Patent Description:
In recent years, breakthrough has been made in the development of organic light-emitting diode (OLED) devices. In order to improve stability and service life of the OLED device, it is usually necessary to encapsulate the OLED device with an encapsulation structure to isolate the OLED device from the outside environment. At present, the OLED device encapsulating methods mainly include plastic encapsulating and thin film encapsulation. According to different encapsulating materials, the thin film encapsulation (TFE) can be divided into inorganic thin film encapsulation, organic thin film encapsulation, and inorganic/organic composite thin film encapsulation.

The encapsulation structure formed by using TFE generally includes an inorganic film layer. In TFE, silicon nitride (SiNx) is generally used as a material, and a plasma enhanced chemical vapor deposition (PECVD) process is used to encapsulate the OLED. An inorganic film layer is formed as the outer layer of the device. However, the inorganic film layer is prone to cracks, and accordingly, the encapsulation performance of the encapsulation structure is poor. Document "<CIT>" discussed that the substrate for a device that collects or emits radiation which comprises a transparent polymer layer and a barrier layer on at least one face of the polymer layer. The barrier layer consists of an antireflection multilayer of at least two thin transparent layers having both alternately lower and higher refractive indices and alternately lower and higher densities, wherein each thin layer of the constituent multilayer of the barrier layer is an oxide, nitride or oxynitride layer. Document "<CIT>" discussed a display device which includes a substrate including a display area configured to display an image and a peripheral area surrounding the display area. The display device also includes a plurality of signal lines provided in the display area, an encapsulation layer provided over the signal lines and a pad portion provided in the peripheral area. The display device further includes a plurality of connection wires connecting the signal lines and the pad portion, wherein each of the connection wires includes a first portion provided in the peripheral area and a second portion provided in the display area. A portion of the encapsulation layer provided on the display area extends to the peripheral area and placed over the first portions of the connection wires. Document "<CIT>" discussed an organic light-emitting diode (OLED) display, an electronic device including the same and a method of manufacturing the OLED display. In one aspect, the OLED display includes a first plastic layer, a first barrier layer formed over the first plastic layer and a first intermediate layer formed over the first barrier layer. The OLED display also includes a second plastic layer formed over the first intermediate layer, a second intermediate layer formed over the second plastic layer and a second barrier layer formed over the second intermediate layer. The OLED display further includes an OLED layer formed over the second barrier layer and a thin-film encapsulation layer encapsulating the OLED layer. Document "<CIT>" discussed a substrate section for a flexible display device. The substrate section prevents adhesion loss between a reinforcing layer and a barrier layer, thereby preventing a peel-off phenomenon between an inorganic barrier layer and a reinforcing layer. Document "<CIT>" discussed an LED device capable of correcting a luminous color even with a structure obtained with simple additional processing.

Document <CIT> discloses a method comprising, forming an organic light-emitting device (OLED) on a substrate; forming a first encapsulation layer, which has a first thin-film density and contains a first inorganic material, on the substrate; and forming a second encapsulation layer, which has a second thin-film density higher than the first thin-film density and contains a second inorganic material, on the first encapsulation layer.

The LED device includes an LED die that is flip-chip mounted on a submount substrate, an encapsulation resin that covers a surrounding of the LED die, and a top face of the submount substrate. The encapsulation resin contains a fluorescent body, on an upper part thereof in which a diffusion layer exists. The diffusion layer is formed by implanting a diffusion material by a sand blast method. A luminous color of the LED device is adjusted according to a degree of diffusion of the diffusion layer.

The scope of the present invention is determined only by the scope of the appended claims.

In a first aspect, the present invention provides an encapsulating method according to claim <NUM> and further detailed in the dependent claims referring back to this claim.

The subject matter which is regarded as the disclosure is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other objects, features, and advantages of the disclosure are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:.

The present disclosure will be described in further detail with reference to the accompanying drawings and embodiments in order to provide a better understanding by those skilled in the art of the technical solutions of the present disclosure. Throughout the description of the disclosure, reference is made to <FIG>. When referring to the figures, like structures and elements shown throughout are indicated with like reference numerals.

