id stringlengths 21 21 | kind stringclasses 3
values | options listlengths 2 6 | target listlengths 2 6 | state stringlengths 168 265 | question stringclasses 7
values | domain stringclasses 1
value | family stringclasses 1
value | source stringclasses 1
value |
|---|---|---|---|---|---|---|---|---|
v3_c98be73436c87c4e_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0.01,
0.08,
0.68,
0.23
] | A grignard reaction quenches with methanol after complete conversion; additionally has an exotherm exceeding the cooling capacity. Context: under the process-safety review, during peak load. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_cfc7e034c7381749_n | noul | [
"false",
"true"
] | [
0.7,
0.3
] | An oxidation step mixes a strong acid with a carbonate base; additionally uses a 10x excess of the nucleophile. Context: with the new catalyst lot, mid-incident. Reported by the supervisor. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_0c088950ecebe499_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.02,
0.28,
0.57,
0.13
] | A grignard reaction runs at 40C under nitrogen; additionally uses a 10x excess of the nucleophile. Context: in the teaching lab, shortly after a software update. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_58f1daf5cfb9de2e_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.02,
0.08,
0.16,
0.64,
0.1,
0
] | A polymerization runs at 40C under nitrogen; additionally uses a 10x excess of the nucleophile. Context: with the new catalyst lot, immediately after go-live. Reported by the operator. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_8d06c2c25a50f5a5_n | noul | [
"false",
"true"
] | [
0.72,
0.28
] | An esterification quenches with methanol after complete conversion; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: with the new catalyst lot, while on-call rotation changed. Reported by the monitoring system. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_2e2236afc2fbc0ed_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.06,
0.33,
0.46,
0.15
] | A grignard reaction quenches with methanol after complete conversion; additionally combines incompatible functional groups on the same substrate. Context: at 10mmol scale, during the quarterly review. Reported by the on-call engineer. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_2be4946c4f7b11f7_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.02,
0.19,
0.31,
0.42,
0.06,
0
] | An esterification quenches with methanol after complete conversion; additionally follows the literature procedure at 0.8x scale. Context: at 10mmol scale, during peak load. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_369e6db1d7714693_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.08,
0.39,
0,
0.53
] | An oxidation step quenches with methanol after complete conversion; additionally combines incompatible functional groups on the same substrate. Context: at 10mmol scale, during the holiday freeze. Reported by the operator. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_ad6158585341acbf_n | noul | [
"false",
"true"
] | [
0.37,
0.63
] | An oxidation step uses a 10x excess of the nucleophile; additionally follows the literature procedure at 0.8x scale. Context: at 10mmol scale, immediately after go-live. Reported by the review queue. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_b238cc4eee4308cd_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0.02,
0.11,
0.58,
0.29,
0
] | An oxidation step produces the thermodynamic product at high temperature; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: at 10mmol scale, during a scheduled maintenance window. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_b52eb9f9e576465c_n | noul | [
"false",
"true"
] | [
0.16,
0.84
] | A grignard reaction combines incompatible functional groups on the same substrate; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: under the process-safety review, under an active deadline. Reported by the monitoring system. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_e8ea7df794b5e667_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.03,
0.44,
0.5,
0.03
] | A grignard reaction follows the literature procedure at 0.8x scale; additionally runs at 40C under nitrogen. Context: with the new catalyst lot, during the system migration. Reported by the supervisor. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_8eae66482a8037ca_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0,
0,
0.01,
0.33,
0.65
] | An esterification heats a peroxide-former to its decomposition point; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: under the process-safety review, as part of a compliance sweep. Reported by the review queue. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_0e52608995b19f75_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0,
0.34,
0.66
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally has an exotherm exceeding the cooling capacity. Context: with the new catalyst lot, mid-incident. Reported by the supervisor. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_b2b0982158f4e84b_n | noul | [
"false",
"true"
] | [
0.24,
0.76
