Patent Number: 056132409
Section: claims

1. A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal comprising providing a substantially dry zeolite, the waste chloride salts, and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material; heating the zeolite, the waste chloride salts, and glass to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite; and thereafter maintaining the sodalite at a pressure and temperature sufficient to form a sodalite product near theoretical density. 2. The method of claim 1, wherein the zeolite is zeolite A or zeolite X or mixtures thereof and is saturated with radionuclides prior to conversion to sodalite. 3. The method of claim 2, wherein the glass is present in an amount of not less than about 5% by weight and sufficient unsaturated zeolite is present to result in occlusion of substantially all the radionuclides by the sodalite produced therefrom. 4. The method of claim 2, wherein the glass is a borosilicate glass present in the range of from about 5% to about 10% by weight of the zeolite. 5. The method of claim 1, wherein the waste chloride salt is principally a mixture of KCl and LiCl with radionuclides including the chlorides of La, Nd, Ce, Y, Sr, Cs, and Ba. 6. The method of claim 1, wherein the glass is initially present as glass frit. 7. The method of claim 1, wherein the sodalite is hot pressed at an elevated temperature of about 1200.degree. K. under pressure of about 20 MPa. 8. The method of claim 1, wherein the sodalite is cold pressed at about 40 MPa and thereafter heated to about 1200.degree. K. at 28 MPa. 9. A method of immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal comprising providing a mixture of substantially dry zeolite and radionuclide salt-occluded zeolite and glass, heating said mixture to a temperature effective to produce sodalite. 10. The method of claim 9, wherein the zeolite is in pellet or powder form. 11. The method of claim 9, wherein the glass is a borosilicate glass. 12. The method of claim 9, wherein the mixture is heated to a temperature of about 1000.degree. K. to effect production of sodalite. 13. The method of claim 12, wherein glass is present in an amount of least 5% by weight. 14. The method of claim 12, wherein glass is present in an amount of up to about 10% by weight. 15. The method of claim 9, wherein the zeolite is zeolite A or zeolite X or mixtures thereof. 16. The method of claim 9, wherein the zeolite includes a portion saturated with radionuclides and a portion substantially free of radionuclides to provide upon heating in the presence of glass frit sufficient sodalite to occlude substantially all of the radionuclides. 17. The method of claim 16, wherein the sodalite is subjected to heat and pressure for a time sufficient to densify the sodalite to near theoretical density.