM> wt-% - <NUM> wt-% fatty acid, preferably from about <NUM> wt-% - <NUM> wt-% fatty acid, and more preferably from about <NUM> wt-% - <NUM> wt-% fatty acid.

The lubricant compositions include a non-ionic emulsifier with lipophylic characteristics. The emulsions of water in oil with a balanced lipophylic and hydrophilic performance are formulated through use of the non-ionic emulsifier, namely a sorbitan ester. The emulsifier type performs in this case an important role in stabilizing the emulsion and is a preferred election in the group comprising the systems constituted by sorbitan esters and ethoxylated sorbitan esters.

In an aspect, sorbitan esters include for example, sorbitan monooleate, sorbitan monolaurate, sorbitan monoestearate, sorbitan triestearate, polyoxyethylenated sorbitan trioleate with <NUM> to <NUM> ethylene oxide mols, ethoxylated sorbitan monoolaurate of <NUM> to <NUM> mols of ethylene oxide, polyethyleneglycol monooleate with a molecular weight comprised between <NUM> and <NUM>, and the ethoxylated nonilphenol of <NUM> to <NUM> mols of ethylene oxide.

Exemplary sorbitan esters include for example, the TWEEN™ series <NUM>, <NUM>, <NUM>, <NUM> and <NUM> polyoxyethylene sorbitan monooleates and SPAN™ series <NUM>, <NUM>, <NUM> and <NUM> of sorbitan esters.

The compositions include from about <NUM> wt-% - <NUM> wt-% sorbitan esters, from about <NUM> wt-% - <NUM> wt-% sorbitan esters, from about <NUM> wt-% - <NUM> wt-% sorbitan esters, from about <NUM> wt-% - <NUM> wt-% sorbitan esters, preferably from about <NUM> wt-% - <NUM> wt-% sorbitan esters.

The lubricant compositions includes a water-miscible lubricant that is a hydroxy-containing compounds such as polyols (e.g., glycerol and propylene glycol); polyalkylene glycols (e.g., polyethylene and methoxypolyethylene glycols); and/or linear copolymers of ethylene and propylene oxides. Preferably, the hydroxy-containing compounds are a polymer or copolymers of poylglycols. In an aspect, the copolymers are a block of polyglycol, particularly polyalkylene-glycol or any other polyalkylene-glycol oxide of a high molecular weight, soluble in water. The polyalkylene-glycol has the following general structure:
<CHM>
Wherein Ri is a hydrogen or alkyl of C<NUM> to C<NUM>; R<NUM> is a hydrogen, methyl, or their mixtures; and n is a whole number.

In an aspect when R<NUM> is hydrogen, these materials are polymers of ethylene oxide that are also known as polyethyleneglycols. When R<NUM> is methyl, these materials are polymers of propylene oxide that are also known as polypropylene glycols. When R<NUM> is methyl, there are also various isomers included, of the resulting polymer position that may exist. The polyalkylene-glycols, polyethyleneglycols, polypropylene glycols, and combinations thereof are preferred for their use in the lubricant of this invention. In an aspect, polyethyleneglycols are particularly preferred polyl glycols for the lubricant compositions.

The compositions include from about <NUM> wt-% - <NUM> wt-% polyl glycols, from about <NUM> wt-% - <NUM> wt-% polyl glycols, from about <NUM> wt-% - <NUM> wt-% polyl glycols, from about <NUM> wt-% - <NUM> wt-% polyl glycols, preferably from about <NUM> wt-% - <NUM> wt-% polyl glycols.

The compositions of the present invention include a nonionic surfactant suitable for aiding in emulsification of the lubricant compositions. The compositions include from about <NUM> wt-% - <NUM> wt-% nonionic surfactant, from about <NUM> wt-% - <NUM> wt-% nonionic surfactant, from about <NUM> wt-% - <NUM> wt-% nonionic surfactant, and preferably from about <NUM> wt-% - <NUM> wt-% nonionic surfactant.

Useful nonionic surfactants are generally characterized by the presence of an organic hydrophobic group and an organic hydrophilic group and are typically produced by the condensation of an organic aliphatic, alkyl aromatic or polyoxyalkylene hydrophobic compound with a hydrophilic alkaline oxide moiety which in common practice is ethylene oxide or a polyhydration product thereof, polyethylene glycol. Practically any hydrophobic compound having a hydroxyl, carboxyl, amino, or amido group with a reactive hydrogen atom can be condensed with ethylene oxide, or its polyhydration adducts, or its mixtures with alkoxylenes such as propylene oxide to form a nonionic surface-active agent. The length of the hydrophilic polyoxyalkylene moiety which is condensed with any particular hydrophobic compound can be readily adjusted to yield a water dispersible or water soluble compound having the desired degree of balance between hydrophilic and hydrophobic properties. Useful nonionic surfactants include:.