] | A polymerization quenches with methanol after complete conversion; additionally runs at 40C under nitrogen. Context: at 10mmol scale, during the morning shift. Reported by the automated check. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_43cc38b8a2c78b5e_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.43,
0.5,
0,
0.07
] | An esterification follows the literature procedure at 0.8x scale; additionally uses a 10x excess of the nucleophile. Context: at 10mmol scale, under reduced staffing. Reported by the monitoring system. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_48c3a6002e1ee7f0_n | noul | [
"false",
"true"
] | [
0.11,
0.89
] | An esterification mixes a strong acid with a carbonate base; additionally uses a 10x excess of the nucleophile. Context: at 10mmol scale, as part of a compliance sweep. Reported by the review queue. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_5dc908814380785b_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.02,
0.07,
0.14,
0.64,
0.12,
0.01
] | A grignard reaction runs at 40C under nitrogen; additionally follows the literature procedure at 0.8x scale. Context: with the new catalyst lot, under an active deadline. Reported by the automated check. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_5ad496b676d925e4_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.03,
0.01,
0.01,
0.02,
0.18,
0.75
] | A grignard reaction mixes a strong acid with a carbonate base; additionally has an exotherm exceeding the cooling capacity. Context: under the process-safety review, during peak load. Reported by the operator. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_e6e33b3bb09e8e41_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.08,
0.12,
0.18,
0.39,
0.2,
0.03
] | A grignard reaction uses a 10x excess of the nucleophile; additionally produces the thermodynamic product at high temperature. Context: in the teaching lab, under an active deadline. Reported by the review queue. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_6e11f7fecbc116df_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0.02,
0.1,
0.66,
0.22,
0
] | An oxidation step produces the thermodynamic product at high temperature; additionally uses a 10x excess of the nucleophile. Context: in the teaching lab, under reduced staffing. Reported by the operator. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_121afd6e6090dd95_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0.01,
0.04,
0.36,
0.56,
0.03
] | A polymerization produces the thermodynamic product at high temperature; additionally mixes a strong acid with a carbonate base. Context: with the new catalyst lot, while legacy systems are still active. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_eb1955b7c8c30074_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.01,
0.15,
0,
0.84
] | A grignard reaction follows the literature procedure at 0.8x scale; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: under the process-safety review, as part of a compliance sweep. Reported by the on-call engineer. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_c34d9c6f20b6548e_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.02,
0.44,
0.47,
0.07
] | An esterification runs water-sensitive chemistry in a humid glovebox failure; additionally runs at 40C under nitrogen. Context: with the new catalyst lot, under reduced staffing. Reported by the monitoring system. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_90cd53cc90d7a6a0_n | noul | [
"false",
"true"
] | [
0.32,
0.68
] | A grignard reaction runs at 40C under nitrogen; additionally follows the literature procedure at 0.8x scale. Context: in the teaching lab, under reduced staffing. Reported by the operator. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_5e01d0dd98f89a8d_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.01,
0.03,
0,
0.96
] | An oxidation step heats a peroxide-former to its decomposition point; additionally uses a 10x excess of the nucleophile. Context: with the new catalyst lot, during the holiday freeze. Reported by the operator. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_b720cdafdc0fd961_n | noul | [
"false",
"true"
] | [
0.41,
0.59
] | A polymerization produces the thermodynamic product at high temperature; additionally uses a 10x excess of the nucleophile. Context: at 10mmol scale, following a recent audit. Reported by the supervisor. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_0df1e8cdb1dd4a1d_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0.01,
0.04,
0.49,
0.46
] | An esterification heats a peroxide-former to its decomposition point; additionally produces the thermodynamic product at high temperature. Context: under the process-safety review, during the quarterly review. Reported by the monitoring system. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_9779a5d3d8e697e9_n | noul | [
"false",
"true"
] | [
0.07,
0.93
] | An esterification combines incompatible functional groups on the same substrate; additionally has an exotherm exceeding the cooling capacity. Context: with the new catalyst lot, while legacy systems are still active. Reported by the supervisor. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_3505f4351ea7be8f_n | noul | [
