Patent Description:
As a negative electrode active material of a nonaqueous electrolyte secondary battery, a carbon material, such as graphite, has been primarily used. In order to improve a battery capacity and cycle characteristics of the nonaqueous electrolyte secondary battery, various carbon materials have been proposed.

PTL <NUM> has disclosed a nonaqueous electrolyte secondary battery which uses a carbon material having an internal void rate of <NUM>% or less as a negative electrode active material.

PTL <NUM> has disclosed a nonaqueous electrolyte secondary battery which uses, as a negative electrode active material, a carbon material having an internal void rate of <NUM>% to less than <NUM>% and a carbon material having an internal void rate of <NUM>% to <NUM>%.

In order to prevent degradation of battery characteristics caused by expansion and contraction of a carbon material in charge/discharge, PTL <NUM> has disclosed a nonaqueous electrolyte secondary battery including an electrode body in which a negative electrode plate and a positive electrode plate are spirally wound with at least one separator interposed therebetween and in which a packing density of a negative electrode mixture layer at a winding inner surface side of the negative electrode plate is decreased lower than a packing density of a negative electrode mixture layer at a winding outer surface side of the negative electrode plate by <NUM>% to <NUM>%.

Further relevant prior art is described in the document <CIT>.

In a nonaqueous electrolyte secondary battery having a spirally wound electrode body, a negative electrode plate is maintained in a curved state. A negative electrode mixture layer at a winding inner surface side of the negative electrode plate in the curved state is compressed to have a high packing density as compared to that in a flat state before winding. On the other hand, a negative electrode mixture layer at a winding outer surface side of the negative electrode plate in the curved state is stretched to have a low packing density as compared to that in the flat state. Hence, in the nonaqueous electrolyte secondary battery having a spirally wound electrode body, there has been a problem in that rates of degradation of the negative electrode mixture layers which form a front and a rear surface of the negative electrode plate in association with charge/discharge cycles are different from each other.

PTL <NUM> has proposed that the packing density of the negative electrode mixture layer at the winding inner surface side of the negative electrode plate is decreased lower than the packing density of the negative electrode mixture layer at the winding outer surface side of the negative electrode plate. However, as disclosed in PTL <NUM>, when a carbon material concentration of a negative electrode mixture slurry is decreased so that the packing density of the negative electrode mixture layer at the winding inner surface side of the negative electrode plate is low, there has been a problem in that the contents of components, such as a binding agent, other than the carbon material are each unbalanced between the front and the rear surface sides of the negative electrode plate.

The present disclosure aims to provide a nonaqueous electrolyte secondary battery excellent in cycle characteristics.

A nonaqueous electrolyte secondary battery according to an aspect of the present disclosure comprises: an electrode body in which a positive electrode plate and a negative electrode plate are wound with a separator interposed therebetween; and an exterior package which receives the electrode body, the negative electrode plate includes a negative electrode collector, a first negative electrode mixture layer formed on a winding inside first surface of the negative electrode collector, and a second negative electrode mixture layer formed on a winding outside second surface of the negative electrode collector, the first negative electrode mixture layer contains first graphite particles as a primary component, the second negative electrode mixture layer contains second graphite particles as a primary component, and the first graphite particles has an internal void rate lower than an internal void rate of the second graphite particles, wherein the internal void rate of the first graphite particles is <NUM> % or less, and the internal void rate of the second graphite particles is <NUM> % to <NUM> %, when the internal void rate is measured by the method indicated in the description.

According to the aspect of the present disclosure, a nonaqueous electrolyte secondary battery which includes a spirally wound electrode body and which is excellent in cycle characteristics can be provided.

In addition, the present invention is not limited to the following embodiment and may be carried out while being appropriately changed and/or modified within the scope of the present invention.

