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class | review_rounds int64 1 3 | review_notes listlengths 1 3 | approx_source_tokens int64 196 246 | source_text stringclasses 10
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|---|---|---|---|---|---|---|---|---|---|---|---|---|
chemrxiv | 60c7442b842e657dcbdb23c4 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without adding or omitting information."
] | 229 | Macrocycles of Higher ortho-Phenylenes: Assembly and Folding <p>Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships. S... | Macrocycles d’ortho-phénylènes supérieurs : Assemblage et repliement
La structure d’ordre supérieur dans les systèmes de foldamères abiotiques représente un objectif important mais largement inexploré. Comme approche à ce défi, l’assemblage covalent peut être utilisé pour assembler des macrocycles avec des sous-unités... | {
"id": "60c7442b842e657dcbdb23c4",
"doi": "10.26434/chemrxiv.8085143.v3",
"authors": "Zacharias Kinney; Viraj Kirinda; Scott Hartley",
"categories": "Organic Synthesis and Reactions; Physical Organic Chemistry; Computational Chemistry and Modeling; Self-Assembly",
"license": "CC BY NC ND 4.0",
"origin": "C... |
chemrxiv | 60c7442b842e657dcbdb23c4 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without omissions or additions."
] | 229 | Macrocycles of Higher ortho-Phenylenes: Assembly and Folding <p>Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships. S... | Makrozyklen höherer ortho-Phenylen: Assemblierung und Faltung
Die höherstufige Struktur in abiotischen Foldamer-Systemen stellt ein wichtiges, aber weitgehend unerreichtes Ziel dar. Als ein Ansatz zu dieser Herausforderung kann die kovalente Assemblierung verwendet werden, um Makrozyklen mit Foldamer-Untereinheiten in... | {
"id": "60c7442b842e657dcbdb23c4",
"doi": "10.26434/chemrxiv.8085143.v3",
"authors": "Zacharias Kinney; Viraj Kirinda; Scott Hartley",
"categories": "Organic Synthesis and Reactions; Physical Organic Chemistry; Computational Chemistry and Modeling; Self-Assembly",
"license": "CC BY NC ND 4.0",
"origin": "C... |
chemrxiv | 60c7442b842e657dcbdb23c4 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, mechanistic descriptions, and scientific details from the source text without omissions or additions."
] | 229 | Macrocycles of Higher ortho-Phenylenes: Assembly and Folding <p>Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships. S... | Macrociclos de orto-Fenilenos Superiores: Montagem e Dobramento
<p>A estrutura de ordem superior em sistemas de foldâmeros abióticos representa um objetivo importante, porém em grande parte não realizado. Como uma abordagem para esse desafio, a montagem covalente pode ser usada para montar macrociclos com subunidades ... | {
"id": "60c7442b842e657dcbdb23c4",
"doi": "10.26434/chemrxiv.8085143.v3",
"authors": "Zacharias Kinney; Viraj Kirinda; Scott Hartley",
"categories": "Organic Synthesis and Reactions; Physical Organic Chemistry; Computational Chemistry and Modeling; Self-Assembly",
"license": "CC BY NC ND 4.0",
"origin": "C... |
chemrxiv | 60c7442b842e657dcbdb23c4 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic descriptions without omissions or additions."
] | 229 | Macrocycles of Higher ortho-Phenylenes: Assembly and Folding <p>Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships. S... | 高阶邻苯撑大环：组装与折叠
非生物折叠体系统中的高阶结构代表了一个重要但在很大程度上尚未实现的目标。作为应对这一挑战的一种方法，共价组装可用于将折叠体亚单元以明确的空间关系组装成大环。此前已有研究表明，此类系统表现出自我分选、新的折叠构象以及动态立体异构现象，然而关于折叠与大环化之间的相互作用以及结构限制对折叠行为的影响仍存在重要问题。在此，我们探讨了延伸邻苯撑（六聚体和十聚体）与棒状连接体的动态共价组装。通过比较环状与非环状体系中典型的¹H化学位移差异与计算构象库，可以确定大环的折叠状态。我们展示了咬合角作为邻苯撑构象体在形状持久大环内适配度的度量，影响组装过程及最终的折叠行为。对于邻苯撑六聚体，咬合角与构象体稳定性协同作用，引... | {
"id": "60c7442b842e657dcbdb23c4",
"doi": "10.26434/chemrxiv.8085143.v3",
"authors": "Zacharias Kinney; Viraj Kirinda; Scott Hartley",
"categories": "Organic Synthesis and Reactions; Physical Organic Chemistry; Computational Chemistry and Modeling; Self-Assembly",
"license": "CC BY NC ND 4.0",
"origin": "C... |
chemrxiv | 60c7442b842e657dcbdb23c4 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without omissions or additions."
] | 229 | Macrocycles of Higher ortho-Phenylenes: Assembly and Folding <p>Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships. S... | Macrociclos de orto-fenilenos superiores: Ensamblaje y plegamiento
La estructura de orden superior en sistemas de foldámeros abióticos representa un objetivo importante pero en gran medida no realizado. Como un enfoque para este desafío, el ensamblaje covalente puede usarse para ensamblar macrociclos con subunidades f... | {
"id": "60c7442b842e657dcbdb23c4",
"doi": "10.26434/chemrxiv.8085143.v3",
"authors": "Zacharias Kinney; Viraj Kirinda; Scott Hartley",
"categories": "Organic Synthesis and Reactions; Physical Organic Chemistry; Computational Chemistry and Modeling; Self-Assembly",
"license": "CC BY NC ND 4.0",
"origin": "C... |
chemrxiv | 670c523351558a15eff8ead0 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The French translation accurately preserves all chemical terms, mechanisms, and quantitative details from the English source without omissions or additions."
] | 201 | Thermochemical Heterolytic Hydrogenation Catalysis Proceeds Through Polarization-Driven Hydride Transfer Heterolytic hydrogenations, which split H2 across a hydride acceptor and proton acceptor, are a key class of reactions that span the chemical value chain, including CO2 hydrogenation to formate and NADH regeneration... | La catalyse thermochimique de l’hydrogénation hétérolytique progresse par un transfert d’hydrure induit par polarisation
Les hydrogénations hétérolytiques, qui scindent H2 entre un accepteur d’hydrure et un accepteur de proton, constituent une classe clé de réactions couvrant la chaîne de valeur chimique, incluant l’h... | {
"id": "670c523351558a15eff8ead0",
"doi": "10.26434/chemrxiv-2024-3rp1x",
"authors": "Hai-Xu Wang; Yogesh Surendranath",
"categories": "Inorganic Chemistry; Catalysis; Electrochemistry; Heterogeneous Catalysis; Nanocatalysis - Reactions & Mechanisms",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"... |
chemrxiv | 670c523351558a15eff8ead0 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, mechanisms, and quantitative details without omissions or additions."
