Patent Description:
The present disclosure relates to a radar transmissive ("RT") coating compositions, layers, and systems and methods for making and using the same.

Autonomous vehicles use various sensor systems, such as cameras, radar, and LIDAR (Light Detection, and Ranging), to detect and locate obstacles in order to safely navigate through an environment. Typically, a radar system includes a transmitter to emit radar waves and a receiver to receive radar waves reflected by the obstacle. Radar waves can be electromagnetic radiation comprising a frequency in a range of <NUM> to <NUM>. Some surfaces may present detection challenges for some radar systems.

Compositions comprising a film-forming resin as well as electrically conductive particles and/or radar transmissive pigments are described in <CIT>, <CIT>, <CIT>, and <CIT>.

The present disclosure provides a coating composition according to claim <NUM>. The coating composition comprises a film-forming resin and <NUM>% to <NUM>% of a flake pigment composition, based on the total weight of the coating composition. The flake pigment composition comprises <NUM>% or greater by weight radar transmissive pigment based on the total weight of the pigment composition and no greater than <NUM>% by weight electrically conductive pigment based on the total weight of the pigment composition. The radar transmissive pigment comprises mica pigment, oxide coated mica pigment, glass flake, oxide coated glass flake, visible light diffractive pigment, visible light reflective organic pigment, metal oxide platelets, or a combination thereof. The pigment composition comprises <NUM>% to <NUM>% by weight aluminum flake based on the total weight of the pigment composition. When the coating composition is applied over a thermoplastic polyolefin ("TPO") substrate and cured at a dry film thickness of <NUM> to form a coating system, the coating system transmits <NUM>% or greater of electromagnetic radiation comprising a frequency of <NUM> to <NUM> through the coating system. The coating system has a flop index of <NUM> or greater, wherein flop index = <NUM> (L<NUM>-L<NUM>)<NUM> / (L<NUM>)<NUM>, and wherein L<NUM> is a CIELAB (color space specified by the International Commission on Illumination) L* value as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, L<NUM> is a CIELAB L* as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, and L<NUM> is a CIELAB L* value as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. The coating system has a CIELAB ΔE of <NUM> or less compared to a color-matched coating system, as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

The present disclosure also provides a coating layer formed by the coating composition.

The present disclosure also provides a coating system comprising the coating layer applied over a radar transmissive substrate.

The present disclosure also provides a method according to claim <NUM> for making the coating system.

The present disclosure also provides a method according to claim <NUM> for making the coating composition. The method comprises combining the film-forming resin and the flake pigment composition to form the coating composition.

It is understood that the inventions described in this specification are not limited to the examples summarized in this Summary. Various other aspects are described and exemplified herein.

The features and advantages of the examples, and the manner of attaining them, will become more apparent, and the examples will be better understood by reference to the following description of examples taken in conjunction with the accompanying drawing, wherein:.

The Figure is a schematic representation of an article comprising an example of a coating system according to the present disclosure.

Corresponding reference characters indicate corresponding parts throughout the several views. The exemplifications set out herein illustrate certain examples, in one form, and such exemplifications are not to be construed as limiting the scope of the examples in any manner.

Certain exemplary aspects of the present disclosure will now be described to provide an overall understanding of the principles of the composition, function, manufacture, and use of the compositions and methods disclosed herein. An example or examples of these aspects are illustrated in the accompanying drawing. Those of ordinary skill in the art will understand that the compositions, articles, and methods specifically described herein and illustrated in the accompanying drawing are non-limiting exemplary aspects and that the scope of the various examples of the present invention is defined solely by the claims. The features illustrated or described in connection with one exemplary aspect may be combined with the features of other aspects. Such modifications and variations are intended to be included within the scope of the present invention.

Reference throughout the specification to "various examples," "some examples," "one example," "an example," or the like, means that a particular feature, structure, or characteristic described in connection with the example is included in an example. Thus, appearances of the phrases "in various examples," "in some examples," "in one example," "in an example," or the like, in places throughout the specification are not necessarily all referring to the same example. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in an example or examples. Thus, the particular features, structures, or characteristics illustrated or described in connection with one example may be combined, in whole or in part, with the features, structures, or characteristics of another example or other examples without limitation. Such modifications and variations are intended to be included within the scope of the present examples.

As used in this specification, particularly in connection with coating layers or films, the terms "on," "onto," "over," and variants thereof (e.g., "applied over," "formed over," "deposited over," "provided over," "located over," and the like) mean applied, formed, deposited, provided, or otherwise located over a surface of a substrate but not necessarily in contact with the surface of the substrate. For example, a coating layer "applied over" a substrate does not preclude the presence of another coating layer or other coating layers of the same or different composition located between the applied coating layer and the substrate. Likewise, a second coating layer "applied over" a first coating layer does not preclude the presence of another coating layer or other coating layers of the same or different composition located between the applied second coating layer and the applied first coating layer.

As used in this specification, the terms "polymer" and "polymeric" means prepolymers, oligomers, and both homopolymers and copolymers. As used in this specification, "prepolymer" means a polymer precursor capable of further reactions or polymerization by a reactive group or reactive groups to form a higher molecular mass or crosslinked state.

As used in this specification, the terms "cure" and "curing" refer to the chemical crosslinking of components in a coating composition applied as a coating layer over a substrate. Accordingly, the terms "cure" and "curing" do not encompass solely physical drying of coating compositions through solvent or carrier evaporation. In this regard, the term "cured," as used in this specification, refers to the condition of a coating layer in which a component of the coating composition forming the layer has chemically reacted to form new covalent bonds in the coating layer (e.g., new covalent bonds formed between a binder resin and a curing agent).

As used herein, the term "flop index" is defined according to "<NPL>. Namely, the flop index is defined according to Equation <NUM>, set forth below. <MAT> wherein:.

As used herein the term "silver" includes neutral or gray colors, as well as chromatic colors, such as slightly to significantly violet, blue, green, yellow, orange, red or a color of any hue (CIE hue value between <NUM>° and <NUM>°) that also exhibit a metallic appearance as defined by a flop index of <NUM> or greater.

