Patent Number: 044302568
Section: claims

1. A nuclear waste package comprising any material containing a radionuclide and a surrounding overpack or backfill containing a non-radioactive compound of the element or analogue of the element of the radionuclide or a natural or synthetic mineral containing an actinide which provides a greater concentration of ions of the non-radioactive elements than are provided by the radionuclides. 2. A nuclear waste package according to claim 1 wherein the radionuclide comprises Cs, Sr, I, Tc, or actinide element and the overpack or backfill contains a non-radioactive element which is Cs, Sr, I, Mn, or lanthanide element. 3. A nuclear waste package according to claim 2 wherein the radionuclide comprises radioactive Cs and the non-radioactive element comprises Cs. 4. A nuclear waste package according to claim 2 wherein the radionuclide comprises radioactive Sr and the non-radioactive element comprises Sr. 5. A nuclear waste package according to claim 2 wherein the radionuclide comprises a radioactive actinide element and the non-radioactive element comprises a lanthanide element. 6. A nuclear waste package according to claim 1 wherein there is employed in the overpack or backfill a form of the non-radioactive element or actinide which is only slightly more soluble than the radioactive waste form of the element in the repository fluid. 7. A nuclear waste package according to claim 6 wherein the radionuclide comprises Cs, Sr, I, Tc, or actinide element and the overpack or backfill contains a non-radioactive element which is Cs, Sr, I, Mn, or lanthanide element. 8. A nuclear waste package according to claim 7 wherein the overpack or backfill material comprises a mineral or ceramic material containing said non-radioactive element or actinide in the form of a compound. 9. A nuclear waste package according to claim 8 wherein the radioactive element is Cs and the overpack or backfill contains the non-radioactive element in the form of a compound of Cs with at least one of Al.sub.2 O.sub.3, SiO.sub.2, P.sub.2 O.sub.5, and TiO.sub.2. 10. A nuclear waste package according to claim 8 wherein the radioactive element is Sr and the overpack or backfill contains the non-radioactive element in the form of a compound of Sr with at least one of Al.sub.2 O.sub.3, SiO.sub.2, and P.sub.2 O.sub.5. 11. A nuclear waste package according to claim 8 wherein the radioactive element is an actinide with the overpack or backfill contains a non-radioactive element which is a lanthanide element in the form of a lanthanide oxide or compound of a lanthanide oxide with at least one of Al.sub.2 O.sub.3, SiO.sub.2, and P.sub.2 O.sub.5. 12. A nuclear waste package according to claim 1 wherein the overpack or backfill is present as a tamped in mineral containing ion-dopant of the non-radioactive element. 13. A nuclear waste package according to claim 1 wherein the overpack or backfill is present as ceramic briquettes of containing ion-dopant of the non-radioactive element or actinide containing mineral surrounding an inner layer of overpack or backfill. 14. A nuclear waste package according to claim 13 containing additional overpack or backfill outside the briquettes. 15. A nuclear waste package according to claim 1 wherein the non-radioactive element or actinide containing mineral is present in various ion concentrations dispersed through the overpack or backfill. 16. A nuclear waste package according to claim 2 having a reverse thermodynamic chemical gradient of non-radioactive Cs, Sr, lanthanide, I, or Mn in an amount between 0.1 and 100.times. the total contained amount of the ion contained in the waste form in an insoluble overpack or backfill material. 17. A package according to claim 16 wherein the non-radioactive concentration is over 1.times.. 18. A process for constructing a reverse thermodynamic barrier comprising surrounding the nuclear waste form of claim 1 in a repository with a mineral overpack or backfill containing the non-radioactive element or actinide containing mineral in compound form. 19. A process according to claim 18 comprising tamping in a mixture of the mineral and an ion-dopant of the non-radioactive element or actinide mineral around the nuclear waste package. 20. A process according to claim 18 comprising surrounding a layer of overpack with ceramic briquettes ion-doped with a compound of the non-radioactive element. 21. A process according to claim 20 including the step of placing additional overpack or backfill around the briquettes. 22. A process according to claim 1 wherein the overpack or backfill contains 0.1 to 100.times. the total amount of ion contained in the radioactive waste form.