In addition to ethoxylated carboxylic acids, commonly called polyethylene glycol esters, other alkanoic acid esters formed by reaction with glycerides, glycerin, and polyhydric (saccharide or sorbitan/sorbitol) alcohols have application in this invention for specialized embodiments, particularly indirect food additive applications. All of these ester moieties have one or more reactive hydrogen sites on their molecule which can undergo further acylation or ethylene oxide (alkoxide) addition to control the hydrophilicity of these substances. Care must be exercised when adding these fatty ester or acylated carbohydrates to compositions of the present invention containing amylase and/or lipase enzymes because of potential incompatibility.

Examples of nonionic low foaming surfactants include:.

Additional examples of effective low foaming nonionics include:
<NUM>. The alkylphenoxypolyethoxyalkanols of <CIT>. and represented by the formula
<CHM>
in which R is an alkyl group of <NUM> to <NUM> carbon atoms, A is an alkylene chain of <NUM> to <NUM> carbon atoms, n is an integer of <NUM> to <NUM>, and m is an integer of <NUM> to <NUM>.

The polyalkylene glycol condensates of <CIT> having alternating hydrophilic oxyethylene chains and hydrophobic oxypropylene chains where the weight of the terminal hydrophobic chains, the weight of the middle hydrophobic unit and the weight of the linking hydrophilic units each represent about one-third of the condensate.

The defoaming nonionic surfactants disclosed in <CIT> having the general formula Z[(OR)nOH]z wherein Z is alkoxylatable material, R is a radical derived from an alkylene oxide which can be ethylene and propylene and n is an integer from, for example, <NUM> to <NUM>,<NUM> or more and z is an integer determined by the number of reactive oxyalkylatable groups.

The conjugated polyoxyalkylene compounds described in <CIT> corresponding to the formula Y(C<NUM>H<NUM>O)n (C<NUM>H<NUM>O)mH wherein Y is the residue of organic compound having from about <NUM> to <NUM> carbon atoms and one reactive hydrogen atom, n has an average value of at least about <NUM>, as determined by hydroxyl number and m has a value such that the oxyethylene portion constitutes about <NUM>% to about <NUM>% by weight of the molecule.

The conjugated polyoxyalkylene compounds described in <CIT> having the formula Y[(C<NUM>H<NUM>On (C<NUM>H<NUM>O)mH]x wherein Y is the residue of an organic compound having from about <NUM> to <NUM> carbon atoms and containing x reactive hydrogen atoms in which x has a value of at least about <NUM>, n has a value such that the molecular weight of the polyoxypropylene hydrophobic base is at least about <NUM> and m has value such that the oxyethylene content of the molecule is from about <NUM>% to about <NUM>% by weight. Compounds falling within the scope of the definition for Y include, for example, propylene glycol, glycerine, pentaerythritol, trimethylolpropane, ethylenediamine and the like. The oxypropylene chains optionally, but advantageously, contain small amounts of ethylene oxide and the oxyethylene chains also optionally, but advantageously, contain small amounts of propylene oxide.

Additional conjugated polyoxyalkylene surface-active agents which are advantageously used in the compositions of this invention correspond to the formula: P[(C<NUM>H<NUM>O)n (C<NUM>H<NUM>O)mH]x wherein P is the residue of an organic compound having from about <NUM> to <NUM> carbon atoms and containing x reactive hydrogen atoms in which x has a value of <NUM> or <NUM>, n has a value such that the molecular weight of the polyoxyethylene portion is at least about <NUM> and m has a value such that the oxypropylene content of the molecule is from about <NUM>% to about <NUM>% by weight. In either case the oxypropylene chains may contain optionally, but advantageously, small amounts of ethylene oxide and the oxyethylene chains may contain also optionally, but advantageously, small amounts of propylene oxide.

Polyhydroxy fatty acid amide surfactants suitable for use in the present compositions include those having the structural formula R<NUM>CONR1Z in which: R1 is H, C<NUM>-C<NUM> hydrocarbyl, <NUM>-hydroxy ethyl, <NUM>-hydroxy propyl, ethoxy, propoxy group, or a mixture thereof; R<NUM> is a C<NUM>-C<NUM> hydrocarbyl, which can be straight-chain; and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least <NUM> hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z can be derived from a reducing sugar in a reductive amination reaction; such as a glycityl moiety.

The alkyl ethoxylate condensation products of aliphatic alcohols with from about <NUM> to about <NUM> moles of ethylene oxide are suitable for use in the present compositions. The alkyl chain of the aliphatic alcohol can either be straight or branched, primary or secondary, and generally contains from <NUM> to <NUM> carbon atoms.

The ethoxylated C<NUM>-C<NUM> fatty alcohols and C<NUM>-C<NUM> mixed ethoxylated and propoxylated fatty alcohols are suitable surfactants for use in the present compositions, particularly those that are water soluble. Suitable ethoxylated fatty alcohols include the C<NUM>-C<NUM> ethoxylated fatty alcohols with a degree of ethoxylation of from <NUM> to <NUM>.

Suitable nonionic alkylpolysaccharide surfactants, particularly for use in the present compositions include those disclosed in <CIT>. These surfactants include a hydrophobic group containing from about <NUM> to about <NUM> carbon atoms and a polysaccharide, e.g., a polyglycoside, hydrophilic group containing from about <NUM> to about <NUM> saccharide units. Any reducing saccharide containing <NUM> or <NUM> carbon atoms can be used, e.g., glucose, galactose and galactosyl moieties can be substituted for the glucosyl moieties. (Optionally the hydrophobic group is attached at the <NUM>-, <NUM>-, <NUM>-, etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside. ) The intersaccharide bonds can be, e.g., between the one position of the additional saccharide units and the <NUM>-, <NUM>-, <NUM>-, and/or <NUM>-positions on the preceding saccharide units.

Fatty acid amide surfactants suitable for use the present compositions include those having the formula: R<NUM>CON(R<NUM>)<NUM> in which R<NUM> is an alkyl group containing from <NUM> to <NUM> carbon atoms and each R<NUM> is independently hydrogen, C<NUM>- C<NUM> alkyl, C<NUM>- C<NUM> hydroxyalkyl, or --( C<NUM>H<NUM>O)XH, where x is in the range of from <NUM> to <NUM>.

A useful class of non-ionic surfactants include the class defined as alkoxylated amines or, most particularly, alcohol alkoxylated/aminated/alkoxylated surfactants. These non-ionic surfactants may be at least in part represented by the general formulae: R<NUM>--(PO)SN--(EO)tH, R<NUM>--(PO)SN--(EO)tH(EO)tH, and R<NUM>--N(EO)tH; in which R<NUM> is an alkyl, alkenyl or other aliphatic group, or an alkyl-aryl group of from <NUM> to <NUM>, preferably <NUM> to <NUM> carbon atoms, EO is oxyethylene, PO is oxypropylene, s is <NUM> to <NUM>, preferably <NUM>-<NUM>, t is <NUM>-<NUM>, preferably <NUM>-<NUM>, and u is <NUM>-<NUM>, preferably <NUM>-<NUM>. Other variations on the scope of these compounds may be represented by the alternative formula: R<NUM>--(PO)v-N[(EO)wH][(EO)zH] in which R<NUM> is as defined above, v is <NUM> to <NUM> (e.g., <NUM>, <NUM>, <NUM>, or <NUM> (preferably <NUM>)), and w and z are independently <NUM>-<NUM>, preferably <NUM>-<NUM>. These compounds are represented commercially by a line of products sold by Huntsman Chemicals as nonionic surfactants. A preferred chemical of this class includes Surfonic™ PEA <NUM> Amine Alkoxylate. Preferred nonionic surfactants for the compositions of the invention include alcohol alkoxylates, EO/PO block copolymers, alkylphenol alkoxylates, and the like.

The treatise<NPL> is an excellent reference on the wide variety of nonionic compounds generally employed in the practice of the present invention. A typical listing of nonionic classes, and species of these surfactants, is given in <CIT>. Further examples are given in "Surface Active Agents and detergents" (Vol. I and II by Schwartz, Perry and Berch).

The semi-polar type of nonionic surface active agents are another class of nonionic surfactant useful in compositions of the present invention. Generally, semi-polar nonionics are high foamers and foam stabilizers, which can limit their application in CIP systems. However, within compositional embodiments of this invention designed for high foam cleaning methodology, semi-polar nonionics would have immediate utility. The semi-polar nonionic surfactants include the amine oxides, phosphine oxides, sulfoxides and their alkoxylated derivatives.

Amine oxides are tertiary amine oxides corresponding to the general formula:
<CHM>
wherein the arrow is a conventional representation of a semi-polar bond; and, R<NUM>, R<NUM>, and R<NUM> may be aliphatic, aromatic, heterocyclic, alicyclic, or combinations thereof. Generally, for amine oxides of detergent interest, R<NUM> is an alkyl radical of from about <NUM> to about <NUM> carbon atoms; R<NUM> and R<NUM> are alkyl or hydroxyalkyl of <NUM>-<NUM> carbon atoms or a mixture thereof; R<NUM> and R<NUM> can be attached to each other, e.g. through an oxygen or nitrogen atom, to form a ring structure; R<NUM> is an alkaline or a hydroxyalkylene group containing <NUM> to <NUM> carbon atoms; and n ranges from <NUM> to about <NUM>.

Useful water soluble amine oxide surfactants are selected from the coconut or tallow alkyl di-(lower alkyl) amine oxides, specific examples of which are dodecyldimethylamine oxide, tridecyldimethylamine oxide, etradecyldimethylamine oxide, pentadecyldimethylamine oxide, hexadecyldimethylamine oxide, heptadecyldimethylamine oxide, octadecyldimethylaine oxide, dodecyldipropylamine oxide, tetradecyldipropylamine oxide, hexadecyldipropylamine oxide, tetradecyldibutylamine oxide, octadecyldibutylamine oxide, bis(<NUM>-hydroxyethyl)dodecylamine oxide, bis(<NUM>-hydroxyethyl)-<NUM>-dodecoxy-<NUM>-hydroxypropylamine oxide, dimethyl-(<NUM>-hydroxydodecyl)amine oxide, <NUM>,<NUM>,<NUM>-trioctadecyldimethylamine oxide and <NUM>-dodecoxy-<NUM>-hydroxypropyldi-(<NUM>-hydroxyethyl)amine oxide.

Useful semi-polar nonionic surfactants also include the water soluble phosphine oxides having the following structure:
<CHM>
wherein the arrow is a conventional representation of a semi-polar bond; and, R<NUM> is an alkyl, alkenyl or hydroxyalkyl moiety ranging from <NUM> to about <NUM> carbon atoms in chain length; and, R<NUM> and R<NUM> are each alkyl moieties separately selected from alkyl or hydroxyalkyl groups containing <NUM> to <NUM> carbon atoms.

Examples of useful phosphine oxides include dimethyldecylphosphine oxide, dimethyltetradecylphosphine oxide, methylethyltetradecylphosphone oxide, dimethylhexadecylphosphine oxide, diethyl-<NUM>-hydroxyoctyldecylphosphine oxide, bis(<NUM>-hydroxyethyl)dodecylphosphine oxide, and bis(hydroxymethyl)tetradecylphosphine oxide.

Semi-polar nonionic surfactants useful herein also include the water soluble sulfoxide compounds which have the structure:
<CHM>
wherein the arrow is a conventional representation of a semi-polar bond; and, R<NUM> is an alkyl or hydroxyalkyl moiety of about <NUM> to about <NUM> carbon atoms, from <NUM> to about <NUM> ether linkages and from <NUM> to about <NUM> hydroxyl substituents; and R<NUM> is an alkyl moiety consisting of alkyl and hydroxyalkyl groups having <NUM> to <NUM> carbon atoms.

Useful examples of these sulfoxides include dodecyl methyl sulfoxide; <NUM>-hydroxy tridecyl methyl sulfoxide; <NUM>-methoxy tridecyl methyl sulfoxide; and <NUM>-hydroxy-<NUM>-dodecoxybutyl methyl sulfoxide.

Semi-polar nonionic surfactants for the compositions of the invention include dimethyl amine oxides, such as lauryl dimethyl amine oxide, myristyl dimethyl amine oxide, cetyl dimethyl amine oxide, combinations thereof, and the like. Useful water soluble amine oxide surfactants are selected from the octyl, decyl, dodecyl, isododecyl, coconut, or tallow alkyl di-(lower alkyl) amine oxides, specific examples of which are octyldimethylamine oxide, nonyldimethylamine oxide, decyldimethylamine oxide, undecyldimethylamine oxide, dodecyldimethylamine oxide, iso-dodecyldimethyl amine oxide, tridecyldimethylamine oxide, tetradecyldimethylamine oxide, pentadecyldimethylamine oxide, hexadecyldimethylamine oxide, heptadecyldimethylamine oxide, octadecyldimethylaine oxide, dodecyldipropylamine oxide, tetradecyldipropylamine oxide, hexadecyldipropylamine oxide, tetradecyldibutylamine oxide, octadecyldibutylamine oxide, bis(<NUM>-hydroxyethyl)dodecylamine oxide, bis(<NUM>-hydroxyethyl)-<NUM>-dodecoxy-<NUM>-hydroxypropylamine oxide, dimethyl-(<NUM>-hydroxydodecyl)amine oxide, <NUM>,<NUM>,<NUM>-trioctadecyldimethylamine oxide and <NUM>-dodecoxy-<NUM>-hydroxypropyldi-(<NUM>-hydroxyethyl)amine oxide.

Suitable nonionic surfactants suitable for use with the compositions of the present invention include alkoxylated surfactants. Suitable alkoxylated surfactants include EO/PO copolymers, capped EO/PO copolymers, alcohol alkoxylates, capped alcohol alkoxylates, mixtures thereof, or the like. Suitable alkoxylated surfactants for use as solvents include EO/PO block copolymers, such as the Pluronic and reverse Pluronic surfactants; alcohol alkoxylates, such as Dehypon LS-<NUM> (R-(EO)<NUM>(PO)<NUM>) and Dehypon LS-<NUM> (R-(EO)<NUM>(PO)<NUM>); and capped alcohol alkoxylates, such as Plurafac LF221 and Tegoten EC11; mixtures thereof, or the like.

The components of the lubricant composition can further be combined with various functional components. In some embodiments, the lubricant composition including the mineral oil, fatty acid, sorbitan esters, poly glycols, and nonionic surfactant make up a large amount, or even substantially all of the total weight of the lubricant composition. For example, in some embodiments few or no additional functional ingredients are disposed therein.

