Patent Description:
As people pay ever-increasing attention to environmental protection, the international and domestic emission standards for combustion-related pollutants are becoming increasingly strict. It has been difficult for some traditional smoke purification methods to make the concentration of pollutants in smoke meet the emission standards. On the other hand, in order to meet higher emission standards, the cost of the existing smoke purification methods and the production, operation and maintenance cost of the existing smoke purification apparatuses have also increased significantly.

In the prior art, the low-temperature plasma (Non-thermal Plasma, NTP) technology has been used to purify the tail gas generated by combustion. Low-temperature plasma is the fourth state of matter following solid, liquid and gaseous states. When the applied voltage reaches the discharge voltage of gas, the gas is broken down to generate a mixture of electrons, various ions, atoms and free radicals. Although the electron temperature is very high in the course of discharge, the temperature of heavy particles is very low and the whole system is in a low temperature state, so this state is called low-temperature plasma and also known as non-equilibrium plasma. The deacidification and denitration principles of the existing NTP technology are that high-energy electrons are generated in a plasma discharge zone to initiate the generation of free radicals such as O, OH, HOz, O<NUM> and other active elements, and the active elements oxidize SO<NUM> and NOx in smoke into high-valence substances, which are finally converted into sulfates and nitrates under the action of sprayed NH<NUM> to achieve removal.

The main features of the existing NTP denitration technology are as follows: <NUM>) the NOx in smoke is treated, but cannot be prevented; <NUM>) the existing NTP technology is a process for achieving denitration by an oxidation reaction of active free radicals directly with the SO<NUM> and NOx molecules in smoke, so it is necessary to enhance the energy density of a discharge zone to increase the free radical density in a reaction area to improve the removal efficiency of SO<NUM> and NOx, but when the energy density is constant, the removal efficiency of NOx and SO<NUM> decreases with an increase in their initial concentration; and <NUM>) the existing NTP technology cannot be used in high-temperature smoke due to a reactor itself, and hence cannot increase the free radical density in the reaction area by high temperature. Therefore, the existing NTP technology has the following disadvantages: the removal efficiency of pollutants is low, and the pollutants fail to meet the standards if the technology is used alone. If a higher removal efficiency is to be achieved, especially in the presence of multiple pollutants, the power needs to be increased, which obviously increases the cost and the requirements for apparatuses. In order to improve the removal efficiency of multiple pollutants in smoke by the NTP technology, in the Chinese Invention Patent Application (<CIT>), a method of dividing a conventional low-temperature plasma into multiple reactor sections is used, and synergists and accelerators are respectively added to different reaction sections, but multi-section reactors are more expensive, and the cost of synergists and accelerators is also higher. In the Chinese Invention Patent Application (<CIT>), a method of oxidizing multiple pollutants in smoke by a low-temperature plasma-assisted catalyst is used to achieve the combined oxidation of multiple pollutants such as SO<NUM>, NOx and Hg<NUM> in smoke, but a solid catalyst is required and its cost is high, and there is also the problem of post-treatment of the catalyst used.

Therefore, those skilled in the art are devoted to developing a method and system capable of effectively reducing the concentration of pollutants in smoke generated by combustion.

<CIT> discloses a device that uses electrical discharges/nonthermal plasmas in a gaseous medium to activate a fuel or fuel-oxidizer mixture. <CIT> discloses a combustion-supporting device of a coal-fired gasification furnace. <CIT> discloses a plasma generating device for an internal combustion engine. <CIT> discloses a device for the pre-treatment of combustion air by exposure to non-thermal plasma.

In view of the above defects of the prior art, a technical problem to be solved by the present invention is to provide a method and system capable of effectively reducing the concentration of pollutants in smoke generated by combustion.

In the prior art, people have noticed the characteristics of low-temperature plasma, and used the characteristics to purify the pollutants that have been produced in the tail gas generated by combustion, which is a remedial treatment. However, in the present invention, the characteristics are used to activate the combustion-supporting gas involved in a combustion reaction before or during combustion, thereby inhibiting the generation of pollutants in the combustion reaction, which is a preventive smoke pollution control technology.

Specifically, in the prior art, the process and principle of using the NTP technology to treat the tail gas generated by combustion are as follows:.

The products generated are high-valence nitrogen and sulfur oxides, and therefore must be neutralized with a agent, usually ammonia, to produce ammonium nitrate and ammonium sulfate. Recently, a relatively expensive agent N<NUM>H<NUM> has been used to generate reducing H that reduces NO to N<NUM>. Although high-valence nitrogen and sulfur oxides are avoided, the agent also costs much.

However, according to the present invention, when NTP or microwave is used to activate the combustion-supporting gas before a combustion reaction occurs, the reactions (<NUM>)-(<NUM>) may occur, but the reactions (<NUM>)-(<NUM>) do not occur. Moreover, the chemically active particles formed in the reactions (<NUM>)-(<NUM>) can further undergo the following reactions under the high temperature conditions of combustion to accelerate the thermochemical conversion and promote the complete combustion of fuel:.

