Patent Number: 052689514
Section: summary

BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to an X-ray exposure apparatus for printing a fine pattern such as a semiconductor integrated circuit pattern or the like. More particularly, the invention is concerned with an optical system including a method for scanning an X-ray beam in an X-ray exposure apparatus using synchrotron radiation or the like as a source. 2. Description of related art. In recent years, synchrotron radiation (hereinafter referred to as SR) has become a promising source for the X-ray exposure apparatus. SR is electromagnetic radiation generated by high energy electrons which run along a circular orbit at a velocity close to the speed of light. SR is emitted in the direction tangential to the orbit and features excellent directivity and high intensity in the wavelength range of about 0.5 to 1.5 nm usually used in the X-ray exposure apparatus. While SR is emitted uniformly in the horizontal plane (orbital plane of electrons), the divergence angle of the component whose wavelength is useful for X-ray exposure is at most 1 milliradian in a vertical plane (the plane extending orthogonally to the orbital plane and in parallel with a predetermined plane. Accordingly in order to expose a fixed object placed at approximate 12 meters from the SR light source over a square field having a side of several tens millimeters, the object must be scanned in the vertical direction by deflecting the SR. To this end, a rotatable reflecting mirror is used in an SR beam scanning system described in "Proceeding of SPIE - The International Society for Optical Engineering", Vol. 448, pp. 93-101. It shows an arrangement of this known optical system in a plane orthogonal to the orbital plane of electrons. The beam emitted from an SR source is deflected by a reflecting mirror to a mask and a wafer held with a gap of several tens of .mu.m therebetween, whereby the pattern of the mask is printed on the wafer. For the sake of convenience, the combination of the mask and the wafer will collectively be termed an object in the following description. The reflecting surface of the mirror is implemented in a cylindrical form ("U" form) to collimate the in the horizontal direction. The reflecting mirror can be rotated about, the axis extending perpendicularly to the plane within an angular range da of about .+-.3 mrad relative to the center position where the grazing incidence angle .alpha. (i.e. angle formed between the incident beam and the reflecting surface) is 24 mrad. As a result, the object located at about 7 m from the reflecting mirror is scanned with the beam over a width of about 40 mm. On the other hand, in the horizontal plane (orthogonal to the plane of the drawing), the SR beam is collimated by a concave reflecting surface, whereby a beam width of about 40 mm is obtained on the object. The beam intensity varies along with the position on the object, giving rise to a first problem that line width control in the resist pattern becomes difficult. See E. Cullman, K. A. Cooper, and W. Vach, "An X-ray Stepper for Production Lithography" SPIE Proc. Vol. 773 Electron-Beam, X-Ray and Ion-Beam Lithographies VI, pp. 2-6 (1987). The conventional method for scanning an x-ray beam across an exposure field is to alter the grazing angle of incidence of a collimating mirror. This results in altering the mirror collimation producing printing distortion for an x-ray proximity printed image on a wafer and introducing non-uniform exposure intensity. In x-ray proximity printing using synchrotron orbital radiation, the x-ray flux emitted by the source is typically collimated by one or more x-ray grazing incidence mirrors such that a maximum of useful flux is delivered to the mask and such that the x-rays arrive at the mask normal to the surface to eliminate geometric printing distortion. The geometric distortion D is given by: EQU D=Gap.times.Tan A where Gap on the order of 10 .mu.M to 50 .mu.M and PA0 A less than 1 milliradian (mrad) for typical mirror systems. PA0 (1) moving the mask and wafer pair through the stationary x-ray beam or PA0 (2) moving the x-ray beam across the stationary mask and wafer pair. PA0 1. A change in the beam collimation, typically separated into the horizontal (Xphase) and vertical (Zphase) error components. PA0 2. A change in the exposure intensity through the field due to the collimation error and changes in the reflectivity of the mirror with grazing angle. Mirror grazing incidence angles are chosen which, combined with the mirror surface material, provide an acceptable reflectivity for x-ray radiation. Typical grazing angles are in the order of 1 to 2 degrees and a typical mirror reflectivity of 70% is available from a gold surface for wavelengths in the 8 to 12 .ANG. range. Once a grazing angle of incidence and a source to mirror distance are selected the mirror focal length `F` is defined (equal to the source to mirror distance for a collimating mirror) and a surface form is chosen which yields acceptable collimation over a given exposure field width. Typical mirror surface forms are cylindrical, toroidal, elliptical, and