In the description of the specification, references made to the term "one embodiment," "some embodiments," "exemplary embodiments," "example," "specific example," "some examples" and the like are intended to refer that specific features and structures, materials or characteristics described in connection with the embodiment or example that are included in at least one embodiment or example of the present disclosure. The schematic expression of the terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be included in any suitable manner in any one or more embodiments or examples.

In order to improve the stability and service life of the OLED device, it is usually necessary to encapsulate the OLED device with an encapsulation structure. <FIG> shows a schematic diagram of an encapsulation structure <NUM> provided in the prior art. As shown in <FIG>, the OLED device <NUM> is disposed on a base substrate <NUM>, and the encapsulation structure <NUM> includes an inorganic film layer <NUM> disposed outside the OLED device <NUM>. The inorganic film layer <NUM> can be formed by a PECVD process using SiNx, and the inorganic film layer <NUM> has a certain water-blocking property, which can isolate the OLED device <NUM> from the outside air. However, the inorganic film layer <NUM> is prone to cracks, so that the encapsulation structure <NUM> has poor encapsulating performance.

The encapsulation structure provided by the embodiments of the present disclosure can reduce the probability of occurrence of cracks in the inorganic film layer and improve the encapsulation performance of the encapsulation structure. A detailed description of the encapsulation structure, the encapsulating method, and the display apparatus provided by the embodiments of the present disclosure is provided below.

<FIG> shows a schematic diagram of an encapsulation structure <NUM> provided according to one embodiment of the present disclosure. As shown in <FIG>, the encapsulation structure <NUM> includes an inorganic film layer <NUM> coated on an external surface of the structure to be encapsulated <NUM>, and the inorganic film layer <NUM> includes at least two sub-film layers. Among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than densification of the sub-film layer closer to the structure to be encapsulated. In one embodiment, as shown in <FIG>, the at least two sub-film layers may be sub-film layer <NUM> to sub-film layer 031n, where n is an integer greater than or equal to <NUM>. The sub-film layers are sequentially disposed farther away from the structure to be encapsulated <NUM> from the sub-film layer <NUM> to the sub-film layer 031n. Therefore, the sub-film layer <NUM> is denser than the sub-film layer <NUM>, the sub-film layer <NUM> is denser than the sub-film layer <NUM>, and so on. The sub-film layer 031n is denser than the sub-film layer <NUM>(n-<NUM>). Furthermore, as shown in <FIG>, the structure to be encapsulated <NUM> is disposed on the base substrate <NUM>.

In the encapsulation structure provided in the embodiment of the present disclosure, since the inorganic film layer includes at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated among the at least two sub-film layers. Therefore, the probability of occurrence of cracks in the inorganic film layer can be reduced, and the problem of poor encapsulation performance of the encapsulation structure can be solved. As a result, the encapsulation performance of the encapsulation structure can be improved.

In one embodiment, among the at least two sub-film layers, the densification of each sub-film layer may be characterized by a refractive index of each sub-film layer, and the densification of each sub-film layer is positively correlated to the refractive index of each sub-film layer. Alternatively, among the at least two sub-film layers, the densification of each sub-film layer may be characterized by a corrosion rate of each sub-film layer, and the densification of each sub-film layer is inversely correlated to the corrosion rate of each sub-film layer. Alternatively, among the at least two sub-film layers, the densification of each sub-film layer may be characterized by the refractive index of each sub-film layer and the corrosion rate of each sub-film layer. The densification of each sub-film layer is positively correlated to the refractive index of each sub-film layer. The density of each sub-film layer is inversely correlated to the corrosion rate of each sub-film layer. Of course, in addition, the densification of the sub-film layer may also be characterized by other physical parameters of the sub-film layer.

