Patent Description:
It is known that, thanks to their particular characteristics, such as the high energy and power density in small volumes, lithium batteries have become the most used power supply system for portable electronics devices. As a result, the massive and ubiquitous presence of rechargeable lithium batteries in portable consumer electronic devices, such as mobile phones, tablets and laptops, and the expected rapid growth in the number of vehicles based on electric engines (EV) and hybrid engines (HEV), represents a significant challenge for the correct disposal and recovery of valuable materials contained in lithium cells. In fact, it is expected that the automotive lithium cell market can reach revenues of about <NUM> billion dollars in <NUM>, equal to about half of the total volume of lithium batteries (about <NUM> billion dollars), with a <NUM>% annual growth starting from <NUM>. As far as portable devices are concerned, about <NUM> billion smartphones, <NUM> million tablets and <NUM> million portable PCs are put on the market every <NUM> months, with numbers constantly growing. Almost <NUM>% of all the world production of lithium (about <NUM> tons) is currently used for the production of lithium batteries.

With the increase in production and use of these batteries, the development of industrial processes capable of allowing their disposal and recovery is becoming increasingly important. In particular, these processes should be as responsive as possible to the concept of sustainability, including economic, environmental and social assessments<NUM>,<NUM>.

Lithium-ion batteries (cells) are storage devices of an electrochemical form of energy, consisting of an anode, a separator and a cathode. The anode is generally constituted by elemental lithium reversibly intercalated in the interplanar spaces of the crystalline lattice of high crystallinity carbononium materials (for example graphite); the separator consists of a polymeric membrane (generally polypropylene or polyvinylidene difluoride, PVDF) permeable to lithium ions; the electrolyte consists of a lithium salt (generally lithium salts soluble in an organic environment such as, for example, LiBF<NUM> or LiPF<NUM>) dissolved in an organic aprotic solvent, with a wide electrochemical stability window (such as diethylcarbonate), but also with non-negligible characteristics of volatility and flammability; the cathode, on the other hand, is generally made up of oxides or insoluble salts of transition metals, capable of reversibly intercalating the lithium in their crystalline lattice, such as, for example, LiCoO<NUM>, LiFePO<NUM> and various mixed oxides such as LiCoxNiyMnzO<NUM>. There is also a binder that allows the perfect adhesion of the powders constituting the two electrodes to the aluminum and copper, metal collectors, respectively to the cathode and to the anode. Externally, there may be an electronic management system, often referred to as BMS.

The presence of elementary lithium, flammable volatile organic solvents and high energy density, poses serious risks for the safety of the operators during the treatment of the batteries in the waste cycle or in their recovery. Elemental lithium, if exposed to air, is able to react violently with oxygen producing a lot of heat and causing violent vaporizing or, in some cases, ignition of organic solvents present in the electrolyte. In addition, some materials present in the batteries, such as LiCoO<NUM>, can decompose and release elemental oxygen, if exposed to high heat sources, further increasing the risk of fire or explosion. Finally, disassembly can generate accidental short circuits that also entail risks of fire or explosion.

Currently, according to the prior art, the methods of securing lithium batteries at the end of their life can be grouped into three main categories: i) reduction of the residual charge<NUM>-<NUM>; ii) heat treatments<NUM>-<NUM> and iii) mechanical treatments in controlled environments<NUM>,<NUM>.

The discharge of the batteries (or reduction of the residual charge) can be obtained by various methods, in particular: i) by immersing the cells in a conductive electrolytic solution<NUM>-<NUM>; ii) by manual discharge via a dedicated device<NUM>,<NUM>.

The heat treatments, on the other hand, can exploit the heat, to evaporate the flammable organic solvents, obtaining their removal, or otherwise they can use cryogenic liquids (such as liquid nitrogen) to drastically reduce their reactivity<NUM>-<NUM>.

Finally, the methods that operate in a controlled environment reduce the risks, operating in an inert atmosphere<NUM>,<NUM>, or in the presence of large quantities of water<NUM>,<NUM>.

Each of the methods previously listed presents, however, some disadvantages.

The reduction of the residual charge by immersion in conductive solutions, often composed of solutions of NaCl<NUM>,<NUM>,<NUM>, NaOH<NUM> or FeCl<NUM><NUM>, can be prevented by the presence of BMS. In addition, this method can generate the production of toxic gases (such as chlorine) and sludges containing heavy metals, resulting from corrosion reactions of the external hull terminals. Moreover, due to this corrosion, the solution can contain a quantity of non-negligible lithium ions and therefore a significant loss of lithium to be recovered.