] | 201 | Thermochemical Heterolytic Hydrogenation Catalysis Proceeds Through Polarization-Driven Hydride Transfer Heterolytic hydrogenations, which split H2 across a hydride acceptor and proton acceptor, are a key class of reactions that span the chemical value chain, including CO2 hydrogenation to formate and NADH regeneration... | Thermochemische heterolytische Hydrierungskatalyse verläuft über polarisationsgetriebene Hydridübertragung
Heterolytische Hydrierungen, bei denen H2 über einen Hydridakzeptor und einen Protonenakzeptor gespalten wird, sind eine wichtige Reaktionsklasse, die die gesamte chemische Wertschöpfungskette umfasst, einschließ... | {
"id": "670c523351558a15eff8ead0",
"doi": "10.26434/chemrxiv-2024-3rp1x",
"authors": "Hai-Xu Wang; Yogesh Surendranath",
"categories": "Inorganic Chemistry; Catalysis; Electrochemistry; Heterogeneous Catalysis; Nanocatalysis - Reactions & Mechanisms",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"... |
chemrxiv | 670c523351558a15eff8ead0 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 3 | [
"Round 1: rejected. The word 'termquímica' is a misspelling of 'termquímica' instead of 'termquímica' (should be 'termquímica' or 'termquímica' corrected to 'termquímica'); The phrase 'para essa classe geral de reações termquímicas' mistranslates 'thermochemical reaction class' as 'reações termquímicas' instead of ... | 201 | Thermochemical Heterolytic Hydrogenation Catalysis Proceeds Through Polarization-Driven Hydride Transfer Heterolytic hydrogenations, which split H2 across a hydride acceptor and proton acceptor, are a key class of reactions that span the chemical value chain, including CO2 hydrogenation to formate and NADH regeneration... | Catálise termoquímica de hidrogenação heterolítica ocorre por meio de transferência de hidreto impulsionada por polarização
As hidrogenações heterolíticas, que dividem H2 entre um aceitador de hidreto e um aceitador de próton, são uma classe fundamental de reações que abrangem a cadeia de valor química, incluindo a hi... | {
"id": "670c523351558a15eff8ead0",
"doi": "10.26434/chemrxiv-2024-3rp1x",
"authors": "Hai-Xu Wang; Yogesh Surendranath",
"categories": "Inorganic Chemistry; Catalysis; Electrochemistry; Heterogeneous Catalysis; Nanocatalysis - Reactions & Mechanisms",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"... |
chemrxiv | 670c523351558a15eff8ead0 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, reaction details, mechanistic descriptions, and quantitative aspects without omission or distortion."
] | 201 | Thermochemical Heterolytic Hydrogenation Catalysis Proceeds Through Polarization-Driven Hydride Transfer Heterolytic hydrogenations, which split H2 across a hydride acceptor and proton acceptor, are a key class of reactions that span the chemical value chain, including CO2 hydrogenation to formate and NADH regeneration... | 热化学异裂氢化催化通过极化驱动的氢化物转移进行
异裂氢化反应将H2分裂为氢化物受体和质子受体，是涵盖化学价值链的重要反应类别，包括CO2氢化生成甲酸盐以及NAD+还原再生NADH。这些反应的异相催化主导机理模型通常采用经典的表面机理，忽略了界面电荷分离的作用。在此，我们量化了催化剂在催化循环过程中的电化学电位，并发现支持该整体热化学反应类别的界面电化学氢化物转移机理的证据。我们发现，质子受体诱导金属催化剂表面的自发电化学极化，从而控制表面M–H中间体的热力学氢化能力，并驱动决定速率的电化学氢化物向氢化物受体底物的转移。总体而言，该模型认为异裂氢化通过两个电化学半反应的耦合进行，即氢还原反应（HRR）和氢氧化反应（HOR），分别将H... | {
"id": "670c523351558a15eff8ead0",
"doi": "10.26434/chemrxiv-2024-3rp1x",
"authors": "Hai-Xu Wang; Yogesh Surendranath",
"categories": "Inorganic Chemistry; Catalysis; Electrochemistry; Heterogeneous Catalysis; Nanocatalysis - Reactions & Mechanisms",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"... |
chemrxiv | 670c523351558a15eff8ead0 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, mechanisms, and quantitative details without adding or omitting information."
] | 201 | Thermochemical Heterolytic Hydrogenation Catalysis Proceeds Through Polarization-Driven Hydride Transfer Heterolytic hydrogenations, which split H2 across a hydride acceptor and proton acceptor, are a key class of reactions that span the chemical value chain, including CO2 hydrogenation to formate and NADH regeneration... | La catálisis termodinámica de la hidrogenación heterolítica procede a través de la transferencia de hidruro impulsada por polarización. Las hidrogenaciones heterolíticas, que dividen H2 entre un aceptor de hidruro y un aceptor de protones, constituyen una clase clave de reacciones que abarcan la cadena de valor química... | {
"id": "670c523351558a15eff8ead0",
"doi": "10.26434/chemrxiv-2024-3rp1x",
"authors": "Hai-Xu Wang; Yogesh Surendranath",
"categories": "Inorganic Chemistry; Catalysis; Electrochemistry; Heterogeneous Catalysis; Nanocatalysis - Reactions & Mechanisms",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"... |
chemrxiv | 60c747459abda24993f8c8a2 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical values, and mechanistic explanations from the source text without omissions or additions."
] | 202 | Controlling the Morphology of Copper-Silica Nanocomposites from Laser Ablation in Liquid <div> <div> <div> <p>Synthesis of copper-silica nanocomposites with controllable morphology and composition were produced with a one-step femtosecond reactive laser ablation in liquid (fs-RLAL) technique. The composite nanomaterial... | Contrôle de la morphologie des nanocomposites cuivre-silice par ablation laser en milieu liquide
La synthèse de nanocomposites cuivre-silice avec une morphologie et une composition contrôlables a été réalisée par une technique d’ablation laser réactive en milieu liquide en une étape utilisant des impulsions femtosecon... | {
"id": "60c747459abda24993f8c8a2",
"doi": "10.26434/chemrxiv.11591973.v1",
"authors": "Mallory John; Katharine Tibbetts",
"categories": "Nanocatalysis - Catalysts & Materials; Nanostructured Materials - Nanoscience",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2020-01-17T00:00:00",
"ur... |
chemrxiv | 60c747459abda24993f8c8a2 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical values, and mechanistic details from the source text without omissions or additions."
] | 202 | Controlling the Morphology of Copper-Silica Nanocomposites from Laser Ablation in Liquid <div> <div> <div> <p>Synthesis of copper-silica nanocomposites with controllable morphology and composition were produced with a one-step femtosecond reactive laser ablation in liquid (fs-RLAL) technique. The composite nanomaterial... | Kontrolle der Morphologie von Kupfer-Siliziumdioxid-Nanokompositen durch Laserablation in Flüssigkeit
Die Synthese von Kupfer-Siliziumdioxid-Nanokompositen mit kontrollierbarer Morphologie und Zusammensetzung wurde mittels einer einstufigen femtosekundenreaktiven Laserablation in Flüssigkeit (fs-RLAL) durchgeführt. Di... | {
"id": "60c747459abda24993f8c8a2",
"doi": "10.26434/chemrxiv.11591973.v1",
"authors": "Mallory John; Katharine Tibbetts",
"categories": "Nanocatalysis - Catalysts & Materials; Nanostructured Materials - Nanoscience",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2020-01-17T00:00:00",
"ur... |
chemrxiv | 60c747459abda24993f8c8a2 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical values, and mechanistic terms from the source text without omissions or additions."