<FIG> is a cross-sectional view of a nonaqueous electrolyte secondary battery <NUM> according to an embodiment of the present disclosure. An electrode body <NUM> is received in a bottom-closed cylindrical exterior package can <NUM> together with a nonaqueous electrolyte. Insulating plates <NUM> and <NUM> are provided at a top and a bottom of the electrode body <NUM>, respectively. A sealing body <NUM> is caulking-fixed to an opening portion of the exterior package can <NUM> with an insulating gasket <NUM> interposed therebetween. Accordingly, the inside of the exterior package can <NUM> is tightly sealed.

The electrode body <NUM> is formed by spirally winding a negative electrode plate <NUM> and a positive electrode plate <NUM> with at least one separator <NUM> interposed therebetween. Along a radial direction of the electrode body <NUM>, the negative electrode plate <NUM> and the positive electrode plate <NUM> are alternately laminated to each other. A negative electrode lead <NUM> and a positive electrode lead <NUM> are bonded to the negative electrode plate <NUM> and the positive electrode plate <NUM>, respectively. A bottom portion of the exterior package can <NUM> is electrically connected to the negative electrode plate with the negative electrode lead <NUM> interposed therebetween, and the sealing body <NUM> is electrically connected to the positive electrode plate with the positive electrode lead <NUM> interposed therebetween. Accordingly, the exterior package can <NUM> functions as a negative electrode exterior terminal, and the sealing body <NUM> functions as a positive electrode exterior terminal. Although the cylindrical electrode body <NUM> is used in the embodiment of the present disclosure, a flat electrode body may also be used. When a flat electrode body is used, as an exterior package which receives the electrode body, a bottom-closed square exterior package can or a pouch exterior package formed from a laminate sheet in which a resin sheet and a metal sheet are laminated to each other may be used.

<FIG> is a partial cross-sectional view of the negative electrode plate <NUM> according to the embodiment of the present disclosure, the plate being placed in a flat state before winding, and <FIG> is a partial cross-sectional view of the negative electrode plate <NUM> according to the embodiment of the present disclosure, the plate being placed in a curved state after winding. The negative electrode plate <NUM> includes a negative electrode collector <NUM> and negative electrode mixture layers <NUM> formed on two facing surfaces of the negative electrode collector <NUM>. The negative electrode mixture layers <NUM> are a first negative electrode mixture layer 32a formed on a winding inside first surface of the negative electrode collector <NUM> and a second negative electrode mixture layer 32b formed on a winding outside second surface of the negative electrode collector <NUM>.

The negative electrode mixture layer <NUM> can be formed such that a negative electrode mixture slurry formed by kneading a negative electrode active material and a binding agent in a dispersion medium is applied on the negative electrode collector <NUM> and is then dried. The negative electrode mixture layer <NUM> thus dried is compressed to have a predetermined thickness by a roller machine. To the negative electrode mixture slurry, a thickening agent is preferably added for viscosity adjustment.

The negative electrode mixture layer <NUM> contains graphite particles as the negative electrode active material. <FIG> schematically shows one example of a cross-section of a graphite particle <NUM>. As shown in <FIG>, in the cross-section of the graphite particle <NUM>, internal voids <NUM> which are regions enclosed in the graphite particle <NUM> and an external void <NUM> extending from the inside to the surface of the particle are present. According to the embodiment of the present disclosure, at least two types of graphite particles having different internal void rates are each used as the negative electrode active material. First graphite particles having a lower internal void rate are contained in the first negative electrode mixture layer 32a as a primary component. Second graphite particles having a higher internal void rate are contained in the second negative electrode mixture layer 32b as a primary component. The internal void rate of the graphite particle <NUM> is a rate of areas of the internal voids <NUM> of the graphite particle <NUM> with respect to a cross-sectional area of the graphite particle <NUM>. The primary component of the negative electrode mixture layer indicates a component having the highest mass ratio among components forming the negative electrode mixture layer.

Hereinafter, one example of a procedure of a measurement method of the internal void rate will be described.

The internal void rate of the graphite particle may be evaluated, for example, based on an average value of internal void rates of <NUM> graphite particles.

