Patent Description:
Triangular shaped abrasive particles and abrasive articles using the triangular shaped abrasive particles are disclosed in <CIT>; <CIT>; and <CIT>. In one embodiment, the abrasive particles' shape comprised an equilateral triangle. Triangular shaped abrasive particles are useful in manufacturing abrasive articles having enhanced cut rates.

<CIT> discloses CMP conditioners which can suppress microscratching of the surface of a semiconductor substrate and can realize stable CMP conditioner properties. The CMP conditioner according to a first aspect comprises a support member and a plurality of hard abrasive grains provided on a surface of the support member, wherein the plurality of hard abrasive grains are regularly arranged on the surface of the support member. The CMP conditioner according to a second aspect comprises a support member and a plurality of hard abrasive grains provided on the surface of the support member, wherein the plurality of hard abrasive grains are arranged on the surface of the support member regularly and so as for the density of the hard abrasive grains to decrease from the inner side of the support member toward the outer side of the support member.

Shaped abrasive particles, in general, can have superior performance over randomly crushed abrasive particles. By controlling the shape of the abrasive particle it is possible to control the resulting performance of the abrasive article. The inventors have discovered that by further controlling the shaped abrasive particles' z-direction rotational orientation, the cut and finish of the resulting coated abrasive article can be altered.

Coated abrasive articles are conventionally made by electrostatic coating (e-coat) the abrasive particles onto a make layer on a backing or drop coating the abrasive particles onto the make layer. Controlling the z-direction rotational orientation of abrasive particles in a coated abrasive article is not possible using conventional electrostatic deposition methods to propel the abrasive grain vertically against the force of gravity onto a make layer by use of an electrostatic field thereby erectly applying the abrasive particles as shown in <CIT>. The adhered abrasive particles to the make layer will have a random z-direction rotational orientation since the particle's rotation as it is being removed from the conveyor belt by the electrostatic field is random and uncontrolled. Similarly, in drop coated abrasive articles, the particle's z-direction rotational orientation is random as the particles are fed from the hopper and fall by the force of gravity onto the make layer.

During the manufacture of rigid abrasive tools, employing a metal bond and diamond abrasive particles, screens can be used to apply the diamond abrasive particles to a rigid support, such a metal disc, in a particular pattern or gird. However, the diamonds in general are not orientated to have any specific z-direction rotational orientation and the screen apertures are such that the diamond is free to rotate in any direction when being placed into the screen aperture. Sometimes the diamonds are oriented with respect to their internal crystallographic direction of maximum hardness as discussed in <CIT>; but it has been heretofore unappreciated to rotationally align formed ceramic abrasive particles with regard to a surface feature of the particle to either increase the cut or alter the resulting finish.

The inventors have discovered that the use of precision screens having precisely spaced and aligned non-circular apertures to hold an individual abrasive particle in a fixed position can be used to rotationally align a surface feature of the abrasive particles in a specific z-direction rotational orientation. Alignment of the surface feature can be used to enhance the cutting action of that surface feature or to change the finish produced on the workpiece by the surface feature.

Furthermore, the precision screens can be used to control the density of the abrasive particles without requiring any specific rotational orientation by creating a predetermined pattern with the abrasive particles in the abrasive layer. These patterns can achieve significantly more "vertex up" placement of the triangular formed abrasive particles on the coated backing than electrostatic coating methods can achieve; especially, at higher densities of the formed abrasive particles on the coated backing.

Additionally, an engineered abrasive layer having a predetermined pattern can be constructed where the spacing in the x and y directions along with the z-direction rotational orientation of the abrasive particles about a z-axis passing through the backing and the abrasive particle is controlled.

Hence, in one embodiment, the invention resides in a coated abrasive article comprising: a plurality of formed ceramic abrasive particles each having a surface feature; the plurality of formed ceramic abrasive particles attached to a flexible backing by a make coat comprising a resinous adhesive forming an abrasive layer; the surface feature having a specified z-direction rotational orientation; and wherein the specified z-direction rotational orientation occurs more frequently in the abrasive layer than would occur by a random z-direction rotational orientation of the surface feature.

It is to be understood by one of ordinary skill in the art that the present discussion is a description of exemplary embodiments only, and is not intended as limiting the broader aspects of the present disclosure, which broader aspects are embodied in the exemplary construction.

Repeated use of reference characters in the specification and drawings is intended to represent the same or analogous features or elements of the disclosure.

As used herein, the term "abrasive dispersion" means an alpha alumina precursor that can be converted into alpha alumina that is introduced into a mold cavity. The composition is referred to as an abrasive dispersion until sufficient volatile components are removed to bring solidification of the abrasive dispersion.