] | 202 | Controlling the Morphology of Copper-Silica Nanocomposites from Laser Ablation in Liquid <div> <div> <div> <p>Synthesis of copper-silica nanocomposites with controllable morphology and composition were produced with a one-step femtosecond reactive laser ablation in liquid (fs-RLAL) technique. The composite nanomaterial... | Controlando a Morfologia de Nanocompósitos de Cobre-Sílica por Ablação a Laser em Líquido
Síntese de nanocompósitos de cobre-sílica com morfologia e composição controláveis foi produzida por meio de uma técnica de ablação a laser reativa em líquido de femtossegundo em uma etapa (fs-RLAL). Os nanomateriais compósitos f... | {
"id": "60c747459abda24993f8c8a2",
"doi": "10.26434/chemrxiv.11591973.v1",
"authors": "Mallory John; Katharine Tibbetts",
"categories": "Nanocatalysis - Catalysts & Materials; Nanostructured Materials - Nanoscience",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2020-01-17T00:00:00",
"ur... |
chemrxiv | 60c747459abda24993f8c8a2 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical values, and mechanistic explanations from the source text without omissions or additions."
] | 202 | Controlling the Morphology of Copper-Silica Nanocomposites from Laser Ablation in Liquid <div> <div> <div> <p>Synthesis of copper-silica nanocomposites with controllable morphology and composition were produced with a one-step femtosecond reactive laser ablation in liquid (fs-RLAL) technique. The composite nanomaterial... | 铜-硅纳米复合材料形貌的控制通过液体中激光烧蚀制备
采用一步法飞秒反应性液体激光烧蚀（fs-RLAL）技术合成了形貌和组成可控的铜-硅纳米复合材料。通过将飞秒近红外激光脉冲聚焦于浸没在铜(II)硝酸盐水溶液中的硅片上制备复合纳米材料，溶液pH值通过硝酸或氢氧化钾调节。在酸性条件下（pH 3.0和5.4），产物主要为硅，铜含量较低（1.4和1.5 wt.%）。这些酸性条件下形成了较大的约30-80 nm硅颗粒，其中部分颗粒为铜核/硅壳结构。相比之下，将溶液pH提高至10.4时，铜负载量极高，达到31.5 wt.%，产物为1.5 nm铜簇分散在无定形硅和铜层硅酸盐基体中。前驱体溶液pH与产物形貌及铜负载量之间的关系归因于硅的零电荷点（... | {
"id": "60c747459abda24993f8c8a2",
"doi": "10.26434/chemrxiv.11591973.v1",
"authors": "Mallory John; Katharine Tibbetts",
"categories": "Nanocatalysis - Catalysts & Materials; Nanostructured Materials - Nanoscience",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2020-01-17T00:00:00",
"ur... |
chemrxiv | 60c747459abda24993f8c8a2 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical values, and mechanistic terms from the source text without omissions or additions."
] | 202 | Controlling the Morphology of Copper-Silica Nanocomposites from Laser Ablation in Liquid <div> <div> <div> <p>Synthesis of copper-silica nanocomposites with controllable morphology and composition were produced with a one-step femtosecond reactive laser ablation in liquid (fs-RLAL) technique. The composite nanomaterial... | Controlando la morfología de nanocompuestos de cobre-sílice mediante ablación láser en líquido
La síntesis de nanocompuestos de cobre-sílice con morfología y composición controlables se produjo mediante una técnica de ablación láser reactiva en líquido de un solo paso con femtosegundos (fs-RLAL). Los nanomateriales co... | {
"id": "60c747459abda24993f8c8a2",
"doi": "10.26434/chemrxiv.11591973.v1",
"authors": "Mallory John; Katharine Tibbetts",
"categories": "Nanocatalysis - Catalysts & Materials; Nanostructured Materials - Nanoscience",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2020-01-17T00:00:00",
"ur... |
chemrxiv | 6725f0315a82cea2facb81e8 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, terms, numerical values, and mechanistic details without omissions or additions."
] | 205 | A Cooperative Model for Metallocene Catalyst Activation by Methylaluminoxane Activation of rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) and sheet models for MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), and (MeAlO)26(Me3Al)9 (26,9) has been studied by DFT. These activators can reversibly form an outer-sphere ion-pair (OSI... | Un modèle coopératif pour l’activation du catalyseur métallocène par le méthylaluminoxane a été étudié par DFT pour l’activation de rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) et des modèles en feuillets pour MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), et (MeAlO)26(Me3Al)9 (26,9). Ces activateurs peuvent former de mani... | {
"id": "6725f0315a82cea2facb81e8",
"doi": "10.26434/chemrxiv-2024-5j3fm",
"authors": "Scott Collins; Mikko Linnolahti",
"categories": "Theoretical and Computational Chemistry; Catalysis; Organometallic Chemistry; Computational Chemistry and Modeling; Homogeneous Catalysis; Polymerization (Organomet.)",
"lice... |
chemrxiv | 6725f0315a82cea2facb81e8 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, numerical data, mechanistic terms, and scientific details without omissions or additions."
] | 205 | A Cooperative Model for Metallocene Catalyst Activation by Methylaluminoxane Activation of rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) and sheet models for MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), and (MeAlO)26(Me3Al)9 (26,9) has been studied by DFT. These activators can reversibly form an outer-sphere ion-pair (OSI... | Ein kooperatives Modell für die Aktivierung von Metallocen-Katalysatoren durch Methylaluminoxan-Aktivierung von rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) und Schichtmodelle für MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5) und (MeAlO)26(Me3Al)9 (26,9) wurde mittels DFT untersucht. Diese Aktivatoren können reversibel ein... | {
"id": "6725f0315a82cea2facb81e8",
"doi": "10.26434/chemrxiv-2024-5j3fm",
"authors": "Scott Collins; Mikko Linnolahti",
"categories": "Theoretical and Computational Chemistry; Catalysis; Organometallic Chemistry; Computational Chemistry and Modeling; Homogeneous Catalysis; Polymerization (Organomet.)",
"lice... |
chemrxiv | 6725f0315a82cea2facb81e8 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, terms, numerical values, and mechanistic details without omissions or additions."
] | 205 | A Cooperative Model for Metallocene Catalyst Activation by Methylaluminoxane Activation of rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) and sheet models for MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), and (MeAlO)26(Me3Al)9 (26,9) has been studied by DFT. These activators can reversibly form an outer-sphere ion-pair (OSI... | Um Modelo Cooperativo para a Ativação de Catalisadores Metallocenos por Metilaluminoxano
A ativação do rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) e modelos em folha para MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5) e (MeAlO)26(Me3Al)9 (26,9) foi estudada por DFT. Esses ativadores podem formar reversivelmente um par iôn... | {
"id": "6725f0315a82cea2facb81e8",
"doi": "10.26434/chemrxiv-2024-5j3fm",
"authors": "Scott Collins; Mikko Linnolahti",
"categories": "Theoretical and Computational Chemistry; Catalysis; Organometallic Chemistry; Computational Chemistry and Modeling; Homogeneous Catalysis; Polymerization (Organomet.)",
"lice... |
chemrxiv | 6725f0315a82cea2facb81e8 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, reaction details, numerical values, and mechanistic terms without omission or addition."
