Patent Description:
Cleaning products are well-known and play an important role in everyday life. Such products will contain surfactant and, if disinfection is desired, usually also a disinfecting agent like for example chlorine bleach, quaternary ammonium compound, e.g., benzalkonium chloride, or chloroxylenol. Such conventional disinfecting agents seems to be effective on wide range of microbes, however, it is reported that such agents may affect one's health.

Traditionally a distinction is made between personal hygiene, i.e., how one takes care of one's own body; and home care including laundry and household care, the latter including the cleaning of hard surfaces like toilets, floors and kitchen tops.

More and more consumers prefer cleaning products with a good environmental profile. That is, they prefer products that are 'eco-friendly' and have less or no impact on the environment when the product is used. There is thus a growing need for cleaning products that mainly or only contain natural and/or biodegradable ingredients. It is also desired that the products are formulated avoiding disinfecting agents, such as chlorine bleach, quaternary ammonium compound, e.g., benzalkonium chloride, or chloroxylenol etc., yet provide disinfection benefit.

Organic acids like citric acid and lactic acid are natural alternatives for synthetic disinfectants like chlorine bleach, benzalkonium chloride and chloroxylenol. These organic acids show antibacterial action, but on their own may not display a broad-spectrum antibacterial action, i.e. act against both gram-negative bacteria (e.g. E. coli and P. aeruginosa) and gram-positive bacteria (e.g. S. aureus and E. Bacteria like E. hirae are known to be more difficult to combat. Also, antiviral action may be limited in efficacy and/or breadth, e.g. only against enveloped virus and not against non-enveloped virus. Non-enveloped viruses are known to be more difficult to combat.

In this regard, <CIT> discloses an acidic hard surface composition which provides cleaning and disinfecting benefit comprising an acidic constituent, which comprises water soluble organic acid, at least one anionic surfactant constituent, at least one non-ionic surfactant, at least one organic solvent constituent, optionally one or more further constituents and balance water. The composition exhibits surprising efficacy against various gram positive and gram-negative type pathogenic bacteria, as well as against fungi in the absence of known cationic quaternary ammonium compounds known to be effective against pathogenic bacteria, as well as other known-art antimicrobial constituents and bleach are excluded.

In view of the above, there remains a need for cleaning compositions with a good environmental profile without compromising consumer satisfaction in terms of performance and disinfection efficacy against bacteria and/or viruses.

We have found that specific combinations of organic acid, anionic surfactant and nonionic surfactant allow for the use of organic acid as a natural disinfecting agent whilst the cleaning composition shows broad spectrum antibacterial efficacy. We have also found that said compositions have antiviral properties.

Accordingly, in a first aspect the invention relates to an aqueous cleaning composition a defined in claim <NUM> comprising:.

The invention further relates to a method of cleaning a surface comprising the step of contacting the surface with the composition according to present invention in neat or dilute form for at least <NUM> seconds.

The invention also relates to the use of a composition of the present invention for incapacitating germs on a surface.

The invention also relates to the use of a composition of the present invention for incapacitating viruses on a surface.

Any feature of one aspect of the present invention may be utilized in any other aspect of the invention. The word "comprising" is intended to mean "including" but not necessarily "consisting of" or "composed of. " In other words, the listed steps or options need not be exhaustive. Except in the operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about". Numerical ranges expressed in the format "from x to y" are understood to include x and y. When for a specific feature multiple preferred ranges are described in the format "x to y", it is understood that all ranges combining the different endpoints are also contemplated. Unless specified otherwise, amounts as used herein are expressed in percentage by weight based on total weight of the composition and is abbreviated as "wt%". The use of any and all examples or exemplary language e.g. "such as" provided herein is intended merely to better illuminate the invention and does not in any way limit the scope of the invention otherwise claimed. Room temperature is defined as a temperature of about <NUM> degrees Celsius.

The cleaning composition of the present invention is an aqueous cleaning composition, that is to say, the composition comprises water. The amount of water will depend on the desired concentration of the other ingredients but will at least be <NUM> wt%, like for example at least <NUM> wt% or at least <NUM> wt%, but typically not more than <NUM> wt%. The amount of water preferably is from <NUM> to <NUM> wt%, more preferably <NUM> to <NUM> wt% and even more preferably <NUM> to <NUM> wt%.

