title stringlengths 8 368 | abstract stringlengths 0 221k | text stringlengths 0 1.04M | doi stringlengths 28 32 |
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Self-Assembly of Charged Oligomeric Bilayers at the Aqueous/Organic Interface Regulated by Ion-Pair Associations | : Phospholipid bilayer membranes show promise as biomolecular soft materials that mimic the ability of living
systems to sense, respond and learn but are fragile. Amphiphilic charged oligomers (oligodimethylsiloxane-methylimidazolium
cation, ODMS-MIM(+)), assembled into bilayers at the oil-aqueous interfaces of dropl... | introduction, except for
the fact that bilayer formation in that case was reversible: once
the voltage was reduced below the threshold, the bilayer
disappeared, and the DIB split into two separate droplets.
The ionic strength-dependent behavior described thus far
suggests that NaCl concentration affected bilayer f... | 10.26434/chemrxiv.12106773.v2 |
Hematene Nanoflakes: A non-van der Waals material with superior nonlinear optical properties | Stable and efficient optical limiters for eye and sensor protection have been of great demand
ever since the advent of high-power lasers. In this study, we report the preparation of highly
stable hematene nanoflakes for optical limiting applications by a facile exfoliation method from
a low-cost, non-van der Waals m... | Introduction
2D materials are being touted as the next best thing to graphene on account of their sterling
physical and chemical properties , which allow their fashioning for various potential
applications such as optoelectronics , spintronics , catalysis , chemical and
biological sensing , supercapacitors , photov... | 10.26434/chemrxiv-2022-fftqk-v2 |
Machine Learning and High-Throughput Robust Design of P3HT-CNT Composite Thin Films for High Electrical Conductivity | Combining high-throughput experiments with machine learning allows quick optimization of
parameter spaces towards achieving target properties. In this study, we demonstrate that
machine learning, combined with multi-labeled datasets, can additionally be used for scientific
understanding and hypothesis testing. We in... | Introduction
One of the biggest bottlenecks for fast and efficient scientific discoveries is the bandwidth
and cognitive ability of human researchers, who can conceive, conduct and comprehend a
limited number of experiments. With the emergence of automation, timelines for scientific
progress can be significantly ac... | 10.26434/chemrxiv.13265288.v1 |
Copper-Catalyzed Three-Component Photo-ATRA-Type Reaction for Asymmetric Intermolecular C-O Coupling | : Atom transfer radical addition (ATRA) reaction of alkenes has had a tremendous impact on the field of radical difunction-
alizations of alkenes. Particularly in the three-component photo-ATRA-type processes, a rich chemical space and structural diversity could
be achieved by smart combination of redox-active radical... | INTRODUCTION
The radical addition of a σ-carbon-halogen bond across a π-
bond of alkene, also called as atom transfer radical addition
(ATRA) reaction or Kharasch addition, was firstly discovered
in 1940s by Kharasch during investigation into the addition of
polyhalogenated alkanes to alkenes,1 Over the past decade... | 10.26434/chemrxiv-2022-jcwcw |
On the Vibrational Architecture of [Fe4S4]0/1+/2+/3+/4+ Iron-Sulfur Cubanes | : We herein present a comprehensive analysis of the oxidation-state-dependence of the 57Fe partial vibra-
tional density of states (PVDOS), measured using nuclear resonance vibrational spectroscopy (NRVS), across a com-
plete oxidation state series of iron-sulfur cubane (Fe4S4) clusters, which covers the [Fe4S4]0/1+/2+... | INTRODUCTION
Biological iron-sulfur cubane-type clusters (Fe4S4)
adopt a large variety of functions, critical to cellular func-
tion in all living organisms.1-10 They were proposed to be
among the earliest enzymatic cofactors, potentially medi-
ating the synthesis of primordial biomolecules at the origin
of life.11... | 10.26434/chemrxiv-2025-djq4q-v2 |
"A Novel Spectral Barcoding and Classification Approach for Complex Biological Samples using Multi-e(...TRUNCATED) | ": We report the development and application of a novel spectral barcoding approach that exploits ou(...TRUNCATED) | "Introduction \nThe amount of information required to accurately classify a \nsample scales with co(...TRUNCATED) | 10.26434/chemrxiv-2024-x0lhh-v2 |
"VOCCluster: Untargeted Metabolomics Feature Clustering Approach for Clinical Breath Gas Chromatogra(...TRUNCATED) | "Motivation: Metabolic profiling of breath analysis involves processing, alignment, scaling and clu(...TRUNCATED) | "Introduction\nBreathomics, the analysis of volatile organic compounds (VOCs) in breath,\noffers a p(...TRUNCATED) | 10.26434/chemrxiv.7728266.v1 |
How Dispersion Interactions at the Excited State Can Tune Photochromism of Embedded Chromophores | "We present QM/MMpol-cLR3, a polarizable embedding QM/MM framework that\nincludes explicit, state-sp(...TRUNCATED) | "Introduction\nUnderstanding how intermolecular interactions shape molecular processes is central to(...TRUNCATED) | 10.26434/chemrxiv-2025-dp1cw |
Acid Strength Effects on Off-Cycle Dimerization During Metal-Free Catalytic Dioxygen Reduction | "Development of earth-abundant catalysts for the reduction of dioxygen (ORR) is essential for \nthe (...TRUNCATED) | "Introduction \nThe oxygen reduction reaction (ORR) is central to the development of new alternativ(...TRUNCATED) | 10.26434/chemrxiv-2024-zk3xs |
Enhancing Dynamic Spectral Diffusion in Metal-Organic Frameworks Through Defect Engineering | ": The crystal packing of organic chromophores has a profound impact on their photophysical properti(...TRUNCATED) | "Introduction. \nPhotoactive organic molecules form the basis of numerous \ntechnologies, including (...TRUNCATED) | 10.26434/chemrxiv-2022-fldj9 |
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