] | 205 | A Cooperative Model for Metallocene Catalyst Activation by Methylaluminoxane Activation of rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) and sheet models for MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), and (MeAlO)26(Me3Al)9 (26,9) has been studied by DFT. These activators can reversibly form an outer-sphere ion-pair (OSI... | 通过DFT研究了甲基铝氧烷（MAO）活化的对映异构体Me2Si(η5-Ind)2ZrMe2（SBIZrMe2）金属茂催化剂的协同活化模型及MAO的片层模型(MeAlO)6(Me3Al)4（6,4）、(MeAlO)7(Me3Al)5（7,5）和(MeAlO)26(Me3Al)9（26,9）。这些活化剂可以可逆地形成外球离子对（OSIP）[SBIZrMe2AlMe2][(MeAlO)n(Me3Al)mMe]3（[n,m]− = [7,4]−和[26,8]−）或由SBIZrMe2形成的接触离子对（CIP）SBIZrMe-μ-Me-6,4（2b）。从3解离Me3Al形成CIP SBIZrMe-μ-Me-n,m（2）通常在甲苯连续介质中不利但... | {
"id": "6725f0315a82cea2facb81e8",
"doi": "10.26434/chemrxiv-2024-5j3fm",
"authors": "Scott Collins; Mikko Linnolahti",
"categories": "Theoretical and Computational Chemistry; Catalysis; Organometallic Chemistry; Computational Chemistry and Modeling; Homogeneous Catalysis; Polymerization (Organomet.)",
"lice... |
chemrxiv | 6725f0315a82cea2facb81e8 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, numerical values, mechanistic terms, and scientific details without omissions or additions."
] | 205 | A Cooperative Model for Metallocene Catalyst Activation by Methylaluminoxane Activation of rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) and sheet models for MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5), and (MeAlO)26(Me3Al)9 (26,9) has been studied by DFT. These activators can reversibly form an outer-sphere ion-pair (OSI... | Un modelo cooperativo para la activación del catalizador metalloceno por metilaluminoxano ha sido estudiado mediante DFT para la activación de rac-Me2Si(η5-Ind)2ZrMe2 (SBIZrMe2) y modelos en hoja para MAO, (MeAlO)6(Me3Al)4 (6,4), (MeAlO)7(Me3Al)5 (7,5) y (MeAlO)26(Me3Al)9 (26,9). Estos activadores pueden formar reversi... | {
"id": "6725f0315a82cea2facb81e8",
"doi": "10.26434/chemrxiv-2024-5j3fm",
"authors": "Scott Collins; Mikko Linnolahti",
"categories": "Theoretical and Computational Chemistry; Catalysis; Organometallic Chemistry; Computational Chemistry and Modeling; Homogeneous Catalysis; Polymerization (Organomet.)",
"lice... |
chemrxiv | 668db4e001103d79c58887d3 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The French translation accurately preserves all chemical formulas, technical terms, numerical values, and scientific details from the English source without omissions or additions."
] | 197 | Theoretical calculation of structural, electronic, magnetic, and thermoelectric properties of KMO2 (M = Sm3+, Tb3+, and Dy3+) oxides by ab initio method. Structural, electronic, optical, thermoelectric and magnetic characteristics of potassium-based rare earth oxides are discussed in this paper. Density-functional theo... | Calcul théorique des propriétés structurales, électroniques, magnétiques et thermoélectriques des oxydes KMO2 (M = Sm3+, Tb3+ et Dy3+) par méthode ab initio. Les caractéristiques structurales, électroniques, optiques, thermoélectriques et magnétiques des oxydes de terres rares à base de potassium sont discutées dans ce... | {
"id": "668db4e001103d79c58887d3",
"doi": "10.26434/chemrxiv-2024-st71n",
"authors": "Khawar Ismail; Ayesha Parveen; Hassan Ali; Asim Ali; Ghulam Murtaza; Sayada Ayesha Zia Bukhari; Muhammad Sohail Abbas",
"categories": "Theoretical and Computational Chemistry; Materials Science; Inorganic Chemistry; Theory -... |
chemrxiv | 668db4e001103d79c58887d3 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, terms, numerical values, and scientific details from the source text without omissions or additions."
] | 197 | Theoretical calculation of structural, electronic, magnetic, and thermoelectric properties of KMO2 (M = Sm3+, Tb3+, and Dy3+) oxides by ab initio method. Structural, electronic, optical, thermoelectric and magnetic characteristics of potassium-based rare earth oxides are discussed in this paper. Density-functional theo... | Theoretische Berechnung der strukturellen, elektronischen, magnetischen und thermoelektrischen Eigenschaften von KMO2 (M = Sm3+, Tb3+ und Dy3+) Oxiden mittels ab initio Methode. In diesem Artikel werden die strukturellen, elektronischen, optischen, thermoelektrischen und magnetischen Eigenschaften von kaliumbasierten S... | {
"id": "668db4e001103d79c58887d3",
"doi": "10.26434/chemrxiv-2024-st71n",
"authors": "Khawar Ismail; Ayesha Parveen; Hassan Ali; Asim Ali; Ghulam Murtaza; Sayada Ayesha Zia Bukhari; Muhammad Sohail Abbas",
"categories": "Theoretical and Computational Chemistry; Materials Science; Inorganic Chemistry; Theory -... |
chemrxiv | 668db4e001103d79c58887d3 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 3 | [
"Round 1: rejected. Mistranslation of 'anti-ferromagnetism' as 'a antiferromagnetismo' instead of 'antiferromagnetismo' (grammatical error affecting meaning); Incorrect phrase 'a aproximação foi realizada' instead of 'foi realizada a aproximação' (word order affects clarity); Omission of 'spin' before 'polarize ban... | 197 | Theoretical calculation of structural, electronic, magnetic, and thermoelectric properties of KMO2 (M = Sm3+, Tb3+, and Dy3+) oxides by ab initio method. Structural, electronic, optical, thermoelectric and magnetic characteristics of potassium-based rare earth oxides are discussed in this paper. Density-functional theo... | Cálculo teórico das propriedades estruturais, eletrônicas, magnéticas e termelétricas dos óxidos KMO2 (M = Sm3+, Tb3+ e Dy3+) pelo método ab initio. Características estruturais, eletrônicas, ópticas, termelétricas e magnéticas dos óxidos de terras raras à base de potássio são discutidas neste artigo. A teoria do funcio... | {
"id": "668db4e001103d79c58887d3",
"doi": "10.26434/chemrxiv-2024-st71n",
"authors": "Khawar Ismail; Ayesha Parveen; Hassan Ali; Asim Ali; Ghulam Murtaza; Sayada Ayesha Zia Bukhari; Muhammad Sohail Abbas",
"categories": "Theoretical and Computational Chemistry; Materials Science; Inorganic Chemistry; Theory -... |
chemrxiv | 668db4e001103d79c58887d3 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical formulas, methods, numerical values, and scientific terms without omissions or additions."