The composition is liquid, that is, it can be poured, and has viscosity at <NUM> of <NUM> to <NUM> mPa. s @ <NUM>-<NUM>. The viscosity is measured using an AR <NUM> Rheometer (TA instruments) using a <NUM>, <NUM>° cone-plate geometry @ <NUM>-<NUM> and <NUM>. Depending on the required use characteristics the composition may be more or less viscous. For example, a more water thin viscosity is desired if the composition is to be used in a trigger spray bottle. If dispensed from a squeeze bottle, a more viscous consistency may be desired. A more viscous viscosity may also be desired if the cleaning product is a toilet cleaning product. Preferably the composition has a viscosity of <NUM> to <NUM> mPa. s @ <NUM>-<NUM> and more preferably of <NUM> to <NUM> mPa. s @ <NUM>-<NUM>. The desired viscosity can suitably be obtained by known methods like for example the use of a viscosity modifying agent.

The composition of the present invention comprises <NUM> to <NUM> wt% anionic surfactant. The anionic surfactant is a sulphate-based surfactant. Preferred anionic surfactants are alkyl ether sulphates of Formula I and alkyl sulphates of Formula II.

Formula I:     (R<NUM>-(OR')n-O-SO<NUM>-)xMx+,.

Preferably, the surfactant of Formula I is sodium lauryl ether sulphate having <NUM> to <NUM> ethylene oxide units per molecule, more preferably, sodium lauryl ether sulphate having <NUM> to <NUM> ethylene oxide units per molecule.

Formula II:     (R<NUM>-O-SO<NUM>-)xMx+,.

Preferably the surfactant of Formula II is sodium lauryl sulphate. Suitable examples include alkyl sulphates from synthetic origin with trade names Safol <NUM>, Dobanol 23A or <NUM>, Lial <NUM>, Alfol <NUM>, Empicol LC3, Empicol 075SR. Further suitable examples, and preferred, include alkyl sulphates commercially available from natural sources with trade names Galaxy <NUM>, Galaxy <NUM>, Galaxy <NUM>, Galaxy <NUM> SP.

Preferably the anionic surfactant is selected from alkyl sulphates, alkyl ether sulphates and combinations thereof.

The composition preferably comprises <NUM> to <NUM> wt% anionic surfactant, more preferably <NUM> to <NUM> wt% and even more preferably <NUM> to <NUM> wt%.

The composition of the present invention comprises <NUM> to <NUM> wt% nonionic surfactant selected from alcohol ethoxylates, short chain alkyl poly glycosides and combinations thereof.

The alcohol ethoxylate has from <NUM> to <NUM> EO. Suitable alcohol ethoxylate surfactants include the condensation products of a higher alcohol (e.g. an alkanol containing about <NUM> to <NUM> carbon atoms in a straight or branched chain configuration) condensed with about <NUM> to <NUM> moles of ethylene oxide, for example, lauryl or myristyl alcohol condensed with about <NUM> moles of ethylene oxide (EO), tridecanol condensed with about <NUM> moles of EO, myristyl alcohol condensed with about <NUM> moles of EO per mole of myristyl alcohol, the condensation product of EO with a cut of coconut fatty alcohol containing a mixture of fatty alcohols with alkyl chains varying from <NUM> to about <NUM> carbon atoms in length and wherein the condensate contains either about <NUM> moles of EO per mole of total alcohol or about <NUM> moles of EO per mole of alcohol and tallow alcohol ethoxylates containing <NUM> EO to <NUM> EO per mole of alcohol. Preferably the alcohol ethoxylate has from <NUM> to <NUM> EO, more preferably <NUM> to <NUM> EO and even more preferably <NUM> EO. Particularly preferred is Lauryl alcohol condensed with <NUM>, <NUM> and <NUM> moles of ethylene oxide (Laureth <NUM>, Laureth <NUM> and Laureth <NUM>). Preferably, the alcohol ethoxylate surfactant is selected from Laureth <NUM>, Laureth <NUM> and Laureth <NUM>, or mixtures thereof.

The nonionic surfactant selected may be such that it comprises a mixture of fatty alcohols e.g. a mixture of C12, C13, C14 and C15 in varying proportions along with <NUM> to <NUM> ethoxylate groups. Such nonionic surfactants are commercially available under NEODOLTM series from Shell. For example, NEODOLTM <NUM>-<NUM> which is a mixture of C9, C10 and C11 with <NUM> EO; NEODOLTM <NUM>-<NUM> which is a mixture of C9, C10 and C11 with <NUM> EO; NEODOLTM <NUM>-<NUM> which is a mixture of C9, C10, and C11 with <NUM> EO; NEODOLTM <NUM>-<NUM> which is a mixture of C12 and C13 with <NUM> EO; NEODOLTM <NUM>-<NUM> which is a mixture of C12, C13, C14 and C15 with <NUM> EO; NEODOLTM <NUM>-<NUM> which is a mixture of C12, C13, C14 and C15 with <NUM> EO; and NEODOLTM <NUM>-<NUM> which is a mixture of C14 and C15 with <NUM> EO. Particularly preferred nonionic surfactant is a mixture of C12, C13, C14 and C15 with <NUM> EO.

Preferably the nonionic surfactant comprises alcohol ethoxylate surfactant. As alcohol ethoxylates provide for especially beneficial for antibacterial efficacy in compositions of the present invent it is especially preferred that the nonionic surfactant is alcohol ethoxylate surfactant.

As used herein alkyl polyglycosides are compounds having the formula R<NUM>O(R<NUM>O)b(Z)a, wherein R<NUM> is a alkyl radical, having from about <NUM> to about <NUM> carbon atoms; R<NUM> is an alkylene radical having from <NUM> to <NUM> carbon atoms; Z is a saccharide residue having <NUM> or <NUM> carbon atoms; b is a number having a value from <NUM> to about <NUM>; and a is a number having a value from <NUM> to about <NUM> (the degree of polymerization). Due to the method by which they are synthesized, alkyl polyglycosides are generally present as mixtures of alkyl polyglycosides having varying amounts of carbon atoms in the alkyl radical and varying degrees of polymerization. Thus, when referring to alkyl polyglycosides, the alkyl radical is generally referred to as having a range of carbon atoms (e.g. C8/<NUM> referring to a range of alkyl radicals having from <NUM>-<NUM> carbon atoms) and the degree of polymerization is generally referred to as the average degree of polymerization of the mixture.

Preferably the alkyl poly glycosides is an alkyl polyglucoside surfactant.

Prefered alkyl polyglycosides suitable for use in the disclosed cleaning formulation include those having the formula I wherein Z is a glucose residue, b is zero, R<NUM> is an alkyl group that contains <NUM> to <NUM> carbon atoms, and the average value of a is about <NUM>-<NUM>. Such alkyl polyglucosides are commercially available, for example, as Glucopon® branded alkyl polyglucoside compositions from BASF (formerly Cognis Corporation), including Glucopon® 215CS UP and <NUM> DK.

The composition preferably comprises <NUM> to <NUM> wt% nonionic surfactant, more preferably <NUM> to <NUM> wt% and even more preferably <NUM> to <NUM> wt%.

Preferably the weight ratio of anionic to nonionic surfactant is from <NUM>:<NUM> to <NUM>:<NUM>, more preferably from <NUM>:<NUM> to <NUM>:<NUM>, and even more preferably from <NUM>:<NUM> to <NUM>:<NUM>.

The composition comprises <NUM> to <NUM> wt% organic acid. The organic acid is used a natural disinfecting agent and together with the anionic surfactant and nonionic surfactant present in the composition of the present invention provides for broad spectrum antibacterial efficacy.

The organic acid is selected from , lactic acid (pKa = <NUM>), acetic acid (pKa = <NUM>), malonic acid (pKa = <NUM>), adipic acid (pKa = <NUM>), glutaric acid (pKa = <NUM>), glycolic acid (pKa = <NUM>), maleic acid (pKa = <NUM>), succinic acid (pKa = <NUM>), malic acid (pKa = <NUM>), tartaric acid (for L+ pKa = <NUM>; and for meso pKa = <NUM>), hexanoic acid (pKa = <NUM>), cyclohexanoic acid (pKa = <NUM>), heptanoic acid (pKa = <NUM>), octanoic acid (pKa = <NUM>), <NUM>-methyl octanoic acid (pKa = <NUM>), nonanoic acid (pKa = <NUM>), decanoic acid (pKa = <NUM>), benzoic acid (pKa = <NUM>), <NUM>-methoxy benzoic acid (pKa = <NUM>), and combinations thereof.

More preferably, the organic acid is selected from lactic acid, glycolic acid and mixtures thereof. Even more preferably, the organic acid is selected from lactic acid, glycolic acid and mixtures thereof. Most preferably, the organic acid selected is glycolic acid.

Preferably the amount of organic acid in the composition is from <NUM> to <NUM> wt%, more preferably <NUM> to <NUM> wt%.

Preferably the weight ratio of surfactant to organic acid is from <NUM>:<NUM> to <NUM>:<NUM>, preferably from <NUM>:<NUM> to <NUM>:<NUM>, and more preferably from <NUM>:<NUM> to <NUM>:<NUM>.

The composition has a pH in the range from <NUM> to <NUM>, preferably from <NUM> to <NUM>, even more preferably from <NUM> to <NUM>. The pH of the composition may be adjusted using suitable pH adjusting agents e.g., hydrochloric acid and sodium hydroxide.

To achieve the desired viscosity, the cleaning composition may comprise <NUM> to <NUM> wt% water soluble rheology modifying polymer. Rheology modifying polymers are known and their ability to impart viscosity to a composition may, in part, depend on the presence or absence of other ingredients.

Water soluble polymers can be used to thicken the composition which includes non-ionic, cationic and amphoteric polymers. Suitable polymers include hydroxy ethyl cellulose, modified hydroxy ethyl cellulose, guar gum, gum tragacanth, xanthan gum, gum arabic, gum acacia, Jaguar® C13S, Jaguar® C14S, Jaguar® C17, Jaguar® HP <NUM> (hydroxy propyl guar), Jaguar® HP <NUM> (hydroxylated propylated guar), Jaguar® S (Native guar gum), Carbopol® Aqua CC, Merquat™ <NUM>, Merquat™ <NUM>, Merquat™ <NUM> and Merquat™ <NUM> from Lubrizol, poly ethylene glycols such as Polyox™ WSR- <NUM> (PEG <NUM>), Polyox™ WSR N-<NUM> (PEG <NUM>), and Polyox™ WSR-<NUM> (PEG <NUM>), and hydrophobically modified hydroxyethyl celluloses like PolySurf™ <NUM> CS, i.e. cetyl hydroxyethylcellulose.

The cleaning composition of the present invention may comprise <NUM> to <NUM> wt% sequestrant. Preferably the amount of sequestrant is <NUM> to <NUM> wt%, preferably <NUM> to <NUM> wt%. The sequestrant has a binding capacity of at least <NUM> Ca/g, preferably at least <NUM> Ca/g and more preferably at least <NUM> Ca/g.

Typical values are mentioned in the table below.

Suitable sequestrants are those based on organophosphonates, aminopolycarboxylates and carboxylic acids. It will be understood that suitable sequestrants include both the acid form and salts thereof.

Examples of sequestrants based on organophosphonates include diethylenetriamine penta(methylene phosphonic acid) (DTPMP), hydroxyethylidenediphosphonic acid (HEDP), and nitrilotrimethylenephosphonic acid (NTMP).

Examples of sequestrants based on aminopolycarboxylates include ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA), and L-Glutamic acid N,N diacetic acid (GLDA).

Examples of sequestrants based on carboxylic acids include gluconic acid and itaconic acid.

Preferably the sequestrant is biodegradable. Preferred biodegradable sequestrants are nitrilotriacetic acid (NTA), ethylenediaminedisuccinic acid, (EDDS), iminodisuccinic acid, (IDS), methylglycine diacetic acid, (MGDA), L-Glutamic acid N,Ndiacetic acid (GLDA), <NUM>-hydroxyethyliminodiacetic acid (HEIDA), ethylenediamine-N,N'-dimalonic acid (EDDM), ethylenediamine-N,N'-diglutaric acid (EDDG), <NUM>-hydroxy-<NUM>,<NUM>-iminodisuccinic acid (HIDS), and <NUM>,<NUM>-pyridine dicarboxylic acid (PDA), gluconic acid and itaconic acid.

The composition according to the present invention is free of organic solvent. The term free of organic solvent herein refers to the composition comprising less than <NUM> wt%, more preferably less than <NUM> wt% and most preferably less than <NUM> wt% of organic solvent.

Preferably the cleaning composition comprises from <NUM> to <NUM> wt% solvent having a flash point of up to <NUM>, more preferably up to <NUM> and even more preferably up to <NUM>. An example of such a solvent is isopropyl alcohol having a flash point of <NUM>, ethanol having flash point <NUM>. More preferably the composition is free of solvent having a flash point of up to <NUM>, more preferably up to <NUM> and even more preferably up to <NUM>.