The securing of the cells by manual discharge, obtainable by means of dedicated devices<NUM> or by short-circuiting, is exempt from the problems described above, but requires the intervention of an operator and the use of suitable devices, entailing high processing costs and dedicated personnel.

Thermal treatments for the removal of organic solvents present high costs, due to heating and, above all, they present the need to reduce the emissions of highly toxic gases, such as CO, HF and PFs, deriving from the decomposition of the polymeric separators and of the and binder<NUM>, <NUM>. The heat treatment, however, is not completely free of risks: in fact, it is possible to generate explosions, since the heating can lead to an increase in pressure inside the cells, in the event that the vent valve is faulty.

The use of cryogenic liquids presents, in addition to the high cost thereof, also safety problems for operators, such as the risk of asphyxiation and burns.

Processes operating in a controlled environment employ appropriate gases, such as nitrogen or carbon dioxide, to deprive of oxygen the environment in which batteries are fragmented. Alternatively, it is possible to use high amounts of water as a means of dispersing heat, avoiding the generation of flames. The first processes are affected by problems of operator safety and by a high cost of management, while the latter produce a large quantity of wastewater, to be treated appropriately, and introduce a further phase of separation of materials<NUM>-<NUM>,<NUM>.

Many patents, based on hydrometallurgical<NUM>,<NUM>-<NUM> and metallurgical<NUM>,<NUM> processes, describe how to operate on the set of powders, foils and plastic materials, which make up the so called black mass, obtained by disassembling the cells. Other patents, instead, report the treatment of the cathodic powder fraction, omitting the description of obtaining these materials<NUM>,<NUM>,<NUM>,<NUM>.

According to the prior art, processes for the separation of the anodic and cathodic metal collectors (copper and aluminum) from the active materials adhered thereto are described, to allow a more efficient recovery of the same.

In the present description, the methods of detachment of the collectors from the active materials have been classified and subdivided into thermal, physical or wet processes. In the methods of thermal separation, the binder and the separating membrane are pyrolyzed in air or in an inert atmosphere, at temperatures in the range of <NUM> to <NUM>. This treatment degrades the binder, facilitating the detachment of active powder from metal collectors, preventing them from being compromised<NUM>, <NUM>-<NUM>. This system has the disadvantage due to the production of toxic gases such as HF, CO and PF<NUM>, especially in the presence of traces of moisture. These gases require an adequate abatement system, which affects the costs of installation and processing.

Physical detachment methods use mills, cyclones and magnetic separations, followed by densimetric or aerodynamic processes<NUM>,<NUM>,<NUM>-<NUM>. In spite of their intrinsic immediacy, as far as industrial applicability is concerned, a limitation of these methods is due to the fact that the separation is not complete and that, therefore, part of the powder containing the active metals remains attached to the collectors.

In methods in wet conditions, the internal components of the cells are put in contact, under mechanical or ultrasonic agitation, with a liquid agent, able to dissolve or weaken the action of the binder. Some methods include the use of organic solvents such as N-dimethyl formamide (DMF)<NUM>, N-methyl pyrrolidone (NMP)<NUM>-<NUM>, or other solvents<NUM>,<NUM>,<NUM> for the dissolution of the binder, assisted by stirring<NUM>,<NUM>,<NUM>, or ultrasounds<NUM>,<NUM>,<NUM>. Although the separation is more efficient than methods in dry conditions, the solvents normally used are often toxic, expensive and can not be reused over several cycles due to increased solvent viscosity.

Other techniques according to the prior art are based on the surface or total dissolution of the collectors, through the use of acids<NUM>-<NUM> or alkalis<NUM>-<NUM>. These techniques can, however, lead to contamination of the phase of the powders with salts coming from the etching of the collectors.

Following separation, the resulting material is mainly composed of the powders of the electrode materials and can be treated with metallurgical or hydrometallurgical methods. In metallurgical processes, the exhausted cells are generally incinerated, with the aim of destroying plastics, solvents, separators and carbonaceous materials. Following this, the materials are generally recovered as molten metals<NUM>,<NUM>,<NUM>, or by the electrolysis of molten salts<NUM>,<NUM>,<NUM>.

