Patent Number: 053226445
Section: claims

1. A process for decontaminating material containing radioactive contaminants, comprising the steps of: a. contacting the material to be decontaminated with a dissolving composition, the composition comprising an amount of a dilute, basic chelating agent containing carbonate solution sufficient to dissolve the contaminants in the material;  b. separating the dissolving composition containing the dissolved contaminants from the contacted material; and  c. recovering the dissolved contaminants from the dissolving composition that has been separated from the material by adsorbing the contaminants contained in the dissolving composition on an anion exchange adsorbent.  a. removing continuously a selected amount of contacted material; and  b. replacing continuously the removed material with material to be contacted.  a. removing continuously a selected amount of the dissolving composition that has contacted the material; and  b. replacing continuously the removed dissolving composition with dissolving composition.  a. filtering the dissolving composition that has been separated from the contacted material to remove particulates prior to adsorbing the contaminants on the anion exchange adsorbent; and  b. eluting the contaminants from the adsorbent to obtain a concentrated solution of the contaminants.  a. contacting the material with a dissolving composition to dissolve the contaminants in the material, said composition comprising a dilute solution of about 0.03 molar ethylene diamine tetraacetic acid, about 0.06 molar carbonate, about 3 grams per liter hydrogen peroxide and an effective amount of sodium hydroxide to adjust the pH of the composition to a pH from about 9 to about 11;  b. separating the dissolving composition containing the dissolved contaminants from the contacted material; and  c. recovering dissolved contaminants from the dissolving composition that has been separated from the material.  a. contacting the material to be decontaminated with a dissolving composition, the composition comprising an amount of a dilute, basic, carbonate solution sufficient to dissolve the contaminants in the material;  b. separating the dissolving composition containing the dissolved contaminants from the contacted material; and  c. recovering dissolved contaminants form the dissolving composition that has been separated form the material, by adsorbing the contaminants contained in the dissolving composition on an a cation exchange adsorbent.  a. contacting the material to be decontaminated with a dissolving composition, the composition comprising an amount of a dilute, basic, chelating agent containing, oxidizing agent containing carbonate solution sufficient to dissolve the contaminants in the material;  b. separating the dissolving composition containing the dissolved contaminants from the contacted material; and  c. recovering dissolved contaminants from the dissolving composition that has been separated from the material by precipitating the contaminants contained in the dissolving composition by destructively oxidizing the chelating agent.  a. contacting the material to be decontaminated with a dissolving composition, the composition comprising an amount of a dilute, basic, chelating agent containing carbonate solution sufficient to dissolve the contaminants in the material;  b. separating the dissolving composition containing the dissolved contaminants form the contacted material; and  c. recovering dissolved contaminants from the dissolving composition that has been separated from the material, by adsorbing the contaminants contained in the dissolving composition on a selective inorganic cation exchange adsorbent. 2. The process of claim 1, wherein the chelating agent is ethylene diamine tetraacetic acid having a concentration from about 0.001 molar to about 0.1 molar in the dissolving composition. 3. The process of claim 1, wherein the chelating agent is selected from the group consisting of diethylene triamine penta acetic acid, citrate, oxalate and 8-hydroxyquinoline. 4. The process of claim 1, wherein the dissolving composition has a pH from about 9 to about 11. 5. The process of claim 1, further comprising the step of adjusting the pH of the dissolving composition to about 10 by adding an effective amount of sodium hydroxide. 6. The process of claim 1, further comprising the step of generating carbonate by adding an effective amount of carbon dioxide gas to the dissolving composition prior to the contacting step. 7. The process of claim 1, wherein the solution further comprises an effective amount of an oxidizing agent sufficient to raise the oxidation state of a radioactive contaminant. 8. The process of claim 7, wherein the oxidizing agent is hydrogen peroxide, and the effective amount is from about 1 to about 3 grams per liter of the dissolving composition. 9. The process of claim 1, wherein the dilute, basic, carbonate solution comprises about 98% by weight water. 10. The process of claim 1, wherein the contacting step further comprises the step of agitating the material with the dissolving composition. 11. The process of claim 1, wherein the step of separating the dissolving composition from the material is a continuous process and comprises the steps of: 12. The process of claim 1, wherein the step of separating the dissolving composition from the material further comprises the steps of: 13. The process of claim 1, wherein the recovering step further comprises the following steps: 14. The process of claim 1, further comprising the step of recirculating to the contacting step the dissolving composition that has been separated from the contacted material. 15. The process of claim 14, further comprising controlling the fluid volume in the recirculating step by evaporating water from the dissolving composition. 16. The process of claim 14, further comprising controlling the fluid volume in the recirculating step by allowing water to leave the recirculating step with the decontaminated material. 17. The process of claim 14, wherein the recirculating step comprises returning directly to the contacting step a selected amount of the dissolving composition that contains the dissolved contaminants. 18. The process of claim 1, further comprising recirculating to the contacting step the dissolving composition from which the contaminants have been recovered in the recovering step. 19. A process for decontaminating material containing radioactive contaminants comprising the steps of: 20. The process of claim 19, wherein the dilute solution of ethylene diamine tetraacetic acid, carbonate, hydrogen peroxide and sodium hydroxide comprises less than about two percent of the total weight of the dissolving composition. 21. The process of claim 1, wherein the radioactive contaminants comprise a radionuclide or mixture of radionuclides selected from the group consisting of uranium, thorium, radium, plutonium and americium. 22. A process for decontaminating material containing radioactive contaminants, comprising the steps of: 23. A process for decontaminating material containing radioactive contaminants, comprising the steps of: 24. A process for decontaminating material containing radioactive contaminants, comprising the steps of: