Patent Number: 052606210
Section: description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT A preferred embodiment of the present invention is shown in FIG. 1 as comprising a stack 22 of alternate emitting nuclide and semiconductor-junction strata, an inner heavy metal shield 24 that absorbs nuclear radiation escaping from stack 22, an intermediate high thermal impedance housing 26 that retards heat transfer from within stack 22, and an external metal casing 28 that snugly receives housing 26. The electrical output of stack 22 is established across a positive terminal 30 and a negative terminal 32. Negative terminal 32 connects electrically to metal casing 28. Positive terminal 30 projects through an opening in an electrically insulating cap 33 at the top of casing 28. As shown in FIG. 2, stack 22 is characterized by a sequence of say ten power cells of the type shown in FIGS. 2 and 3. Each power cell includes a pair of semiconductor-junction strata 34 between which is sandwiched a radionuclide emitter stratum 36. Each semiconductor-junction stratum typically ranges in thickness from 1 to 250 microns. At the lower end of this range, the semi-conductor junction stratum, in one form, is deposited on a substrate composed, for example, of silicon. Each emitter stratum typically ranges in thickness from 0.1 to 5 microns. The upper thickness limit is determined by undue self-absorption of emitted particles. Each semiconductor-junction stratum has an electrically positive face region 38 and an electrically negative face region 40. Positive face region 38 is established by subjection to a p-dopant selected, for example, from the class consisting of zinc and cadmium. Negative face region 40 is established by subjection to an n-dopant selected, for example, from the class consisting of silicon and sulfur. A lead 42 from positive face region 38 and a lead 44 from negative face region 40 connect into the remainder of the electrical system. In one form, emitter strata 36 produce alpha particles characterized by a monoenergetic level in excess of 4.5 MeV and ranging upwardly to about 6.5 MeV and ordinarily 5 to 6.1 MeV. In another form, emitter strata 36 produce beta particles having a maximum energy level in excess of 0.01 MeV and ranging upwardly to about 3.0 MeV. Typical compositions of emitter strata 36 are selected from the class consisting of the isotopes listed in the following table, in which E.sub.max refers to maximum energy, E.sub.avg to average energy, and T.sub.1/2 to half life: ______________________________________ Type of Maximum Half Emitter Energy Life Isotope (Mev) (Mev) Years ______________________________________ H.sup.3 .beta. 0.018 12.3 Ni.sup.63 .beta. 0.067 92.0 Sr.sup.30 /Y.sup.90 .beta. 0.545/ 27.7 2.26 Pm.sup.147 .beta. 0.230 2.62 Tl.sup.204 .beta. 0.765 3.75 Kr.sup.85 .beta. 0.670 10.9 Pu.sup.238 .alpha. 5.50 66.4 Cm.sup.242 .alpha. 6.10 0.45 Cm.sup.244 .alpha. 5.80 18.0 Po.sup.210 .alpha. 5.30 .38 ______________________________________ Preferably, voltaic-junctions strata 34 are inorganic semiconductors which are binary, ternary and/or quarternary compounds of Group III and Group V elements of the Periodic Table. Preferred Group III elements are selected form the class consisting of boron, aluminum, gallium and indium. Preferred Group V elements are selected from the class consisting of phosphorous, arsenic and antimony. These compounds are typified by the class consisting of AlGaAs, GaAsP, AlInP, InAlAs, AlAsSb, AlGaInP, AlGaInAs, AlGaAsSb, InGaAs, GaAsSb, InAsP, AlGaSb, AlInSb, InGaAsP, AlGaAsSb and AlGaInSb. Equivalent circuits of various embodiments of the battery of FIGS. 1 to 3 are shown in FIGS. 4 to 7. These embodiments are illustrated as schematics in which various series and parallel combinations achieve a range of output currents and voltages. In FIG. 4, a plurality of cells 50 are arranged in parallel to produce relatively high current. In FIG. 5, a plurality of cells 52 are arranged in series to produce relatively high voltage. FIG. 7 shows a plurality of parallel strings of cells 54, each string having a plurality of cells in series. FIG. 8 shows a plurality of submodules 56 in series, each submodule having a plurality of cells in parallel. EXAMPLE The present invention is specifically illustrated by a configuration of the cell of FIGS. 1, 2 and 3 in which voltaic junction 34 is an indium phosphide stratum, opposite face regions of which are implanted with (1) zinc ions to establish a p-region and (2) silicon ions to establish an n-region. Each voltaic-junction stratum is approximately 150 microns thick. In one version of this example, emitter stratum is composed of Pu-238. In another version of this example, the emitter stratum is composed of Sr-90. Each emitter stratum is approximately 1.5 microns in thickness. Radiation shielding enclosure 24 is composed of tantalum. Thermal insulating enclosure 26 is composed of ceramic. The thickness and composition of insulating enclosure 26 is selected to maintain the temperature