Patent Description:
According to recent increasing of energy consumption, demand for alternative energy replacing fossil energy has been rising as measures to cope with global warming. As a source of the alternative energy, solar cells have been attracted the attention and hence progressively developed. They are studied for various practical applications. From a practical viewpoint, it is particularly desired to improve their flexibility and durability so that they can be installed on various places. However, single crystal silicon solar cells, which are the most basic solar cells, are expensive and it is difficult to produce flexible ones. On the other hand, organic solar cells and organic-inorganic hybrid solar cells, in which many researchers have been lately interested, have room for improvement in durability.

In addition to the above solar cells, other photoelectric conversion devices, such as organic EL devices and photosensors, have been also researched with the aim of improving their flexibility and durability. Those devices usually comprise indium-doped tin oxide (hereinafter, often referred to as "ITO") films as transparent electrodes. The ITO films are normally formed by sputtering or the like. In order that the ITO films can have high electroconductivity, it is necessary to carry out the sputtering procedure at a high temperature and to anneal thereafter the formed films at a high temperature. However, it is often the case that organic materials cannot be subjected to those procedures at a high temperature. Further, when the ITO films are installed in the devices, metal ions such as indium ion and/or halogen ions may intrude into the active elements such as the photoelectric conversion layers to impair the activity of the devices.

Meanwhile, it is sometimes the case that low-resistant and high-transparent ITO/Ag/ITO or silver nanowires are adopted as the transparent electrodes. However, in those electrodes, silver is often deteriorated by acids or halogens. In addition, silver tends to cause migration and, as a result, may react with water and the like to lower the transparency of the electrode or may migrate into the active elements to impair the activity of the devices.

There are also some cases in which graphene-containing membranes are adopted as the material of transparent electrode. However, although excellent in electroconductivity and stability, graphene-containing membranes are known to have various disadvantages.

<CIT> describes a transparent electrode that includes: a conductive layer containing an amorphous inorganic oxide-containing film; and a shielding layer formed on the conductive layer and containing a graphene film containing a self-doping type conductive polymer film containing a Bronsted acid anion and a localized cation in a side chain, and/or nitrogen atoms.

<CIT> describes a method for attaching a reducible nanomaterial to an organic polymer that includes subjecting a reaction mixture that includes the reducible nanomaterial and the organic polymer to a reducing agent under reaction conditions sufficient to reduce the nanomaterial, activate the organic polymer, and attach the reduced nanomaterial to the organic polymer during the reaction.

<CIT> describes anion exchange membranes that are the polymerization product of at least one functional monomer comprising a tertiary amine which is reacted with a quaternizing agent in the polymerization process.

In view of the above problem, embodiments of the present disclosure provide a method for easily evaluating anion-permeability of a graphene-containing membrane used in an electrochemical device.

The method according to the embodiment for evaluating anion-permeability of a graphene-containing membrane comprises the steps of:.

The embodiments will be described below in detail.

First, the method according to the first embodiment for evaluating anion-permeability of a graphene-containing membrane is explained with reference to <FIG>.

In the method of the embodiment, the current I<NUM> in (ii) or I<NUM> in (iii) is measured under the condition that the graphene-containing membrane as the evaluating object is absent or present, respectively. Specifically, only the aqueous solution is subjected directly to cyclic voltammetry in (ii) while subjected to cyclic voltammetry through the graphene-containing membrane in (iii). Either measurement may be carried out first. <FIG> shows a schematic sketch of an apparatus by which the current I<NUM> in the presence of the graphene-containing membrane is measured in a manner according to one example of the embodiment.

The measuring apparatus for the evaluation comprises an aqueous solution <NUM> containing anions, a working electrode <NUM> containing silver-metal, a counter electrode <NUM> and a reference electrode <NUM>. The working electrode, the counter electrode and the reference electrode are electrically connected through an external circuit. In <FIG>, the external circuit is provided with a power supply <NUM> which applies potential between the working electrode and the counter electrode, and the circuit is also provided with an ammeter <NUM>. Those electrodes, the power supply and the ammeter are electrically connected so that they can form a circuit similar to a potentiostat generally used in cyclic voltammetry. Accordingly, the reference electrode in the embodiment serves as a standard for accurately determining the potential of the working electrode.