The hydrometallurgical methods provide for the dissolution (leaching) of metals and metal oxides in acid or alkaline solution. In the formulation of acid etching mixtures, a reducing agent is often included, to facilitate the solubilization of metal oxides with high oxidation states (such as, for example, cobalt III oxides). Many methods use sulfuric or hydrochloric acid, in combination with a reducing compound, such as H<NUM>O<NUM><NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM> citric acid<NUM>, sodium thiosulfate or sugars<NUM>.

From this solution, commonly referred to as liquor, metals can be separated by precipitation<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>, extraction in organic solvents<NUM>,<NUM>,<NUM>, electroreduction<NUM>,<NUM>, combinations of these techniques<NUM>,<NUM>,<NUM>,<NUM> or can be used to re-produce cathode materials for batteries<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>,<NUM>.

In this context is inserted the solution according to this invention, which aims to provide a process for the treatment of lithium batteries, designed to overcome the critical issues that plague the processes according to the prior art of recovery of metals contained therein.

These and other results are obtained according to the present invention by proposing a process based on hydrometallurgical techniques, applicable to various types of lithium batteries, regardless of their internal chemistry and the physical dimensions of the batteries themselves.

In particular, the method for treatment of lithium batteries and recovery of the metals contained therein according to the present invention comprises the following steps: completely discharging the single cells by immersion in a conductive solid material, so that the disassembly of the batteries can be conducted in safe conditions; removal of the active materials from metal collectors, non-destructive to the latter, by immersing the black mass in a solution of a weak organic acid; dissolving (by leaching) metals from active powder by using inorganic acids in combination with organic acids having reducing properties; separation of lithium from the other metals present in the liquor, by precipitation of the latter, by using sodium or potassium sulphide; recovery of lithium, by precipitation as carbonate.

The object of the present invention is therefore to provide a hydrometallurgical process for the treatment of lithium batteries and the recovery of the metals contained, which allows to overcome the limits of the processes according to the prior art and to obtain the previously described technical results.

A further object of the invention is that said hydrometallurgical process can be carried out with substantially contained costs.

Not least object of the invention is to propose a hydrometallurgical process for the treatment of lithium batteries and recovery of the metals contained therein that is simple, safe and reliable.

It is therefore a specific object of the present invention a hydrometallurgical process for the treatment of lithium batteries and recovery of the metals contained therein comprising the following steps:.

Preferably, according to the present invention, said solid electric conductor is composed of copper, bronze, brass, iron or steel, aluminum, carbon.

In particular, according to the invention, said step of separating black mass from metal shells can be obtained by manual opening, grinding, cutting or fragmentation.

Moreover, according to the invention, said aqueous solution of a weak organic acid used in said step of removing active powder from metal collectors and from separating membranes is constituted by formic acid in a concentration range comprised between <NUM>,<NUM> and <NUM> in a concentration range comprised between <NUM>:<NUM> a <NUM>:<NUM> with respect to the black mass; preferably at a temperature comprised between <NUM> and <NUM>, with stirring, for a period comprised between <NUM> and <NUM> minutes.

Preferably, according to the invention, said step of leaching provides for the addition of chloridric acid, in such an amount to reach a concentration comprised between <NUM> and <NUM> in solution, preferably at boiling temperature, for a period not shorter than <NUM>.

Always according to the present invention, in said step of precipitation of the transition metals, the pH of the solution can be adjusted within a range of <NUM> to <NUM> by the addition of a solution of an alkaline hydroxide in a concentration comprised between <NUM> and <NUM>%, preferably operating at a temperature comprised between <NUM> and <NUM>.

In particular, according to the invention, said step of acidification of the lithium solution with strong acids involves the pH change to a value lower than <NUM>.

Finally, always according to the present invention, said step of precipitation of lithium as carbonate is operated at a temperature comprised between <NUM> and the boiling temperature.

It is evident the efficacy of the hydrometallurgical process for the treatment of lithium batteries and recovery of the metals contained therein of the present invention, which allows to overcome the limits present in the procedures according to the prior art, with regard to the safety of the cells before disassembling, the detachment of active powder from metal collectors, the leaching of active metals.

