Patent Description:
Kitchen counters made of marble are preferably used as housing equipment, especially kitchen counters from the viewpoint of heat resistance and aesthetics. For example, a sink in which a coating layer made of enamel glass is formed on a base material made of a metal such as stainless steel is also used. However, in recent years, it has been investigated to use a resin molded body having a thermal sprayed ceramic coating on its surface as housing equipment for water used area such as a system kitchen, a unit bath, a washstand, and a toilet from the viewpoint of heat resistance, aesthetics, workability, and lightweight. However, the resin molded body having a thermal sprayed ceramic coating on its surface has a problem that the adhesive property between the resin structure and the thermal sprayed ceramic coating is weak. Hence, Patent Literature <NUM> discloses that a thermal sprayed ceramic coating is formed by forming an intermediate layer containing an inorganic filler having a thermal conductivity of a certain value or more and an organic binder between the resin structure and the thermal sprayed ceramic coating. Patent Literature <NUM> discloses a kitchen counter comprising a resin molded article which comprises a resin structure, an underlayer made of binder and ceramic particles, and a thermal sprayed ceramic coating.

However, the conventional resin molded body having a thermal sprayed ceramic coating on its surface has a problem that the adhesive strength between the thermal sprayed ceramic coating and the resin structure is not sufficient.

Accordingly, an object of the present invention is to provide a resin molded body in which the adhesive strength between a thermal sprayed ceramic coating and a resin structure is high.

In order to achieve the object, the resin molded body according to the present invention includes.

wherein the inorganic filler is amorphous in shape and has a central particle diameter of <NUM> or more and <NUM> or less, wherein the inorganic filler is a crushed inorganic filler and the central particle diameter of the inorganic filler is the particle diameter d50 defined by the median diameter, wherein the particle diameter d50 refers to the volume average particle diameter at which the cumulative volume calculated from the small diameter side is <NUM>% in the particle diameter distribution on a volume basis measured by the laser diffraction method, and wherein the intermediate layer has a thickness of <NUM> or more and <NUM> or less, the central particle diameter a of the inorganic filler and the thickness b of the intermediate layer satisfy the relationship of b ≥ 2a, the inorganic filler is contained in the intermediate layer in an amount of <NUM>% to <NUM>% as a volume ratio, and the surface of the intermediate layer on which the thermal sprayed ceramic coating is formed has irregularities capable of effectively exerting an anchor effect on the thermal sprayed ceramic coating.

According to the present invention configured as described above, it is possible to provide a resin molded body in which the adhesive strength between a thermal sprayed ceramic coating and a resin structure is high.

Hereinafter, a resin molded body of an embodiment according to the present invention will be described with reference to the drawings.

The resin molded body of an embodiment according to the present invention includes, for example, a resin structure <NUM> molded by cast molding, an intermediate layer 10a provided on the resin structure <NUM>, and a thermal sprayed ceramic coating 10c provided on the intermediate layer 10a. The adhesive strength between the thermal sprayed ceramic coating and the resin structure is improved by forming the intermediate layer 10a using an organic resin binder containing an inorganic filler <NUM> and setting the shape of the inorganic filler <NUM>, the central particle diameter of the inorganic filler <NUM>, the amount of the inorganic filler <NUM> contained in the intermediate layer 10a, and the thickness of the intermediate layer 10a as to be described in detail later.

Hereinafter, the resin molded body <NUM> will be described in detail.

In the resin molded body of the embodiment, the resin structure <NUM> is fabricated, for example, by cast molding. As the resin material for the resin structure <NUM>, for example, various thermosetting resins such as an epoxy resin, a vinyl ester resin, an unsaturated polyester resin, and an acrylic resin are used. The resin structure <NUM> may contain an inorganic filler. By containing an inorganic filler, it is possible to improve the heat resistance of the resin structure <NUM> as well as it is possible to lower the coefficient of thermal expansion of the resin structure <NUM> and bring the coefficient of thermal expansion closer to the coefficient of thermal expansion of the thermal sprayed ceramic coating to be deposited later.

