Patent Number: 045086419
Section: claims

1. A process for the decontamination of steel surfaces by removal of the contaminated surface layer with an aqueous decontaminating solution in a recirculation loop and for final treating the used aqueous solution after removal of the surface layer for waste disposal, which process comprises: (a.sup.1) contacting the steel surfaces with an aqueous decontaminating solution comprising at least one acid selected from the group consisting of formic acid and acetic acid, and at least one reducing agent selected from the group consisting of formaldehyde and acetaldehyde, in a concentration to hold dissolved Fe.sup.2+ -ions stably in the solution;  (b.sup.1) monitoring the concentration of dissolved Fe.sup.2+ -ions, acid and aldehyde of the decontaminating solution during the dissolution process;  (c.sup.1) treating the used decontaminating solution to precipitate iron values dissolved therein in the form of iron hydroxide or in the form of water-insoluble iron (III) compounds, and separating precipitated iron compounds from the liquid by filtering; and  (d.sup.1) treating the aqueous solution remaining after said precipitation to obtain a regenerated decontaminating solution having the desired content of acid and aldehyde, and recircuate it for a new dissolution cycle; and  (e.sup.1) treating the used decontaminating solution to precipitate iron values dissolved therein in the form of iron hydroxide or in the form of water-insoluble iron (III)-compounds and separating precipitated iron compounds from the liquid by filtering;  (f.sup.1) decomposing the precipitated iron compounds of steps (c.sup.1) and (e.sup.1) thermally and/or catalytically into iron oxide-containing radioactive materials- and into radioactivity-free gaseous decomposition products, and subjecting the iron oxide to nuclear waste disposal by mixing it with cement; and  (g.sup.1) oxidizing the radioactivity-free solution of step (e.sup.1) with an oxidizing agent and decomposing therein dissolved formate or acetate salts.  (a.sup.2) contacting the steel surface with an aqueous decontaminating solution comprising formic acid and formaldehyde as a reducing agent in a concentration to hold dissolved Fe.sup.2+ -ions stably in the solution;  (b.sup.2) monitoring the concentration of dissolved Fe.sup.2+ -ions, formic acid, and formaldehyde of the decontaminating solution during the dissolution process;  (c.sup.2) treating the used decontaminating solution by electrolysis to precipitate iron values dissolved in the solution as metallic iron for waste disposal and to oxidize acid-ions to formic acid; and  (d.sup.2) treating the liquid of the electrolytic process to obtain a regenerated decontaminating solution having the desired content of formic acid and formaldehyde and recirculate it for a new dissolution cycle; and  (e.sup.2) treating the used decontaminating solution to precipitate iron values dissolved therein in the form of iron hydroxide or in the form of water-insoluble iron (III)-compounds and separating precipitated iron compounds from the liquid by filtering;  (f.sup.2) decomposing the precipitated iron compounds of steps (c.sup.2) and (e.sup.2) thermally and/or catalytically into iron oxide--containing radioactive materials--and into radioactivity-free gaseous decomposition products,  (g.sup.2) oxidizing the radioactivity-free solution of step (e.sup.1) with an oxidizing agent and decomposing therein dissolved formate or acetate salts.  (a.sup.3) contacting the steel surfaces with an aqueous decontaminating solution comprising formic acid and formaldehyde as a reducing agent in a concentration to hold dissolved Fe.sup.2+ -ions stably in the solution;  (b.sup.3) monitoring the concentration of Fe.sup.2+ -ions, formic acid and formaldehyde of the decontaminating solution during the dissolution process;  (c.sup.3) treating the used decontaminating solution by electrolysis to precipitate iron values dissolved in the solution as metallic iron--containing radioactive materials--and to decomposite the aqueous solution to gaseous decomposition products; and  (d.sup.3) treating the precipitated iron for waste disposal. 2. A process according to claim 1, wherein before precipitation of the iron in the used decontaminating solution, dissolved iron (II) compounds are oxidized to iron (III) compounds by the addition of an oxidizing agent and are precipitated as water-insoluble iron (III) compounds. 3. A process according to claim 1, wherein, to precipitate iron hydroxide or iron (III) compounds from the used decontaminating solution, alkali metal hydroxide or carbonate is added and after separation of the precipitate from the liquid the alkali metal salt present therein is oxidatively decomposed into alkali metal hydroxide, alkali metal carbonate, carbon dioxide and water. 4. A process according to claim 3, wherein the precipitation of water-insoluble iron compounds from the used decontaminating solution is carried out in a batch process wherein after the precipitation of a first batch of decontaminating solution and the oxidizing treatment of the separated liquid the thus treated liquid is used for precipitation of the iron compounds from a second batch of decontaminating liquid and the process is repeated until all the iron is precipitated from the whole of the decontaminating solution. 5. A process according to claim 1, wherein before filtering the precipitate of a preceding precipitation process is added to the used decontaminating solution as a flocculating agent. 6. A process according to claim 1, wherein the mixing of the precipitate with cement is such that a ferrocement-like product is produced. 7. A process for the decontamination of steel surfaces by removal of the contaminated surface layer with an aqueous decontaminating solution in a recirculation loop and for final treating the aqueous solution after removal of the surface layer for waste disposal, which process comprises: 8. A process as claimed in claim 7, wherein the electrolysis is conducted with an iron cathode. 9. A process according to claim 7 wherein before precipitation of the iron in the used decontaminating solution, dissolved iron (II) compounds are oxidized to iron (III) compounds by the addition of an oxidizing agent. 10. A process according to claim 7 wherein, to precipitate iron hydroxide or iron (III) compounds from the used decontaminating solution, alkali metal hydroxide or carbonate is added and after separation of the precipitate from the liquid the alkali metal salt present therein is oxidatively decomposed into alkali metal hydroxide, alakali metal carbonate, carbon dioxide and water. 11. A process according to claim 10, wherein the precipitation of water-insoluble iron compounds from the used decontaminating solution is carried out in a batch process wherein after the precipitation of a first batch of decontaminating solution and the oxidizing treatment of the separated liquid the thus treated liquid is used for precipitation of the iron compounds from a second batch of decontaminating liquid and the process is repeated until all the iron is precipitated from the whole of the decontaminating solution. 12. A process according to claim 7, wherein before filtering the precipitate of a preceding precipitation process is added to the used decontaminating solution as a flocculating agent. 13. A process according to claim 7, wherein before the mixing of the precipitate with cement is such that a ferrocement-like product is produced. 14. A process for the decontamination of steel surfaces with an aqueous decontaminating solution and for treating the aqueous solution after decontamination of the surfaces for waste disposal, which process comprises the steps: 15. A process according to claim 14, wherein the aqueous decontaminating solution is recirculated in a loop for the treatment of the contaminated steel surfaces, wherein during the removal of the contaminated surface layer the used decontaminating solution is treated by electrolysis to precipitate the dissolved iron and to oxidize acid-ions to formic acid, and liquid of the electrolysis process is regenerated to decontaminating solution having the desired content of formic acid and formaldehyde and is recirculated for a new dissolution cycle. 16. A process according to claim 14, wherein the electrolysis is conducted with an iron cathode.