Patent Description:
A variety of advantageous transparent electrically conductive oxide (TCO) coatings are known in the art. Commonly, these coatings include an indium tin oxide film. In some cases, the indium tin oxide film is located beneath an overcoat film of silicon nitride, silicon oxynitride, or silicon dioxide.

As is well known, the solar heat gain coefficient (SHGC) of a window is the fraction of incident solar radiation that is admitted through a window. There are a number of applications where low solar heat gain windows are of particular benefit. In warm climates, it is desirable to have low solar heat gain windows. For example, solar heat gain coefficients of about <NUM> and below are generally recommended for buildings in the southern United States. Similarly, windows that are exposed to a lot of sun preferably have a low solar heat gain coefficient. Windows on the east or west side of a building, for example, tend to get a lot of sun in the morning or afternoon. Of course, sunrooms, solariums, and greenhouses also get a great deal of sun. For applications like these, the solar heat gain coefficient of a window plays a role in maintaining a comfortable environment within the building. Thus, it is beneficial to provide windows of this nature with coatings that establish a low solar heat gain coefficient (i.e., "low solar heat gain coatings").

A tradeoff is sometimes made in low solar heat gain coatings whereby the films selected to achieve a low SHGC have the effect of restricting the visible reflectance to a higher level than is ideal. As a consequence, windows bearing these coatings may have a somewhat mirror-like appearance. It would be desirable to provide a low solar heat gain coating that has sufficiently low visible reflectance to obviate this mirror-like appearance problem, and ideally has exceptional visible reflectance properties.

<CIT> discloses a glass substrate coated with a stack of layers, comprising ITO.

<CIT> discloses solar control glazings, wherein the solar control coating comprises ITO.

In addition to having undesirably high visible reflection, the reflected colors of certain low solar heat gain coatings are not ideal. For example, some coatings exhibit hues that are more red and/or yellow than is desired. Additionally or alternatively, the chroma of these coatings may be greater than is desired. In most cases, it is preferable to provide a coating that is as color neutral (i.e., colorless) as possible. Thus, the reflected colors of certain low solar heat gain coatings may be less than ideal, both in terms of hue and chroma.

It would be desirable to provide a low solar heat gain coating based on ITO that has low visible transmission and low visible reflection. It would be particularly desirable to provide such a coating where both the interior and exterior visible reflections are low. Further, it would be desirable to provide a low solar heat gain coating that exhibits a neutral (e.g., grey) color in reflection. Still further, it would be desirable to provide laminated glass panels that include at least a low solar heat gain coating of this nature, optionally together with a low-emissivity coating. In some cases, it would be particularly desirable to provide a laminated glass panel having both a low solar heat gain coating of the nature described and a low-emissivity coating comprising three silver-containing films.

Certain embodiments provide a coated glass pane having a surface that bears a coating. In the present embodiments, the coating comprises, in sequence moving outwardly from the surface, a first indium tin oxide film, a first nickel compound film, a second indium tin oxide film, a second nickel compound film, and an overcoat layer. Preferably, the first indium tin oxide film has a thickness of between <NUM>Å and <NUM>Å, the first nickel compound film has a thickness of between <NUM>Å and <NUM>Å, the second indium tin oxide film has a thickness of between <NUM>Å and <NUM>Å, and the second nickel compound film has a thickness of between <NUM>Å and <NUM>Å.

In some embodiments, the invention provides a laminated glass panel including two glass panes and an interlayer. The interlayer is sandwiched between the two glass panes and bonded thereto. At least one of the two glass panes has an interior surface that bears a coating. In the present embodiments, the coating comprises, in sequence moving away from the noted interior surface and toward the interlayer, a first indium tin oxide film, a first nickel-aluminum film, a second indium tin oxide film, a second nickel-aluminum film, and an overcoat layer. Preferably, the first indium tin oxide film has a thickness of between <NUM>Å and <NUM>Å, the first nickel-aluminum film has a thickness of between <NUM>Å and <NUM>Å, the second indium tin oxide film has a thickness of between <NUM>Å and <NUM>Å, and the second nickel-aluminum film has a thickness of between <NUM>Å and <NUM>Å.

Some embodiments of the invention provide a laminated glass panel including first and second glass panes and an interlayer. At least one of the two glass panes has an interior surface that bears an ITO-based coating. The interlayer is sandwiched between the first and second glass panes. In the present embodiments, the laminated glass panel has an exterior reflected color characterized by a chroma magnitude number of less than <NUM>.

Certain embodiments provide a laminated glass panel including first and second glass panes and an interlayer. The interlayer is sandwiched between the first and second glass panes. The first pane has an interior surface facing the interlayer. The second pane has an interior surface facing the interlayer. In the present embodiments, the interior surface of the first pane bears an ITO-based coating, and the interior surface of the second pane bears a low-emissivity coating comprising three silver layers.

The following detailed description is to be read with reference to the drawings, in which like elements in different drawings have like reference numerals. Skilled artisans will recognize that the examples provided herein have many useful alternatives that fall within the scope of the invention.

Many embodiments of the invention involve a coated substrate. A variety of substrate types are suitable for use in the invention. In some embodiments, the substrate <NUM> is a sheet-like substrate having generally opposed first and second major surfaces. For example, the substrate <NUM> can be a sheet of transparent material (i.e., a transparent sheet). The substrate, however, is not required to be a sheet, nor is it required to be transparent.

For many applications, the substrate <NUM> will comprise a transparent (or at least translucent) material, such as glass or clear plastic. For example, the substrate <NUM> is a glass pane (e.g., a window pane) in certain embodiments. In any embodiment of the present disclosure, the (or each) substrate can optionally be a glass pane. A variety of known glass types can be used, such as soda-lime glass. In some cases, it may be desirable to use "white glass," a low iron glass, etc. In certain embodiments, the substrate is part of a window, door, skylight, or other glazing. Depending on the level of solar control desired, the present coating may be applied to tinted glass. Thus, the low solar heat gain coating <NUM> of any embodiment disclosed herein can optionally be provided on a sheet of tinted glass.

Substrates of various sizes can be used in the present invention. Commonly, large-area substrates are used. Certain embodiments involve a substrate <NUM> having a major dimension (e.g., a length or width) of at least about <NUM> meter, preferably at least about <NUM> meter, perhaps more preferably at least about <NUM> meters (e.g., between about <NUM> meters and about <NUM> meters), and in some cases at least about <NUM> meters. In some embodiments, the substrate is a jumbo glass sheet having a length and/or width that is between about <NUM> meters and about <NUM> meters, e.g., a glass sheet having a width of about <NUM> meters and a length of about <NUM> meters. Substrates having a length and/or width of greater than about <NUM> meters are also anticipated.

Substrates of various thicknesses can be used in the present invention. In some embodiments, the substrate <NUM> (which can optionally be a glass pane) has a thickness of about <NUM>-<NUM>. Certain embodiments involve a substrate with a thickness of between about <NUM> and about <NUM>, and perhaps more preferably between about <NUM> and about <NUM>. In one particular embodiment, a glass pane (e.g., soda-lime glass) with a thickness of about <NUM> is used.

