Patent Number: 061334987
Section: claims

1. A method for producing phosphate ceramic products, comprising the steps of: contacting a starter oxide with a phosphate-containing solution to create phosphates of the oxide in a slurry;  adding at least one reducing agent to the slurry;  mixing the slurry; and  allowing the slurry to set into a phosphate ceramic product.  combining the waste with a starter oxide to obtain a powder;  contacting the waste and powder mixture with a phosphate-containing solution to create phosphates of the oxide in a slurry;  adding at least one reducing agent, such that the oxidation state of the metal anion is reduced;  mixing the slurry; and  allowing the slurry to set into a phosphate ceramic product, thereby chemically and physically encapsulating the waste. 2. The method according to claim 1, wherein the step of adding the reducing agent includes adding the reducing agent to the starter oxide prior to contacting the starter oxide with the phosphate containing solution. 3. The method according to claim 1, wherein the reducing agent is a stannous salt. 4. The method according to claim 1, wherein the reducing agent is tin chloride. 5. The method according to claim 1, wherein the reducing agent is selected from the group consisting of sodium monosulfide, potassium monosulfide, calcium sulfide, iron sulfide, iron sulfate, sodium thiosulfate, sulfur dioxide, sodium borohydride, hydrazine, sodium bisulfite, calcium hydroxide, sodium hydroxide, sodium carbonate, sulfuric acid, and formic acid. 6. The method according to claim 1, further comprising the step of first heating the starter oxide in a reducing atmosphere. 7. The method according to claim 1, further comprising the step of first calcining the starter oxide in a vacuum. 8. The method according to claim 1, wherein the starter oxide is haematite. 9. The method according to claim 1, wherein the starter oxide is an oxide or hydroxide of an element or compound selected from the group consisting of aluminum, calcium, iron, magnesium, titanium, and zirconium, and combinations thereof. 10. The method according to claim 1, wherein the phosphate-containing solution is comprised of a solution selected from the group consisting of phosphoric acid and acid phosphate, and further comprises an acid phosphate of a compound selected from the group consisting of aluminum, ammonium, beryllium, calcium, iron, lanthanum, magnesium, magnesium-sodium, magnesium-potassium, sodium, yttrium, zinc, and zirconium, and combinations thereof. 11. The method according to claim 1, wherein the phosphate-containing solution is phosphoric acid having a concentration in the range of between about 30 and about 50 weight percent and wherein the starter oxide is haematite. 12. The method according to claim 1, wherein the phosphate-containing solution is a diluted phosphoric acid having a concentration in the range of between about 30 and about 40 weight percent, and wherein the starter oxide is selected from the group consisting of magnetite or iron oxide. 13. The method according to claim 1, further comprising the step of partially neutralizing the phosphate-containing solution prior to the step of contacting the starter oxide with the phosphate-containing solution, thereby decreasing the rate of reaction. 14. The method according to claim 1, further comprising the step of adding boric acid to the slurry to control the rate of reaction. 15. The method according to claim 1, further comprising the step of adding a waste material to the slurry, such that the waste material is encapsulated by the phosphate ceramic product. 16. The method according to claim 1, wherein the phosphate ceramic product is a glass-crystalline ceramic. 17. The phosphate ceramic product produced by the method of claim 1. 18. A method for stabilizing waste containing at least one metal anion, in a phosphate ceramic product, comprising the steps of: 19. The method according to claim 18, wherein the step of adding the reducing agent includes adding the reducing agent to the waste prior to combining the waste with the starter oxide powder. 20. The method according to claim 18, wherein the step of adding the reducing agent includes adding the reducing agent to the waste and powder mixture prior to contacting the waste and powder mixture with the phosphate-containing solution. 21. The method according to claim 18, wherein the step of adding the reducing agent includes adding the reducing agent to the slurry. 22. The method according to claim 18, wherein the reducing agent is a stannous salt. 23. The method according to claim 18, wherein the reducing agent is tin chloride. 24. The method according to claim 18, wherein the reducing agent is selected from the group consisting of sodium monosulfide, potassium monosulfide, calcium sulfide, iron sulfide, iron sulfate, sodium thiosulfate, sulfur dioxide, sodium borohydride, hydrazine, sodium bisulfite, calcium hydroxide, sodium hydroxide, sodium carbonate, sulfuric acid, and formic acid. 25. The method according to claim 18, wherein the starter oxide is an oxide or hydroxide of an element or compound selected from the group consisting of aluminum, calcium, iron, magnesium, titanium, and zirconium, and combinations thereof. 26. The method according to claim 18, wherein the phosphate-containing solution is comprised of a solution selected from the group consisting of phosphoric acid and acid phosphate, and further comprises an acid phosphate of a compound selected from the group consisting of aluminum, ammonium, beryllium, calcium, iron, lanthanum, magnesium, magnesium-sodium, magnesium-potassium, sodium, yttrium, zinc, and zirconium, and combinations thereof. 27. The method according to claim 18, wherein the metal anion is an anion of a metal selected from the group consisting of antimony, arsenic, chromium, mercury, selenium, and technetium. 28. The method according to claim 18, wherein the metal is chromium and the reducing agent is selected from the group consisting of tin chloride and sodium monosulfide. 29. The method according to claim 18, wherein the metal is selected from the group consisting of arsenic, selenium, and technetium and the reducing agent is tin chloride. 30. The method according to claim 18, wherein the metal is mercury and the reducing agent is sodium monosulfide. 31. The method according to claim 18, wherein the metal anion is chromate and the step of adding a reducing agent to the slurry reduces the valency of chromate from +6 to +4. 32. The method according to claim 18, wherein the metal anion is technetium-99 and the step of adding a reducing agent to the slurry reduces the valency of technetium-99 from +7 to +4. 33. The method according to claim 18, wherein the metal anion is technetium-99 and the pH of the slurry is maintained at no greater than 7.