Patent Number: 044951400
Section: claims

1. The method of permanently deactivating, in the event of an emergency, a nuclear reactor whose working fluid is a gas and whose fuel is contained in a body having channels for conducting the working fluid, the said method comprising deriving borane from boron trifluoride etherate in which the boron is substantially enriched in B.sub.10, reacting said borane with one or more of the class consisting of unsaturated hydrocarbons and ammonia to produce respectively one or more of the class consisting of carboranes, alkyl boranes, and alkyl diboranes or boron nitrogen products, (the carboranes, boranes, diboranes, and carbon nitrogen products being all herein referred to as last-named compounds), injecting one or more of said last-named compounds into said working fluid so that said compounds are circulated with said working fluid through said channels of said body, while said compounds are in said body converting said compounds into one or more of the class of materials consisting of boron and the highly-refractory compounds of boron and carbon and/or boron and nitrogen, and adhering said material to the walls of said channels, sufficient compounds being converted to provide sufficient converted material to deactivate said nuclear reactor permanently. 2. The method of permanently deactivating, in the event of an emergency, a nuclear reactor whose working fluid is a gas and whose fuel is contained in a body having channels for conducting the working fluid, the said method comprising: responsive to the occurrence of said emergency generating one or more compounds of boron containing one or more of the class consisting of carbon and nitrogen, circulating said compound in said working fluid as a fluid through said channels, while said compounds are in said body converting said compounds into one or more of the class of materials consisting of boron and of highly-refractory compounds of boron and carbon and boron and nitrogen and adhering said material to the walls of said channels, sufficient highly-refractory compounds being generated to provide sufficient converted material to deactivate said nuclear reactor permanently. 3. The method of claim 1 wherein the boron in the compounds is substantially enriched in the isotope B.sub.10. 4. The method of claim 1 for use with a nuclear reactor having a core whose coolant channels are composed of graphite wherein the converted compounds of boron are converted into boron nitride. 5. The method of claim 1 including the additional step of reacting diborane with alkyl hydrocarbons to produce the heat-sensitive compounds alkydiboranes for circulation through the fluid channels and conversion. 6. The method of claim 1 including the additional step of reacting diborane with acetylene to produce heat-sensitive carboranes compounds for circulation through said channels and conversion. 7. The method of claim 1 including the step of reacting diborane with ammonia to produce compounds of boron and nitrogen for circulation through the channels and conversion. 8. The method of claim 5 wherein the diborane and alkyborane are reacted predominately in the coolant of the nuclear reactor. 9. The method of claim 6 wherein the diborane and the acetylene are reacted predominately in the coolant of the nuclear reactor. 10. The method of claim 7 wherein the diborane and ammonia are reacted predominately in the coolant of the nuclear reactor. 11. The method of claim 1 wherein the fluid compound is repeatedly circulated through the fluid channels, the circulation through the fluid channels taking place in a short-time interval such that a number of passes sufficient to deactivate the reactor are completed before the emergency event can result in the catastrophe which the method is carried out to preclude. 12. The method of permanently deactivating the nuclear reactor, which constitutes the primary energy source of a propulsion plant of a ship to preclude an increase in reactivity resulting from the flooding of the core, the fuel of said nuclear reactor being embedded in a body having fluid channels accessible to the fuel and the working fluid of said nuclear reactor being a gas, the said method comprising, responsive to the flooding of the core on the sinking of the ship, generating compounds of boron containing one or more of the class consisting of carbon or nitrogen, circulating said compounds in said working fluid as a fluid through said fluid channels in said body, while said compounds are in said body converting said compounds into one or more of the class of materials consisting of boron and of highly-refractory compounds of boron, carbon and nitrogen, and adhering said material to the walls of said channels to deactivate said nuclear reactor, sufficient highly-refractory compounds being generated to provide sufficient converted material to deactivate said nuclear reactor permanently, said compounds being circulated and converted and said nuclear reactor being deactivated in a time interval that is so short that said reactor is deactivated before flooding occurs. 13. The method of claim 12 wherein the compounds are generated in the coolant. 14. The method of permanently deactivating, in the event of an emergency resulting in increased core reactivity, a nuclear reactor whose working fluid is a gas and whose fuel is contained in a body having channels for conducting said working fluid, the said method comprising, responsive to the occurrence of said emergency, injecting in said working fluid as a fluid a metal borohydride, circulating said metal borohydride as a fluid in said working fluid through said channels, while said metal borohydride is in said body dissociating said metal borohydride into a material of one of the class consisting of metal borides and boron, and adhering said material to the walls of said channels, sufficient metal borohydride being injected to provide sufficient material to deactivate said nuclear reactor permanently. 15. The method of claim 14 wherein the metal borohydride is one or more of the class consisting of thorium borohydride and hafnium borohydride. 16. The method of claim 1 wherein the highly-refractory compounds of boron and carbon and boron and nitrogen include one or more of the class consisting of boron, boron carbide, and boron nitride.