As used herein "formed ceramic abrasive particle" means a ceramic abrasive particle having at least a partially replicated shape. Non-limiting processes to make formed abrasive particles include shaping the precursor abrasive particle in a mold having a predetermined shape, extruding the precursor abrasive particle through an orifice having a predetermined shape, printing the precursor abrasive particle though an opening in a printing screen having a predetermined shape, or embossing the precursor abrasive particle into a predetermined shape or pattern. Non-limiting examples of formed ceramic abrasive particles include shaped abrasive particles formed in a mold, such as triangular plates as disclosed in <CIT>; <CIT>, and <CIT>; or extruded elongated ceramic rods/filaments often having a circular cross section produced by Saint-Gobain Abrasives an example of which is disclosed in <CIT>. Formed abrasive particle as used herein excludes randomly sized abrasive particles obtained by a mechanical crushing operation.

As used herein, the term "precursor shaped abrasive particle" means the unsintered particle produced by removing a sufficient amount of the volatile component from the abrasive dispersion, when it is in the mold cavity, to form a solidified body that can be removed from the mold cavity and substantially retain its molded shape in subsequent processing operations.

As used herein, the term "shaped abrasive particle", means a ceramic abrasive particle with at least a portion of the abrasive particle having a predetermined shape that is replicated from a mold cavity used to form the shaped precursor abrasive particle. Except in the case of abrasive shards (e.g. as described in U. patent publication <CIT>, the shaped abrasive particle will generally have a predetermined geometric shape that substantially replicates the mold cavity that was used to form the shaped abrasive particle. Shaped abrasive particle as used herein excludes randomly sized abrasive particles obtained by a mechanical crushing operation.

As used herein, "z-direction rotational orientation" refers to the particle's angular rotation about a z-axis passing through the particle and through the backing at a <NUM> degree angle to the backing when the particle is attached to the backing by a make layer.

Referring to <FIG> an exemplary shaped abrasive particle <NUM> with a sloping sidewall <NUM> is illustrated. The material from which the shaped abrasive particle <NUM> with a sloping sidewall <NUM> is made comprises a ceramic and specifically in one embodiment alpha alumina. Alpha alumina particles can be made from a dispersion of aluminum oxide monohydrate that is gelled, molded to shape, dried to retain the shape, calcined, and then sintered. The shaped abrasive particle's shape is retained without the need for a binder to form an agglomerate comprising abrasive particles in a binder that are then formed into a shaped structure.

In general, the shaped abrasive particles <NUM> with a sloping sidewall <NUM> comprise thin bodies having a first face <NUM>, and a second face <NUM> and having a thickness t. The first face <NUM> and the second face <NUM> are connected to each other by at least one sloping sidewall <NUM>. In some embodiments, more than one sloping sidewall <NUM> can be present and the slope or angle for each sloping sidewall <NUM> may be the same as shown in <FIG> or different.

In some embodiments, the first face <NUM> is substantially planar, the second face <NUM> is substantially planar, or both faces are substantially planar. Alternatively, the faces could be concave or convex as discussed in more detail in <CIT>. Additionally, an opening or aperture through the faces could be present as discussed in more detail in <CIT>.

In one embodiment, the first face <NUM> and the second face <NUM> are substantially parallel to each other. In other embodiments, the first face <NUM> and second face <NUM> can be nonparallel such that one face is sloped with respect to the other face and imaginary lines tangent to each face would intersect at a point. The sloping sidewall <NUM> of the shaped abrasive particle <NUM> with a sloping sidewall <NUM> can vary and it generally forms the perimeter <NUM> of the first face <NUM> and the second face <NUM>. In one embodiment, the perimeter <NUM> of the first face <NUM> and second face <NUM> is selected to be a geometric shape, and the first face <NUM> and the second face <NUM> are selected to have the same geometric shape, although, they differ in size with one face being larger than the other face. In one embodiment, the perimeter <NUM> of first face <NUM> and the perimeter <NUM> of the second face <NUM> was a triangular shape that is illustrated.

Referring to <FIG>, a draft angle α between the second face <NUM> and the sloping sidewall <NUM> of the shaped abrasive particle <NUM> can be varied to change the relative sizes of each face. In various embodiments of the invention, the draft angle α can be between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees. As discussed in <CIT>, specific ranges for the draft angle α have been found to produce surprising increases in the grinding performance of coated abrasive articles made from the shaped abrasive particles with a sloping sidewall.

Referring now to <FIG>, a coated abrasive article <NUM> is shown having a first major surface <NUM> of a backing <NUM> covered by an abrasive layer. The abrasive layer comprises a make coat <NUM>, and a plurality of shaped abrasive particles <NUM> with a sloping sidewall <NUM> attached to the backing <NUM> by the make coat <NUM>. A size coat <NUM> is applied to further attach or adhere the shaped abrasive particles <NUM> with a sloping sidewall <NUM> to the backing <NUM>.

As seen, the majority of the shaped abrasive particles <NUM> with a sloping sidewall <NUM> are tipped or leaning to one side. This results in the majority of the shaped abrasive particles <NUM> with a sloping sidewall <NUM> having an orientation angle β less than <NUM> degrees relative to the first major surface <NUM> of the backing <NUM>. As seen, once the shaped abrasive particles with a sloping sidewall are applied and allowed to lean onto the sloping sidewall, the very tips <NUM> of the shaped abrasive particles have generally the same height, h.