The silver-metal contained in the working electrode <NUM> does not need to be simple substance of silver and may be a silver-containing alloy. Further, there are no particular restrictions on the shape of the silver-metal, and hence the working electrode may be in the shape of a silver-metal film or may be made of silver nanowires. The working electrode shown in <FIG> is in film shape, but the shape thereof is not limited to that. However, the working electrode is preferably in the shape of a film. That is because, if the electrode is in film shape, a homogeneous current can be used in the measurement since the evaluating object is also in the shape of a film.

In <FIG>, the graphene-containing membrane <NUM> is sandwiched between the working electrode <NUM> and the aqueous solution <NUM>. This means that one face of the graphene-containing membrane <NUM> is in contact with the working electrode <NUM> and the other face is in contact with the aqueous solution <NUM>.

The graphene-containing membrane <NUM> is overlaid on and kept in contact with the working electrode <NUM>, and thereby they are electrically connected.

In <FIG>, the aqueous solution <NUM> is contained in the space surrounded by a cylinder <NUM> and the graphene-containing membrane <NUM>. The aqueous solution <NUM> is thus in contact with the membrane <NUM> and electrically connected to the working electrode <NUM> through the membrane <NUM>. In order to prevent the aqueous solution from leaking out, there may be a seal <NUM> between the cylinder <NUM> and the membrane <NUM>.

In the apparatus described above, the reaction current I<NUM> between the silver-metal contained in the working electrode and the anions is measured with the ammeter <NUM> in the presence of the graphene-containing membrane <NUM> while the working electrode potential based on the reference electrode is being periodically changed.

Apart from the measurement of I<NUM>, the above measurement is repeated except for removing the graphene-containing membrane <NUM> from the apparatus so that the aqueous solution <NUM> is directly in contact with the working electrode <NUM>, to measure the reaction current I<NUM> between the silver-metal contained in the working electrode and the anions in the absence of the graphene-containing membrane <NUM>.

The above-measured reaction currents are generated by reactions explained below.

When the anions (e.g., halogen ions X-) diffuse through the graphene-containing membrane <NUM> and reach the working electrode <NUM> containing silver-metal (Ag) under the condition that the applied potential exceeds the oxidation potential of the anions, the following reaction (<NUM>) occurs.

Subsequently, when the potential is reversely applied, the following reverse reaction (<NUM>) occurs.

The currents are generated by electron migration based on the above reactions. If the graphene-containing membrane has low anion-permeability, the reaction current I<NUM> is small. On the other hand, in the absence of the graphene-containing membrane, the reaction current I<NUM> serving as the standard is measured without receiving influence from the graphene-containing membrane. The reaction current I<NUM> depends substantially only on the concentration of the anions. From the comparison of those reaction currents, it is possible to evaluate the anion-permeability of the graphene-containing membrane.

There are generally two types of methods for measuring currents under application of potentials. One is a method, such as amperometry, in which the current is detected under application of a constant potential; and the other is a method, such as voltammetry, in which the current is detected under application of a periodically changed potential. In the embodiment, while the potential is being periodically changed, the responding change of the current is observed (i.e., cyclic voltammetry). However, there are some cases in which the current waveform responding to the time gradually changes. In those cases, when coming to change by <NUM>% or less, the waveform is adopted. The reaction amount (current amount) of (<NUM>) can be estimated from the charge amount which can be obtained by integrating the current waveform on the positive side with respect to the time. Further, the anion-permeability of the membrane as the measurement object can be evaluated from the comparison between the currents I<NUM> and I<NUM> in the absence and presence of the graphene-containing membrane, respectively. In view of analytical easiness, if voltammetry is used for the measurement, the measurement is preferably carried out according to, what is called, cyclic voltammetry, in which the potential is changed linearly to the time.

