Patent Number: 056132441
Section: description

EXAMPLES Example 1 Furnace ready feed material was prepared from glass-forming minerals, organic reductants, and simulated high-sodium low-level liquid waste having the composition listed in Table 1. The resulting 3,925 pounds of furnace feed were melted to form a fluid glass that tapped readily from the electric furnace at 1,350.degree. C. Appropriate weights of glass-forming minerals, reductants, binder, and simulated low-level liquid waste to prepare 420-pound batches are as follows: TABLE 1 ______________________________________ Composition of Hanford-Site Low-Level Liquid Waste Concentration Component grams/liter wt percent ______________________________________ A1203 51.439 3.544 Ca0 0.040 0.003 Cr203 0.648 0.045 Cs20 2.349 0.162 Fe203 0.040 0.003 K20 23.370 1.610 Mg0 0.040 0.003 Mn02 0.040 0.003 Mo03 2.390 0.165 Cl 5.627 0.388 F 4.710 0.324 I 2.092 0.144 Na20 307.449 21.181 P205 3.038 0.209 SO3 3.443 0.237 SrO 1.701 0.117 Subtotal 408.42 28.14 (inorganic components) CO2 16.010 1.103 H2O 672.746 46.348 NO3-- 196.326 13.526 NO2-- 76.660 5.281 OH-- 65.183 4.491 Org C 16.173 1.114 Subtotal 1043.10 71.863 (volatile components) Total 1451.51 100.00 (all components) ______________________________________ 1.1 Pellet production: Finely divided dry solids comprising 19.25 lb Bayer alumina, 37.52 lb boric acid, 12.64 lb southern bentonite, 178.20 lb diatomite, 64.50 lb Micro-Cel, 34.68 lb minus 200 mesh silica, 11.79 lb powered sugar, and 11.03 lb activated carbon were mixed for 10 min in a 100 cubic foot capacity double-ribbon mixer. The mixed materials were pelletized with water spray on a 36-inch diameter disc pelletizer to prepare wet pellets. Wet pellets then were heated to 100.degree. C. in an oven overnight to prepare physically strong dry pellets as an intermediate product. 1.2. Furnace feed preparation: Dry intermediate product pellets in 50-lb batches were sprayed with 51 lb of low-level liquid waste while being tumbled in a conventional cement mixer to prepare wet loaded pellets, which were spread on a conveyor belt and heated for 1 hour by infrared heaters to remove about 30 percent of the free moisture. The partially dried pellets then were further heated to 350.degree. C. in 20 minutes within a steel-belt dryer to complete water removal and to cause reaction of sugar and carbon in the pellets with nitrates and nitrites in the low level liquid waste to evolve nitrogen, carbon dioxide, and water as gases. The resulting product constitutes dry homogeneous denitrified furnace feed which produced glass with 25 pct waste loading. Chemical reactions to decompose sodium nitrate and sodium nitrite with sugar and carbon are given by equations A, B, C, and D. Sucrose reductant: EQU Equation A. 5 C.sub.12 H.sub.22 O.sub.11 +48 NaNO.sub.3 ----&gt;24 Na.sub.2 O+24 N.sub.2 +60 CO.sub.2 +55 H.sub.2 O EQU Equation B. 3 C.sub.12 H.sub.22 O.sub.11 +48 NaNO.sub.2 ----&gt;24 Na.sub.2 O+24 N.sub.2 +36 CO.sub.2 +33 H.sub.2 O Carbon reductant: EQU Equation C. 5 C+4 NaNO.sub.3 ----&gt;2 Na.sub.2 O+2N.sub.2 +5 CO.sub.2 EQU Equation D. 3 C+4 NaNO.sub.2 ----&gt;2 Na.sub.2 O+2N.sub.2 +3 CO.sub.2. The invention is illustrated in Example 1 for a substrate which contains boria, alumina, calcia, and silica as major components after reaction, but other compositions readily recognizable by one versed in the art are also claimed. Further treatment of the substrate by addition of chemical species or thermal treatment to modify physical properties including but not limited to, strength, porosity, and surface area are within the purview of the invention. Also claimed is the addition of catalytic materials to achieve desired reactions or to modify reaction mechanisms or temperature. Reaction of components or additives within the substrate constitutes an essential element of the example illustrated in Example 1, however it is understood that the invention is not dependent upon chemical reaction within the substrate. The substrate may function only as a carrier for the appropriate hazardous component or components in the liquid waste. It is further understood that the invention is applicable to numerous liquid wastes amenable to treatment by vitrification or melting. It is further understood that the chemical, physical and crystallographic properties of the final waste form are readily modified by post melting thermal treatment such as quenching in water or other liquid, casting onto a cooled substram, programmed cooling, soaking at a temperature below the melting temperature, or reheating of programmatically cooled material. Extreme and preferred conditions are given below for application of the preferred embodiment of the subject invention to the treatment of low-level radioactive high-sodium liquid wastes currently stored in underground tanks at the Hanford Nuclear Reservation in Washington State. Composition of the substrate: The preferred composition is 10.15 pct boric acid, 5.21 pct Bayer alumina, 3.42 pct southern bentonite, 48.21 pct diatomite, 17.45 pct Micro-Cel, 9.38 pct minus 200 mesh silica, 3.19 pct powdered sugar, and 2.99 pct activated carbon, where ingredients were selected to provide dry pellets with physical strength to withstand normal handling and absorptive capacity to provide 25 pct waste loading in product glass. Boric acid is technical grade material with the formula H.sub.3 BO.sub.3 ; Bayer alumina is "cell grade" aluminum oxide containing 0.2 to 0.5 pct Na.sub.2 O as major impurity, as used by the aluminum industry in electrolytic reduction cells; southern bentonite, the binder material for dry intermediate product pellets, was selected to contain minimum sodium; diatomite is an abundant mineral with large specific surface area containing about 85 pct SiO.sub.2 ; minus 200 mesh silica is a readily available industrial mineral, Micro-Cel (Trademark of