Patent Description:
In recent years, devices such as memory circuits, logic circuits, and image sensors (for example, CMOS sensors) have become highly integrated. In the process of forming these devices, foreign matter, such as fine particles and dust, may be attached to the devices. Foreign matter attached to the devices may cause a short circuit between interconnects and may cause circuit malfunction. Therefore, in order to improve the reliability of the devices, it is necessary to clean a wafer on which the devices are formed to remove the foreign matter from the wafer. Foreign matter, such as fine particles and dust as described above, may also be attached to a back surface (non-device surface) of the wafer. When such foreign matter is attached to the back surface of the wafer, the wafer is separated from a stage reference plane of an exposure apparatus, or the wafer surface is inclined with respect to the stage reference plane, resulting in patterning shift or focal-length shift.

In view of this, there is a method of emitting a two-fluid jet composed of a fluid mixture of liquid and gas to a surface (front side or back side) of a wafer to clean the surface of the wafer. When this two-fluid jet cleaning is performed, a periphery of the wafer is held by claws of chucks, and the two-fluid jet is emitted from a nozzle onto the surface of the wafer while the chucks are rotated together with the wafer about a central axis of the wafer. Further, the nozzle oscillates (or scans) in a radial direction of the wafer, so that the two-fluid jet can be supplied over the entire surface of the rotating wafer.

However, when the nozzle is located above the periphery of the wafer, the two-fluid jet collides with the chuck claws and as a result, a large amount of liquid may be scattered. Therefore, in order to prevent such scattering of the liquid, a cleaning device of a type configured to hold a periphery of a wafer with a plurality of rollers instead of the chuck and rotate these rollers to thereby rotate the wafer has been proposed. According to this type of cleaning device, positions of the rollers themselves are fixed, so that the two-fluid jet does not collide with the rollers even when the nozzle is located above the periphery of the wafer.

Reference is made to <CIT>. Reference is also made to <CIT> related to a substrate treatment apparatus and method. The apparatus comprises a liquid droplet nozzle for emitting liquid and gas towards the substrate, wherein the gas is used to break up the liquid into droplets, as well as a protective liquid nozzle, which is directed towards the substrate and the liquid droplet nozzle such that in operation a protective film is formed beneath the liquid droplet nozzle. This protective film inhibits the liquid droplets from directly hitting the substrate to avoid damage to the substrate.

However, compared to the chuck type, the roller-type cleaning device cannot rotate the wafer at a high speed (usually, a maximum of <NUM>-<NUM>). Therefore, in order to clean the entire surface of the wafer, it is inevitably necessary to lower the moving speed of the nozzle. As a result, a time required for the nozzle to make one reciprocation (one scan) increases, and a portion of the wafer that is not in contact with the liquid becomes semidry. Further, since the rotation speed of the wafer is low, a strong centrifugal force does not act on the liquid on the wafer, and the particles lifted by the two-fluid jet may remain on the wafer.

Therefore, the present invention provides a substrate cleaning method and a substrate cleaning apparatus capable of preventing a substrate, such as a wafer, from becoming semidry and reliably removing particles lifted by a two-fluid jet from a surface of the substrate.

In accordance with the invention, a substrate cleaning method and a substrate cleaning apparatus as set forth in the appended claims are provided. In one embodiment, there is provided a substrate cleaning method comprising: holding a periphery of a substrate with holding rollers; rotating the substrate about its central axis by rotating the holding rollers about their respective central axes; delivering a two-fluid jet from a two-fluid jet nozzle to a surface of the substrate while moving the two-fluid jet nozzle in a radial direction of the substrate, the two-fluid jet being composed of a mixture of a first liquid and a gas; and when the two-fluid jet is being delivered to the surface of the substrate, delivering a fan-shaped jet of a second liquid from a spray nozzle to the surface of the substrate to form a flow of the second liquid on the surface of the substrate, the fan-shaped jet being located away from the two-fluid jet, wherein the fan spray nozzle is oriented in the direction such that both the fan-shaped jet emitted from the fan spray nozzle and a flow of the second liquid formed on the surface of the wafer do not collide with the two-fluid jet emitted from the two-fluid jet nozzle.

