Patent Description:
A coke oven with multiple carbonization chambers charges coal using a charging car and then heats the coal at a temperature of approximately <NUM> or higher while blocking external air for about <NUM> hours, and produces gray-white coke from which volatile components contained in the coal are removed, which is a kind of coal-drying operation. Furthermore, coke that has been retorted is discharged from the carbonization chamber using an extruder, and is transported to a fire quenching tower and quenched.

Meanwhile, although not illustrated in separate drawings, the COG described above is generated by thermal decomposition during a retorting process of the coal charged in the carbonization chamber, and the COG is transported to a purification facility (e.g., a chemical by-product plant) through a lifting tube provided at an upper portion of each carbonization chamber.

The COG contains acidic gases such as hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN), and when the COG is burned, hydrogen sulfide (H<NUM>S) is converted into sulfur dioxide (SO<NUM>), and hydrogen cyanide (HCN) is converted into nitrogen oxide (NOx), which may cause ultrafine dust. Thus, before the COG transported to the chemical by-product plant is burned, tar, hydrogen sulfide, and hydrogen cyanide need to be removed through a purification process. However, as environmental regulations are increasingly strengthened, quality improvement of COG is desired. Accordingly, as a method for improving the absorption efficiency of an H<NUM>S scrubber that removes hydrogen sulfide and hydrogen cyanide of the COG in the chemical by-product plant, a method for additionally installing the H<NUM>S scrubber and using sodium hydroxide (NaOH) compounds, ammonia (NH<NUM>) compounds, or amine compounds is used.

Furthermore, <CIT> discloses a constitution in which ammonia liquor used in an H<NUM>S scrubber is transported to an ammonia regeneration tower to separate and refine hydrogen sulfide from the ammonia liquor, and then the sulfide is recirculated back to the H<NUM>S scrubber.

<CIT> discloses a process for removing H2S from concentrated ammonia liquor by contacting with iron sulfate and precipitating iron sulfide.

Accordingly, a method for removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) contained in concentrated ammonia liquor which is an absorption liquid supplied to an H<NUM>S scrubber in a relatively simple process may be expected to be useful in related fields.

An aspect of the present disclosure is to provide a method for removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) contained in concentrated ammonia liquor using an iron oxide catalyst.

According to an aspect of the present disclosure, a method for removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) contained in concentrated ammonia liquor includes: a catalyst treatment step of bringing concentrated ammonia liquor containing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) into contact with an iron oxide catalyst; and a regeneration step of regenerating the iron oxide catalyst by supplying a regeneration liquid to the iron oxide catalyst.

According to an aspect of the present disclosure, by simultaneously removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) contained in concentrated ammonia liquor, the absorption efficiency of hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) of coke oven gas (COG) may be improved when the concentrated ammonia liquor is used in an H<NUM>S scrubber (H2S/S).

Hereinafter, a preferred embodiment of the present disclosure will be described. However, embodiments of the present disclosure may be modified in several different forms, and the scope of the present disclosure is not limited to the embodiments described below.

The present disclosure which targets concentrated ammonia liquor used in an H<NUM>S scrubber (H<NUM>S/S) in a process of treating COG generated in a coke oven, relates to a method for reducing a concentration of the concentrated ammonia liquor by removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) dissolved in the concentrated ammonia liquor. In the present disclosure, concentrated ammonia liquor refers to an absorbent solution supplied to the H<NUM>S scrubber (H<NUM>S/S) to absorb hydrogen sulfide and hydrogen cyanide contained in the COG, and generally, it is an aqueous solution including NH<NUM>, H<NUM>S, CO<NUM>, HCN, and BTX (i.e., benzene, toluene and xylene), and has a pH of <NUM> to <NUM>.

More specifically, the method therefor includes a catalyst treatment step of bringing concentrated ammonia liquor containing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) into contact with an iron oxide catalyst; and a regeneration step of regenerating the iron oxide catalyst by supplying a regeneration liquid to the iron oxide catalyst.

The concentrated ammonia liquor used for purification of the COG is used to absorb hydrogen sulfide and hydrogen cyanide contained in the COG. Thus, absorption efficiency of hydrogen sulfide and hydrogen cyanide from the COG may be improved using the concentrated ammonia liquor of which the concentration is reduced by removing hydrogen sulfide and hydrogen cyanide, in the H<NUM>S scrubber (H<NUM>S/S).

Hydrogen sulfide and hydrogen cyanide may be removed from the concentrated ammonia liquor through the catalyst treatment step of brining the concentrated ammonia liquor in contact with the iron oxide catalyst. Iron oxide that may be used at this time may be selected from the group consisting of iron oxide (FeO), triiron tetraoxide (Fe<NUM>O<NUM>), hematite (Fe<NUM>O<NUM>) and iron hydroxide (Fe(OH)<NUM>, Fe(OH)<NUM>), and, preferably, the hematite (Fe<NUM>O<NUM>) and the iron hydroxide (Fe(OH)<NUM>) may be used.

