Patent Description:
Only a small portion of the electomagnetic spectrum is of concern to the human eye. This portion of the spectrum lies in a range of wavelengths from about <NUM> to about <NUM>, and can be divided into several discrete groupings -- ultraviolet (UV) light, high energy visible (HEV) light, and low energy visible light. UV light ranges in wavelength from about <NUM> to about <NUM>, and is subdivided into <NUM> regions -- UVC (<NUM> to <NUM>), UVB (<NUM> to <NUM>), and UVA (<NUM> to <NUM>). HEV light ranges in wavelength from about <NUM> to about <NUM>, and generally corresponds to the blue (or blue-violet) region of the visible spectrum. The last region that is of consequence to the human eye is low energy visible light, which ranges in wavelength from about <NUM> to about <NUM>.

It is widely known that UV light is harmful to the eye. UVC is completely blocked by the ozone layer, which also blocks most of UVB. Consequently, about <NUM>% of the UV light from the sun consists of UVA. There is also a growing body of research indicating that HEV light from <NUM> to <NUM> can cause damage to the eye and in particular the retina. Although the lens and cornea of the human eye blocks UVB and most of UVA, virtually all of the HEV light can penetrate the lens and impact the retina at the back of the eye.

HEV light affects the eye in multiple ways. HEV light has been implicated in Age related Macular Degeneration (AMD), which is the leading cause of progressive blindness in seniors. One of the causes of AMD appears to be damage to the retinal pigment epithelium (RPE), a layer of light sensitive cells that lie behind the photoreceptors in the retina which are responsible for vision. Although the exact pathology of AMD is not completely understood, there is growing evidence that the exposure to HEV light may play an important role in damaging RPE cells and the development of AMD.

HEV light is also thought to contribute to eyestrain and to reduced visual acuity under certain conditions. The short, high energy wavelengths associated with HEV light may cause blue light to flicker and create glare more easily than longer, lower energy wavelengths. As a result, prolonged exposure to HEV light (e.g., from computer screens and energy efficient lighting) may cause eyestrain, headaches, physical and mental fatigue. In addition, the axial (longitudinal) chromatic abberation of light through the crystalline lens of the eye can create a "blue light blur". <FIG> shows light of different wavelengths <NUM>, <NUM>, <NUM> passing through the lens <NUM> of an eye <NUM>. The different wavelengths are refracted differently and focus at different distances from the lens. Blue light refracts more than the other wavelengths, resulting in a focal point <NUM> of blue light in front of and not on the retina <NUM>. This effect may be observed as a blue haze around objects in bright light (e.g., sun and snow), and also in foggy conditions where blue light is strongly reflected. In addition, fluorescent lamps and LED lighting (e.g., automobile headlights) have significant output of HEV light and can similarly contribute to a loss of visual acuity, especially at night while driving. Thus, the growing ubiquity of blue light from computer displays and other electronic devices, modern lighting, and other sources makes the management of HEV light a matter of growing importance.

Notwithstanding the problems associated with HEV light, visible light between about <NUM> to about <NUM> is a regulator of the circadian response in humans. Therefore, it would be desirable to reduce exposure to HEV light and, in particular, reduce eyestrain and blue light blur, without significantly affecting transmission of light in the range from about <NUM> to about <NUM> so as to not inhibit the natural function of the circadian cycle. A patent document disclosing an ophthalmic lens reducing the exposure to HEV light is the patent application <CIT> <CIT>.

A thin film coating for an ophthalmic lens is disclosed that a comprises alternating layers of high and low index materials. In one embodiment, the thin film coating attenuates the transmission of light as defined in appended claim <NUM>. The thin film coating is applied to the front surface of an optical lens, as defined in claim <NUM>.

In yet another embodiment, the thin film coating has a spectral reflectance curve that comprises first and second regions according to appended claim <NUM>.

The embodiments described herein and other features, advantages, and disclosures contained herein, and the manner of attaining them, will be better understood from the following description in conjunction with the accompanying drawing figures, in which like reference numerals identify like elements, and wherein:.

In the following detailed description of embodiments of the present disclosure, reference is made to the accompanying drawings that form a part hereof, and in which is shown by way of illustration, and not by way of limitation, such specific embodiments. It is to be understood that other embodiments may be utilized and that changes may be made without departing from the scope of the present disclosure.

Reference is now made to <FIG>, which illustrates an ophthalmic lens system <NUM>, that comprises an optical lens <NUM> having a (object side) front surface <NUM> and a (eye side) back surface <NUM>. Optical lenses used in ophthalmic systems are typically produced with a convex front surface <NUM> and concave back surface <NUM>. A thin film coating <NUM> that attenuates transmission of HEV light is applied to front surface <NUM>. An optional anti-reflective thin film coating <NUM> may be applied to back surface <NUM>.