At least part of the ingredients of the cleaning composition, calculated on total product excluding water and inorganic materials, is biodegradable. To be truly biodegradable, a substance or material should break down into carbon dioxide (a nutrient for plants) and water. Naturally occurring minerals that do not cause harm to the ecosystem are already in their natural mineral state and do not need to biodegrade.

Preferably at least <NUM> wt%, more preferably at least <NUM> wt% and still more preferably at least <NUM> wt% of the ingredients is biodegradable. Preferably at least <NUM> wt% is biodegradable and even more preferably essentially all ingredients are biodegradable.

For the purpose of the invention the term 'biodegradable' refers to `Inherently and Ultimately biodegradable' as per the OECD <NUM> guidelines/tests. Preferably the term 'biodegradable' refers to 'Readily and Ultimately biodegradable' as per the OECD <NUM> series or <NUM> guidelines/tests.

Preferably at least part of the organic ingredients of the cleaning composition, calculated on total product excluding water, is natural. For the purpose of this invention, natural is defined as the ingredient comprising at least <NUM> wt% plant derived, i.e. from a natural source, material; preferably at least <NUM> wt%, more preferably at least <NUM> wt% and still more preferably at least <NUM> wt%. Preferably at least <NUM> wt% is plant derived and even more preferably essentially all of a natural ingredient is plant derived.

Preferably at least <NUM> wt%, more preferably at least <NUM> wt% and still more preferably at least <NUM> wt% of the organic ingredients is natural. Preferably at least <NUM> wt% is natural and even more preferably essentially all organic ingredients are natural.

Preferably the composition of the present invention is free of quaternary ammonium compounds.

ABS is not readily available from renewable carbon or biorenewable carbon sources. Therefore, the cleaning composition of the present composition is free of alkylbenzene sulphonates and derivatives thereof.

Alkylbenzene sulphonates (ABS) and derivatives thereof include water-soluble alkali metal salts of organic sulphonates having alkyl radicals typically containing from about <NUM> to about <NUM> carbon atoms, preferably <NUM> to <NUM> carbon atoms, still more preferably <NUM> to <NUM> carbon atoms and may be saturated or unsaturated. Examples include sodium salt of linear alkylbenzene sulphonate, alkyl toluene sulphonate, alkyl xylene sulphonate, alkyl phenol sulphonate, alkyl naphthalene-sulphonate, ammonium diamylnaphthalene-sulphonate and sodium dinonylnaphthalene-sulphonate and mixtures with olefin sulphonates.

Preferably the composition of the present invention is free of any sulphonated surfactant.

The invention also relates to a method of cleaning a surface comprising the steps of.

Typically, the surface is contacted with the cleaning composition between <NUM> seconds and <NUM> minutes. Preferably between <NUM> seconds and <NUM> minutes, more preferably <NUM> to <NUM> minutes and even more preferably <NUM> to <NUM> minutes. A typical contact time for hand washing is at least <NUM> seconds.

The surface may be any surface suitable for cleaning including human skin like e.g. hands, and household hard surfaces like e.g. utensils or kitchenware, floors, toilets, bathroom surfaces and kitchen surfaces.

Preferably the surface is a household care hard surface and more preferably the surface is a toilet surface.

Cleaning of a toilet surface is preferably done with a neat solution that has a more viscous consistency like for example <NUM> to <NUM> mPa. s @ <NUM>-<NUM>. The contact time is usually longer and typically varies between <NUM> seconds and <NUM> minutes after which the toilet surface is rinsed with water.

Typically, the composition of the invention is applied onto a hard surface in neat or diluted form. The composition may be applied by any known method such as by using a cleaning implement, such as scrub, sponge paper, cloth, wipes or any other direct or indirect application. The applied composition may be cleaned using a cleaning implement such as a scrub, sponge, paper, cloth or wipes with or without water, or rinsed off with water, optionally running water.

Preferably the surface is human skin. For handwashing, typically an amount of neat cleaning composition with a small amount of water is used to wash the skin surface of the hands such that foam is generated and the cleaning composition is in contact with the skin for at least <NUM> seconds, preferably at least <NUM> seconds. A typical dilution rate is <NUM> to <NUM> %, preferably <NUM> to <NUM>% like for example <NUM>%. The cleaning composition including foam is then rinsed of with water and the hands are dried e.g., by using an air blower or paper cloth or towel.

Antibacterial efficacy of a compound can be determined using several protocols, with EN1279 and EN13697 being among the most used. EN1279 is a so-called suspension test and EN13697 is a so-called surface test. For household hard surfaces, EN13697 is a better indicator. We have found that some known cleaning compositions do not always show the desired antibacterial efficacy when tested according to EN <NUM>.