In one embodiment, the densification of the at least two sub-film layers of the inorganic film layer <NUM> increases in a gradient from the sub-film layer near the structure to be encapsulated <NUM> to the sub-film layer away from the structure to be encapsulated <NUM>, thereby achieving stepwise increase in the densification of the inorganic film layers <NUM>. That is, the densification of the at least two sub-film layers of the inorganic film layer <NUM> increases by equal gradients from the sub-film layer closer to the structure to be encapsulated <NUM> to the sub-film layer farther away from the structure to be encapsulated <NUM>. For example, the densification of the sub-film layer <NUM> to the sub-film layer 031n increases by an equal gradient.

In one embodiment, as shown in <FIG>, the surface of each of the at least two sub-film layers of the inorganic film layer <NUM> has a rugged microstructure. In other words, the surface of each of the at least two sub-film layers of the inorganic film layer <NUM> is rough. In one embodiment, the surface roughness of each sub-film layer ranges from <NUM> to <NUM>. The surface roughness of each of the at least two sub-film layers of the inorganic film layer <NUM> may be equal or not equal, but the surface roughness of any sub-film layer may range from <NUM> to <NUM>. For example, in one embodiment, the surface roughness of the sub-film layer <NUM> is <NUM>, the surface roughness of the sub-film layer <NUM> is <NUM>, the surface roughness of the sub-film layer <NUM> is <NUM>, and the surface roughness of the sub-film layer 031n is <NUM> or the like. The microstructure can scatter light, so that the surface of the sub-film layer is uneven and the light can be scattered on the surface of the sub-film layer. When a light emitting body is encapsulated by the encapsulation structure <NUM>, the surface of the sub-film layer is a rugged microstructure that can improve the light extraction efficiency of the encapsulation structure <NUM> and facilitate light extraction. The light emitting body may be an unencapsulated OLED apparatus, and the surface of the sub-film layer is uneven and the microstructure is favorable to the apparatus of the top emission structure, which is a structure in which light is emitted from a side of the unencapsulated OLED apparatus away from the substrate.

<FIG> shows a schematic diagram of an encapsulation structure <NUM> provided according to one embodiment of the present disclosure. As shown in <FIG>, the at least two sub-film layers of the inorganic film layer <NUM> are three sub-film layers. The three sub-film layers are sub-film layer <NUM>, sub-film layer <NUM>, and sub-film layer <NUM> arranged in this order away from the structure to be encapsulated <NUM>.

The encapsulation structure <NUM> shown in <FIG> and <FIG> may be an inorganic thin film encapsulation structure. The encapsulation structure <NUM> provided in the embodiment of the present disclosure may also be an inorganic/organic composite film encapsulation structure. The inorganic/organic composite film encapsulation structure may be as shown in <FIG>.

<FIG> shows a schematic diagram of an encapsulation structure <NUM> provided according to one embodiment of the present disclosure. In one embodiment, as shown in <FIG>, the encapsulation structure <NUM> includes an inorganic film layer <NUM> and an organic film layer <NUM> alternately superimposed on an external surface of the structure to be encapsulated <NUM>. The structure of any two inorganic film layers <NUM> may be the same, and the structure of each inorganic film layer <NUM> can be as shown in <FIG> or <FIG>. In the embodiment of the present disclosure, the sub-film layers of the inorganic film layer <NUM> are not drawn in <FIG> for the convenience of drawing.

In the embodiments of the present disclosure, the structure to be encapsulated <NUM> may be an unencapsulated electroluminescent apparatus. The electroluminescent apparatus may be an OLED display apparatus or an OLED lighting apparatus. In addition, the structure to be encapsulated may also be a quantum dot light emitting diode (QLED) display apparatus or a QLED lighting apparatus. The base substrate <NUM> may include a display area and a non-display area, and a display apparatus such as an OLED display apparatus may be disposed on the display area of the base substrate <NUM>. The base substrate <NUM> may be a transparent substrate, which may be a substrate made of light-guiding non-metallic materials with certain sturdiness such as glass, quartz, and transparent resin. In addition, a flexible substrate (not shown in <FIG>) may be generally disposed on the base substrate <NUM>, and the display apparatus may be disposed on the flexible substrate. After the encapsulation structure <NUM> is formed, the base substrate <NUM> can be peeled off from the flexible substrate, and the flexible substrate can be used for flexible display. The flexible substrate may be a flexible substrate formed using polyimide (PI). The inorganic film layer <NUM> may be made of SiNx or SiON (silicon oxynitride), and the inorganic film layer <NUM> may be formed by a PECVD process. SiNx is typically produced by a PECVD process from silicon hydride (SiH<NUM>), ammonia (NH<NUM>) and hydrogen (H<NUM>). SiON is usually produced by a PECVD process from SiH<NUM>, NH<NUM>, H<NUM> and nitrous oxide (N<NUM>O). The organic film layer <NUM> may be formed using an ink jet printing process or a coating process.