The substrate <NUM> has opposed surfaces <NUM> and <NUM>, which preferably are opposed major surfaces (or "opposed faces"). In some cases, surface <NUM> is destined to be an interior surface in contact with an interlayer of a laminated glass panel, while surface <NUM> is destined to be an exterior surface exposed to an outdoor environment (and thus exposed to periodic contact with rain). This, however, will not be the case in all embodiments.

As shown in <FIG>, the substrate <NUM> bears a low solar heat gain coating <NUM>. In <FIG>, the coating <NUM> includes, in sequence moving away from surface <NUM>, a first indium tin oxide film <NUM>, a first nickel compound film <NUM>, a second indium tin oxide film <NUM>, a second nickel compound film <NUM>, and an overcoat layer <NUM>. The films can be provided in the form of discrete layers, thicknesses of graded film, or a combination of both including at least one discrete layer and at least one thickness of graded film. In some cases, all the films of the coating <NUM> are sputtered films.

The indium tin oxide films <NUM>, <NUM> both comprise (i.e., include) indium tin oxide. Each of these films can optionally comprise indium tin oxide together with one or more other materials. If desired, zinc, aluminum, antimony, fluorine, carbon nanotubes, or other additives can be included in the film. Preferably, the indium tin oxide film consists essentially of, or consists of, indium tin oxide. Each indium tin oxide film <NUM>, <NUM> can contain various relative percentages of indium oxide and tin oxide. Indium oxide is the major constituent. That is, it accounts for more than <NUM>% of the film's total weight. Preferably, the composition of the film ranges from about <NUM>% indium oxide/<NUM>% tin oxide to about <NUM>% indium oxide/<NUM>% tin oxide, such as about <NUM>% indium oxide/<NUM>% tin oxide.

In <FIG>, the first indium tin oxide film <NUM> is deposited over surface <NUM> of substrate <NUM>. The indium tin oxide film <NUM>, as deposited, is a sub-oxide (i.e., its oxygen content is substoichiometric). Preferably, the deposition method involves sputtering a metallic indium tin target in an oxidizing atmosphere. Thus, each indium tin oxide film <NUM>, <NUM> can optionally be an ITO film characterized by having been sputter deposited from one or more metallic indium tin targets in an oxidizing atmosphere. The deposition technique can be, for example, in accordance with any non-limiting sputter deposition example described below.

Preferably, the first indium tin oxide film <NUM> is directly on (i.e., in contact with) surface <NUM> of the substrate <NUM>. If desired, however, there can be a base film (e.g., silicon dioxide, silicon nitride, or silicon oxynitride, optionally with a small amount of aluminum or other dopant) between the substrate <NUM> and the first indium tin oxide film <NUM>. Moreover, when provided, such a base film may comprise two or more layers, e.g., a first layer comprising silicon and a second layer comprising tin. In one non-limiting example, the first layer comprises silicon dioxide, silicon nitride, and/or silicon oxynitride while the second layer comprises tin oxide.

The first indium tin oxide film <NUM> preferably has a thickness of between 400Å and 900Å. In certain embodiments, the first indium tin oxide film <NUM> has a thickness of between <NUM>Å and <NUM>Å, such as about <NUM>Å, or between <NUM>Å and <NUM>Å, such as about <NUM>Å. For any embodiment of the present disclosure, the first indium tin oxide film <NUM> can optionally have a thickness in any one or more (e.g., all three) of the ranges noted in this paragraph. The thicknesses recited herein are physical thicknesses unless otherwise specified to be optical thicknesses.

With respect to the two nickel compound films <NUM>, <NUM>, each comprises an alloy or other compound including nickel and at least one other metal. Preferably, the nickel compound film comprises nickel aluminum. Another option is nickel titanium. Still another option is nickel chromium. Yet another option is nickel aluminum titanium. A further option is nickel titanium niobium. Other compounds comprising nickel and at least one other metal can also be used.

In some cases, each of the two nickel compound films <NUM>, <NUM> comprises oxygen. For example, an upper thickness of the nickel compound film may comprise oxide film (optionally fully oxidized film) while a lower thickness is metallic or substoichiometric. In certain preferred embodiments, each nickel compound film <NUM>, <NUM> is deposited as metallic film. In some cases, the first nickel compound film <NUM> comprises nickel, aluminum, and oxygen, and the second nickel compound film <NUM> comprises nickel, aluminum, and nitrogen. In certain embodiments, each nickel compound film <NUM>, <NUM> comprises, consists essentially of, or consists of, nickel, aluminum, and oxygen.

The first nickel compound film <NUM> preferably has a thickness of between <NUM>Å and <NUM>Å. In certain embodiments, the first nickel compound film <NUM> has a thickness of between <NUM>Å and <NUM>Å, such as <NUM>Å, or between 90Å and <NUM>Å, such as <NUM>Å. For any embodiment of the present disclosure, the first nickel compound film <NUM> can optionally have a thickness in any one or more (e.g., all three) of the ranges noted in this paragraph.

The first nickel compound film <NUM> is formed over the first indium tin oxide film <NUM>. In some cases, the first nickel compound film <NUM> is deposited as a metallic (i.e., elemental metal) film. Such film can be sputtered, for example from one or more metallic compound (e.g., alloy) targets, onto the first indium tin oxide film <NUM> in an inert atmosphere (e.g., argon). If desired, one or more nickel alloy (e.g., Ni-Al) targets can be used. Alternatively, a first metallic target (optionally comprising Al) can be co-sputtered with a nickel alloy target. The thus coated substrate may then be conveyed into a subsequent oxygen-containing sputtering zone, e.g., where the second indium tin oxide film <NUM> is deposited onto the first nickel compound film <NUM>. As a result of this exposure, the nickel compound film will typically become at least partially oxidized. Preferably, an outer portion of this film (or at least a metal therein, such as aluminum when present) will become oxidized, while an inner portion (or at least nickel therein) remains metallic. Providing metallic nickel in the inner portion can impart absorption of visible radiation, thus facilitating good control over visible transmission, reflection, and color. This is particularly advantageous for providing the coating with low levels of visible transmission and reflection.

