Patent Description:
Polyolefins, in particular polyethylene and polypropylene are increasingly consumed in large amounts in a wide range of applications, including packaging for food and other goods, fibres, automotive components, and a great variety of manufactured articles.

Polypropylene based materials offer significant potential for mechanical recycling, as these materials are extensively used in packaging. Taking into account the huge amount of waste collected compared to the amount of waste recycled back into the stream, there is still a great potential for intelligent reuse of plastic waste streams and for mechanical recycling of plastic wastes.

Development of polyolefins and polyolefin blends is often focussed on the continuous goal of improving the balance of mechanical properties, and also the more effective handling of waste streams, for both economical and also environmental reasons. It is usually understood that the use of recycled materials in polymer blends tends to lead to a degradation of mechanical properties, since the mechanical properties of virgin polymers can be easily modified by the polymerization conditions, whereas controlling the properties of a recycled material is intrinsically more difficult, resulting in poorer performance of these compositions. Given this understanding in the field, a polyolefin composition that is able to make use of recycled materials as a modifier for a virgin polyolefin, said composition having improved mechanical properties over the component virgin polyolefin, would be of great importance in the field of repurposing of waste polyolefin materials.

Such combinations of recycled material and virgin material have not been widely reported.

Rather, modificiations of recycled polyolefin compositions with a minor amount of modifiers can be found in the prior art.

For example, <CIT> relates to polypropylene-polyethylene blends comprising A) <NUM> to <NUM> wt. -% of a blend of A-<NUM>) polypropylene and A-<NUM>) polyethylene and B) <NUM> to <NUM> wt. -% of a compatibilizer being a heterophasic polyolefin composition comprising B-<NUM>) a polypropylene with an MFR2 between <NUM> and <NUM>/<NUM> (according to ISO <NUM> at <NUM> at a load of <NUM>) and B-<NUM>) a copolymer of ethylene and propylene or C4 to C10 alpha olefin with a Tg (measured with dynamic-mechanical thermal analysis, DMTA, according to ISO <NUM>-<NUM>) of below -<NUM> and an intrinsic viscosity (measured in decalin according to DIN ISO <NUM>/<NUM> at <NUM>) of at least <NUM> dl/g, whereby the blend has simultaneously increased Charpy Notched Impact Strength (according to ISO <NUM>-leA, measured at <NUM>), Flexural Modulus (according to ISO <NUM>) as well as heat deflection resistance (determined with DMTA according to ISO <NUM>-<NUM>). Although not limited as such, the blend A) may be a recycled material, such as Krublend or DIPOLEN S.

Likewise, <CIT> refers to a composition of polypropylene and polyethylene, which contains a specific compatibilizer and flow enhancer. The compatibilizer and flow enhancer is a heterophasic polyolefin composition comprising <NUM> to <NUM> wt. -% of a matrix being a polypropylene and <NUM> to <NUM> wt. -% of an elastomer being a copolymer of ethylene and propylene or C4 to C10 alpha olefin with a glass transition temperature Tg measured according to ISO <NUM>-<NUM> of below -<NUM> and an intrinsic viscosity measured according to DIN ISO <NUM>/<NUM> at <NUM> of at least <NUM> dl/g.

In both cases, improvements are only achieved with respect to the composition of polypropylene and polyethylene (i.e. the recycled material), not in comparison to the applied compatibilizer or modifier.

It is further well known in the art that increasing the melt flow rate of polypropylene compositions is often detrimental to the impact strength; consequently, in addition to having an improved balance stiffness and impact properties, it is a further object of the present invention to provide a composition having a good balance of high melt flow rate and high impact strength.

Furthermore, in the interests of economy, the present application is directed to simple, economic blends that achieve the goals of the invention without resorting to the introduction of fillers or other polymeric modifiers.

<CIT> relates to a polyolefin composition, the use of the polyolefin composition in a compound with one or more virgin polymers for automotive articles or applications, pipes or profiles for construction applications, the use of a heterophasic polypropylene (HECO) as compatibilizer for polyolefin blends A) between a copolymer of ethylene and one or more C4 to C19 alpha olefin B) and a reinforcing mineral filler D) as well as a process for producing the polyolefin composition. <CIT> relates to polyolefin compositions comprising, by weight: A) <NUM>-<NUM>% of a polyolefin component containing not less than <NUM>% of a waste material selected from polyethylene, polypropylene or their mixtures; B) <NUM>-<NUM>% of a heterophasic polyolefin composition having flexural modulus equal to or lower than <NUM> MPa. <CIT> relates to a polymer composition comprising: - a first polypropylene (A); - at least one ethylene vinyl acetate copolymer; wherein said first polypropylene (A) is a recycled polypropylene comprising at most <NUM> % by weight of polyethylene based on the total weight of polypropylene (A). <CIT> relates to a composition comprising a heterophasic propylene copolymer with low melt flow rate and rather low amount of xylene cold solubles and a recycled polymer composition being rich in polypropylene.

The present invention is based upon the finding that a specific recycled material, containing polypropylene and polyethylene, can be used to improve the mechanical properties of a virgin heterophasic propylene copolymer (HECO). The stiffness of blends of said recycled material and virgin HECO is equal to or greater than that of the virgin HECO and the impact strength is markedly improved.

The present invention is therefore directed to a polypropylene composition (C) obtainable by blending:.

wherein the polypropylene composition (C) has a melt flow rate (MFR<NUM>) measured according to ISO <NUM> at <NUM> and <NUM> in the range from <NUM> to <NUM>/<NUM>, and the sum of the content of the heterophasic propylene copolymer (HECO) and the content of blend (A) is at least <NUM> wt. -%, based on the total weight of the composition.

In another aspect, the present invention is directed to an article comprising more than <NUM> wt. -%, preferably more than <NUM> wt. -%, of the polypropylene composition according to any of the preceding claims, preferably a molded article, more preferably an injection molded article or a foam injection molded article.

In a further aspect, the present invention is directed to a use of a modifier being a blend (A), which comprises:.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the invention pertains. Although, any methods and materials similar or equivalent to those described herein can be used in practice for testing of the present invention, the preferred materials and methods are described herein. In describing and claiming the present invention, the following terminology will be used in accordance with the definitions set out below.

Unless clearly indicated otherwise, use of the terms "a," "an," and the like refers to one or more.

A heterophasic polypropylene is a propylene-based copolymer with a crystalline matrix phase, which can be a propylene homopolymer or a random copolymer of propylene and at least one alpha-olefin comonomer, and an elastomeric phase dispersed therein. In case of a random heterophasic propylene copolymer, said crystalline matrix phase is a random copolymer of propylene and at least one alpha-olefin comonomer. The polymers according to the present invention have such morphology.

The elastomeric phase can be a propylene copolymer with a high amount of comonomer that is not randomly distributed in the polymer chain but is distributed in a comonomer-rich block structure and a propylene-rich block structure. A heterophasic polypropylene usually differentiates from a one-phasic propylene copolymer in that it shows two distinct glass transition temperatures Tg which are attributed to the matrix phase and the elastomeric phase.

A propylene homopolymer is a polymer that essentially consists of propylene monomer units. Due to impurities especially during commercial polymerization processes a propylene homopolymer can comprise up to <NUM> mol% comonomer units, preferably up to <NUM> mol% comonomer units and most preferably up to <NUM> mol% comonomer units. A propylene random copolymer is a copolymer of propylene monomer units and comonomer units, preferably selected from ethylene and C4-C12 alpha-olefins, in which the comonomer units are distributed randomly over the polymeric chain. The propylene random copolymer can comprise comonomer units from one or more comonomers different in their amounts of carbon atoms. In the following amounts are given in % by weight (wt. -%) unless it is stated otherwise.

For the purposes of the present description and of the subsequent claims, the term "recycled waste" and is used to indicate a material recovered from both post-consumer waste and post-industrial waste, as opposed to virgin polymers. Post-consumer waste refers to objects having completed at least a first use cycle (or life cycle), i.e. having already served their first purpose; while post-industrial waste refers to manufacturing scrap, which does not normally reach a consumer.

The term "virgin" denotes the newly produced materials and/or objects prior to their first use, which have not already been recycled.

Many different kinds of polyethylene or polypropylene can be present in "recycled waste". Blend (A) according to the present invention includes at least a propylene homopolymer, polyethylene, limonene and fatty acids.

Blend (A) is further characterized by a content of isotactic propylene homopolymer of <NUM> to <NUM> wt. The content of isotactic propylene homopolymer may easily be determined by FT-IR spectroscopy, whereby FT-IR spectroscopy needs to be calibrated by using <NUM>C-NMR spectroscopy as described in the experimental section.

Blend (A) is further characterized by a content of polyethylene and ethylene containing copolymers of <NUM> - <NUM> wt. Polyethylene denotes any of the conventional polyethylenes such as LDPE, LLDPE, MDPE, and HDPE.

Ethylene containing copolymers are extremely widespread and may include for example ethylene propylene copolymers such as ethylene propylene rubber, plastomers such as C<NUM>C<NUM> rubbers, and countless other polymers including ethylene-derived units.

The amount of polyamide-<NUM> quoted is furthermore a realistic measurement of the total amount of units derived from amides considering the common and widespread use of polyamide-<NUM> resulting in an acceptable error margin.

The term "recycled material" such as used herein denotes materials reprocessed from "recycled waste".

A polymer blend denotes a mixture of two or more polymeric components. In general, the blend can be prepared by mixing the two or more polymeric components. Suitable mixing procedures known in the art are post-polymerization blending procedures. Post-polymerization blending can be dry blending of polymeric components such as polymer powders and/or compounded polymer pellets or melt blending by melt mixing the polymeric components.

If not indicated otherwise "%" refers to weight-%.

The polypropylene composition (C) according to the present invention comprises <NUM> to <NUM> wt. -%, based on the total weight of the composition, of the heterophasic propylene copolymer (HECO), preferably <NUM> to <NUM> wt. -%, most preferably <NUM> to <NUM> wt.

The heterophasic propylene copolymer (HECO) according to the present invention comprises:.

The crystalline matrix (M) is a propylene homo- or copolymer, preferably a homopolymer.

The crystalline matrix (M) preferably has a melt flow rate (MFR<NUM>) measured according to ISO <NUM> at <NUM> and <NUM> in the range from <NUM> to <NUM>/<NUM>, more preferably in the range from <NUM> to <NUM>/<NUM>, most preferably in the range from <NUM> to <NUM>/<NUM>.

The crystalline matrix component (M) preferably has an isotactic pentad concentration [mmmm] as determined by <NUM>C-NMR spectroscopy of more than <NUM>%, and a content of <NUM>,<NUM>-regiodefects in the range from <NUM> to <NUM> mol%. Such ranges are typical for polypropylenes polymerized using metallocene catalysts.

Preferably the heterophasic propylene copolymer (HECO) has been polymerized in the presence of a single site catalyst, more preferably a metallocene catalyst.

In a heterophasic propylene copolymer the matrix and elastomeric phases cannot be separated and measured, since the elastomeric phase is dispersed within the crystalline matrix. In order to characterize the matrix and elastomeric phases of a heterophasic propylene copolymer several methods are known. One method is the extraction with xylene of a fraction that contains for the most part the elastomeric phase, thus separating a xylene cold soluble (XCS) fraction from a xylene cold insoluble (XCI) fraction. The XCS fraction contains for the most part the elastomeric phase and only a small part of the matrix phase, whereas the XCI fraction contains for the most part the matrix phase and only a small part of the elastomeric phase.

As an alternative method the separation of a crystalline fraction and a soluble fraction with the CRYSTEX QC method using trichlorobenzene (TCB) as a solvent. This method is described below in the determination methods section. The crystalline fraction (CF) contains for the most part the matrix phase and only a small part of the elastomeric phase and the soluble fraction (SF) contains for the most part the elastomeric phase and only a small part of the matrix phase. In some cases, this method results in more useful data, since the crystalline fraction (CF) and the soluble fraction (SF) more accurately correspond to the matrix and elastomeric phases respectively. Due to the differences in the separation methods of xylene extraction and CRYSTEX QC method the properties of XCS/XCI fractions on the one hand and crystalline/soluble (CF/SF) fractions on the other hand are not exactly the same, meaning that the amounts of matrix phase and elastomeric phase can differ as well as the properties.

The heterophasic propylene copolymer preferably has a content of xylene cold solubles (XCS), determined at <NUM> according to ISO <NUM>; <NUM>th edition; <NUM>-<NUM>-<NUM>, of from <NUM> to <NUM> wt. -%, more preferably from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt.

Said xylene cold soluble fraction preferably has an ethylene (C2) content (C2(XCS)), as determined by quantitative <NUM>C-NMR spectroscopy, of from <NUM> to <NUM> wt. -%, more preferably from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt.

Said xylene cold soluble fraction preferably has an intrinsic viscosity (iV(XCS)) of from <NUM> to <NUM> dl/g, more preferably from <NUM> to <NUM> dl/g, most preferably from <NUM> to <NUM> dl/g.

The heterophasic propylene copolymer (HECO) of the present invention has a content of crystalline fraction (CF), determined according to the method described in the determination methods, within the range from <NUM> to <NUM> wt. -%, preferably <NUM> to <NUM> wt. -%, based on the total weight of the heterophasic propylene copolymer.

The heterophasic propylene copolymer (HECO) of the present invention has a content of soluble fraction (SF), determined according to the method described in the determination methods, within the range from <NUM> to <NUM> wt. -%, preferably <NUM> to <NUM> wt. -%, based on the total weight of the heterophasic propylene copolymer.

