Patent Number: 
Section: claims

1. An X-ray fluorescence analyzer comprising:an X-ray source;an irradiation area restricting member that restricts an area of a measurement sample to be irradiated with an X ray emitted as a primary X-ray from the X-ray source;a detector that detects a secondary X-ray generated from the measurement sample;a calibration sample for calibrating a device including the X-ray source, the irradiation area restricting member, and the detector;a sample stage on which the measurement sample is mounted, the sample stage arranging the measurement sample at a position in which a surface of the measurement sample faces the irradiation area restricting member with a predetermined distance from the irradiation area restricting member on an irradiation axis of the primary X-ray; anda calibration sample moving mechanism including holding the calibration sample at a retraction position which is an arbitrary position deviated from a route of the primary X-ray and a spatial position during sample measurement, and moving the calibration sample from the retraction position to a same irradiation position of the measurement sample having a same predetermined irradiation distance by the primary X-ray which separates the measurement sample from the irradiation area restricting member, wherein the calibration sample moving mechanism being configured to be independent from the sample stage. 2. The X-ray fluorescence analyzer according to claim 1 further comprising:a controller that controls the X-ray source, the detector, and the calibration sample moving mechanism; andan automatic device calibrator that operates the calibration sample moving mechanism to move the calibration sample to the spatial position that is same with the primary X-ray irradiation position of the measurement sample, and operates the detector to detect a secondary X-ray which is generated by irradiating the calibration sample with the X ray emitted from the irradiation area restricting member, and automatically calibrates the device based on a result of detection f the secondary X-ray. 3. The X-ray fluorescence analyzer according to claim 2,wherein the sample stage is provided with a sample stage moving mechanism that moves in at least one direction of a three-dimensional directions of X, Y, and Z directions, andwherein the controller controls the sample stage moving mechanism to retract the measurement sample to a position where the calibration sample does not interfere with the measurement sample before operating the calibration sample moving mechanism. 4. The X-ray fluorescence analyzer according to claim 1, wherein: the irradiation area restricting member is provided with a collimator. 5. The X-ray fluorescence analyzer according to claim 1, wherein the irradiation area restricting member is provided with a poly-capillary. 6. The X-ray fluorescence analyzer according to claim 1, wherein the irradiation area restricting member is provided with a mono-capillary. 7. An X-ray fluorescence analyzer having a measurement device, comprising:an X-ray source that irradiates X-ray;an irradiation area restricting member that restricts an area of a measurement sample to be irradiated with the X-ray as a primary X-ray; anda detector that detects a secondary X-ray generated from the measurement sample by being irradiated with the primary X-ray;a sample stage that holds and moves the measurement sample between a measurement position at which the measurement sample is irradiated with the primary X-ray and a first retracted position at which the measurement sample is retracted away from the measurement position during calibration; anda calibration sample moving mechanism that holds a calibration sample at a second retraction position which is an arbitrary position retracted from the measurement position during sample measurement, such that during calibration, the calibration sample is moved from the second retraction position to a same irradiation position of the measurement sample having a same predetermined irradiation distance by the primary X-ray which separates the measurement sample from the irradiation area restricting member.