To further optimize the leaning orientation, the shaped abrasive particles with a sloping sidewall can be applied to the backing in an open coat abrasive layer. A closed coat abrasive layer in an electrostatic application system is the maximum weight of abrasive particles or a blend of abrasive particles that can be applied to a make coat of an abrasive article in a single pass through the maker. An open coat is an amount of abrasive particles or a blend of abrasive particles, weighing less than the maximum weight in grams that can be applied, that is applied to a make coat of a coated abrasive article. An open coat abrasive layer will result in less than <NUM>% coverage of the make coat with abrasive particles thereby leaving open areas and a visible resin layer between the particles.

It is believed that if too many of the shaped abrasive particles with a sloping sidewall are applied to the backing, insufficient spaces between the particles will be present to allow for them to lean or tip prior to curing the make and size coats. In various embodiments of the invention, greater than <NUM>, <NUM>, <NUM>, <NUM>, or <NUM> percent of the shaped abrasive particles in the coated abrasive article having an open or closed coat abrasive layer are tipped or leaning having an orientation angle β of less than <NUM> degrees. Precision aperture screens can be used to evenly space the shaped abrasive particles while still allowing for them to tip or lean at significantly higher abrasive particle densities in the abrasive layer that approach or equal closed coat densities.

Without wishing to be bound by theory, it is believed that an orientation angle β less than <NUM> degrees results in enhanced cutting performance of the shaped abrasive particles with a sloping sidewall. In various embodiments of the invention, the orientation angle β for at least a majority of the shaped abrasive particles with a sloping sidewall in an abrasive layer of a coated abrasive article can be between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees, or between about <NUM> degrees to about <NUM> degrees.

The shaped abrasive particles <NUM> with a sloping sidewall can have various volumetric aspect ratios. The volumetric aspect ratio is defined as the ratio of the maximum cross sectional area passing through the centroid of a volume divided by the minimum cross sectional area passing through the centroid. For some shapes, the maximum or minimum cross sectional area may be a plane tipped, angled, or tilted with respect to the external geometry of the shape. For example, a sphere would have a volumetric aspect ratio of <NUM> while a cube will have a volumetric aspect ratio of <NUM>. A shaped abrasive particle in the form of an equilateral triangle having each side equal to length A and a uniform thickness equal to A will have a volumetric aspect ratio of <NUM>, and if the uniform thickness is reduced to <NUM>. 25A, the volumetric aspect ratio is increased to <NUM>. It is believed that shaped abrasive particles having a larger volumetric aspect ratio have enhanced cutting performance. In various embodiments of the invention, the volumetric aspect ratio for the shaped abrasive particles with a sloping sidewall can be greater than about <NUM>, or greater than about <NUM>, or greater than about <NUM>, or between about <NUM> to about <NUM>, or between about <NUM> to about <NUM>, or between about <NUM> to about <NUM>.

Other suitable shaped abrasive particles are disclosed in <CIT>; <CIT>; <CIT>; <CIT> entitled "Dual tapered Shaped Abrasive Particles"; <CIT> entitled "Ceramic Shaped Abrasive Particles, Method Of Making The Same, And Abrasive Articles Containing The Same"; and <CIT> entitled "Intersecting Plate Shaped Abrasive Particles".

Materials that can be made into formed ceramic abrasive particles include physical precursors such as finely divided particles of known ceramic materials such as alpha alumina, silicon carbide, alumina/zirconia and boron carbide. Also included are chemical and/or morphological precursors such as aluminum trihydrate, boehmite, gamma alumina and other transitional aluminas and bauxite. The most useful of the above are typically based on alumina and its physical or chemical precursors. It is to be understood however that the invention is not so limited but is capable of being adapted for use with a plurality of different precursor ceramic materials.

Suitable methods for making formed ceramic abrasive particles are disclosed in: <CIT> entitled "Method Of Making Abrasive Shards, Shaped Abrasive Particles With An Opening, Or Dish-shaped Abrasive Particles"; <CIT> entitled Transfer Assisted Screen Printing Method Of Making Shaped Abrasive Particles And The Resulting Shaped Abrasive Particles; and in the patents referenced in the definition of formed ceramic abrasive particle.

Particles suitable for mixing with the shaped abrasive particles <NUM> with a sloping sidewall <NUM> include conventional abrasive grains, diluent grains, or erodable agglomerates, such as those described in <CIT> and <CIT>. Representative examples of conventional abrasive grains include fused aluminum oxide, silicon carbide, garnet, fused alumina zirconia, cubic boron nitride, diamond, and the like. Representative examples of diluent grains include marble, gypsum, and glass. Blends of differently shaped abrasive particles <NUM> with a sloping sidewall <NUM> (triangles and squares for example) or blends of shaped abrasive particles <NUM> with different draft angles (for example particles having an <NUM> degree draft angle mixed with particles having a <NUM> degree draft angle) can be used in abrasive articles.