The crystalline fraction (CF) of the heterophasic propylene copolymer (HECO) preferably has an ethylene content (C2(CF)), as determined by the method described in the determination methods, in the range from <NUM> to <NUM> wt. -%, more preferably in the range from <NUM> to <NUM> wt. -%, most preferably in the range from <NUM> to <NUM> wt.

The soluble fraction (SF) of the heterophasic propylene copolymer (HECO) has an ethylene content (C2(SF)), as determined by the method described in the determination methods, in the range from <NUM> to <NUM> wt. -%, preferably in the range from <NUM> to <NUM> wt. -%, more preferably in the range from <NUM> to <NUM> wt.

The soluble fraction (SF) of the heterophasic propylene copolymer (HECO) has an intrinsic viscosity (iV(SF)), determined according to the method described in the determination methods, in the range from <NUM> to <NUM> dl/g, preferably in the range from <NUM> to <NUM> dl/g, more preferably in the range from <NUM> to <NUM> dl/g.

The heterophasic propylene copolymer (HECO) preferably has a total ethylene (C2) content, as determined by the method described in the determination methods, of from <NUM> to <NUM> wt. -%, more preferably from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt.

The heterophasic propylene copolymer (HECO) preferably has a melt flow rate (MFR<NUM>) measured according to ISO <NUM> at <NUM> and <NUM> in the range from <NUM> to <NUM>/<NUM>, more preferably from <NUM> to <NUM>/<NUM>, most preferably from <NUM> to <NUM>/<NUM>.

The heterophasic propylene copolymer (HECO) has a melting temperature (Tm) measured by the method described in the determination methods in the range from <NUM> to <NUM>, more preferably in the range from <NUM> to <NUM>, most preferably in the range from <NUM> to <NUM>.

The heterophasic propylene copolymer (HECO) preferably has a crystallization temperature (Tc) measured by the method described in the determination methods in the range from <NUM> to <NUM>, more preferably in the range from <NUM> to <NUM>, most preferably in the range from <NUM> to <NUM>.

The heterophasic propylene copolymer of the present invention may be polymerised by sequential polymerisation in the presence of a metallocene catalyst system, wherein.

In a preferred embodiment, the polymerisation process is carried out in the presence of a metallocene catalyst system as laid out herein.

The heterophasic polypropylene composition of the present invention is typically and preferably made in a multistep process well known in the art. A preferred multistage process is a loop-gas phase-process, such as developed by Borealis A/S, Denmark (known as BORSTAR(R) technology) described e.g. in patent literature, such as in <CIT> or in <CIT>.

The invention preferably relates to the copolymerisation of propylene, ethylene and optionally further comonomers as defined above and below, in an at least two, optionally three step process so as to form the heterophasic polypropylene composition. Preferably, propylene and ethylene are the only monomers used.

Ideally, the process of the invention employs two, preferably three main reactors, a first reactor operating in bulk, a first gas phase reactor and optionally a second gas phase reactor.

The process may also utilize a prepolymerisation step, taking place in a separate reactor before the three main reactors.

The crystalline matrix may be present in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt. -%, based on the total weight of the heterophasic polypropylene composition.

The elastomeric phase comprised in the heterophasic polypropylene composition and dispersed in above mentioned matrix, may be present in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt. -%, based on the total weight of the heterophasic polypropylene composition.

The comonomer content, C2 (total), of the inventive polymer may be in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt.

The crystalline matrix being a propylene homo- or copolymer is being produced in a bulk step, then transferred to the second stage in which the amorphous propylene ethylene elastomer is produced in a first gas phase reactor (GPR1) in the presence of the first polypropylene fraction.

The comonomer content of the crystalline matrix may be in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt.

It is particularly preferable that the crystalline matrix (a) is a propylene homopolymer and comprises <NUM> wt. -% of comonomer.

The MFR of the crystalline matrix may be in the range of <NUM> to <NUM>/<NUM>, preferably in the range of <NUM> to <NUM>/<NUM>, more preferably in the range of <NUM> to <NUM>/<NUM>. This applies regardless of the (bi)-modality of the crystalline matrix.

In case, the crystalline matrix is bimodal, then the first polypropylene fraction is being produced in a bulk step, then transferred to the second stage in which the second polypropylene fraction is prepared in a first gas phase reactor (GPR1) in the presence of the first polypropylene fraction. This mixture, being the crystalline matrix and comprising said first and second polypropylene fractions together, is transferred to the third stage in which the amorphous propylene-ethylene elastomer is prepared in a gas phase reactor (GPR2) in the presence of the crystalline matrix.

The MFR<NUM> of the polymer produced in the first stage, being the first polypropylene fraction, may be in the range of <NUM> to <NUM>/<NUM>, preferably in the range of <NUM> to <NUM>/<NUM>, more preferably in the range of <NUM> to <NUM>/<NUM>.

The MFR<NUM> of the polymer produced in the second stage, being the second polypropylene fraction, may be in the range of <NUM> to <NUM>/<NUM>, preferably in the range of <NUM> to <NUM>/<NUM>, more preferably in the range of <NUM> to <NUM>/<NUM>.

Given the second polypropylene fraction is produced in the presence of the first polypropylene fraction, it is understood, that it's properties cannot be analysed as such, but have to be determined based on the properties of the first polypropylene fraction and the properties of the crystalline fraction.

In a preferred embodiment, the heterophasic polypropylene composition comprises.

Preferably, the amount of the first polypropylene fraction is equal or higher than the amount of the second polypropylene fraction based on the total weight of the crystalline matrix.

The amount of the first polypropylene fraction may be in the range of <NUM> - <NUM> wt. -%, preferably <NUM> - <NUM> wt. -%, more preferably in the range of <NUM> - <NUM> wt. -% based on the total weight of the crystalline matrix.

The amount of the second polypropylene fraction may be in the range of <NUM> - <NUM> wt. -%, preferably <NUM> - <NUM> wt. -%, more preferably in the range of <NUM> - <NUM> wt. -% based on the total weight of the crystalline matrix.

The ratio of the amount of the first and the second polypropylene fraction may be in the ranges of <NUM>:<NUM> to <NUM>:<NUM>, like <NUM>:<NUM> to <NUM>:<NUM>, preferably <NUM>:<NUM> to <NUM>:<NUM>.

For bulk and gas phase copolymerisation reactions, the reaction temperature used will generally be in the range <NUM> to <NUM> (e.g. <NUM> to <NUM>), the reactor pressure will generally be in the range <NUM> to <NUM> bar for gas phase reactions with bulk polymerisation operating at slightly higher pressures. The residence time will generally be <NUM> to <NUM> hours (e.g. <NUM> to <NUM> hours).

The comonomer content of the first and second polypropylene fraction may be same or different and independently chosen from each other.

