Patent Description:
The relative ease of manufacture of plastics, coupled with its wide functionality has made plastics a widely accepted material. Indeed, plastics have penetrated all industries as the preferred packaging material. However, the last decade has seen growing concerns surrounding the accumulation of non-biodegradable material, including plastics, and therefore a large amount of research has been focussed on recycling techniques for making plastic-use more sustainable.

<CIT> reveals process for recycling plastic waste comprising segregation of cleaned waste, grinding and vent extrusion to obtain molten plastic which can be re-used. Typically, plastic may only be recycled with other plastics having similar chemical and physical properties, such as backbone structure, and density. Therefore, non-cumbersome segregation of plastic waste is of high importance, especially in the scenario of day-to-day usage of large and variety of plastics.

Further, laminated plastic material is noted to allow enhancement of properties, for instance a multi-layer material may allow inclusion of aesthetic layer along with chemico-mechanical stability. In this regard, plastic laminated tubes or lamitubes are noted to have a wide market-reach with applications including cosmetic and nutraceuticals packaging.

<CIT> reveals laminated tube comprising high density polyethylene (HDPE), ethylene vinyl alcohol (EVOH) and at least one compatibilizer. Said tubes are noted to have <NUM>-<NUM>% HDPE.

A tube largely made up of HDPE, has advantages of high mechanical strength. Also, such tubes can be readily recycled as part of the HDPE stream, thus making them highly favourable. However, on the flip side, such tubes are noted to possess the problems with ovality, i.e., such tubes are noted to be too stiff (due to high HDPE content) to process into a perfectly circular shape.

Although, considerable efforts have been made to overcome this problem, the present state of the art still requires a plastic packaging material that, in addition to being mechanically strong is also flexible and can be easily molded in the desired shape.

<CIT> discloses a recyclable package including an outer layer consisting essentially of a first high-density polyethylene (HDPE), an inner layer including a second HDPE, a barrier layer positioned between the outer layer and the inner layer. The outer layer and the inner layer do not include a low-density polyethylene (LDPE), a linear low-density polyethylene (LLDPE), a medium-density polyethylene (MDPE), or a polypropylene (PP).

<CIT> discloses a packaging laminate having a first laminate layer and a second laminate layer, wherein the first laminate layer is a co-extruded composite, elongated in the machine direction, consisting of a substrate layer having a high HDPE component of at least <NUM> % by volume, a connecting layer and a barrier layer consisting of a barrier polymer, preferably polyamide or ethylene vinyl alcohol copolymer.

<CIT> discloses a fuel container comprising a laminate having at least one layer comprising an ethylene/vinyl alcohol copolymer (A) and layers comprising a thermoplastic resin (B) arranged on both sides of the layer comprising the ethylene/vinyl alcohol copolymer (A).

<CIT> discloses the production and use of a laminate for tube and container structures, whereby the containers are defined with a rotationally symmetric limit dimensioning by the smallest commercial diameter D = <NUM>, the smallest shoulder radius R = <NUM> and by the largest possible shoulder angle of α = <NUM>°.

<CIT> discloses a recyclable food package prepared using a polyethylene structure having a first web and a second web, each web containing at least one layer of High Density Polyethylene (HDPE) to provide stiffness. The outer web also contains a layer of lower density polyethylene for improved optical properties.

<CIT> discloses a multi-layer film and packaging, including heavy duty sacks made therefrom, including a mLLDPE-containing skin layer and a core layer that includes both HDPE and mLLDPE.

<CIT> discloses a resin laminate structure comprising a layer of a polymer selected from the group consisting of polyolefins and saponified products of ethylene-vinyl acetate copolymers and a layer of a blend comprising (A) a polyolefin and (B) a saponified product of an ethylene-vinyl acetate copolymer, at an A:B mixing weight ratio ranging from <NUM>:<NUM> to <NUM>:<NUM>.