Typically, a radar system can be mounted behind a coated bumper cover of a vehicle and can emit and receive radar waves via the coated bumper cover. The coating on the bumper cover can provide a desirable aesthetic appearance. However, the coating may cause transmission loss of radar waves, which can affect the performance of the radar system. Thus, an RT coating system and a method for making and using the same are provided. The RT coating system comprises a flop index of <NUM> or greater and <NUM>% or greater radar transmission. The RT coating system comprises a RT coating layer, which comprises a film-forming resin and a pigment composition.

The RT coating layer <NUM> can be applied from a RT coating composition formulated with a liquid viscosity suitable for atomization and droplet formation under the high-shear conditions associated with single or multiple component airless spray application techniques at a temperature of -<NUM> or greater, such as, a temperature of <NUM> or greater, a temperature of <NUM> or greater, a temperature of <NUM> or greater, a temperature of <NUM> or greater, or a temperature of <NUM> or greater. The RT coating composition can be formulated with a liquid viscosity suitable for atomization and droplet formation under the high-shear conditions associated with single or multiple component airless spray application techniques at a temperature of <NUM> or lower, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower. The RT coating composition can be formulated with a liquid viscosity suitable for atomization and droplet formation under the high-shear conditions associated with single or multiple component airless spray application techniques in a temperature range of -<NUM> to <NUM>, such as, -<NUM> to <NUM>, -<NUM> to <NUM>, -<NUM> to <NUM>, or <NUM> to <NUM>.

The RT coating layer <NUM> can comprise a pigment composition suitable to provide a metallic appearance, such as a silver color, to the RT coating system <NUM>. The RT coating system <NUM> comprises a flop index of <NUM> or greater, such as, for example <NUM> or greater, <NUM> or greater, or <NUM> or greater. The RT coating system <NUM> can comprise a flop index of <NUM> or lower, such as, for example, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM>. The RT coating system <NUM> can comprise a flop index in a range of <NUM> to <NUM>, such as, for example <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>.

The RT coating composition comprises <NUM>% or greater by weight pigment composition based on the total weight of the RT coating composition, such as, <NUM>% or greater by weight pigment composition, <NUM>% or greater by weight pigment composition, <NUM>% or greater by weight pigment composition, <NUM>% or greater by weight pigment composition, <NUM>% or greater by weight pigment composition, <NUM>% or greater by weight pigment composition, or <NUM>% or greater by weight pigment composition, all based on the total weight of the RT coating composition. The RT coating composition comprises <NUM>% or lower by weight pigment composition based on the total weight of the RT coating composition, such as, <NUM>% or lower by weight pigment composition, <NUM>% or lower by weight pigment composition, <NUM>% or lower by weight pigment composition, <NUM>% or lower by weight pigment composition, <NUM>% or lower by weight pigment composition, <NUM>% or lower by weight pigment composition, or <NUM>% or lower by weight pigment composition, all based on the total weight of the RT coating composition. The RT coating composition comprises a range of <NUM>% to <NUM>% by weight pigment composition based on the total weight of the RT coating composition, such as, <NUM>% to <NUM>% by weight pigment composition, <NUM>% to <NUM>% by weight pigment composition, <NUM>% to <NUM>% by weight pigment composition, <NUM>% to <NUM>% by weight pigment composition, <NUM>% to <NUM>% by weight pigment composition, or <NUM>% to <NUM>% by weight pigment composition, all based on the total weight of the RT coating composition.

The pigment composition comprises a mixture of different pigments. The pigment composition comprises a radar transmissive pigment and, electrically conductive flake pigment, namely aluminum flake. Additionally, the pigment can comprise, for example, carbazole dioxazine crude pigment, azo, monoazo, disazo, naphthol AS, salt type (lakes), benzimidazolone, condensation, metal complex, isoindolinone, isoindoline and polycyclic phthalocyanine, quinacridone, perylene, perinone, diketopyrrolo pyrrole, thioindigo, anthraquinone, indanthrone, anthrapyrimidine, flavanthrone, pyranthrone, anthanthrone, dioxazine, triarylcarbonium, quinophthalone pigments, diketo pyrrolo pyrrole red, titanium dioxide, carbon black, and combinations of any thereof. The pigment can comprise, for example, a finely divided solid powder that is insoluble but wettable under the conditions of use. The pigment can be organic or inorganic and can be agglomerated or non-agglomerated. The pigment can be incorporated into the RT coating composition by grinding or simple mixing. The pigment can be incorporated by grinding into the coating composition by use of a grind vehicle, such as an acrylic grind vehicle. The pigment can be a flake pigment or other suitable shape.

The pigment composition can affect the color of the RT coating system <NUM> and/or the radar transmission of the RT coating system <NUM>. The pigment composition comprises <NUM>% or greater by weight radar transmissive pigment based on the total weight of the pigment composition, such as, <NUM>% or greater by weight radar transmissive pigment, <NUM>% or greater by weight radar transmissive pigment, <NUM>% or greater by weight radar transmissive pigment, <NUM>% or greater by weight radar transmissive pigment, <NUM>% or greater by weight radar transmissive pigment, <NUM>% or greater by weight radar transmissive pigment, or <NUM>% or greater by weight radar transmissive pigment, all based on the total weight of the pigment composition. The pigment composition can comprise <NUM>% or lower by weight radar transmissive pigment based on the total weight of the pigment composition, such as, <NUM>% or lower by weight radar transmissive pigment, <NUM>% or lower by weight radar transmissive pigment, <NUM>% or lower by weight radar transmissive pigment, <NUM>% or lower by weight radar transmissive pigment, <NUM>% or lower by weight radar transmissive pigment, or <NUM>% or lower by weight radar transmissive pigment, all based on the total weight of the pigment composition. The pigment composition can comprise <NUM>% to <NUM>% by weight radar transmissive pigment based on the total weight of the composition, such as, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, <NUM>% to <NUM>% by weight radar transmissive pigment, or <NUM>% to <NUM>% by weight radar transmissive pigment, all based on the total weight of the pigment composition. The pigment composition can consist essentially of radar transmissive pigment.

The radar transmissive pigment comprises mica pigment, oxide coated mica pigment, glass flake, oxide coated glass flake, visible light diffractive pigment, visible light reflective organic pigment, metal oxide platelets, or a combination thereof. For example, the visible light diffractive pigment can comprise ordered arrays of particles in a polymeric matrix, such as, for example, the color effect pigments described in <CIT>. and the colorant described in <CIT>. The visible light reflective organic pigment can comprise polymeric layers, such as, for example, the pigments described in <CIT>. The metal oxide platelets can be, for example, aluminum oxide and titanium oxide. The radar transmissive pigment can be electrically non-conductive.