In other embodiments, additional functional ingredients may be included in the lubricant compositions. The functional ingredients provide desired properties and functionalities to the compositions. For the purpose of this application, the term "functional ingredient" includes a material that when dispersed or dissolved in a use and/or concentrate solution, such as an aqueous solution, provides a beneficial property in a particular use.

The compositions do not include silicone fluids, emulsions or components which undesirably present formulation limitations for use on metal surfaces, in addition to plastic surfaces. Exemplary silicone materials, which are excluded from the dry lubricant compositions, includes for example silicone emulsions (such as emulsions formed from methyl(dimethyl), higher alkyl and aryl silicones; and functionalized silicones such as chlorosilanes; amino-, methoxy-, epoxy- and vinyl-substituted siloxanes; silanols); polydimethylsiloxanes, high molecular weight hydroxy-terminated dimethyl silicone; anionic and/or cationic surfactants employing silicon functional groups; silicone powders; and the like.

In other embodiments, the compositions may include antimicrobial agents, colorants, defoaming agents or foam generators, cracking inhibitors (e.g. PET stress cracking inhibitors), film-forming materials, additional surfactants, anti-redeposition agents, bleaching agents, solubility modifiers, dispersants, rinse aids, metal protecting agents, stabilizing agents, corrosion inhibitors, tracers, additional sequestrants and/or fragrances and/or dyes, rheology modifiers or thickeners, hydrotropes or couplers, buffers, solvents and the like. The amounts and types of such additional components will be apparent to those skilled in the art.

Useful emulsifier agents include ethoxylate compounds providing further lubricant benefits, based on one or more of the group including alcohol ethoxylates, chlorine, methyl, propyl or butyl end capped alcohol ethoxylates, ethoxylated alkyphenol compounds, and poly(ethylene oxide-propylene oxide) copolymers, such as those disclosed in <CIT> which is incorporated herein by reference in its entirety. A particularly preferred ethoxylate compound for use as an additional emulsifier in the dry lubricant composition is an ethoxylated lauryl alcohol.

Useful antimicrobial agents include disinfectants, antiseptics and preservatives. Non-limiting examples of useful antimicrobial agents include acidic polysaccharides, phenols including halo- and nitrophenols and substituted bisphenols such as <NUM>-hexylresorcinol, <NUM>-benzyl-<NUM>-chlorophenol and <NUM>,<NUM>,<NUM>'-trichloro-<NUM>'-hydroxydiphenyl ether, organic and inorganic acids and its esters and salts such as dehydroacetic acid, peroxycarboxylic acids, peroxyacetic acid, methyl p-hydroxy benzoic acid, cationic agents such as quaternary ammonium compound, aldehydes such as glutaraldehyde, antimicrobial dyes such as is acridines, triphenylmethane dyes and quinones and halogens including iodine and chlorine compounds. The antimicrobial agents can be used in an amount sufficient to provide desired antimicrobial properties. For example, from <NUM> to about <NUM> weight percent, preferably about <NUM> to about <NUM> weight percent of antimicrobial agent, or preferably about <NUM> to about <NUM> weight percent of antimicrobial agent based on the total weight of the dry lubricant composition.

Useful foam inhibitors include methyl silicone polymers. Non-limiting examples of useful foam generators include surfactants such as non-ionic, anionic, cationic and amphoteric compounds. In a preferred embodiment non-silicone polymers are employed as foam inhibitors and/or foam generators. These components can be used in amounts to give the desired results.

Useful viscosity modifiers include pour-point depressants and viscosity improvers such as polymethacrylates, polyisobutylenes and polyalkyl styrenes. The viscosity modifier is used in amount to give desired results, for example, from <NUM> to about <NUM> weight percent, preferably about <NUM> to about <NUM> weight percent, based on the total weight of the composition.

Useful esters for use in the dry lubricant compositions to prevent or reduce residues experienced overtime from use of the dry lubricant compositions employing a mineral oil, include for example fatty esters. In an aspect, a fatty ester may be used in combination with the concentration of mineral oil in the formulations or may replace all or a portion of the mineral oil. Particularly useful esters include, for example, emollient esters, polyesters and the like. Esters include a --OCO-moiety. In some embodiments, the ester preferably includes no atoms other than carbon, hydrogen and oxygen atoms. In some embodiments, the ester preferably includes carboxy (--COO--) oxygen atoms; and may include ether (--O-) oxygen atoms. An example of a commercially available ester suitable for use with the dry lubricant compositions to prevent residues are Crodamol ® products from Croda (ester based).