<CIT> discloses a recyclable package such as a Stand Up Pouch (SUP) which is prepared using a coextruded polyethylene structure having a first surface layer, a first intermediate layer, a second intermediate layer, and a second surface layer which is a sealable layer. The coextruded structure contains two layers of High Density Polyethylene (HDPE) to provide stiffness.

<CIT> discloses collapsible tube containers formed from blown film polymeric material or blown film milti-layer polymeric material, and in particular a nine-layer polymeric material comprising layers of HDPE, MDPE, LDPE and a layer of EVOH.

<CIT> discloses a multilayer structure comprising a first polyethylene layer as a first external layer, a second polyethylene layer as a second external layer and further a layer made of a copolymer of EVOH between the first external layer and the second external layer and a tie layer on each side of the EVOH layer. Furthermore, the tie layers comprise one or more copolymers of ethylene.

In an aspect of the present disclosure, there is provided a lamitube as claimed in claim <NUM>.

In another aspect of the present disclosure, there is a provided a process as claimed in claim <NUM>, for manufacturing the lamitube of the invention.

These and other features, aspects, and advantages of the present subject matter will be better understood with reference to the following description and appended claims. This summary is provided to introduce a selection of concepts in a simplified form.

For convenience, before further description of the present disclosure, certain terms employed in the specification, and examples are collected here. These definitions should be read in the light of the remainder of the disclosure and understood as by a person of skill in the art. The terms used herein have the meanings recognized and known to those of skill in the art, however, for convenience and completeness, particular terms and their meanings are set forth below.

The terms "comprise" and "comprising" are used in the inclusive, open sense, meaning that additional elements may be included. It is not intended to be construed as "consists of only".

The term "including" is used to mean "including but not limited to", "including" and "including but not limited to" are used interchangeably.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this disclosure belongs. Although methods and materials similar or equivalent to those described herein can be used in the practice or testing of the disclosure, the preferred methods, and materials are now described.

Ratios, concentrations, amounts, and other numerical data may be presented herein in a range format. It is to be understood that such range format is used merely for convenience and brevity and should be interpreted flexibly to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a thickness range of about <NUM> - about <NUM> should be interpreted to include not only the explicitly recited limits of about <NUM> - about <NUM>, but also to include sub-ranges, such as <NUM> - <NUM>, <NUM> - <NUM>, and so forth, as well as individual amounts, including fractional amounts, within the specified ranges, such as <NUM>, <NUM>, and <NUM>, for example.

The term "ovality" used herein refers to the percentage deviation of the lamitubes from conforming to perfectly circular shape.

The term "lamitube" used herein refers to laminated tubes comprising: a) a top layer comprising at least one ethylene polymer; and b) a second layer comprising at least one ethylene polymer having a first surface and a second surface, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

The term "favourable" used herein refers to the lamitubes of the present disclosure being readily recyclable as part of the high density polyethylene (HDPE) code #<NUM> stream with simple methods of segregation or sorting.

The term "heat sealable blocking layer" used herein refers to a barrier layer which can also be used as sealant layer. The examples include, but are not limited to, EVOH barrier layer.

The phrase "at least one ethylene polymer" used herein refers to a combination of high density polyethylene (HDPE) and medium density polyethylene (MDPE). It may also include a polyethylene master batch (MB).

The term "stiffness" used herein refers to the resistance of a material to deformation under an applied force.

The term "young's modulus" used herein refers to the property of a material that is calculated by measuring the ratio of stress to strain incurred in the material. Young's modulus gives a measure of the stiffness of the material or the ease with which it can be stretched or bent. Higher the value of the young's modulus, lesser is the extent to which a material can be stretched or elongated, higher is the stiffness. It is measured in terms of N/m<NUM> or Pascal (Pa).

The term "melt flow index" or "MFI" used refers to the grams of polymer flowing per <NUM> minutes through a capillary tube. It is a measure of the ease of flowing of the polymer melt denoted in terms of g/<NUM>.