The comonomer content of the polymer produced in the first stage, namely the first polypropylene fraction, may be in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt.

It is particularly preferable that the first polypropylene fraction is a propylene homopolymer and comprises <NUM> wt. -% of comonomer.

The comonomer content of the polymer produced in the second stage, namely the second polypropylene fraction, may be in the range of <NUM> to <NUM> wt. -%, preferably in the range of <NUM> to <NUM> wt. -%, more preferably in the range of <NUM> to <NUM> wt.

It is particularly preferable, that the second polypropylene fraction is a propylene homopolymer and comprises <NUM> wt. -% of comonomer.

Within this application it is understood, that the comonomer content of the crystalline matrix, when available as distinct material sample, is determined via quantitative FT-IR spectroscopy calibrated by <NUM>C-NMR spectroscopy. When the comonomer content of the matrix and the dispersed fraction should be evaluated starting from the final polymer (comprising both the matrix and the dispersed fraction), then the matrix (and its properties) is reflected by the crystalline fraction (CF) determined according to CRYSTEX QC analysis. Accordingly, the dispersed amorphous propylene ethylene elastomer is reflected by the soluble fraction (SF) determined according to CRYSTEX QC analysis.

The heterophasic polypropylene composition according to the invention is preferably obtainable by a catalyst system comprising by a single-site catalyst, more preferably being obtainable by a metallocene catalyst complex and cocatalysts.

Preferred complexes of the metallocene catalyst include:.

Especially preferred is rac-anti-dimethylsilanediyl[<NUM>-methyl-<NUM>,<NUM>-bis-(<NUM>',<NUM>'-dimethylphenyl)-<NUM>,<NUM>,<NUM>,<NUM>-tetrahydro-s indacen-<NUM>-yl] [<NUM>-methyl-<NUM>-(<NUM>',<NUM>'-dimethylphenyl)-<NUM>-methoxy-<NUM>-tert10butylinden-<NUM>-yl] zirconium dichloride.

To form an active catalytic species it is normally necessary to employ a cocatalyst as is well known in the art.

According to the present invention a cocatalyst system comprising a boron containing cocatalyst and an aluminoxane cocatalyst is used in combination with the above defined metallocene catalyst complex.

The aluminoxane cocatalyst can be one of formula (I):
<CHM>
where n is from <NUM> to <NUM> and R has the meaning below.

Aluminoxanes are formed on partial hydrolysis of organoaluminum compounds, for example those of the formula AlR<NUM>, AlR<NUM>Y and Al<NUM>R<NUM>Y<NUM> where R can be, for example, C1- C10-alkyl, preferably C1-C5-alkyl, or C3-C10-cycloalkyl, C7-C12-arylalkyl or -alkylaryl and/or phenyl or naphthyl, and where Y can be hydrogen, halogen, preferably chlorine or bromine, or C1-C10-alkoxy, preferably methoxy or ethoxy. The resulting oxygen-containing aluminoxanes are not in general pure compounds but mixtures of oligomers of the formula (I).

The preferred aluminoxane is methylaluminoxane (MAO). Since the aluminoxanes used according to the invention as cocatalysts are not, owing to their mode of preparation, pure compounds, the molarity of aluminoxane solutions hereinafter is based on their aluminium content.

Also a boron containing cocatalyst is used in combination with the aluminoxane cocatalyst.

The catalyst complex ideally comprises a co-catalyst, certain boron containing cocatalysts are preferred. Especially preferred borates of use in the invention therefore comprise the trityl, i.e. triphenylcarbenium, ion. Thus the use of Ph<NUM>CB(PhF<NUM>)<NUM> and analogues therefore are especially favoured.

The catalyst system of the invention is used in supported form. The particulate support material used is silica or a mixed oxide such as silica-alumina, in particular silica. The use of a silica support is preferred. The skilled practitioner is aware of the procedures required to support a metallocene catalyst.

In a preferred embodiment, the catalyst system corresponds to the ICS3 of <CIT>.

The polypropylene composition according to the present invention comprises from <NUM> to <NUM> wt. -% of blend (A). It is the essence of the present invention that blend (A) is obtained from a recycled waste stream. Blend (A) can be either recycled post-consumer waste or industrial waste, such as for example from the automobile industry, or alternatively, a combination of both.

The polypropylene composition (C) preferably contains from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt. -% of blend (A).

It is particularly preferred that blend (A) consists of recycled post-consumer waste and/or industrial waste.

Preferably, blend (A) is obtained from recycled waste by means of plastic recycling processes known in the art. Such recyclates are commercially available, e.g. from Corepla (Italian Consortium for the collection, recovery, recycling of packaging plastic wastes), Resource Plastics Corp. (Brampton, ON), Kruschitz GmbH, Plastics and Recycling (AT), Vogt Plastik GmbH (DE), Mtm Plastics GmbH (DE) etc. Non-exhaustive examples of polyethylene rich recycled materials include: DIPOLEN S (Mtm Plastics GmbH), food grade rHDPE (BIFFA PLC) and a range of polyethylene rich materials, such as e.g. HD-LM02041 from PLASgran Ltd.

In a certain preferred embodiment, the recycled polyethylene rich material is DIPOLEN (Mtm Plastics GmbH), such as DIPOLEN S or DIPOLEN H, preferably DIPOLEN S. DIPOLEN is obtained from domestic waste streams (i.e. it is a product of domestic recycling) for example the "yellow bag" recycling system, which operates in some parts of Germany.

Blend (A) comprises the following components:.

wherein amounts of A-<NUM>) to A-<NUM>) are given with respect to the total weight of blend (A).

Blend (A) may further comprise the following components:.

Blend (A) may have a a content of polyethylene and ethylene containing copolymers of greater than <NUM> wt. -%, but less than <NUM> wt. -%, with respect to the total weight of blend (A).

In addition, blend (A) may have a content of isotactic polypropylene homopolymer of greater than <NUM> wt. -%, but less than <NUM> wt. -%, with respect to the total weight of blend (A). Blend (A) may also have a relative amount of polystyrene of between <NUM> and <NUM> wt. -%, preferably between <NUM> and <NUM> wt. -%, more preferably between <NUM> and <NUM> wt. -%, most preferably between <NUM> and <NUM> wt.

Blend (A) may also have a relative amount of polyamide-<NUM> of between <NUM> and <NUM> wt. -%, more preferably between <NUM> and <NUM> wt. -%, most preferably between <NUM> and <NUM> wt.

Blend (A) may also have a relative amount of poly(ethylene terephthalate) of between <NUM> and <NUM> wt. -%, preferably between <NUM> and <NUM> wt. -%, more preferably between <NUM> and <NUM> wt. -%, most preferably between <NUM> and <NUM> wt.

Consequently, blend (A) may comprise the following components.

