Patent Number: 048204730
Section: claims

1. A method of reducing radioactivity in a nuclear plant by preliminarily forming oxide films on the surfaces of metallic structural members to be in contact with high-temperature and high-pressure reactor water containing radioactive substances before said metallic structural members are exposed to said reactor water, comprising the steps of: subjecting said structural members to a first-step oxidation treatment of heating said structural members in water of a temperature of at least 200.degree. C., and  further subjecting the thus treated structural members to a second-step oxidation treatment of heating said treated structural members in water, of a temperature of at least 200.degree. C., having a higher oxidizing capacity than that of said water in said first-step oxidation treatment, such that in the first-step oxidation treatment a relatively thick and porous oxide film, as compared to the oxide film formed in the second-step oxidation treatment, is formed, and in the second-step oxidation treatment a relatively denser and thinner oxide film than the oxide film obtained in said first-step oxidation treatment is formed, so that adherence of radioactive substances to said metallic structural members is suppresed as compared to adherence of radioactive substances to metallic structural members not having been subjected to both the firstand second-step oxidation treatments.  controlling the oxidizing capacity of pure water to be lower than that of said reactor water,  subjecting said structural members to a first-step oxidation treatment of heating by circulation of pure water of a temperature of at least 200.degree. C., the pure water being the pure water having the oxidizing capacity controlled to be lower than that of the reactor water,  further controlling the controlled pure water to have a higher oxidizing capacity than that of said reactor water, and  further subjecting the thus treated structural members to a second-step oxidation treatment of heating by circulation of the further controlled pure water, of a temperature of at least 200.degree. C., further controlled to have the higher oxidizing capacity than that of said reactor water, such that in the first-step oxidation treatment a relatively thick and porous oxide film, as compared to the oxide film formed in the second-step oxidation treatment, is formed, and in the second-step oxidation treatment a relatively denser and thinner oxide film than the oxide film obtained in said first-step oxidation treatment is formed.  subjecting feed water heater tubes to a first-step oxidation treatment of heating by circulating pure water of a temperature, of at least 200.degree. C., having a lower oxidizing capacity than that of reactor water passed through the heater tubes during operation of the nuclear plant for nuclear heating, and  further subjecting the thus treated heater tubes to a second-step oxidation treatment of heating by circulating pure water of a temperature, of at least 200.degree. having a higher oxidizing capacity than that of said reactor water, such that in the first-step oxidation treatment a relatively thick and porous oxide film, as compared to the oxide film formed in the second-step oxidation treatment, is formed, and in the second-step oxidation treatment a relatively denser and thinner oxide film than the oxide film obtained in said first-step oxidation treatment is formed,  said first- and second-step oxidation treatments being conducted before start of the nuclear heating in the nuclear plant which generates electric power by rotating a generator with a turbine driven by steam generated in a reactor.  preparing reactor water, to be used in the nuclear plant, the reactor water being substantially free from radioactive substances;  effecting a first control of the dissolved oxygen concentration of said reactor water so as to be less in its oxidizing capacity than that of the reactor water used in the nuclear plant;  subjecting said structural members to a first-step oxidation treatment of heating said structural members in contact with said reactor water controlled in said first control of the dissolved oxygen concentration at 200.degree. C. or higher for a predetermined period of time, thereby to provide thick and porous oxide films on the surfaces of the structural members;  effecting a second control of the dissolved oxygen concentration of said reactor water so as to be higher in the oxidizing capacity than that of the reactor water used in the nuclear plant;  further subjecting said structural members treated in said first-step oxidation treatment to a second-step oxidation treatment of heating said treated structural members in contact with said reactor water controlled in said second control of the dissolved oxygen concentration at 200.degree. C. or higher for a predetermined period of time, thereby to make said oxide films into thick and dense oxide films; and then  operating the nuclear plant to produce electric power. 2. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein said firststep oxidation treatment is conducted with pure water of a temperature of at least 200.degree. C., having a dissolved oxygen concentration of lower than 200 ppb. 3. A method of reducing radioactivity in a nuclear plant as claimed in claim 3, wherein said pure water in said first-step oxidation treatment has a dissolved oxygen concentration of 40 to 100 ppb. 4. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein said water in said first-step oxidation treatment is pure water of a temperature of at least 200.degree. C., containing one or more members selected from the group consisting of hydrazine and salts of organic acids. 5. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein said second-step oxidation treatment is conducted with pure water of a temperature of at least 200.degree. C., having a dissolved oxygen concentration of higher than 200 ppb. 6. A method of reducing radioactivity in a nuclear plant as claimed in claim 5, wherein said pure water in said second-step oxidation treatment has a dissolved oxygen concentration of 300 to 1,000 ppb. 7. A method of reducing radioactivity in a nuclear plant as claimed in claim 4, wherein said second-step oxidation treatment is conducted with pure water of a temperature of at least 200.degree. C. containing one or more members selected from the group consisting of hydrogen peroxide, chromates, and permanganates. 8. A method of reducing radioactivity in a nuclear plant as claimed in claim 7, wherein said pure water is weakly alkaline with a pH of 8 to 10. 9. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein said metallic structural members are made of steel. 10. A method of reducing radioactivity in a nuclear plant as claimed in claim 9, wherein said structural members are subjected to said first-step oxidation treatment so as to form an iron oxide film, and are subjected to said second-step oxidation treatment so as to form an iron oxide film denser and thinner than the iron oxide film formed in the first-step oxidation treatment. 11. A method of reducing radioactivity in a nuclear plant as claimed in claim 13, wherein the steel structural members are made of steel selected from the group consisting of carbon steel and stainless steel. 12. A method of reducing radioactivity in a nuclear plant as claimed in claim 11, wherein said structural members are subjected to said first-step oxidation treatment so as to form an iron oxide film, and are subjected to said second-step oxidation treatment so as to form an iron oxide film denser and thinner than the iron oxide film formed in the first-step oxidation treatment. 13. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein said reactor water has an oxidizing capacity, wherein the environment of a temperature of at least 200.degree. C. to which the structural members are subjected during the first-step oxidation treatment is water having a lower oxidizing capacity than that of said reactor water, and wherein the environment of the second-step oxidation treatment is water having a higher oxidizing capacity than that of said reactor water. 14. A method of reducing radioactivity in a nuclear plant as claimed in claim 1, wherein the thickness of the oxide film formed in the first-step oxidation treatment is 0.5 to 3 .mu.m, and the thickness of the denser oxide film formed in the second-step oxidation treatment is 0.05 to 0.5 .mu.m. 15. A method of reducing radioactivity in a nuclear plant as claimed in claim 2, wherein said second-step oxidation treatment is conducted with pure water of a temperature of at least 200.degree. C., having a dissolved oxygen concentration of higher than 200 ppb. 16. A method of reducing radioactivity in a nuclear plant by forming oxide films on the surfaces of metallic structural members which constitute a nuclear power plant which generates electric power by rotating a generator with a turbine driven by steam generated in a reactor, the oxide films being formed by circulating pure water of a temperature of at least 200.degree. C. from a pressure vessel of the reactor through a recycling system and partially through a reactor water purification system to said pressure vessel before said structural members are exposed to reactor water containing radioactive substances, said reactor water having an oxidizing capacity, comprising the steps of: 17. A method of reducing radioactivity in a nuclear plant as claimed in claim 16, wherein said metallic structural members are made of steel. 18. A method of reducing radioactivity in a nuclear plant as claimed in claim 17, wherein the steel structural members are made of steel selected from the group consisting of carbon steel and stainless steel. 19. A method of reducing radioactivity in a nuclear plant comprising the steps of: 20. A method of reducing radioactivity in a nuclear plant as claimed in claim 19, wherein said feed water heater tubes are made of steel. 21. A method of reducing radioactivity in a nuclear plant as claimed in claim 20, wherein the steel feed water heater tubes are made of steel selected from the group consisting of carbon steel and stainless steel. 22. A method of reducing radioactivity in a nuclear plant by forming oxide films on the surfaces of structural members made of steel to be in contact with high-temperature and high-pressure reactor water, comprising the steps of: 23. A method of reducing radioactivity in a nuclear plant as claimed in claim 22, wherein, in the first and second control steps, the dissolved oxygen concentrations are controlled to be 50 to 100 ppb and 300 to 1,000 ppb, respectively. 24. A method of reducing radioactivity in a nuclear plant as claimed in claim 23, wherein said first- and second-step oxidation treatments each are conducted for 100 to 500 hours. 25. A method of reducing radioactivity in a nuclear plant as claimed in claim 22, wherein the steel structural members are made of steel selected from the group consisting of carbon steel and stainless steel.