"false",
"true"
] | [
0.17,
0.83
] | A grignard reaction runs at 40C under nitrogen; additionally combines incompatible functional groups on the same substrate. Context: under the process-safety review, following a recent audit. Reported by the supervisor. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_6179e237e8904486_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.01,
0.74,
0,
0.25
] | A polymerization runs water-sensitive chemistry in a humid glovebox failure; additionally produces the thermodynamic product at high temperature. Context: at 10mmol scale, at the end of the fiscal period. Reported by the on-call engineer. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_0a8a6f148bcefea9_n | noul | [
"false",
"true"
] | [
0.71,
0.29
] | An oxidation step quenches with methanol after complete conversion; additionally has an exotherm exceeding the cooling capacity. Context: in the teaching lab, under reduced staffing. Reported by the operator. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_2931e12ede76e5b1_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0.08,
0.15,
0.65,
0.11,
0
] | A polymerization produces the thermodynamic product at high temperature; additionally uses a 10x excess of the nucleophile. Context: in the teaching lab, with a new vendor onboarded. Reported by the automated check. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_f4aa078c06cbd9be_n | noul | [
"false",
"true"
] | [
0.51,
0.49
] | A polymerization heats a peroxide-former to its decomposition point; additionally quenches with methanol after complete conversion. Context: at 10mmol scale, at the end of the fiscal period. Reported by the monitoring system. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_8f44d403d5c743b5_n | noul | [
"false",
"true"
] | [
0.1,
0.9
] | An esterification uses a 10x excess of the nucleophile; additionally heats a peroxide-former to its decomposition point. Context: at 10mmol scale, shortly after a software update. Reported by the review queue. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_ced522194e4fc00d_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.01,
0.31,
0.68
] | A grignard reaction follows the literature procedure at 0.8x scale; additionally heats a peroxide-former to its decomposition point. Context: with the new catalyst lot, during peak load. Reported by the monitoring system. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_4f6c78d9cac6f329_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0,
0.11,
0.89
] | An oxidation step has an exotherm exceeding the cooling capacity; additionally quenches with methanol after complete conversion. Context: under the process-safety review, during the holiday freeze. Reported by the on-call engineer. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_d1ec16784fa7557b_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.01,
0.21,
0.64,
0.14
] | A grignard reaction uses a 10x excess of the nucleophile; additionally runs at 40C under nitrogen. Context: with the new catalyst lot, while on-call rotation changed. Reported by the operator. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_17660b8e58e27247_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.63,
0.21,
0.01,
0.15
] | A grignard reaction follows the literature procedure at 0.8x scale; additionally quenches with methanol after complete conversion. Context: in the teaching lab, shortly after a software update. Reported by the operator. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_0e7e7a7d2271d71e_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.04,
0.02,
0,
0.94
] | A grignard reaction heats a peroxide-former to its decomposition point; additionally quenches with methanol after complete conversion. Context: with the new catalyst lot, with staffing at reduced levels. Reported by the monitoring system. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_73fef612029eb90f_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.01,
0.01,
0,
0.98
] | A grignard reaction quenches with methanol after complete conversion; additionally has an exotherm exceeding the cooling capacity. Context: in the teaching lab, with a new vendor onboarded. Reported by the automated check. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_5ecdee832069f536_n | noul | [
"false",
"true"
] | [
0.39,
0.61
] | An oxidation step uses a 10x excess of the nucleophile; additionally quenches with methanol after complete conversion. Context: with the new catalyst lot, under reduced staffing. Reported by the operator. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_5bce54a4c996d80c_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0.01,
0.15,
0.84
] | An esterification quenches with methanol after complete conversion; additionally heats a peroxide-former to its decomposition point. Context: with the new catalyst lot, at the end of the fiscal period. Reported by the on-call engineer. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_650fe17f98002b33_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0.04,
0.12,
0.35,
0.42,
0.06
] | A grignard reaction produces the thermodynamic product at high temperature; additionally mixes a strong acid with a carbonate base. Context: at 10mmol scale, during normal operations. Reported by the monitoring system. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_efd25db9c4d94675_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0,
0.01,
0.13,
0.77,
0.08
] | A polymerization runs water-sensitive chemistry in a humid glovebox failure; additionally uses a 10x excess of the nucleophile. Context: with the new catalyst lot, with staffing at reduced levels. Reported by the monitoring system. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_03741b87ad9f41ff_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0.01,
0.21,
0.76,
0.02
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally produces the thermodynamic product at high temperature. Context: at 10mmol scale, while legacy systems are still active. Reported by the monitoring system. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_f330a57682fd8ea6_n | noul | [
"false",
"true"
] | [
0.3,
0.7
] | A polymerization mixes a strong acid with a carbonate base; additionally uses a 10x excess of the nucleophile. Context: in the teaching lab, under an active deadline. Reported by the supervisor. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_e5432a07ae1f333c_n | noul | [
"false",
"true"
] | [
0.14,
0.86
] | A grignard reaction heats a peroxide-former to its decomposition point; additionally uses a 10x excess of the nucleophile. Context: with the new catalyst lot, as part of a compliance sweep. Reported by the monitoring system. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_653359303deb94e9_n | noul | [
"false",
"true"
] | [
0.2,
0.8
] | An oxidation step quenches with methanol after complete conversion; additionally produces the thermodynamic product at high temperature. Context: under the process-safety review, at the end of the fiscal period. Reported by the supervisor. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_de29493596a7518a_n | noul | [
"false",
"true"
] | [
0.76,
0.24
] | An oxidation step follows the literature procedure at 0.8x scale; additionally mixes a strong acid with a carbonate base. Context: at 10mmol scale, immediately after go-live. Reported by the on-call engineer. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_0dd1bf049fa3a9b0_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.01,
0.09,
0.43,
0.47
] | A grignard reaction quenches with methanol after complete conversion; additionally has an exotherm exceeding the cooling capacity. Context: at 10mmol scale, during the holiday freeze. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_eb9de4f4c543fc37_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0.02,
0.27,
0.71
] | A grignard reaction has an exotherm exceeding the cooling capacity; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: at 10mmol scale, immediately after go-live. Reported by the on-call engineer. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_c4c74f59e5af5d96_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.01,
0.48,
0.51
] | An oxidation step follows the literature procedure at 0.8x scale; additionally heats a peroxide-former to its decomposition point. Context: with the new catalyst lot, with staffing at reduced levels. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_07383138573455cf_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.25,
0.02,
0,
0.73
] | A polymerization heats a peroxide-former to its decomposition point; additionally follows the literature procedure at 0.8x scale. Context: in the teaching lab, during normal operations. Reported by the monitoring system. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_4f16d4e1f2cc8693_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.02,
0.64,
0.34
] | A grignard reaction uses a 10x excess of the nucleophile; additionally has an exotherm exceeding the cooling capacity. Context: in the teaching lab, with a new vendor onboarded. Reported by the monitoring system. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_328a64024fba026d_n | noul | [
"false",
"true"
] | [
0.21,
0.79
] | A polymerization heats a peroxide-former to its decomposition point; additionally quenches with methanol after complete conversion. Context: in the teaching lab, immediately after go-live. Reported by the review queue. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_77944b9adf3da742_n | noul | [
"false",
"true"
] | [
0.06,
0.94
] | A grignard reaction heats a peroxide-former to its decomposition point; additionally has an exotherm exceeding the cooling capacity. Context: at 10mmol scale, during peak load. Reported by the operator. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_9b9366bc0fb9965c_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0.11,
0.58,
0.31
] | A polymerization follows the literature procedure at 0.8x scale; additionally mixes a strong acid with a carbonate base. Context: under the process-safety review, with a new vendor onboarded. Reported by the supervisor. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_37da5a5a008ef6df_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0.04,
0.15,
0.74,
0.07,
0