The contact step is not particularly limited, but may be performed by, for example, spraying the concentrated ammonia liquor to an iron oxide catalyst or immersing the iron oxide catalyst in the concentrated ammonia liquor, but a contact method thereof is not particularly limited. For example, when the concentrated ammonia liquor is sprayed, the concentrated ammonia liquor and the iron oxide catalysts may be effectively brought into contact with each other, thereby increasing the efficiency of removing hydrogen sulfide and hydrogen cyanide from the concentrated ammonia liquor.

A particulate phase may be used as the iron oxide catalyst. Specifically, since the catalyst may be mixed with solid sulfur generated in the catalyst treatment step, the particulate phase other than powder may be used to separate the solid sulfur in the regeneration step and easily regenerate the catalyst. Particles with an average particle diameter of, preferably, <NUM> to <NUM> may be used, and particles with an average particle diameter of, most preferably, <NUM> to <NUM> may be used, but the particles are not limited thereto and may be used without limitation as long as they have a size that may be easily separated from the solid sulfur in the regeneration step and be easy to regenerate the catalyst.

Meanwhile, the catalyst treatment step may be performed by supplying air, oxygen, or combinations thereof to the iron oxide catalyst. The air, oxygen, or combinations thereof may be supplied to the iron oxide catalyst in the same direction as a flow direction of the concentrated ammonia liquor when the concentrated ammonia liquor and the iron oxide catalyst come into contact with each other, and an activity of the iron oxide catalyst may be restored when the activity thereof is reduced by removing hydrogen sulfide and hydrogen cyanide contained in the concentrated ammonia liquor. For example, when the concentrated ammonia liquor is sprayed on the iron oxide catalyst, air may be supplied in the same direction as an injection direction of the concentrated ammonia liquor, and in this case, oxygen in the air may restore the activity of the iron oxide catalyst, and may be supplied in an appropriate amount depending on an amount of concentrated ammonia liquor to be treated, the concentrations of hydrogen sulfide and hydrogen cyanide contained in the concentrated ammonia liquor.

For example, when the air, oxygen, or combinations thereof is supplied to the iron oxide catalyst with a regeneration liquid during the catalyst treatment step, the following reaction occurs.

<NUM><NUM>S + Fe<NUM>O<NUM> → Fe<NUM>S<NUM> + <NUM><NUM>O.

<NUM><NUM>S + 2Fe(OH)<NUM> → Fe<NUM>S<NUM> + <NUM><NUM>O.

2Fe<NUM>S<NUM> + 3O<NUM> → 2Fe<NUM>O<NUM> + <NUM><NUM>.

SCN- + 2O<NUM> + <NUM><NUM>O → SO<NUM><NUM>- + CO<NUM> + NH<NUM>+.

That is, the solid sulfur of S<NUM> to S<NUM> produced when hydrogen sulfide (H<NUM>S) comes into contact with the iron oxide catalyst and reacts therewith serves to remove hydrogen cyanide (HCN) by reacting with the hydrogen cyanide (HCN). Thus, hydrogen sulfide and hydrogen cyanide may be removed together.

Then, carbon dioxide generated during the reaction process is released in the form of a gas, and ammonium ions and sulfate ions are present as ions in the concentrated ammonia liquor.

The iron oxide catalyst is used in an amount of, preferably, <NUM> to <NUM> based on <NUM> of the concentrated ammonia liquor, and in an amount of, more preferably, <NUM> to <NUM>. When a weight of the iron oxide catalyst is less than <NUM>, the removal efficiency may be reduced due to an insufficient effect of the catalyst, and when the weight thereof exceeds <NUM>, an additional increase effect of the removal efficiency may be insignificant, which may be uneconomical.

In the present disclosure, the concentration of hydrogen sulfide contained in the concentrated ammonia liquor may be reduced to <NUM>% to <NUM>% and the concentration of hydrogen cyanide may be reduced to <NUM>% to <NUM>% through the catalyst treatment step of bringing the concentrated ammonia liquor into contact with the iron oxide catalyst.

Meanwhile, the present disclosure includes a regeneration step in which the concentrated ammonia liquor is brought into contact with the iron oxide catalyst and then a catalyst is regenerated by supplying a regeneration liquid to the iron oxide catalyst.

The regeneration step may be performed using an oxidative regeneration liquid, and in this case, the following reaction may occur.

2Fe<NUM>S<NUM> + <NUM><NUM>O<NUM> → 2Fe<NUM>O<NUM> + <NUM><NUM>O + <NUM><NUM>.