The polyethylene of the recycled material typically includes recycled high-density polyethylene (rHDPE), recycled medium-density polyethylene (rMDPE), recycled low-density polyethylene (rLDPE) and the mixtures thereof. In a certain embodiment, the polyethylene is high density PE with an average density of greater than <NUM>/cm<NUM>, preferably greater than <NUM>/cm<NUM>, most preferably greater than <NUM>/cm<NUM>.

According to the present invention, blend (A) has a content of limonene as determined using solid phase microextraction (HS-SPME-GC-MS) of from <NUM> ppm to <NUM> ppm, preferably from <NUM> ppm to <NUM> ppm, more preferably from <NUM> ppm to <NUM> ppm, most preferably from <NUM> ppm to <NUM> ppm. Limonene is conventionally found in recycled polyolefin materials and originates from packaging applications in the field of cosmetics, detergents, shampoos and similar products. Therefore, blend (A) contains limonene, when blend (A) contains material that originates from such types of domestic waste streams.

The fatty acid content is yet another indication of the recycling origin of blend (A). However, in some cases, the fatty acid content may be below the detection limit due to specific treatments in the recycling process.

According to the present invention, blend (A) preferably has a content of fatty acids as determined using solid phase microextraction (HS-SPME-GC-MS) of from <NUM> ppm to <NUM> ppm, preferably from <NUM> ppm to <NUM> ppm, more preferably from <NUM> ppm to <NUM> ppm, most preferably from <NUM> ppm to <NUM> ppm.

Due to the recycling origin, blend (A) may also contain:.

in amounts of up to <NUM> wt. -% with respect to the weight of blend (A).

According to the present invention, blend (A) has a melt flow rate (ISO <NUM>, <NUM>, <NUM>) of <NUM> to <NUM>/<NUM>, preferably of <NUM> to <NUM>/<NUM>, more preferably of <NUM> to <NUM>/<NUM>, most preferably of <NUM> to <NUM>/<NUM>.

It is needless to say, during recycling usually any reasonable measure will be taken for lowering polyamides, talc, chalk, paper, wood and metal as far as final application or use suggests such measure.

The polypropylene composition of the invention is obtainable by blending:.

The polypropylene composition (C) of the present invention can comprise further components, in addition to the essential components as defined above. However, the individual contents of the heterophasic propylene copolymer (HECO) and blend (A) must add up to at least <NUM> wt. -%, most preferably at least <NUM> wt. -% based on the total weight of the polypropylene composition (C).

Typical further components could be, for example, additives, the selection of which would be well-known to the skilled practitioner, and masterbatch polypropylenes, used to introduce the additives to the polypropylene composition (C).

Typically additives would be selected from antioxidants, anti-slip agents, nucleating agents, anti-scratch agents, anti-scorch agents, metal deactivators, UV-stabilisers, acid scavengers, lubricants, anti-static agents, pigments and the like, as well as combinations thereof. These additives are well known in the polymer industry and their use will be familiar to the skilled practitioner. Any additives which are present may be added as an isolated raw material or in a mixture with a carrier polymer, i.e. in a so-called master batch.

The content of heterophasic propylene copolymer (HECO) within the polypropylene composition (C) is from <NUM> to <NUM> wt. -%, more preferably from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt.

The content of blend (A) within the polypropylene composition (C) is from <NUM> to <NUM> wt. -%, more preferably from <NUM> to <NUM> wt. -%, most preferably from <NUM> to <NUM> wt.

It is therefore preferred that the polypropylene composition (C) comprises:.

It is further preferred that the polypropylene composition (C) comprises:.

Preparing and further processing the polypropylene composition (C) includes mixing the individual components of the polypropylene composition (C), for instance by use of a conventional compounding or blending apparatus, e.g. a Banbury mixer, a <NUM>-roll rubber mill, Buss-co- kneader or a twin screw extruder. A typical extruding temperature is in the range of <NUM> to <NUM>, or more preferably in the range of <NUM> to <NUM>.

The polypropylene composition (C) has a melt flow rate (MFR<NUM>) measured according to ISO <NUM> at <NUM> and <NUM> in the range from <NUM> to <NUM>/<NUM>, more preferably in the range from <NUM> to <NUM>/<NUM>, most preferably in the range from <NUM> to <NUM>/<NUM>.

The propylene composition (C) preferably has a Charpy Notched Impact Strength (NIS) measured according to ISO <NUM>-1eA at <NUM> in the range from <NUM> to <NUM> kJ/m<NUM>, preferably in the range from <NUM> to <NUM> kJ/m<NUM>, more preferably in the range from <NUM> to <NUM> kJ/m<NUM>.

The propylene composition (C) preferably has a Charpy Notched Impact Strength (NIS) measured according to ISO <NUM>-1eA at -<NUM> in the range from <NUM> to <NUM> kJ/m<NUM> preferably in the range from <NUM> to <NUM> kJ/m<NUM>, more preferably in the range from <NUM> to <NUM> kJ/m<NUM>.

The propylene composition (C) preferably has a tensile modulus measured according to ISO <NUM>-<NUM> in the range from <NUM> to <NUM> MPa, preferably in the range from <NUM> to <NUM> MPa, more preferably in the range from <NUM> to <NUM> MPa.

The propylene composition (C) preferably has a melting temperature (Tm) measured by the method described in the determination methods in the range from <NUM> to <NUM>, more preferably in the range from <NUM> to <NUM>, most preferably in the range from <NUM> to <NUM>.

The propylene composition (C) preferably has a crystallization temperature (Tc) measured by the method described in the determination methods in the range from <NUM> to <NUM>, more preferably in the range from <NUM> to <NUM>, most preferably in the range from <NUM> to <NUM>.

The propylene composition (C) preferably has numerical values of the Charpy Notched Impact Strength (NIS), measured according to ISO <NUM>-1eA at <NUM> given in kJ/m<NUM>, and the melt flow rate (MFR<NUM>), measured according to ISO <NUM> at <NUM> and <NUM> given in g/<NUM>, which follow the following inequation (I), more preferably inequation (Ia), most preferably inequation (Ib): <MAT> <MAT> <MAT>.

The polypropylene composition of the present invention has a desirable balance of stiffness (as given by the tensile modulus) and impact strength (Charpy). This balance makes the copolymer a good candidate for automotive components.

The present invention is therefore further directed to an article comprising the polypropylene composition as described above.

Said article comprises more than <NUM> wt. -%, preferably more than <NUM> wt. -%, more preferably more than <NUM> wt. -%, still more preferably more than <NUM> wt. -% of the polypropylene composition of the present invention. In a separate embodiment, the article consists of just said polypropylene composition.

If present, other components may be, for example, further polymeric components, fillers, fibers, and other suitable components well known to the skilled practitioner.

The article may be a molded article, preferably an injection molded article or a foam injection molded article.