The shaped abrasive particles <NUM> with a sloping sidewall <NUM> may also have a surface coating. Surface coatings are known to improve the adhesion between abrasive grains and the binder in abrasive articles or can be used to aid in electrostatic deposition of the shaped abrasive particles <NUM>. Such surface coatings are described in <CIT>; <CIT>; <CIT>; <CIT>; <CIT>; <CIT>; <CIT>; and <CIT>. Additionally, the surface coating may prevent the shaped abrasive particle from capping. Capping is the term to describe the phenomenon where metal particles from the workpiece being abraded become welded to the tops of the shaped abrasive particles. Surface coatings to perform the above functions are known to those of skill in the art. Coated Abrasive Article Having Z-Direction Rotationally Aligned Abrasive Particles.

Referring to <FIG>, a coated abrasive article <NUM> comprises a backing <NUM> having a first layer of binder, hereinafter referred to as the make coat <NUM>, applied over a first major surface <NUM> of backing <NUM>. Attached or partially embedded in the make coat <NUM> are a plurality of formed ceramic abrasive particles which, in one embodiment, comprises shaped abrasive particles <NUM> with a sloping sidewall <NUM> forming an abrasive layer. Over the shaped abrasive particles <NUM> with a sloping sidewall <NUM> is a second layer of binder, hereinafter referred to as the size coat <NUM>. The purpose of make coat <NUM> is to secure shaped abrasive particles <NUM> with the sloping sidewall <NUM> to backing <NUM> and the purpose of size coat <NUM> is to reinforce shaped abrasive particles <NUM> with a sloping sidewall <NUM>. The majority of the shaped abrasive particles <NUM> with a sloping sidewall <NUM> are oriented such that the tip <NUM> or vertex points away from the backing <NUM> and the shaped abrasive particles are resting on the sloping sidewall <NUM> and tipped or leaning as shown.

Each of the plurality of formed ceramic abrasive particles can have a specified z-direction rotational orientation about a z-axis passing through the formed ceramic abrasive particle and through the backing <NUM> at a <NUM> degree angle to the backing as shown in <FIG>. The formed abrasive particles are orientated with a surface feature, such as a substantially planar surface of the first face <NUM> or the second face <NUM>, rotated into a specified angular position about the z-axis. The specified z-direction rotational orientation in the coated abrasive article occurs more frequently than would occur by a random z-directional rotational orientation of the surface feature due to electrostatic coating or drop coating of the formed abrasive particles when forming the abrasive layer. As such, by controlling the z-direction rotational orientation of a significantly large number of the formed ceramic abrasive particles, the cut rate, finish, or both of the coated abrasive article can be varied from those manufactured using an electrostatic coating method. In various embodiments of the invention, at least <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, or <NUM> percent of the formed ceramic abrasive particles in the abrasive layer can have a specified z-direction rotational orientation which does not occur randomly and which can be substantially the same for all of the aligned particles. In other embodiments, about <NUM> percent of the formed ceramic abrasive particles can be aligned in a first direction and about <NUM> percent of the formed ceramic abrasive particles can be aligned in a second direction (<FIG>). In one embodiment, the first direction is substantially orthogonal to the second direction.

The surface feature is formed during the molding, extrusion, screen printing or other process that shapes the formed ceramic abrasive particle. Non-limiting surface features can include: a substantially planer surface; a substantially planar surface having a triangular, rectangular, hexagonal, or polygonal perimeter; a concave surface; a convex surface; a vertex; an aperture; a ridge; a line or a plurality of lines; a protrusion; or a depression. The surface feature is often chosen to change the cut rate, reduce wear of the formed abrasive particles, or change the resulting finish. Often, the surface feature will be an edge, a plane, or a point and the z-direction rotational orientation of that feature in the abrasive layer will be selected taking into consideration the motion of the abrasive layer, the motion of the work piece, and the angle of the abrasive layer relative to the workpiece surface during grinding.

Referring now to <FIG>, <FIG>, <FIG>; various patterns of the formed ceramic abrasive particles in the abrasive layer of coated abrasive discs, sheets, or belts are illustrated. The illustrations represent top views of the abrasive layer having a plurality of shaped abrasive particles as shown in <FIG>, B. For simplicity, each individual shaped abrasive particle is represented as a short line segment representative of the position of the base (sloping sidewall) of the shaped abrasive particle attached to the make coat. In the illustrations representative of a sheet or belt, a longitudinal axis <NUM> is drawn for reference. Arrows indicating the disc's or belt's direction of travel when placed onto grinding tool are additionally provided.