2Fe<NUM>S<NUM> + <NUM><NUM>O<NUM> → 4Fe(OH)<NUM> + <NUM><NUM>.

2Fe<NUM>S<NUM> + 6ClO- → 2Fe<NUM>O<NUM> + 6Cl- + <NUM><NUM>.

2Fe<NUM>S<NUM> + 3ClO<NUM>- → 2Fe<NUM>O<NUM> + 3Cl- + <NUM><NUM>.

Furthermore, the regeneration liquid may serve to wash away solid sulfur generated on a catalyst surface.

The regeneration liquid may be at least one oxidation regeneration liquid selected from the group consisting of water, ozone water, chlorine dioxide water, H<NUM>O<NUM>, NaOCl, NaClO<NUM>, NaClO<NUM>, NaClO<NUM>, KMnO<NUM>, and HNO<NUM>.

In the regeneration step, at least one oxidizing gas selected from the group consisting of air, oxygen, ozone, and ClO<NUM> gases may be supplied to the iron oxide catalyst together with the regeneration liquid, and preferably, oxygen may be supplied.

2Fe<NUM>S<NUM> + 3O<NUM> + <NUM><NUM>O → 4Fe(OH)<NUM> + <NUM><NUM>.

As in the reaction described above, the oxidizing gas is supplied to the iron oxide catalyst together with the regeneration liquid to separate small particles such as solid sulfur from the iron oxide catalyst.

A catalyst regenerated through the regeneration step may have a catalytic efficiency of <NUM>% or more, as compared to a new catalyst. In consideration of the time and costs required for the catalyst regeneration step, a regenerated catalyst may be regenerated so that the regenerated catalyst has a catalytic efficiency of <NUM>% to <NUM>%, as compared to the new catalyst. The iron oxide catalyst may be used semipermanently through the regeneration step, thereby reducing costs.

In the present disclosure, a recovery step of recovering concentrated ammonia liquor obtained from the catalyst treatment step may be further included.

The recovery step may include a solid-liquid separation process, and for example, in the recovery step, only the concentrated ammonia liquor may be recovered through solid-liquid separation by a decanting process by a specific gravity difference or centrifugation in order to additionally remove solid sulfur particles, but the present disclosure is not limited thereto.

Hereinafter, the present disclosure will be described in more detail with reference to specific embodiments. The following embodiments are merely examples for better understanding of the present disclosure, and the scope of the present disclosure is not limited thereto.

<NUM> of concentrated ammonia liquor at room temperature (<NUM>) in which <NUM>/L of hydrogen sulfide (H<NUM>S) and <NUM>/L of hydrogen cyanide (HCN) were dissolved was sprayed and injected into a reactor filled with <NUM> of particulate hematite (Fe<NUM>O<NUM>) catalyst having an average particle diameter of <NUM>. At the same time, air was circulated inside the catalytic reactor. Afterwards, the concentrated ammonia liquor that passed through the iron oxide catalyst was recovered, and the concentration of hydrogen sulfide contained in the recovered concentrated ammonia liquor was calculated by ion chromatography, and the concentration of hydrogen cyanide was analyzed by a continuous flow method, and the results thereof are illustrated in <FIG>.

As illustrated in <FIG>, hydrogen sulfide contained in the concentrated ammonia liquor was reduced to <NUM>/L, and hydrogen cyanide contained therein was reduced to <NUM>/L.

After regenerating a catalyst while using distilled water as a regeneration liquid and injecting air, in order to compare the catalytic efficiency of the regenerated catalyst and a new catalyst, the same method as that of Example <NUM> was performed except for using the regenerated catalyst or the new catalyst, and then, the concentration change of hydrogen sulfide contained in the concentrated ammonia liquor was measured over time and results thereof is illustrated in <FIG>.

As illustrated in <FIG>, when the regenerated catalyst and the new catalyst react for the same time, after <NUM> minutes, the concentration of hydrogen sulfide decreased from <NUM>/L to <NUM>/L for the new catalyst, and the concentration of hydrogen sulfide decreased from <NUM>/L to <NUM>/L for the regenerated catalyst. Accordingly, the efficiency of removing hydrogen sulfide from the new catalyst was measured to be about <NUM>%, and the efficiency of removing the regenerated catalyst was measured to be about <NUM>%. Since the regenerated catalyst shows a hydrogen sulfide removal efficiency of <NUM>% as compared to the new catalyst, it was confirmed that the catalyst may be used semipermanently by regenerating the catalyst.

Claim 1:
A method for removing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) from concentrated ammonia liquor, the method comprising:
a catalyst treatment step of bringing concentrated ammonia liquor containing hydrogen sulfide (H<NUM>S) and hydrogen cyanide (HCN) into contact with an iron oxide catalyst; and
a regeneration step of regenerating the iron oxide catalyst by supplying a regeneration liquid to the iron oxide catalyst.