Patent Number: 
Section: claims

1. A zirconium-based metal alloy composition, comprising:zirconium;a first metal element additive in which the permeability of hydrogen decreases with increasing temperatures at least over a temperature range extending from 350° C. to 750° C.;a second metal element additive having a solubility value in zirconium over the temperature range extending from 350° C. to 750° C., wherein at least one of a solubility value of the first metal element additive in the second metal element additive over the temperature range extending from 350° C. to 750° C. and a solubility value of the second metal element additive in the first metal element additive over the temperature range extending from 350° C. to 750° C. is higher than the solubility value of the second metal element additive in zirconium over the temperature range extending from 350° C. to 750° C.;wherein the zirconium-based metal alloy composition has a microstructure comprising:a first plurality of grains comprising a first phase, the first phase comprising a zirconium-based metal alloy; anda second phase disposed at grain boundaries of the first plurality of grains, the second phase comprising a metal alloy based on the second metal element additive. 2. The zirconium-based metal alloy composition of claim 1, wherein the zirconium comprises at least about ninety percent by weight (90.0 wt %) of the zirconium-based metal alloy composition. 3. The zirconium-based metal alloy composition of claim 1, wherein the first metal element additive comprises between about one-tenth of one percent by weight (0.1 wt %) and about nine percent by weight (9.0 wt %) of the zirconium-based metal alloy composition. 4. The zirconium-based metal alloy composition of claim 1, wherein the second metal element additive comprises between about one-hundredth of one percent by weight (0.01 wt %) and about one percent by weight (1.0 wt %) of the zirconium-based metal alloy composition. 5. The zirconium-based metal alloy composition of claim 1, wherein the first metal element additive comprises one or more elements selected from the group consisting of niobium (Nb), tantalum (Ta), and vanadium (V). 6. The zirconium-based metal alloy composition of claim 1, wherein the second metal element additive comprises one or more elements selected from the group consisting of molybdenum (Mo), antimony (Sb), and palladium (Pd). 7. The zirconium-based metal alloy composition of claim 1, wherein:the first metal element additive comprises one or more elements selected from the group consisting of niobium (Nb), tantalum (Ta), and vanadium (V); andthe second metal element additive comprises one or more elements selected from the group consisting of molybdenum (Mo), antimony (Sb), and palladium (Pd). 8. The zirconium-based metal alloy composition of claim 7, wherein:the first metal element additive comprises between about one-tenth of one percent by weight (0.1 wt %) and about nine percent by weight (9.0 wt %) of the zirconium-based metal alloy composition; andthe second metal element additive comprises between about one-hundredth of one percent by weight (0.01 wt %) and about one percent by weight (1.0 wt %) of the zirconium-based metal alloy composition. 9. The zirconium-based metal alloy composition of claim 8, wherein the zirconium comprises at least about ninety percent by weight (90.0 wt %) of the zirconium-based metal alloy composition. 10. The zirconium-based metal alloy composition of claim 1, wherein the solubility value of the second metal element additive in the first metal element additive over the temperature range extending from 350° C. to 750° C. is higher than the solubility value of the second metal element additive in zirconium over the temperature range extending from 350° C. to 750° C. 11. The zirconium-based metal alloy composition of claim 1, further comprising a third additive, the third additive comprising a grain-growth inhibitor that impedes the growth of grains of the zirconium-based metal alloy composition over the temperature range extending from 350° C. to 750° C. 12. The zirconium-based metal alloy composition of claim 11, wherein the third additive comprises one or more materials selected from the group consisting of thorium oxide, yttrium oxide, lanthanum oxide, neodymium oxide, cerium oxide, and dysprosium oxide. 13. The zirconium-based metal alloy composition of claim 11, wherein the third additive comprises between about six-hundredths of one percent by volume (0.06 wt %) and about six-tenths of one percent by volume (0.60 wt %) of the zirconium-based metal alloy composition. 14. The zirconium-based metal alloy composition of claim 1, wherein the grains of the first plurality of grains have an average grain size of between about twenty-five nanometers (25 nm) and about one hundred microns (100 μm). 15. The zirconium-based metal alloy composition of claim 14, wherein the grains of the first plurality of grains comprise between about ninety percent (90%) and about ninety-nine and one-half percent (99.5%) of the volume of the zirconium-based metal alloy composition. 16. The zirconium-based metal alloy composition of claim 1, wherein the second phase comprises a second plurality of grains having an average grain size of between about ten nanometers (10 nm) and about one thousand nanometers (1,000 nm). 17. The zirconium-based metal alloy composition of claim 1, wherein the second phase comprises between about three-tenths of one percent (0.3%) and about ten percent (10%) of the volume of the zirconium-based metal alloy composition. 