When the electrode body <NUM> is formed, if the negative electrode plate <NUM> and the positive electrode plate <NUM> are spirally wound together with the separator <NUM>, as shown in <FIG>, the first negative electrode mixture layer 32a at a winding inner surface side of the negative electrode collector <NUM> is placed in a compressed state. On the other hand, the second negative electrode mixture layer 32b at a winding outer surface side of the negative electrode collector <NUM> is placed in a stretched state along a winding direction. Hence, the packing density of the first negative electrode mixture layer 32a becomes higher than the packing density of the second negative electrode mixture layer 32b, and hence, the difference in packing density of the negative electrode mixture layer <NUM> is generated between a front side and a rear side. If the packing density of the first negative electrode mixture layer 32a is excessively increased, for example, problems may arise in that the nonaqueous electrolyte is difficult to retain by the first negative electrode mixture layer 32a, and by the expansion and the contraction of the negative electrode active material in association with charge/discharge, the first negative electrode mixture layer 32a is liable to be cracked.

The present inventors obtain a novel finding in that when the internal void rate of graphite particles forming a negative electrode mixture layer is decreased, the negative electrode mixture layer is not likely to be compressed. That is, in the case in which the negative electrode plate <NUM> is formed, when the negative electrode mixture layer <NUM> is compressed, or when the negative electrode plate <NUM> is wound so as to be curved, an effect in that the first negative electrode mixture layer 32a is not likely to be compressed as compared to the second negative electrode mixture layer 32b can be obtained. Hence, according to the embodiment of the present disclosure, even when a winding type electrode body is used in a nonaqueous electrolyte secondary battery, the difference in packing density between the front and the rear sides of the negative electrode mixture layer <NUM> is not likely to be generated.

As the graphite particles, for example, a natural graphite or an artificial graphite may be used without being limited. However, since the internal void rate can be easily adjusted in a wide range, an artificial graphite is preferably used. Although being not particularly limited, the interplanar spacing (d<NUM>) of the (<NUM>) plane of graphite particles by an X-ray diffraction method is preferably <NUM> or more and more preferably <NUM> or more. In addition, the interplanar spacing (d<NUM>) of the (<NUM>) plane of graphite particles is preferably <NUM> or less. When graphite particles having an interplanar spacing (d<NUM>) of the (<NUM>) plane in the range described above are used as the negative electrode active material, a nonaqueous electrolyte secondary battery excellent in battery characteristics, such as cycle characteristics, can be provided.

Hereinafter, an adjustment method of the internal void rate of graphite particles will be described using an artificial graphite as an example. First, a coke which is a precursor of an artificial graphite is pulverized to have a predetermined size. Subsequently, pulverized coke particles are aggregated by a binding agent and then pressure-molded to have a block shape. This block-shaped molded body is graphitized by firing at a temperature of <NUM>,<NUM> or more. Finally, the graphitized block-shaped molded body is pulverized and sieved to have a predetermined particle size, so that graphite particles are obtained. The internal void rate of the graphite particles can be adjusted by a volatile component contained in the block-shaped molded body. When the binding agent added to the coke particles is partially evaporated in the firing, the binding agent may also be used as the volatile component. As the binding agent described above, a pitch may be mentioned as one example.

The method for manufacturing graphite particles described above is suitable when graphite particles having a high internal void rate are manufactured. On the other hand, when graphite particles having a low internal void rate is manufactured, the following manufacturing method is preferable.

First, a coke which is a precursor of an artificial graphite is pulverized to have a predetermined size. Subsequently, pulverized coke particles are aggregated by a binding agent and then graphitized by firing at a temperature of <NUM>,<NUM> or more. The graphitized aggregate is crushed and sieved to have a predetermined particle size, so that graphite particles are obtained. As described above, since the pulverized coke is graphitized without being molded into a block shape, graphite particles having a low internal void rate can be obtained. The method for manufacturing graphite particles described above is particularly suitable for manufacturing of graphite particles having an internal void rate of <NUM> or less. The internal void rate of the graphite particles may be adjusted, for example, by an average particle diameter of the coke after pulverization. In addition, as the average particle diameter of the graphite or the coke, in the present disclosure, a volume-basis median diameter (D50) is used.