The applied potential is preferably within a range in which water is hardly electrolyzed to generate oxygen and hydrogen, namely, within a range of -<NUM> to +<NUM> mV (when the reference electrode is a silver-silver chloride electrode). In the cyclic voltammetry, the potential scan rate is preferably <NUM> to <NUM> mV/s, more preferably <NUM> to <NUM> mV/s.

Although properly adjusted according to the permeability of the membrane, the anion concentration in the aqueous solution is preferably <NUM> to <NUM> mass%.

Silver tends to react with oxygen to be oxidized. Accordingly, in order to prevent oxidization of silver-metal contained in the working electrode, the aqueous solution is preferably saturated with nitrogen gas and the measurement is preferably carried out in a nitrogen gas atmosphere. The measurement temperature is preferably <NUM> to <NUM>.

In the present embodiment, the apparatus is preferably further equipped with such a protective film as prevents the aqueous solution from direct contact with the working electrode containing silver-metal. For example, in an embodied case different from one shown in <FIG>, the working electrode, the counter electrode and the reference electrode are brought in contact with the aqueous solution contained in a vessel. In that system, after the graphene-containing membrane as the measurement object is overlaid on a part of the working electrode, the bare part of the working electrode can be covered with the protective film. In that embodied case, the method of the embodiment can be carried out by use of a versatile vessel instead of the cylinder <NUM> and the seal <NUM> in combination, in which there is fear of leakage of the aqueous solution.

As the anions in the present embodiment, halogen or hydroxide ions are preferably used. Halogen ions have high reactivity with silver, and the size and/or reaction potential thereof can be easily changed by selecting proper ions from chloride ions, bromide ions, iodide ions and the like. Hydroxide ions also have high reactivity with silver, and are suitable for evaluating the ion-permeability of the graphene-containing membrane under an alkaline condition.

There are no particular restrictions on the graphene-containing membrane as the object evaluated by the method of the present embodiment, but the membrane is preferably a graphene-containing one employed as a transparent electrode in a photoelectric conversion device.

The working electrode in the present embodiment contains silver-metal, which may be either pure silver or an alloy. The alloy is preferably silver with Pd, Pt, Au, Sn, Zn or Cu. The working electrode may be silver-metal in the shape of a film, a rod or a pad. Further, the silver-metal may be silver nanowires. In that case, the working electrode may consist of only silver nanowires or may be made of silver nanowires combined with electroconductive material.

If the working electrode is an ultrathin film of silver-metal, the average thickness thereof is preferably <NUM> to <NUM>. If thinner than <NUM>, the electrode tends to have such high electric resistance that it is often difficult to measure the reaction current with high accuracy. On the other hand, if the electrode is thicker than <NUM>, the transparency thereof may be impaired. The thickness is more preferably <NUM> to <NUM> inclusive. If the silver-metal is silver nano-wires, the average diameter thereof is preferably <NUM> to <NUM>. If it is smaller than <NUM>, the stability tends to be lowered. On the other hand, if it is larger than <NUM>, a dispersion thereof tends to be unstable. If the working electrode is in the shape of a film, the average thickness thereof is preferably <NUM> to <NUM> in view of processing and handling.

The thickness of the silver film or the diameter of the silver nanowires can be measured by observing the surface or section thereof with an electron microscope. Specifically, a planer image of the silver nanowires is observed to measure widths thereof. If one of the silver nanowires has an uneven width, the width is measured at three points. The average value can be obtained from the results at <NUM> measured points randomly selected.

The graphene-containing membrane as the measurement object can be produced in various manners.

There are some kinds of the graphene-containing membrane, and one of them is a monolayer graphene film. The monolayer graphene film can be produced according to, for example, chemical vapor deposition (CVD) method. Specifically, a graphene layer is formed on an underlying catalyst layer of Cu foil according to the CVD method in which a mixed gas of methane, hydrogen and argon is used as the reaction gas. The surface of the Cu foil is preferably beforehand subjected to anneal treatment so as to grow crystal grains on the Cu foil surface. The anneal treatment can be carried out by laser irradiation heating. The formed graphene layer is heated in a stream of argon mixed gas, and then cooled in a stream of argon gas. After a thermal transfer film is laminated by press-bonding onto the surface of the formed graphene layer, the layered body is immersed in ammonia alkaline copper(II) chloride etchant so that Cu may be dissolved to transfer the graphene monolayer onto the thermal transfer film. Thus, a monolayer graphene film can be produced.

It is also possible to produce a multilayer graphene film having a laminated structure of graphene layers. The multilayer graphene film can be formed by repeating the procedure of forming a monolayer graphene film so that the monolayer graphene films may be stacked.

The thus-formed graphene-containing membrane can be heat-transferred onto a film containing silver-metal.

It is also possible to produce a membrane containing graphene in which carbon atoms in the graphene skeleton are partly substituted with nitrogen atoms (hereinafter, this membrane is often referred to as "nitrogen-substituted graphene-containing membrane"). The graphene-containing membrane of this kind is preferred because interacting with the anions largely enough to reduce diffusion of the anions.

The above kind of graphene-containing membrane can be formed by the CVD method in which not only basic materials such as methane and hydrogen but also low molecular-weight nitrogen compounds such as ammonia, pyridine, methylamine, ethylenediamine and urea are used in combination.

Further, the nitrogen-substituted graphene-containing membrane can be formed by a method other than the above CVD method. For example, an aqueous dispersion of graphene oxide is applied by spin-coating on metal (e.g., Cu) surface to form a film, which is then subjected to heat treatment under a mixed gas atmosphere of ammonia, hydrogen and argon. By adopting this treatment, a part of carbon atoms in the graphene skeleton can be replaced with nitrogen atoms.

Furthermore, the nitrogen-substituted graphene-containing membrane can be formed by any of the following methods:.

Still further, it is yet also possible to produce a membrane containing graphene in which an alkyl chain-containing substituent is connected to the graphene skeleton. The graphene-containing membrane of this kind has such improved dispersibility in organic solvent as to be easily formed in film shape. In addition, because of the alkyl chain-containing substituent, it can reduce diffusion of the anions. This kind of graphene-containing membrane can be produced by making graphene oxide react with a reducing agent and a compound having both an alkyl chain and a functional group capable of reacting with a functional group, such as carboxyl, hydroxy or epoxy, of the graphene oxide. The alkyl chain preferably has <NUM> to <NUM> carbon atoms in view of dispersibility, may have a branched structure and may contain a hetero atom such as oxygen or nitrogen atom in the chain. The terminal group may be methyl, hydroxy, amino or carboxyl. It is possible to control the zeta potential of the graphene membrane by selecting the terminal group. If the alkyl chain-containing compound is reductive, the reducing agent can be omitted. As the reducing agent, hydrazine is preferred for producing a nitrogen-substituted graphene-containing membrane.

Yet further, it is still also possible to produce a membrane containing graphene in which carbon atoms in the graphene skeleton are partly substituted with boron atoms. This kind of graphene-containing membrane can be formed by the CVD method in which diborane, methane, hydrogen and argon are used as the mixed reaction gas.

A layered structure of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film of about <NUM> thickness is spin-coated with an aqueous solution of graphene oxide (manufactured by Graphenea), which is then reduced at <NUM> in hydrated hydrazine vapor to form a nitrogen-substituted graphene-containing membrane. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms.

A titanium wire is fixed on the ITO/silver alloy/ITO with silver paste so that they can be electrically connected. The bonding part is protected with a silicone tape, and the back surface of the PET film is also protected with a silicone tape. The thus-prepared sample is immersed in a <NUM> mass% aqueous sodium chloride solution and subjected to cyclic voltammetry (sample area: <NUM><NUM>). In the meantime, a sample prepared by only heating at <NUM> (sample area: <NUM><NUM>) as a sample not comprising the graphene-containing membrane, another sample prepared by heating at <NUM> in hydrazine hydrate vapor (sample area: <NUM><NUM>) and yet another sample prepared by spin-coating of graphene oxide and heating at <NUM> (sample area: <NUM><NUM>) are subjected to cyclic voltammetry in the same manner.