] | A polymerization produces the thermodynamic product at high temperature; additionally follows the literature procedure at 0.8x scale. Context: at 10mmol scale, with a new vendor onboarded. Reported by the automated check. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_e3a29886e454cae8_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0,
0.04,
0.96
] | An oxidation step has an exotherm exceeding the cooling capacity; additionally heats a peroxide-former to its decomposition point. Context: at 10mmol scale, while on-call rotation changed. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_955b6ecf6fb0260a_n | noul | [
"false",
"true"
] | [
0.43,
0.57
] | An esterification combines incompatible functional groups on the same substrate; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: under the process-safety review, during normal operations. Reported by the operator. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_b067b7dc78296568_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0.19,
0.4,
0.39,
0.01,
0
] | An esterification uses a 10x excess of the nucleophile; additionally runs at 40C under nitrogen. Context: at 10mmol scale, during an external partner integration. Reported by the operator. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_787d2e61562aa2d0_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0,
0.1,
0,
0.9
] | An oxidation step mixes a strong acid with a carbonate base; additionally combines incompatible functional groups on the same substrate. Context: at 10mmol scale, shortly after a software update. Reported by the automated check. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_c5c000d017c2adce_n | noul | [
"false",
"true"
] | [
0.17,
0.83
] | An oxidation step runs at 40C under nitrogen; additionally uses a 10x excess of the nucleophile. Context: under the process-safety review, with a new vendor onboarded. Reported by the automated check. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_93257d2dd3d68b93_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.06,
0.02,
0.03,
0.07,
0.35,
0.47
] | A grignard reaction mixes a strong acid with a carbonate base; additionally uses a 10x excess of the nucleophile. Context: at 10mmol scale, during peak load. Reported by the supervisor. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_2056b62b38099674_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.03,
0.15,
0.53,
0.29
] | A polymerization combines incompatible functional groups on the same substrate; additionally quenches with methanol after complete conversion. Context: with the new catalyst lot, under reduced staffing. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_56837639ea9611ab_n | noul | [
"false",
"true"
] | [
0.21,
0.79
] | An oxidation step mixes a strong acid with a carbonate base; additionally produces the thermodynamic product at high temperature. Context: with the new catalyst lot, during the holiday freeze. Reported by the supervisor. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_c73c2974417bfc08_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0.06,
0.3,
0,
0.64
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally quenches with methanol after complete conversion. Context: in the teaching lab, under an active deadline. Reported by the monitoring system. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_b2726e7a7f036fff_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.01,
0.23,
0.69,
0.07
] | A grignard reaction follows the literature procedure at 0.8x scale; additionally runs at 40C under nitrogen. Context: under the process-safety review, while legacy systems are still active. Reported by the on-call engineer. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_4720a818739009e7_n | noul | [
"false",
"true"
] | [
0.16,
0.84
] | An oxidation step heats a peroxide-former to its decomposition point; additionally runs at 40C under nitrogen. Context: under the process-safety review, during peak load. Reported by the on-call engineer. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_439464d7ef9e1916_n | noul | [
"false",
"true"
] | [
0.72,
0.28
] | A polymerization follows the literature procedure at 0.8x scale; additionally quenches with methanol after complete conversion. Context: in the teaching lab, under an active deadline. Reported by the monitoring system. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_6cfaa23a8d860b15_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.07,
0.01,
0.02,
0.07,
0.36,
0.47
] | A grignard reaction mixes a strong acid with a carbonate base; additionally combines incompatible functional groups on the same substrate. Context: in the teaching lab, while legacy systems are still active. Reported by the monitoring system. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_2aa656aba27888c4_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0,
0.2,
0.8
] | A polymerization heats a peroxide-former to its decomposition point; additionally has an exotherm exceeding the cooling capacity. Context: under the process-safety review, under an active deadline. Reported by the review queue. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_42a08ff0156924e4_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.02,