In one embodiment, an angle of the spray nozzle with respect to the surface of the substrate is in a range of <NUM>° to <NUM>°.

In one embodiment, a width of the fan-shaped jet is at least three-quarters of a radius of the substrate.

In one embodiment, a direction of the fan-shaped jet is oriented toward an outside of the substrate.

In one embodiment, the spray nozzle is located above the substrate.

In one embodiment, delivering the fan-shaped jet comprises delivering the fan-shaped jet from the spray nozzle to the surface of the substrate to form the flow of the second liquid on the surface of the substrate while moving the spray nozzle.

In one embodiment, the two-fluid jet nozzle and the spray nozzle are fixed to a common arm.

In one embodiment, there is provided a substrate cleaning apparatus comprising: holding rollers having substrate holding surfaces configured to hold a periphery of a substrate, the holding rollers being rotatable about their own central axes; a two-fluid jet nozzle configured to form a two-fluid jet composed of a mixture of a first liquid and a gas; a fan spray nozzle configured to form a fan-shaped jet of a second liquid; and a nozzle moving device configured to translate the two-fluid jet nozzle, the two-fluid jet nozzle and the fan spray nozzle being oriented toward a region surrounded by the substrate holding surfaces, and the fan spray nozzle being oriented in a direction in which the fan-shaped jet does not collide with the two-fluid jet.

In one embodiment, an angle of the fan spray nozzle with respect to a plane extending through the substrate holding surfaces is in a range of <NUM>° to <NUM>°.

In one embodiment, the fan spray nozzle is configured to form the fan-shaped jet having a width of at least three-quarters of a radius of the substrate.

In one embodiment, the nozzle moving device includes an arm holding the two-fluid jet nozzle and the fan spray nozzle.

According to the present invention, the fan-shaped jet forms a uniform flow of the second liquid over a large area of the surface of the substrate. This flow of the second liquid can flush out the particles that have been once lifted by the two-fluid jet, and can prevent the substrate from becoming semidry.

<FIG> is a perspective view showing an embodiment of a substrate cleaning apparatus, and <FIG> is a top view of the substrate cleaning apparatus shown in <FIG>. The substrate cleaning apparatus according to the present embodiment is an apparatus for cleaning a surface (or an upper surface) of a wafer W which is an example of a substrate. Hereinafter, the substrate cleaning apparatus will be described in detail.

The substrate cleaning apparatus includes a wafer holder (or a substrate holder) <NUM> configured to hold the wafer W and rotate the wafer W about a central axis of the wafer W in a direction indicated by arrow A, a two-fluid jet nozzle <NUM> configured to deliver a two-fluid jet to the surface (upper surface) of the wafer W held by the wafer holder <NUM>, and a fan spray nozzle <NUM> configured to deliver a fan-shaped jet to the surface (upper surface) of the wafer W held by the wafer holder <NUM>.

The wafer holder (substrate holder) <NUM> includes a plurality of holding rollers <NUM> configured to hold a periphery of the wafer W, and roller motors <NUM> configured to rotate these holding rollers <NUM>. These holding rollers <NUM> are arranged around a predetermined reference axis O. In this embodiment, four holding rollers <NUM> are provided. The holding rollers <NUM> when holding the wafer W are located at the same distance from the reference axis O. Therefore, the center of the wafer W when held by the holding rollers <NUM> coincides with the reference axis O. In one embodiment, only three holding rollers <NUM> may be provided, or five or more holding rollers <NUM> may be provided. The wafer W to be cleaned is placed on the holding rollers <NUM> by a transfer device (not shown), and is rotated by the holding rollers <NUM> in the direction indicated by the arrow A in <FIG>.