parabolic with the toroidal shape being the most common due to ease of manufacture and lower cost. If the mirror location with respect to the source or grazing angle of incidence is changed, the collimation of the beam changes as well as the flux per unit horizontal length at the exposure field, both producing adverse proximity printing results. Several options are available to expose the full mask field. Since the horizontal field size is typically determined by the source to mirror distance, the mirror surface form, and the degree of acceptable collimation error, the task is reduced to covering a desired vertical field size. This is done either by as follows: It is now believed that the most accurate mask to wafer registration will be achieved for the case where the mask and wafer are stationary, due to the difficulties in maintaining alignment between mask and wafer stages during vertical acceleration and scanning. The preserved option is to scan the x-ray beam across the vertical exposure field. The most commonly used method to scan the x-rays across the exposure field is to alter the mirror grazing angle to produce the desired shift at the mask. The errors resulting from this form of scanning are: The merits of various mirror forms in reducing these errors is discussed in J. P. Silverman, R. P. Haelbich, and J. M. Warlaumont, "Synchrotron Radiation X-ray Lithography: Recent Results", SPIE Proc. Vol. 488, pages 50-59 (1984.) U.S. Pat. No. 5,077,774, Piestrup, et. al., "X-ray lithography Source", Col. 18, see lines 2-46 describing, in an x-ray source, a grazing angle reflector which is wobbled comprising a flat or slightly curve x-ray mirror which reflects a diverging x-ray beam. The divergence of the x-ray beam introduces an "overlay error (increased shadowing of the circuit of the mask on the resist)." U.S. Pat. No. 5,031,199, Cole, et. al., "X-ray Lithography Beamline Method and apparatus" describes a beamline apparatus for X-ray lithography which receives synchrotron radiation. The apparatus comprises a first, entrance mirror in the beamline with a reflecting surface which is concave along its width and concave along its length, positioned to receive the fan of radiation from a synchrotron at a grazing angle and to partially collimate the X-rays in one dimension. In addition, a second, refocusing mirror is positioned to receive the X-rays reflected from the entrance mirror at a grazing angle. The refocusing mirror has a reflecting surface which is concave along its length and convex along its width. The refocusing mirror acts to collimate the X-rays horizontally and to focus the X-rays vertically, the entrance mirror and the refocusing mirror positioned to cooperate to provide a beam having a substantially uniform image at an image plane with a substantially uniform power distribution. The entrance mirror and the refocusing mirror each have a grazing angle to the X-rays of approximately 2 degrees. The apparatus includes a structure for enclosing the beamline along its length including the entrance and refocusing mirrors and a window closing the end of the beamline to seal the interior of the beamline from the external atmosphere and to cooperate with the entrance and refocusing mirrors to provide an X-ray beam as passed through the window having X-rays above and below a desired energy band substantially attenuated. U.S. Pat. No. 4,984,259 Jan. 8, 1991 of Itou et al for "X-ray Exposure Apparatus" describes an X-ray exposure apparatus comprising an X-ray source, a reflecting mirror for deflecting an X-ray beam radiated from the X-ray source to an object, and mechanisms for rotating the reflecting mirror about an axis of rotation apart from a reflecting surface of the reflecting mirror. The reflecting mirror has such a shape that the angle of incidence remains constant relative to the X-ray beam at given angles of rotation. The X-ray exposure apparatus comprises: an X-ray source; a reflecting mirror having a reflecting surface for deflecting an X-ray beam radiated from the X-ray source to an object; means for rotating the reflecting mirror having the reflecting surface about an axis of rotation, the axis of rotation being disposed apart from the reflecting surface; the reflecting surface being configured with a shape so that an angle of grazing incidence of the X-ray beam is maintained at a constant value when the reflecting mirror rotates about the axis of rotation; and means for scanning the object with the X-ray beam by rotating the reflecting mirror about the axis of rotation by means of the rotating means. A purpose of the Itou patent was to provide a beam scanning system for an X-ray exposure apparatus in which the beam intensity and the incident direction on the object can always be held constant in the course of scanning of an object with a SR beam by means of a simple rotating mechanism. An object of this invention is to allow scanning of an x-ray beam across an exposure field while avoiding the introduction of printing distortion and non-uniform exposure, and with capability of producing deliberate printing distortion independently in the vertical and horizontal exposure axes.