0.03,
0.19,
0.76
] | A grignard reaction mixes a strong acid with a carbonate base; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: under the process-safety review, during normal operations. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_47489d5e1e1f6f07_n | noul | [
"false",
"true"
] | [
0.62,
0.38
] | An oxidation step produces the thermodynamic product at high temperature; additionally follows the literature procedure at 0.8x scale. Context: with the new catalyst lot, while legacy systems are still active. Reported by the supervisor. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_dbd99378f3edbdde_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0.11,
0.3,
0.48,
0.1,
0
] | An oxidation step runs at 40C under nitrogen; additionally produces the thermodynamic product at high temperature. Context: at 10mmol scale, during an external partner integration. Reported by the review queue. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_0ee3b1fa002d3b74_n | noul | [
"false",
"true"
] | [
0.74,
0.26
] | An esterification heats a peroxide-former to its decomposition point; additionally runs at 40C under nitrogen. Context: under the process-safety review, during the holiday freeze. Reported by the on-call engineer. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_dda5a7a0cee734bc_n | noul | [
"false",
"true"
] | [
0.8,
0.2
] | A polymerization has an exotherm exceeding the cooling capacity; additionally uses a 10x excess of the nucleophile. Context: in the teaching lab, during the holiday freeze. Reported by the review queue. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_859c23f3bf14f36a_n | noul | [
"false",
"true"
] | [
0.17,
0.83
] | An esterification quenches with methanol after complete conversion; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: at 10mmol scale, during an external partner integration. Reported by the monitoring system. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_69fc018703b79c9d_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.04,
0.65,
0.31
] | An oxidation step has an exotherm exceeding the cooling capacity; additionally quenches with methanol after complete conversion. Context: under the process-safety review, during peak load. Reported by the automated check. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_c5efac89d090a1f7_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.07,
0.87,
0.06
] | An esterification runs water-sensitive chemistry in a humid glovebox failure; additionally combines incompatible functional groups on the same substrate. Context: with the new catalyst lot, while legacy systems are still active. Reported by the operator. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_5b6b45b31b773d1a_n | noul | [
"false",
"true"
] | [
0.64,
0.36
] | A polymerization produces the thermodynamic product at high temperature; additionally quenches with methanol after complete conversion. Context: at 10mmol scale, during the morning shift. Reported by the operator. | Is this scenario one where: a runaway risk exists? | reaction_prediction | chemistry | yuri_v3 |
v3_cbe48e850b0cdd40_n | noul | [
"false",
"true"
] | [
0.83,
0.17
] | A polymerization uses a 10x excess of the nucleophile; additionally mixes a strong acid with a carbonate base. Context: at 10mmol scale, shortly after a software update. Reported by the automated check. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_c78d17824514b468_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.02,
0.01,
0.01,
0.03,
0.27,
0.66
] | A grignard reaction heats a peroxide-former to its decomposition point; additionally mixes a strong acid with a carbonate base. Context: with the new catalyst lot, mid-incident. Reported by the on-call engineer. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_58af738708d043e0_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.04,
0.61,
0.32,
0.03
] | A polymerization runs water-sensitive chemistry in a humid glovebox failure; additionally follows the literature procedure at 0.8x scale. Context: at 10mmol scale, at the end of the fiscal period. Reported by the monitoring system. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_6a5a93f51d6b5d6b_n | noul | [
"false",
"true"
] | [
0.74,
0.26
] | An esterification runs water-sensitive chemistry in a humid glovebox failure; additionally follows the literature procedure at 0.8x scale. Context: with the new catalyst lot, while legacy systems are still active. Reported by the review queue. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_d8e39755f4095c23_n | noul | [
"false",
"true"
] | [
0.47,
0.53
] | A polymerization has an exotherm exceeding the cooling capacity; additionally quenches with methanol after complete conversion. Context: with the new catalyst lot, mid-incident. Reported by the supervisor. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_2b1b706a9ae11ca9_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0,
0.28,
0.72
] | An oxidation step has an exotherm exceeding the cooling capacity; additionally combines incompatible functional groups on the same substrate. Context: in the teaching lab, at the end of the fiscal period. Reported by the on-call engineer. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_bf2b539a4e55fab4_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0.04,
0.44,
0.52
] | An oxidation step mixes a strong acid with a carbonate base; additionally heats a peroxide-former to its decomposition point. Context: at 10mmol scale, with staffing at reduced levels. Reported by the automated check. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_ce413a4838f60233_n | noul | [
"false",
"true"
] | [
0.94,
0.06
] | A grignard reaction runs water-sensitive chemistry in a humid glovebox failure; additionally heats a peroxide-former to its decomposition point. Context: at 10mmol scale, during the quarterly review. Reported by the operator. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_d070a942dde2c275_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0.01,
0.01,
0.04,
0.08,
0.36,
0.5
] | A grignard reaction quenches with methanol after complete conversion; additionally heats a peroxide-former to its decomposition point. Context: with the new catalyst lot, during normal operations. Reported by the automated check. | Rate reaction feasibility for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_3192e21915c3b79a_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0.01,
0.38,
0.61,
0
] | A polymerization uses a 10x excess of the nucleophile; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: at 10mmol scale, with a new vendor onboarded. Reported by the review queue. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_c95c9c199a9f80e7_n | noul | [
"false",
"true"
] | [
0.11,
0.89
] | An oxidation step uses a 10x excess of the nucleophile; additionally mixes a strong acid with a carbonate base. Context: under the process-safety review, with a new vendor onboarded. Reported by the review queue. | Is this scenario one where: the product mixture will need purification? | reaction_prediction | chemistry | yuri_v3 |
v3_f15b979728bd052c_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0,
0.05,
0.78,
0.17
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally mixes a strong acid with a carbonate base. Context: in the teaching lab, while legacy systems are still active. Reported by the automated check. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_e515433c03e3aa16_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0.01,
0.39,
0.54,
0.06
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally follows the literature procedure at 0.8x scale. Context: in the teaching lab, during an external partner integration. Reported by the operator. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_82b509d8625fca81_s | score | [
"0",
"1",
"2",
"3",
"4",
"5"
] | [
0,
0,
0.05,
0.29,
0.62,
0.04
] | An esterification has an exotherm exceeding the cooling capacity; additionally quenches with methanol after complete conversion. Context: at 10mmol scale, during the system migration. Reported by the supervisor. | Rate process hazard for this scenario on a 0-5 scale. | reaction_prediction | chemistry | yuri_v3 |
v3_b0602d11ff3cbd06_n | noul | [
"false",
"true"
] | [
0.83,
0.17
] | A polymerization has an exotherm exceeding the cooling capacity; additionally uses a 10x excess of the nucleophile. Context: at 10mmol scale, immediately after go-live. Reported by the supervisor. | Is this scenario one where: this reaction is feasible as written? | reaction_prediction | chemistry | yuri_v3 |
v3_fc6d7827dc261454_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0,
0.19,
0,
0.81
] | An oxidation step combines incompatible functional groups on the same substrate; additionally runs water-sensitive chemistry in a humid glovebox failure. Context: at 10mmol scale, under an active deadline. Reported by the on-call engineer. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_06a5abeb462aefe1_c | choice | [
"low",
"moderate",
"high",
"severe"
] | [
0,
0.06,
0.65,
0.29
] | An oxidation step uses a 10x excess of the nucleophile; additionally combines incompatible functional groups on the same substrate. Context: at 10mmol scale, under reduced staffing. Reported by the supervisor. | Hazard class for this scenario. | reaction_prediction | chemistry | yuri_v3 |
v3_2342c6a0e256e425_c | choice | [
"desired_product",
"side_reaction",
"no_reaction",
"hazard_event"
] | [
0,
0.01,
0,
0.99
] | An oxidation step runs water-sensitive chemistry in a humid glovebox failure; additionally mixes a strong acid with a carbonate base. Context: under the process-safety review, with a new vendor onboarded. Reported by the operator. | Likely outcome for this scenario. | reaction_prediction | chemistry | yuri_v3 |
End of preview. Expand in Data Studio
JEV corpus - reaction_prediction
7,497 typed calibrated decision rows from the jev-distill-corpus-v3 corpus (domain: reaction_prediction).
Each row is one typed decision: kind (noul / choice / score), a state, a question, options, and a target probability distribution over the options.
Part of the per-domain split of SargeDev/jev-distill-corpus-v3 - the full corpus in one repo.
Domains:
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