<FIG> shows cyclic voltammograms measured at <NUM> mV/s under the same measurement conditions. From the waveform area on the positive potential side, the reaction amount between chloride ions and silver, namely, the integrated charge amount can be obtained. Here, the "waveform area" represents a total of charge when the potential is increased and decreased. The integrated charge amounts can be compared by comparing the waveform areas. Specifically, on the assumption that the waveform area corresponding to the integrated charge amount Q<NUM> of the sample (<NUM>) having the nitrogen-substituted graphene-containing membrane is regarded as <NUM>, that corresponding to the integrated charge amount Q<NUM> of the sample (<NUM>), which does not have the substituted graphene-containing membrane and which is only heated at <NUM>, is <NUM>. Those of the sample (<NUM>), which is heated at <NUM> in hydrazine hydrate vapor, and of the sample (<NUM>), which is spin-coated with graphene oxide and heated at <NUM>, are <NUM> and <NUM>, respectively. Accordingly, the integrated charge amount of the sample having the nitrogen-substituted graphene-containing membrane is <NUM>% (<NUM>/<NUM>) based on that of the sample not having the graphene-containing membrane. The reaction amount with chloride ions in the sample having the graphene oxide membrane is larger than that in the sample not having the graphene-containing membrane. The reason of that is thought to be because of the concentration effect.

An aqueous solution of branched polyethyleneimine is added into an aqueous dispersion of graphene oxide, and heated at <NUM> for <NUM> hour. Subsequently, after hydrated hydrazine is added, the solution is further heated at <NUM> for <NUM> hour. The obtained mixture is subjected to centrifugation at <NUM> rpm, and the precipitates are collected. The precipitates are dispersed again in water, and then subjected to centrifugation at <NUM> rpm to obtain precipitates. Those procedures are repeated twice to remove unreacted polyethyleneimine and hydrated hydrazine. The resultant precipitates are dried and then dispersed in iso-propanol.

Thereafter, a layered structure of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film of about <NUM> thickness is coated with the above iso-propanol dispersion with a bar-coater, and then dried at <NUM>. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. In this case, the membrane contains many nitrogen atoms coming from the polyethyleneimine. From IR spectroscopy, it is found that the graphene is linked with an alkyl chain.

A titanium wire is fixed on the ITO/silver alloy/ITO with silver paste so that they can be electrically connected. As shown in <FIG>, the graphene-containing membrane is then brought into contact with a <NUM> mass% aqueous sodium chloride solution. In order to prevent the solution from leaking out, a seal is provided between the membrane and the vessel containing the solution. The cyclic voltammetry is then carried out (sample area: <NUM><NUM>). In the meantime, a sample prepared by only heating at <NUM> as a sample not comprising the graphene-containing membrane is subjected to the cyclic voltammetry in the same manner. The measurements of those samples are carried out under the same condition (<NUM> mV/s). As a result, the reaction amount between chloride ions and silver in the sample having the graphene-containing membrane is less than <NUM>% based on that in the sample not comprising the graphene-containing membrane.

A Cu foil is irradiated with laser light to heat the surface, and annealed to grow crystal grains. The thus-treated Cu foil is employed as an underlying catalyst layer, on which a planar monolayer nitrogen-substituted graphene-containing membrane is formed by the CVD method in which ammonia, methane, hydrogen and argon (<NUM>:<NUM>:<NUM>:<NUM> ccm) are used as a mixed reaction gas at <NUM> for <NUM> minutes. In this procedure, the formed membrane is almost a monolayer nitrogen-substituted graphene-containing one but, depending on the conditions, partly a bi- or more- layered nitrogen-substituted graphene-containing membrane may be formed. After treated at <NUM> for <NUM> minutes in a stream of ammonia-argon mixed gas, the formed membrane is cooled in a stream of argon gas. The monolayer nitrogen-substituted graphene-containing membrane and a thermal transfer film (thickness: <NUM>) are pressed and adhered together, and then immersed in ammonia alkaline copper(II) chloride etchant so that Cu may be dissolved to transfer the monolayer nitrogen-substituted graphene-containing membrane onto the thermal transfer film. The same procedure is repeated four times to obtain a multilayer nitrogen-substituted graphene-containing membrane.