In particular, as far as the securing of cells before disassembling is concerned, the hydrometallurgical process for the treatment of lithium batteries and the recovery of the metals contained therein according to the present invention and the relative system provide a step of discharge of the cells by immersion in an electrically conductive solid, with the purpose of creating an electrical contact between the cell terminals. With respect to similar discharge processes according to the prior art (such as for example Chinese patent application No. <CIT>), the hydro-metallurgical process according to the present invention does not require the use of a mixture of water and a conductive medium (coal, iron, copper), which on the one hand can make temperature control easier, but on the other hand would involve the problems related to the previously exposedl iquid discharge methods<NUM>,<NUM>-<NUM>, ie the electrolytic corrosion with sludge formation and possible development of toxic gases, and furthermore, it would be necessary to wash the cells after treatment, to guarantee the elimination of traces of the conductive medium and to prevent the contamination of the internal components of the batteries subjected to subsequent treatments. The procedure according to the present invention, on the other hand, using only a solid dry conductive material, has the following advantages: i) lowering of the cell potential to values close to zero, an acceptable level to prevent the risks of explosion or fire, ii) absence of development of byproducts, and iii) absence of modifications of the conductive material, which is therefore reusable for numerous treatments.

With regard to the detachment of active powder from metal collectors, the process according to the present invention provides for the use of a weak organic acid with reducing properties, preferably formic acid, and consequently, compared to the methods present in literature, is able to overcome the problems related to the separation of dust-collectors for the following reasons: i) the corrosion of the collectors is extremely reduced, while maintaining the efficiency of the detachment process typical of treatments with more aggressive species<NUM>-<NUM>; ii) the costs of the reagents are limited compared to processes using known organic solvents<NUM>,<NUM>-<NUM>; iii) the reproducibility and the efficiency of the detachment process are high compared to dry methods<NUM>,<NUM>,<NUM>-<NUM>; iv) there is no need for a further separation of the active material from the detachment solution (with regard to this last point, one of the greatest potentials of this step consists in the possibility of exploiting the organic acid both for the detachment of active powder, both for its reducing characteristics in the subsequent step of leaching of active metals).

Finally, as far as the leaching of active metals is concerned, the etching formulation proposed in the process according to the present invention is composed of an organic acid with reducing characteristics, in combination with a strong inorganic acid, the process allowing the quantitative dissolution of all the metal species present in powder, with efficiencies comparable to acid etchings much more aggressive known in the prior art (for example aqua regia, HNO<NUM>/HCl in ratio <NUM>/<NUM>, H<NUM>O<NUM>/H<NUM>SO<NUM>), leaving as the only insoluble residue the carbon used in formulation of the electrodes. In this regard it should be noted that the organic acid used in the step of detachment of the powders from the collectors described above, is used as a reducing agent in this step of leaching.

The invention will be described below by way of illustration, but not by way of limitation, with particular reference to some illustrative examples, according to a preferred embodiment, with particular reference to the attached figure, which shows a block diagram of a plant for the execution of the hydrometallurgical process for the treatment of lithium batteries and recovery of the metals contained therein according to the present invention.

With reference to the figure, a plant for the execution of the hydrometallurgical process for the treatment of lithium batteries and the recovery of the metals contaimed therein according to the present invention comprises the following sections: a section for the complete discharge of the individual cells by immersion in a conductive solid material, so that the disassembly can be conducted in safe conditions; a section for the removal of active materials from metal collectors, non-destructive for the latter, by immersing the black mass in a solution of a weak organic acid; a section for dissolving (leaching) metals from active powder by using inorganic acids in combination with organic acids having reducing properties; a section for the separation of lithium from the other metals present in the "liquor" by precipitation of the latter through the use of sodium or potassium sulphide; and a lithium recovery section by precipitation as carbonate.

With regard to the complete discharge of the individual cells of the lithium batteries, the hydrometallurgical process for the treatment of lithium batteries and the recovery of the metals contained therein according to the invention provides that the batteries <NUM> reach a first station <NUM>, where they are deprived of their control and protection circuits <NUM> (BMS), and are then sent to a discharge container <NUM> for discharge of the cells, wherein they are immersed in a solid electric conductor <NUM>, i.e. a solid material, electrically and thermally conductive, for a minimum time equal to <NUM> hours, preferably between <NUM> and <NUM> hours. The term of the procedure can be identified by the sample measurement of the cell potentials or the absence of heat production inside the discharge container <NUM>.