It has been found that the attenuation of HEV light in a range of wavelengths centered at about <NUM> reduces the problem of glare and blue blur caused by HEV light, without significantly affecting the portion of the spectrum that is important for the circadian response. In one embodiment, thin film coating <NUM> attenuates light in a range of about <NUM> to about <NUM>, which reduces the transmission of HEV light while avoiding significant interference with the circadian response. In a further embodiment, the transmission of light is attenuated by at least about <NUM>% at about <NUM> and decreases to about <NUM>% or less at about <NUM>. Within this range, the transmission of light is preferably attenuated between about <NUM>% to about <NUM>% at a wavelength of about <NUM>, and more preferably by about <NUM>% at a wavelength of about <NUM>.

It is desirable that the attenuation of light decreases rapidly above about <NUM>, to minimize interference with the circadian response after blocking unwanted HEV and UV wavelengths. Thus, in a preferred embodiment, the attenuation of HEV light between about <NUM> and about <NUM> has a curve that is monotonically decreasing -- i.e. is either decreasing or nonincreasing over the range from <NUM> to <NUM>. More preferably, the attenuation of HEV light between about <NUM> and about <NUM> has a curve that is strictly decreasing -- i.e. is continuously decreasing without a plateau. In a particularly preferred embodiment, the attenuation of light comprises a spectral reflectance curve that is strictly decreasing between about <NUM> and about <NUM>, and has a slope of about -<NUM> at about <NUM>.

Thin film coating <NUM> may also assist in blocking transmission of UV light by attenuating light in a range of wavelengths less than about <NUM>. In one embodiment, thin film coating <NUM> may further attenuate light by about <NUM>% or more in a region from about <NUM> to about <NUM>. The attenuation of visible light above about <NUM> is ideally minimized. The attenuation of light in a range of about <NUM> to about <NUM> is attenuated by about <NUM>% or less, and more preferably by about <NUM>% or less.

Thin film coatings that are designed to attenuate light below about <NUM> may give the ophthalmic lens system an undesirable purple or dark blue reflection. It has been found that this effect may be reduced by the attenuation of transmitted light in a secondary region that comprises a peak of attenuation between about <NUM> to <NUM>%, at a wavelength between about <NUM> to about <NUM>. In one embodiment, the secondary region comprises a peak of attenuation between about <NUM>% to about <NUM>%, at about <NUM>, with a full width at half maximum (FWHM) of about <NUM>. In a preferred embodiment, the secondary region has a peak of attenuation of about <NUM>%. Less than <NUM>% attenuation does not significantly reduce the purple or dark blue reflectance.

Thin film coating <NUM> comprises multiple layers of alternating high and low index materials, such as metal oxides, metal fluorides and other materials known in the art. High index materials have an index of refraction greater than about <NUM>, and include, but are not limited to: TiO<NUM>, ZrO<NUM>, HfO<NUM>, and commercially available materials such as Dralo (Umicore Thin Film Products - Providence, RI). The low index materials have an index of refraction of less than about <NUM> and include but are not limited to: SiO<NUM>, MgF<NUM>, Al<NUM>O<NUM>. In a preferred embodiment, the low index material has an index of refraction of about <NUM> or less. Other fluorides and carbides are known in the art to have suitable refractive indices for use in thin film coating <NUM>, such as CeF<NUM>, cryolite (Na<NUM>AlF<NUM>), and AlP.

The number of layers and the thickness of the highand low index materials in each layer determine the characteristics of the attenuation of transmission of light and spectral reflectance curve of the thin film coating. In one embodiment, thin film coating <NUM> comprises at least eight layers of alternating high and low index materials, and preferably comprises ten layers. In a particularly preferred embodiment, thin film coating comprises ten layers of alternating high and low index materials, and most preferably ten layers of alternating TiO<NUM> and SiO<NUM>. Although more than ten alternating layers are possible, the benefits provided by the additional layers may be outweighed by the increased manufacturing time.

The layers of alternating high and low index materials that comprise thin film coating <NUM> may be applied to the front surface <NUM> of the substrate optical lens <NUM> by various methods known in the art, including chemical vapor deposition, and physical vapor deposition such as sputtering and electron beam evaporation. In one embodiment, high index layers of TiO<NUM> may be applied by vapor deposition of a Ti<NUM>O<NUM> starting material, as is known in the art.

