Patent Number: 049922327
Section: claims

1. An improved method of utilizing hydrogen water chemistry in a boiling water reactor nuclear power plant, the plant including a reactor which boils water to produce a liquid phase and a steam phase, a turbine for extracting power from the steam phase, a condenser for condensing steam from which power has been extracted, and a feed water system returning the condensed steam as boiler feed water to the reactor, wherein the process of injecting hydrogen into the boiler feed water is utilized to reduce stress corrosion, the improvement comprising the step of reducing the transfer of radioactive gaseous nitrogen compounds from the liquid phase to the steam by inhibiting the formation of said nitrogen compounds in the liquid phase. 2. The process of claim 1, wherein said inhibiting step comprises chemically inhibiting the formation of volatile N-16 species in the liquid phase. 3. The process of claim 2, wherein said inhibiting step includes adding at least one free-radical scavenger to the boiler feedwater, whereby the evolution of gaseous nitrogen compounds is inhibited. 4. The method of claim 3, wherein said scavenger is selected from the group consisting of nitrous oxide, copper, zinc, low molecular weight alcohols and ketones, carbon dioxide, nitrite and nitrate. 5. The process of claim 1, wherein said inhibiting step comprises adjusting the pH of said water to a basic level in the range from about 7 to 8.6, whereby the evolution of volatile nitrogen compounds is inhibited. 6. The process of claim 1, wherein said inhibiting step comprises the use of reduced sparging in a core of said reactor. 7. The process of claim 1, wherein said inhibiting step comprises increasing the recirculation rate of water flow. 8. The process of claim 1, wherein said inhibiting step comprises adjusting a control rod pattern. 9. The process of claim 1, wherein said inhibiting step comprises raising the reactor water level. 10. The process of claim 1, wherein said inhibiting step comprises injecting said hydrogen into a preselected region in the recirculation system, said region having been selected to allow for reduced hydrogen utilization, whereby less radioactive volatile nitrogen is evolved. 11. The process of claim 10, wherein hydrogen is injected into a region below a jet pump inlet in the recirculation system. 12. The process of claim 11, wherein hydrogen is injected into a bypass region in a core inlet. 13. The process of claim 1, wherein the transfer of radioactive volatile nitrogen compounds is inhibited by use of a selective adsorbent to increase the hold-up time of the nitrogen compounds to allow for further decay. 14. The process of claim 1, wherein the transfer of radioactive volatile nitrogen compounds is inhibited by increasing the hold-up time in steam lines from the reactor. 15. The process of claim 1, wherein the transfer of radioactive volatile nitrogen compounds is inhibited by the use of surface catalysis to improve hydrogen utilization, whereby the evolution of gaseous nitrogen is decreased. 16. The process of claim 1, wherein the transfer of radioactive volatile nitrogen compounds is inhibited by the use of increased radiation to enhance hydrogen-oxygen recombination. 17. The process of claim 1, wherein the transfer of radioactive volatile nitrogen compounds is inhibited by operating at a more positive electropotential allowing less hydrogen addition. 18. An improved method of utilizing hydrogen water chemistry in a boiling water reactor nuclear power plant, the plant including a reactor which boils water to produce a liquid phase and a steam phase, the improvement comprising the step of adding a free-radical scavenger to the liquid phase to inhibit the transfer of gaseous nitrogen compounds from the liquid phase to the steam phase. 19. The method of claim 18, wherein said scavenger is selected from the group consisting of nitrous oxide, copper, zinc, low molecular weight alcohols and ketones, carbon dioxide, nitrite and nitrate.