In certain embodiments, each nickel compound film <NUM>, <NUM> is deposited as a sub-oxide (i.e., substoichiometric) film. If desired, the nickel compound film, as deposited, can be substoichiometric across the entire thickness of the film. In some cases, a sub-oxide nickel compound film is deposited by sputtering one or more sub-oxide targets containing nickel and at least one other metal (such as Al) onto the first indium tin oxide film <NUM> in an inert atmosphere. If desired, some oxygen, nitrogen, or both can be used in the sputtering atmosphere, but in an amount small enough to deposit the film as a sub-oxide. When provided, the sub-oxide target(s) can optionally further include titanium sub-oxide, e.g., TiOx, where x is less than <NUM>. In other cases, a sub-oxide nickel compound film is deposited by sputtering one or more nickel alloy targets onto the first indium tin oxide film <NUM> in an oxidizing atmosphere wherein the amount and/or reactivity of oxygen is controlled to deposit the film as a sub-oxide. In still other cases, separate targets of different compositions are co-sputtered in a sub-oxidizing atmosphere (wherein the amount and/or reactivity of oxygen are controlled to deposit the film as a sub-oxide). If desired, one or each of the co-sputtered targets may include titanium. Regardless of which deposition method is used, the thus coated substrate may then be conveyed into a subsequent oxygen-containing sputtering zone (e.g., where a subsequent indium tin oxide film <NUM> is deposited onto the sub-oxide nickel alloy film). As a result of this exposure, the sub-oxide film will become further oxidized. Preferably, an outer portion of this layer (or at least a metal therein, such as aluminum when present) will become more oxidized (optionally fully oxidized), while an inner portion (or at least nickel therein) remains less oxidized (e.g., substoichiometric).

It has been discovered that the combination of nickel and aluminum, as used in certain embodiments, can provide particularly good durability and color properties. This can be especially advantageous for laminated glass embodiments (where both the ITO-based coating and a polymer interlayer are sandwiched between two glass panes, such that there is no air space between the two panes).

It is to be understood that the term "nickel compound," as used herein, refers to any compound that includes at least some nickel and at least one other metal. The term "nickel alloy," as used herein, refers to any alloy or other metallic mixture that includes at least some nickel and at least one other metal. The term "nickel aluminum" is used herein to refer to any compound that includes at least some nickel and at least some aluminum. Included in this definition is any compound comprising both nickel and aluminum, whether in metallic (i.e., elemental metal) form or in the form of an oxide, a nitride, an oxynitride, etc., and optionally including one or more other desired materials.

In some embodiments, nickel and aluminum are the only metals dispersed along the entire thickness of each nickel compound film <NUM>, <NUM>. For example, each nickel compound film <NUM>, <NUM> can optionally be free of (i.e., devoid of) metals other than nickel and aluminum. If desired, the nickel aluminum can consist essentially of nickel and aluminum, optionally together with oxygen, nitrogen, or both. The discussion in this paragraph applies for each nickel compound film in the coating.

Preferably, each nickel compound film <NUM>, <NUM> contains (and/or is deposited as film containing) more than <NUM>% aluminum by weight. Additionally or alternatively, the film can optionally contain (and/or be deposited as film containing) less than <NUM>% aluminum by weight. Thus, the nickel compound film can advantageously contain (and/or be deposited as film containing) aluminum at a weight percentage of between <NUM>% and <NUM>%, such as between <NUM>% and <NUM>%, or between <NUM>% and <NUM>%, e.g., about <NUM>%, with the remainder optionally being nickel. In one embodiment, each nickel compound film <NUM>, <NUM> is deposited as film containing about <NUM>% nickel and about <NUM>% aluminum. In embodiments where the nickel compound film comprises oxygen, nitrogen, or both, the foregoing percentages are on a metal-only basis. The discussion in this paragraph applies for each nickel compound film in the coating.

In some cases, one or each nickel compound film <NUM>, <NUM> comprises nickel, aluminum, and titanium. In such cases, the relative amounts of nickel, aluminum, and titanium can be varied depending upon the particular application, the properties desired, etc. When provided, titanium can be present in the film in metallic form, stoichiometric oxide form, and/or sub-oxide form.

The first nickel compound film <NUM> is in contact with both the first indium tin oxide film <NUM> and the second indium tin oxide film <NUM>. This can be appreciated, for example, by referring to <FIG>. Thus, in <FIG>, the second indium tin oxide film <NUM> is directly on the first nickel compound film <NUM>. In other cases, a transparent dielectric film may be provided between the first nickel compound film <NUM> and the second indium tin oxide film <NUM>.

The second indium tin oxide film <NUM> preferably has a thickness of between 400Å and <NUM>,000Å. In preferred embodiments, the second indium tin oxide film <NUM> has a thickness of between <NUM>Å and <NUM>Å, or between <NUM>Å and <NUM>Å, such as <NUM>Å or <NUM>Å. For any embodiment of the present disclosure, the second indium tin oxide film <NUM> can optionally have a thickness in any one or more (e.g., all three) of the ranges noted in this paragraph.

In some cases, the second indium tin oxide film <NUM> is thicker than the first indium tin oxide film <NUM>. This can optionally be the case in combination with the two indium tin oxide films <NUM>, <NUM> having thicknesses within any one or more (e.g., all three) of the ranges noted above for each indium tin oxide film. The second indium tin oxide film <NUM> can optionally be thicker than the first indium tin oxide film <NUM> by at least <NUM>Å, at least <NUM>Å, at least <NUM>Å, or at least <NUM>Å. It is to be appreciated, however, that this is by no means required. Instead, the two indium tin oxide films <NUM>, <NUM> can have the same thickness, or the first <NUM> can be thicker than the second <NUM>.

The second nickel compound film <NUM> is formed over the second indium tin oxide film <NUM>. Preferably, the second nickel compound film <NUM> is in contact with the second indium tin oxide film <NUM>. The second nickel compound film <NUM> can have any composition, and can be formed using any deposition method, described above for the first nickel compound film <NUM>.

The second nickel compound film <NUM> preferably has a thickness of between <NUM>Å and <NUM>Å. In certain embodiments, the second nickel alloy film <NUM> has a thickness of between <NUM>Å and <NUM>Å, or between <NUM>Å and <NUM>Å, such as <NUM>Å or <NUM>Å. For any embodiment of the present disclosure, the second nickel compound film <NUM> can optionally have a thickness in any one or more (e.g., all three) of the ranges noted in this paragraph.

In some embodiments, the first nickel compound film <NUM> is thicker than the second nickel compound film <NUM>. This can optionally be the case in combination with the two nickel compound films <NUM>, <NUM> having thicknesses within any one or more (e.g., all three) of the ranges noted above for each nickel compound film. In other embodiments, the first and second nickel compound films <NUM>, <NUM> have the same thickness.

In some cases, the second nickel compound film <NUM> is deposited as a metallic (i.e., elemental metal) film. Such film can be sputtered, for example from one or more metallic compound (e.g., alloy) targets, onto the second indium tin oxide film <NUM> in an inert atmosphere (e.g., argon). If desired, one or more nickel alloy (e.g., Ni-Al) targets can be used. Alternatively, a first metallic target (optionally comprising Al) can be co-sputtered with a nickel alloy target. The thus coated substrate may then be conveyed into a subsequent oxygen-containing sputtering zone, e.g., where the overcoat layer <NUM> is deposited onto the second nickel compound film <NUM>. As a result of this exposure, the nickel compound film will typically become at least partially oxidized, nitrided, or oxynitrided. Preferably, an outer portion of this film (or at least a metal therein, such as aluminum when present) will become oxidized, nitrided, or oxynitrided, while an inner portion (or at least nickel therein) remains metallic. Providing metallic nickel in the inner portion can impart absorption of visible radiation, thus facilitating good control over visible transmission, reflection, and color. This is particularly advantageous for providing the coating with low levels of visible transmission and reflection.