<FIG> is an enlarged side view of the holding roller <NUM>. Each holding roller <NUM> has a cylindrical substrate holding surface (wafer holding surface) 6a and a tapered portion 6b inclined downward along a radially outward direction. The tapered portion 6b is connected to a lower end of the substrate holding surface 6a and extends radially outwardly from the substrate holding surface 6a. The tapered portion 6b is circular and concentric with the substrate holding surface 6a. The center of the tapered portion 6b and the center of the substrate holding surface 6a are on a central axis CP of the holding roller <NUM>. The holding roller <NUM> is configured to be rotatable about its central axis CP.

<FIG> is a diagram showing a state in which the wafer W is placed on the holding roller <NUM> but is not held by the holding roller <NUM>. As shown in <FIG>, the periphery of the wafer W is placed on the tapered portion 6b of the holding roller <NUM> by the transfer device (not shown). Thereafter, as shown in <FIG>, the entire holding roller <NUM> moves in a direction indicated by arrow, until the substrate holding surface 6a of the holding roller <NUM> comes into contact with the periphery of the wafer W, whereby the periphery of the wafer W is held by the substrate holding surface 6a. When the holding roller <NUM> rotates about the central axis CP with the periphery of the wafer W being in contact with the substrate holding surface 6a, the wafer W rotates. Each holding roller <NUM> rotates about each central axis CP, while the position of each holding roller <NUM> itself is fixed.

Referring back to <FIG>, two of the four holding rollers <NUM> are coupled to each other by a torque transmission mechanism <NUM>, and the other two holding rollers <NUM> are also coupled to each other by another torque transmission mechanism <NUM>. Each torque transmission mechanism <NUM> is composed of, for example, a combination of pulleys and a belt. In this embodiment, two roller motors <NUM> are provided. One of the two roller motors <NUM> is coupled to the two holding rollers <NUM> which are coupled to each other by the torque transmission mechanism <NUM>, and the other roller motor <NUM> is coupled to the other two holding rollers <NUM> which are coupled to each other by the other torque transmission mechanism <NUM>.

In one embodiment, one roller motor may be coupled to all the holding rollers <NUM> via a torque transmission mechanism. In the present embodiment, all the holding rollers <NUM> are coupled to the roller motors <NUM>, while some of the plurality of holding rollers <NUM> may be coupled to the roller motor(s) <NUM>. It is preferable that at least two of the plurality of holding rollers <NUM> are coupled to the roller motor(s) <NUM>.

In the present embodiment, two of the four holding rollers <NUM> can be moved toward and away from the other two holding rollers <NUM> by a moving mechanism (not shown). After the wafer W is placed on the tapered portions 6b of the four holding rollers <NUM> by the transfer device (not shown), the two holding rollers <NUM> move toward the other two holding rollers <NUM>, until the substrate holding surfaces 6a of the four holding rollers <NUM> hold the periphery of the wafer W.

After cleaning of the wafer W, the two holding rollers <NUM> move away from the other two holding rollers <NUM>, so that the substrate holding surfaces 6a of the four holding rollers <NUM> release the periphery of the wafer W, until the periphery of the wafer W is located on the tapered portions 6b of the four holding rollers <NUM>. The wafer W is removed from the holding rollers <NUM> by the transfer device (not shown). In one embodiment, all the holding rollers <NUM> may be configured to be movable by a moving mechanism(s) (not shown).

The two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> are configured to form a two-fluid jet and a fan-shaped jet, respectively, for cleaning the surface (upper surface) of the wafer W held by the holding rollers <NUM>. As shown in <FIG>, the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> are arranged so as to be oriented toward a region surrounded by the substrate holding surfaces 6a of the holding rollers <NUM>. This region surrounded by the substrate holding surfaces 6a is a region where the wafer W is held by the holding rollers <NUM>. Therefore, the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> are arranged so as to be oriented toward the surface (upper surface) of the wafer W held by the substrate holding surfaces 6a of the holding rollers <NUM>.

