Patent Number: 
Section: claims

1. A process for immobilizing metallic sodium in glass form, comprising the steps of:(A) introducing the following constituents, (i), (ii) and (iii) into a reactor:(i) a vitrified matrix precursor,(ii) sodium in the metallic state, and(iii) iron oxide Fe2O3, in an amount sufficient to ensure oxidation of the metallic sodium (ii) introduced, said constituents (i), (ii) and (iii) being introduced into the reactor in a dispersed form;(B) producing, by bringing constituents (i), (ii) and (iii) in dispersed form into contact with each other within the reactor, a homogeneous mixture of these constituents;(C) heating the mixture obtained to a temperature of between 1000 and 1600° C., whereby a homogeneous mixture in the molten state is formed, in which the sodium initially introduced is in the sodium oxide state; and(D) recovering the molten mixture thus obtained and cooling it, whereby a vitrified matrix of homogeneous composition is obtained that incorporates the initially introduced sodium as constituent oxide of the said vitrified matrix. 2. The process of claim 1, wherein the metallic sodium employed contains radioactive elements. 3. The process of claim 1, wherein the vitrified matrix precursor (i) includes solid particles, said particles containing at least one oxide selected from the group consisting of:silicon oxide SiO2;calcium oxide CaO and boron oxide B2O3. 4. The process of claim 3, wherein the particles present in the vitrified matrix precursor have a mean size of between 0.1 and 20 millimeters. 5. The process of claim 1, wherein the metallic sodium employed is introduced into the reactor in the form of liquid droplets. 6. The process of claim 1, wherein the metallic sodium employed is introduced in the form of sodium deposited on all or a part of the particles of present in vitrified matrix precursor. 7. The process of claim 1, wherein the mass of metallic sodium introduced is between 3% and 20% by mass with respect to the mass of vitrified matrix precursor which is introduced. 8. The process of claim 1, wherein the iron oxide Fe2O3 is introduced in the form of particles comprising iron oxide Fe2O3 and having a mean size of between 0.1 and 20 millimeters. 9. The process of claim 1, wherein the molar ratio of the amount of iron introduced in the form of iron oxide Fe2O3 to the amount of sodium introduced is between 0.5/1 and 3/1. 10. The process of claim 1, wherein the mass of Fe2O3 introduced is between 5% and 50% by mass with respect to the mass of vitrified matrix precursor introduced. 11. The process of claim 1, wherein the operation of producing the homogeneous mixture in step (B) is carried out by introducing the vitrified matrix precursor and the iron oxide into the reactor in the form of a rain of particles and by spraying the sodium in the liquid state into the said rain of particles. 12. The process of claim 1, wherein the homogeneous mixture produced during step (B) is heated to a temperature of between 150° C. and 400° C. prior to the heat treatment of step (C). 13. The process of claim 1, wherein step (C) is carried out by means of induction heating. 14. The process of claim 1, wherein the said process is a process carried out continuously. 15. The process of claim 14, wherein the ratio of the mass flow rate of metallic sodium introduced to the mass flow rate of vitrified matrix precursor introduced is between 0.03 and 0.3 to 1. 16. The process of claim 14, wherein the ratio of the molar flow rate of iron introduced in the form of iron oxide Fe2O3 to the flow rate of sodium introduced is between 0.5/1 and 3/1. 17. The process of claim 1, wherein the ratio of the mass flow rate of Fe2O3 introduced to the mass flow rate of vitrified matrix precursor introduced is between 0.05 and 0.5 to 1. 18. The process of claim 1, wherein said process is carried out in a reactor maintained under reduced pressure. 19. The process of claim 1, wherein that, during step (A), the metallic sodium (ii) is introduced in conjunction with another alkali metal in metallic form. 20. A method for the containment, in a vitrified matrix, of radioactive elements present within metallic sodium, which implements the process of claim 1. 21. A method for the containment, in a vitrified matrix, of radioactive elements present within a mixture of alkali metals, including metallic sodium, which implements the process of claim 19. 22. The process of claim 21, wherein the metallic sodium is introduced in the form of a Na/K mixture containing radioactive elements.