In the resin molded body of the embodiment, the intermediate layer 10a is a layer provided between the resin structure <NUM> and the thermal sprayed ceramic coating 10c in order to increase the adhesive strength between the resin structure <NUM> and the thermal sprayed ceramic coating 10c. The intermediate layer 10a is formed of, for example, a resin layer in which an inorganic filler <NUM> such as ceramic particles is added and dispersed. The intermediate layer 10a suppresses transfer of heat at the time of thermal spraying to the resin structure <NUM> and melting or deterioration of the resin. After thermal spraying, the stress caused by the difference in coefficient of thermal expansion between the thermal sprayed ceramic coating 10c and the resin structure <NUM> can be relaxed, and the durability of the resin molded body can be improved. As the organic resin binder <NUM> in the intermediate layer 10a, an epoxy resin, a polyester resin, a polyurethane resin, an acrylic resin, a phenol resin, a urea resin, a melamine resin, or a silicone resin can be used. The organic resin binder is preferably a reaction curable type that is cured by heat, UV or the like when the intermediate layer 10a is formed.

Among these, it is preferable to use an epoxy resin as the organic resin binder <NUM>, and this makes it possible to form a high-strength intermediate layer 10a that is firmly attached to the resin structure <NUM>. An epoxy resin easily attains firm adhesion regardless of the kind of resin forming the resin structure <NUM>. The intermediate layer 10a formed of an epoxy resin exhibits high heat resistance and thus can withstand the heat load applied when forming the thermal sprayed ceramic coating and the heat load when using the molded body in which the thermal sprayed ceramic coating 10c is formed on the resin structure <NUM> as a product and the adhesive strength between the resin structure <NUM> and the ceramic coating 10c can be maintained for a long period of time. As the epoxy resin for organic resin binder <NUM>, an epoxy resin containing at least one or more of a phenol novolac type epoxy resin, a cresol novolac type epoxy resin, a biphenyl type epoxy resin, or a naphthalene type epoxy resin is preferable in addition to a bisphenol A type epoxy resin. In the case of containing these heat resistant organic resin binders, the heat resistance of the intermediate layer 10a is favorable, and deformation of the irregular shape of the intermediate layer 10a at the time of ceramic thermal spraying can be suppressed, or thermal deterioration of the intermediate layer 10a at the time of thermal spraying can be prevented. In this manner, sufficient adhesive strength of the thermal sprayed ceramic coating 10c can be attained. As the epoxy resin for organic resin binder <NUM>, one epoxy resin may be used.

As the inorganic filler <NUM> in the intermediate layer 10a, for example, particles of each of alumina, gray alumina, alumina titania, titania, alumina zirconia, spinel, mullite, and zirconia can be used. It is preferable that the inorganic filler <NUM> in the intermediate layer 10a contains at least one or more selected from a group consisting of alumina and a composite metal oxide containing an aluminum element. It is more preferable to contain at least one or more of inorganic fillers that are the same kind as the material for the thermal sprayed ceramic coating.

It is preferable that the inorganic filler <NUM> in the intermediate layer 10a contains at least one or more selected from a group consisting of aluminum, a metal capable of forming an alloy with aluminum, and an aluminum alloy containing metal elements thereof. Specifically, the inorganic filler <NUM> preferably contains one or more selected from the group consisting of Al, Ni, Cu, Mn, Si, Mg, Zn, and Li. The intermediate layer 10a can be formed by mixing the ceramic particles with the organic resin binder <NUM> and applying the mixture.

In the resin molded body of the embodiment, the adhesive strength between the resin structure <NUM> and the thermal sprayed ceramic coating 10c is increased as the intermediate layer 10a satisfies the following five conditions of the first to fifth conditions.

First condition: the inorganic filler <NUM> is amorphous in shape.