The substrate cleaning apparatus further includes a nozzle moving device <NUM> configured to translate the two-fluid jet nozzle <NUM>. The nozzle moving device <NUM> includes an arm <NUM> holding the two-fluid jet nozzle <NUM>, a support shaft <NUM> supporting the arm <NUM>, and a pivoting motor <NUM> coupled to the support shaft <NUM>. The two-fluid jet nozzle <NUM>, the fan spray nozzle <NUM>, and the arm <NUM> are located higher than the holding rollers <NUM>. The two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> are located above the wafer W held by the holding rollers <NUM>.

The two-fluid jet nozzle <NUM> is fixed to a distal end of the arm <NUM>, and the support shaft <NUM> is fixed to the other end of the arm <NUM>. The two-fluid jet nozzle <NUM> extends vertically and downwardly from the distal end of the arm <NUM>. The pivoting motor <NUM> is configured to be able to rotate the support shaft <NUM> clockwise and counterclockwise by a predetermined angle. When the pivoting motor <NUM> rotates the support shaft <NUM>, the arm <NUM> and the two-fluid jet nozzle <NUM> rotate or pivot clockwise and counterclockwise around a pivot axis P of the support shaft <NUM> by a predetermined angle.

As shown in <FIG>, as the arm <NUM> pivots, the two-fluid jet nozzle <NUM> moves in an arc-shaped path extending through the center of the wafer W (corresponding to the reference axis O) held by the holding rollers <NUM>. More specifically, during cleaning of the wafer W, the two-fluid jet nozzle <NUM> oscillates (or reciprocates) between the center of the wafer W and the periphery of the wafer W. The moving direction of the two-fluid jet nozzle <NUM> is substantially the radial direction of the wafer W.

The two-fluid jet nozzle <NUM> is perpendicular to the surface (upper surface) of the wafer W when the wafer W is held by the holding rollers <NUM>. In the present embodiment, the central axes of the holding rollers <NUM> and the two-fluid jet nozzle <NUM> extend in the vertical direction, and the wafer W is held horizontally by the holding rollers <NUM>. In one embodiment, the central axes of the holding rollers <NUM> may be inclined with respect to the vertical direction, and the wafer W may be held by the holding rollers <NUM> in an inclined state.

The two-fluid jet nozzle <NUM> is coupled to a gas supply line <NUM> that supplies a gas, such as air or an inert gas (for example, nitrogen gas), and a liquid supply line <NUM> that supplies a first liquid, such as pure water or carbonated water. The gas supply line <NUM> is coupled to a gas supply source (not shown), and the liquid supply line <NUM> is coupled to a liquid supply source (not shown). The two-fluid jet nozzle <NUM> is configured to form a two-fluid jet composed of a mixture of the first liquid and the gas. The two-fluid jet is emitted from the two-fluid jet nozzle <NUM> perpendicularly to the surface (upper surface) of the wafer W.

As shown in <FIG>, as the two-fluid jet nozzle <NUM> oscillates, the two-fluid jet is delivered to a first region R1 of the surface of the wafer W. This first region R1 is an elongated region or a strip-shaped region extending in the radial direction of the wafer W. The first region R1 includes the center of the wafer W. The two-fluid jet can collide perpendicularly with the surface of the wafer W and can remove particles from the surface of the wafer W. During cleaning of the wafer W, each holding roller <NUM> rotates about each central axis CP (see <FIG>), but the position of each holding roller <NUM> itself is fixed. Therefore, the two-fluid jet does not collide with the holding rollers <NUM>, and the liquid constituting the two-fluid jet is not scattered.