The term "density" used herein refers to the mass of polymer present per unit volume of the lamitube. It is measured in terms of g/cm<NUM>.

As mentioned in the background section, there is a need for tubes that can overcome the problem associated with ovality. Multi-layer laminated tubes involving a mixture of low-density plastics can provide a possible solution, however, in such cases the compatibility with HDPE recycle streams is noted to drastically reduce. Therefore, there is need for lamitubes that offer both low ovality and are environmentally friendly to use. The present disclosure provides a lamitube as claimed in claim <NUM>. The present lamitube, having density on the higher side, allows easy recyclability in the HDPE recycling stream. Moreover, despite the high density, the lamitube shows surprisingly low ovality in the range of <NUM> - <NUM>%. Hence, in view of the above-mentioned superior properties, the lamitube of the present disclosure would open new opportunities in the realm of currently used packaging materials. The invention concerns a lamitube comprising: (a) a top layer comprising a resin composition comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE) having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes and a density in the range of <NUM> - <NUM> gm/cm<NUM>; (b) a second layer comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE), having a first surface and a second surface, whereby the meaning of the first and second surface of the second layer is given herein, wherein the second layer is a heat sealable blocking layer comprising <NUM>-<NUM> layers and having a thickness in the range of <NUM> - <NUM>, comprising EVOH having a weight percentage in the range of <NUM> - <NUM>% with respect to the lamitube; wherein the heat sealable blocking layer comprises a core layer, an outer layer, an inner layer, and at least one third adhesive layer; (c) at least one first adhesive layer present between the top layer and the first surface of second layer; (d) a third layer, wherein the third layer is a sealant layer comprising a resin composition comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE) having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes and a density in the range of <NUM> - <NUM> gm/cm<NUM>; and (e) at least one second adhesive layer present between the third layer and the second surface of the second layer; wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>, and has a tube ovality in the range of <NUM>-<NUM>% measured using prefrabricated gauge method,and a thickness in the range of <NUM>-<NUM>.

In an embodiment of the present disclosure, the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>. In another embodiment of the present disclosure, the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the lamitube has a tube ovality in the range of <NUM> - <NUM>%. In another embodiment of the present disclosure, the lamitube has a tube ovality in the range of <NUM> - <NUM>%.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the top layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>. In one another embodiment of the present disclosure, the top layer comprises <NUM>-<NUM> layers. In yet another embodiment of the present disclosure, the top layer has a thickness in the range of <NUM> - <NUM>. In one another embodiment of the present disclosure, the top layer has a thickness in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the top layer has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure there is provided a lamitube as described herein, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM> and the top layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure there is provided a lamitube as described herein, wherein the top layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the second layer comprises <NUM> - <NUM> layers.