] | 197 | Theoretical calculation of structural, electronic, magnetic, and thermoelectric properties of KMO2 (M = Sm3+, Tb3+, and Dy3+) oxides by ab initio method. Structural, electronic, optical, thermoelectric and magnetic characteristics of potassium-based rare earth oxides are discussed in this paper. Density-functional theo... | KMO2（M = Sm3+、Tb3+ 和 Dy3+）氧化物的结构、电子、磁性及热电性能的第一性原理计算。本文讨论了基于钾的稀土氧化物的结构、电子、光学、热电和磁性特征。采用基于全势线性缀加平面波加局域轨道（FP-LAPW + lo）体系的密度泛函理论（DFT），在Wien2k软件中进行计算；交换-相关能采用PBE + GGA近似。所研究材料的晶体结构为六方晶系，空间群为166_R-3m。因此，体积优化图结果表明，所研究化合物在铁磁态下比反铁磁态和非磁态更具能量稳定性。此外，所研究材料的自旋极化能带结构和态密度（DOS）显示对应自旋通道具有金属和半导体特性。然而，所研究材料表现出半金属性质，在费米能级EF处具有100%的自旋极化。KM... | {
"id": "668db4e001103d79c58887d3",
"doi": "10.26434/chemrxiv-2024-st71n",
"authors": "Khawar Ismail; Ayesha Parveen; Hassan Ali; Asim Ali; Ghulam Murtaza; Sayada Ayesha Zia Bukhari; Muhammad Sohail Abbas",
"categories": "Theoretical and Computational Chemistry; Materials Science; Inorganic Chemistry; Theory -... |
chemrxiv | 668db4e001103d79c58887d3 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 2 | [
"Round 1: rejected. The source states 'half metallic nature' but the translation uses 'naturaleza semimetálica', which is not equivalent.; The phrase 'spin polarize band structure' is mistranslated as 'estructura de bandas polarizada por espín' without clarifying the spin polarization context properly.; The phrase ... | 197 | Theoretical calculation of structural, electronic, magnetic, and thermoelectric properties of KMO2 (M = Sm3+, Tb3+, and Dy3+) oxides by ab initio method. Structural, electronic, optical, thermoelectric and magnetic characteristics of potassium-based rare earth oxides are discussed in this paper. Density-functional theo... | Cálculo teórico de las propiedades estructurales, electrónicas, magnéticas y termoeléctricas de óxidos KMO2 (M = Sm3+, Tb3+ y Dy3+) mediante método ab initio. En este artículo se discuten las características estructurales, electrónicas, ópticas, termoeléctricas y magnéticas de óxidos de tierras raras basados en potasio... | {
"id": "668db4e001103d79c58887d3",
"doi": "10.26434/chemrxiv-2024-st71n",
"authors": "Khawar Ismail; Ayesha Parveen; Hassan Ali; Asim Ali; Ghulam Murtaza; Sayada Ayesha Zia Bukhari; Muhammad Sohail Abbas",
"categories": "Theoretical and Computational Chemistry; Materials Science; Inorganic Chemistry; Theory -... |
chemrxiv | 62439b4a80488216c9fea1ec | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and scientific concepts from the source text without omissions or additions."
] | 241 | Enhancing Li-ion Transport in Solid Electrolytes by Confined Water Developing new oxide solid electrolytes with fast Li-ion transport and high stability is an important step to realize high-performance solid-state Li-ion batteries. Hydrates materials containing confined water widely exist in nature or can be easily syn... | Amélioration du transport des ions Li dans les électrolytes solides par l’eau confinée
Le développement de nouveaux électrolytes solides à base d’oxydes présentant un transport rapide des ions Li et une grande stabilité constitue une étape importante pour réaliser des batteries Li-ion à l’état solide à haute performan... | {
"id": "62439b4a80488216c9fea1ec",
"doi": "10.26434/chemrxiv-2022-jgxc7",
"authors": "Yutong Li; Shitong Wang; Jin Leng; Zunqiu Xiao; Zhongtai Zhang; Tao Gao; Zilong Tang",
"categories": "Materials Science; Nanostructured Materials - Materials",
"license": "CC BY 4.0",
"origin": "CHEMRXIV",
"date": "202... |
chemrxiv | 62439b4a80488216c9fea1ec | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and scientific concepts without omissions or additions."
] | 241 | Enhancing Li-ion Transport in Solid Electrolytes by Confined Water Developing new oxide solid electrolytes with fast Li-ion transport and high stability is an important step to realize high-performance solid-state Li-ion batteries. Hydrates materials containing confined water widely exist in nature or can be easily syn... | Verbesserung des Li-Ionentransports in Festkörperelektrolyten durch eingeschlossenes Wasser
Die Entwicklung neuer Oxid-Festkörperelektrolyte mit schnellem Li-Ionentransport und hoher Stabilität ist ein wichtiger Schritt zur Realisierung leistungsstarker Festkörper-Li-Ionen-Batterien. Hydratmaterialien, die eingeschlos... | {
"id": "62439b4a80488216c9fea1ec",
"doi": "10.26434/chemrxiv-2022-jgxc7",
"authors": "Yutong Li; Shitong Wang; Jin Leng; Zunqiu Xiao; Zhongtai Zhang; Tao Gao; Zilong Tang",
"categories": "Materials Science; Nanostructured Materials - Materials",
"license": "CC BY 4.0",
"origin": "CHEMRXIV",
"date": "202... |
chemrxiv | 62439b4a80488216c9fea1ec | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical data, and scientific meaning without omissions or additions."
] | 241 | Enhancing Li-ion Transport in Solid Electrolytes by Confined Water Developing new oxide solid electrolytes with fast Li-ion transport and high stability is an important step to realize high-performance solid-state Li-ion batteries. Hydrates materials containing confined water widely exist in nature or can be easily syn... | Melhorando o Transporte de Íons de Li em Eletrólitos Sólidos por Meio de Água Confinada
Desenvolver novos eletrólitos sólidos à base de óxidos com transporte rápido de íons de Li e alta estabilidade é um passo importante para viabilizar baterias de íons de Li em estado sólido de alto desempenho. Materiais hidratados c... | {
"id": "62439b4a80488216c9fea1ec",
"doi": "10.26434/chemrxiv-2022-jgxc7",
"authors": "Yutong Li; Shitong Wang; Jin Leng; Zunqiu Xiao; Zhongtai Zhang; Tao Gao; Zilong Tang",
"categories": "Materials Science; Nanostructured Materials - Materials",
"license": "CC BY 4.0",
"origin": "CHEMRXIV",
"date": "202... |
chemrxiv | 62439b4a80488216c9fea1ec | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical details, numerical data, and scientific meanings from the source text without omissions or additions."