The fan spray nozzle <NUM> is fixed to a holding member, such as a bracket (not shown). Therefore, unlike the two-fluid jet nozzle <NUM>, the position of the fan spray nozzle <NUM> is fixed during cleaning of the wafer W. The fan spray nozzle <NUM> is coupled to a liquid supply line <NUM> that supplies a second liquid, such as pure water, an alkaline liquid, or a liquid containing a surfactant. The fan spray nozzle <NUM> is configured to form a fan-shaped jet of the second liquid that has been supplied through the liquid supply line <NUM>.

The fan spray nozzle <NUM> is located outwardly of the path of the two-fluid jet nozzle <NUM>, and is arranged such that the two-fluid jet nozzle <NUM>, which moves together with the arm <NUM>, does not collide with the fan spray nozzle <NUM>. The emission of the fan-shaped jet begins at the same time as or after the emission of the two-fluid jet begins. The emission of the fan-shaped jet is stopped at the same time as or after the emission of the two-fluid jet is stopped.

The fan spray nozzle <NUM> is arranged so as to be oriented diagonally downward. As shown in <FIG>, the fan-shaped jet is a wide jet that spreads in lateral direction, and has a substantially constant flow-velocity distribution from one end to other end of the fan-shaped jet. In the present embodiment, a width direction of the fan-shaped jet is along the radial direction of the wafer W. An outer end of the fan-shaped jet is located outwardly of the wafer W. A width of the fan-shaped jet is at least three-quarters of a radius of the wafer W. In one embodiment, the width of the fan-shaped jet is greater than the radius of the wafer W.

The fan-shaped jet is obliquely incident on the surface of the wafer W and forms a flow of the second liquid on the surface (upper surface) of the wafer W. This flow of the second liquid is formed on a second region R2 including the periphery of the wafer W. The second region R2 is located away from the above-mentioned first region R1. It is advantageous that the fan spray nozzle <NUM> allows the second liquid to contact a wider area of the wafer W and can form the flow of the second liquid having a uniform flow rate on the wafer W, as compared with a conical spray nozzle that sprays a conical liquid jet.

As shown in <FIG>, the fan spray nozzle <NUM> is oriented in a direction along the rotating direction of the wafer W indicated by the arrow A as viewed from above, and is arranged to so as to form the fan-shaped jet toward the outside of the wafer W. The fan spray nozzle <NUM> is oriented in the direction in which the fan-shaped jet does not collide with the two-fluid jet. Specifically, the fan-shaped jet emitted from the fan spray nozzle <NUM> is formed at a position away from the two-fluid jet emitted from the two-fluid jet nozzle <NUM>. Since the fan spray nozzle <NUM> is arranged at such position, the two-fluid jet can collide with the surface of the wafer W without being hindered by the fan-shaped jet, and can therefore remove particles from the surface of the wafer W.

The fan spray nozzle <NUM> is oriented in the direction such that both the fan-shaped jet emitted from the fan spray nozzle <NUM> and the flow of the second liquid formed on the surface (upper surface) of the wafer W do not collide with the two-fluid jet emitted from the two-fluid jet nozzle <NUM>. The two-fluid jet can collide with the surface of the wafer W and can remove particles from the surface of the wafer W without being hindered by the fan-shaped jet and the flow of the second liquid on the wafer W.

<FIG> is a side view showing the fan spray nozzle <NUM> as viewed from a direction parallel to the upper surface of the wafer W. The fan spray nozzle <NUM> is inclined with respect to the surface (upper surface) of the wafer W. If an angle of the fan spray nozzle <NUM> is too large, an action of the fan-shaped jet stemming the particles becomes dominant over an action of the fan-shaped jet washing away the particles, and the particles cannot be efficiently discharged from the wafer W. From this point of view, in one embodiment, an angle α of the fan spray nozzle <NUM> with respect to the surface (upper surface) of the wafer W is in a range of <NUM>° to <NUM>°. In one embodiment, the angle α of the fan spray nozzle <NUM> is <NUM>°. The wafer W is held by the substrate holding surfaces 6a of the four holding rollers <NUM> (only the two holding rollers <NUM> are shown in <FIG>), and the surface (upper surface) of the wafer W is parallel to a plane S (which is an imaginary plane) extending through these substrate holding surfaces 6a. Therefore, the angle α of the fan spray nozzle <NUM> with respect to the plane (imaginary surface) S extending through the substrate holding surfaces 6a is in the range of <NUM>° to <NUM>°.