Second condition: the central particle diameter of the inorganic filler <NUM> is <NUM> or more and <NUM> or less.

Third condition: the thickness of the intermediate layer 10a is <NUM> or more and <NUM> or less.

Fourth condition: the central particle diameter "a" of the inorganic filler <NUM> and the thickness "b" of the intermediate layer 10a satisfy the relationship of b ≥ 2a.

Fifth condition: the amount of the inorganic filler <NUM> contained in the intermediate layer 10a is <NUM>% to <NUM>% as a volume ratio.

The fact of the first condition that the inorganic filler <NUM> is amorphous in shape means a non-spherical inorganic filler excluding particles fabricated in a spherical shape by so-called build-up methods such as vapor phase growth and sol-gel methods. Inorganic fillers such as a crushed inorganic filler, a flaky inorganic filler, and a rod-shaped inorganic filler can be mentioned. A crushed inorganic filler and a flaky inorganic filler can be fabricated by, for example, mechanical grinding such as a grinding method, and the rod-shaped inorganic filler can be fabricated by, for example, growth in which the inorganic filler grows at a fast speed in one direction so as to exhibit anisotropy. According to the present invention, a crushed inorganic filler is used as the inorganic filler <NUM>. As an example of the crushed inorganic filler, a scanning electron micrograph of the crushed inorganic filler used in Example <NUM> to be described later is illustrated in <FIG>. As an example of the spherical inorganic filler, a scanning electron micrograph of the spherical inorganic filler used in Comparative Example <NUM> to be described later is illustrated in <FIG>.

In the present invention, a spherical filler can also be used in combination, but the surface roughness is likely to be small and the desired surface roughness cannot be attained when the intermediate layer 10a is formed using only a spherical filler. Inorganic fillers having various aspect ratios are used. One having an aspect ratio of <NUM> or more is preferable from the viewpoint that the surface roughness Rz of the intermediate layer 10a obtained is likely to be large. A powdery inorganic filler is preferred to a fibrous inorganic filler from the viewpoint of application property when forming the intermediate layer 10a. The central particle diameter of the inorganic filler <NUM> in the second condition is the particle diameter (particle diameter d50) defined by the median diameter. In the present invention, the "particle diameter d50" refers to the volume average particle diameter at which the cumulative volume calculated from the small diameter side is <NUM>% in the particle diameter distribution (volume basis) measured by the laser diffraction method.

In the intermediate layer 10a of the embodiment configured as described above, it is possible to form irregularities on the surface of the intermediate layer 10a on which the thermal sprayed ceramic coating 10c is formed as illustrated in <FIG> and to increase the adhesive strength of the thermal sprayed ceramic coating 10c by the anchor effect.

In other words, in the resin molded body according to the present embodiment, the inorganic filler <NUM> satisfying the first condition and the second condition is selected as the inorganic filler <NUM> to be contained in the intermediate layer 10a and the content of the inorganic filler <NUM> with respect to the organic resin binder when forming the intermediate layer 10a is set so as to satisfy the fifth condition. The thickness of the intermediate layer 10a is set so as to satisfy the third condition and the fourth condition. In this manner, irregularities that can effectively exert an anchor effect is formed on the surface of the intermediate layer 10a when the thermal sprayed ceramic coating 10c is formed on the surface of the intermediate layer 10a and the adhesive strength of the thermal sprayed ceramic coating 10c is increased.

In more detail, for example, in the case of forming a thermal sprayed ceramic coating on the surface of a metal substrate, it is possible to secure the adhesive property of the thermal sprayed coating by forming irregularities on the surface of the metal substrate by blasting or machine cutting the surface of the metal substrate and forming a thermal sprayed ceramic coating on this surface.

However, unlike a metal substrate, it is difficult to roughen the surface by blasting or the like in the case of a structure formed of a resin. Generally, resin molding materials contain inorganic fillers and reinforcing fibers added to resins, and these additives may be exposed, a large irregular shape cannot be thus formed, and the strength of the resin base material itself may decrease when it is attempted to mechanically roughen the surface.

