Patent Number: 043022952
Section: description

FIG. 1 shows a nuclear fuel element according to one embodiment of this invention. It is seen that a plurality of pellets 2, prepared by molding uranium dioxide, followed by sintering, are loaded in a cladding tube 1. Loaded in plenum 3 of the cladding tube 1 are a metal foil 5 having a tag gas implanted thereinto by ion implantation method and a spring 4. Both open ends of the cladding tube 1 are sealed by stoppers 6 and 7. In general, the cladding tube 1 and the stoppers 6, 7 are formed of a zirconium alloy for a BWR and of stainless steel for a fast breeder reactor. The spring 4 serves to maintain the pellets 2 and the metal foil 5 at their proper locations. In the embodiment of FIG. 1, the metal foil 5 is disposed on the laminated pellets 2. But, the metal foil may be disposed beneath or between the pellets. The tag gas-implanted metal foil can be prepared by employing a known ion implantation apparatus and method disclosed in, for example, U.S. Pat. No. 4,051,063 granted to R. S. Nelson et al. and U.S. Pat. No. 4,124,802 granted to M. Terasawa et al. FIG. 2 illustrates how Kr gas is implanted into an aluminum foil by using an apparatus disclosed in the latter U.S. patent. As shown in the drawing, Kr gas is sent from a gas reservoir 10 through a pressure control value into an ion source 11 so as to be ionized into Kr.sup.+. The krypton ion (Kr.sup.+) is accelerated by an accelerator 12 to have an energy of about 50 KeV and runs through a magnetic deflection device 13 so as to be implanted into a metal aluminum foil 15 disposed within an implantation chamber 14. It is seen that an evacuation means 16 is provided for evacuating the ion source 11, the accelerator 12 and the implantation chamber 14. When implanted into an aluminum foil, Kr.sup.+ with 50 KeV of acceleration energy penetrates about 300 A into the foil and is distributed as shown in FIG. 3. The maximum amount of tag gas which can be implanted into a metal foil, i.e., saturation amount, is determined by the acceleration energy imparted to the tag gas. Where a tag gas imparted with 50 KeV of acceleration energy is implanted into an aluminum foil, the saturation amount of the tag gas is about 1.times.10.sup.7 Kr/cm.sup.2. The ionized tag gas implanted into a metal foil is retained within the metal foil in the form of individual atoms or aggregation of atoms forming bubbles and is thermally diffused and released from the foil to the outside when the foil has been heated. The release of tag gas is promoted in accordance with elevation of the heating temperature. But, all the tag gas implanted into the metal foil is not always released by the heating. For example, about 55% of Kr gas implanted into an aluminum foil is released at a temperature of 450.degree. C. to which the plenum of a fuel element is exposed at the initial stage of a nuclear reactor operation, with about 45% of Kr gas retained within the aluminum foil. Naturally, the residual amount within a foil should be taken into account in determining the amount of tag gas which is to be implanted into the foil. In other words, the foil should be enabled to release a tag gas in an amount large enough to be detected. Where Kr ions accelerated to have an energy level of 500 KeV were implanted into a stainless steel foil in an amount of 2.times.10.sup.15 Kr/cm.sup.2, the implanted Kr begins to be released from the foil at 820.degree. C. and substantially all the Kr atoms are released at 1,200.degree. C. In general, a tag gas is implanted into a metal foil in an amount about two times as much as that required for detection. The required area of a metal foil is determined by the saturation amount of tag gas determined by the acceleration energy imparted to the ionized tag gas. If a tag gas is implanted into both sides of a metal foil, it naturally suffices for one surface area of the foil to be half the required area. A metal foil having a thickness greater than the penetration range of the ionized tag gas can perform its function. FIG. 3 shows that it suffices for a metal foil to be about 1,000 A thick in view of its tag gas sealing function. However, it is practical in view of manufacturing process and mechanical strength to use a metal foil about 1 to 3 .mu.m thick. Also, the shape of a metal foil need not be restricted as far as the foil can be loaded in a cladding tube. For example, a plurality of circular foils about 5.5 mm in diameter can be loaded in the form of a laminate or apart from each other within a cladding tube having an inner diameter of 5.6 mm. It is also possible to wind a ribbon-shaped foil into a coil of a diameter smaller than the inner diameter of a cladding tube for loading of the coil within the cladding tube. A tag gas can be implanted into a metal foil formed into a desired shape, or a tag gas-implanted metal foil can be formed into a desired shape. Where a tag gas is implanted into a stainless steel foil, the foil should desirably be disposed between fuel pellets because somewhat high temperature is required for releasing the implanted tag gas. In general, isotopes of Kr and Xe are used in the form of a mixture or independently as a tag gas. It is possible to implant a mixed gas into a metal foil. It is also possible to implant the tag gas components individually and successively into a metal foil. According to a preferred embodiment of this invention, each component of the tag gas is implanted separately into a single metal foil having a particular shape and a plurality of gas-implanted foils are loaded in combination within a cladding tube. In this embodiment, it is possible to make arrangement such that the kind of the tag gas component can be distinguished by the shape of the metal foil. This renders it possible to load a desired amount of a desired tag gas into a cladding tube efficiently. In addition, the mixing ratio of the components can be readily adjusted by counting the number of metal foils. A tag gas of Kr was actually implanted by ion implantation method into a ribbon-shaped aluminum foil 3 .mu.m in thickness, 2 cm in width and 650 cm in length. The volume of the foil was: EQU 2 cm.times.650 cm.times.0.0003 cm=0.39 cm.sup.3. The Kr gas was implanted at an acceleration energy of 50 KeV into both surface area of the foil, followed by winding the foil into a coil 5.0 mm in diameter and 2 cm in height. The coil was small enough to be loaded into a cladding tube of a fuel element. Suppose Kr was implanted into the foil at the amount of 4.times.10.sup.16 Kr/cm.sup.2, which is somewhat lower than the saturation amount under the acceleration energy of 50 KeV, i.e., 1.times.10.sup.17 Kr/cm.sup.2. In this case, the total amount of Kr implanted into the entire foil is about 1.times.10.sup.20 Kr (the entire surface area of the foil is: EQU 2 cm.times.650 cm.times.2=2,600 cm.sup.2). As a matter of fact, about 5.5.times.10.sup.19 Kr atoms were released from the foil when heated at 450.degree. C. for 5 minutes. Incidentally, 2 cc of Kr gas at standard condition, which is sufficient for use as a tag gas, contains 5.4.times.10.sup.19 Kr atoms. In other words, the amount of Kr atoms actually released from the foil in the above-described experiment is sufficient for use as a tag gas. As described above in detail, a tag gas is sealed in a metal foil in this invention, resulting in that the sealed tag gas is not released unless the metal foil is heated. In other words, the sealed tag gas is not released by the impulse or vibration in the step of assembly or transportation of a fuel element, rendering it very easy to handle the fuel element. In addition, a conventional apparatus can be used for assembling a fuel element, a special apparatus need not be used. It should also be noted that metal foils of different shapes can be used for sealing different tag gas components separately, rendering it possible to distinguish the tag gas component by the shape of the metal foil. In this case, the tag gas components can be mixed at a desired ratio quite easily. To reiterate, a tag gas implanted into a metal foil is released from the foil in accordance with elevation of the ambient temperature caused by start-up of a nuclear reactor operation. As a result, a cladding tube is filled with the tag gas in an amount large enough to be detected, rendering it possible to carry out gas tagging.