Subsequently, the thermal transfer film is laminated on a layered structure of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film of about <NUM> thickness, and then heated so as to transfer the graphene-containing membrane. From XPS measurement, the nitrogen content is found to be <NUM> to <NUM> atom% under that condition.

The procedure of Example <NUM> is repeated except that the iso-propanol dispersion of graphene obtained in Example <NUM> is applied with a bar coater on a coating film of silver nanowires having an average diameter of <NUM> and that the concentration of the aqueous sodium chloride solution is changed into <NUM> mass%, to evaluate the chloride ion permeability. The coating film of silver nanowires is formed on a PET film of about <NUM> thickness. The measurements are carried out under the same condition (<NUM> mV/s). As a result, the reaction amount between chloride ions and silver in the sample having the graphene-containing membrane is less than <NUM>% based on that in the sample not comprising the graphene-containing membrane.

A solar cell <NUM> shown in <FIG> is produced.

In the same manner as in Example <NUM>, a layered structure <NUM> of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film <NUM> of about <NUM> thickness is spin-coated with an aqueous solution of graphene oxide (manufactured by Graphenea), which is then reduced at <NUM> in hydrated hydrazine vapor to form a nitrogen-substituted graphene-containing membrane <NUM>. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. On the membrane <NUM>, a toluene solution of C<NUM>-PCBN is applied with a bar coater and then dried to form an electron transport layer <NUM>. Subsequently, a chlorobenzene solution containing poly(<NUM>-hexyl- thiophene-<NUM>,<NUM>-diyl) (hereinafter, referred to as "P3HT") and C<NUM>-PCBM is applied with a bar-coater, and dried at <NUM> for <NUM> minutes to form a photoelectric conversion layer <NUM>.

One surface of a stainless steel foil <NUM> provided with an insulating ceramic film formed on the other surface is treated with diluted hydrochloric acid to remove the surface oxide film, and then spin-coated with an aqueous solution of graphene oxide to form a graphene oxide membrane, which is thereafter reduced at <NUM> in hydrated hydrazine vapor to form a nitrogen-substituted graphene-containing membrane <NUM>.

On the nitrogen-substituted graphene-containing membrane <NUM>, an aqueous PEDOT·PSS solution containing sorbitol is applied with a bar coater and dried at <NUM> for <NUM> minutes to form an adhesive layer <NUM> containing PEDOT·PSS (thickness: <NUM>).

The thus-prepared laminate is then so adhered at <NUM> on the photoelectric conversion layer <NUM> that the above adhesive layer <NUM> may be in contact with the conversion layer <NUM>. UV-cut ink containing <NUM>-hydroxy-<NUM>-methoxybenzophenone is screen-printed on the surface of the PET film to form a UV-cut layer <NUM>, on which a silica film is then formed by vacuum deposition to form a gas-barrier layer <NUM>. In this way, a solar cell <NUM> is produced.

The thus-produced solar cell shows an energy conversion efficiency of <NUM>% or more under <NUM> SUN solar light illumination, and the efficiency deteriorates by less than <NUM>% even after the solar cell is left outdoor for <NUM> month.

In the same manner as in Example <NUM>, an aqueous solution of branched polyethyleneimine is added into an aqueous dispersion of graphene oxide, and heated at <NUM> for <NUM> hour. Subsequently, after hydrated hydrazine is added, the solution is further heated at <NUM> for <NUM> hour. The obtained mixture is subjected to centrifugation at <NUM> rpm, and the precipitates are collected. The precipitates are dispersed again in water, and then subjected to centrifugation at <NUM> rpm to obtain precipitates. Those procedures are repeated twice to remove unreacted polyethyleneimine and hydrated hydrazine. The resultant precipitates are dried and then dispersed in iso-propanol.