Hence, it has been investigated to form an intermediate layer as a ground layer (undercoat layer) on the surface on which the thermal sprayed ceramic coating is formed of the resin structure in order to form irregularities. As a result, it has been found out that the surface of the intermediate layer 10a is provided with irregularities capable of effectively exerting an anchor effect on the thermal sprayed ceramic coating 10c when the intermediate layer 10a is formed so as to satisfy the first to fifth conditions, and the present invention has been completed.

In other words, the surface shape of the intermediate layer 10a formed on the resin structure is closely related to the shape, central particle diameter, and content of the inorganic filler <NUM> to be contained in the intermediate layer 10a and the thickness of the intermediate layer 10a and the adhesive strength of the thermal sprayed coating changes as these conditions change. The surface shape of the intermediate layer 10a can be expressed by the surface roughness Rz, and the surface shape of the surface of the intermediate layer 10a can be a surface roughness Rz that can improve the adhesive strength of the thermal sprayed coating when the intermediate layer 10a is formed so as to satisfy the first to fifth conditions. Specifically, the surface roughness Rz of the surface of the intermediate layer 10a that can improve the adhesive strength of the thermal sprayed coating is preferably <NUM> or more and <NUM> or less, more preferably <NUM> or more and <NUM> or less, still more preferably a range of <NUM> or more and <NUM> or less. The most preferable range of the surface roughness Rz of the surface of the intermediate layer 10a is <NUM> to <NUM>.

As Rz of the surface of the intermediate layer 10a increases, the ceramic particles that melt and adhere during the thermal spraying more easily enter into an irregular shape portion of the intermediate layer 10a and the adhesive strength between the thermal sprayed coating and the resin base material increases. On the other hand, when the surface roughness Rz of the intermediate layer 10a is too large, the strength of the irregular shape portion of the intermediate layer 10a may decrease and the adhesive strength between the thermal sprayed coating and the resin base material may decrease. From this fact, the adhesive strength of the thermal sprayed coating is closely related to the average length Rsm of the roughness curve element representing the pitch-to-pitch distance of the surface roughness in addition to the surface roughness Rz of the intermediate layer 10a. In the range of the surface roughness Rz presented above, Rsm is in a range of <NUM> or more and <NUM> or less, preferably <NUM> or more and <NUM> or less, more preferably in a range of <NUM> or more and <NUM> or less. The most preferable range of the average length Rsm of the intermediate layer 10a is <NUM> to <NUM>.

The surface shape of the intermediate layer 10a is also related to the material composition used when forming the intermediate layer 10a, namely, the amount of the binder resin and the amount of the inorganic filler <NUM>. The amount of the inorganic filler <NUM> contained in the intermediate layer 10a is preferably <NUM>% or more and <NUM>% or less, more preferably <NUM>% or more and <NUM>% or less, still more preferably <NUM>% or more and <NUM> % or less as a volume ratio. The surface roughness Rz can be increased when the amount of the inorganic filler <NUM> contained in the intermediate layer 10a is increased, but the strength of the intermediate layer 10a itself decreases and the adhesive strength decreases or the application property for forming the undercoat layer decreases when the amount of the inorganic filler <NUM> is too large. The same applies to the particle diameter of the inorganic filler <NUM>, and the strength of the intermediate layer 10a itself decreases and the adhesive strength decreases or the application property when forming the intermediate layer 10a decreases when the particle diameter of the inorganic filler <NUM> is too large.