of stack 22 at 50.degree. C. in an environment where the temperature is no greater than approximately 20.degree. C., i.e. (1) for space applications in which the cell is shielded from heating by solar radiation, or (2) no greater than 35.degree. C., i.e., for terrestrial applications in which the cell operates at room or body temperature. The indium phosphide anneals most of its radiation damage at temperatures below 100.degree. C. OPERATION AND CONCLUSIONS The present invention contemplates semiconductors with three unique features (1) relatively high radiation resistance, (2) continued photovoltaic function at elevated temperatures, and (3) real time annealing of radiation damage in the same temperature range. These features support a high energy density radio-nuclide battery operating with relatively high energy beta and/or alpha particle sources. The design of these batteries takes into consideration the rapidity of annealing of radiation damage in InP when irradiated at 100.degree. C., continued operation during annealing, and tolerance of different intensities of alpha and beta radiation for different applications. Annealing at elevated temperature supports a large dose rate with minimal degradation in power output. These properties make it possible to consider a much wider range of radioisotopes than has been possible with silicon betavoltaic cells. Since most previously developed silicon-based beta voltaic cells have used Pm-147, this nuclide serves as a good basis for comparison of prior art batteries with batteries of the present invention. Pm-147 emits beta particles with a peak energy of 0.23 MeV, average energy of 0.063 MeV, and half-life of 2.62 years. Promethium cells generally provide a maximum power of 1000 .mu.W/cm.sup.3 which drops to 266 .mu.W/cm.sup.3 after 5 years. At least 1.5 Ci/cm.sup.2 has been required to produce 50 .mu.W/cm.sup.2. To illustrate the advantage provided by InP, the Pm-147 silicon cell is compared below in Table 2 with other beta isotopes and an alpha emitter. In Table 2, T refers to half-life, E.sub.max refers to maximum energy, Ci/cm.sup.2 refers to curies per square centimeter, BOL refers to "Beginning Of Life", EOL refers to "End Of Life", W refers to watts and h refers to hours. ______________________________________ Output (5 years) T.sub.1/2 E.sub.max Activity BOL EOL Total Isotope Years MeV Ci/cm.sup.2 W/cm.sup.3 W/cm.sup.3 W-h/cm.sup.3 ______________________________________ Pm-147 2.62 0.230 1.50 1000 266 24.3 Tl-204 3.75 0.765 1.05 672 266 19.2 Sr-90 27.7 0.545 0.19 301 266 13.3 Pu-238 86.4 5.5 0.004 276 266 11.9 ______________________________________ The activity level for each of the above isotopes was adjusted to give the same End Of Life power density as Pm-147. This means that the longer lived isotopes require a much smaller activity level to achieve the same End Of Life power level. We note that total energy output of the Pu-238 powered cell at the end of twenty years is calculated to be 44.7 W-h/cm.sup.3 and its power density 235 W-h/cm.sup.3. After 20 years, the Pm-147 cell is calculated to generate just 33.0 W-h/cm.sup.2 and its power density is calculated to be 5.04 .mu.Wcm.sup.3. Another method of comparison is by lifetimes, assuming that the same average power is produced. Table 3 below compares the power output half-life for four cases, all starting at 1 mW/cm.sup.3 and generating an average power of 722 .mu.W/cm.sup.3. ______________________________________ Best Chemical Batteries Hg-Zn (chemical battery) 1 Month 0.55 W-h/cm.sup.3 Best Betavoltaic - Si Pm.sup.147 -Si 16.6 W-h/cm.sup.3 2.6 Years InP at Room Temp (No Anneal) Sr.sup.90 /Y.sup.90 -InP 182 W-h/cm.sup.3 28 Years InP with Anneal Pu.sup.238 -InP 544 W-H/cm.sup.3 86 Years ______________________________________ It is to be noted that even without annealing, the higher energy output of Sr-90 is far superior to previous configurations based on Si junctions, even ignoring emissions of the daughter nuclide, Y-90, which would also contribute. Annealing during operation allows an alpha source, such as Pu-238, to provide enormous operating times. The present invention anticipates that a nuclide with an extended alpha emitting decay chain (Ra-226) actually may increase power output as it ages. It is coincidence in this comparison, that the long lived materials actually use less radioactive material, in curies (Ci) or becquerel (Bq), than Pm-147. The number of curies required to provide a given power level is directly related to lifetime and inversely related to average energy of the emitted particles. Thus: for Pm-147, the activity is 1.5 Ci/cm.sup.2 ; PA1 for Sr-90, the activity is 0.63 Ci/cm.sup.2 ; and PA1 for Pu-238, the activity is 0.017 Ci/cm.sup.2. It is found that damage effectiveness of electrons drops rapidly with energy below 1 MeV and, for a pure Sr-90 beta spectrum, is estimated to be 1.2% of that for 1 MeV electrons. Tests have established that 10.sup.16 /cm.sup.2 of 1 MeV electrons drop InP cell efficiency to 80% of its initial