As the negative electrode active material, the negative electrode mixture layer <NUM> may contain, besides the graphite particles, another material capable of reversibly occluding and releasing lithium ions. For example, silicon material particles composed of silicon, an alloy containing silicon, an oxide containing silicon, or the like may be mentioned. Since having a large charge/discharge capacity per unit mass, the silicon material particles are suitably used for an increase in capacity of a nonaqueous electrolyte secondary battery. An effect of improving cycle characteristics of the present disclosure can be significantly obtained when a silicon material having a large volume change in charge/discharge is used. As the silicon material, a silicon oxide represented by SiOx (<NUM>≤x<<NUM>) or a composite material represented by Li2zSiO(<NUM>+z) (<NUM><z<<NUM>) in which silicon particles are dispersed in a lithium silicate phase is preferable. As the negative electrode active material, when the silicon material particles are used together with the graphite particles, the content of the silicon material particles in the negative electrode mixture layer with respect to the total mass of the graphite particles and the silicon material particles is preferably <NUM> to <NUM> percent by mass and more preferably <NUM> to <NUM> percent by mass.

The positive electrode plate <NUM> includes a positive electrode collector and positive electrode mixture layers formed on two facing surfaces of the positive electrode collector. The positive mixture layer can be formed by applying a positive electrode mixture slurry formed by kneading a positive electrode active material and a binding agent in a dispersion medium to the positive electrode collector, followed by drying. The positive electrode mixture layer thus dried is compressed by a roller machine to have a predetermined thickness. To the positive electrode mixture slurry, an electrically conductive agent, such as a carbon powder, is preferably added.

As the positive electrode active material, a lithium transition metal composite oxide capable of reversibly occluding and releasing lithium ions may be used. As the lithium transition metal composite oxide, a general formula of LiMO<NUM> (M indicates at least one of Co, Ni, and Mn), LiMn<NUM>O<NUM>, or LiFePO<NUM> may be mentioned. Those composite oxides may be used alone, or at least two types thereof may be used by mixing. A mixture obtained by adding at least one selected from the group consisting of Al, Ti, Mg, and Zr to the lithium transition metal composite oxide or a compound obtained by substituting a transition metal element of the lithium transition metal composite oxide by the element mentioned above may also be used. To particle surfaces of the lithium transition metal composite oxide, for example, oxide particles of Al, Zr, and/or Er may also be fixed.

As the separator <NUM>, a fine porous film containing a polyolefin, such as a polyethylene (PE) or a polypropylene (PP), as a primary component may be used. As the fine porous film, one layer may only be used, or at least two layers laminated to each other may also be used. In a laminate separator having at least three layers, a layer containing a polyethylene (PE) having a low melting point as a primary component is preferably used as an intermediate layer, and a polypropylene (PP) having an excellent oxidation resistance is preferably used as a surface layer. To the separator, inorganic particles composed of, for example, aluminum oxide (Al<NUM>O<NUM>), titanium oxide (TiO<NUM>), or silicon oxide (SiO<NUM>) may be added. The inorganic particles mentioned above may be supported in the separator or may be applied to the surface of the separator with a binding agent. An aramid-based resin may be applied to the surface of the separator. In the case described above, the inorganic particles mentioned above are preferably added to the aramid-based resin.

As the nonaqueous electrolyte, an electrolyte in which a lithium salt functioning as an electrolyte salt is dissolved in a nonaqueous solvent may be used. A nonaqueous electrolyte in which a gel polymer is used instead of a nonaqueous solvent or in combination therewith may also be used.