] | 241 | Enhancing Li-ion Transport in Solid Electrolytes by Confined Water Developing new oxide solid electrolytes with fast Li-ion transport and high stability is an important step to realize high-performance solid-state Li-ion batteries. Hydrates materials containing confined water widely exist in nature or can be easily syn... | 通过限制水增强固态电解质中的锂离子传输
开发具有快速锂离子传输和高稳定性的新型氧化物固态电解质，是实现高性能固态锂离子电池的重要步骤。含有限制水的水合物材料广泛存在于自然界或可被轻易合成。然而，由于普遍认为水的存在会限制固态电解质的电化学稳定窗口，这类材料作为锂固态电解质的研究甚少。在本工作中，我们以Li-H-Ti-O四元化合物为示例体系，证明了限制水能够增强锂离子传输，同时不损害固态电解质的稳定窗口。合成了三种含有不同量限制水的Li-H-Ti-O四元化合物，并比较了它们的离子电导率和电化学稳定性。含有纳米限制伪水的化合物显示出比无水Li4Ti5O12高2~3个数量级的离子电导率，且具有相似的稳定窗口。以该新化合物作为固态电解质制... | {
"id": "62439b4a80488216c9fea1ec",
"doi": "10.26434/chemrxiv-2022-jgxc7",
"authors": "Yutong Li; Shitong Wang; Jin Leng; Zunqiu Xiao; Zhongtai Zhang; Tao Gao; Zilong Tang",
"categories": "Materials Science; Nanostructured Materials - Materials",
"license": "CC BY 4.0",
"origin": "CHEMRXIV",
"date": "202... |
chemrxiv | 62439b4a80488216c9fea1ec | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and scientific concepts without omissions or additions."
] | 241 | Enhancing Li-ion Transport in Solid Electrolytes by Confined Water Developing new oxide solid electrolytes with fast Li-ion transport and high stability is an important step to realize high-performance solid-state Li-ion batteries. Hydrates materials containing confined water widely exist in nature or can be easily syn... | Mejora del transporte de iones Li en electrolitos sólidos mediante agua confinada
Desarrollar nuevos electrolitos sólidos de óxido con transporte rápido de iones Li y alta estabilidad es un paso importante para lograr baterías de estado sólido de iones Li de alto rendimiento. Los materiales hidratados que contienen ag... | {
"id": "62439b4a80488216c9fea1ec",
"doi": "10.26434/chemrxiv-2022-jgxc7",
"authors": "Yutong Li; Shitong Wang; Jin Leng; Zunqiu Xiao; Zhongtai Zhang; Tao Gao; Zilong Tang",
"categories": "Materials Science; Nanostructured Materials - Materials",
"license": "CC BY 4.0",
"origin": "CHEMRXIV",
"date": "202... |
chemrxiv | 6527fea08bab5d205534456b | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical values, units, and technical details from the source text without omissions or additions."
] | 246 | 200 GHz single chip dynamic nuclear polarization microsystems The single chip integration of the sensitivity relevant part of nuclear magnetic resonance (NMR) [1-17], electron spin resonance (ESR) [18-26], and dynamic nuclear polarization (DNP) enhanced NMR detectors [27] is a promising approach to improve the limit of... | Microsystèmes à polarisation nucléaire dynamique sur puce unique à 200 GHz
L’intégration sur puce unique de la partie sensible pertinente de la résonance magnétique nucléaire (RMN) [1-17], de la résonance de spin électronique (RSE) [18-26] et des détecteurs RMN améliorés par polarisation nucléaire dynamique (PND) [27]... | {
"id": "6527fea08bab5d205534456b",
"doi": "10.26434/chemrxiv-2023-zdk7d",
"authors": "Nergiz Sahin Solmaz; Reza Farsi; Giovanni Boero",
"categories": "Analytical Chemistry; Spectroscopy (Anal. Chem.)",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2023-10-16T00:00:00",
"url": "https://ch... |
chemrxiv | 6527fea08bab5d205534456b | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical values, units, and technical details from the source text without omissions or additions."
] | 246 | 200 GHz single chip dynamic nuclear polarization microsystems The single chip integration of the sensitivity relevant part of nuclear magnetic resonance (NMR) [1-17], electron spin resonance (ESR) [18-26], and dynamic nuclear polarization (DNP) enhanced NMR detectors [27] is a promising approach to improve the limit of... | 200-GHz-Einzelchip-Dynamische-Kernpolarisation-Mikrosysteme
Die Einzelchip-Integration des sensitivitätsrelevanten Teils der Kernspinresonanz (NMR) [1-17], Elektronenspinresonanz (ESR) [18-26] und dynamisch kernpolarisationserhöhter (DNP) NMR-Detektoren [27] ist ein vielversprechender Ansatz zur Verbesserung der Nachw... | {
"id": "6527fea08bab5d205534456b",
"doi": "10.26434/chemrxiv-2023-zdk7d",
"authors": "Nergiz Sahin Solmaz; Reza Farsi; Giovanni Boero",
"categories": "Analytical Chemistry; Spectroscopy (Anal. Chem.)",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2023-10-16T00:00:00",
"url": "https://ch... |
chemrxiv | 6527fea08bab5d205534456b | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 2 | [
"Round 1: rejected. Incorrect translation of 'gyrotron' as 'giroscópio', which changes the meaning from a specific high-power microwave generator to a gyroscope.",
"Round 2: approved. The translation accurately preserves all chemical terms, numerical values, units, and technical details without omissions or addit... | 246 | 200 GHz single chip dynamic nuclear polarization microsystems The single chip integration of the sensitivity relevant part of nuclear magnetic resonance (NMR) [1-17], electron spin resonance (ESR) [18-26], and dynamic nuclear polarization (DNP) enhanced NMR detectors [27] is a promising approach to improve the limit of... | Microssistemas de polarização nuclear dinâmica de chip único a 200 GHz
A integração em chip único da parte relevante para sensibilidade da ressonância magnética nuclear (RMN) [1-17], ressonância de spin eletrônico (RSE) [18-26] e detectores de RMN aprimorados por polarização nuclear dinâmica (PND) [27] é uma abordagem... | {
"id": "6527fea08bab5d205534456b",
"doi": "10.26434/chemrxiv-2023-zdk7d",
"authors": "Nergiz Sahin Solmaz; Reza Farsi; Giovanni Boero",
"categories": "Analytical Chemistry; Spectroscopy (Anal. Chem.)",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2023-10-16T00:00:00",
"url": "https://ch... |
chemrxiv | 6527fea08bab5d205534456b | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical names, numerical values, units, and technical terms without omissions or additions."