value at room temperature. Considering the spread of energies in a Sr-90 beta spectrum, there is a requirement for an exposure of 10.sup.18 Sr-90 beta particles to produce the same effect as a 1 MeV electron beam. For 0.667 curies/cm.sup.2 of Sr-90 and again neglecting the daughter emissions, approximately 2.47.times.10.sup.10 electrons/cm.sup.2 /sec penetrate one face of the InP stratum. Since activity is sandwiched between two cells, actual curies/cm.sup.2 is 1.33 Ci from which 2.47.times.10 .sup.10 /sec follows. Exposure time required to reach a fluence of 10.sup.18 is estimated at 4.05.times.10.sup.7 seconds, 1.125.times.10.sup.4 hours, or 1.28 years. An electron beam of 10 .mu.A/cm.sup.2 delivers a fluence of 10.sup.16 /cm.sup.2 in 2.67 minutes so that test irradiation takes no longer than an hour. Efficiency of isotope powered cells is the fraction of particle energy converted to electrical energy. For Pm-147 powered silicon cells, it has been found that 5.55.times.10.sup.10 beta particles per square centimeter per second yielded a power output of 25 .mu.W/cm.sup.2. For Pm-147 beta particles with an average energy of 0.0625 MeV the input power is 555 .mu.W/cm.sup.2. The total efficiency achieved in this case is 4.5%. The theoretical efficiency achievable has been calculated as greater than 10%. High energy particles, such as alpha particles from Pu-238, will displace atoms from their normal bound positions in a crystalline semiconductor, such as indium phosphide. The number of atoms displaced depends upon the energy and mass of the incident particle, the mass of the target atoms, and the minimum energy required to remove it from its bound lattice position. A displaced atom can have considerable recoil energy immediately after being struck by the incident particles. The excess energy is dissipated by ionizing and displacing adjacent atoms in the crystal lattice until the primary recoil energy has dropped to thermal energies (0.025 eV at room temperature). The end result is a number of vacant lattice sites (vacancies) and displaced atoms in interstitual positions in the lattice (interstitials). At room temperature (300.degree. K.) the vacancies and interstitials are mobile, and diffuse through the crystal lattice until they interact with other defects or lattice impurities, or reach the surface, or annihilate. Many of the complex defects that result from these interactions are stable at room temperature and introduce energy levels throughout the forbidden gap of the semiconductor. The defect energy levels can reduce the lifetime of minority carriers, the majority carrier concentration, and the mobility of the majority carriers. All of these properties have a major impact on the operation of a device such as a solar cell. Each semiconductor material exposed to the same radiation develops a spectrum of radiation defects that are unique to that material. In addition, for a given material, the spectrum of defects observed is a strong function of the temperature at which the material is irradiated. At sufficiently low temperatures, the primary vacancies and interstitials can be "frozen in", and the changes in semiconductor properties associated with them studied as the semiconductor is warmed to room temperature and above. At sufficiently high temperatures, the material can be restored to its original state. Note that in semiconductors such as silicon the temperature required to restore the original properties is so high that it would destroy any device composed of the material. At such a temperature, impurities deliberately implanted in certain regions of the device to form p-n junctions diffuse throughout the material, and metal contacts are destroyed, thereby rendering the device useless. In accordance with the present invention, III-V compounds like indium phosphide are unique in that a large fraction of the radiation induced defects anneal at fairly low temperatures, in the case of indium phosphide, below 100.degree. C. The integrity of such devices therefore are maintained. The major factor governing the ability of a material to anneal damage is traceable to the stability of the complex defects formed under irradiation. Whether a semiconductor will anneal radiation induced damage at low temperatures or not has to be determined by experiment. No single property or combination of properties has been identified as being responsible for such behavior. In the case of indium phosphide, experiments have shown that the net defect density introduced by energetic particles is much less than in the case of common semiconductors such as silicon and gallium arsenide. The latter semiconductors, when irradiated at room temperature, form defects which are stable and which markedly affect their properties. Semiconductors that exhibit annealing behavior at particular temperatures can be determined only by experiment. Factors such as energy gap, threshold energy for displacement, diffusion coefficient, and defect mobility are not sufficient to identify a likely material.