In an embodiment of the present disclosure, the heat sealable blocking layer comprises <NUM>-<NUM> layers. In yet another embodiment of the present disclosure, the heat sealable blocking layer comprises <NUM>-<NUM> layers. In one another embodiment of the present disclosure, the heat sealable blocking layer has a thickness in the range of <NUM> -<NUM>. In yet another embodiment of the present disclosure, the heat sealable blocking layer has a thickness in the range of <NUM> -<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the heat sealable blocking layer comprises EVOH having a weight percentage in the range of <NUM>-<NUM>% with respect to the lamitube. In yet another embodiment of the present disclosure, the heat sealable blocking layer comprises EVOH having a weight percentage in the range of <NUM>-<NUM>% with respect to the lamitube. In one another embodiment of the present disclosure, the heat sealable blocking layer comprises EVOH having a weight percentage of <NUM>% with respect to the lamitube.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the sealant layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>. In one another embodiment of the present disclosure, the sealant layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the sealant layer comprises <NUM>-<NUM> layers and has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the core layer, the outer layer, the inner layer, and the at least one third adhesive layer independently is a single or multilayer structure.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer independently has a thickness in the range of <NUM> - <NUM>. In one another embodiment of the present disclosure, the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer independently has a thickness in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer independently has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer comprises ethylene polymer having a density in the range of <NUM> - <NUM> gm/cm<NUM>. In one another embodiment of the present disclosure, the at least one first adhesive layer and the at least one second adhesive layer comprises ethylene polymer having a density in the range of <NUM> - <NUM> gm/cm<NUM>. In yet another embodiment of the present disclosure, the at least one first adhesive layer and the at least one second adhesive layer comprises ethylene polymer having a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer independently has a thickness in the range of <NUM> - <NUM> and the at least one first adhesive layer and the at least one second adhesive layer comprises ethylene polymer having a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure there is provided a as described herein, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM> and the lamitube further comprises a third layer, wherein the third layer is a sealant layer and the at least one first adhesive layer, the at least one second adhesive layer, and the at least one third adhesive layer independently has a thickness in the range of <NUM> - <NUM> and the at least one first adhesive layer and the at least one second adhesive layer comprises ethylene polymer having a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the top layer and the sealant layer independently has a resin composition comprising: a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE)having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes. In yet another embodiment of the present disclosure, the top layer and the sealant layer independently has a resin composition comprising: a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE) having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes. In one another embodiment of the present disclosure, the top layer and the sealant layer independently has a resin composition comprising: a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE)having a density in the range of <NUM> - <NUM> gm/cm<NUM>. In yet another embodiment of the present disclosure, the top layer and the sealant layer independently has a resin composition comprising: a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE)having a density in the range of <NUM> - <NUM> gm/cm<NUM>. In one another embodiment of the present disclosure, the top layer and the sealant layer independently has a resin composition comprising: a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE)having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes and a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the resin composition comprises a colorant master batch having a weight percentage in the range of <NUM> - <NUM>% with respect to the resin composition. In one another embodiment of the present disclosure, the resin composition comprises a colorant master batch having a weight percentage in the range of <NUM> - <NUM>% with respect to the resin composition. In yet another embodiment of the present disclosure, the resin composition comprises a colorant master batch having a weight percentage in the range of <NUM> - <NUM>% with respect to the resin composition. In one another embodiment of the present disclosure, the resin composition does not comprise the colorant master batch.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the colorant master batch comprises at least one pigment selected from the group consisting of titanium dioxide (TiO<NUM>), zinc sulphide (ZnS<NUM>), zinc oxide (ZnO), barium sulfate (BaSO<NUM>), and calcium carbonate (CaCO<NUM>). In another embodiment of the present disclosure, a white colorant master batch is made from titanium dioxide (TiO<NUM>).

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the lamitube has a stiffness in the range of <NUM> - <NUM>. In one another embodiment of the present disclosure, the lamitube has a stiffness in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the lamitube has a stiffness in the range of <NUM> - <NUM>. The stiffness of the lamitube may be tested by TAPPI T556 standard method.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the lamitube has a young's modulus in the range of <NUM> - <NUM> MPa. In one another embodiment of the present disclosure, the lamitube has a young's modulus in the range of <NUM> - <NUM> MPa. In yet another embodiment of the present disclosure, the lamitube has a young's modulus in the range of <NUM> - <NUM> MPa. The young's modulus may be tested by ASTM D882 method.

In an embodiment of the present disclosure there is provided a lamitube as described herein, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM> and the lamitube has a stiffness in the range of <NUM> - <NUM> and the lamitube has a young's modulus in the range of <NUM> - <NUM> MPa.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein lamitube is sustainable.

In an embodiment of the present disclosure, there is provided a lamitube as described herein, wherein the lamitube has a thickness in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the lamitube has a thickness in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure, there is provided a process for manufacturing the lamitube as described herein, said process comprises the steps of forming the layers and laminating the layers together, then slitting into reels of desired width in the range of <NUM> - <NUM>, followed by tubing from the reels. In one another embodiment of the present disclosure, the desired width is in the range of <NUM> - <NUM>. In yet another embodiment of the present disclosure, the desired width is in the range of <NUM> - <NUM>.