The invention also relates to the use of a composition according to the present invention for incapacitating germs on a surface. The specific combination of anionic surfactant, nonionic surfactant and organic acid allows for broad antibacterial efficacy without the need for synthetic disinfecting agents.

The invention also relates to the use of a composition according to the present invention for incapacitating viruses on a surface. The specific combination of anionic surfactant, nonionic surfactant and organic acid allows for antiviral efficacy without the need for synthetic disinfecting agents. This specific combination is effective against both enveloped and non-enveloped viruses. Preferably the virus includes non-enveloped virus, like for example COVID-<NUM> (or Sars-Cov-<NUM>).

For the purpose of the invention 'incapacitating' is defined as including killing, interrupting growth and limiting the ability to infect an animal. Preferably 'incapacitating' is defined as killing.

The invention will now be illustrated by means of the following non-limiting examples.

Germ removal efficacy of the composition along with a control composition shown in table <NUM> below were carried out using EN13697 or EN <NUM> protocol for estimating antimicrobial efficacy. Soil conditions clean were created with <NUM>% Bovine Serum Albumin (BSA); and dirty conditions were created by using <NUM>% BSA with a contact time of <NUM>.

The following organisms used were as test organisms:.

Differential media was used for enumerating the test organisms (to eliminate the growth of Bacillus along with the test organism).

From a <NUM> hours old plate culture (not more than <NUM> passages), a saline suspension of the above-mentioned test organisms is made. The optical density of the saline suspension is adjusted at <NUM> to obtain <NUM><NUM> cells/ mL. All glycerol stocks of bacteria were maintained at - <NUM>; and were revived just before the carrying out the experiments.

Compositions were tested neat (i.e., undiluted) or diluted. Dilution is indicated by times of dilution. For example, 200x dilution means that to <NUM> of cleaning composition water is added to a total volume of <NUM>.

This was performed for all test organisms for all test products at the highest test concentration that was tested. Dilution neutralization method used was as follows:.

All plating was carried out on sterile tryptic soy agar (TAS) plates. The plates were incubated <NUM> for <NUM> to <NUM> hours; and results were recorded.

Log reduction is calculated as difference of log of culture control in test mixture from log of count obtained in test mixture.

To show the effect of non-ionic surfactant, formulations according to Tables 1A and 1B were prepared. Anti-bacterial efficacy was tested as indicated and the results are shown.

To show the effect of different types of non-ionic surfactant, formulations according to Tables <NUM> and <NUM> were prepared. Anti-bacterial efficacy was tested as indicated and the results are shown.

To show the effect of different types of organic acids, formulations according to Table <NUM> were prepared. It is noted that formulation <NUM> comprising citric acid is not according to the invention. Anti-bacterial efficacy was tested as indicated and the results are shown.

To show the effect of different pH, formulations according to Table <NUM> were prepared. Anti-bacterial efficacy was tested as indicated and the results are shown.

A diluted formulation according to Table <NUM> was prepared. Anti-bacterial efficacy was tested as indicated and the results are shown.

To test anti-virus efficacy the composition as in Table <NUM> was used in standard protocol EN14476 under clean condition.

Claim 1:
Aqueous cleaning composition comprising:
a. <NUM> to <NUM> wt% anionic surfactant selected from alkyl sulphates, alkyl ether sulphates and combinations thereof;
b. <NUM> to <NUM> wt% nonionic surfactant selected from alcohol ethoxylates, short chain alkyl poly glycosides and combinations thereof; and
c. <NUM> to <NUM> wt% organic acid selected from lactic acid, acetic acid, malonic acid, adipic acid, glutaric acid, glycolic acid, maleic acid, succinic acid, malic acid, tartaric acid, hexanoic acid, cyclohexanoic acid, heptanoic acid, octanoic acid, <NUM>-methyl octanoic acid, nonanoic acid, decanoic acid, benzoic acid, <NUM>-methoxy benzoic acid and mixtures thereof;
wherein the composition has a pH of <NUM> to <NUM>;
wherein the alcohol ethoxylate has from <NUM> to <NUM> EO; and
wherein the alkyl poly glycoside has alkyl groups from C8 to C10,
wherein the composition is free of organic solvent, wherein free of organic solvent means that the composition comprises less than <NUM> wt% of organic solvent.