Referring now to <FIG>, the coated abrasive article can comprise a disc <NUM> or a sheet <NUM> or a belt <NUM>. In <FIG> the coated abrasive article is a disc and the specified z-direction rotational orientation positions the substantially planar surface <NUM> circumferentially and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of concentric circles. In <FIG>, the coated abrasive article is a sheet <NUM> or a belt <NUM> and the specified z-direction rotational orientation positions the substantially planar surface <NUM> at an angle of approximately <NUM> degrees to the longitudinal axis <NUM> of the belt or the sheet and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of parallel lines. Referring to <FIG>, the precision apertured screen <NUM> for precisely placing and rotationally aligning the formed abrasive particles when making the disc in <FIG> is shown.

Referring now to <FIG>, the coated abrasive article can comprise a disc <NUM> or a sheet <NUM> or a belt <NUM>. In <FIG> the coated abrasive article is a disc <NUM> and the specified z-direction rotational orientation positions the substantially planar surface <NUM> radically and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of concentric circles. In <FIG> the coated abrasive article comprises a sheet <NUM> or a belt <NUM> and the specified z-direction rotational orientation positions the substantially planar surface <NUM> at an angle of approximately <NUM> degrees to the longitudinal axis <NUM> of the belt or the sheet and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of parallel lines. Referring to <FIG>, the precision apertured screen <NUM> for precisely placing and rotationally aligning the formed abrasive particles when making the disc in <FIG> is shown.

Referring now to <FIG>, the coated abrasive article can comprise a disc <NUM> or a sheet <NUM> or a belt <NUM>. In <FIG> the coated abrasive article is a disc <NUM> and the specified z-direction rotational orientation positions the substantially planar surface <NUM> at an angle of approximately <NUM> degrees to a diameter <NUM> of the disc and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of parallel lines. In <FIG> the coated abrasive article is a sheet <NUM> or a belt <NUM> and the specified z-direction rotational orientation positions the substantially planar surface <NUM> at an angle of approximately <NUM> degrees to the longitudinal axis <NUM> of the belt or the sheet and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of parallel lines. Referring to <FIG>, the precision apertured screen <NUM> for precisely placing and rotationally aligning the formed abrasive particles when making the disc in <FIG> is shown. In other embodiments, the substantially planar surface can be positioned at any angle between <NUM> degrees and <NUM> degrees such as <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, and <NUM> degrees. Ranges of the foregoing angular rotations are possible by selecting any two of the listed values to create and an upper and a lower limit.

Referring now to <FIG>, the coated abrasive article can comprise a disc <NUM> or a sheet <NUM> or a belt <NUM>. In <FIG> the coated abrasive article is a disc <NUM> and the specified z-direction rotational orientation positions approximately <NUM> percent of the formed abrasive particles having the substantially planar surface <NUM> aligned at approximately <NUM> degrees and approximately <NUM> percent of the formed abrasive particles having the substantially planar surface <NUM> aligned at an angle of approximately <NUM> degrees and the pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of orthogonal lines. In <FIG> the coated abrasive article is a sheet <NUM> or a belt <NUM> and the specified z-direction rotational orientation positions approximately <NUM> percent of the formed abrasive particles having the substantially planar surface <NUM> aligned at approximately <NUM> degrees to the longitudinal axis <NUM> and approximately <NUM> percent of the formed abrasive particles having the substantially planar surface <NUM> aligned at an angle of approximately <NUM> degrees to the longitudinal axis <NUM> and a pattern created by the plurality of formed ceramic abrasive particles comprises a plurality of orthogonal lines. Referring to <FIG>, the precision apertured screen <NUM> for precisely placing and rotationally aligning the formed abrasive particles when making the disc in <FIG> is shown.

The make coat <NUM> and size coat <NUM> comprise a resinous adhesive. The resinous adhesive of the make coat <NUM> can be the same as or different from that of the size coat <NUM>. Examples of resinous adhesives that are suitable for these coats include phenolic resins, epoxy resins, urea-formaldehyde resins, acrylate resins, aminoplast resins, melamine resins, acrylated epoxy resins, urethane resins and combinations thereof. In addition to the resinous adhesive, the make coat <NUM> or size coat <NUM>, or both coats, may further comprise additives that are known in the art, such as, for example, fillers, grinding aids, wetting agents, surfactants, dyes, pigments, coupling agents, adhesion promoters, and combinations thereof. Examples of fillers include calcium carbonate, silica, talc, clay, calcium metasilicate, dolomite, aluminum sulfate and combinations thereof.

Suitable flexible backings include polymeric films, metal foils, woven fabrics, knitted fabrics, paper, vulcanized fiber, nonwovens, foams, screens, laminates, and combinations thereof. The coated abrasive article with a flexible backing may be in the form of sheets, discs, belts, pads, or rolls. In some embodiments, the backing should be sufficiently flexible to allow the coated abrasive article to be formed into a loop to make an abrasive belt that can be run on suitable grinding equipment.