In an embodiment of the present disclosure, there is provided a lamitube comprising: a) a top layer comprising <NUM> layers having a total thickness in the range of <NUM> - <NUM> comprising the combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE); b) a second layer comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE and comprising <NUM>-<NUM> layers having a thickness in the range of <NUM> - <NUM>, wherein the second layer is a heat sealable blocking layer comprising EVOH in the weight percentage range of <NUM> - <NUM>% with respect to the lamitube; c) a first adhesive layer present between the top layer and the first surface of the second layer comprising the at least one ethylene polymer having a total thickness in the range of <NUM> - <NUM>; d) a third layer comprising <NUM> layers having a thickness in the range of <NUM> - <NUM>, wherein the third layer is a sealant layer comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE; and e) a second adhesive layer present between the third layer and the second surface of the second layer comprising the at least one ethylene polymer having a total thickness in the range of <NUM> - <NUM>, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube comprising: a) a top layer comprising <NUM> layers having a total thickness in the range of <NUM> - <NUM> comprising: (<NUM>) layer <NUM> comprising a combination of HDPE and MDPE; (<NUM>) layer <NUM> comprising a combination of HDPE, MDPE and optionally a colorant master batch; and (<NUM>) layer <NUM> comprising a combination of HDPE, MDPE and optionally a colorant master batch; b) a second layer comprising <NUM> layers having a thickness in the range of <NUM> - <NUM>, wherein the second layer is a heat sealable blocking layer comprising: (i) a first surface comprising a combination of HDPE, MDPE and optionally a colorant master batch; (ii) layer <NUM> comprising HDPE or LDPE based third adhesive layer; (iii) layer <NUM> comprising EVOH or third adhesive layer; (iv) layer <NUM> comprising EVOH; (v) layer <NUM> comprising EVOH or third adhesive layer; (vi) layer <NUM> comprising HDPE or LDPE based third adhesive layer; and (vii) a second surface comprising a combination of HDPE, MDPE and optionally a colorant master batch, wherein EVOH is in the weight percentage range of <NUM> - <NUM>% with respect to the lamitube; c) a first adhesive layer present between the top layer and the first surface of the second layer comprising the at least one ethylene polymer selected from HDPE, LLDPE, LDPE and combinations thereof having a total thickness in the range of <NUM> - <NUM>, d) a third layer comprising <NUM> layers and a thickness in the range of <NUM> - <NUM>, wherein the third layer is a sealant layer comprising: (I) layer <NUM> comprising a combination of HDPE and MDPE; (II) layer <NUM> comprising a combination of HDPE, MDPE and optionally a colorant master batch; and (III) layer <NUM> comprising a combination of HDPE and MDPE; and e) a second adhesive layer present between the third layer and the second surface of the second layer comprising the at least one ethylene polymer selected from HDPE, LLDPE, LDPE and combinations thereof having a total thickness in the range of <NUM> - <NUM>, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein comprising: a) a top layer having a total thickness of <NUM> comprising <NUM> layers comprising: (<NUM>) layer <NUM> having a thickness of <NUM> comprising a combination of HDPE and MDPE; (<NUM>) layer <NUM> having a thickness of <NUM> comprising a combination of HDPE, MDPE and optionally a colorant master batch; and (<NUM>) layer <NUM> having a thickness of <NUM> comprising a combination of HDPE, MDPE and optionally a colorant master batch; b) a second layer comprising <NUM> layers having a thickness in the range of <NUM> - <NUM>, wherein the second layer is a heat sealable blocking layer comprising: (i) a first surface comprising a combination of HDPE, MDPE and optionally a colorant master batch; (ii) layer <NUM> comprising HDPE or LDPE based third adhesive layer; (iii) layer <NUM> comprising EVOH or third adhesive layer; (iv) layer <NUM> comprising EVOH; (v) layer <NUM> comprising EVOH or third adhesive layer; (vi) layer <NUM> comprising HDPE or LDPE based third adhesive layer; and (vii) a second surface comprising a combination of HDPE, MDPE and optionally a colorant master batch, wherein EVOH is in the weight percentage range of <NUM> - <NUM>% with respect to the lamitube; and c) a first adhesive layer present between the top layer and the first surface of the second layer having a thickness of <NUM> comprising a combination of HDPE and LDPE, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

