Patent Number: 046831142
Section: claims

1. The method of forming nuclar fuel pellets having a burnable absorber combined therewith comprising: combining discrete particles of a boron-containing burnable absorber and discrete particles of a boroncontaining glass composition to form a coating mixture, said boron-containing glass composition comprising 20-30 percent by weight B.sub.2 O.sub.3 ;  applying said coating mixture to the surface of nuclear fuel pellets;  heating said nuclear fuel pellets having said coating mixture on the surface thereof, to an elevated temperature sufficient to melt said boron-containing glass, and incorporate said boron-containing burnable absorber in the resultant melt while preventing reaction between the burnable absorber and the boron-containing glass; and  cooling said pellets.  20-80 percent by weight of boron-containing burnable absorber; and  8- 20percent by weight of a boron-containing glass composition containing, in percent by weight;  30-60 percent SiO.sub.2  20-30 percent B.sub.2 O.sub.3  5-15 percent of an alkali oxide selected from the group consisting of Na.sub.2 O and K.sub.2 O  5-15 percent BaO  5-15 percent CaO  5-15 percent Al.sub.2 O.sub.3.  3- 60% SiO.sub.2  20-30% B.sub.2 O.sub.3  5-15% BaO  5-15% CaO  5-15% Al.sub.2 O.sub.3 in addition to 5-15% alkali oxide selected from the group consisting of Na.sub.2 O and K.sub.2 O. 2. The method as defined in claim 1 wherein said discrete particles to form said coating mixture comprise 20-80 percent by weight of said boron-containing burnable absorber and 80-20 percent by weight of said boron-containing glass composition. 3. The method as defined in claim 2 wherein said boron-containing glass composition consists essentially of 30-60 percent by weight SiO.sub.2, 20-30 percent by weight B.sub.2 O.sub.3, 5-15 percent by weight of an alkali oxide selected from the group consisting of Na.sub.2 O and K.sub.2 O, 5-15 percent by weight BaO, 5-15 percent by weight CaO, and 5-15 percent by weight Al.sub.2 O.sub.3. 4. The method as defined in claim 3 wherein said boron-containing burnable absorber is boron carbide. 5. The method as defined in claim 4 wherein said boron-containing glass composition consists essentially of 40 percent by weight SiO.sub.2, 20 percent by weight B.sub.2 O.sub.3, 10 percent by weight Na.sub.2 O, 10 percent by weight BaO, 10 percent by weight CaO, and 10 percent by weight Al.sub.2 O.sub.3. 6. The method as defined in claim 2 wherein said discrete particles of boron-containing burnable absorber and said discrete particles of boron-containing glass are all smaller than 325 mesh. 7. The method as defined in claim 6 wherein said discrete particles of boron-containing burnable absorber are of a size such that at least 90 percent of the particles are less than 10 microns in diameter. 8. The method as defined in claim 7 wherein said discrete particles of boron-containing glass are of a size of 5 microns or less in diameter. 9. The method as defined in claim 2 wherein said nuclear fuel pellets having said coating mixture on the surface thereof are heated to a temperature of between about 900.degree.-1100.degree. C. 10. The method as defined in claim 9 wherein said nuclear fuel pellets having said coating mixture on the surface thereof are heated to a temperature of between about 1000.degree.-1050.degree. C. 11. The method as defined in claim 9 wherein said heating is in a hydrogen atmosphere. 12. The method as defined in claim 9 wherein said heating is in an argon atmosphere. 13. The method as defined in claim 1 wherein the resultant coating on the nuclear fuel pellets is of a thickness of one mil or less. 14. The method as defined in claim 13 wherein the resultant coating contains an amount of B.sup.10 equivalent to about 1 to 2 mg per inch of pellet length. 15. The method as defined in claim 1 wherein after said applying of the coating mixture to the surface of the pellets and prior to said heating, a layer of said boron-containing glass composition is applied over said coating mixture. 16. A nuclear fuel pellet produced by the process of claim 1. 17. A nuclear fuel pellet produced by the process of claim 15. 18. A burnable absorber-containing coating composition for use in forming nuclear fuel pellets having a burnable absorber combined therewith comprising a mixture of discrete particles of: 19. A burnable absorber-containing coating composition as defined in claim 18 wherein said boron-containing burnable absorber is boron carbide. 20. A burnable absorber-containing coating composition as defined in claim 19 wherein the amount of said SiO.sub.2 is 40 percent, said B.sub.2 O.sub.3 is 20 percent, said Na.sub.2 O is 10 percent, said BaO is 10 percent, said CaO is 10 percent, and said Al.sub.2 O.sub.3 is 10 percent. 21. A burnable absorber-containing coating composition as defined in claim 18 wherein said discrete particles in said mixture are all below 325 mesh. 22. A burnable absorber-containing coating composition as defined in claim 21 wherein said discrete particles of boron carbide are of a size such that at least 90 percent of the particles are less than 10 microns in diameter. 23. The burnable absorber-containing coating composition as defined in claim 22 wherein said discrete particles of boron-containing glass are of a size of 5 microns or less in diameter. 24. A burnable absorber-containing coating composition for use in coating nuclear fuel pellets, said coating composition comprising a mixture of discrete particles of a boron-containing burnable absorber and discrete particles of a boron-containing glass composition, said boron-containing glass composition containing 5-15% of an alkali oxide selected from the group consisting of Na.sub.2 O and K.sub.2 O, the alkali oxide acting to increase the thermal expansion coefficient of the boron-containing glass composition to result in a burnable absorber-containing coating composition having a coefficient of thermal expansion greater than or equal to the coefficient of thermal expansion of an uncoated nuclear fuel pellet. 25. The burnable absorber-containing coating composition as defined in claim 24 wherein said boron-containing glass composition comprises, in percent by weight; 26. The burnable absorber-containing coating composition as defined in claim 25 wherein said boron-containing burnable absorber is boron carbide.