In one embodiment, the encapsulation structure <NUM> may further include a cover plate (not shown in <FIG>) disposed outside the encapsulation film layer farthest away from the structure to be encapsulated <NUM>. The encapsulation film farthest away from the structure to be encapsulated <NUM> may be an inorganic film layer or an organic film layer. The cover plate may be a light-transmitting, non-metallic, transparent substrate such as glass, quartz, transparent resin, etc., or may be a flexible substrate formed using PI, which is not limited in this embodiment of the present disclosure.

In the encapsulation structures provided in the embodiments of the present disclosure, since the inorganic film layer includes at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated among the at least two sub-film layers. Therefore, the probability of occurrence of cracks in the inorganic film layer can be reduced, and the problem of poor encapsulation performance of the encapsulation structure can be solved. As such, the encapsulation performance of the encapsulation structure can be improved.

In the embodiments of the present disclosure, the inorganic film layer adopts a layered structure, which can reduce the risk of stress increase of the inorganic film layer while improving densification.

The encapsulation structure provided by the embodiment of the present disclosure may be produced using the following method. The encapsulating method and the encapsulation principle of the embodiment of the present disclosure can be referred to the description in the following embodiments.

An embodiment of the present disclosure further provides an encapsulating method. The encapsulating method can be used to encapsulate a structure to be encapsulated and form an encapsulation structure. In one embodiment, the encapsulating method includes the following:.

An inorganic film layer covering the structure to be encapsulated is formed on the outside of the structure to be encapsulated, and the inorganic film layer includes at least two sub-film layers. Among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated.

In one embodiment, among the at least two sub-film layers, the densification of each sub-film layer is characterized by a refractive index of each sub-film layer, and the densification of each sub-film layer is positively correlated to the refractive index of each sub-layer.

In one embodiment, among the at least two sub-film layers, the densification of each sub-film layer is characterized by a corrosion rate of each sub-film layer, and the densification of each sub-film layer is negatively correlated to the corrosion rate of each sub-film layer.

In one embodiment, an inorganic film layer is formed outside the structure to be encapsulated, and the inorganic film layer includes at least two sub-film layers. Among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated. The method includes forming the at least two sub-film layers sequentially on the outside of the structure to be encapsulated by using a plasma mixture, wherein an amount of a preset gas in the plasma mixture forming the sub-film layer farther away from the structure to be encapsulated is greater than an amount of the preset gas in the plasma mixture forming the sub-film layer closer to the structure to be encapsulated. As such, the inorganic film layer is obtained.

In one embodiment, the amount of the preset gas in the plasma mixtures increases at a gradient in accordance with the formation sequence of the at least two sub-layers.

In one embodiment, the amount of the preset gas in the plasma mixtures increases at a gradient x of <NUM>%*A in the order of formation of the at least two sub-film layers. The term "A" denotes the amount of the preset gas in the plasma mixture forming the sub-film layer closest to the structure to be encapsulated among the at least two sub-film layers.

In one embodiment, the plasma mixture is a mixed gas of silicon hydride, ammonia, and hydrogen, and the preset gas is hydrogen.

In one embodiment, the ratio of silicon hydride, ammonia, and hydrogen in the plasma mixture that forms the closest sub-film layer to the structure to be encapsulated among the at least two sub-film layers is in the range of [<NUM>, <NUM>] : [<NUM>, <NUM>] : [<NUM> , <NUM>].