In an embodiment of the present disclosure, there is provided a lamitube as described herein having a thickness of <NUM> comprising: a) a top layer having a total thickness of <NUM> comprising <NUM> layers comprising: (<NUM>) layer <NUM> comprising a combination of HDPE and MDPE; (<NUM>) layer <NUM> comprising a combination of HDPE, MDPE and <NUM> % white colorant master batch; and (<NUM>) layer <NUM> comprising a combination of HDPE and MDPE; b) a second layer comprising <NUM> layers having a thickness of <NUM>, wherein the second layer is a heat sealable blocking layer comprising: (i) a first surface comprising a combination of HDPE and MDPE; (ii) third adhesive layer comprising a maleic anhydride grafted LLDPE; (iii) core layer comprising EVOH; (iv) third adhesive layer comprising a maleic anhydride grafted LLDPE; and (v) a second surface comprising a combination of HDPE and MDPE, wherein EVOH is in the weight percentage range of <NUM> - <NUM> % with respect to the lamitube; c) a first adhesive layer comprising LDPE present between the top layer and the first surface of the second layer having a thickness of <NUM>, d) a third layer comprising <NUM> layers and a thickness of <NUM>, wherein the third layer is a sealant layer comprising: (I) layer <NUM> comprising a combination of HDPE and MDPE; (II) layer <NUM> comprising a combination of HDPE and MDPE; and (III) layer <NUM> comprising a combination of HDPE and MDPE; and e) a second adhesive layer comprising LDPE present between the third layer and the second surface of the second layer having a thickness of <NUM>, wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>.

Although the subject matter has been described in considerable detail with reference to certain preferred embodiments thereof, other embodiments are possible.

A process of manufacturing the lamitube comprises the steps of forming the layers and laminating the layers together, then slitting into reels of desired width (<NUM> to <NUM>), followed by tubing from the reels. The exemplary lamitubes are illustrated below:.

In further examples, lamitubes having thickness of <NUM>, <NUM>, and <NUM> were prepared with the layer wise distribution as depicted in Table <NUM>. Similarly, other lamitubes with thickness <NUM>, and <NUM> were also prepared and included in testing for the mechanical properties.

Mechanical properties of the lamitubes (as prepared in Example <NUM>) having thickness <NUM>, <NUM>, <NUM>, and <NUM> were tested. Stiffness (mg) and young's modulus of the lamitubes was measured, the results for which are illustrated in Table <NUM>. Comparative tests were conducted on a commercial lamitube having thickness <NUM> and the results are recorded in the Table <NUM> below. The stiffness test was conducted on the lamitubes by following the TAPPI T556 standard method. Young's modulus was measured by following ASTM D882. Similarly, resilience and bounce back tests were also conducted.

It can be observed with the data revealed in Table <NUM> that the stiffness of the lamitubes increased with increasing thickness from <NUM> - <NUM>. On the other hand, the young's modulus of the films did not show any particular trend. It is also clear from the Table <NUM> that the resin selection and orientation method are the primary variables that influence tensile values and thereby the stiffness of the lamitube. The value of young's modulus reflects the tensile modulus. Observing a higher modulus for the lamitube <NUM> having the same thickness as that of the comparative example indicated, that the lamitube was more stiffer and hence, had more resistance to elongation. Moreover, the present lamitubes despite the thickness being on the lower side, i.e., within the range of <NUM> - <NUM>, did not show any reduction in the stiffness of the film.