The surface roughness Rz of the intermediate layer 10a tends to increase when the thickness of the intermediate layer 10a is thin, but sufficient adhesive strength cannot be attained when the thickness of the intermediate layer 10a is too thin in comparison with the particle diameter of the inorganic filler <NUM>. On the other hand, the surface roughness Rz of the intermediate layer 10a tends to decrease when the thickness of the intermediate layer 10a is too thick. When the thickness of the intermediate layer 10a is too thick, the inorganic filler <NUM> settles in the intermediate layer 10a and is nonuniformly distributed or the strength of the intermediate layer 10a itself decreases and sufficient adhesive strength cannot be attained. When the particle diameter of the inorganic filler is large and when the content is small, the inorganic filler settles in the coating film immediately after coating in some cases. When settling of the inorganic filler occurs, the surface roughness Rz of the intermediate layer 10a formed after curing tends to be small, and as a result, the thermal sprayed ceramic coating 10c does not have sufficient adhesive strength in some cases. In order to suppress settling of the inorganic filler in the coating material and the coating film before curing, it is preferable to blend an anti-settling agent or a viscosity modifier called a rheology control agent into the coating material. The viscosity modifier is not particularly limited, but those described below may be used. Polyethylene and amide can be used as an organic substance-based viscosity modifier, and bentonite, silica, sepiolite and the like can be used as an inorganic substance-based viscosity modifier. Among these, an amide-based viscosity modifier is preferable from the viewpoint of exhibiting heat resistance and not increasing the viscosity too much.

The resin molded body of the present embodiment has a thermal sprayed ceramic coating on the resin structure. When a ceramic is thermal sprayed to form a thermal sprayed ceramic coating, the coating is formed by high temperature spraying such as plasma spraying as to be described later. The ceramic thermal sprayed material thus melted by plasma spraying or the like collides with and adheres to the surface of the intermediate layer 10a at a significantly high temperature and a high speed to form a thermal sprayed coating. Hence, the surface of the intermediate layer 10a is likely to be deformed as the molten ceramic thermal sprayed material collides at a high speed. For this reason, it is required to set the surface shape and thickness of the intermediate layer 10a on the assumption that deformation occurs at the time of thermal spraying. That is, when the surface roughness Rz is too low, the irregularities of the intermediate layer 10a collapse at the time of thermal spraying and a sufficient anchor effect is not attained in some cases. When the thickness of the intermediate layer 10a is too thin, the thermal sprayed material penetrates through the intermediate layer 10a and reaches the resin structure and sufficient adhesive property is not attained in some cases.

The surface shape of the intermediate layer 10a described above, namely, the surface roughness Rz in a preferable range of the surface of the intermediate layer 10a, is set in consideration of the points described above. The inorganic filler <NUM> satisfying the first condition and the second condition is selected, and the intermediate layer 10a is formed so as to satisfy the third condition and the fourth condition. The content of the inorganic filler contained in the intermediate layer 10a is set so as to satisfy the fifth condition. This makes it possible to form the surface of the intermediate layer 10a in a shape having a surface roughness Rz in a preferable range.

In the resin molded body <NUM> of the embodiment, the thermal sprayed ceramic coating 10c is a coating in which flat ceramic particles <NUM> are fused and deposited between adjacent ones as illustrated in <FIG>. This thermal sprayed ceramic coating 10c is formed as a large number of heated and melted or softened ceramic particles collide with and are sequentially deposited on the surface of the resin structure <NUM> as to be described later. The ceramic material for this thermal sprayed ceramic coating 10c is not particularly limited to the following ones, but alumina, gray alumina, alumina titania, titania, alumina zirconia, spinel, mullite, zirconia and the like can be used. The thickness of the thermal sprayed ceramic coating 10c is, for example, in a range of <NUM> to <NUM>, preferably in a range of <NUM> to <NUM>, more preferably in a range of <NUM> to <NUM> when the uniformity of the thickness of the thermal sprayed ceramic coating on the base material and coating strength are regarded as important. The thickness of the thermal sprayed ceramic coating 10c is in a range of <NUM> to <NUM>, preferably <NUM> to <NUM>, more preferably <NUM> to <NUM> when the adhesive property between the ceramic thermal sprayed coating and the base material, the cracking of the ceramic thermal sprayed coating, and the material cost required for thermal spraying processing are regarded as important.