The cells, after being discharged, are disassembled and ground in a grinding station <NUM>. After grinding, the metal shells <NUM> can be removed by means of separation methods which are part of the prior art. The remaining material, referred to as black mass <NUM>, is mainly composed of active materials, supported on copper and aluminum collectors, and polymer separators.

The black mass <NUM> is then subjected to the step of separation of the active electrode materials (coal plus active metals) from the metal collectors into a powder/collector separation reactor <NUM>. The process involves the treatment of the black mass with a solution of a weak acid <NUM> , in particular a weak organic acid (formic acid), in a concentration in the range <NUM>-<NUM> and stirred for <NUM>-<NUM> minutes at a temperature between <NUM> and <NUM> and with a treatment solution/black mass ratio between <NUM>:<NUM> and <NUM>:<NUM> by weight. The optimal conditions identified for this step are: formic acid <NUM>, solution/black mass ratio of about <NUM>:<NUM>, one hour of stirring at <NUM>. This process is able to effectively remove the active materials from the copper and aluminum collectors, without appreciable dissolution of the latter. The humid mixture <NUM> of collectors and detached powders accumulates at the bottom of the separation reactor <NUM>, from which it is sent to a sifter <NUM>, where collectors and polymer membranes <NUM> are separated from the mixture <NUM> of carbonaceous powders containing the active metals in the solution of formic acid.

Collectors and polymeric membranes <NUM> are sent to a washing station <NUM>, where they are subjected to washing with water <NUM>, by which further amounts of carbonaceous particles containing active metals are separated, and then to a drying station <NUM>, to be finally recovered.

The mixture <NUM> is sent to an etching reactor <NUM>, where it is subjected to leaching, or chemical etching, by adding water <NUM> and a mineral acid <NUM>, preferably hydrochloric acid. In this process, the presence of a weak organic acid, appropriately selected with reducing properties (for example formic acid), promotes the reduction of high-valence metal oxides, making them soluble. An amount of mineral acid is added to obtain a concentration between <NUM> and <NUM>, preferably <NUM>. The etching solution <NUM> is subjected to heating under stirring for <NUM>-<NUM> minutes, preferably boiling for <NUM> minutes. Once the etching process has been terminated, the obtained liquid liquor <NUM> is separated from the residues of insoluble carbon materials <NUM> by filtration in a filtering station <NUM>. The insoluble phase <NUM> is mainly constituted by carbonaceous materials, which could possibly be recovered and used for other purposes. The liquid phase <NUM> contains ions of the metals present in the cathode material.

The separation of lithium from the liquor or liquid phase <NUM> is obtained by precipitation in a precipitation reactor <NUM>. Initially, the pH of the liquor <NUM> is brought to a value between <NUM> and <NUM>, by adding an aqueous solution of an alkaline hydroxide, in concentration between <NUM> and <NUM>% by weight, preferably <NUM>% sodium hydroxide. A solution <NUM> of an alkaline sulfide is then added under stirring in a concentration of <NUM> to <NUM>, preferably <NUM> sodium sulfide, maintaining the temperature in a range of from <NUM> to <NUM>° C. This solution <NUM> is added until the complete precipitation of all the transition metals present in the solution is obtained, with the exception of the lithium ions. This condition can be determined by methods according to the prior art. Once the solution addition is complete, the suspension is digested for at least <NUM> minutes, to obtain a clarified solution <NUM> containing lithium and a precipitate <NUM>. The precipitate <NUM>, containing the metal sulfides, is separated by filtration in a station of filtering <NUM>. From the clarified solution <NUM>, lithium can be recovered by precipitation in the form of carbonate, as follows: the sodium and/or potassium content of the solution is reduced due to the effect of pH and concentration. For example, referring again to <FIG>, the clarified solution <NUM> can be acidified, preferably with hydrochloric acid <NUM>, to a pH lower than <NUM>, concentrated by evaporation in a special evaporation tank <NUM>, obtaining the precipitation of the sodium and potassium salts <NUM> from the solution <NUM> of lithium and sodium or potassium, which are separated by filtration into a filtering station <NUM>. The lithium is finally obtained as carbonate, by hot precipitation in a precipitation reactor <NUM>, following the addition of a solution <NUM> of sodium or potassium carbonate. The lithium carbonate <NUM> precipitates at the bottom of the precipitation reactor <NUM>, is separated, by filtration in a filtering station <NUM>, from the mother liquors <NUM>, which can be recycled in the step of precipitation. The lithium carbonate <NUM> is then purified by recrystallization.