To ensure that ovality of tubes does not exceed a certain limit, experiments were conducted by two methods, measurement method A and measurement method B. Vernier Calipers with least count of <NUM> were used.

In the mesurement method A, the outside diameter of the tube at the extremity of the shoulder was measured. On the same tube, the outside diameter of the open end of tube (maximum diameter at the open end circumference of the tube) was measured. Caution was taken to read value with the minimum contact between calipers and tube since this can lower the reading.

In the measurement method B, prefrabricated gauge method was used. In this method, ring gauges were made based on the below given formula for percentage out of roundness. Tubes were passed through these ring gauges of specific ovality. If a tube passes through <NUM>% ovality ring gauges and doesn't pass through <NUM>% ovality ring gauge, it implies that ovality of tube is more than <NUM>% and less than <NUM>%. Hence, using the above two methods, the ovality of the present lamitube was found to be in the range of <NUM> - <NUM>%.

Various parameters, such as, melt flow index, density, and screen pack pressure were calculated for the lamitube of the present disclosure. The test methods used for these experiments are listed in the Table <NUM> below.

One of the well-established recycle streams is blow moulded HDPE bottles. The properties of the recycled HDPE resin obtained from present lamitube can be compared with this established recycle stream to establish equivalence in performance.

For this study, the properties of a blend of <NUM>% recycled HDPE lamitube based resin + <NUM>% recycled HDPE blown bottle grade resin (test) was compared with <NUM>% recycled HDPE blown bottle grade (control). Table <NUM> illustrates the results obtained for the <NUM> lamitube and Table <NUM> illustrates the results for <NUM> lamitube.

As can be seen from the Table <NUM> above, both the test lamitubes (<NUM> and <NUM>) obtained from recycled material of the present lamitubes showed equivalent performance as per the standard recycled material. Hence, the present lamitubes can be recycled in code <NUM> (HDPE) stream as the values for all the parameters falls within the specification of the benchmark resin.

The lamitube composition as disclosed in the present disclosure has a high density in the range of <NUM> - <NUM> gm/cm<NUM>, which allows easy recyclability in the HDPE recycling stream. The present lamitubes also overcomes the problem of achieving desired ovality by offering lamitubes having low ovality in the range of <NUM> - <NUM>%. The stiffness of the lamitubes of the present disclosure with thickness in the range of <NUM> - <NUM> is higher almost by <NUM> - <NUM>% as compared to the commercial lamitubes of the same thickness, thereby enabling source i.e., the lamitube thickness is reduced without affecting the essential functionalities such as, stability, stiffness, and elongation in use.

Claim 1:
A lamitube comprising:
(a) a top layer comprising a resin composition comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE) having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes and a density in the range of <NUM> - <NUM> gm/cm<NUM>; and
(b) a second layer comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE), having a first surface and a second surface, whereby the meaning of the first and second surface of the second layer is given in the description,
wherein the second layer is a heat sealable blocking layer comprising <NUM>-<NUM> layers and having a thickness in the range of <NUM> - <NUM>,
comprising EVOH having a weight percentage in the range of <NUM> - <NUM>% with respect to the lamitube;
wherein the heat sealable blocking layer comprises a core layer, an outer layer, an inner layer, and at least one third adhesive layer;
(c) at least one first adhesive layer present between the top layer and the first surface of second layer;
(d) a third layer, wherein the third layer is a sealant layer comprising a resin composition comprising a combination of high-density polyethylene (HDPE) and medium density polyethylene (MDPE) having a melt flow index in the range of <NUM> - <NUM>/<NUM> minutes and a density in the range of <NUM> - <NUM> gm/cm<NUM>; and
(e) at least one second adhesive layer present between the third layer and the second surface of the second layer;
wherein the lamitube has a density in the range of <NUM> - <NUM> gm/cm<NUM>, has a tube ovality in the range of <NUM>-<NUM>% measured using prefrabricated gauge method, and a thickness in the range of <NUM>-<NUM>.