As described above, the thermal sprayed ceramic coating 10c is a coating in which the flat ceramic particles <NUM> are fused and deposited between adjacent ones and thus there are pores (gaps) between the ceramic particles <NUM> after thermal spraying. This thermal sprayed ceramic coating 10c may contain a resin filled in the gap portion. A resin <NUM> filled in the gap portion between the ceramic particles <NUM> can prevent water or oil from entering the inside of the thermal sprayed ceramic coating 10c and further improve the durability. The resin <NUM> filled in the gap portion of the thermal sprayed ceramic coating 10c is preferably a curable resin or a resin containing fluorine or silicon, and this makes for the thermal sprayed ceramic coating 10c hardly get dirty and facilitates cleaning.

The surface of the thermal sprayed ceramic coating 10c is preferably a polished surface, this provides excellent aesthetics, can suppress the attachment of dirt, and facilitates cleaning.

Next, a method for manufacturing the resin molded body <NUM> will be described with reference to <FIG>.

In the present manufacturing method, the resin structure <NUM> is first fabricated by molding. For example, the resin structure <NUM> is fabricated by injecting a monomer resin into the cavity of a clamped mold and curing the monomer resin (cast molding). The method for molding the resin structure <NUM> is not limited to cast molding and may be, for example, press molding or injection molding.

Next, at least the part on which the thermal sprayed ceramic coating 10c is formed of the surface of the resin structure <NUM> is roughened (<FIG>). Specifically, the surface is roughened by sandblasting, etching, or polishing with sandpaper so that, for example, the surface roughness should be Rz = <NUM> to <NUM>, preferably Rz = <NUM> to <NUM>, more preferably Rz = <NUM> to <NUM>.

This roughening can increase the adhesive property between the resin structure <NUM> and the intermediate layer 10a. The adhesive property between the resin structure <NUM> and the intermediate layer 10a can be further increased by roughening the surface so as to have a surface roughness in the above range.

Next, the intermediate layer 10a is formed on the roughened surface of the resin structure <NUM> (<FIG>). The intermediate layer 10a is formed by, for example, mixing the inorganic filler <NUM> such as alumina with the organic resin binder <NUM> and applying the mixture. The shape of the inorganic filler <NUM> is amorphous, and the central particle diameter of the inorganic filler <NUM> is <NUM> or more and <NUM> or less. The above-mentioned epoxy resin can be used as the organic resin binder <NUM>. This mixture of the organic resin binder <NUM> and the inorganic filler <NUM> can be appllied on the roughened surface of the resin structure <NUM> by spray coating, coating with a coater, brush coating or the like. The surface roughness Rz and average length Rsm of the intermediate layer 10a in the present invention are required to be controlled while the intermediate layer 10a has a thickness of a certain value or more, and it is thus more preferable to form the intermediate layer 10a by spray coating among the coating methods. The intermediate layer 10a is formed so that the blended volume percentage of the organic resin binder <NUM> to the ceramic particles after drying is preferably <NUM>% or more and <NUM>% or less, more preferably <NUM>% or more and <NUM>% or less, still more preferably <NUM>% or more and <NUM>% or less.

The intermediate layer 10a is formed so that the thickness is <NUM> or more and <NUM> or less and the central particle diameter "a" of the inorganic filler <NUM> and the thickness "b" of the intermediate layer 10a satisfy the relationship of b <NUM>2a.

The thermal sprayed ceramic coating 10c is formed by allowing the melted or softened ceramic particles to collide with the intermediate layer 10a using the thermal spraying gun <NUM> to deposit the ceramic particles. The thermal spraying method can be selected from various thermal spraying methods such as flame spraying, arc spraying, laser spraying, and plasma spraying in consideration of the thermal spraying target, the working environment, and the like.