Useful tracers or tracing components for use in the dry lubricant compositions include for example fluorescent compounds. Such compounds are typically aromatic or aromatic heterocyclic materials often containing condensed ring system. An important feature of these compounds is the presence of an uninterrupted chain of conjugated double bonds associated with an aromatic ring. The number of such conjugated double bonds is dependent on substituents as well as the planarity of the fluorescent part of the molecule. Most compounds are derivatives of stilbene or <NUM>,<NUM>'-diamino stilbene, biphenyl, five membered heterocycles (triazoles, oxazoles, imidazoles, etc.) or six membered heterocycles (cumarins, naphthalamides, triazines, etc.). Such components are commercially available and will be appreciated by those skilled in the art. Exemplary tracers or tracing components which may be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiophene-<NUM>,<NUM>-dioxide, azoles, <NUM>- and <NUM>-membered-ring heterocycles and other miscellaneous agents. Stilbene derivatives which may be useful in the present invention include, but are not necessarily limited to, derivatives of bis(triazinyl)amino- stilbene; bisacylamino derivatives of stilbene; triazole derivatives of stilbene; oxadiazole derivatives of stilbene; oxazole derivatives of stilbene; and styryl derivatives of stilbene, examples of which are available under the trade name Tinopal CBS-X. Other commercially available tracers or tracing components are available under the names are stilbene3; FBA351, and benzenesulfonic acid <NUM>,<NUM>'-(<NUM>,<NUM>'-biphenylylenedivinylene)di-disodium salt. Other fluorescent tracers used in the lubricant of the invention are thiophene of benzoxazole, benzoxazole thiophene, aminotriazine formaldehyde co-condensates with organic dyes, and combinations thereof, and where the organic dyes of aminotriazine formaldehyde co-condensates may be pigmented melanin, sulfonamide, copolymer of formaldehyde. Additional description of suitable fluorescent tracers is set forth in <CIT>.

In an embodiment, the present invention relates to a method for lubricating the passage of a container along a conveyor. This embodiment can include applying a lubricant composition to at least a portion of a container-contacting surface of the conveyor or to at least a portion of a conveyor-contacting surface of the container. In an aspect, the lubricant compositions are applied directly on the surface of the plastic and/or metallic chains, such as those found on a conveyor belt surface, without any extra dissolvent. In an aspect, the application can be performed through the preferred use of a manual or automatic sprayer or nozzle that spray the conveyor chain surface with the lubricant composition. Alternatively, the lubricant compositions can be applied with a brush, such as a plastic brush with nylon bristles (with a thickness of approximately <NUM>) that allows an adequate distribution of the lubricant along the conveyor chain to form a permanent layer or film of lubricant on the surface of said conveyor chain.

The lubricant coating can be applied in a constant or intermittent fashion. Preferably, the lubricant coating is applied in an intermittent fashion in order to minimize the amount of applied lubricant composition. It has been discovered that the present invention may be applied intermittently and maintain a low coefficient of friction in between applications, or avoid a condition known as "drying". Specifically, the present invention may be applied for a period of time and then not applied for at least <NUM> minutes or longer, or at least <NUM> minutes or longer for a semi-dry mode. The present invention may be applied for a period of time and then not applied for at least an hour, or at least <NUM> hours, or at least <NUM> hours or longer for a total-dry mode. The application period may be long enough to spread the composition over the conveyor belt (i.e. one revolution of the conveyor belt). During the application period, the actual application may be continuous, i.e. lubricant is applied to the entire conveyor, or intermittent, i.e. lubricant is applied in bands and the containers spread the lubricant around. The lubricant is preferably applied to the conveyor surface at a location that is not populated by packages or containers. For example, it is preferable to apply the lubricant spray upstream of the package or container flow or on the inverted conveyor surface moving underneath and upstream of the container or package.

In some embodiments, the ratio of application time to non-application time may be at least <NUM>:<NUM>, at least <NUM>:<NUM>, at least <NUM>:<NUM>, at least <NUM>:<NUM>, and at least <NUM>:<NUM>, and wherein the lubricant maintains a low coefficient of friction in between lubricant applications.

In some embodiments, the lubricant maintains a coefficient of friction below about <NUM>, below about <NUM>, and preferably below about <NUM> or below about <NUM>.

In some embodiments, a feedback loop may be used to determine when the coefficient of friction reaches an unacceptably high level. The feedback loop may trigger the lubricant composition to turn on for a period of time and then optionally turn the lubricant composition off when the coefficient of friction returns to an acceptable level.

A layer of the lubricant composition is applied to treated surfaces. In an embodiment, the lubricant coating thickness provides a coefficient of friction below about <NUM>, below about <NUM>, and preferably below about <NUM> or below about <NUM>. In other embodiments, the lubricant coating thickness provides a coefficient of friction below about <NUM>, below about <NUM>, and preferably below about <NUM> or below about <NUM> and preferably is maintained generally at the interface at least about <NUM>, more preferably about <NUM> to about <NUM>, and most preferably about <NUM> to about <NUM>.