A grinding aid can be applied to the coated abrasive article. A grinding aid is defined as particulate material, the addition of which has a significant effect on the chemical and physical processes of abrading, thereby resulting in improved performance. Grinding aids encompass a wide variety of different materials and can be inorganic or organic. Examples of chemical groups of grinding aids include waxes, organic halide compounds, halide salts, and metals and their alloys. The organic halide compounds will typically break down during abrading and release a halogen acid or a gaseous halide compound. Examples of such materials include chlorinated waxes, such as tetrachloronaphthalene, pentachloronaphthalene; and polyvinyl chloride. Examples of halide salts include sodium chloride, potassium cryolite, sodium cryolite, ammonium cryolite, potassium tetrafluoroborate, sodium tetrafluoroborate, silicon fluorides, potassium chloride, magnesium chloride. Examples of metals include tin, lead, bismuth, cobalt, antimony, cadmium, iron, and titanium. Other grinding aids include sulfur, organic sulfur compounds, graphite, and metallic sulfides. It is also within the scope of this invention to use a combination of different grinding aids; in some instances, this may produce a synergistic effect. In one embodiment, the grinding aid was cryolite or potassium tetrafluoroborate. The amount of such additives can be adjusted to give desired properties.

It is also within the scope of this invention to utilize a supersize coating over the size coating. The supersize coating typically contains a binder and a grinding aid. The binders can be formed from such materials as phenolic resins, acrylate resins, epoxy resins, urea-formaldehyde resins, melamine resins, urethane resins, and combinations thereof.

Various methods can be used to make the coated abrasive articles of the present disclosure. In one embodiment, not covered by the present invention, an electrostatic coating method can be employed as described in copending patent application having <CIT> entitled "Electrostatic Abrasive Particle Coating Apparatus and Method. " In this particular method, an electrostatically charged vibratory feeder can be used to propel formed abrasive particles off of a feeding surface towards a conductive member located behind the coated backing. In some embodiments, the feeding surface is substantially horizontal and the coated backing is traveling substantially vertically. It was surprisingly found that varying the gap between the feeding surface and the conductive member in contact with the backing changes the z-direction rotational orientation of formed abrasive particles comprising thin triangular plates from predominately cross machine direction aligned plates to predominately machine direction aligned plates as seen in <FIG> and <NUM> of the patent application.

A method of achieving z-direction rotational orientation of formed abrasive particles according to an embodiment of the present invention uses precision apertured screens that position the formed abrasive particle into a specific z-direction rotational orientation such that the formed abrasive particle can only fit into the precision apertured screen in a few specific orientations such as less than or equal to <NUM>, <NUM>, <NUM>, or <NUM> orientations. For example, a rectangular opening just slightly bigger than the cross section of a formed abrasive particle comprising a rectangular plate will orient the formed abrasive particle in one of two possible <NUM> degree opposed z-direction rotational orientations. The precision apertured screen can be designed such that the formed abrasive particles, while positioned in the screen's apertures, can rotate about their z-axis (normal to the screen's surface when the formed abrasive particles are positioned in the aperture) less than or equal to about <NUM>, <NUM>, <NUM>, <NUM>, <NUM>, or <NUM> angular degrees.

The precision apertured screen having a plurality of apertures selected to z-directionally orient formed abrasive particles into a pattern, can have a retaining member such as adhesive tape on a second precision apertured screen with a matching aperture pattern, an electrostatic field used to hold the particles in the first precision screen or a mechanical lock such as two precision apertured screens with matching aperture patterns twisted in opposite directions to pinch the particles within the apertures. The first precision aperture screen is filled with the formed abrasive particles, and the retaining member is used to hold the formed abrasive particles in place in the apertures. In one embodiment, adhesive tape on the surface of a second precision aperture screen aligned in a stack with the first precision aperture screen causes the formed abrasive particles to stay in the apertures of the first precision screen stuck to the surface of the tape exposed in the second precision aperture screen's apertures.

A coated backing having a make layer is positioned parallel to the first precision aperture screen surface containing the plurality of formed abrasive particles with the make layer facing the formed abrasive particles in the apertures. Thereafter, the coated backing and the first precision aperture screen are brought into contact to adhere the formed abrasive particles to the make layer. The retaining member is released such as removing the second precision aperture screen with taped surface, untwisting the two precision aperture screens, or eliminating the electrostatic field. Then the first precision aperture screen is then removed leaving the formed abrasive particles having a specified z-directional rotational orientation on the coated abrasive article for further conventional processing such as applying a size coat and curing the make and size coats.

Objects and advantages of this disclosure are further illustrated by the following non-limiting examples. The particular materials and amounts thereof recited in these examples as well as other conditions and details, should not be construed to unduly limit this disclosure. The following non SI-units and abbreviations are used:.

Shaped abrasive particles were prepared according to the disclosure of <CIT>. The shaped abrasive particles were prepared by molding alumina sol gel in equilateral triangle-shaped polypropylene mold cavities of side length <NUM> inch (<NUM>) and a mold depth of <NUM> inch (<NUM>). After drying and firing, the resulting shaped abrasive particles resembled <FIG> except the draft angle α was approximately <NUM> degrees. The fired shaped abrasive particles were about <NUM> (side length) x <NUM> thick and would pass through a <NUM>-mesh sieve.