The article may further be a part of household appliances, especially of washing machine or dishwasher components, or automotive articles, especially of car interiors and exteriors, like instrumental carriers, shrouds, structural carriers, bumpers, side trims, step assists, body panels, spoilers, dashboards, interior trims and the like.

All embodiments and restrictions of the composition as discussed above may equally be applied to the composition in said article.

The present invention is further directed to the use of a modifier being a blend (A), which comprises:.

wherein amounts of A-<NUM>) to A-<NUM>) are given with respect to the total weight of blend (A), wherein blend (A) is a recycled material, which is recovered from a waste plastic material derived from post-consumer and/or post-industrial waste,.

for modifying a heterophasic propylene copolymer (HECO) comprising:.

The improvement in the Charpy Notched Impact Strength (NIS), measured according to ISO <NUM>-1eA at <NUM>, is at least <NUM>% relative to the raw heterophasic propylene copolymer (HECO), preferably at least <NUM>%, more preferably at least <NUM>%, most preferably at least <NUM>%.

All embodiments and restrictions of the individual components or the composition as discussed above may equally be applied in said use.

The melt flow rate (MFR) is determined according to ISO <NUM> and is indicated in g/<NUM>. The MFR is an indication of the flowability, and hence the processability, of the polymer. The higher the melt flow rate, the lower the viscosity of the polymer. The MFR<NUM> of polypropylene is determined at a temperature of <NUM> and a load of <NUM>.

Quantitative nuclear-magnetic resonance (NMR) spectroscopy was used to quantify the stereo-regularity (tacticity) and regio-regularity of the crystalline matrix of the polymers. Quantitative 13C {<NUM>} NMR spectra were recorded in the solution-state using a Bruker Advance III <NUM> NMR spectrometer operating at <NUM> and <NUM> for <NUM> and 13C respectively. All spectra were recorded using a 13C optimised <NUM> extended temperature probe head at <NUM> using nitrogen gas for all pneumatics.

For propylene homopolymers approximately <NUM> of material was dissolved in <NUM>,<NUM>-tetrachloroethane-d2 (TCE-d2). To ensure a homogenous solution, after initial sample preparation in a heat block, the NMR tube was further heated in a rotatary oven for at least <NUM> hour. Upon insertion into the magnet the tube was spun at <NUM>. This setup was chosen primarily for the high resolution needed for tacticity distribution quantification (<NPL>; <NPL>). Standard single-pulse excitation was employed utilising the NOE and bi-level WALTZ <NUM> decoupling scheme (<NPL>; <NPL>). A total of <NUM> (<NUM>) transients were acquired per spectra.

Quantitative 13C{<NUM>} NMR spectra were processed, integrated and relevant quantitative properties determined from the integrals using proprietary computer programs. For propylene homopolymers all chemical shifts are internally referenced to the methyl isotactic pentad (mmmm) at <NUM> ppm. The tacticity distribution was quantified through integration of the methyl region between <NUM>-<NUM> ppm correcting for any sites not related to the stereo sequences of interest (<NPL>; <NPL>). Specifically the influence of regio defects and comonomer on the quantification of the tacticity distribution was corrected for by subtraction of representative regio defect and comonomer integrals from the specific integral regions of the stereo sequences. The isotacticity was determined at the pentad level and reported as the percentage of isotactic pentad (mmmm) sequences with respect to all pentad sequences: <MAT>.

The presence of <NUM>,<NUM> erythro regio defects was indicated by the presence of the two methyl sites at <NUM> and <NUM> ppm and confirmed by other characteristic sites.

Characteristic signals corresponding to other types of regio defects were not observed (<NPL>). The amount of <NUM>,<NUM> erythro regio defects was quantified using the average integral of the two characteristic methyl sites at <NUM> and <NUM> ppm: <MAT>.

The total amount of propene was quantified as the sum of primary inserted propene and all other present regio defects: <MAT>.

The mole percent of <NUM>,<NUM> erythro regio defects was quantified with respect to all propene: <MAT>.

Quantitative nuclear-magnetic resonance (NMR) spectroscopy was used to quantify the comonomer content and comonomer sequence distribution of the polymers. Quantitative <NUM>C{<NUM>H} NMR spectra were recorded in the solution-state using a Bruker Avance III <NUM> NMR spectrometer operating at <NUM> and <NUM> for <NUM>H and <NUM>C respectively. All spectra were recorded using a <NUM>C optimised <NUM> extended temperature probehead at <NUM> using nitrogen gas for all pneumatics. Approximately <NUM> of material was dissolved in <NUM> of <NUM>,<NUM>-tetrachloroethane-d<NUM> (TCE-d<NUM>) along with chromium-(III)-acetylacetonate (Cr(acac)<NUM>) resulting in a <NUM> solution of relaxation agent in solvent (<NPL>). To ensure a homogenous solution, after initial sample preparation in a heat block, the NMR tube was further heated in a rotary oven for at least <NUM> hour. Upon insertion into the magnet the tube was spun at <NUM>. This setup was chosen primarily for the high resolution and quantitatively needed for accurate ethylene content quantification. Standard single-pulse excitation was employed without NOE, using an optimised tip angle, <NUM> recycle delay and a bi-level WALTZ <NUM> decoupling scheme (<NPL>; <NPL>). A total of <NUM> (<NUM>) transients were acquired per spectra.

Quantitative <NUM>C{<NUM>H} NMR spectra were processed, integrated and relevant quantitative properties determined from the integrals using proprietary computer programs. All chemical shifts were indirectly referenced to the central methylene group of the ethylene block (EEE) at <NUM> ppm using the chemical shift of the solvent. This approach allowed comparable referencing even when this structural unit was not present. Characteristic signals corresponding to the incorporation of ethylene were observed <NPL>).

Xylene Cold Soluble fraction at room temperature (XCS, wt. -%) is determined at <NUM> according to ISO <NUM>; <NUM>th edition; <NUM>-<NUM>-<NUM>.

The tensile modulus was measured according to ISO <NUM>-<NUM> (cross head speed = <NUM>/min; test speed <NUM>/min at <NUM>) using compression moulded specimens as described in EN ISO <NUM>-<NUM> (dog bone shape, <NUM> thickness). The measurement was done after <NUM> conditioning time of the specimen.

The Charpy notched impact strength (NIS) was measured according to ISO <NUM>1eA at +<NUM> or -<NUM>, using injection moulded bar test specimens of 80x10x4 mm<NUM> prepared in accordance with EN ISO <NUM>-<NUM>.

The crystalline (CF) and soluble fractions (SF) of the polypropylene (PP) compositions as well as the comonomer content and intrinsic viscosities of the respective fractions were analyzed by the CRYSTEX QC, Polymer Char (Valencia, Spain).

