Patent Number: 055240321
Section: claims

1. A cladding tube having a cross-section, the cladding tube comprising: a zirconium alloy outer circumferential substrate having an inner surface, the zirconium alloy also having one or more alloying elements;  a zirconium barrier layer bonded to the inner surface of the outer circumferential substrate and having a width defined between its inner and outer surfaces, the barrier layer being alloyed with the one or more alloying elements; and  a zirconium alloy inner circumferential liner bonded to the inner surface of the zirconium barrier layer.  (a) alloying elements are present at excess concentrations of at least about 0.03 weight percent iron and at least about 0.01 weight percent nickel at the zirconium barrier layer's interface with the inner liner, and  (b) substantially no excess alloying elements are present at a distance of at most about 10% of the total barrier layer width from the zirconium barrier layer's interface with the inner liner.  a cladding tube including a zirconium alloy outer circumferential substrate having an inner surface, a zirconium barrier layer bonded to the inner surface of the outer circumferential substrate and having a defined width between its inner and outer surfaces, and a zirconium alloy inner circumferential liner bonded to the inner surface of the zirconium barrier layer, wherein the barrier layer is alloyed with iron and/or nickel;  nuclear fuel material disposed within said tube; and  means for sealing the respective ends of said tube with said nuclear material therein.  (a) alloying elements are present at an excess concentration of at least about 0.03 weight percent iron and at least about 0.01 weight percent nickel at the zirconium barrier layer's interface with the inner liner, and  (b) substantially no excess alloying elements are present at a distance of 10% of the total barrier layer width from the zirconium barrier layer's interface with the inner liner.  a zirconium alloy outer circumferential substrate having an inner surface, the zirconium alloy also having one or more alloying elements;  a zirconium barrier layer bonded to the inner surface of the outer circumferential substrate and having an interior defined between inner and outer surfaces, the distance between the inner and outer surfaces defining a barrier layer width;  a diffusion layer extending from zirconium barrier layer inner surface into the barrier layer interior, the diffusion layer having a maximum concentration of said one or more alloying elements at the barrier layer inner surface and a minimum concentration of said one or more alloying elements in the barrier layer interior; and  a zirconium alloy inner circumferential liner bonded to the inner surface of the zirconium barrier layer. 2. The cladding tube of claim 1 wherein the zirconium barrier layer has concentration profile in which 3. The cladding tube of claim 2 wherein alloying elements are present at an excess concentration of at least about 0.03 weight percent iron and at least about 0.01 weight percent nickel at the zirconium barrier layer's interface with the outer circumferential substrate. 4. The cladding tube of claim 2 wherein the alloying elements are present in the zirconium barrier layer's interface with the inner liner in excess concentrations of about 0.03 to 0.4 weight percent iron, about 0.01 to 0.4 weight percent chromium, and about 0.01 to 0.2 weight percent nickel. 5. The cladding tube of claim 1 wherein the outer circumferential substrate comprises Zircaloy-2 or Zircaloy-4. 6. The cladding tube of claim 1 wherein the inner liner comprises a Zircaloy or modified Zircaloy. 7. The cladding tube of claim 6 wherein the inner liner comprises less than about 900 ppm oxygen by weight. 8. The cladding tube of claim 1 wherein the inner liner has an average thickness of between about 10 and 50 micrometers. 9. A fuel element comprising: 10. The fuel element of claim 9 wherein the zirconium barrier layer has concentration profile in which 11. The cladding tube of claim 10 wherein alloying elements are present at an excess concentration of at least about 0.03 weight percent iron and at least about 0.02 weight percent nickel at the zirconium barrier layer's interface with the outer circumferential substrate. 12. The cladding tube of claim 9 wherein the inner liner is made from an iron and nickel containing material selected from the group consisting of Zircaloy, modified Zircaloy, stainless steel, and Inconel. 13. A cladding tube having a cross-section, the cladding tube comprising: 14. The cladding tube of claim 13 wherein alloying elements are present at an excess concentration of at least about 0.03 weight percent iron and at least about 0.01 weight percent nickel at the zirconium barrier layer's interface with the inner liner, and substantially no alloying elements are present at the diffusion layer's interior side. 15. The cladding tube of claim 14 wherein the diffusion layer is at most between about 10% of the barrier layer width. 16. The cladding tube of claim 13 wherein alloying elements are present at an excess concentration of at least about 0.03 weight percent iron and at least about 0.01 weight percent nickel at the zirconium barrier layer's interface with the outer circumferential substrate. 17. The cladding tube of claim 15 wherein the diffusion layer is at most about 5% of the barrier layer width.