Although N<NUM> is activated and may be oxidized, due to the generation and activation of a large number of reducing molecules such as H<NUM>: <MAT> <MAT>, the activated H radicals have extremely high reducibility and can quickly reduce intermediate products of N.

Moreover, in the combustion process, the most effective active element is O, i.e. active O atoms, followed by other neutral atoms and active elements. It is easier for active O atoms to oxidize fuel molecules than N<NUM>, which is a recognized principle in this field. Active O atoms can not only promote ignition, but also help oxidize and eliminate those intermediate products that can produce dioxins, i.e. carbon-based substances, so dioxins lose carriers and precursors for their synthesis.

In order to promote the occurrence of the reactions (<NUM>) and (<NUM>), air can be humidified or water vapor discharged as exhaust gas can be introduced before the NTP reactor and microwave pretreatment.

Based on the above principles, the present invention first provides a method for reducing the concentration of pollutants in smoke generated by combustion, which is characterized in that: combustion-supporting gas is first subjected to low-temperature plasma or microwave activation, and then supplied as secondary air to complete the combustion of a combustible material, and the secondary air is activated and supplied to the center of the flame. The pollutants are NOx and/or dioxins and/or CO. The combustible material is selected from one or more of waste, coal, biomass, oil, volatile matter and combustible gas. The combustion-supporting gas is air.

The temperature of the combustion-supporting gas is between normal temperature and <NUM>. The combustion-supporting gas may also be humidified gas. The activation is a process of introducing the combustion-supporting gas to a low-temperature plasma reactor or a microwave reactor to generate chemically active particles. The chemically active particles are free radicals such as active O atoms, H atoms, O<NUM> or OH, and HO<NUM>. The low-temperature plasma reactor and/or microwave reactor is divided into one or two sections. The method further comprises a step of further purifying the smoke generated by combustion. The further purification step is a deacidification and/or dust removal step. The present invention also provides a system for reducing the concentration of pollutants in smoke generated by combustion, which is characterized by comprising a combustion-supporting gas pretreater and a combustion furnace, the combustion-supporting gas pretreater being connected to the combustion furnace through an air supply duct, wherein the combustion-supporting gas pretreater is a low-temperature plasma reactor or a microwave reactor, and is arranged at the upstream of the combustion furnace; and the combustion furnace is an incinerator, a boiler, a sintering furnace, a gasifier or a pyrolysis furnace where fuels such as coal, biomass, waste, oil, combustible gas and volatile matter are to be burnt. The system may further comprise a deacidification and/or dust removal apparatus which is located at the downstream of the combustion furnace and connected to the combustion furnace through an air supply duct. The generator mode of the low-temperature plasma reactor is corona discharge, pulsed arc discharge, glow discharge or dielectric barrier discharge.

The method and system provided by the present invention have the following beneficial effects: <NUM>) the generation of NOx and dioxins during combustion can be inhibited, and the concentration of pollutants in smoke generated by combustion can be effectively reduced, wherein the generation of NOx is inhibited by more than <NUM>% and the generation of dioxins is inhibited by more than <NUM>%; <NUM>) the low-temperature plasma reactor and/or microwave reactor does not contact corrosive components in smoke, and has no dust contamination and product accumulation, and hence is very easy to maintain and has a greatly prolonged life; <NUM>) there is no need to add a catalyst to the low-temperature plasma reactor and/or microwave reactor or to spray ammonia after reaction; and no additional secondary pollution is caused; and <NUM>) only an acidic gas and dust purification facility needs to be kept in a smoke cooling and purification system, and a low-temperature plasma reactor and/or a microwave reactor is additionally arranged at an air supply position to avoid any impact on a smoke waste-heat recovery process, so such arrangement is simple and feasible for the existing device.

The concept, specific structure and technical effects of the present invention will be further described below in conjunction with the drawings so as to fully understand the objects, features and effects of the present invention.

The present invention will be further described below with reference to the drawings and particular embodiments.

For a waste incinerator using an existing wet purification system for purification, the concentration of acidic gas was qualified, but the concentration of NOx was <NUM>/m<NUM>, and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM> and also unqualified.

By adopting the method of the present invention, all the secondary air was treated by a high voltage direct current (HVDC) pulse-type low-temperature plasma reactor and then fed into a nozzle of the secondary air, wherein the pulse discharge power was <NUM> J/pulse. Without changing any other settings of the system, it was found that the concentration of NOx was <NUM>/m<NUM>, and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>, which met the new emission standards. The purification efficiency reached <NUM>% and <NUM>% respectively.