A schematic representation of the CRYSTEX QC instrument is shown in <FIG>. The crystalline and amorphous fractions are separated through temperature cycles of dissolution at <NUM>, crystallization at <NUM> and re-dissolution in a <NUM>,<NUM>,<NUM>-trichlorobenzene (<NUM>,<NUM>,<NUM>-TCB) at <NUM> as shown in <FIG>. Quantification of SF and CF and determination of ethylene content (C2) of the parent EP copolymer and its soluble and crystalline fractions are achieved by means of an infrared detector (IR4) and an online <NUM>-capillary viscometer which is used for the determination of the intrinsic viscosity (iV).

The IR4 detector is a multiple wavelength detector detecting IR absorbance at two different bands (CH3 and CH2) for the determination of the concentration and the Ethylene content in Ethylene-Propylene copolymers. IR4 detector is calibrated with series of <NUM> EP copolymers with known Ethylene content in the range of <NUM> wt. -% to <NUM> wt. -% (determined by <NUM>C-NMR spectroscopy) and various concentration between <NUM> and <NUM>/ml for each used EP copolymer used for calibration.

The amount of Soluble fraction (SF) and Crystalline Fraction (CF) are correlated through the XS calibration to the "Xylene Cold Soluble" (XCS) quantity and respectively Xylene Cold Insoluble (XCI) fractions, determined according to standard gravimetric method as per ISO16152. XS calibration is achieved by testing various EP copolymers with XS content in the range <NUM>-<NUM> wt.

The intrinsic viscosity (iV) of the parent EP copolymer and its soluble and crystalline fractions are determined with a use of an online <NUM>-capillary viscometer and are correlated to corresponding iV's determined by standard method in decalin according to ISO <NUM>. Calibration is achieved with various EP PP copolymers with iV = <NUM>-<NUM> dL/g.

A sample of the PP composition to be analyzed is weighed out in concentrations of <NUM>/ml to <NUM>/ml. After automated filling of the vial with <NUM>,<NUM>,<NUM>-TCB containing <NUM>/l <NUM>,<NUM>-tert-butyl-<NUM>-methylphenol (BHT) as antioxidant, the sample is dissolved at <NUM> until complete dissolution is achieved, usually for <NUM>, with constant stirring of <NUM> rpm.

As shown in a <FIG>, a defined volume of the sample solution is injected into the column filled with inert support where the crystallization of the sample and separation of the soluble fraction from the crystalline part is taking place. This process is repeated two times. During the first injection the whole sample is measured at high temperature, determining the iV[dl/g] and the C2[wt. -%] of the PP composition. During the second injection the soluble fraction (at low temperature) and the crystalline fraction (at high temperature) with the crystallization cycle are measured (wt. -% C2, iV).

The intrinsic viscosity (iV) is measured according to DIN ISO <NUM>/<NUM>, October <NUM>, in Decalin at <NUM>.

Calibration standards are prepared by blending iPP and HDPE to create a calibration curve. The thickness of the films of the calibration standards are <NUM>. For the quantification of the iPP, PS, PET and PA <NUM> content in the samples quantitative IR spectra are recorded in the solid-state using a Bruker Vertex <NUM> FTIR spectrometer. Spectra are recorded on 25x25 mm square films of <NUM>-<NUM> thickness prepared by compression moulding at <NUM> and <NUM> - <NUM> mPa. Standard transmission FTIR spectroscopy is employed using a spectral range of <NUM>-<NUM>-<NUM>, an aperture of <NUM>, a spectral resolution of <NUM>-<NUM>, <NUM> background scans, <NUM> spectrum scans, an interferogram zero filling factor of <NUM> and Norton Beer strong apodisation.

The absorption of the band at <NUM>-<NUM> in iPP is measured and the iPP content is quantified according to a calibration curve (absorption/thickness in cm versus iPP content in weight %). The absorption of the band at <NUM>-<NUM> (PS), at <NUM>-<NUM> (PET) and <NUM>-<NUM> (PA6) are measured and the PS, PET and PA6 content quantified according to the calibration curve (absorption/thickness in cm versus PS, PET and PA content in wt %). The content of polyethylene and ethylene containing copolymers is obtained by subtracting (iPP+PS+PET+PA6) from <NUM>, taking into account the content of non-polymeric impurities as determined in the methods below. The analysis is performed as double determination.

The talc and chalk contents were measured by Thermogravimetric Analysis (TGA); experiments were performed with a Perkin Elmer TGA <NUM>. Approximately <NUM>-<NUM> of material was placed in a platinum pan. The temperature was equilibrated at <NUM> for <NUM> minutes, and afterwards raised to <NUM> under nitrogen at a heating rate of <NUM>/min. The weight loss between ca. <NUM> and <NUM> (WCO2) was assigned to CO2 evolving from CaCO3, and therefore the chalk content was evaluated as: <MAT>.

Afterwards the temperature was lowered to <NUM> at a cooling rate of <NUM>/min. Then the gas was switched to oxygen, and the temperature was raised again to <NUM>. The weight loss in this step was assigned to carbon black (Wcb). Knowing the content of carbon black and chalk, the ash content excluding chalk and carbon black was calculated as: <MAT>.

Where Ash residue is the weight% measured at <NUM> in the first step conducted under nitrogen. The ash content is estimated to be the same as the talc content for the investigated recyclates.

The contents of paper and wood were determined by conventional laboratory methods including milling, floatation, microscopy and Thermogravimetric Analysis (TGA).

The metal content was determined by X-ray fluorescence (XRF).

The limonene content was determined by solid phase microextraction (HS-SPME-GC-MS). Additional details are given below with respect to the specific sample.

The fatty acid content was determined by solid phase microextraction (HS-SPME-GC-MS). Additional details are given below with respect to the specific sample.

The catalyst used was Anti-dimethylsilanediyl[<NUM>-methyl-<NUM>,<NUM>-di(<NUM>,<NUM>-dimethylphenyl)-<NUM>,<NUM>,<NUM>,<NUM>-tetrahydro-s-indacen-<NUM>-yl][<NUM>-methyl-<NUM>-(<NUM>,<NUM>-dimethylphenyl)-<NUM>-methoxy-<NUM>-tert-butylinden-<NUM>-yl] zirconium dichloride as disclosed in <CIT> as ICS3.

A steel reactor equipped with a mechanical stirrer and a filter net was flushed with nitrogen and the reactor temperature was set to <NUM>. Next silica grade DM-L-<NUM> from AGC Si-Tech Co, pre-calcined at <NUM> (<NUM>) was added from a feeding drum followed by careful pressurising and depressurising with nitrogen using manual valves. Then toluene (<NUM>) was added. The mixture was stirred for <NUM>. Next <NUM> wt. -% solution of MAO in toluene (<NUM>) from Lanxess was added via feed line on the top of the reactor within <NUM>. The reaction mixture was then heated up to <NUM> and stirred at <NUM> for additional two hours. The slurry was allowed to settle and the mother liquor was filtered off. The catalyst was washed twice with toluene (<NUM>) at <NUM>, following by settling and filtration. The reactor was cooled off to <NUM> and the solid was washed with heptane (<NUM>). Finally MAO treated SiO2 was dried at <NUM> under nitrogen flow for <NUM> hours and then for <NUM> hours under vacuum (-<NUM> barg) with stirring. MAO treated support was collected as a free-flowing white powder found to contain <NUM>% Al by weight.