A batch consisting of <NUM> grams of lithium ion rechargeable cells, two of flat shape and two of cylindrical shape of the ICR18630 type, deprived of their BMS, were immersed in a pot of Dewar (thermally insulated) containing <NUM> of shavings of bronze for a time equal to <NUM> hours. The production of heat during the process was monitored by an infrared thermometer. The temperature, starting from a value of <NUM>, has increased to a maximum of <NUM> in two hours, then decreasing in the following hours. After <NUM> hours the temperature was around <NUM>, indicating the absence of further production of heat and, therefore, the end of the discharge process. The cells were then separated from the filings by sieves and manually disassembled using a circular saw for the removal of plastic and steel hulls. No flames, heat or gas development were detected during this procedure. The internal parts of the cells, composed of anode, cathode and polymeric separators, were cut manually into fragments of about <NUM> on each side. The fragments, weighing <NUM>, were placed in a beaker, added with <NUM> of a <NUM> solution of formic acid and heated under stirring for one hour at <NUM>, obtaining the detachment of the active materials from the metal collectors. The separation of the suspended powders in solution containing the active metals was obtained through a sieve of appropriate dimensions; the metal collectors of copper and aluminum and the polypropylene separators were then washed, dried and finally weighed.

The weight of this fraction was <NUM>; no evident corrosion was detected on the copper foils, while the surface of the aluminum foils was opaque, thus indicating partial corrosion. The suspension consisting of the active powder and the formic acid solution was then inserted into an etching reactor for the step of dissolution (leaching) and <NUM> of concentrated hydrochloric acid (<NUM>% by weight) were added and heated up to boiling for un hour under stirring. After this time, the solution was allowed to cool and filtered, separating the insoluble solids in the reaction environment. The solid part, made up entirely of elemental carbon, was dried and weighed, amounting to about <NUM> (about <NUM>% of the weight of the entire black mass). The solution containing the ions of the active metals, called "liquor", had a volume of about <NUM> of volume and was analyzed by ICP-MS (Inductively Coupled Plasma - Mass Spectrometry) to determine the content of metal ions, the results of which are shown in Table <NUM>.

The copper amount is very low, indicating a slight dissolution during the step of detachment of the powders from the collectors, while a not negligible quantity of aluminum in solution has been detected. Subsequently, the "liquor" was heated up to <NUM>, the pH increased up to a value of around <NUM> by means of an aqueous solution of <NUM>% by weight sodium hydroxide (about <NUM> of equivalent NaOH) and a <NUM> Na<NUM>S solution was added for the precipitation of all metal ions with the exception of lithium. About <NUM> of <NUM> sodium sulfide solution was needed. The precipitate was then filtered, dried and weighed; about <NUM> of transition metal sulfide were obtained. The aqueous portion, having a volume of <NUM>, containing lithium and sodium ions was acidified to pH <NUM> with hydrochloric acid and evaporated to about <NUM>/<NUM> of its initial volume, thus obtaining the precipitation of sodium chloride, which was then separated from the mother liquor by filtration and removed. The supernatant, enriched with lithium chloride, was heated up to <NUM>, obtaining, by adding <NUM> of <NUM>% aqueous potassium carbonate, the precipitation of lithium carbonate, then separated from the mother liquors by filtration. The obtained precipitate, washed with water at boiling temperature and subsequently dried and weighed, amounted to about <NUM>, corresponding to <NUM>% of the lithium contained in the etching liquor. The obtained product was analyzed by ICP-MS. The results are shown in Table <NUM>.