The pigment composition can comprise <NUM>% or lower by weight electrically conductive pigment based on the total weight of the pigment composition, such as, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, <NUM>% or lower by weight electrically conductive pigment, or <NUM>% or lower by weight electrically conductive pigment, all based on the total weight of the pigment composition. The pigment composition can comprise <NUM>% or greater by weight electrically conductive pigment based on the total weight of the pigment composition, such as, <NUM>% or greater by weight electrically conductive pigment, <NUM>% or greater by weight electrically conductive pigment, <NUM>% or greater by weight electrically conductive pigment, <NUM>% or greater by weight electrically conductive pigment, <NUM>% or greater by weight electrically conductive pigment, <NUM>% or greater by weight electrically conductive pigment, or <NUM>% or greater by weight electrically conductive pigment, all based on the total weight of the pigment composition. The pigment composition can comprise <NUM>% to <NUM>% by weight electrically conductive pigment based on the total weight of the pigment composition, such as, <NUM>% to <NUM>% by weight electrically conductive pigment, <NUM>% to <NUM>% by weight electrically conductive pigment, <NUM>% to <NUM>% by weight electrically conductive pigment, <NUM>% to <NUM>% by weight electrically conductive pigment, or <NUM>% to <NUM>% by weight electrically conductive pigment, all based on the total weight of the pigment composition.

In addition to aluminum flake, the electrically conductive pigment can comprise electrically conductive material or comprise a dielectric substrate and an electrically conductive layer surrounding the dielectric substrate. The additional electrically conductive pigment can be, for example, steel flake, copper flake, silver particles, conductive carbon pigments, or a combination thereof.

The pigment composition comprises <NUM>% or lower by weight aluminum flake based on the total weight of the pigment composition, such as, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, <NUM>% or lower by weight aluminum flake, or <NUM>% or lower by weight aluminum flake, all based on the total weight of the pigment composition. The pigment composition comprises <NUM>% or greater by weight aluminum flake based on the total weight of the pigment composition, such as, <NUM>% or greater by weight aluminum flake, <NUM>% or greater by weight aluminum flake, <NUM>% or greater by weight aluminum flake, <NUM>% or greater by weight aluminum flake, <NUM>% or greater by weight aluminum flake, <NUM>% or greater by weight aluminum flake, or <NUM>% or greater by weight aluminum flake, all based on the total weight of the pigment composition. The pigment composition comprises <NUM>% to <NUM>% by weight aluminum flake based on the total weight of the pigment composition, such as, <NUM>% to <NUM>% by weight aluminum flake, <NUM>% to <NUM>% by weight aluminum flake, <NUM>% to <NUM>% by weight aluminum flake, <NUM>% to <NUM>% by weight aluminum flake, <NUM>% to <NUM>% by weight aluminum flake, or <NUM>% to <NUM>% by weight aluminum flake, all based on the total weight of the pigment composition. The aluminum flake can comprise Aluminum Paste 634A from Toyal Aluminum K. and/or TSB 2044A Aluminum Paste from Toyal America. Minimizing the aluminum flake in the pigment composition can enable higher radar transmission by the RT coating layer.

As used herein, "average particle size" refers to the z-average size measured using dynamic light scattering, which is the intensity-weighted harmonic mean particle diameter (e.g., D<NUM>). Average particle size for pigments except flakes according to the present disclosure as reported herein were measured according to ISO-<NUM>. Average particle size according to the present disclosure for a flake such as aluminum flake as reported herein were measured according to column <NUM> line <NUM> to column <NUM> line <NUM> of <CIT>. As used herein, "average particle size" when referring to a flake is used interchangeably with "mean particle size".

The pigment used in the pigment composition can comprise an average particle size of <NUM> or greater, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater. The pigment composition can comprise an average particle size of <NUM> or lower, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower. The pigment used in the pigment composition can comprise an average particle size in a range of <NUM> to <NUM>, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>.

As illustrated in the Figure, an RT coating system <NUM> comprising an RT coating layer <NUM> is provided. The RT coating layer <NUM> can be applied to a substrate <NUM> and the RT coating layer <NUM> can be suitable for the transmission of radio waves throughout the RT coating layer <NUM>. The substrate <NUM> can be a radar transmissive substrate (e.g., allow transmission of electromagnetic radiation in a wavelength range of <NUM> to <NUM> with minimal, if any, absorption, scattering, or reflection through the substrate) such as a non-metallic substrate. Non-metallic substrates may include polymeric, such as plastic, including polyester, polyolefin, polyamide, cellulosic, polystyrene, polyacrylic, poly(ethylene naphthalate), polypropylene, polyethylene, nylon, ethylene vinyl alcohol, polylactic acid, other "green" polymeric substrates, poly(ethyleneterephthalate), polycarbonate, polycarbonate acrylobutadiene styrene, or polyamide. The substrate <NUM> can comprise at least a portion of a vehicle component. A vehicle component as described herein means a portion of a machine capable of transporting people and/or cargo (e.g., an automobile, a truck, a bus, a motorcycle, a train, a watercraft, an aircraft, a spacecraft). For example, a vehicle component can comprise a bumper cover, a fender, a hood, a trunk, a door, or a mirror housing.

The substrate <NUM> can be at least partially coated with the RT coating layer <NUM>. For example, the RT coating layer <NUM> can be applied to <NUM>% or greater of an exterior surface area of the substrate <NUM>, such as, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, or <NUM>% or greater of an exterior surface area of the substrate <NUM>. The RT coating layer <NUM> can be applied to <NUM>% or lower of an exterior surface area of the substrate <NUM>, such as, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, or <NUM>% or lower of an exterior surface area of the substrate <NUM>. The RT coating layer <NUM> can be applied to <NUM>% to <NUM>% of an exterior surface area of the substrate <NUM>, such as, <NUM>% to <NUM>%, <NUM>% to <NUM>%, <NUM>% to <NUM>%, or <NUM>% to <NUM>% of an exterior surface area of the substrate <NUM>. For example, the RT coating layer <NUM> may be a decorative coating.