-% MAO in toluene (<NUM>) was added into a steel nitrogen blanked reactor via a burette at <NUM>. Toluene (<NUM>) was then added under stirring. The catalyst as cited above (<NUM>) was added from a metal cylinder followed by flushing with <NUM> toluene. The mixture was stirred for <NUM> minutes at <NUM>. Trityl tetrakis(pentafluorophenyl) borate (<NUM>) was then added from a metal cylinder followed by a flush with <NUM> of toluene. The mixture was stirred for <NUM> at room temperature. The resulting solution was added to a stirred cake of MAO-silica support prepared as described above over <NUM> hour. The cake was allowed to stay for <NUM> hours, followed by drying under N2 flow at <NUM> for <NUM> and additionally for <NUM> under vacuum (-<NUM> barg) under stirring. Dried catalyst was sampled in the form of pink free flowing powder containing <NUM>% Al and <NUM>% Zr.

The Ziegler-Natta catalyst was an emulsion-type Ziegler-Natta catalyst, being identical to of the catalyst employed in the polymerisation of the inventive examples of <CIT>.

The crystalline matrices of synthesized HECO1 and HECO2, i. e the polymers as sampled after the first GPR, both have an isotactic pentad concentration [mmmm] as determined by <NUM>C-NMR spectroscopy of <NUM>% and a content of <NUM>,<NUM>-regiodefects of <NUM> mol%.

The crystalline matrices of synthesized HECO3 and HECO4, i. e the polymers as sampled after the first GPR, both have an isotactic pentad concentration [mmmm] as determined by <NUM>C-NMR spectroscopy of <NUM>% and are free of <NUM>,<NUM>-regiodefects.

DIPOLEN S has been used as blend (A), being a polyethylene-polypropylene blend from Mtm Plastics GmbH, materials according to the August <NUM> specifications:.

Limonene quantification was carried out using solid phase microextraction (HS-SPME-GC-MS) by standard addition.

<NUM> ground samples were weighed into <NUM> headspace vials and after the addition of limonene in different concentrations and a glass-coated magnetic stir bar, the vial was closed with a magnetic cap lined with silicone/PTFE. Micro capillaries (<NUM> pL) were used to add diluted limonene standards of known concentrations to the sample. Addition of <NUM>, <NUM>, <NUM> and <NUM> ng equals <NUM>/kg, <NUM>/kg, <NUM>/kg and <NUM>/kg limonene, in addition standard amounts of <NUM>/kg, <NUM>/kg and <NUM>/kg limonene were used in combination with some of the samples tested in this application. For quantification, ion-<NUM> acquired in SIM mode was used. Enrichment of the volatile fraction was carried out by headspace solid phase microextraction with a <NUM> stable flex <NUM>/<NUM> pm DVB/Carboxen/PDMS fibre at <NUM> for <NUM> minutes. Desorption was carried out directly in the heated injection port of a GCMS system at <NUM>.

Fatty acid quantification was carried out using headspace solid phase micro-extraction (HS-SPME-GC-MS) by standard addition.

<NUM> ground samples were weighed in <NUM> headspace vial and after the addition of limonene in different concentrations and a glass coated magnetic stir bar the vial was closed with a magnetic cap lined with silicone/PTFE. <NUM>µL Micro-capillaries were used to add diluted free fatty acid mix (acetic acid, propionic acid, butyric acid, pentanoic acid, hexanoic acid and octanoic acid) standards of known concentrations to the sample at three different levels. Addition of <NUM>, <NUM>, <NUM> and <NUM> ng equals <NUM>/kg, <NUM>/kg, <NUM>/kg and <NUM>/kg of each individual acid. For quantification ion <NUM> acquired in SIM mode was used for all acids except propanoic acid, here ion <NUM> was used.

<NUM>The concentration of acetic acid, propionic acid, butyric acid, pentanoic acid, hexanoic acid octanoic acid, nonanoic acid and decanoic acid in each sample was added together to give a totally fatty acid concentration value.

A number of compositions were compounded according to the recipes given in Table <NUM>.

Claim 1:
A polypropylene composition (C) obtainable by blending:
a) <NUM> to <NUM> wt.-%, based on the total weight of the composition, of a heterophasic propylene copolymer (HECO), comprising
i) a crystalline matrix (M) being a propylene homo- or copolymer, preferably a homopolymer;
ii) an amorphous propylene-ethylene elastomer (E);
wherein the heterophasic propylene copolymer (HECO) has a crystalline fraction (CF) content determined according to the method described in the determination methods in the range from <NUM> to <NUM> wt.-%, and a soluble fraction (SF) content determined according to the method described in the determination methods in the range from <NUM> to <NUM> wt.-%, said soluble fraction (SF) having an ethylene content (C2(SF)), as determined according to the method described in the determination methods, in the range from <NUM> to <NUM> wt.-%, an intrinsic viscosity (iV(SF)), ad determined according to the method described in the determination methods, in the range from <NUM> to <NUM> dl/g, and a melting temperature (Tm) determined according to the method described in the determination methods in the range from <NUM> to <NUM>;
b) <NUM> to <NUM> wt.-%, based on the total weight of the composition, of a blend (A) comprising
A-<NUM>) a content of isotactic propylene homopolymer of <NUM> to <NUM> wt.-%,
A-<NUM>) a content of polyethylene and ethylene containing copolymers of <NUM> to <NUM> wt.-%,
A-<NUM>) <NUM> to <NUM> wt.-% of polystyrene,
A-<NUM>) <NUM> to <NUM> wt.-% polyamide-<NUM>,
A-<NUM>) <NUM> to <NUM> wt.-% of poly(ethylene terephthalate),
A-<NUM>) <NUM> ppm to <NUM> ppm of limonene as determined by using solid phase microextraction (HS-SPME-GC-MS), and
A-<NUM>) <NUM> ppm to <NUM> ppm total fatty acid content as determined by using solid phase microextraction (HS-SPME-GC-MS)
wherein amounts of A-<NUM>) to A-<NUM>) are given with respect to the total weight of blend (A),
wherein blend (A) is a recycled material recovered from a waste plastic material derived from post-consumer and/or post-industrial waste;
wherein the polypropylene composition (C) has a melt flow rate (MFR<NUM>) measured according to ISO <NUM> at <NUM> and <NUM> in the range from <NUM> to <NUM>/<NUM>, and the sum of the content of the heterophasic propylene copolymer (HECO) and the content of blend (A) is at least <NUM> wt.-%, based on the total weight of the composition.