In the smoke from a sintering furnace of an iron and steel plant, the concentration of NOx was <NUM>/m<NUM>, which failed to meet the new emission standards; and dioxins had an emission concentration of <NUM> ng-TEQ/Nm<NUM>, a low temperature (<NUM>-<NUM>) and a high flow rate. SNCR denitrification could not be carried out, and the cost of SCR denitrification was high.

By adopting the method of the present invention, the combustion-supporting air for sintering was pretreated by a <NUM>-stage HVDC pulse-type low-temperature plasma reactor and then fed into the sintering furnace, wherein the <NUM>-stage pulse discharge power was <NUM> J/pulse. An existing smoke deacidification and dust removal system was kept. The final concentration of NOx was <NUM>/m<NUM>, and the final concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>, which met the new emission standards. The purification efficiency reached more than <NUM>% and <NUM>% respectively.

An industrial boiler for burning heavy oil was only provided with a deacidification column, in which steam atomization was used. The concentration of SO<NUM> was qualified, but the concentration of NOx was <NUM>/m<NUM>, which failed to meet the local emission standards of air pollutants for boilers (GB-<NUM>-<NUM>) (the limit of NOx is <NUM>/m<NUM>).

When the smoke was purified by the method of the present invention, an HVDC pulse low-temperature plasma reactor was mounted in front of a heavy oil burner to pretreat combustion-supporting air which was then fed into a boiler, wherein the pulse discharge power was <NUM> J/pulse. The final emission concentration of NOx was <NUM>/m<NUM>, which met the emission requirements.

In the above Example <NUM>, when the smoke was purified by the method of the present invention, <NUM>-<NUM>% of the air required for combustion was fed into a <NUM> KW microwave reactor for activation, and then fed into the center of the flame. The final emission concentration of NOx was <NUM>/m<NUM>, which met the emission requirements.

A biomass pellet boiler was provided with a water-film dust removal column. The concentration of acidic gas and dust was qualified, but the emission concentration of NOx was <NUM>/m<NUM> and unqualified, and the advantages of biomass boilers were also not exhibited.

When the smoke was purified by the method of the present invention, a high-voltage AC dielectric barrier discharge low-temperature plasma reactor was mounted in front of a boiler to pretreat combustion-supporting air which was then fed into the boiler, wherein the air supply rate of the boiler was <NUM><NUM>/h. The power of the high-voltage AC dielectric barrier discharge low-temperature plasma reactor was <NUM> KW. The final emission concentration of NOx was <NUM>/m<NUM>, which met the emission requirements.

In the above Example <NUM>, when the smoke was purified by the method of the present invention, the air with a flow rate of <NUM><NUM>/h required for combustion was divided into two streams and fed into a combustion furnace, and the air with a flow rate of <NUM><NUM>/h was fed from a lower part of a grate as primary air; and the air with a flow rate of <NUM><NUM>/h was first fed into a <NUM> KW microwave reactor for activation, and then fed into an upper part of the flame. The final emission concentration of NOx was <NUM>/m<NUM>, which met the emission requirements.

A waste pyrolysis gasifier was equipped with an acidic gas purification and dust removal system, in which the combustible gas generated by gasification was used for combustion. The emissions of HCl, SO<NUM> and dust were qualified. However, the concentration of Ox was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>.

When the smoke was purified by the method of the present invention, combustion-supporting air was pretreated by an HVDC narrow pulse low-temperature plasma reactor and then fed into a combustion furnace, wherein the pulse discharge power was <NUM> J/pulse. On the premise of keeping an existing smoke purification system, the final emissions of HCl, SO<NUM> and dust were still qualified. The concentration of NOx was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>.

In the above Example <NUM>, when the smoke was purified by the method of the present invention, <NUM>% of combustion-supporting air was pretreated by an HVDC narrow pulse low-temperature plasma reactor and then fed into a combustion furnace, wherein the pulse discharge power was <NUM> J/pulse. On the premise of keeping the existing smoke purification system, the final emissions of HCl, SO<NUM> and dust were still qualified. The concentration of NOx was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>.

For an industrial sludge pyrolysis furnace, the volatile matter generated by sludge pyrolysis was used for combustion, the high-temperature smoke generated by combustion was used to heat the pyrolysis furnace, and finally the smoke was cooled and discharged. A deacidification and dust removal system was arranged for the smoke, but no control steps of NOx and no control measures of dioxins were taken. The concentration of NOx in tail gas was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>.

When the smoke was purified by the method of the present invention, <NUM>% of combustion-supporting air was pretreated by an HVDC narrow pulse low-temperature plasma reactor and then fed into the flame center of a combustion furnace, wherein the pulse discharge power was <NUM> J/pulse. On the premise of keeping the existing smoke purification system, the final emissions of HCl, SO<NUM> and dust were still qualified. The concentration of NOx was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>. Since the emission concentration of dioxins for industrial sludge pyrolysis furnaces is <NUM>. 3ng-TEQ/Nm<NUM>, the emission standards have been met.