The dry film thickness of the RT coating layer <NUM> can be <NUM> or greater, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater. The dry film thickness of the RT coating layer <NUM> can be <NUM> or less, such as, <NUM> or less, <NUM> or less, <NUM> or less, <NUM> or less, <NUM> or less, <NUM> or less, or <NUM> or less. The dry film thickness of the RT coating layer <NUM> can be in a range of <NUM> to <NUM>, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>.

The RT coating layer <NUM> may be formed from a single layer or from a multilayer coating stack, such as a multilayer coating stack including at least two RT coating layers, a first RT coating layer and a second RT coating layer underneath at least a portion of the first RT coating layer. The RT coating system <NUM> can comprise additional layers, such as, a topcoat (e.g., clearcoat) <NUM>, a primer layer <NUM>, and combinations thereof. The RT coating layer <NUM> can be applied, for example, directly on the substrate <NUM>, over the primer layer <NUM>, or other underlying layer. The topcoat <NUM> can be applied directly onto the RT coating layer <NUM> or over another underlying layer (not shown).

The RT coating layer <NUM> can be applied from a RT coating composition that can be formulated as a solvent-based composition, a water-based composition, or a <NUM>% solid composition that does not comprise a volatile solvent or aqueous carrier. The RT coating composition can be a liquid at a temperature of -<NUM> or greater, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater. The RT coating composition can be a liquid at a temperature of <NUM> or lower, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower. The RT coating composition can be a liquid at a temperature in a range of -<NUM> to <NUM>, such as, -<NUM> to <NUM>, -<NUM> to <NUM>, -<NUM> to <NUM>, or <NUM> to <NUM>. The RT coating composition can be a liquid at room temperature.

Referring to the Figure, a radar system <NUM> may be positioned proximal to and/or adjacent to the RT coating system <NUM>. The radar system <NUM> can transmit radio waves 112a that can traverse through the RT coating layer <NUM> and, if present, the substrate <NUM>, the primer layer <NUM>, and/or the topcoat <NUM>. However, the RT coating system <NUM> can reduce a portion of the transmission of the radio waves 112a, and the remaining radio waves 112b can exit the RT coating system <NUM>. For example, the transmission of radio waves 112a through the RT coating system <NUM> can be reduced by reflection (e.g., as reflected radio waves 112c), absorption, and/or scattering. The remaining radio waves 112b can be used for the detection of an object (not shown). For example, the remaining radio waves 112b can reflect off of the object and return through the RT coating system <NUM> and be detected by the radar system <NUM>. Additionally, the thickness of the RT coating layer <NUM> can affect the reduction in the transmission of the radio waves 112a. For example, the thicker the RT coating layer <NUM>, the more reflection, absorption, and/or scattering that may occur as the radio waves 112a traverse through the thickness of the RT coating layer <NUM>. Similarly, the thinner the RT coating layer <NUM>, the less reflection, absorption, and/or scattering that may occur as the radio waves 112a traverse through the thickness of the RT coating layer <NUM>.

Radar signal transmission of the RT coating system <NUM> can be defined as the percent of the radio waves 112a that are transmitted through the RT coating system <NUM> and exit the RT coating system <NUM> as remaining radio waves 112b. As used herein, "radar signal transmission" is measured by measuring insertion loss according to standard test method CTG-TM-<NUM>-<NUM>, available at: https://compasstech. com/wp-content/uploads/<NUM><NUM>/<NUM>/CTG-Focused-Beam-Mesurement-System-Standard. pdf, and converting the insertion loss to radar signal transmission using Equation <NUM>. The insertion loss can be measured by passing radio waves through a thermoplastic polyolefin ("TPO") panel coated with the coating layer, and optionally, an adhesion promoter and a clearcoat. Radar signal transmission can be measured in a frequency range of <NUM> to <NUM>. The radar signal transmission can be measured at a frequency of <NUM> and/or <NUM>.

The RT coating layer <NUM> and/or RT coating system <NUM> can be configured to transmit an amount of electromagnetic radiation comprising a frequency of <NUM> to <NUM> through the RT coating layer <NUM> and/or RT coating system <NUM> of <NUM>% or greater, such as, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, or <NUM>% or greater, all as measured according to standard test method CTG-TM-<NUM>-<NUM>. The RT coating layer <NUM> and/or RT coating system <NUM> can be configured to transmit an amount of electromagnetic radiation comprising a frequency of <NUM> to <NUM> through the RT coating layer <NUM> and/or RT coating system <NUM> of <NUM>% or lower, such as, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, or <NUM>% or lower, all as measured according to standard test method CTG-TM-<NUM>-<NUM>. The RT coating layer <NUM> and/or RT coating system <NUM> can be configured to transmit an amount of electromagnetic radiation comprising a frequency of <NUM> to <NUM> through the RT coating layer <NUM> and/or RT coating system <NUM> in a range of <NUM>% to <NUM>%, such as, <NUM>% to <NUM>%, <NUM>% to <NUM>%, <NUM>% to <NUM>%, or <NUM>% to <NUM>%, all as measured according to standard test method CTG-TM-<NUM>-<NUM>. For example, configuring the RT coating layer <NUM> and/or RT coating system <NUM> to transmit a desired amount of electromagnetic radiation comprising a frequency of <NUM> to <NUM> can comprise reducing the amount of pigments in the RT coating layer <NUM> and/or RT coating system <NUM> which reflect, absorb, and/or scatter electromagnetic radiation comprising a frequency of <NUM> to <NUM>.

The area coverage of flake pigments in the RT coating layer <NUM> can affect the color of and the radar transmission of the RT coating system <NUM>. It may be desirable to optimize the area coverage of flake pigments in the RT coating layer <NUM>.

As used herein, the phrase "area coverage" is a two dimensional measure of an area occupied by a component in a coating layer where the coating layer is observed/measured from a position above and perpendicular to the plane of the surface of the coating layer, projecting the three-dimensional view of the coating layer into two dimensions (X, Y) and the area occupied by the component is compared to the total two dimensional area occupied by the coating layer.