Thereafter, a layered structure of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film of about <NUM> thickness is coated with the above iso-propanol dispersion with a bar-coater, and then dried at <NUM> to obtain a nitrogen-substituted graphene-containing membrane. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. In this case, the membrane contains many nitrogen atoms coming from the polyethyleneimine. From IR spectroscopy, it is found that the graphene is linked with an alkyl chain.

On the above graphene-containing membrane, a toluene solution of C<NUM>-PCBN is applied with a bar coater and then dried to form an electron transport layer. Subsequently, a chlorobenzene solution containing poly(<NUM>-hexylthiophene-<NUM>,<NUM>-diyl) (hereinafter, referred to as "P3HT") and C<NUM>-PCBM is applied with a bar-coater, and dried at <NUM> for <NUM> minutes to form a photoelectric conversion layer.

One surface of a stainless steel foil provided with an insulating ceramic film formed on the other surface is treated with diluted hydrochloric acid to remove the surface oxide film, and then spin-coated with the above iso-propanol dispersion of nitrogen-substituted graphene to form a nitrogen-substituted graphene-containing membrane. Thereafter, the procedure of Example <NUM> is repeated to produce a solar cell.

The procedure of Example <NUM> is repeated except for not producing the nitrogen-substituted graphene-containing membranes <NUM> and <NUM>, to produce a solar cell. The obtained solar cell shows an energy conversion efficiency of <NUM>% or more under <NUM> SUN solar light illumination, but the efficiency deteriorates by <NUM>% or more after the solar cell is left outdoor for <NUM> month.

An organic EL device <NUM> shown in <FIG> is produced.

In the same manner as in Example <NUM>, a layered structure <NUM> of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film <NUM> of about <NUM> thickness is spin-coated with an aqueous solution of graphene oxide (manufactured by Graphenea), which is then reduced at <NUM> in hydrated hydrazine vapor to form a nitrogen-substituted graphene-containing membrane <NUM>. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. On the membrane <NUM>, tris(<NUM>-hydroxyquinoline)- aluminum (Alq<NUM>) (<NUM>) is vapor-deposited to form a photoelectric conversion layer <NUM>. Further, N,N'-di-<NUM>-naphthyl-N,N'-diphenyl-<NUM>,<NUM>'-biphenyl-<NUM>,<NUM>'-diamine (hereinafter, referred to as "NPD") is vapor-deposited thereon in a thickness of <NUM> to form a hole transport layer <NUM>. Furthermore, a gold electrode <NUM> is formed thereon by sputtering. Finally, the boundary is sealed to produce an organic EL device.

The obtained organic EL device hardly deteriorates in output light. Specifically, even after continuous running for <NUM> hours, the output falls by <NUM>% or less.

A transparent organic EL device is produced.

In the same manner as in Example <NUM>, a layered structure of ITO (thickness: <NUM>)/silver alloy (thickness: <NUM>)/ITO (thickness: <NUM>) provided on a PET film of about <NUM> thickness is spin-coated with an aqueous solution of graphene oxide (manufactured by Graphenea), which is then reduced at <NUM> in hydrated hydrazine vapor to form a nitrogen-substituted graphene-containing membrane. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. On the graphene, tris(<NUM>-hydroxyquinoline)aluminum (Alq<NUM>) (<NUM>) is vapor-deposited to form a photoelectric conversion layer serving as a light-emitting layer. Further, N,N'-di-<NUM>-naphthyl-N,N'-diphenyl-<NUM>,<NUM>'-biphenyl-<NUM>,<NUM>'-diamine (hereinafter, referred to as "NPD") is vapor-deposited thereon in a thickness of <NUM> to form a hole transport layer. Furthermore, a film of a-ITO (<NUM>)/silver (<NUM>)/a-ITO (<NUM>) is formed thereon by sputtering. Finally, the boundary of the device is sealed to produce an organic EL device.

The procedure of Example <NUM> is repeated except for not forming the nitrogen-substituted graphene-containing membrane, to produce an organic EL device. The obtained organic EL device so deteriorates that the output falls to <NUM>% or less after continuous running for <NUM> hours.