In some embodiments, the lubrication is provided by the dry lubricant in dirty zones of application of use, such as where spillage has occurred and before washing. Beneficially, the dry lubricant composition whether used in clean or dirty zones does not cause reduction in the coefficient of friction, such that the lubrication is maintained. In an aspect, the dry lubricant provides a coefficient of friction below about <NUM>, below about <NUM>, below about <NUM>, below about <NUM>, and preferably below about <NUM> in both clean and dirty zones.

Application of the lubricant composition can be carried out using any suitable technique including spraying, including standard energized (e.g. pressurized) or non-energized spray nozzle systems, wiping, brushing, drip coating, roll coating, hydraulic systems, and other methods for application of a thin film. In a preferred aspect, the application of the lubricant composition is with a spray nozzle.

In an aspect of the invention, the lubricant composition is applied directly without diluting on the conveyor chain to form a lubricant layer that adheres to the surface of the conveyor chain for a period that may last up to <NUM> hours. In a preferred aspect, the lubricant composition is applied directly without diluting on a plastic conveyor chain to form a lubricant layer that adheres to the surface of the conveyor chain for a period that may last up to <NUM> hours.

A variety of kinds of conveyors and conveyor parts can be coated with the lubricant composition. Parts of the conveyor that support or guide or move the containers and thus are preferably coated with the lubricant composition include belts, chains, gates, chutes, sensors, and ramps having surfaces made of fabrics, metals, plastics, composites, or combinations of these materials.

The lubricant composition can also be applied to a wide variety of containers including beverage containers; food containers; household or commercial cleaning product containers; and containers for oils, antifreeze or other industrial fluids. The containers can be made of a wide variety of materials including glasses; plastics (e.g., polyolefins such as polyethylene and polypropylene; polystyrenes; polyesters such as PET and polyethylene naphthalate (PEN); polyamides, polycarbonates; and mixtures or copolymers thereof); metals (e.g., aluminum, tin or steel); papers (e.g., untreated, treated, waxed or other coated papers); ceramics; and laminates or composites of two or more of these materials (e.g., laminates of PET, PEN or mixtures thereof with another plastic material). In an embodiment of the method, the container preferably includes polyethylene terephthalate, polyethylene naphthalate, glass, or metal. The containers can have a variety of sizes and forms, including cartons (e.g., waxed cartons or TETRAPACK™ boxes), cans, bottles and the like.

Although any desired portion of the container can be coated with the lubricant composition, the lubricant composition preferably is applied only to parts of the container that will come into contact with the conveyor or with other containers.

Preferably, the lubricant composition is not applied to portions of thermoplastic containers that are prone to stress cracking. However, beneficially according to the invention, the dry lubricant compositions are PET compatible and do not cause stress cracking.

In a preferred embodiment, the present invention relates to a method for lubricating the passage of a container along a conveyor. This embodiment can include applying an undiluted lubricant composition to at least a portion of a container-contacting surface of the conveyor or to at least a portion of a conveyor-contacting surface of the container; conveying containers on the conveyor; washing or rinsing the conveyor and removing soil; continuing to convey containers after washing, conveying being conducted with a coefficient of friction of less than or equal to about <NUM>. In an embodiment of the composition, the composition is PET compatible to the extent that is graded A or B in a stress cracking test for refillable PET bottles.

Embodiments of the present invention are further defined in the following non-limiting Examples. It should be understood that these Examples are given by way of illustration only.

A Lubricity Test was conducted to measure frictional force of a cylinder vessel on a short track lubricated by control formulations and a dry lubricant formulation according to the invention. The bottom of a cylinder packages made of mild steel (aluminum), glass, or PET were loaded with approximately <NUM> liters of water, and the short track conveyor belt was either stainless steel or delrin (plastic). The short track conveyor belt was washed with water and rinsed for at least <NUM> minutes.

The lubricant formulations were prepared and dosed using nozzles for dosing equipment. The short track conveyor belt was run for <NUM> minutes before taking an initial measurement. The dynamometer was zeroed out and the cylinder bottlers were placed on the conveyor and fastened with a cord to the dynamometer to register force readings. The drag force, using an average value, was measured with a solid state transducer, which was connected to the cylinder by a thin monofilament fishing line. The drag force was monitored with a strip chart recorder. The coefficient of friction (COF), also referred to as the lubrication value, was calculated by dividing the drag force (F) by the weight of the cylinder package (W): COF=F/W. Measurements were obtained every <NUM>-<NUM> minutes until the full consumption of the lubricant formulations (or control formulations). Additional observations were obtained, including for example, foam formation, sounds of conveyor, appearance and cleaning of the conveyor.

The conveyor and the cylinder bottles were cleaned for the application of lubricant formations. The test duration was <NUM> hours using <NUM> aluminum cans, <NUM> glass bottles and PET bottles on the stainless steel conveyor track. The test duration was also <NUM> hours using <NUM> aluminum cans, <NUM> glass bottles and PET bottles on the plastic conveyor tract.