For any embodiment of the present disclosure, the thicknesses of the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, and the second nickel compound film <NUM> preferably are all within the first range (i.e., the broadest range) noted above for each such film, more preferably are all within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally are all within the third range (i.e., the narrowest range) noted above for each such film. These preferred thickness ranges help establish low visible transmission, exceptional reflection properties, and good color properties.

The overcoat layer <NUM> is formed over the second nickel compound film <NUM>. Preferably, the overcoat layer <NUM> is in contact with the second nickel compound film <NUM>. The overcoat layer preferably comprises a transparent dielectric material. In certain embodiments, the overcoat layer comprises (e.g., consists essentially of) silicon dioxide, silicon nitride, and/or silicon oxynitride, optionally together with a small amount of aluminum or another dopant. In other cases, the overcoat layer comprises (e.g., consists essentially of) tin oxide. The overcoat layer <NUM> preferably is the outermost film of the coating <NUM>.

The overcoat layer <NUM> preferably has a thickness of between <NUM>Å and <NUM>,<NUM>Å. In certain embodiments, the overcoat layer <NUM> has a thickness of between <NUM>Å and <NUM>Å, or between <NUM>Å and <NUM>Å, such as <NUM>Å. For any embodiment of the present disclosure, the overcoat layer <NUM> can optionally have a thickness in any one or more (e.g., all three) of the ranges noted in this paragraph. The overcoat layer and the preferred thickness ranges noted in this paragraph help establish exceptional color properties.

For any embodiment of the present disclosure, the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> preferably are all within the first range (i.e., the broadest range) noted above for each such film, more preferably are all within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally are all within the third range (i.e., the narrowest range) noted above for each such film.

Tables <NUM> and <NUM> below show two non-limiting layer stacks that can be used as the low solar heat gain coating <NUM>. In Table <NUM>, the SiAlON film is the outermost film of the coating. In Table <NUM>, the SiAlN film is the outermost film of the coating.

The layer stacks of Tables <NUM> and <NUM> are representative of embodiments wherein the second indium tin oxide film <NUM> is at least <NUM>Å thicker, at least <NUM>Å thicker, at least <NUM>Å thicker, or at least <NUM>Å thicker than the first indium tin oxide film <NUM>. This can optionally be the case for any embodiment of the present disclosure. In some embodiments, this relative thickness arrangement is provided for the two indium tin oxide films <NUM>, <NUM> in combination with having the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all be within the first range (i.e., the broadest range) noted above for each such film, more preferably within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally within the third range (i.e., the narrowest range) noted above for each such film.

With respect to the layer stack of Table <NUM>, this is representative of embodiments wherein the first nickel compound film <NUM> is at least <NUM>Å thicker than the second nickel compound film <NUM>. In such embodiments, the thicknesses noted in the preceding paragraph can optionally be used.

In some cases, the substrate <NUM> is heated prior to film deposition, during deposition, or both. Additionally or alternatively, the coated substrate <NUM> can be heat treated after being coated. If desired, post-deposition heat treatment (such as glass tempering) can be performed in air. When the coated substrate <NUM> is heat treated, defects in the ITO can be healed and improvement of crystalline structure can occur in the indium tin oxide films <NUM>, <NUM> without an uncontrollable change in their chemistry. The nickel compound films <NUM>, <NUM> may provide resistance to oxygen reaching and reacting with the indium tin oxide films <NUM>, <NUM> during heat treatment.

In certain embodiments, the low solar heat gain coating <NUM> is on a glass pane, and this coated glass pane is heat treated through a process that leaves the coated glass cut-able by conventional glass cutting techniques. The heat treatment, for example, can involve using lower temperature for conversion so as to maintain the stress in the glass such that the coated glass remains cut-able even after the heat treatment. One non-limiting example of such a heat treatment process is any of the flash-treatment processes described in <CIT> and <CIT> and <CIT>.

In certain embodiments, the invention provides a monolithic coated glass pane <NUM>. Reference is made to <FIG>. In other embodiments, the coated glass pane <NUM> is part of a laminated glass panel <NUM> that comprises at least two glass panes <NUM>, <NUM>' and an interlayer <NUM>. Reference is made to <FIG> and <FIG>. While the present discussions focus on the substrate <NUM>, or each substrate <NUM>, <NUM>', being a glass pane, other substrate types (including those described above) can alternatively be used.

The interlayer <NUM> preferably is a tear-resistant polymer layer. In some cases, it is a sheet of ionoplast plastic. In other cases, it is a sheet of polyvinylbutyral (PVB). Various other materials known to be suitable for the interlayer of a laminated glass panel can also be used.

In many cases, a laminated glass panel is produced through two operations: (<NUM>) an assembly operation, and (<NUM>) an autoclave operation. In the assembly operation, the interlayer is positioned between two glass substrates to form a sandwich, which is then heated (commonly to a temperature of between about <NUM> (<NUM>°F) and about <NUM> (<NUM>°F) and roller pressed to initiate removal of air trapped between the interlayer and to initiate adhesion of the interlayer to the glass. In the autoclave operation, the sandwich is exposed to an elevated temperature (commonly between about <NUM> (<NUM>°F) and about <NUM> (<NUM> °F) and an elevated atmospheric pressure (commonly between about <NUM> kPa (<NUM> psig) and about <NUM> kPa (<NUM> psig) until there is complete adhesion of the interlayer to the glass and complete dissolution of air trapped within the interlayer. It is not uncommon for the autoclave operation to last two hours or four hours per treatment. Various autoclave methods are known to skilled artisans.

In other cases, the laminated glass panel <NUM> is made by a non-autoclave process. Suitable processes of this nature are described in <CIT> and <CIT>.

In some embodiments where the low solar heat gain coating <NUM> is part of a laminated glass panel <NUM>, the low solar heat gain coating is the only coating located between the two glass panes <NUM>, <NUM>'. Reference is made to <FIG>.

In other embodiments, the laminated glass panel <NUM> also includes a low-emissivity coating <NUM>. In the embodiment of <FIG>, for example, the laminated glass panel <NUM> includes a low-emissivity coating <NUM> on the interior surface <NUM> of pane <NUM>'. When provided, the low-emissivity coating <NUM> preferably includes at least one silver-inclusive film, which desirably contains more than <NUM>% silver by weight (e.g., a metallic silver film). In certain preferred embodiments, the low-emissivity coating <NUM> includes three or more infrared-reflective films (e.g., silver-containing films). Low-emissivity coatings having three or more infrared-reflective films are described in <CIT>and <CIT> and <CIT> and <CIT> and <CIT> and<CIT> and <CIT>. In other cases, the low-emissivity coating can be a "single silver" or "double silver" low-emissivity coating, which are well-known to skilled artisans. Advantageous coatings of this nature are commercially available from, for example, Cardinal CG Company (Eden Prairie, Minnesota, U.