Optical lens <NUM> may be formed of a variety of different plastic materials that are known in the art. In one embodiment, the lens material is a high refractive index material such as a urethane-based polymer. In a preferred embodiment, the lens material does not significantly attenuate the transmission of light. Conventional UV/blue blocking lenses involve dyes that can give the lens an undesirable yellowish to red tint. These conventional lenses may also generally reduce the transmission of light across a large portion of the visible spectrum, thereby reducing their effectiveness to daytime wear only. In contrast, the attenuation and light transmission curve of the ophthalmic lens system may be substantially determined by thin film coating <NUM>, which allows optical lens <NUM> to be colorless. By eliminating the need for the dyes, the color acuity and total amount of light entering the eye are improved.

Nonetheless, optical lens <NUM> may contain in-mass dyes or other additives. In one embodiment, optical lens <NUM> may contain a dye or pigment that gives the lens an aesthetically desirable tint or coloring. In another embodiment, optical lens <NUM> may contain an in-mass, UV absorbing additive that supplements the UV blocking properties of thin film coating <NUM>. UV/blue absorbing dyes and additives are commercially available, and include BPI Melanin Therapeutic Tint, Diamond Dye <NUM>, UV Blue Filter Vision <NUM> (Brain Power Inc. - Miami, FL), and C200-<NUM> Opti-Safe Lens Dye (Phantom Research Laboratories Inc. - Miami, FL). Other UV absorbing additives known in the art include polyamides, benzophenones, hydroxybenzophenone, hydroxyphenylbenzotriazole, benzotriazoles, hydroxyphenyltriazines, <NUM>-(<NUM>-hydroxyphenyl)-benzotriazoles, <NUM>-hydroxy-benzophenones, hydroxyphenyl-s-triazines, and oxalanilides. In a preferred embodiment, the UV absorbing additive attenuates the transmission of light by at least about <NUM>% in a wavelength range from about <NUM> to about <NUM> and more preferably, attenuates transmission by at least <NUM>% in a range from about <NUM> to about <NUM>. The addition of a UV absorbing additive may give optical lens <NUM> a pronounced yellow to red tint.

Ophthalmic lens system <NUM> optionally includes, but does not require an anti-reflective coating <NUM> applied to back surface <NUM> of optical lens <NUM>. Anti-reflective coating <NUM> reduces the unwanted reflection of UV and HEV light from back surface <NUM> back toward the wearer's eye. In one embodiment, anti-reflective coating <NUM> has a transmission of at least about <NUM>% in the range of wavelengths from about <NUM> to about <NUM>. In a preferred embodiment, anti-reflective coating <NUM> reflects less than about <NUM>% of light in a range from about <NUM> to about <NUM>. Such anti-reflective coatings and methods of applying them to optical lenses are well known in the art.

The following examples are included to demonstrate preferred embodiments of the invention. It should be appreciated by those of skill in the art that the techniques disclosed in the examples which follow represent techniques discovered by the inventors to function well in the practice of the invention, and thus can be considered to constitute preferred modes for its practice. However, those of skill in the art should, in light of the present disclosure, appreciate that many changes can be made in the specific embodiments which are disclosed and still obtain a like or similar result without departing from the scope of the invention.

A thin film coating comprising ten layers of alternating high index (TiO<NUM>) and low index (SiO<NUM>) materials was developed as shown in Table <NUM>. Layer <NUM> represents the layer positioned closest to optical lens <NUM>, with TiO<NUM> being the first, innermost material in the thin film coating. Layer <NUM> represents the layer positioned farthest from optical lens <NUM>, with SiO<NUM> being the last, outermost material in the thin film coating. The thickness of the materials in each layer is shown in Table <NUM>.

The spectral reflectance curve of the thin film coating at wavelengths ranging from <NUM> to <NUM> is shown in <FIG>. The attenuation of transmission is characterized by a primary reflection region having a spectral reflectance curve <NUM> with about <NUM>% reflectance at about <NUM> and a slope of about m = -<NUM>. Reflectance is at least about <NUM>% from about <NUM> to about <NUM>, at least about <NUM>% at about <NUM>, is strictly decreasing from about <NUM>% at <NUM> to about <NUM>% or less at <NUM>, and is about <NUM>% or less from about <NUM> to about <NUM>. A secondary reflection region <NUM> is present having a peak of reflectance of about <NUM>% at about <NUM>, with an FWHM of about <NUM>. Reflectance decreases on either side of the peak to about <NUM>% or less at <NUM> and <NUM>. The secondary reflection region reduces the purple or dark blue reflection discussed above and provides some attenuation of HEV light in the range of about <NUM> to about <NUM>, while providing sufficient transmission of light above <NUM> to avoid impairment of the circadian response.

As shown in <FIG>, attenuation of transmission decreases at wavelengths less than about <NUM>. As discussed above, the UV blocking characteristics of ophthalmic lens system <NUM> may be supplemented by adding an in-mass UV absorbing additive to optical lens <NUM>, such that attenuation of transmission is at least about <NUM>% from about <NUM> to about <NUM>.