] | 246 | 200 GHz single chip dynamic nuclear polarization microsystems The single chip integration of the sensitivity relevant part of nuclear magnetic resonance (NMR) [1-17], electron spin resonance (ESR) [18-26], and dynamic nuclear polarization (DNP) enhanced NMR detectors [27] is a promising approach to improve the limit of... | 200 GHz 单芯片动态核极化微系统
核磁共振（NMR）[1-17]、电子自旋共振（ESR）[18-26] 和动态核极化（DNP）增强核磁共振探测器[27] 中与灵敏度相关部分的单芯片集成，是提高检测限的有前景的方法，尤其适用于纳升级和亚纳升级样品。近期，已展示了工作于 11 GHz（ESR）/16 MHz（NMR）的 DNP 微系统的单芯片集成[27]。本文报道了工作于 200 GHz（ESR）/300 MHz（NMR）的单芯片 DNP 微系统。该单芯片集成微系统包括一个或一组工作于约 200 GHz 的微波振荡器，用于 ESR 激发/检测，以及一个工作于约 300 MHz 并带有频率下变换的射频接收器，用于 NMR 检测。所... | {
"id": "6527fea08bab5d205534456b",
"doi": "10.26434/chemrxiv-2023-zdk7d",
"authors": "Nergiz Sahin Solmaz; Reza Farsi; Giovanni Boero",
"categories": "Analytical Chemistry; Spectroscopy (Anal. Chem.)",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2023-10-16T00:00:00",
"url": "https://ch... |
chemrxiv | 6527fea08bab5d205534456b | English | Spanish | openai-agentic | gpt-4.1-mini | true | 2 | [
"Round 1: rejected. Incorrect translation of 'gyrotron' as 'giroscopio'; Abbreviation ESR translated as REE instead of resonancia de espín electrónico (REE) is acceptable but 'REE' is not a standard abbreviation in Spanish for ESR and should be clarified or kept as ESR; Minor inconsistency in chemical name translat... | 246 | 200 GHz single chip dynamic nuclear polarization microsystems The single chip integration of the sensitivity relevant part of nuclear magnetic resonance (NMR) [1-17], electron spin resonance (ESR) [18-26], and dynamic nuclear polarization (DNP) enhanced NMR detectors [27] is a promising approach to improve the limit of... | Microsistemas de polarización nuclear dinámica de un solo chip a 200 GHz
La integración en un solo chip de la parte relevante para la sensibilidad de la resonancia magnética nuclear (RMN) [1-17], la resonancia de espín electrónico (REE, por sus siglas en inglés ESR) [18-26] y los detectores de RMN mejorados por polari... | {
"id": "6527fea08bab5d205534456b",
"doi": "10.26434/chemrxiv-2023-zdk7d",
"authors": "Nergiz Sahin Solmaz; Reza Farsi; Giovanni Boero",
"categories": "Analytical Chemistry; Spectroscopy (Anal. Chem.)",
"license": "CC BY NC ND 4.0",
"origin": "CHEMRXIV",
"date": "2023-10-16T00:00:00",
"url": "https://ch... |
chemrxiv | 60c75629f96a0021a9288a03 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, domain names, mechanistic details, and quantitative descriptions without omissions or additions."
] | 196 | An Engineered Nonribosomal Peptide Synthetase Shows Opposite Amino Acid Loading and Condensation Specificity <div> <p>Engineering of nonribosomal peptide synthetases (NRPS) has faced numerous obstacles despite being an attractive path towards novel bioactive molecules. Specificity filters in the nonribosomal peptide as... | Une synthétase de peptides non ribosomaux conçue présente une spécificité opposée de chargement des acides aminés et de condensation
L’ingénierie des synthétases de peptides non ribosomaux (NRPS) a rencontré de nombreux obstacles malgré son attrait en tant que voie vers de nouvelles molécules bioactives. Les filtres d... | {
"id": "60c75629f96a0021a9288a03",
"doi": "10.26434/chemrxiv.14199695.v1",
"authors": "Aleksa Stanišić; Annika Hüsken; Philipp Stephan; David L. Niquille; Jochen Reinstein; Hajo Kries",
"categories": "Biochemistry; Bioengineering and Biotechnology; Chemical Biology; Microbiology",
"license": "CC BY NC ND 4.0... |
chemrxiv | 60c75629f96a0021a9288a03 | English | German | openai-agentic | gpt-4.1-mini | true | 2 | [
"Round 1: rejected. Translation of 'deacylating the T-domain' as 'deacetyliert' instead of 'deacylates', which changes the chemical meaning; Use of 'Thiolerungs-' instead of 'Thiolation-' for T-domain, which is a mistranslation of the mechanistic term",
"Round 2: approved. The translation accurately preserves all... | 196 | An Engineered Nonribosomal Peptide Synthetase Shows Opposite Amino Acid Loading and Condensation Specificity <div> <p>Engineering of nonribosomal peptide synthetases (NRPS) has faced numerous obstacles despite being an attractive path towards novel bioactive molecules. Specificity filters in the nonribosomal peptide as... | Ein konstruierter nichtribosomaler Peptidsynthetase zeigt entgegengesetzte Aminosäurebeladungs- und Kondensationsspezifität
Die Entwicklung nichtribosomaler Peptidsynthetasen (NRPS) ist trotz ihres Potenzials zur Erzeugung neuartiger bioaktiver Moleküle mit zahlreichen Hindernissen konfrontiert. Spezifitätsfilter in d... | {
"id": "60c75629f96a0021a9288a03",
"doi": "10.26434/chemrxiv.14199695.v1",
"authors": "Aleksa Stanišić; Annika Hüsken; Philipp Stephan; David L. Niquille; Jochen Reinstein; Hajo Kries",
"categories": "Biochemistry; Bioengineering and Biotechnology; Chemical Biology; Microbiology",
"license": "CC BY NC ND 4.0... |
chemrxiv | 60c75629f96a0021a9288a03 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, domain names, processes, and quantitative descriptions from the source without omissions or additions."
] | 196 | An Engineered Nonribosomal Peptide Synthetase Shows Opposite Amino Acid Loading and Condensation Specificity <div> <p>Engineering of nonribosomal peptide synthetases (NRPS) has faced numerous obstacles despite being an attractive path towards novel bioactive molecules. Specificity filters in the nonribosomal peptide as... | Uma Sintetase de Peptídeo Não Ribossomal Projetada Mostra Especificidade Oposta na Carga e Condensação de Aminoácidos
A engenharia de sintetases de peptídeos não ribossomais (NRPS) enfrentou inúmeros obstáculos, apesar de ser um caminho atraente para moléculas bioativas novas. Filtros de especificidade na linha de mon... | {
"id": "60c75629f96a0021a9288a03",
"doi": "10.26434/chemrxiv.14199695.v1",
"authors": "Aleksa Stanišić; Annika Hüsken; Philipp Stephan; David L. Niquille; Jochen Reinstein; Hajo Kries",
"categories": "Biochemistry; Bioengineering and Biotechnology; Chemical Biology; Microbiology",
"license": "CC BY NC ND 4.0... |
chemrxiv | 60c75629f96a0021a9288a03 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, domain names, processes, and quantitative relationships without adding or omitting information."
] | 196 | An Engineered Nonribosomal Peptide Synthetase Shows Opposite Amino Acid Loading and Condensation Specificity <div> <p>Engineering of nonribosomal peptide synthetases (NRPS) has faced numerous obstacles despite being an attractive path towards novel bioactive molecules. Specificity filters in the nonribosomal peptide as... | 一种工程化非核糖体肽合成酶表现出相反的氨基酸加载和缩合特异性
非核糖体肽合成酶（NRPS）的工程改造尽管是获得新型生物活性分子的有吸引力途径，但面临诸多障碍。非核糖体肽合成线中的特异性筛选决定了工程改造的成功，而腺苷酸化（A-）结构域和缩合（C-）结构域的相对贡献仍存在争议。在工程化的双模NRPS sdV-GrsA/GrsB1中，第一个模块是一个亚结构域交换的嵌合体，表现出底物多样性。针对sdV-GrsA及其进化突变体，我们采用动力学建模研究了底物竞争条件下的产物特异性。我们的模型包含一个步骤，即A结构域对硫酯化（T-）结构域进行酰基化，以及一个缩合步骤对T结构域进行去酰基化。该简化模型与实验确定的酰基化偏好高度一致，并显示缩合特... | {
"id": "60c75629f96a0021a9288a03",
"doi": "10.26434/chemrxiv.14199695.v1",
"authors": "Aleksa Stanišić; Annika Hüsken; Philipp Stephan; David L. Niquille; Jochen Reinstein; Hajo Kries",
"categories": "Biochemistry; Bioengineering and Biotechnology; Chemical Biology; Microbiology",
"license": "CC BY NC ND 4.0... |
chemrxiv | 60c75629f96a0021a9288a03 | English | Spanish | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, domain names, processes, and quantitative details without adding or omitting information."