Thus, in certain preferred embodiments, the interior surface <NUM> of the second pane <NUM>' bears a low-emissivity coating <NUM>, and that coating includes three layers comprising silver. These embodiments provide, among other beneficial properties, particularly low visible transmission (e.g., lami Tvis of less than <NUM>%), exceptionally low solar transmission (e.g., lami Tsolar of less than <NUM>%), and low solar heat gain coefficient (e.g., lami SHGC of less than <NUM>). Moreover, when the preferred film compositions and thicknesses described above for the low solar heat gain coating <NUM> are used, the laminated glass panel can have exceptional visible reflection and color properties. Preferred reflection and color properties are discussed below.

The laminated glass panel <NUM> can optionally be mounted in a frame (e.g., a window sash or window frame) <NUM> such that the exterior surface <NUM> of the outboard pane <NUM> is exposed to an outdoor environment <NUM> while the exterior surface <NUM> of the inboard pane <NUM>' is exposed to an indoor (e.g., room-side) environment <NUM>. Reference is made to <FIG>.

In <FIG>, the "first" (or "#<NUM>") surface is exposed to the outdoor environment <NUM>. Accordingly, it is the #<NUM> surface that radiation from the sun first strikes. Thus, the exterior surface <NUM> of the outboard pane <NUM> is the so-called first surface. Moving from the #<NUM> surface toward the interior of the building, the next surface is the "second" (or "#<NUM>") surface. Thus, the interior surface <NUM> of the outboard pane <NUM> is the so-called second surface. Moving further toward the interior of the building, the next surface is the "third" (or "#<NUM>") surface, followed by the "fourth" (or "#<NUM>") surface. In <FIG>, the interior surface <NUM> of the inboard pane <NUM>' is the #<NUM> surface, and the exterior surface <NUM> of that pane is the #<NUM> surface.

The low solar heat gain coating <NUM> has a number of beneficial properties. The ensuing discussion reports several of these properties. In some cases, properties are reported herein for a single (i.e., monolithic) glass pane <NUM> bearing the low solar heat gain coating <NUM> on one surface <NUM>, where the glass pane is clear <NUM> soda-lime float glass ("the present pane"). In other cases, properties are reported herein for a laminated glass panel <NUM> having the low solar heat gain coating <NUM> on the #<NUM> surface, where both panes are clear <NUM> soda-lime float glass and the interlayer is <NUM> (<NUM> inch) thick PVB ("the present panel"). In still other cases, properties are reported herein for a laminated glass panel <NUM> having the low solar heat gain coating <NUM> on the #<NUM> surface and a triple silver low-emissivity coating <NUM> on the #<NUM> surface. The triple silver low-emissivity coating is known commercially as the LoE<NUM>-<NUM>™ product from Cardinal CG Company. The reported properties are for such a laminated glass panel wherein both panes are clear <NUM> soda-lime float glass and the interlayer is <NUM> (<NUM> inch) thick PVB ("the present LowE panel"). The specifics in this paragraph are by no means limiting to the invention. For example, when provided, the low-emissivity coating <NUM> can alternatively be a single or double silver low-emissivity coating, etc. Absent an express statement to the contrary, the present disclosure reports determinations made using the well-known LBNL WINDOW <NUM> computer program (e.g., calculating center of glass data) under NFRC100-<NUM> conditions.

The low solar heat gain coating <NUM> has low emissivity. The emissivity of the coating <NUM> is less than <NUM>. Preferably, the emissivity is less than <NUM>, or even less than <NUM>, such as about <NUM>. In contrast, an uncoated pane of clear glass would typically have an emissivity of about <NUM>.

The term "emissivity" is well known in the present art. This term is used herein in accordance with its well-known meaning to refer to the ratio of radiation emitted by a surface to the radiation emitted by a blackbody at the same temperature. Emissivity is a characteristic of both absorption and reflectance. It is usually represented by the formula: E = <NUM> - Reflectance. The present emissivity values can be determined as specified in "<NPL>.

In addition to low emissivity, the present coating <NUM> provides low UV transmission. Preferably, the UV transmission is less than <NUM>%, less than <NUM>%, or even less than <NUM>% for the present pane. While the desired level of UV transmission can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with a UV transmission of between <NUM>% and <NUM>%, such as about <NUM>%. Moreover, for the present panel and the present LowE panel, the UV transmission is less than <NUM>%, and preferably is less than <NUM>%. The UV transmission reported herein is a weighted transmission from <NUM> - <NUM> using the solar spectrum (AM1. <NUM>) found in ASTM G173.

The low solar heat gain coating <NUM> also provides low solar transmission. Preferably, the solar transmission is less than <NUM>%, less than <NUM>%, or even less than <NUM>% for the present pane. While the desired level of solar transmission can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with a solar transmission of between <NUM>% and <NUM>%, such as about <NUM>%.

With respect to the present panel and the present LowE panel, the solar transmission is less than <NUM>%, and preferably is less than <NUM>%. While the desired level of solar transmission can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide: (i) the present panel with a solar transmission of between <NUM>% and <NUM>%, such as about <NUM>%, and (ii) the present LowE panel with a solar transmission of between <NUM>% and <NUM>%, such as about <NUM>%.

In any embodiment of the present disclosure, the present pane can optionally have an exterior solar reflectance of less than <NUM>, and preferably less than <NUM>, such as about <NUM>-<NUM>. The solar transmission and solar reflectance reported herein are determined in accordance with NFRC <NUM>-<NUM>.

As noted above, coating <NUM> provides advantageous solar heat gain properties. As is well known, the solar heat gain coefficient (SHGC) of a window is the fraction of incident solar radiation that is admitted through a window. The present coating <NUM> provides a low SHGC. For example, the SHGC of the present pane is less than <NUM>. Preferably, the present pane has a SHGC of less than <NUM>. While the desired SHGC level can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with a SHGC of between <NUM> and <NUM>, such as about <NUM>.

With respect to the present panel, it has a SHGC of less than <NUM>, and preferably less than <NUM>. While the desired SHGC level can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present panel with a SHGC of between <NUM> and <NUM>, such as about <NUM>.

With respect to the present lowE panel, it has a SHGC of less than <NUM>, and preferably less than <NUM>. While the desired SHGC level can be selected and varied to accommodate different applications, some preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present lowE panel with a SHGC of between <NUM> and <NUM>, such as about <NUM>.

The term "solar heat gain coefficient" is used herein in accordance with its well-known meaning. Reference is made to NFRC <NUM>-<NUM>. The SHGC can be calculated using the methodology embedded in the well-known LBNL WINDOW <NUM> computer program.

Preferably, the present pane has both a solar transmission of about <NUM>% to <NUM>% and a solar heat gain coefficient of about <NUM>-<NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present pane having a UV transmission of between <NUM>% and <NUM>%. Furthermore, for any such embodiment, the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> preferably are all within the first range (i.e., the broadest range) noted above for each such film, more preferably are all within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally are all within the third range (i.e., the narrowest range) noted above for each such film.