As the nonaqueous solvent, a cyclic carbonate ester, a chain carbonate ester, a cyclic carboxylic acid ester, or a chain carboxylic acid ester may be used, and at least two types thereof are preferably used by mixing. As the cyclic carbonate ester, for example, ethylene carbonate (EC), propylene carbonate (PC), or butylene carbonate (BC) may be mentioned. In addition, as a fluoroethylene carbonate (FEC), a cyclic carbonate ester in which at least one hydrogen atom is substituted by fluorine may also be used. As the chain carbonate ester, for example, dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC), or methyl propyl carbonate (MPC) may be mentioned. As the cyclic carboxylic acid ester, for example, γ-butyrolactone (γ-BL) or γ-valerolactone (γ-VL) may be mentioned, and as the chain carboxylic acid ester, for example, methyl pivalate, ethyl pivalate, methyl isobutyrate, or methyl propionate may be mentioned.

As the lithium salt, for example, LiPF<NUM>, LiBF<NUM>, LiCF<NUM>SO<NUM>, LiN(CF<NUM>SO<NUM>)<NUM>, LiN(C<NUM>F<NUM>SO<NUM>)<NUM>, LiN (CF<NUM>SO<NUM>)(C<NUM>F<NUM>SO<NUM>), LiC(CF<NUM>SO<NUM>)<NUM>, LiC(C<NUM>F<NUM>SO<NUM>)<NUM>, LiAsF<NUM>, LiClO<NUM>, Li<NUM>B<NUM>Cl<NUM>, or Li<NUM>B<NUM>Cl<NUM> may be mentioned. Among those mentioned above, LiPF<NUM> is particularly preferable, and the concentration in the nonaqueous electrolyte is preferably <NUM> to <NUM> mol/L. Another lithium salt, such as LiBF<NUM>, may also be mixed with LiPF<NUM>.

Hereinafter, the embodiment of the present invention will be described in more detail with reference to experimental examples. In the experimental examples, the cylindrical nonaqueous electrolyte secondary battery according to the embodiment of the present disclosure was used, and the negative electrode active material was appropriately changed.

Graphite particles A used for a first negative electrode mixture layer at a winding inner surface side of a negative electrode collector were formed as described below. First, after a coke which was a precursor of graphite was pulverized to have an average particle diameter of <NUM>, a pitch functioning as a binding agent was added to the pulverized coke, and the coke was aggregated to have an average particle diameter of <NUM>. After being graphitized by firing at a temperature of <NUM>,<NUM>, the aggregate thus obtained was classified using a <NUM>-mesh sieve, so that graphite particles A having an average particle diameter of <NUM> and an internal void rate of <NUM>% were obtained.

The graphite particles A, a carboxymethyl cellulose (CMC), and a styrene-butadiene rubber (SBR) were used as a negative electrode active material, a thickening agent, and a binding agent, respectively. After <NUM> parts by mass of the graphite particles A, <NUM> part by mass of the CMC, and <NUM> part by mass of the SBR were mixed together, and a mixture thereof was kneaded in purified water functioning as a dispersion medium, so that a negative electrode mixture slurry A was formed.

Graphite particles B used for a second negative electrode mixture layer at a winding outer surface side of the negative electrode collector were formed as described below. First, after a coke which was a precursor of graphite was pulverized to have an average particle diameter of <NUM>, a pitch functioning as a binding agent was added to the pulverized coke, and the coke was aggregated. An isotropic pressure was applied to the aggregate to form a block-shaped molded body having a density of <NUM> to <NUM>/cm<NUM>. After being graphitized by firing at a temperature of <NUM>,<NUM>, the block-shaped molded body thus obtained was pulverized and then classified using a <NUM>-mesh sieve, so that graphite particles B having an average particle diameter of <NUM> and an internal void rate of <NUM>% were obtained.

The graphite particles B, a CMC, and an SBR were used as a negative electrode active material, a thickening agent, and a binding agent, respectively. After <NUM> parts by mass of the graphite particles B, <NUM> part by mass of the CMC, and <NUM> part by mass of the SBR were mixed together, and a mixture thereof was kneaded in purified water functioning as a dispersion medium, so that a negative electrode mixture slurry B was formed.