The fan-shaped jet emitted from the fan spray nozzle <NUM> inclined in this way is also incident on the surface (upper surface) of the wafer W at substantially the same angle as the fan spray nozzle <NUM>. The fan-shaped jet forms the flow of the second liquid on the wide second region R2 of the surface of the wafer W. The flow of the second liquid travels toward the outside of the wafer W, can wash out the particles lifted by the two-fluid jet, and can prevent the semidry of the wafer W.

As shown in <FIG>, the substrate cleaning apparatus further includes a rinsing nozzle <NUM> that supplies a rinsing liquid to the surface (upper surface) of the wafer W held by the holding rollers <NUM>. The rinsing nozzle <NUM> is arranged so as to be oriented toward the center of the surface of the wafer W, i.e., the reference axis O. The rinsing nozzle <NUM> is coupled to a rinsing-liquid supply line <NUM> that supplies the rinsing liquid, such as pure water. After cleaning of the wafer W with the two-fluid jet and cleaning of the wafer W with the fan-shaped jet are terminated, the rinsing liquid is supplied from the rinsing nozzle <NUM> to the rotating wafer W to rinse the entire surface of the wafer W.

Next, an embodiment of the cleaning operation for the wafer W will be described with reference to a flowchart shown in <FIG>.

In step <NUM>, the periphery of the wafer W is held by the holding rollers <NUM>. As shown in <FIG>, the periphery of the wafer W is held by each substrate holding surface 6a of each holding roller <NUM>.

In step <NUM>, the roller motors <NUM> shown in <FIG> are set in motion to rotate the holding rollers <NUM> about the respective central axes CP. The wafer W is rotated about the central axis of the wafer W by the rotating holding rollers <NUM>.

In step <NUM>, while the two-fluid jet nozzle <NUM> is moving in the radial direction of the wafer W, the two-fluid jet composed of a mixture of the first liquid and the gas is delivered from the two-fluid jet nozzle <NUM> to the first region R1 of the surface (upper surface) of the wafer W. The two-fluid jet nozzle <NUM> reciprocates between the center of the rotating wafer W and the periphery of the wafer W by a predetermined number of times.

In step <NUM>, when the two-fluid jet is delivered to the first region R1, the fan-shaped jet composed of the second liquid is delivered from the fan spray nozzle <NUM> to the surface of the wafer W, so that the flow of the second liquid is formed on the second region R2 of the surface of the wafer W. The emission of the fan-shaped jet begins at the same time as or after the emission of the two-fluid jet begins. Therefore, the steps <NUM> and <NUM> are performed substantially simultaneously.

In step <NUM>, the emission of the two-fluid jet is stopped, and at the same time or thereafter, the emission of the fan-shaped jet is stopped.

In step <NUM>, the rinsing liquid is supplied from the rinsing nozzle <NUM> to the surface (upper surface) of the wafer W while the rotation of the wafer W is maintained, whereby the surface of the wafer W is rinsed with the rinsing liquid.

In step <NUM>, the roller motors <NUM> are stopped, whereby the rotation of the wafer W is stopped.

Next, another embodiment of the substrate cleaning apparatus will be described with reference to <FIG>. Configurations and operations of the present embodiment, which will not be particularly described, are the same as those of the above-described embodiments, and therefore duplicated descriptions thereof will be omitted. <FIG> is a side view showing another embodiment of the substrate cleaning apparatus, and <FIG> is a view of two-fluid jet nozzle <NUM> and fan spray nozzle <NUM> shown in <FIG> as viewed from axial direction of arm <NUM>. <FIG> is a top view of the substrate cleaning apparatus shown in <FIG>. Although some components are note depicted in <FIG>, the configurations of the present embodiment are the same as those of the above-described embodiments unless otherwise described.