As used herein, the term "flake pigment" means pigment that is flake shaped, where the ratio of the width of the pigment to the thickness of the pigment (termed aspect ratio) is at least <NUM>, such as, for example, at least <NUM>, at least <NUM>, at least <NUM>, at least <NUM>, at least <NUM>, or at least <NUM>,<NUM>. The aspect ratio of flake pigment can be less than <NUM>,<NUM>, such as, for example, less than <NUM>,<NUM>, less than <NUM>, less than <NUM>, less than <NUM>, less than <NUM>, or less than <NUM>. The aspect ratio of the flake pigment can be in the range of <NUM> to <NUM>,<NUM>, such as, for example, <NUM> to <NUM>, <NUM> to <NUM>,<NUM>, <NUM> to <NUM>, or <NUM> to <NUM>. Flake pigment can comprise a thickness of less than <NUM> microns as measured by scanning electron microscopy (SEM) or by transmission electron microscopy (TEM), such as, for example, less than <NUM> microns, less than <NUM> microns, or less than <NUM> microns all measured by SEM or by TEM. Flake pigment can comprise a thickness greater than <NUM> microns as measured by SEM or by TEM, such as, for example, greater than <NUM> microns, greater than <NUM> microns, or greater than <NUM> microns all measured by SEM or by TEM. Flake pigment can comprise a thickness in a range of <NUM> microns to <NUM> microns as measured by SEM or by TEM, such as, for example, <NUM> to <NUM> microns as measured by SEM or by TEM. Flake pigment can comprise a width of less than <NUM> microns as measured by optical microscopy, by SEM, or by TEM, such as, for example, less than <NUM> microns, less than <NUM> microns, less than <NUM> microns, less than <NUM> microns, or less than <NUM> microns all measured by optical microscopy, by SEM, or by TEM. Flake pigment can comprise a width of greater than <NUM> micron as measured by optical microscopy or by SEM or by TEM, such as, for example, greater than <NUM> microns, greater than <NUM> microns, greater than <NUM> microns, greater than <NUM> microns, greater than <NUM> microns, or greater than <NUM> microns all measured by optical microscopy, by SEM, or by TEM. Flake pigment can comprise a width in a range of <NUM> to <NUM> microns as measured by optical microscopy, by SEM, or by TEM, such as, for example, <NUM> to <NUM> microns or <NUM> to <NUM> microns all measured optical microscopy, by SEM, by TEM.

Flake pigments can comprise rounded edges, a smooth and flat surface, angular edges, and/or uneven surfaces. Flake pigments comprising flake-shaped particles with angular edges and/or uneven surface are known in the art as "cornflakes". Flake pigments comprising flake-shaped particles distinguished by more rounded edges, smoother, flatter surfaces are referred to as "silver dollar" flakes. Flake pigments can comprise a coating applied thereon, such as, for example, silica coated copper flakes. Electrically conductive pigments can be flake pigments. Radar transmissive pigments can be flake pigments. Flake pigments can be a mixture of both electrically conductive pigments and radar transmissive pigments.

The RT coating system <NUM> can comprise an area coverage of flake pigments in the RT coating layer <NUM> of <NUM>% or greater based on a total area coverage of the RT coating layer <NUM>, such as, for example, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, <NUM>% or greater, or <NUM>% or greater all based on the total area coverage of the RT coating layer <NUM>. The RT coating system <NUM> can comprise an area coverage of flake pigments in the RT coating layer <NUM> of <NUM>% or lower based on a total area coverage of the RT coating layer <NUM>, such as, for example, <NUM>% or lower <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, <NUM>% or lower, or <NUM>% or lower, all based on the total area coverage of the RT coating layer <NUM>. The RT coating system <NUM> can comprise an area coverage of flake pigments in the RT coating layer <NUM> in a range of <NUM>% to <NUM>% based on a total area coverage of the RT coating layer <NUM>, such as, for example, <NUM>% to <NUM>%, <NUM>% to <NUM>%, or <NUM>% to <NUM>%, all based on the total area coverage of the RT coating layer <NUM>.

The area coverage of flake pigments in the RT coating layer <NUM> as reported herein was determined using a Keyence VK-X260K/X250K confocal laser scanning microscope, using the transparent film mode with a 50x objective and an RT coating layer <NUM> thickness in a range of <NUM> to <NUM>. The RT coating layer <NUM> was <NUM> while measuring the area coverage of flake pigments in the RT coating layer <NUM> as reported herein. A height map is output from the confocal laser scanning microscope measurement and the height range threshold for the height map is adjusted until the flake pigments are isolated (e.g., areas where flake pigment is present are blue and all other areas where flake pigment is absent are black). The adjusted height map is loaded into ImageJ analysis software (image analysis software available at https://imagej. gov/ij/ from the National Institutes of Health Bethesda, Maryland) and binarized to create a black and white image where areas that flake pigment is present are one color (e.g., black or white) and all other areas where flake pigment is absent are the opposing color. The area coverage of flake pigments in the RT coating layer <NUM> as reported herein was calculated based on the area covered by the color representing flake pigments in the binarized image in the ImageJ analysis software based on the total coverage area of both colors.

Typical coating systems having a coating layer comprising a pigment composition consisting of aluminum flake can have a desirable aesthetic appearance but may undesirably reduce radio waves through the typical coating systems. The pigment composition in the RT coating layer <NUM> can affect the aesthetic appearance of the RT coating system <NUM> and/or the transmission of radio waves through the RT coating system <NUM>. Thus, it may be desirable to minimize the CIELAB color difference (ΔE) of the RT coating system <NUM> compared to a color-matched coating system while maintaining desirable transmission of radio waves through the RT coating system <NUM>. As used herein, the phrase "a color-matched coating system" is a reference coating system that includes a coating composition used for the coating layer that comprises a flake pigment composition consisting of aluminum flake. For example, the difference between the RT coating system <NUM> and the reference color-matched coating system may be the amount of aluminium flake present in the flake pigment composition of each respective system, if any.

The ΔE values reported herein were determined using a multi-angle spectrophotometer, specifically a BYKmac i, with D65 illumination and <NUM>° observer. The ΔE is the difference between two colors in the CIELAB color space based on the difference between collected values of L*, a*, and b*, according to Equation <NUM>.