Eight inch diameter by <NUM> mil thick (<NUM> x <NUM>) circular precision apertured metal screens were obtained from Fotofab Inc. , Chicago IL. The precision aperture screens were produced by photolithographic chemical etching. The individual apertures were etched from rectangular lithographic features. Due to the etching process, the actual features had rounded corners and the apertures were larger on the front and back surfaces than at the center of the sheet. The maximum surface dimension of each aperture was approximately <NUM> wide by <NUM> long. The dimension at the narrowest portion of each aperture was approximately <NUM> wide by <NUM> long.

Four different screen patterns were produced, each having the same density of apertures. The first screen, <FIG> (Example <NUM>), had concentric rings of apertures where the long dimension of each aperture was oriented radially with respect to the circular precision aperture screen. The second screen, <FIG> (Example <NUM>), had concentric rings of apertures where the long dimension of each aperture was oriented circumferentially with respect to the circular precision aperture screen. In the third screen, <FIG> (Example <NUM>), the apertures were in concentric rings with the apertures oriented at an angle halfway between the first two screens, i.e. with a <NUM> degree offset from either the radial or the circumferential orientation. The fourth screen, <FIG> (Example <NUM>), was made with apertures on a rectangular array with a repeat pattern altering vertical and horizontal apertures in each row with succeeding rows offset relative to each other such that each horizontal aperture is surrounded by four vertical apertures and each vertical aperture is surrounded by four horizontal apertures excepting at the screen's outer circular edge where the pattern may be cut off.

In order to properly restrain and orient the shaped abrasive particles in the screen apertures, it was necessary to stack two precision aperture screens on top of each other with all of the apertures aligned. The two identical precision aperture screens were held in alignment and secured with small tabs of foil tape at the screen's edges. One face of one screen of the indexed screen stack was then covered with masking tape ("SCOTCH <NUM>+", <NUM><NUM>/<NUM> inch width, <NUM> Co. St Paul, MN). The indexed screen stack was now ready to receive shaped abrasive particles.

The dimensions of the shaped abrasive particles were such that only the vertex of a triangular plate would fit into the screen aperture, and only when it was oriented parallel to the long axis of the aperture can the vertex of the shaped abrasive particle contact the adhesive surface of the tape at the bottom of the aperture on the bottom screen.

A quantity of the shaped abrasive particles was applied to the surface of the indexed screen stack opposite the tape covered bottom screen surface and the indexed screen stack was gently tapped from the bottom. The indexed apertures were soon filled with shaped abrasive particles held vertex down and base up and oriented in the direction of the aperture's long dimension. Additional shaped abrasive particles were applied in this manner until greater than <NUM> percent of the apertures contained shaped abrasive particles that were secured by the exposed masking tape adhesive at their apexes.

A make resin was prepared by mixing <NUM> parts epoxy resin ("HELOXY <NUM>", Hexion Specialty Chemicals, Houston, TX), <NUM> parts acrylate monomer("TMPTA", UCB Radcure, Savannah, GA) and adding <NUM> parts photoinitiator ("IRGACURE <NUM>", Ciba Specialty Chemicals, Hawthorne, NY) with heating until the photoinitiator was dissolved. <NUM> parts resole phenolic resin (based-catalyzed condensate from <NUM>:<NUM> to <NUM>:<NUM> molar ratio of phenol : formaldehyde), <NUM> parts calcium carbonate (HUBERCARB, Huber Engineered Materials, Quincy, IL) and <NUM> parts water were added with mixing. <NUM> grams of this mixture was then applied via a brush to a <NUM> in (<NUM>) diameter x <NUM> thick vulcanized fiber web ("DYNOS Vulcanized Fibre", DYNOS GmbH, Troisdorf, Germany) having a <NUM> in (<NUM>) center hole. The coated abrasive disc was then passed under a UV lamp at <NUM> ft/min (<NUM>/min) to gel the coating.

The foil tape tabs connecting the two precision aperture screens were removed from the shaped abrasive particle filled indexed screen stack. The shaped abrasive particles themselves in the apertures were sufficient to index the two screens. The make resin-coated fiber disc was placed make resin side up on a flat surface. The shaped abrasive particle filled indexed screen stack was centered on the fiber disc and the mineral-loaded face was placed in contact with the make resin. While holding the assembly stationary, the top precision aperture screen having the taped surface was carefully separated from the bottom precision aperture screen containing the shaped abrasive particles, releasing the shaped abrasive particles. The bottom precision aperture screen was then carefully lifted from the make resin surface of the fiber disc. This resulted in the shaped abrasive particles being transferred to make resin with their vertexes up while largely maintaining the z-direction rotational orientation established by the screen's apertures. The weight of the shaped abrasive particles transferred to each disc was <NUM> grams. The make resin was thermally cured (<NUM> degrees C for <NUM> minutes followed by <NUM> degrees C for <NUM> hours). Each disc was then coated with a conventional cryolite-containing phenolic size resin and cured (<NUM> degrees C for <NUM> minutes followed by <NUM> hours at <NUM> degrees C).