18. The zirconium-based metal alloy composition of claim 1, further comprising a third additive, the third additive comprising a grain-growth inhibitor that impedes the growth of grains of the zirconium-based metal alloy composition over the temperature range extending from 350° C. to 750° C., and wherein the microstructure of the zirconium-based metal alloy composition further comprises a third plurality of grains disposed at grain boundaries of the first plurality of grains, the third plurality of grains comprising the third additive. 19. A nuclear fuel rod for use in a nuclear reaction, comprising:a volume of nuclear fuel material; anda cladding material at least partially surrounding the volume of nuclear fuel material, the cladding material comprising a zirconium-based metal alloy composition, comprising:zirconium;a first metal element additive in which the permeability of hydrogen decreases with increasing temperatures at least over a temperature range extending from 350° C. to 750° C.;a second metal element additive having a solubility value in zirconium over the temperature range extending from 350° C. to 750° C., wherein at least one of a solubility value of the first metal element additive in the second metal element additive over the temperature range extending from 350° C. to 750° C. and a solubility value of the second metal element additive in the first metal element additive over the temperature range extending from 350° C. to 750° C. is higher than the solubility value of the second metal element additive in zirconium over the temperature range extending from 350° C. to 750° C.;wherein the zirconium-based metal alloy composition has a microstructure comprising:a first plurality of grains comprising a zirconium-based metal alloy; anda second plurality of grains disposed at grain boundaries of the first plurality of grains, the second plurality of grains comprising a metal alloy based on the second metal element additive. 20. The nuclear fuel rod of claim 19, wherein:the first metal element additive comprises one or more elements selected from the group consisting of niobium (Nb), tantalum (Ta), and vanadium (V); andthe second metal element additive comprises one or more elements selected from the group consisting of molybdenum (Mo), antimony (Sb), and palladium (Pd). 21. The nuclear fuel rod of claim 19, wherein:the first metal element additive comprises between about one-tenth of one percent by weight (0.1 wt %) and about nine percent by weight (9.0 wt %) of the zirconium-based metal alloy composition; andthe second metal element additive comprises between about one-hundredth of one percent by weight (0.01 wt %) and about one percent by weight (1.0 wt %) of the zirconium-based metal alloy composition. 22. The nuclear fuel rod of claim 19, wherein the zirconium comprises at least about ninety percent by weight (90.0 wt %) of the zirconium-based metal alloy composition. 23. The nuclear fuel rod of claim 19, further comprising a third additive, the third additive comprising a grain-growth inhibitor that impedes the growth of grains of the zirconium-based metal alloy composition over the temperature range extending from 350° C. to 750° C. 24. The nuclear fuel rod of claim 23, wherein the third additive comprises between about six-hundredths of one percent by volume (0.06 wt %) and about six-tenths one percent by volume (0.6 wt %) of the zirconium-based metal alloy composition. 25. The nuclear fuel rod of claim 19, wherein the grains of the first plurality of grains have an average grain size of between about twenty-five nanometers (25 nm) and about one hundred microns (100 μm). 26. The nuclear fuel rod of claim 25, wherein the grains of the first plurality of grains comprise between about ninety percent (90%) and about ninety-nine and one-half percent (99.5%) of the volume of the zirconium-based metal alloy composition. 27. The nuclear fuel rod of claim 19, wherein the grains of the second plurality of grains have an average grain size of between about ten nanometers (10 nm) and about one thousand nanometers (1,000 nm). 28. The nuclear fuel rod of claim 19, wherein the grains of the second plurality of grains comprise between about three-tenths of one percent (0.3%) and about ten percent (10%) of the volume of the zirconium-based metal alloy composition. 29. The nuclear fuel rod of claim 19, wherein the zirconium-based metal alloy composition further comprises a third additive, the third additive comprising a grain-growth inhibitor that impedes the growth of grains of the zirconium-based metal alloy composition over the temperature range extending from 350° C. to 750° C., and wherein the microstructure of the zirconium-based metal alloy composition further comprises a third plurality of grains disposed at grain boundaries of the first plurality of grains, the third plurality of grains comprising the third additive. 