A batch consisting of <NUM> grams of primary (non- rechargeable) and secondary (rechargeable) cells of lithium ions, including cells of the CR2 type, cells of flat shape and cells of cylindrical shape ICR18630 type, deprived of their BMS (where present) were immersed in a Dewar vessel (thermally insulated) containing bronze shavings for a period of <NUM> hours. The production of heat during the process was monitored by an infrared thermometer. The temperature, starting from a value of <NUM>, has increased to a maximum of <NUM> in three hours, then decreasing in the following hours. After <NUM> hours the temperature was around <NUM>, indicating the absence of further production of heat and, therefore, the end of the discharge process. The thermal energy released by the discharge process amounted to about 6kJ. The cells were then separated from the filings by sieves and manually disassembled using a circular saw for the removal of plastic and steel hulls. No flames, heat or gas development were detected during this process. The internal parts of the cells, composed of anode, cathode and separators, were cut manually into <NUM> diameter fragments and left for two hours exposed to an air stream in order to eliminate the organic solvents that make up the electrolyte before proceeding with other treatments. The fragments, weighing <NUM>, were placed in a beaker and added with <NUM> of a solution of <NUM> formic acid, heated under stirring for two hours at room temperature (about <NUM>), obtaining the detachment of the active materials from metal collectors. Once the detachment was completed, the copper and aluminum metal collectors and the polypropylene separators were separated by a sieve, washed, dried and finally weighed. The weight of this fraction was <NUM>; partial corrosion was detected on the copper foils, while the thickness of the aluminum foils was appreciably reduced, thus indicating substantial corrosion. Furthermore, part of the active powder remained adhered to the surface of the aluminum. The suspension consisting of active powder and the formic acid solution was then inserted into the leaching reactor and added with <NUM> of concentrated hydrochloric acid (<NUM>% by weight) and reflow heated for one hour under stirring. After this time, the solution was allowed to cool and filtered, separating the insoluble solids in the reaction environment, which were washed with <NUM> of distilled water. The solid part, consisting entirely of elemental carbon, was dried and weighed to a total of about <NUM> (about <NUM>% of the weight of the entire black mass). The etching "liquor" (about <NUM> of volume) was analyzed by ICP-MS (Inductively Coupled Plasma - mass spectrometry) to determine the metallic content; the data are shown in table <NUM>.

The phase composed of metal collectors and separators was etched in aqua regia and also analyzed by ICP-MS, with the aim of determining the metallic content; the values are shown in table <NUM>, while the percentage distribution between the two phases, powders and foils, are shown in table <NUM>.

Although the visual inspection showed signs of corrosion on both copper and aluminum, only the latter was detected in appreciable quantities in the "liquor", indicating that copper was only partially etched. It should be noted, however, that part of the active powder remained adhered to the aluminum foils (table <NUM>). The pH of the "liquor" was adjusted around a value of <NUM> by adding an aqueous solution of <NUM>% by weight sodium hydroxide (about <NUM> of equivalent NaOH), leading to the precipitation of the aluminum traces, in the form of hydroxides, which were removed by filtration. The metals contained in the liquor (with the exception of lithium) were precipitated by adding a <NUM> solution of Na<NUM>S at <NUM> under stirring until the reaction was complete (further addition of sulfide did not lead to any additional formation of precipitate). About <NUM> of <NUM> sodium sulfide solution was needed. The precipitate was then filtered, dried and weighed; approximately <NUM> of transition metal sulfide were obtained. The aqueous part, having a volume of about <NUM>, containing lithium and sodium ions was acidified to pH <NUM> with hydrochloric acid and evaporated to about <NUM>/<NUM> of its initial volume, thus obtaining the precipitation of sodium chloride, which was then separated from the mother liquors by filtration and removed. The supernatant, enriched with lithium chloride, was heated up to <NUM>, obtaining, by adding <NUM> of <NUM>% aqueous potassium carbonate, the precipitation of lithium carbonate, then separated from the mother liquors by filtration. The obtained precipitate, washed with water at boiling temperature and subsequently dried and weighed, amounted to about <NUM>, corresponding to <NUM>% of the lithium contained in the etching liquor and to about <NUM>% of the content total of lithium contained in the lot. The obtained product was analyzed by ICP-MS. The results are shown in table <NUM>.