The finished coated abrasive discs were allowed to equilibrate at ambient humidity for a week followed by <NUM> days at <NUM>% RH before testing.

Comparative Example A was prepared identically to Examples <NUM>-<NUM> except that the shaped abrasive particles were applied via electrostatic coating and were therefore had a random z-direction rotational orientation.

The grinding performance of the various discs was evaluated by grinding <NUM> mild carbon steel using the following procedure. Seven inch (<NUM>) diameter abrasive discs for evaluation were attached to a rotary grinder fitted with a <NUM>-inch (<NUM>) smooth disc pad face plate ("<NUM> Hard Black" obtained from <NUM> Company, St. Paul, Minnesota). The grinder was then activated and urged against an end face of a <NUM> x <NUM> in (<NUM> x <NUM>) pre-weighed <NUM> steel bar under a load of <NUM> lb (<NUM>). The resulting rotational speed of the grinder under this load and against this workpiece was <NUM> rpm. The workpiece was abraded under these conditions for <NUM>-second grinding intervals (passes). Following each <NUM>-second interval, the workpiece was allowed to cool to room temperature and weighed to determine the cut of the abrasive operation. Test results were reported as the incremental cut for each interval and the total cut removed. The test end point was determined when the cut fell below <NUM>% of the initial cut value. The test was repeated for all Examples at an <NUM>-lb (<NUM>) load. If desired, the testing can be automated using suitable equipment.

Test results are shown in Table <NUM>. <FIG> plots the cut results for various Example disks and the e-coated Control disc under a <NUM> lb load and <FIG> plots the cut results for various Example disks and the e-coated Control discs under the <NUM> pound load. As seen, varying the z-direction rotational orientation of the substantially planar surface significantly affected the cut rate of the various Example discs.

In Example <NUM>, apertured screens were used to control the vertex up orientation of triangular shaped abrasive particles in screen coated abrasive discs and compared to electrostatically coated (e-coated) Control abrasive discs for total cut on stainless steel. The weight of the triangular shaped abrasive particles placed into the apertured screen was varied and compared to e-coated control discs of the triangular shaped abrasive particles of various weights. In this example a simple <NUM> mesh woven wire sieve screen was used to align the triangular shaped abrasive particles in the proper vertex up orientation. The triangular shaped particles were prepared by shaping alumina sol gel from equilateral, triangular-shaped polypropylene mold cavities of side length <NUM> mils, a mold depth of <NUM> mils, and a <NUM> degree draft angle. After drying and firing, the resulting triangular shaped abrasive particles had a side length of about <NUM>" (<NUM>), a thickness of about <NUM>" (<NUM>), and a -<NUM>+<NUM> mesh sieve size.

For these screen coated abrasive discs, the rotational alignment of the triangular shaped abrasive particles was not controlled, and the screen's apertures allowed for a random z-direction rotational orientation. However, the apertured screens assured that approximately <NUM> percent of the triangular shaped abrasive grain in the abrasive layer had its vertex pointing away from the backing. As the percent closed coat density is increased for the e-coated samples, more and more of the triangular shaped abrasive particles become attached in the abrasive layer by their vertex thereby presenting a horizontal surface to the workpiece to be abraded. As seen in <FIG>, the screen coated discs had significantly higher cut at percent closed coat densities greater than <NUM> percent. In various embodiments of the invention, screen coated discs can have a percent closed coat density from about <NUM> to about <NUM> percent, or from about <NUM> to about <NUM> percent. At these densities, significantly more shaped abrasive particles comprising triangular plates are attached to the make layer by the triangle's base with the vertex pointing away from the make layer significantly enhancing the total cut of the coated abrasive article.

Claim 1:
A method of making a coated abrasive article (<NUM>), comprising:
filling a plurality of formed abrasive particles (<NUM>) into a plurality of apertures of a first precision apertured screen to position the formed abrasive particles into a specified z-direction rotational orientation,
positioning a coated backing (<NUM>) having a make layer (<NUM>) parallel to the first precision apertured screen surface containing the plurality of formed abrasive particles with the make layer facing the formed abrasive particles in the apertures;
bringing the coated backing into contact with the formed abrasive particles in the first precision apertured screen to adhere the formed abrasive particles to the make layer; and
removing the first precision apertured screen, thereby leaving the formed abrasive particles having the specified z-direction rotational orientation on the coated backing,
wherein the specified z-direction rotational orientation of each of the plurality of formed ceramic abrasive particles is about a z-axis passing through the formed ceramic abrasive particle and through the backing at a <NUM> degree angle to the backing.