In one embodiment, the encapsulating method further includes roughening the surface of each of the at least two sub-film layers. Roughening the surface of each of the at least two sub-film layers may include bombarding the surface of each of the at least two sub-film layers with a preset plasma to roughen the surface of each of the at least two sub-film layers. In one embodiment, the preset plasma is argon plasma.

In one embodiment, the surface roughness of each of the at least two sub-film layers ranges from <NUM> to <NUM>.

In one embodiment, the encapsulating method further includes forming an organic film layer covering the inorganic film layer.

All of the foregoing optional technical solutions may be combined randomly to form alternative embodiments of the present disclosure, and will not be repeated here.

In the encapsulating method provided in the embodiment of the present disclosure, since the inorganic film layer includes at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated among the at least two sub-film layers. Therefore, the probability of occurrence of cracks in the inorganic film layer can be reduced, and the problem of poor encapsulation performance of the encapsulation structure can be solved. As such, the encapsulation performance of the encapsulation structure can be improved.

<FIG> shows a flowchart of an encapsulating method provided by an embodiment of the present disclosure. The encapsulating method can be used to encapsulate a structure to be encapsulated to form an encapsulation structure. The encapsulation structure may be the encapsulation structure shown in any one of <FIG>. As shown in <FIG>, the encapsulating method includes the following:.

In step <NUM>, an inorganic film layer covering an external surface of the structure to be encapsulated is formed. The inorganic film layer includes at least two sub-film layers. Among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated.

As shown in each of <FIG>, the structure to be encapsulated <NUM> is disposed on the base substrate <NUM>, and the inorganic film layer <NUM> that covers the structure to be encapsulated <NUM> is formed outside the structure to be encapsulated <NUM>. That is, the inorganic film layer <NUM> is formed on the base substrate <NUM> having the structure to be encapsulated <NUM> formed thereon. The inorganic film layer <NUM> covers the outside of the structure to be encapsulated <NUM>, and the inorganic film layer <NUM> includes at least two sub-film layers. Among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated <NUM> is greater than the densification of the sub-film layer closer to the structure to be encapsulated <NUM>.

In one embodiment, as shown in <FIG>, the inorganic film layer <NUM> includes n sub-film layers of sub-layer <NUM> to sub-layer 031n. The densification of the sub-film layer <NUM> is greater than the densification of the sub-film layer <NUM>, the densification of the sub-film layer <NUM> is greater than the densification of the sub-film layer <NUM>, and so on.

In another embodiment, as shown in <FIG>, the inorganic film layer <NUM> includes three sub-film layers of sub-film layer <NUM>, sub-film layer <NUM>, and sub-film layer <NUM>. The densification of the sub-layer <NUM> is greater than that of the sub-layer <NUM>, and the densification of the sub-layer <NUM> is greater than that of the sub-layer <NUM>. In the embodiments of the present disclosure, the densification of the sub-film layer may be characterized by a refractive index, and the densification of each sub-film layer is positively correlated to the refractive index of each sub-film layer. That is, for a certain sub-film layer, the higher the refractive index of the sub-film layer, the higher the densification of the sub-film layer. Alternatively, the densification of the sub-film layers can be characterized by the corrosion rate, and the densification of the sub-film layers is inversely correlated to the corrosion rates of the sub-film layers respectively. That is, the lower the corrosion rate of the sub-film layer, the higher the densification of the sub-film layer. Alternatively, the densification of the sub-film layer can be characterized by the refractive index and the corrosion rate, which are not limited in the embodiment of the present disclosure.

<FIG> shows a flowchart of a method of forming an inorganic film layer <NUM> covering the structure to be encapsulated <NUM> on the outside of the structure to be encapsulated <NUM> according to an embodiment of the present disclosure. As shown in <FIG>, the method includes the following:.

In sub-step <NUM>, at least two sub-film layers are formed on the outside of the structure to be encapsulated using a plasma mixture. The amount of the preset gas in the plasma mixture forming the sub-film layer farther away from the structure to be encapsulated is greater than the amount of the preset gas in the plasma mixture forming the sub-film layer closer to the structure to be encapsulated.