In the thermal spraying process, different ceramic particles may be simultaneously thermal sprayed using a plurality of thermal spraying guns <NUM> to form the thermal sprayed ceramic coating 10c. In this manner, for example, it is possible to impart changes in color of the surface and thus to improve the decorativeness. In the thermal spraying process, different ceramic particles may be alternately thermal sprayed using a plurality of thermal spraying guns to form the thermal sprayed ceramic coating 10c. In this manner, for example, it is possible to form a thermal sprayed ceramic coating having a plurality of functions such as corrosion resistance and heat resistance at the same time.

A resin is impregnated (filled) into the pores of the thermal sprayed ceramic coating 10c formed by thermal spraying and the resin is cured (sealing treatment). As the resin to be impregnated, for example, an epoxy resin, an acrylic resin, a silicone resin or the like can be used. In this sealing treatment, when the thermal sprayed ceramic coating 10c is formed by thermal spraying, the coating immediately after thermal spraying has pores with a porosity of, for example, <NUM>% to <NUM>%. When such pores are present, there is a possibility that a substance that causes corrosion reaches the resin structure <NUM> through the pores and corrodes the resin structure <NUM>. The sealing treatment is performed to prevent this. When a resin is contained in the pores of the thermal sprayed ceramic coating 10c, namely, the gap portions, the pores are blocked, and the gap portions are not contaminated, and cleaning is easy.

The resin molded body of the embodiment can be fabricated through the above processes.

The effects of the present invention were confirmed by the following Examples.

In Examples, a <NUM>-thick unsaturated polyester-based fiber-reinforced resin molded plate was first prepared as a resin structure.

Intermediate layer materials for forming the intermediate layers in Examples <NUM> to <NUM> and Comparative Examples <NUM> to <NUM> were each prepared.

The configurations of the materials for intermediate layer formation in Examples <NUM> to <NUM> and Comparative Examples <NUM> to <NUM> and the properties (film thickness, surface roughness Rz, Rsm) of the intermediate layers are presented in Table <NUM>.

The trade names of fillers presented in Table <NUM> are the following fillers, respectively.

<FIG> illustrates a scanning electron micrograph of the crushed inorganic filler (AF180) used in Example <NUM>, and <FIG> illustrates a scanning electron micrograph of the spherical inorganic filler (AX75-<NUM>) used in Comparative Example <NUM>.

Here, the particle diameter d50 of the inorganic filler was measured by the laser diffraction method described above under the following measurement conditions.

Specifically, <NUM> of the inorganic filler was weighed, and the particle diameter distribution of the weighed inorganic filler was measured using a laser diffraction/scattering type particle diameter distribution measuring apparatus (Model number "Microtrac MT3300EX-II" manufactured by Nikkiso Co. The central particle diameter (d50) at which the cumulative volume calculated from the small diameter side is <NUM>% in each particle diameter distribution (volume basis) measured is presented in Table <NUM> as the particle diameter (µm) of the filler used as a raw material.

The range of the filler particle diameter is presented by the minimum value and maximum value in each particle diameter distribution measured above.

<NUM> to <NUM> of the blended proportions of coating materials presented in Table <NUM> indicate that the coating materials are each blended at the proportions presented in Table <NUM>. The blended proportions in Table <NUM> are presented as a weight ratio.

As the coating material for intermediate layer 10a formation, the epoxy resin, curing agent, diluent, and viscosity modifier presented in Table <NUM> were weighed so as to be at the proportions presented in Table <NUM>, and uniformly stirred using a disperser. Next, a filler was added thereto, and the mixture was stirred using a disperser until the filler was uniformly dispersed to prepare a coating material for intermediate layer.

In Examples <NUM> to <NUM>, the coating materials No. <NUM> to No. <NUM> presented in Table <NUM> were applied to a <NUM> × <NUM> square unsaturated polyester-based fiber-reinforced resin molded plate (FRP) in predetermined thicknesses using an applicator capable of adjusting the film thickness by adjusting the interval.