A thin film coating comprising ten layers of alternating high index (TiO<NUM>) and low index (SiO<NUM>) materials was developed as described in Example <NUM>, except that the thickness of the materials in each layer was as shown in Table <NUM>.

The spectral reflectance curve of the thin film coating at wavelengths ranging from <NUM> to <NUM> is shown in <FIG>. The attenuation of transmission is characterized by a primary reflection region similar to the thin film coating of Example <NUM>, and having a spectral reflectance curve <NUM> with about <NUM>% reflectance at about <NUM> and a slope of about m = -<NUM>. A secondary reflection region <NUM> is present having a peak of reflectance of about <NUM>% at about <NUM>, with an FWHM of about <NUM>. Reflectance decreases on either side of the peak to a reflectance of about <NUM>% or less at <NUM> and <NUM>.

The spectral reflectance curve of the thin film coating at wavelengths ranging from <NUM> to <NUM> is shown in <FIG>. The attenuation of transmission is characterized by a primary reflection region similar to the thin film coating of Example <NUM>, and having a spectral reflectance curve <NUM> with about <NUM>% reflectance at about <NUM> and a slope of about m = -<NUM>. A secondary reflection region <NUM> is present having a peak attenuation of about <NUM>% at about <NUM>, with an FWHM of about <NUM>. Reflectance decreases on either side of the peak to about <NUM>% or less at <NUM> and <NUM>.

It is also possible to develop thin film coatings having characteristics that resemble the attenuation of transmission in conventional UV/blue blocking lenses, without the need for in-mass dyes or pigments. A thin film coating comprising ten layers of alternating high index (TiO<NUM>) and low index (SiO<NUM>) materials was developed as described in Example <NUM>, except that the thickness of the materials in each layer was as shown in Table <NUM>.

The spectral reflectance curve of the thin film coating at wavelengths ranging from <NUM> to <NUM> is shown in <FIG>. The attenuation of transmission is characterized by a primary reflection region similar to the thin film coating of Example <NUM>, except shifted toward higher wavelengths -- i.e. having a spectral reflectance curve <NUM> with about <NUM>% reflectance at about <NUM> and a slope of about m = -<NUM>. Reflectance is at least about <NUM>% from about <NUM> to about <NUM>, at least about <NUM>% at about <NUM>, is strictly decreasing from about <NUM>% at <NUM> to about <NUM>% or less at <NUM>, and is about <NUM>% or less from about <NUM> to about <NUM>. A secondary reflection region <NUM> is present having a peak of reflectance of about <NUM>% at about <NUM>, with an FWHM of about <NUM>. Reflectance decreases on either side of the peak to about <NUM>% or less at <NUM> and <NUM>. Thus, the primary reflection region attenuates transmission of a wider range of HEV light, but overlaps significantly with the range of from about <NUM> to about <NUM> which is believed to be important for the circadian response.

The ophthalmic lens system <NUM> in accordance with the embodiments described herein provides attenuation of damaging and fatigue-inducing UV and HEV light. The thin film coating <NUM> particularly minimizes transmission of the portions of HEV light that cause glare and blue light blur such that visual acuity is improved in viewing computer and electronic device displays, and under modern lighting conditions such as fluorescent and LED lamps. Meanwhile, the ophthalmic lens system <NUM> allow significant transmission of light in the wavelength range associated with the circadian cycle of the body to reach the eye.

Although thin film coating <NUM> is described as applied to the front surface of an ophthalmic lens system <NUM>, those of skill in the art will appreciate that thin film coating <NUM> may also be applied to the back surface of an ophthalmic lens system. In addition, other types of coatings known in the art may be incorporated into thin film coating <NUM>. For example, thin film coating <NUM> may also incorporate an anti-static coating, a scratch resistant coating, a hydrophobic/oleophobic coating and/or an anti-reflective coating as are known in the art.

Claim 1:
An ophthalmic lens (<NUM>), comprising:
an optical lens (<NUM>) having a front surface (<NUM>) and a back surface (<NUM>); and
a thin film coating (<NUM>) on the front surface comprising alternating layers of high and low index materials, the coating attenuating transmission of light and having a spectral reflectance curve (<NUM>, <NUM>, <NUM>) comprising a reflectance of at least about <NUM>% over the range from about <NUM> to about <NUM>, and <NUM>% or less over the range from <NUM> to <NUM>,
characterized in that the spectral reflectance curve is monotonically decreasing from greater than <NUM>% to <NUM>% or less between <NUM> to <NUM>, and
wherein the spectral reflectance curve further comprises a peak of reflectance (<NUM>, <NUM>, <NUM>) between about <NUM>% to about <NUM>% at a wavelength of between about <NUM> and about <NUM>.