In the embodiment of the present disclosure, when forming the at least two sub-film layers, a sub-film layer closer to the structure to be encapsulated is formed first, and then a sub-film layer farther away from the structure to be encapsulated is formed. Therefore, the amount of the preset gas in the plasma mixture can be increased in sequence according to the formation order of the at least two sub-film layers, so that the densification of the at least two sub-film layers can be sequentially increased. In one embodiment, in order to increase the densities of the at least two sub-film layers at a gradient, the amount of the preset gas in the plasma mixtures may increase at a gradient according to the order of formation of the at least two sub-film layers. In one embodiment, the amount of the preset gas in the plasma mixtures can be increased by equal gradients according to the order of the formation of the at least two sub-layers so that the densities of the at least two sub-film layers increase by equal gradients. In one embodiment, in order to make the densities of any two neighboring sub-film layers less different, the amount of the preset gas in the plasma mixture may increase by a gradient of x=<NUM>% *A in accordance with the formation sequence of at least two sub-film layers. The term "A" is the amount of a preset gas in the plasma mixture forming the sub-layer film closest to the structure to be encapsulated among the at least two sub-film layers.

In the embodiments of the present disclosure, the material for forming each of the at least two sub-film layers may be SiNx or SiON.

When the material for forming each of the at least two sub-layers is SiNx, the plasma mixture for forming each sub-film layer may be a mixture of SiH<NUM>, NH<NUM>, and H<NUM>. As such, the process of forming a sub-film layer may include exciting a mixture of SiH<NUM>, NH<NUM>, and H<NUM> to form a plasma mixture through a PECVD process, forming SiNx from the mixture of SiH<NUM>, NH<NUM>, and H<NUM>, depositing the SiNx outside the structure to be encapsulated <NUM> to form a SiNx layer, and processing the SiNx layer through one patterning process to obtain the sub-film layer. The step of exciting a mixture of SiH<NUM>, NH<NUM>, and H<NUM> to form a plasma mixture through a PECVD process can refer to related relevant art.

The one patterning process may include photoresist coating, exposure, development, etching, and photoresist stripping. In one embodiment, processing the SiNx layer through one patterning process to obtain the sub-film layer includes the following:.

First, a layer of photoresist is coated on the SiNx layer to obtain a photoresist layer, and then the photoresist layer is exposed using a mask to form a fully exposed area and a non-exposed area of the photoresist layer. Then, after the exposed photoresist layer is processed by a developing process, the photoresist in the fully exposed area is removed, and the photoresist in the non-exposed area is retained. Then, the corresponding area of the fully exposed area on the SiNx layer is etched. Finally, the photoresist in the non-exposed area is stripped, and a sub-film layer is formed on the SiNx layer corresponding to the non-exposed area. The embodiments of the present disclosure are described by using a positive photoresist to form a sub-film layer as an example. In practical applications, a negative photoresist may also be used to form a sub-film layer.

When the material for forming each of the at least two sub-film layers is SiON, the plasma mixture for forming each sub-film layer may be a mixture of SiH<NUM>, NH<NUM>, H<NUM>, and SiON. As such, the process of forming a sub-film layer may include exciting a mixture of SiH<NUM>, NH<NUM>, H<NUM> and SiON to form a plasma mixture through a PECVD process, forming SiON from the mixture of SiH<NUM>, NH<NUM>, H<NUM> and SiON, depositing the SiON outside the structure to be encapsulated <NUM> to form a SiON layer, and processing the SiON layer through one patterning process to obtain the sub-film layer. The step of exciting a mixture of SiH<NUM>, NH<NUM>, H<NUM> and SiON to form a plasma mixture through a PECVD process can refer to related relevant art. The step of processing the SiON layer through one patterning process is similar to the above step of processing the SiNx layer through one patterning process, which will not be repeated here.