The measurements of the ΔE as reported herein were determined from a coating system comprising a substrate, a primer layer, a coating layer, and a clear coat layer. When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE of <NUM> or less as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all as measured at <NUM>° using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE of <NUM> or greater as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE in a range of <NUM> to <NUM> as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM> as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE of <NUM> or less as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or less, <NUM> or less, <NUM> or less, or <NUM> or less, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE of <NUM> or greater as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> can comprise a ΔE in a range of <NUM> to <NUM> compared to a color-matched coating system, as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or lower as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or greater as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE in a range of <NUM> to <NUM> as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination, and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

When compared to a color-matched coating system, the RT coating layer <NUM> of the present disclosure can comprise a ΔE of <NUM> or lower as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or greater as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE in a range from <NUM> to <NUM> as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or lower as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or greater as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE in a range from <NUM> to <NUM> as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or lower based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE of <NUM> or greater based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer. When compared to a color-matched coating system, the RT coating system <NUM> of the present disclosure can comprise a ΔE in a range of <NUM> to <NUM> based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all based on an average of the measurements from <NUM>°, <NUM>°, <NUM>°, <NUM>°, and <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.

The primer layer <NUM> can be disposed adjacent to the RT coating layer <NUM>. The primer layer <NUM> can lower the ΔE of the RT coating system <NUM> compared to a color-matched coating system. For example, the primer layer <NUM> can be opaque and can obscure the color of the substrate <NUM> (e.g., the primer layer <NUM> can be hiding). The primer layer <NUM> may not contain an effect pigment, such as, a reflective pigment, a refractive pigment, a mirror pigment, or an iridescence pigment. The primer layer <NUM> can comprise a CIELAB L* value of <NUM> or lower, as measured with an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included, such as, <NUM> or lower, <NUM> or lower, <NUM> or lower, or <NUM> or lower, all as measured using an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included. The primer layer <NUM> can comprise a CIELAB L* value of <NUM> or greater, as measured with an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included, such as, <NUM> or greater, <NUM> or greater, <NUM> or greater, or <NUM> or greater, all as measured using an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included. The primer layer <NUM> can comprise a CIELAB L* value in a range of <NUM> to <NUM>, as measured with an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included, such as, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, <NUM> to <NUM>, or <NUM> to <NUM>, all as measured using an integrating sphere spectrophotometer, with D65 Illumination, <NUM>° observer, and specular component included. The measurements of the primer layer <NUM> as reported herein were determined with the primer layer applied over the substrate <NUM>.

The RT coating layer <NUM> can be applied from a RT coating composition comprising a film-forming resin and the pigment composition. The film-forming resin can include a resin that can form a self-supporting continuous film on the substrate <NUM> or other underlying layer upon removal of any diluents or carriers present with the film-forming resin or upon curing at ambient or elevated temperature. A film-forming resin can comprise any resin used in an automotive original equipment manufacturer coating composition, an automotive refinish coating composition, an industrial coating composition, an architectural coating composition, a coil coating composition, a packaging coating composition, a marine coating composition, an aerospace coating composition, and the like. Film forming resin refers to resins that are self-crosslinking, resins that are crosslinked by reaction with a crosslinker, mixtures thereof and the like. That is, "film-forming resin" can include both a resin and crosslinker therfor.

The film-forming resin can comprise a thermosetting film-forming resin, a thermoplastic film-forming resin, or a combination thereof. As used herein, the term "thermosetting" refers to resins that "set" irreversibly upon curing or crosslinking, where the polymer chains of the polymeric components are joined together by covalent bonds, which is often induced, for example, by heat or radiation. Curing or a crosslinking reaction can be carried out under ambient conditions or at elevated temperatures. Once cured or crosslinked, a thermosetting film-forming resin may not melt upon the application of heat and can be insoluble in conventional solvents. As used herein, the term "thermoplastic" refers to resins that include polymeric components that are not joined by covalent bonds and thereby can undergo liquid flow upon heating and are soluble in conventional solvents.

Thermosetting coating compositions may include a crosslinking agent that may be selected from, for example, aminoplasts, polyisocyanates (including blocked isocyanates), polyepoxides, beta-hydroxyalkylamides, polyacids, anhydrides, organometallic acid-functional materials, polyamines, polyamides, and mixtures of any of the foregoing.

A film-forming resin may have functional groups that are reactive with the crosslinking agent. The film-forming resin in the coatings described herein may be selected from any of a variety of polymers well known in the art. The film-forming resin may be selected from, for example, acrylic polymers, polyester polymers, polyurethane polymers, polyamide polymers, polyether polymers, polysiloxane polymers, copolymers thereof, and mixtures thereof. Generally, these polymers may be any polymers of these types made by any method known to those skilled in the art. The functional groups on the film-forming resin may be selected from any of a variety of reactive functional groups, including, for example, carboxylic acid groups, amine groups, epoxide groups, hydroxyl groups, thiol groups, carbamate groups, amide groups, urea groups, isocyanate groups (including blocked isocyanate groups), mercaptan groups, and combinations thereof.

A method for making an RT coating comprises combining a film-forming resin and a pigment composition to form an RT coating layer <NUM> comprising a flop index of <NUM> or greater. The flop index of <NUM> or greater can be achieved by formulating a pigment composition according to the present disclosure. The RT coating can comprise a radar transmission of greater than <NUM>% such as, greater than <NUM>%.

A method for applying a coating system to a substrate comprises applying a RT coating composition over at least a portion of a substrate <NUM> to form the RT coating layer <NUM>. The RT coating composition can be applied by spray coating, spin coating, dip coating, roll coating, flow coating, film coating, or a combination thereof. After applying the RT coating composition over the substrate <NUM>, the RT coating composition may be allowed to coalesce to form a substantially continuous film on the substrate <NUM> and the RT coating composition can be cured to form the RT coating layer <NUM>. The RT coating composition can be cured at a temperature of -<NUM> or greater, such as, <NUM> or greater. The RT coating composition can be cured at a temperature of <NUM> or lower, such as, <NUM> or lower. The RT coating composition can be cured at a temperature in a range of -<NUM> to <NUM>. The curing can comprise a thermal bake in an oven. Additional layers, such as, the topcoat <NUM>, the primer <NUM>, and combinations thereof, may be applied before or after the RT coating layer <NUM>. In various examples, the RT coating layer <NUM> may be manufactured as a preformed film and thereafter applied to the substrate. For example, the coating composition can be applied to a substrate, cured, and then removed from the substrate as a preformed film. A release agent may or may not be used to facilitate the release of the preformed film from the substrate.