The present pane, the present panel, and the present LowE panel preferably each have a visible transmission Tv of less than <NUM>%. Thus, for any embodiment of the present disclosure (including those described in the paragraph immediately above), the visible transmission can optionally be less than <NUM>%. Preferably, the visible transmission Tv is less than <NUM>%, or even less than <NUM>%, such as about <NUM> % for the present pane, about <NUM>-<NUM>% for the present panel, and about <NUM>% for the present LowE panel.

The term "visible transmission" is well known in the art and is used herein in accordance with its well-known meaning to refer to the percentage of all incident visible radiation that is transmitted through the IG unit <NUM>. Visible radiation constitutes the wavelength range of between about <NUM> and about <NUM>. Visible transmittance, as well as visible reflectance, can be determined in accordance with NFRC <NUM>-<NUM>, Standard Test Method for Determining the Solar and Infrared Optical Properties of Glazing Materials and Fading Resistance of Systems. The well-known LBNL WINDOW <NUM> computer program can be used in calculating these and other reported optical properties.

As noted above, a tradeoff is sometimes made in low solar heat gain coatings whereby the films selected to achieve a low SHGC have the effect of restricting the visible reflection to a higher level than is ideal. In contrast, the present low solar heat gain coating <NUM> has exceptional, surprising reflection properties.

The present pane, for example, has an exterior visible reflectance Rv, e (off the glass side of the present pane) of less than <NUM>. Preferably, the exterior visible reflectance Rv, e of the present pane is less than <NUM>, or even less than <NUM>. While the precise level of exterior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with an exterior visible reflectance Rv, e of about <NUM>-<NUM>, such as about <NUM>.

The present pane also has an interior visible reflectance Rv, i(off the film side of the present pane) of less than <NUM>. Preferably, the present pane has interior visible reflectance Rv, i of less than <NUM>, or even less than <NUM>. While the precise level of interior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with an interior visible reflectance Rv, i of about <NUM>-<NUM>, such as about <NUM>.

Thus, in certain embodiments, the present pane has an exterior visible reflectance Rv, e and an interior visible reflectance Rv, i that are each less than <NUM>, or even less than <NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present pane preferably has both a solar transmission of about <NUM>% to <NUM>% and a solar heat gain coefficient of about <NUM>-<NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present pane having a UV transmission of between <NUM>% and <NUM>%.

The present panel has an exterior visible reflectance Rv, e (off the #<NUM> surface) of less than <NUM>. Preferably, the present panel achieves an exterior visible reflectance Rv, e of less than <NUM>, or even less than <NUM>. While the precise level of exterior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present panel with an exterior visible reflectance Rv, e of about <NUM> to <NUM>, such as about <NUM>.

The present panel also has an interior visible reflectance Rv, i (off the #<NUM> surface) of less than <NUM>. Preferably, the present panel achieves an interior visible reflectance Rv, i of less than <NUM>, or even less than <NUM>. While the precise level of interior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present panel with an interior visible reflectance Rv, i of about <NUM> to <NUM>, such as about <NUM>-<NUM>.

Thus, in certain embodiments, the present panel has an exterior visible reflectance Rv, e and an interior visible reflectance Rv, i that are each less than <NUM>, or even less than <NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present panel having a UV transmission of less than <NUM>%.

The present lowE panel has an exterior visible reflectance Rv, e (off the #<NUM> surface) of less than about <NUM>. Preferably, the present lowE panel achieves an exterior visible reflectance Rv, e of less than about <NUM>, or even less than <NUM>. While the precise level of exterior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present lowE panel with an exterior visible reflectance Rv, e of about <NUM>-<NUM>, such as about <NUM>.

The present lowE panel also has an interior visible reflectance Rv, i (off the #<NUM> surface) of less than <NUM>. Preferably, the present lowE panel achieves an interior visible reflectance Rv, i of less than <NUM>, or even less than <NUM>. While the precise level of interior visible reflectance can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present lowE panel with an interior visible reflectance Rv, i of about <NUM>-<NUM>, such as about <NUM>.

Thus, in certain embodiments, the present lowE panel has an exterior visible reflectance Rv, e and an interior visible reflectance Rv, i that are each less than <NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present lowE panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present lowE panel having a UV transmission of less than <NUM>%.

The term "visible reflectance" is well known in the art. This term is used herein in accordance with its well-known meaning to refer to the percentage of all incident visible radiation that is reflected off the glass side of the present pane (which bears coating <NUM> on the opposite, film side), or off the film side of the present pane, or off the exterior (i.e., #<NUM> surface) or interior (e.g., #<NUM> surface) of a laminated glass panel. Skilled artisans will appreciate that the visible reflectance off the glass side of a monolithic pane includes not only visible radiation reflected at surface <NUM>, but also visible radiation reflected at surface <NUM>. Similarly, the visible reflectance off the exterior of a laminated glass panel includes not only visible radiation reflected at surface <NUM>, but also visible radiation reflected at surfaces <NUM>, <NUM>, and <NUM>. Skilled artisans will appreciate that the situation is similar for interior monolithic reflectance and interior laminated reflectance. The reported visible reflectance is measured off a central portion of the glass or film side of the monolithic coated pane, or off a central portion of the exterior surface of the outboard pane <NUM> or inboard pane <NUM>' of the laminated glass panel. Visible reflectance can be determined as specified in the above-noted NFRC <NUM>-<NUM>.

The low solar heat gain coating <NUM> provides exceptional color properties. For example, the present pane has an exterior reflected color characterized by a chroma magnitude number of less than <NUM>, preferably less than <NUM>, or even less than <NUM>. While the precise exterior reflected color properties can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present pane with an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, such as about <NUM>.

Thus, in certain embodiments, the present pane has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present pane preferably has both a solar transmission of about <NUM>% to <NUM>% and a solar heat gain coefficient of about <NUM>-<NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present pane having a UV transmission of between <NUM>% and <NUM>%. Furthermore, the present pane can optionally also have an exterior visible reflectance Rv, e of about <NUM>-<NUM>, an interior visible reflectance Rv, i of about <NUM>-<NUM>, or both.

With respect to the present panel, it preferably has an exterior reflected color characterized by a chroma magnitude number of less than <NUM>, or even less than <NUM>. While the precise exterior reflected color properties can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present panel with an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, such as about <NUM> or about <NUM>.

In addition, the present panel exhibits an interior reflected color that ranges from good to exceptional. Preferably, the interior reflected color of the present panel is characterized by a chroma magnitude number of less than <NUM>. While the precise interior reflected color properties can be selected and varied in accordance with the present teachings, some preferred embodiments (e.g., where coating <NUM> is the first exemplary film stack tabulated above) provide the present panel with an interior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, such as about <NUM>. In other cases, it less than <NUM>, or even less than <NUM>. For example, other preferred embodiments (e.g., where coating <NUM> is the second exemplary film stack tabulated above) provide the present panel with an interior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, such as about <NUM>.