In the present embodiment, the nozzle moving device <NUM> is configured to translate the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> together. Both the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> are held by the arm <NUM>. The fan spray nozzle <NUM> is attached to a bracket <NUM> fixed to the arm <NUM>. In one embodiment, the fan spray nozzle <NUM> may be fixed directly to the arm <NUM>. Since the fan spray nozzle <NUM> is coupled to the arm <NUM> in this way, the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> move together with the pivoting motion of the arm <NUM>. The fan spray nozzle <NUM> is located between the two-fluid jet nozzle <NUM> and the support shaft <NUM>. Therefore, the fan spray nozzle <NUM> moves in a path different from that of the two-fluid jet nozzle <NUM>.

As the arm <NUM> pivots, the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> deliver the two-fluid jet and the fan-shaped jet to the surface (upper surface) of the wafer W. The fan spray nozzle <NUM> is oriented in a direction perpendicular to the extending direction of the arm <NUM> as viewed from above. Therefore, the fan spray nozzle <NUM> emits the fan-shaped jet in the moving direction of the fan spray nozzle <NUM> as viewed from above. The fan spray nozzle <NUM> is arranged away from the two-fluid jet nozzle <NUM> at a distance such that the fan-shaped jet does not collide with the two-fluid jet. Specifically, the fan spray nozzle <NUM> emits the fan-shaped jet in a direction away from the two-fluid jet nozzle <NUM> and the two-fluid jet, so that the fan-shaped jet does not collide with the two-fluid jet. The inclination angle of the fan spray nozzle <NUM> is the same as the angle described with reference to <FIG>.

In the present embodiment, the fan spray nozzle <NUM> can deliver the fan-shaped jet of the second liquid to the surface (upper surface) of the wafer W while the fan spray nozzle <NUM> is moving. Therefore, the flow of the second liquid can be formed over a wide area on the surface (upper surface) of the wafer W. The flow of the second liquid can wash out the particles lifted by the two-fluid jet and can prevent the semidry of the wafer W.

In step <NUM>, the arm <NUM> pivots around the support shaft <NUM> to move the two-fluid jet nozzle <NUM> and the fan spray nozzle <NUM> together, while the fluid jet nozzle <NUM> delivers the two-fluid jet composed of a mixture of the first liquid and the gas to the surface (upper surface) of the wafer W, and the fan spray nozzle <NUM> delivers the fan-shaped jet of the second liquid to the surface (upper surface) of the wafer W. The moving direction of the two-fluid jet nozzle <NUM> is the radial direction of the wafer W. The emission of the fan-shaped jet begins at the same time as or after the emission of the two-fluid jet begins. The two-fluid jet nozzle <NUM> reciprocates between the center of the rotating wafer W and the periphery of the wafer W by a predetermined number of times.

Claim 1:
A substrate cleaning method comprising:
rotating the substrate (W) about its central axis;
delivering a two-fluid jet from a two-fluid jet nozzle (<NUM>) to a surface of the substrate (W) while moving the two-fluid jet nozzle (<NUM>) in a radial direction of the substrate (W), the two-fluid jet being composed of a mixture of a first liquid and a gas; and
when the two-fluid jet is being delivered to the surface of the substrate (W), delivering a fan-shaped jet of a second liquid from a fan spray nozzle (<NUM>) to the surface of the substrate to form a flow of the second liquid on the surface of the substrate (W), the fan-shaped jet being located away from the two-fluid jet, characterized in that the fan spray nozzle (<NUM>) is oriented in the direction such that both the fan-shaped jet emitted from the fan spray nozzle (<NUM>) and a flow of the second liquid formed on the surface of the wafer (W) do not collide with the two-fluid jet emitted from the two-fluid jet nozzle (<NUM>).