Celite Corp.) is a commercially prepared synthetic calcium silicate having large specific surface area, powdered sugar is either beet or cane sugar, and activated carbon is NUSORB LN100-325X wood-derived activated carbon from NUCON International Inc. The extreme range of composition is 0 to 20 pct boric acid, 0 to 10 pct Bayer alumina, 0 to 20 pct southern bentonite, 25 to 75 pct diatomite, 0 to 25 pct Micro-Cel, 0 to 25 pct finely divided silica, 0 to 15 pct sugar and 0 to 10 pct carbon. It is understood that the essential oxides can be obtained from numerous minerals and industrial product sources. For example, boria can be obtained from colemanite (calcium borate); alumina can be obtained from mullite (aluminum silicate) or clay; SiO.sub.2 can be obtained from silica sand, fumed silica, or clay; and calcia can be obtained from limestone (CaCO.sub.3), slacked lime (Ca(OH).sub.2), or quick lime (CaO). Southern bentonire is not an essential ingredient of the substrate, in that intermediate pellet binders may be omitted, and other binders, both organic and inorganic, are appropriate under special circumstances. It is further understood that numerous reductants are applicable including but not limited to formic acid, other organic acids, starch, urea, lamp black, other forms of carbon, silicon, aluminum, and other active metals. Temperature for reaction: The preferred conditions for reaction of the exampled composition is 350.degree. C. Reaction occurs while heating to that temperature. The extreme range for reaction is 150.degree. to 450.degree. C. Alternative embodiments of the invention: Finely divided solids comprising glass forming minerals and reductants can alternatively be mixed with the subject liquid waste, and the resultant slurry or thick paste can be formed into wet pellets, bricks, briquettes, plates, extrudates, or other shape by conventional methods including mixing, rolling, compacting, extruding (ring pelletizer), agglomerating (disc pelletizer), or other pelletizing technique. The resultant shape can be dried in the temperature range 20.degree. C. to 120.degree. C., and the resultant dried shape can be reacted in the temperature range 150.degree. C. to 450.degree. C. in order to initiate and complete reaction between nitrogenous species and the reductant. The resultant material is indistinguishable from material described in Example 1. However, the latter method introduces the radioactive waste to the glass former materials in the initial operation, and there/ore, requires the treatment and handling of nearly three times more radioactive material than the preferred embodiment. Example 2 Furnace ready feed material was prepared from glass-forming minerals, organic reductants, and simulated high-sodium low-level liquid waste by the following steps. The resulting 26,155 pounds of furnace feed were melted to form a fluid glass indistinguishable from glass provided by example 1. Appropriate weights of glass formers, reductants, and simulated low-level liquid waste to prepare 485-pound batches of wet pellets are as follows: 1.1 Pellet production: Finely divided dry solids comprising 13.99 lb Bayer alumina, 24.03 lb boric acid, 23.28 lb limestone, 119.19 lb diatomite, 45.12 lb minus 200 mesh silica, 7.55 lb powered sugar, and 7.07 lb activated carbon were mixed for 10 minutes in a 100 cubic foot capacity double-ribbon mixer. Over a 6-minute period of time 239.55 lb of simulated low-level liquid waste was added to the mixer through a distribution pipe extending the length of the mixer. Water (8 lb) then was added over 5 minutes with continued mixing to cause agglomeration resulting in wet loaded pellets. 1.2. Furnace feed preparation: The wet pellets were dried and reacted as described in Example 1 to prepare dry homogeneous denitrified furnace feed. Glass or slag forming minerals and suitable binders can alternatively be mixed, pelletized, dried, and indurated (sintered) to form rugged pellets to withstand severe physical abuse. Such properties could be required if pellet production facilities were located far from the melter requiring extensive transportation and handling of pellets. In this embodiment the reductant(s) must be dissolved (soluble) in the liquid waste. Example 3 Furnace ready feed material was prepared from glass-forming minerals, sugar, and simulated high-sodium low-level liquid waste by the following steps. The resulting 26.67 pounds of furnace feed were melted to form a fluid glass indistinguishable from glass provided by examples 1 and 2. Appropriate weights of glass formers, sugar, and simulated low-level high-sodium liquid waste to prepare 26.67 pounds of dry furnace feed are as follows: 3.1. Pellet production: Finely divided dry solids comprising 2.43 lb boric acid, 1.02 lb Bayer alumina, 0.88 lb southern bentonite, 13.57 lb diatomite, and 4.20 lb Micro-Cel were thoroughly mixed, and the mixture was pelletized with water spray on a disc pelletizer. The resulting wet pellets were dried at 100.degree. C. overnight, and then indurated (sintered) for 1 hour in air at 800.degree. C. to prepare 20.00 lb of indurated pellets. 3.2. Conditioning of liquid waste: Common beet sugar, 2.97 lb, was dissolved in 1.80 lb water, and the resulting solution was added with stirring to 23.69 lb of simulated high-sodium low-level liquid waste. 3.3. Furnace feed production: Indurated pellets (20.00 lb) prepared in step 3.1 were sprayed with the conditioned liquid waste (28.46 lb) prepared in step 3.2 to prepare 48.46 lb of wet loaded pellets. The wet loaded pellets were dried at 100.degree. C. overnight and then were heated to 250.degree. C. to cause reaction of sugar with nitrates and nitrites to evolve nitrogen, carbon dioxide, and water as gases. The resulting product, 26.67 lb, constitutes dry homogeneous denitrified furnace feed providing 25 pct waste loading in product glass.