A titanium wire is fixed on the ITO/silver alloy/ITO with silver paste so that they can be electrically connected. The bonding part is protected with a silicone tape, and the back surface of the PET film is also protected with a silicone tape. The thus-prepared sample is immersed in a <NUM> mass% aqueous sodium chloride solution and subjected to cyclic voltammetry. In the meantime, a sample prepared by only heating at <NUM> as a sample not comprising the graphene-containing membrane is subjected to cyclic voltammetry in the same manner. The measurements of those samples are carried out under the same condition (<NUM> mV/s). As a result, the reaction amount between chloride ions and silver in the sample having the graphene-containing membrane is <NUM>% based on that in the sample not comprising the graphene-containing membrane.

Thereafter, the procedure of Example <NUM> is repeated to produce an organic EL device. The obtained organic EL device hardly deteriorates in output light. Specifically, even after continuous running for <NUM> hours, the output falls by <NUM>% or less.

A titanium wire is fixed on the ITO/silver alloy/ITO with silver paste so as to ensure electric conduction. The bonding part is protected with a silicone tape, and the back surface of the PET film is also protected with a silicone tape. The thus-prepared sample is immersed in a <NUM> mass% aqueous sodium chloride solution and subjected to cyclic voltammetry. In the meantime, a sample prepared by only heating at <NUM> as a sample not comprising the graphene-containing membrane is subjected to cyclic voltammetry in the same manner. The measurements of those samples are carried out under the same condition (<NUM> mV/s). As a result, the reaction amount between chloride ions and silver in the sample having the graphene-containing membrane is <NUM>% based on that in the sample not comprising the graphene-containing membrane.

Thereafter, the procedure of Example <NUM> is repeated to produce an organic EL device. The obtained organic EL device so deteriorates that the output falls to <NUM>% or less after continuous running for <NUM> hours.

Silver nanowires having an average diameter of <NUM> are applied with a bar coater on a PET film of about <NUM> thickness. Further, the above iso-propanol dispersion is applied thereon with a bar-coater and then dried at <NUM> to obtain a nitrogen-substituted graphene-containing membrane. From XPS measurement, the content of the nitrogen atoms is found to be <NUM>% of the carbon atoms. In this case, the membrane contains many nitrogen atoms coming from the polyethyleneimine. From IR spectroscopy, it is found that the graphene is linked with an alkyl chain.

On the above graphene-containing membrane, a toluene solution of C<NUM>-PCBN is applied with a bar coater and then dried to form an electron transport layer. Subsequently, a chlorobenzene solution containing poly(<NUM>-hexylthiophene-<NUM>,<NUM>-diyl) (hereinafter, referred to as "P3HT") and C<NUM>-PCBM is applied with a bar-coater, and dried at <NUM> for <NUM> minutes to form a photo- electric conversion layer.

Claim 1:
A method for evaluating anion-permeability of a graphene-containing membrane (<NUM>) comprising the steps of:
(i) preparing a measuring apparatus which comprises an aqueous solution containing anions (<NUM>), a working electrode (<NUM>) containing silver-metal, a counter electrode (<NUM>) and a reference electrode (<NUM>) and in which said working electrode, said counter electrode and said reference electrode are electrically connected through an external circuit;
(ii) measuring the reaction current I<NUM> between the silver-metal and the anions while the electrode potential of said working electrode to said counter electrode is being periodically changed and driven under the condition that said working electrode, said counter electrode and said reference electrode are in contact with said aqueous solution;
(iii) measuring the reaction current I<NUM> between the silver-metal and the anions while the electrode potential of said working electrode to said counter electrode is being periodically changed and driven under the condition that, instead of said working electrode, the graphene-containing membrane electrically connecting to said working electrode is in contact with said aqueous solution and that said working electrode is not directly in contact with said aqueous solution; and
(iv) comparing the reaction currents I<NUM> in (ii) and I<NUM> in (iii) so as to evaluate anion-permeability of said graphene-containing membrane.