In the embodiments of the present disclosure, when the plasma mixture forming the at least two sub-film layers may be a mixed gas of SiH<NUM>, NH<NUM>, and H<NUM>, the preset gas may be H<NUM>. In one embodiment, when the at least two sub-film layers are sub-film layer <NUM>, sub-film layer <NUM> and sub-film layer <NUM> shown in <FIG> , the amount of H<NUM> in the plasma mixture forming the sub-film layer <NUM> may be A. The amount of H<NUM> in the plasma mixture forming the sub-layer <NUM> may be A + <NUM>% a, and the amount of H<NUM> in the plasma mixture forming the sub-layer <NUM> may be A + <NUM>% a. In one embodiment, in the plasma mixture forming the sub-film layer closest to the structure <NUM> to be encapsulated among the at least two sub-film layers, the volume ratio of SiH<NUM>, NH<NUM>, and H<NUM> may be in the range of [<NUM>, <NUM>] : [ <NUM>,<NUM>] : [<NUM>,<NUM>]. In one embodiment, the volume ratio of SiH<NUM>, NH<NUM>, and H<NUM> is <NUM>:<NUM>:<NUM>. In the embodiments of the present disclosure, the composition of the plasma mixture, the ratio of SiH<NUM>, NH<NUM>, and H2in the plasma mixture forming the sub-film layer closest to the structure <NUM> to be encapsulated among the at least two sub-film layers, and the gradient of <NUM>% A are only exemplary and not limited in the embodiments of the present disclosure.

In the embodiments of the present disclosure, on one hand, H<NUM> can decompose SiH<NUM> into SiH<NUM>+ and SiH<NUM>+, SiH<NUM>+ can react with SiH<NUM> to consume reactants, and H<NUM> can also react with SiH<NUM>+. On the other hand, H<NUM> facilitates the diffusion of SiH<NUM>+ and allows SiH<NUM>+ to grow at regular positions. By increasing the amount of H<NUM> in the plasma mixtures forming the sub-film layers, the activity of the film-forming material can be increased, thereby increasing the densification of the formed sub-film layers. Furthermore, the hydrogen content in the formed sub-film layers also increases.

In sub-step <NUM> , the surface of each of the at least two sub-film layers is roughened. In one embodiment, a preset plasma may be used to bombard the surface of each of the at least two sub-film layers to roughen the surface of each of the at least two sub-film layers. The preset plasma may be an argon (Ar) plasma. After roughening, the surface roughness of each of the at least two sub-film layers may be within a range from <NUM> to <NUM>.

In one embodiment, a low power Ar plasma can be used to bombard the surface of the sub-film layer to treat the less dense areas of the sub-film layer, and the denser areas are retained, thereby improving the film quality of the sub-film layers. This low power is usually half the power of the bombarding apparatus. After roughening the surface of the sub-film layer, the surface of the sub-film layer can form a rugged microstructure, which improves the light extraction efficiency of the encapsulation structure and facilitates light extraction, which is advantageous for the display device of top emission structure.

In one embodiment, each time a sub-film layer is formed, the surface of the sub-film layer is roughened. Then, a sub-film layer is formed on the sub-film layer after the roughening treatment, and the surface of the formed sub-film layer is roughened again, and so on. That is, the above sub-step <NUM> and sub-step <NUM> can actually be alternated. In the embodiments of the present disclosure, the sub-film layer is formed by using a mixed gas of SiH<NUM>, NH<NUM>, and H<NUM>, and the process of forming the inorganic film layer <NUM> shown in <FIG> is described with reference to <FIG>.