The negative electrode mixture slurry A was applied to a winding inside first surface of a negative electrode collector formed from copper foil having a thickness of <NUM>. Next, the negative electrode mixture slurry B was applied to a winding outside second surface of the negative electrode collector. The negative electrode mixture slurry A and the negative electrode mixture slurry B applied to the negative electrode collector were dried to form a first negative electrode mixture layer and a second negative electrode mixture layer on the first surface and the second surface, respectively, of the negative electrode collector. The first and the second negative electrode mixture layers were compressed by a roller machine to have predetermined thicknesses, and an electrode plate thus compressed was cut to have predetermined dimensions, so that a negative electrode plate was formed. At a winding finish-side end portion of the negative electrode plate, negative electrode collector exposed portions at which the first and the second negative electrode mixture layers were not formed were provided, and a negative electrode lead formed from a nickel plate was bonded to the negative electrode collector exposed portions. The graphite particles A and the graphite particles B in Experimental Example <NUM> correspond to the first graphite particles and the second graphite particles of the present disclosure, respectively.

As a positive electrode active material, lithium nickelate (LiNi<NUM>Co<NUM>Al<NUM>) containing aluminum and cobalt was used. After <NUM> parts by mass of the positive electrode active material, <NUM> part by mass of a carbon black functioning as an electrically conductive agent, and <NUM> part by mass of a poly(vinylidene fluoride) (PVdF) functioning as a binding agent were mixed together, a mixture thereof was kneaded in N-methyl-<NUM>-pyrrolidone (NMP) functioning as a dispersion medium, so that a positive electrode mixture slurry was formed. The positive electrode mixture slurry thus formed was applied by a doctor blade method on two facing surfaces of a positive electrode collector formed from aluminum foil (thickness: <NUM>), followed by drying, so that positive electrode mixture layers were formed. After the positive electrode mixture layers thus formed were compressed by a roller machine to have predetermined thicknesses, an electrode plate thus compressed was cut to have predetermined dimensions, so that a positive electrode plate was formed. At an intermediate portion of the positive electrode plate in a longitudinal direction, positive electrode collector exposed portions at which no positive electrode mixture layers were formed on the two facing surfaces of the positive electrode collector were provided, and a positive electrode lead formed from an aluminum plate was bonded to the positive electrode collector exposed portion.

The negative electrode plate and the positive electrode plate thus formed were spirally wound with separators each formed from a polyethylene-made fine porous film to form an electrode body. In this case, the first negative electrode mixture layer and the second negative electrode mixture layer were disposed at a winding inside and a winding outside, respectively, of the electrode body.

Ethylene carbonate (EC) and dimethyl carbonate (DMC) were mixed together at a volume ratio of <NUM>: <NUM>, so that a nonaqueous solvent was prepared. After <NUM> parts by mass of vinylene carbonate (VC) was added to <NUM> parts by mass of this nonaqueous solvent, lithium hexafluorophosphate (LiPF<NUM>) was dissolved therein to have a concentration of <NUM> mol/L, so that a nonaqueous electrolyte was prepared.

Insulating plates were disposed at a top and a bottom of the electrode body, and the electrode body was received in an exterior package can. The negative electrode lead was bonded to a bottom portion of the exterior package can, and a groove portion was formed around a periphery of a side surface of an opening portion of the exterior package can by press working. After the positive electrode lead was bonded to an internal terminal plate of a sealing body, the nonaqueous electrolyte was charged in the exterior package can. Finally, the sealing body was caulking-fixed to the opening portion of the exterior package can with a gasket supported by the groove portion, so that a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed.

Except for that the internal void rate of the graphite particles B was set to <NUM>%, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>. The graphite particles B having an internal void rate of <NUM>% were obtained by increasing the addition amount of the pitch larger than that in Experimental Example <NUM>.