The present disclosure will be more fully understood by reference to the following examples, which provide illustrative non-limiting aspects of the invention. It is understood that the invention described in this specification is not necessarily limited to the examples described in this section.

As used herein, the term "parts" refers to parts by weight unless indicated to the contrary.

A-C® <NUM> oxidized polyethylene was purchased from Honeywell. To prepare the polyethylene dispersion, a tank was charged with <NUM> pounds ("lbs. With mixing turned on, <NUM> lbs. of A-C® <NUM> oxidized polyethylene was added to the tank and a nitrogen sparge was applied. The material in the tank was heated to <NUM> degrees Fahrenheit ("°F") and held until dissolved. The material in the tank was then cooled to <NUM> °F and held for <NUM> minutes after which <NUM> lbs. of xylene was added. The material in the tank was then held at <NUM> °F for <NUM> minutes and the polyethylene dispersion was formed.

Claytone <NUM> was purchased from BYK Additives and Instruments. of polyethylene dispersion from Example <NUM> was premixed for <NUM> minutes under Cowles agitation with <NUM> lbs. of n-butyl acetate and <NUM> lbs. of acrylic grind vehicle in a vessel. The Acrylic Grind Vehicle consists of <NUM>% tertiary dodecyl mercaptan, <NUM>% glacial acrylic acid inhibited, <NUM>% <NUM>-hydroxyethyl acrylate, <NUM>% n-butyl methacrylate, <NUM>% methacrylic acid, <NUM>% <NUM>-ethylhexyl acrylate, <NUM>% methyl methacrylate, and <NUM>% styrene made at <NUM>% solids by weight in a <NUM>% isobutyl alcohol/<NUM>% exempt VM&P naphtha/<NUM>% n-butyl acetate solvent mixture. of Claytone <NUM> was added to the vessel and mixed at high speed for <NUM> minutes using a Cowles blade. The material was then milled on a horizontal mill using <NUM> media for two hours to create the anti-settling intermediate.

The components listed in Table <NUM> were added in order starting at the top of Table <NUM> while mixing at low speed in order to create a paint base. Conventional solvent-borne tints (e.g., carbon black, pigment blue <NUM>, white TiO<NUM>, pigment blue <NUM>:<NUM>, pigment violet <NUM>) were used in preparation of a paint base.

The paint base prepared in Example <NUM> was used to prepare silver color coatings ("CCs"), Silver CC <NUM>, Silver CC <NUM>, and Silver CC <NUM>, as shown in Table <NUM> with various levels of aluminum flake and mica. The components of the Silver CC <NUM>-<NUM> listed in Table <NUM> were combined and mixed thoroughly to create the silver CCs <NUM>-<NUM>. The compositions of the Silver CCs <NUM>-<NUM> are listed in Table <NUM> on a weight percentage basis.

Automotive TPO panels (Lyondell Hasell Hifax TPO, Standard Plaque Inc. ) comprising a width of <NUM> inches, a length of <NUM> inches, and a thickness of <NUM> inches were hand sprayed with CMPP3700 commercial adhesion promoter available from PPG Industries Inc. , Pittsburgh, PA, at <NUM> dry film thickness. The adhesion promoter coated TPO panels were dried overnight at ambient conditions. The CIELAB color of the TPO panels was measured before application of the adhesion promoter and after application of the adhesion promoter using specular-excluded data from an X-rite Color i7800 integrating sphere spectrophotometer with D65 illumination and a <NUM> ° observer. The results are listed in Table <NUM>.

The adhesion promoter coated TPO panels were then coated with the Silver CCs <NUM>-<NUM> prepared in Example <NUM> via a spray gun mounted on a Spraymation model No. <NUM>. The traverse speed on the Spraymation was set to <NUM>,<NUM> inches per minute, the spray gun was opened <NUM> clicks, and the Silver CCs <NUM>-<NUM> were applied in two coats that totaled <NUM> dry film thickness to their respective panels. The TPO panels coated with the Silver CCs <NUM>-<NUM> were flashed at ambient conditions for two minutes followed by a five-minute bake at <NUM>. TKU2000CS commercial clearcoat available from PPG Industries Inc. , Pittsburgh, PA, was then applied to the TPO panels coated with Silver CCs <NUM>-<NUM> in two coats totaling <NUM> dry film thickness at <NUM> inches per minute traverse speed with the spray gun open <NUM> clicks, followed by a <NUM>-minute ambient flash and then a <NUM>-minute bake at <NUM> on each panel to create silver panels <NUM>-<NUM>. Silver panel <NUM> is a TPO panel coated with adhesion promoter, Silver CC <NUM>, and clearcoat. Silver panel <NUM> is a TPO panel coated with adhesion promoter, Silver CC <NUM>, and clearcoat. Silver panel <NUM> is a TPO panel coated with adhesion promoter, Silver CC <NUM>, and clearcoat.

The silver panels <NUM>-<NUM> prepared in Example <NUM> were measured for CIELAB color at multiple angles using a BYK-mac i spectrophotometer. To determine the difference in color between the control, silver panels <NUM> and <NUM>, and the inventive panel, silver panel <NUM>, the L*, a*, and b* values of the silver panels <NUM>-<NUM> were measured using a BKY-mac i spectrophotometer with D65 illumination and a <NUM>° observer. The color data for each silver panel <NUM>-<NUM> is listed in Tables <NUM>-<NUM>. The flop index was calculated for silver panels <NUM>-<NUM> using Equation <NUM> and are listed in Table <NUM>. The color difference, ΔE, values were calculated for silver panels <NUM>-<NUM> using Equation <NUM> and are listed in Table <NUM>.

Insertion loss was measured using a focused beam method at Compass Technology Group (Alpharetta, Georgia) for silver panels <NUM>-<NUM> according to standard test method CTG-TM-<NUM>-<NUM>, available at: https://compasstech. com/wp-content/uploads/<NUM>/<NUM>/CTG-Focused-Beam-Mesurement-System-Standard. The insertion loss measurement occurred in a radar range of <NUM> to <NUM> (<NUM> points) using an IF bandwidth of <NUM>, no averaging factor, and a <NUM> ns time-domain gate. The insertion loss was measured on a Copper Mountain Technologies <NUM> network analyzer driving the E-Band modules using the power levels recommended by the manufacturer.