In the above Example <NUM>, when the smoke was purified by the method of the present invention, all the combustion-supporting air, together with all the residual odor sprayed and cooled by the water vapor generated in the sludge drying process of the system, was pretreated by a microwave reactor with a power of <NUM> KW and then fed into a combustion furnace. On the premise of keeping the existing smoke purification system, the final emissions of HCl, SO<NUM> and dust were still qualified. The concentration of NOx was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>. Since the emission concentration of dioxins for industrial sludge pyrolysis furnaces is <NUM>. 3ng-TEQ/Nm<NUM>, the emission standards have been met.

In the above Example <NUM>, when the smoke was purified by the method of the present invention, <NUM>% of combustion-supporting air was mixed with <NUM>% of high-temperature smoke until the final temperature was <NUM>, and the mixture was fed into a low-temperature plasma reactor with a pulse discharge power of <NUM> J/pulse for treatment, and then into a combustion furnace. On the premise of keeping the existing smoke purification system, the final emissions of HCl, SO<NUM> and dust were still qualified. The concentration of NOx was <NUM>/m<NUM> and the emission concentration of dioxins was <NUM> ng-TEQ/Nm<NUM>. Therefore, the emission standards have been met.

<FIG> shows a system for reducing the concentration of pollutants in smoke generated by combustion not according to the present invention.

Combustion-supporting air <NUM> first enters a low-temperature plasma reactor <NUM> via an air supply duct to form activated combustion-supporting air <NUM> which then enters a combustion furnace <NUM>. The combustion furnace <NUM> is an incinerator, a boiler, a sintering furnace, a gasifier or a pyrolysis furnace where fuels such as coal, biomass, waste, oil, combustible gas and volatile matter are to be burnt. The combustion-supporting air then enters a deacidification and/or dust removal apparatus <NUM> for purification, and exhaust gas that meets the emission standards is finally formed and discharged into the atmosphere.

<FIG> shows an embodiment of the system for reducing the concentration of pollutants in smoke generated by combustion according to the present invention. <NUM>%-<NUM>% of combustion-supporting air <NUM> first enters a low-temperature plasma reactor and/or a microwave reactor <NUM> via a secondary air duct to form activated combustion-supporting air <NUM> which then enters the center or/and an upper part of the flame in a combustion furnace <NUM>. The combustion furnace <NUM> is an incinerator, a boiler, a sintering furnace, a gasifier or a pyrolysis furnace where fuels such as coal, biomass, waste, oil, combustible gas and volatile matter are to be burnt. The combustion-supporting air then enters a deacidification and/or dust removal apparatus <NUM> for purification, and exhaust gas that meets the emission standards is finally formed and discharged into the atmosphere.

In the field, low-temperature plasma refers to an activated form formed by allowing normal or negative pressure gas to be partially ionized after treatment with corona discharge, pulsed arc discharge, glow discharge or dielectric barrier discharge, etc., in which equal amounts of positive and negative ions coexist in the gas; and the microwave reactor refers to a reactor consisting of a power source (that can generally provide a high voltage of <NUM>,<NUM> V and above), a magnetron, a control circuit, a treatment chamber and the like, wherein the magnetron continuously generates microwaves under the excitation of the power source, and then is coupled into the treatment chamber through a waveguide system, and the normal or negative pressure air flow passes through the treatment chamber to form active gas.

In the field, the primary air refers to the air, oxygen or oxygen-containing gas in the combustion-supporting gas that is distributed to contact a combustible material for the first time and allows the combustible material to be burnt, generally accounting for <NUM>% or more of the total amount of the combustion-supporting gas; and the secondary air refers to the air, oxygen, oxygen-containing gas or just water vapor in the combustion-supporting gas that is distributed to the center or an upper part of the flame and allows the residual combustible material in the flame to be burnt out, generally accounting for <NUM>-<NUM>% of the combustion-supporting gas.

Claim 1:
A method for reducing the concentration of pollutants in smoke generated by combustion, characterized in that:
combustion-supporting gas is divided into two streams, wherein one stream is primary air, which accounts for <NUM>% or more of total amount of the combustion-supporting gas, and another stream is secondary air, which accounts for <NUM>%-<NUM>% of total amount of the combustion-supporting gas;
the primary air is directly fed into a combustion furnace, and the primary air is in contact with a combustible material within the combustion furnace, wherein the combustible material is selected from one or more of waste, coal, biomass, oil, volatile matter and combustible gas;
the secondary air is subjected to low-temperature plasma or microwave activation to generate chemically active particles, and then the activated secondary air is fed into the combustion furnace; and
the activated secondary air is supplied into the center of the combustion flame within the combustion furnace.