The unsaturated polyester-based fiber-reinforced resin molded plate (FRP) coated with the coating material for intermediate layer 10a formation was subjected to a heat treatment at <NUM> for <NUM> hours in a drying furnace and then further subjected to a heat treatment at <NUM> for <NUM> minutes to fabricate a resin structure having an intermediate layer formed.

In Examples <NUM> and <NUM>, the coating material No. <NUM> presented in Table <NUM> was applied to a <NUM> × <NUM> square FRP in a predetermined thickness using a spray coating apparatus. W200-<NUM> (manufactured by ANEST IWATA Corporation) was used as a spraying gun, and spray coating was performed at a spraying air pressure of <NUM> MPa. In Examples <NUM> and <NUM>, spray coating was performed by adjusting the distance from the tip of the spraying gun to the FRP in order to adjust the surface roughness Rz and Rsm of the intermediate layer 10a. After that, the FRP coated with the coating material for intermediate layer 10a formation by spray coating was subjected to a heat treatment at <NUM> for <NUM> hours in a drying furnace and then further subjected to a heat treatment at <NUM> for <NUM> minutes to fabricate a resin structure having an intermediate layer formed.

A thermal sprayed material (white alumina, product name: SURPREX AW50 (-<NUM>+<NUM>) manufactured by FUJIMI CORPORATION) was thermally sprayed on each of the intermediate layers under the following conditions to form a thermal sprayed ceramic coating.

Under the above conditions, the number of passes, the amount of the thermal sprayed material supplied, and the operation speed of the coating target were appropriately adjusted to form the thermal sprayed ceramic coating so that the film thickness was the film thickness presented in Table <NUM>.

The adhesive strengths of the thermal sprayed ceramic coatings formed on the intermediate layers in Examples <NUM> to <NUM> and Comparative Examples <NUM> to <NUM> are presented in Table <NUM>.

Here, the adhesive strength was measured by the evaluation method prescribed in JIS K-<NUM>-<NUM>-<NUM>.

As presented in Table <NUM>, the adhesive strengths of the thermal sprayed ceramic coatings in Examples <NUM> to <NUM> formed on the intermediate layer 10a satisfying the first to fifth conditions described in the embodiment were practically acceptable. In Examples <NUM> and <NUM>, it is possible to form an intermediate layer having a large Rz and a small Rsm in a thin film thickness since the intermediate layer is formed by spray coating. In this manner, it is possible to provide a resin molded body including a thermal sprayed ceramic coating that is excellent in adhesive property and appearance at low cost.

In contrast to the thermal sprayed ceramic coatings in Examples <NUM> to <NUM> above, the thermal sprayed ceramic coatings in Comparative Examples <NUM> to <NUM> formed on the intermediate layer lacking the first to fifth conditions were not practically acceptable since peeling off thereof occurred immediately after thermal spraying.

Claim 1:
A resin molded body comprising:
a resin structure;
an intermediate layer comprising an inorganic filler and an organic resin binder and provided on a surface of at least a part of the resin structure; and
a thermal sprayed ceramic coating provided on the intermediate layer, wherein
the inorganic filler is amorphous in shape and has a central particle diameter of <NUM> or more and <NUM> or less, wherein the inorganic filler is a crushed inorganic filler and the central particle diameter of the inorganic filler is the particle diameter d50 defined by the median diameter, wherein the particle diameter d50 refers to the volume average particle diameter at which the cumulative volume calculated from the small diameter side is <NUM>% in the particle diameter distribution on a volume basis measured by the laser diffraction method, and
wherein the intermediate layer has a thickness of <NUM> or more and <NUM> or less,
the central particle diameter a of the inorganic filler and the thickness b of the intermediate layer satisfy the relationship of <MAT>
the inorganic filler is contained in the intermediate layer in an amount of <NUM>% to <NUM>% as a volume ratio, and
the surface of the intermediate layer on which the thermal sprayed ceramic coating is formed has irregularities capable of effectively exerting an anchor effect on the thermal sprayed ceramic coating.