A batch consisting of <NUM> grams of rechargeable lithium ion cells, two of flat shape and two of cylindrical shape type ICR18630, deprived of their BMS, were immersed in a vase of Dewar (thermally insulated), containing bronze shavings, for a time equal to <NUM> hours. The production of heat during the process was monitored by an infrared thermometer. The temperature, starting from a value of <NUM>, increased to a maximum of <NUM> in three hours, then decreasing in the following hours. After <NUM> hours the temperature was around <NUM> indicating the absence of further production of heat and, therefore, the end of the discharge process. The thermal energy released by the discharge process amounted to about 12kJ. The cells were then separated from the filings by means of sieves and manually disassembled, using a circular saw for the removal of plastic and steel hulls, whose weight amounted to <NUM>. No flames, heat or gas development were detected during this procedure. The internal parts of the cells, composed of anode, cathode and separators, were cut manually into <NUM> diameter fragments and left for two hours exposed to an air stream in order to eliminate the organic solvents that make up the electrolyte before proceeding further. The fragments weighing <NUM> were placed in a beaker, added with <NUM> of a solution of <NUM> formic acid, and stirred for one hour at room temperature, obtaining the detachment of the active materials from the metal collectors. Once the detachment was completed, the copper and aluminum metal collectors and the polypropylene separators were separated by a sieve, washed, dried and finally weighed. The weight of this fraction was <NUM>; no evident corrosion was detected on the copper foils, while the surface of the aluminum foils was opaque, thus indicating a possible partial corrosion. Part of the powders had remained attached to the surface of the aluminum and separators. The suspension consisting of the active powder and the formic acid solution was then inserted into the leaching reactor and added with <NUM> of concentrated hydrochloric acid (<NUM>% by weight) and reflow heated for one hour under stirring. After this time, the solution was allowed to cool and filtered, separating the insoluble solids from the reaction environment. The solid part, consisting entirely of elemental carbon, was washed with <NUM> of water, dried and weighed, amounting to about <NUM> (about <NUM>% of the weight of the entire black mass). The "etching liquor" (about <NUM> of volume) was analyzed by ICP-MS to determine the metallic content; the data are shown in table <NUM>.

The phase composed of metal collectors and separators was etched in aqua regia and also analyzed by ICP-MS, in order to determine its metallic content; the values are shown in Table <NUM>, while the percentage distribution between the two phases, powders and foils, are shown in Table <NUM>.

As expected, the copper was not appreciably etched during the step of separation of the powders, while a not negligible quantity of aluminum in solution was detected. It should be noted, however, that part of the active powder remained attached to the aluminum foils (Table <NUM>). The pH of the "liquor" was adjusted around a value of <NUM> by adding an aqueous solution of <NUM>% by weight sodium hydroxide (about <NUM> of equivalent NaOH) leading to the precipitation of the traces of aluminum as hydroxides, which were eliminated by filtration. The metals contained in the liquor (with the exception of lithium) were precipitated by adding a solution of Na<NUM>S <NUM> at <NUM> under stirring until the reaction was complete (further addition of sulfide did not lead to further precipitate formation). Approximately <NUM> of <NUM> sodium sulphide solution were required. The precipitate was then filtered, dried and weighed; approximately <NUM> of transition metal sulfide were obtained. The aqueous portion, having a volume of <NUM> containing lithium and sodium ions was acidified to pH <NUM> with hydrochloric acid and evaporated to about <NUM>/<NUM> of its initial volume, resulting in precipitation of sodium chloride, which was then separated from the mother liquor by filtration and eliminated. The supernatant, enriched with lithium chloride, was heated up to <NUM>, obtaining, by adding <NUM> of <NUM>% aqueous potassium carbonate, the precipitation of lithium carbonate, then separated from the mother liquors by filtration. The obtained precipitate, washed with water at boiling temperature and subsequently dried and weighed, amounted to about <NUM>, corresponding to <NUM>% of the lithium contained in the etching "liquor" and to approximately <NUM>% of the total content of lithium contained in the batch. The obtained product was analyzed by ICP-MS. The results are shown in table <NUM>.

Claim 1:
Method for treatment of lithium batteries and recovery of the metals contained therein comprising the following steps:
- completely discharging the single cells by immersion in a conductive solid material;
- separating black mass from metal shells,
- removing active powder from metal collectors and from separating membranes, non-destructive to the latter, by immersion of black mass in an aqueous solution of a weak organic acid;
- recovering and separating metal collectors and separating membranes from active powder by sieving;
- dissolving, by leaching, the metals from active powder by using a detachment acid solution, by adding a stronger acid; heating and subsequent filtration of the leachate to remove insoluble parts;
- precipitation of the transition metals contained in the leachate as sulfides by adjusting the pH and adding a solution of a source of sulfide ions, preferably an alkaline sulfide;
- filtering, washing and recovering the precipitate;
- acidification of the lithium solution with strong acids, evaporation and precipitation of sodium and potassium salts;
- filtering sodium and potassium salts to obtain only lithium in the solution;
- lithium precipitation as lithium carbonate, by adding an alkaline carbonate;
- washing the lithium carbonate precipitate with hot water to obtain a purified product.