The insertion loss was measured by passing radio waves comprising a frequency of <NUM> through the TPO panel, the adhesion promoter, the silver coating layer, and the clearcoat. The insertion loss at <NUM> was reported in decibels ("dB") and converted to percent transmission using Equation <NUM>. The results of the insertion loss measurements are listed in Table <NUM>.

As shown in Table <NUM>, silver panel <NUM> has a <NUM>% improvement in radar signal transmission compared to silver panel <NUM> as measured at <NUM> according to CTG-TM-<NUM>-<NUM>. Silver panel <NUM> has a <NUM>% improvement in radar signal transmission compared to silver panel <NUM> as measured at <NUM> according to CTG-TM-<NUM>-<NUM>.

While the examples show the use of a pigment composition comprising <NUM>% by weight aluminum flake and <NUM> % by weight mica and a pigment composition comprising <NUM> % by mica, it will be understood that RT coating layer can comprise a suitable ΔE and radar signal transmission throughout the ranges of aluminum flake and mica described herein.

The silver panels <NUM>-<NUM> prepared in Example <NUM> were measured for area coverage of the flake pigments (e.g., mica and aluminium flake) in the silver CC <NUM>-<NUM> cured thereon. The area coverage of flake pigments of the silver CC <NUM>-<NUM> cured on silver panels <NUM>-<NUM> was determined using a Keyence VK-X260K/X250K confocal laser scanning microscope, using the transparent film mode with a 50x objective. The height map output from the microscope was adjusted to isolate the flake pigment and binarized with ImageJ software to calculate area coverage of the flake pigments of the silver CC <NUM>-<NUM> cured on silver panels <NUM>-<NUM>. The results are listed in Table <NUM>.

As shown in Table <NUM>, the area coverage of flake pigments in the silver CC <NUM>-<NUM> cured on silver panels <NUM>-<NUM> was sufficient to provide a desired color of the respective panel.

The components listed in Table <NUM> were added in order starting at the top of Table <NUM> to create silver color coating <NUM> ("silver CC <NUM>") similar to <CIT> Components <NUM>-<NUM> were added while mixing with a disperser (e.g., Cowles) blade until homogenous then the remaining components were added while mixing with a propeller mixing blade. Additionally, a control coating ("silver CC <NUM>") was made the same as silver CC <NUM> except the mica pigment was replaced with the same volume of Aluminium Flake. The components listed in Table <NUM> were added in order starting at the top of Table <NUM> while mixing, in the same manner as those from Table <NUM>, in order to create silver CC <NUM>.

Thereafter, TPO panels (Lyondell Basell HiFax TRC779X, <NUM> inches x <NUM> inches x <NUM>-inch, available from Standard Plaque, Inc. ) were cleaned with SXA-<NUM> and coated with SU-<NUM> adhesion promoter, both from PPG Industries. The CIELAB color of the TPO panels after application of the adhesion promoter were measured using specular-excluded data from an X-rite Color i7800 integrating sphere spectrophotometer with D65 illumination and a <NUM> ° observer. The results are listed in Table <NUM>.

Some adhesion promoter coated TPO panels were then sprayed with silver CC4 of Table <NUM> ("silver panel <NUM>") and other adhesion promoter coated TPO panels were sprayed with silver CC5 of Table <NUM> ("silver panel <NUM>"). Both silver CC4 and silver CC5 were sprayed after thinning with DT870 (available from PPG industries) at a <NUM>:<NUM> volume ratio of silver CC4 or silver CC5 to DT870. Additionally, silver panels <NUM> and <NUM> were coated with a top coat of DC4000 (available from PPG Industries) using DCH3085 hardener at a <NUM>:<NUM> volume ratio of DC4000:DCH3085.

To determine the difference in color between the control, silver panel <NUM>, and the silver panel <NUM>, the L*, a*, and b* values of the silver panels <NUM>-<NUM> were measured using a BKY-mac i spectrophotometer with D65 illumination and a <NUM>° observer. The color data for each silver panel <NUM>-<NUM> is listed in Tables <NUM>-<NUM>. The flop index was calculated for silver panels <NUM>-<NUM> using Equation <NUM> and are listed in Table <NUM>. The color difference, ΔE, values were calculated for silver panels <NUM>-<NUM> using Equation <NUM> and are listed in Table <NUM>.

Claim 1:
A coating composition comprising:
a film-forming resin; and
<NUM>% to <NUM>% of a flake pigment composition based on the total weight of the coating composition, the flake pigment composition comprising:
<NUM>% or greater by weight of a radar transmissive pigment based on the total weight of the pigment composition, wherein the radar transmissive pigment comprises mica pigment, oxide coated mica pigment, glass flake, oxide coated glass flake, visible light diffractive pigment, visible light reflective organic pigment, metal oxide platelets, or a combination thereof; and
no greater than <NUM>% by weight electrically conductive pigment based on the total weight of the pigment composition;
wherein the pigment composition comprises <NUM>% to <NUM>% by weight aluminum flake based on the total weight of the pigment composition;
wherein when the coating composition is applied over a thermoplastic polyolefin substrate and cured at a dry film thickness of <NUM> to form a coating system, the coating system:
transmits <NUM>% or greater of electromagnetic radiation comprising a frequency of <NUM> to <NUM> through the coating system; and
has a flop index of <NUM> or greater, wherein the flop index = <NUM> (L<NUM>-L<NUM>)<NUM> / (L<NUM>)<NUM>, and wherein
L<NUM> is a CIELAB L* value as measured at <NUM>°, using a multi-angle
spectrophotometer with D65 Illumination and <NUM>° observer,
L<NUM> is a CIELAB L* value as measured at <NUM>°, using a multi-angle
spectrophotometer with D65 Illumination and <NUM>° observer, and
L<NUM> is a CIELAB L* value as measured at <NUM>°, using a multi-angle
spectrophotometer with D65 Illumination and <NUM>° observer, and
has a CIELAB ΔE of <NUM> or less as compared to a color-matched coating system as measured at <NUM>°, using a multi-angle spectrophotometer with D65 Illumination and <NUM>° observer.