30. A nuclear reactor, comprising:a reactor core for generating thermal energy, comprising:a liquid; andat least one fuel rod disposed within the liquid, the at least one fuel rod including at least one nuclear fuel material at least partially surrounded by a cladding material, the cladding material comprising a zirconium-based metal alloy composition, comprising:zirconium;a first metal element additive in which the permeability of hydrogen decreases with increasing temperatures at least over a temperature range extending from 350° C. to 750° C.;a second metal element additive having a solubility value in zirconium over the temperature range extending from 350° C. to 750° C., wherein at least one of a solubility value of the first metal element additive in the second metal element additive over the temperature range extending from 350° C. to 750° C. and a solubility value of the second metal element additive in the first metal element additive over the temperature range extending from 350° C. to 750° C. is higher than the solubility value of the second metal element additive in zirconium over the temperature range extending from 350° C. to 750° C.;wherein the zirconium-based metal alloy composition has a microstructure comprising:a first plurality of grains comprising a zirconium-based metal alloy; anda second plurality of grains disposed at grain boundaries of the first plurality of grains, the second plurality of grains comprising a metal alloy based on the second metal element additive. 31. A method of forming a zirconium-based metal alloy composition, comprising:mixing zirconium particles, first metal element additive particles, second metal element additive particles, and third additive particles to form a particle mixture;wherein the first metal element additive particles comprise one or more elements in which the permeability of hydrogen decreases with increasing temperatures at least over a temperature range extending from 350° C. to 750° C.;wherein the second metal element additive particles comprise an element having a solubility value in zirconium over the temperature range extending from 350° C. to 750° C., and wherein at least one of a solubility value of the element of the first metal element additive particles in the element of the second metal element additive particles over the temperature range extending from 350° C. to 750° C. and a solubility value of the element of the second metal element additive particles in the element of the first metal element additive particles over the temperature range extending from 350° C. to 750° C. is higher than the solubility value of the element of the second metal element additive particles in zirconium over the temperature range extending from 350° C. to 750° C.;wherein the third additive particles comprise a grain-growth inhibitor that impedes the growth of grains of a zirconium-based metal alloy composition over the temperature range extending from 350° C. to 750° C.;pressing the particle mixture to form a green body; andsintering the green body. 32. The method of claim 31, wherein sintering the green body comprises sublimating at least one component of the third additive particles. 33. The method of claim 31, wherein:the first metal element additive particles comprise to comprise one or more elements from the group consisting of niobium (Nb), tantalum (Ta), and vanadium (V); andthe second metal element additive particles comprise one or more elements from the group consisting of molybdenum (Mo), antimony (Sb), and palladium (Pd). 34. The method of claim 33, wherein:the first metal element additive particles comprise between about one-tenth of one percent by weight (0.1 wt %) and about nine percent by weight (9.0 wt %) of the zirconium-based metal alloy composition; andthe second metal element additive particles comprise between about one-hundredth of one percent by weight (0.01 wt %) and about one percent by weight (1.0 wt %) of the zirconium-based metal alloy composition. 35. The method of claim 34, wherein the zirconium particles comprise at least about ninety percent by weight (90.0 wt %) of the zirconium-based metal alloy composition. 36. The method of claim 31, wherein the third additive particles comprise between about six-hundredths of one percent by volume (0.06 wt %) and about six-tenths of one percent by volume (0.6 wt %) of the zirconium-based metal alloy composition. 37. The method of claim 31, further comprising forming a microstructure comprising:a first plurality of grains comprising a zirconium-based metal alloy; anda second plurality of grains disposed at grain boundaries of the first plurality of grains, the second plurality of grains comprising a metal alloy based on the second metal element additive particles. 38. The method of claim 37, further comprising forming the grains of the first plurality of grains to have an average grain size of between about twenty-five nanometers (25 nm) and about one hundred microns (100 μm). 39. The method of claim 38, further comprising forming the grains of the first plurality of grains to comprise between about ninety percent (90%) and about ninety-nine and one-half percent (99.5%) of the volume of the zirconium-based metal alloy composition. 40. The method of claim 37, further comprising forming the grains of the second plurality of grains to have an average grain size of between about ten nanometers (10 nm) and about one thousand nanometers (1,000 nm). 41. The method of claim 40, further comprising forming the grains of the second plurality of grains to comprise between about three-tenths of one percent (0.3%) and about ten percent (10%) of the volume of the zirconium-based metal alloy composition. 42. The method of claim 37, further comprising forming the microstructure of the zirconium-based metal alloy composition to comprise a third plurality of grains disposed at grain boundaries of the first plurality of grains, the third plurality of grains comprising a material formed from the third additive particles.