Patent Number: 062434330
Section: claims

1. A nuclear fuel element, comprising: a central core of a body of nuclear fuel material selected from the group consisting of compounds of uranium, plutonium, thorium and mixtures thereof; and,  an elongated composite container having a hollow central bore, the container comprised of an outer metallic tubular portion and an inner metallic barrier metallurgically bonded to the outer metallic tubular portion, the inner metallic barrier having a combination of crack resistance and corrosion resistance consisting essentially of commercially pure zirconium microalloyed with iron in the range of about 850-1500 ppm and the balance incidental impurities. 2. The nuclear fuel element of claim 1 wherein the inner metallic barrier having a combination of acceptable cracking resistance and superior corrosion resistance consists essentially of iron in a range of about 1000.+-.150 ppm. 3. The nuclear fuel element of claim 1 wherein the corrosion resistance of the inner metallic barrier as measured by the modified ASTM G2 steam test is less than about 5 mg/dm.sup.2 /day. 4. The nuclear fuel element of claim 1 wherein the thickness of the inner metallic barrier is about 10-20% of the total thickness of the elongated composite cladding container. 5. The nuclear fuel element of claim 1 wherein the cracking resistance of the inner metallic barrier measured by PCI resistance testing at 315.degree. C. has a failure rate of 50% or less. 6. The nuclear fuel element of claim 1 wherein the nuclear fuel material is selected from the group consisting of compounds of uranium, plutonium, thorium and mixtures thereof. 7. The nuclear fuel element of claim 1 wherein the microstructure of the inner metallic barrier is recrystallized, having a grain size in the range of ASTM 9 to ASTM 11. 8. The nuclear fuel element of claim 2 wherein the microstructure of the inner metallic barrier is recrystallized, having a grain size in the range of ASTM 9 to ASTM 12. 9. The nuclear fuel element of claim 1 wherein the outer metallic tubular portion is selected from the group consisting of zirconium and its alloys, stainless steel, aluminum and its alloys, niobium and magnesium alloys. 10. The nuclear fuel element of claim 9 wherein the outer metallic tubular portion is comprised of zirconium and its alloys. 11. The nuclear fuel element of claim 10 wherein the inner metallic barrier consists essentially of iron in the range of about 850-1500 ppm, and the weight percent of zirconium in the inner metallic barrier is greater than the weight percent of zirconium in the outer metallic tubular portion. 12. The nuclear fuel element of claim 1 in which the inner metallic barrier consists essentially of iron in the range of about 1000-1500 ppm. 13. The nuclear fuel element of claim 12 wherein the microstructure of the inner metallic barrier is recrystallized, having a grain size in the range of ASTM 9 to ASTM 12. 14. The nuclear fuel element of claim 12 wherein the cracking resistance of the inner metallic barrier measured by PCI resistance testing at 315.degree. C. has a failure rate of 10% or less. 15. The nuclear fuel element of claim 14 wherein the corrosion resistance of the inner metallic barrier as measured by the modified ASTM G2 steam test is about 2 mg/dm.sup.2 /day. 16. The nuclear fuel element of claim 15 wherein the inner metallic barrier comprises about 10 to about 20% of the total composite container thickness.