Except for that the internal void rate of the graphite particles A was set to <NUM>%, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>. The graphite particles A having an internal void rate of <NUM> were obtained such that the average particle diameter of the pulverized coke particles functioning as a precursor of the graphite particles was set to <NUM>.

Except for that the internal void rate of the graphite particles B was set to <NUM>%, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>.

Except for that the internal void rate of the graphite particles A was set to <NUM>, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>.

Except for that silicon oxide (SiO) particles functioning as the negative electrode active material were added to the first negative electrode mixture layer and the second negative electrode mixture layer, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>. The contents of the SiO particles of the first negative electrode mixture layer and the second negative electrode mixture layer were each set to <NUM> percent by mass with respect to the total mass of the graphite particles and the SiO particles.

Except for that the internal void rate of the graphite particles A was set to <NUM>%, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>.

Except for that the contents of the SiO particles of the first negative electrode mixture layer and the second negative electrode mixture layer were each set to <NUM> percent by mass, a nonaqueous electrolyte secondary battery according to Experimental Example <NUM> was formed in a manner similar to that of Experimental Example <NUM>.

The batteries of the experimental examples were each charged at a constant current of <NUM> It (=<NUM> mA) to a battery voltage of <NUM> V and then charged at a constant voltage of <NUM> V to a current of <NUM> It (=<NUM> mA). Subsequently, the batteries of the examples were each discharged at a constant current of <NUM> It to a battery voltage of <NUM> V. This charge/discharge cycle was repeatedly performed <NUM>,<NUM> cycles in an environment at <NUM>. A rate (%) of a discharge capacity at a <NUM>,<NUM>th cycle to the discharge capacity at the first cycle was calculated as a capacity retention rate, and the cycle characteristics were evaluated thereby. The results are shown in Table <NUM>.

The results of the cycle characteristics of Experimental Examples <NUM> to <NUM> in Table <NUM> show that when the internal void rate of the graphite particles A contained in the winding inside first negative electrode mixture layer of the negative electrode plate is set lower than the internal void rate of the graphite particles B contained in the winding outside second negative electrode mixture layer of the negative electrode plate, the cycle characteristics are improved. For example, when the cycle characteristics of Experimental Examples <NUM> to <NUM> in each of which the content of the SiO particles is <NUM> percent by mass are compared to each other, it is found that compared to Experimental Examples <NUM> and <NUM> in which the graphite particles having the same internal void rate are used at the winding inside and the winding outside of the negative electrode plate, the cycle characteristics of Experimental Example <NUM> is improved by <NUM>% to <NUM>%. In particular, from the results of the cycle characteristics of Experimental Examples <NUM> to <NUM>, it is found that the content of the SiO particles is more preferably <NUM> to <NUM> percent by mass. The contents of the SiO particles in the first negative electrode mixture layer and the second negative electrode mixture layer are not always required to be the same.

Claim 1:
A nonaqueous electrolyte secondary battery (<NUM>) comprising: an electrode body (<NUM>)in which a positive electrode plate (<NUM>) and a negative electrode plate (<NUM>)are wound with a separator (<NUM>) interposed therebetween; and an exterior package which receives the electrode body(<NUM>),
wherein the negative electrode plate (<NUM>) includes a negative electrode collector(<NUM>), a first negative electrode mixture layer (32a) formed on a winding inside first surface of the negative electrode collector(<NUM>), and a second negative electrode mixture layer (32b)formed on a winding outside second surface of the negative electrode collector(<NUM>),
the first negative electrode mixture layer (32a) contains first graphite particles as a primary component,
the second negative electrode mixture layer (32b) contains second graphite particles as a primary component, and
the first graphite particles has an internal void rate lower than an internal void rate of the second graphite particles,
wherein the internal void rate of the first graphite particles is <NUM> or less, and
the internal void rate of the second graphite particles is <NUM>% to <NUM>%, when the internal void rate is measured by the method indicated in the description.