Patent Number: 
Section: claims

1. An X-ray inspecting device comprising:a sample stage on which an inspection target sample is placed;image observing means for observing an image of the sample placed on the sample stage;a positioning mechanism that is controlled based on an image observation result of the sample by the image observing means to move the sample stage in two orthogonal directions on a horizontal plane, a height direction, and an in-plane rotation direction;a goniometer including first and second rotation members that rotate independently of each other along a virtual plane perpendicular to a surface of the sample around a rotational axis contained in the same plane as the surface of the sample placed on the sample stage;an X-ray irradiation unit that is installed in the first rotation member and focuses and irradiates characteristic X-rays to an inspection position set in the same plane as the surface of the sample placed on the sample stage;an X-ray detector installed in the second rotation member, wherein the X-ray irradiation unit includes an X-ray tube for generating X-rays, and an X-ray optical element for receiving X-rays irradiated from the X-ray tube, extracting only characteristic X-rays of a specific wavelength and focusing the extracted characteristic X-rays on the inspection position, and the X-ray optical element includes a first X-ray optical element for focusing the characteristic X-rays so that a height of the characteristic X-rays decreases within a virtual vertical plane orthogonal to the surface of the sample and containing an optical axis, and a second X-ray optical element for focusing the characteristic X-rays so that a width of the characteristic X-rays decreases within a virtual plane orthogonal to the virtual vertical plane and containing the optical axis, and wherein the first X-ray optical element is constituted by a crystal material having high crystallinity, and the second X-ray optical element comprises a multilayer mirror; androcking curve measuring means for executing a method for measuring rocking curve on a sample in which a thin film crystal is epitaxially grown on a substrate crystal, wherein the rocking curve measuring means has a function of executing the following operations (I) to (VI):(I) selecting two equivalent asymmetrical reflection crystal lattice planes for the sample;(II) arranging the X-ray irradiation unit and the X-ray detector at angular positions for the sample surface determined based on a Bragg angle of the substrate crystal in the sample for one of the selected crystal lattice planes;(III) irradiating the sample surface with X-rays from the X-ray irradiation unit, and detecting a reflection angle and intensity of diffracted X-rays reflected from the sample by the X-ray detector;(V) arranging the X-ray irradiation unit and the X-ray detector at angular positions for the sample surface determined based on a Bragg angle of the substrate crystal in the sample for the other selected crystal lattice plane;(V) irradiating the sample surface with X-rays from the X-ray irradiation unit, and detecting a reflection angle and intensity of diffracted X-rays reflected from the sample by the X-ray detector; and(VI) obtaining a rocking curve based on the reflection angle and intensity of the diffracted X-rays detected by the X-ray detector, and analyzing data on the rocking curve,wherein the rocking curve measuring means further has a function of executing the following operations (VI-I) to (VI-IV) in the operation (VI):(VI-I) determining an angular difference between a diffraction peak in the substrate crystal of the sample and diffraction peaks of two equivalent asymmetric reflections in the thin film crystal of the sample;(VI-II) calculating a lattice constant of the thin film crystal of the sample from the angular difference of the diffraction peaks determined by the operation (VI-I);(VI-III) calculating, from a known elastic constant of the thin film crystal of the sample and the calculated lattice constant, at least one of a strain of the thin film crystal, a lattice constant under a state where a stress of the thin film crystal is released, a composition of the thin film crystal and the stress of the thin film crystal; and(VI-IV) outputting a calculation result obtained by the operation (VI-III). 2. The X-ray inspecting device according to claim 1, wherein the first X-ray optical element uses a crystal material and is configured to reflect X-rays by lattice planes having an inherent rocking curve width of 0.06° or less in the crystal material. 3. The X-ray inspecting device according to claim 1, wherein the X-ray irradiation unit includes a focusing angle control member for controlling a focusing angle of the characteristic X-rays in the virtual vertical plane orthogonal to the surface of the sample and containing the optical axis. 4. The X-ray inspecting device according to claim 3, wherein the focusing angle control member comprises a slit member having a slit for transmitting only a part having any width of the characteristic X-rays focused by the first X-ray optical element. 5. The X-ray inspecting device according to claim 4, wherein the X-ray irradiation unit is configured so that respective components of the X-ray tube, the X-ray optical element, and the slit member are incorporated in an unit main body that is rotatably installed in the first rotation member. 6. The X-ray inspecting device according to claim 1, wherein the X-ray detector comprises a one-dimensional X-ray detector or a two-dimensional X-ray detector. 7. A method for measuring rocking curve that uses the X-ray inspecting device according to claim 1 to perform a rocking curve measurement on a sample in which a thin film crystal is epitaxially grown on a substrate crystal and includes the following steps A to D:step A of selecting two equivalent asymmetric reflection crystal lattice planes for the sample;step B of arranging the X-ray irradiation unit and the X-ray detector at angular positions for the sample surface determined based on a Bragg angle of the substrate crystal in the sample for one of the selected crystal lattice planes;step C of irradiating the sample surface with X-rays from the X-ray irradiation unit, and detecting a reflection angle and intensity of diffracted X-rays reflected from the sample by the X-ray detector;step D of arranging the X-ray irradiation unit and the X-ray detector at angular positions for the sample surface determined based on a Bragg angle of the substrate crystal in the sample for the other selected crystal lattice plane;step E of irradiating the sample surface with X-rays from the X-ray irradiation unit, and detecting a reflection angle and intensity of diffracted X-rays reflected from the sample by the X-ray detector; andstep F of obtaining a rocking curve based on the reflection angle and intensity of the diffracted X-rays detected by the X-ray detector, and analyzing data on the rocking curve,wherein the step F further includes the following steps F-1 to F-4:step F-1 of determining an angular difference between a diffraction peak in the substrate crystal of the sample and diffraction peaks of two equivalent asymmetric reflections in the thin film crystal of the sample;step F-2 of calculating a lattice constant of the thin film crystal of the sample from the angular difference of the diffraction peaks determined by the operation of the step F-1;step F-3 of calculating, from a known elastic constant of the thin film crystal of the sample and the calculated lattice constant, at least one of a strain of the thin film crystal, a lattice constant under a state where a stress of the thin film crystal is released, a composition of the thin film crystal and the stress of the thin film crystal; andstep F-4 of outputting a calculation result obtained in the step F-3. 8. The X-ray inspecting device according to claim 1, wherein the X-ray irradiation unit includes a focusing angle control member for controlling a focusing angle of the characteristic X-rays in a virtual vertical plane orthogonal to the surface of the sample and containing the optical axis, sets a focusing angle of X-rays to be irradiated on the sample surface from the X-ray irradiation unit to 2° or more by the focusing angle control member, and irradiates the sample surface with X-rays in an angle range of 2° or more, and wherein the X-ray detector comprises a one-dimensional X-ray detector or a two-dimensional X-ray detector, and diffracted X-rays reflected from the sample are made incident to the X-ray detector to detect a reflection angle and intensity of the diffracted X-rays. 9. The X-ray inspecting device according to claim 8, wherein the X-ray irradiation unit is configured to oscillate in a virtual vertical plane orthogonal to the surface of the sample and containing the optical axis to irradiate the sample surface with X-rays. 10. The X-ray inspecting device according to claim 8, wherein the X-ray detector and the X-ray irradiation unit are scanned interlockingly with each other within a virtual vertical plane orthogonal to the surface of the sample and containing the optical axis to measure diffracted X-rays reflected from the sample by a scanning method based on a TDI Mode.