Thus, in certain embodiments, the present panel has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, an interior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, or both. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present panel having a UV transmission of less than <NUM>%. Furthermore, the present panel can optionally also have an exterior visible reflectance Rv, e of about <NUM> to <NUM>, an interior visible reflectance Rv, i of about about <NUM> to <NUM>, or both.

With respect to the present lowE panel, it preferably has an exterior reflected color characterized by a chroma magnitude number of less than <NUM>, or even less than <NUM>. While the precise exterior reflected color properties can be selected and varied in accordance with the present teachings, certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above) provide the present lowE panel with an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>, such as about <NUM>.

Thus, in certain embodiments, the present lowE panel has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present lowE panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present lowE panel having a UV transmission of less than <NUM>%. Furthermore, the present lowE panel can optionally also have an exterior visible reflectance Rv, e of about <NUM>-<NUM>, an interior visible reflectance Rv, i of about <NUM>-<NUM>, or both.

With respect to the present pane, in certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above), the present pane exhibits an exterior reflected color characterized by an "a" color coordinate of between -<NUM> and <NUM> (e.g., between -<NUM> and <NUM>, such as about -<NUM>) and a "b" color coordinate of between -<NUM> and <NUM> (e.g., -<NUM> and <NUM>, such as about -<NUM>).

In addition to having exterior reflected color within one or each range recited in the previous paragraph, the present pane preferably has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present pane preferably has both a solar transmission of about <NUM>% to <NUM>% and a solar heat gain coefficient of about <NUM>-<NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present pane having a UV transmission of between <NUM>% and <NUM>%. Furthermore, the present pane can optionally also have an exterior visible reflectance Rv, e of about <NUM>-<NUM>, an interior visible reflectance Rv, i of about <NUM>-<NUM>, or both.

With respect to the present panel, in certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above), the present panel exhibits an exterior reflected color characterized by an "a" color coordinate of between -<NUM> and <NUM> (e.g., between - <NUM> and <NUM>, such as about -<NUM>) and a "b" color coordinate of between -<NUM> and <NUM> (e.g., -<NUM> and <NUM>, such as about <NUM>).

In addition to having exterior reflected color within one or each range recited in the previous paragraph, the present panel preferably has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present panel having a UV transmission of less than <NUM>%. Furthermore, the present panel can optionally also have an exterior visible reflectance Rv, e of about <NUM> to <NUM>, an interior visible reflectance Rv, i of about about <NUM> to <NUM>, or both.

With respect to the present lowE panel <NUM>, in certain preferred embodiments (e.g., where coating <NUM> is one of the exemplary film stacks tabulated above), the present lowE panel exhibits an exterior reflected color characterized by an "a" color coordinate of between -<NUM> and <NUM> (e.g., between -<NUM> and <NUM>, such as about -<NUM>) and a "b" color coordinate of between -<NUM> and <NUM> (e.g., -<NUM> and <NUM>, such as about <NUM>).

In addition to having exterior reflected color within one or each range recited in the previous paragraph, the present lowE panel preferably has an exterior reflected color characterized by a chroma magnitude number in the range of <NUM>-<NUM>. This can optionally be in combination with the thicknesses for the first indium tin oxide film <NUM>, the first nickel compound film <NUM>, the second indium tin oxide film <NUM>, the second nickel compound film <NUM>, and the overcoat layer <NUM> all being within the first range (i.e., the broadest range) noted above for each such film, more preferably all being within the second range (i.e., the intermediate range) noted above for each such film, and perhaps optimally all being within the third range (i.e., the narrowest range) noted above for each such film. In addition, the present lowE panel preferably has both a solar transmission of between <NUM>% and <NUM>% and a solar heat gain coefficient of between <NUM> and <NUM>. This can optionally be in combination with: (i) the low solar heat gain coating <NUM> having an emissivity of less than <NUM>, and (ii) the present lowE panel having a UV transmission of less than <NUM>%. Furthermore, the present lowE panel can optionally also have an exterior visible reflectance Rv, e of about <NUM>-<NUM>, an interior visible reflectance Rv, i of about <NUM>-<NUM>, or both.

The present discussion of color properties is reported using the well-known color coordinates of "a" and "b. " In more detail, the color coordinates are indicated herein using the subscript h (i.e., ah and bh) to represent the conventional use of the well-known Hunter Lab Color System (Hunter methods/units, Ill. D65, <NUM> degree observer). The present color properties can be calculated as specified in "<NPL>). For purposes of the present disclosure, the chroma magnitude number is defined as the square root of [a<NUM> + b<NUM>].

In one group of embodiments, the laminated glass panel <NUM> has an exterior reflected color characterized by a chroma magnitude number of less than <NUM>. As one example, when the present panel employs coating <NUM> in the form of the first exemplary film stack tabulated above, the exterior reflected color is characterized by a chroma magnitude number of about <NUM>. As another example, when the present lowE panel employs coating <NUM> in the form of the first exemplary film stack tabulated above, the exterior reflected color is characterized by a chroma magnitude number of about <NUM>. Given the present teachings as a guide, skilled artisans will be able to provide various other ITO-based coatings to achieve the low chroma magnitude number of this embodiment group. In the present group of embodiments, the low solar heat gain coating <NUM> preferably comprises two indium tin oxide films. In more detail, the low solar heat gain coating <NUM> in these embodiments preferably comprises, in sequence moving toward the interlayer, a first indium tin oxide film, a first nickel compound film, a second indium tin oxide film, a second nickel compound film, and an overcoat layer. Preferably, the first indium tin oxide film <NUM> has a thickness of between <NUM>Å and <NUM>Å, the first nickel compound film <NUM> has a thickness of between <NUM>Å and <NUM>Å, the second indium tin oxide film <NUM> has a thickness of between <NUM>Å and <NUM>Å, and the second nickel compound film <NUM> has a thickness of between <NUM>Å and <NUM>Å.

The invention also provides methods for producing the low solar heat gain coating <NUM>. In the present methods, a substrate <NUM> having a surface <NUM> is provided. If desired, this surface <NUM> can be prepared by suitable washing or chemical preparation. The coating <NUM> is deposited on the surface <NUM> of the substrate <NUM>, e.g., as a series of discrete layers, as a thickness of graded film, or as a combination including at least one discrete layer and at least one thickness of graded film. The coating can be deposited using any thin film deposition technique that is suitable for depositing the desired film materials at the desired thicknesses. Thus, the present invention includes method embodiments wherein, using any one or more suitable thin film deposition techniques, the films of any embodiment disclosed herein are deposited sequentially upon a substrate (e.g., a sheet of glass or plastic) <NUM>. In preferred embodiments, the films are deposited by sputtering. Sputtering is well known in the present art. One preferred method uses DC magnetron sputtering, which is commonly known in industry. Reference is made to Chapin's <CIT>. In some cases, the present coatings are sputtered by AC or pulsed DC from a pair of cathodes. HiPIMS and other modern sputtering methods can be used as well.