] | 196 | An Engineered Nonribosomal Peptide Synthetase Shows Opposite Amino Acid Loading and Condensation Specificity <div> <p>Engineering of nonribosomal peptide synthetases (NRPS) has faced numerous obstacles despite being an attractive path towards novel bioactive molecules. Specificity filters in the nonribosomal peptide as... | Una Sintetasa de Péptidos No Ribosómicos Ingenierizada Muestra Especificidad Opuesta en la Carga y Condensación de Aminoácidos
La ingeniería de sintetasa de péptidos no ribosómicos (NRPS) ha enfrentado numerosos obstáculos a pesar de ser una vía atractiva hacia nuevas moléculas bioactivas. Los filtros de especificidad... | {
"id": "60c75629f96a0021a9288a03",
"doi": "10.26434/chemrxiv.14199695.v1",
"authors": "Aleksa Stanišić; Annika Hüsken; Philipp Stephan; David L. Niquille; Jochen Reinstein; Hajo Kries",
"categories": "Biochemistry; Bioengineering and Biotechnology; Chemical Biology; Microbiology",
"license": "CC BY NC ND 4.0... |
chemrxiv | 60c749d1702a9b389818b1c9 | English | French | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The French translation accurately preserves all chemical terms, numerical details, and scientific meanings from the English source without omissions or additions."
] | 228 | Sonocrystallization as an Efficient Way to Control Size, Morphology and Purity of Coordination Compounds Microcrystallites: Application to Single-Chain Magnets <p> Size, morphology and purity control of coordination compounds powders is a key stage for their conversion into materials and devices. In particular, surface... | La sonocristallisation comme méthode efficace pour contrôler la taille, la morphologie et la pureté des microcristallites de composés de coordination : application aux aimants à chaîne unique <p> Le contrôle de la taille, de la morphologie et de la pureté des poudres de composés de coordination est une étape clé pour l... | {
"id": "60c749d1702a9b389818b1c9",
"doi": "10.26434/chemrxiv.12104040.v1",
"authors": "Quentin Evrard; Felix Houard; Carole Daiguebonne; guillaume calvez; yan suffren; olivier guillou; Matteo Mannini; Kevin Bernot",
"categories": "Coordination Chemistry (Inorg.); Lanthanides and Actinides; Magnetism",
"licen... |
chemrxiv | 60c749d1702a9b389818b1c9 | English | German | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without omissions or additions."
] | 228 | Sonocrystallization as an Efficient Way to Control Size, Morphology and Purity of Coordination Compounds Microcrystallites: Application to Single-Chain Magnets <p> Size, morphology and purity control of coordination compounds powders is a key stage for their conversion into materials and devices. In particular, surface... | Sonokristallisation als effizienter Weg zur Kontrolle von Größe, Morphologie und Reinheit von Mikrokristalliten von Koordinationsverbindungen: Anwendung auf Einzelkettenmagneten
Die Kontrolle von Größe, Morphologie und Reinheit von Pulvern aus Koordinationsverbindungen ist eine Schlüsselphase für deren Umwandlung in M... | {
"id": "60c749d1702a9b389818b1c9",
"doi": "10.26434/chemrxiv.12104040.v1",
"authors": "Quentin Evrard; Felix Houard; Carole Daiguebonne; guillaume calvez; yan suffren; olivier guillou; Matteo Mannini; Kevin Bernot",
"categories": "Coordination Chemistry (Inorg.); Lanthanides and Actinides; Magnetism",
"licen... |
chemrxiv | 60c749d1702a9b389818b1c9 | English | Portuguese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without omissions or additions."
] | 228 | Sonocrystallization as an Efficient Way to Control Size, Morphology and Purity of Coordination Compounds Microcrystallites: Application to Single-Chain Magnets <p> Size, morphology and purity control of coordination compounds powders is a key stage for their conversion into materials and devices. In particular, surface... | Sonocristalização como um Método Eficiente para Controlar o Tamanho, Morfologia e Pureza de Microcristais de Compostos de Coordenação: Aplicação a Ímãs de Cadeia Única
O controle do tamanho, morfologia e pureza de pós de compostos de coordenação é uma etapa fundamental para sua conversão em materiais e dispositivos. E... | {
"id": "60c749d1702a9b389818b1c9",
"doi": "10.26434/chemrxiv.12104040.v1",
"authors": "Quentin Evrard; Felix Houard; Carole Daiguebonne; guillaume calvez; yan suffren; olivier guillou; Matteo Mannini; Kevin Bernot",
"categories": "Coordination Chemistry (Inorg.); Lanthanides and Actinides; Magnetism",
"licen... |
chemrxiv | 60c749d1702a9b389818b1c9 | English | Chinese | openai-agentic | gpt-4.1-mini | true | 1 | [
"Round 1: approved. The translation accurately preserves all chemical terms, numerical data, and mechanistic details without omissions or additions."
] | 228 | Sonocrystallization as an Efficient Way to Control Size, Morphology and Purity of Coordination Compounds Microcrystallites: Application to Single-Chain Magnets <p> Size, morphology and purity control of coordination compounds powders is a key stage for their conversion into materials and devices. In particular, surface... | 声致晶化作为控制配位化合物微晶粒尺寸、形貌和纯度的高效方法：单链磁体的应用
配位化合物粉末的尺寸、形貌和纯度控制是其转化为材料和器件的关键步骤。特别是，表面科学技术需要高度纯净的块体材料，且晶粒尺寸分布狭窄，同时要求结晶工艺简便、可扩展且可重复。在本工作中，我们展示了声致晶化，即在结晶过程中施加超声波，能够非常快速地制备出尺寸、形貌和纯度受控的晶粒粉末。我们表明该过程显著降低了晶粒尺寸分布（低多分散指数，PDI）和晶粒长宽比。通过将超声处理样品与多种静态结晶条件下的样品进行比较，我们明确证明晶粒形貌和尺寸分布的改善并非由任何热效应引起，而是由于结晶介质的超声处理。将声致晶化应用于单链磁体（SCM）的结晶批次，保持了SCM的化学完整... | {
"id": "60c749d1702a9b389818b1c9",
"doi": "10.26434/chemrxiv.12104040.v1",
"authors": "Quentin Evrard; Felix Houard; Carole Daiguebonne; guillaume calvez; yan suffren; olivier guillou; Matteo Mannini; Kevin Bernot",
"categories": "Coordination Chemistry (Inorg.); Lanthanides and Actinides; Magnetism",
"licen... |
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