First, a sub-film layer <NUM> is formed outside the structure to be encapsulated <NUM> according to the method provided in sub-step <NUM>. The surface of the sub-film layer <NUM> is a smooth plane. At this time, the sub-film layer <NUM> is as shown in <FIG>. Then, the surface of the sub-film layer <NUM> is roughened according to the method provided in sub-step <NUM>. After processing, the sub-film layer <NUM> is shown in <FIG>. Then, a sub-film layer <NUM> is formed on the sub-film layer <NUM> according to the method provided in sub-step <NUM>. The surface of the sub-film layer <NUM> is a smooth plane. At this time, the sub-film layer <NUM> is as shown in <FIG>. Then, the surface of the sub-film layer <NUM> is roughened according to the method provided in sub-step <NUM>. After processing, the sub-film layer <NUM> is shown in <FIG>. Then, a sub-film layer <NUM> is formed on the sub-film layer <NUM> according to the method provided in sub-step <NUM>. The surface of the sub-film layer <NUM> is a smooth plane. At this time, the sub-film layer <NUM> is as shown in <FIG>. Finally, the surface of the sub-film layer <NUM> is roughened according to the method provided in sub-step <NUM>. After processing, the sub-film layer <NUM> is as shown in <FIG>. Thus, the inorganic film layer <NUM> shown in <FIG> is obtained.

In step <NUM>, an organic film layer covering an external surface of the inorganic film layer is formed.

<FIG> shows a schematic diagram of an organic film layer <NUM> covering the inorganic film layer <NUM> according to an embodiment of the present disclosure. As shown in <FIG>, the organic film layer <NUM> covers the inorganic film layer <NUM>. In one embodiment, an organic film layer <NUM> can be formed at an external surface of the inorganic film layer <NUM> by using an ink jet printing process with an acrylic or epoxy resin. The arrangement of the organic film layer <NUM> can improve the bendability of the encapsulation structure and facilitate realization of curved surface display. For the process of forming the organic film layer <NUM> by the ink jet printing process, reference may be made to related technologies, and the embodiments of the present disclosure will not be repeated here.

According to the encapsulating method provided in the embodiment of the present disclosure, since the inorganic film layer includes at least two sub-film layers, among the at least two sub-film layers, the densification of the sub-film layer farther away from the structure to be encapsulated is greater than the densification of the sub-film layer closer to the structure to be encapsulated. Therefore, the probability of occurrence of cracks in the inorganic film layer can be reduced, and the problem of poor encapsulation performance of the encapsulation structure can be solved. As such, the encapsulation performance of the encapsulation structure can be improved.

An embodiment of the present disclosure further provides an electroluminescent apparatus. The electroluminescent apparatus includes the encapsulation structure <NUM> shown in any one of <FIG>. In addition, the electroluminescent apparatus may further include an electroluminescent component, and the encapsulation structure <NUM> is used to encapsulate the electroluminescent component. The electroluminescent apparatus may be an OLED display apparatus or an OLED lighting apparatus. In addition, the electroluminescent apparatus can also be a QLED display apparatus or a QLED lighting apparatus.

An embodiment of the present disclosure further provides a display apparatus including an electroluminescent apparatus according to one embodiment of the present disclosure. The electroluminescent apparatus may be an OLED display apparatus or an OLED lighting apparatus. The display apparatus may be any product or component having a display function such as a mobile phone, a tablet computer, a television set, a display, a notebook computer, a digital photo frame, or a navigator.

Claim 1:
An encapsulating method, comprising:
forming (<NUM>) an inorganic film (<NUM>) covering a structure (<NUM>) to be encapsulated,
wherein the inorganic film layer comprises at least two sub-film layers (<NUM>, <NUM>, <NUM>, 031n); and among the at least two sub-film layers, densification of a sub-film layer farther away from the structure to be encapsulated is greater than densification of a sub-film layer closer to the structure to be encapsulated;
characterized in that the forming (<NUM>) the inorganic film layer covering the structure to be encapsulated comprises:
forming (<NUM>) each of the at least two sub-film layers sequentially on the structure to be encapsulated using a plasma mixture, to make an amount of a gas in the plasma mixture forming the sub-film layer farther away from the structure to be encapsulated to be greater than an amount of the gas in the plasma mixture forming the sub-film layer closer to the structure to be encapsulated, to form the inorganic film layer;
the amount of the gas in the plasma mixture forming each of the at least two sub-film layers increases at the gradient <NUM>%*A in accordance with the sequence of formation of the at least two sub-film layers, wherein A is an amount of the gas in the plasma mixture forming a sub-film layer closest to the structure to be encapsulated among the at least two sub-film layers.