Briefly, magnetron sputtering involves transporting a substrate <NUM> through a series of low pressure zones (or "chambers" or "bays") in which the various films that make up the coating are sequentially applied. To deposit oxide film, the target may be formed of an oxide itself, and the sputtering may proceed in an inert or oxidizing atmosphere. To deposit indium tin oxide, for example, a ceramic indium tin oxide target can be sputtered in an inert or oxidizing atmosphere. Alternatively, the oxide film can be deposited by sputtering one or more metallic targets (e.g., of metallic indium tin material) in a reactive atmosphere. Nickel alloy film (e.g., Ni-Al) can be deposited by sputtering one or more nickel alloy (e.g., Ni-Al) targets. Silicon nitride can be deposited by sputtering one or more silicon targets (which may be doped with aluminum or the like to improve conductivity) in a reactive atmosphere containing nitrogen gas. Silicon oxynitride can be deposited by sputtering one or more silicon targets (which may be doped with aluminum or the like) in a reactive atmosphere containing oxygen and nitrogen gas. Tin oxide can be deposited by sputtering one or more tin targets in a reactive atmosphere containing oxygen gas. The thicknesses of the deposited films can be controlled by varying the speed of the substrate, by varying the power on the targets, or by varying the ratio of power to partial pressure of the reactive gas.

Following is a first non-limiting process for depositing one embodiment of the low solar heat gain coating <NUM> onto a glass pane. A pair of rotatable metallic indium-tin targets is sputtered while an uncoated glass pane is conveyed past the activated targets at a rate of about <NUM> (<NUM> inches) per minute when depositing the first indium tin oxide film <NUM>. In this example, the relative weight amounts of the two metals in the sputterable material of the target is: indium <NUM>%, tin <NUM>%. Here, a power of <NUM> kW is used for the pair of rotary targets. The sputtering atmosphere is <NUM> Pa (<NUM> mTorr) with a gas flow of <NUM>% argon and <NUM>% oxygen. The resulting indium tin oxide film has a thickness of about <NUM>Å. Directly over this first ITO film, a first nickel-aluminum film is applied. Here, the nickel-aluminum is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute past a pair of rotary Ni-Al targets sputtered at <NUM> kW in a <NUM> Pa (<NUM> mTorr) atmosphere with a gas flow of <NUM>% argon. Directly over the first nickel-aluminum film, a second indium tin oxide film is applied. A pair of rotatable metallic indium-tin targets is sputtered while the glass pane is conveyed past the activated targets at a rate of about <NUM> (<NUM> inches) per minute when depositing the second indium tin oxide film. The relative weight amounts of the two metals in the sputterable material of the target is: indium <NUM>%, tin <NUM>%. A power of <NUM> kW is used for the pair of rotary targets. The sputtering atmosphere is <NUM> Pa (<NUM> mTorr) with a gas flow of <NUM>% argon and <NUM>% oxygen. The resulting indium tin oxide film has a thickness of about <NUM>Å. Directly over this second ITO film, a second nickel-aluminum film is applied. Here, the nickel-aluminum is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute past a pair of rotary Ni-Al targets sputtered at <NUM> kW in a <NUM> Pa (<NUM> mTorr) atmosphere with a gas flow of <NUM>% argon. Finally, a silicon oxynitride film is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute in two passes beneath a pair of rotary silicon targets (<NUM>% Si, <NUM>% Al, by weight) sputtered at <NUM> kW in a <NUM> mTorr atmosphere with a gas flow of <NUM>% nitrogen and <NUM>% oxygen.

Following is a second non-limiting process for depositing another embodiment of the low solar heat gain coating <NUM> onto a glass pane. A pair of rotatable metallic indium-tin targets is sputtered while an uncoated glass pane is conveyed past the activated targets at a rate of about <NUM> (<NUM> inches) per minute when depositing the first indium tin oxide film. The relative weight amount of the two metals in the sputterable material of the target is: indium <NUM>%, tin <NUM>%. Here, a power of <NUM> kW is used for the pair of rotary targets. The sputtering atmosphere is <NUM> Pa (<NUM> mTorr) with a gas flow of <NUM>% argon and <NUM>% oxygen. The resulting indium tin oxide film has a thickness of about <NUM>Å. Directly over this first ITO film, a first nickel-aluminum film is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute past a pair of rotary Ni-Al targets sputtered at <NUM> kW in a <NUM> Pa (<NUM> mTorr) atmosphere with a gas flow of <NUM>% argon. Directly over the first nickel-aluminum film, a second indium tin oxide film is applied. A pair of rotatable metallic indium-tin targets is sputtered while the glass pane is conveyed past the activated targets at a rate of about <NUM> (<NUM> inches) per minute when depositing the second indium tin oxide film. Here again, the relative weight amounts of the two metals in the sputterable material of the target is: indium <NUM>%, tin <NUM>%. A power of <NUM> kW is used for the pair of rotary targets. The sputtering atmosphere is <NUM> Pa (<NUM> mTorr) with a gas flow of <NUM>% argon and <NUM>% oxygen. The resulting indium tin oxide film has a thickness of about <NUM>Å. Directly over this second ITO film, a second nickel-aluminum film is applied. Here, the nickel-aluminum is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute past a pair of rotary Ni-Al targets sputtered at <NUM> kW in a <NUM> Pa (<NUM> mTorr) atmosphere with a gas flow of <NUM>% argon. Finally, a silicon nitride film is applied at a thickness of about <NUM>Å by conveying the glass pane at about <NUM> (<NUM> inches) per minute in two passes beneath a pair of rotary silicon targets (<NUM>% Si, <NUM>% Al, by weight) sputtered at <NUM> kW in a <NUM> Pa (<NUM> mTorr) atmosphere with a gas flow of <NUM>% nitrogen.

Once the glass pane has been coated, it preferably is heat treated. Various heat treatment processes can be used. For example, the coated pane can be heat treated on a conventional production tempering line. In tempering, glass is placed in a furnace maintained at about <NUM>-<NUM> (preferably controlled to <NUM>-<NUM>). The glass is typically held in the furnace for <NUM>-<NUM> seconds with constant movement to better ensure temperature uniformity of the product. This is intended to raise the glass temperature to about <NUM>. The glass is then removed from the furnace and placed in a stream of air for about <NUM> seconds such that the glass is cool enough for an operator to handle. Another option is to heat treat the coated glass pane by a flash treatment method of the type described above. Moreover, as already explained, the substrate can alternatively be heated prior to film deposition, during deposition, or both.

Claim 1:
A coated glass pane having a surface that bears a low solar heat gain coating, the low solar heat gain coating comprising, in sequence moving outwardly from the surface, a first indium tin oxide film, a first nickel compound film, a second indium tin oxide film, a second nickel compound film, and an overcoat layer, the first indium tin oxide film having a thickness of between <NUM>Å and <NUM>Å, the first nickel compound film having a thickness of between <NUM>Å and <NUM>Å, the second indium tin oxide film having a thickness of between <NUM>Å and <NUM>Å, and the second nickel compound film having a thickness of between <NUM>Å and <NUM>Å, wherein the first nickel compound film is in contact with both the first and second indium tin oxide films.