A control using a commercially available silicon and fatty amine-based lubricant (Control (positive) DryExx®, Ecolab Inc. Paul, MN), a control using water spray along on the track (Control (negative)), and a formulation according to the formula in Table <NUM> (Dry Lubricant) were evaluated for use as "dry" lubricants for various containers on a stainless steel and a delrin (plastic) conveyor. Lubricant compositions were applied to the surface of the belt using a <NUM> inch brush applicator without any dilution; which is representative of application by various means including commercial uses often employing nozzle application to spray the dry lubricant compositions on a surface in need of treatment. The amount of initial lubricant applied was <NUM> grams for the stainless steel conveyor and <NUM> grams for the delrin (plastic) conveyor. After the initial application of lubricant, the belt was allowed to run for <NUM> hours without application of additional lubricant while the force exerted on the strain gauge was recorded.

The results are shown in <FIG> (stainless steel conveyor for (A) glass, (B) aluminum, and (C) PET containers) and 2A-C (delrin (plastic) conveyor for (A) glass, (B) aluminum, and (C) PET containers). These experiments demonstrated that conventional lubricant compositions showed unacceptable increases in coefficient of friction and are not suitable for dry mode application.

The dry lubricant according to an embodiment of the invention was more effective (lower coefficient of friction (COF)) on all surfaces in dry mode than the positive and negative controls. Beneficially, the Dry Lubricant according to the invention produced a COF below at least <NUM> on all surfaces, and below <NUM> on all surfaces except glass with the metal conveyor (wherein the COF slightly exceeded <NUM>), demonstrating coefficients of friction that are desirable in the industry and outperform positive controls for use as dry lubricants.

An exemplary dry lubrication formulation according to the invention was evaluated for PET compatibility utilizing a PET stress crack evaluation. Compatibility of lubricant compositions with PET beverage bottles was determined by charging bottles with carbonated water, contacting with the lubricant composition, storing at elevated temperatures and humidity for a period of <NUM> days, and counting the number of bottles that either burst or leaked through cracks in the base portion of the bottle. Standard Coca-Cola <NUM> liter bottles were filled with tap water and stored under ambient conditions (<NUM>-<NUM>) overnight. Twenty four bottles were pressurized and then dry lubricant composition was applied (including at <NUM> times concentrate) and remained in contact for <NUM> days under the maintained pressure of <NUM> psi, then placed in a standard bus pan lined with a polyethylene bag. For each composition tested, a total of four bus pans of <NUM> bottles were used. Immediately after placing bottles and test aqueous composition into bus pans, the bus pans were moved to an environmental chamber under conditions of <NUM>°F and <NUM>% relative humidity. Bins were checked on a daily basis and again after <NUM> days of compete testing and the number of failed bottles (burst or leak of liquid through cracks in the bottle base) was recorded.

The dry lubricant formulations evaluated included soft water (Control (negative)), the Dry Lubricant Concentrate (formulation in Example <NUM>, Table <NUM>), and the Dry Lubricant <NUM>%.

The evaluation of the degree of crazing was done according the Coca Cola--Line Lubrication Stress Crack Test. Four categories are established A, B, C, and D (including a (-) or (+) grading available for each), with evaluation grades as follow:.

The results are shown in <FIG> which demonstrate that a conveyor lubricant composition according to the present invention exhibited an advantageous low level of stress cracking in a standard test for compatibility with PET bottles. <FIG> show the starting measurements, <FIG> show the measurements at <NUM> days with lubricant, and <FIG> show the final measurements after <NUM> days with lubricant.

Table <NUM> provides further summary of the evaluation.

The results show that overall the dry lubricant according to the invention provided excellent PET compatibility with PET beverage bottles.

The methods of Example <NUM> where further used to evaluate an exemplary dry lubrication formulation according to the invention for use with returnable PET bottles utilizing a PET stress crack evaluation. The dry lubricant formulations evaluated included soft water (Control (negative)), the Dry Lubricant Concentrate (formulation in Example <NUM>, Table <NUM>), and the Dry Lubricant <NUM>%.

The results are shown in <FIG> which demonstrate that a conveyor lubricant composition according to the present invention exhibited an advantageous low level of stress cracking in a standard test for compatibility with returnable PET bottles. <FIG> show the final measurements with the dry lubricant concentrate, and <FIG> show the final measurements with the dry lubricant <NUM>%.

Claim 1:
A dry lubricant composition comprising:
<NUM> wt% to <NUM> wt% of one or more fatty acids;
<NUM> wt% to <NUM> wt% of one or more mineral oils;
<NUM> wt% to <NUM> wt% of one or more sorbitan esters; and
<NUM> wt% to <NUM> wt% of one or more nonionic surfactants, wherein the non-ionic surfactant is an alcohol alkoxylate, an EO/PO block copolymer or an alkyl phenol alkoxylate; and
<NUM>.001wt% to <NUM> wt% of one or more polyglycols; and
Wherein the composition is substantially-free of water and free of a silicone component, and provides lubricity for metal and plastic conveyors.