Patent Number: 055704689
Section: description

DESCRIPTION OF THE PREFERRED EMBODIMENT In FIG. 1, numeral 4 indicates a washing device, which includes a spray device 1 for ejecting liquid, a solvent filtering device 2, and a chelate liquid filtering device 3. The spray device 1, which is not shown in detail in the drawing, comprises a pipe provided with a multitude of nozzles. As shown in FIGS. 3 and 4, the washing device 4 comprises a frame 15, to which is provided a main vessel 18 having an opening 16 and a lid 17. A decontamination vessel 22 is rotatably arranged in the main vessel 18. Numeral 19 indicates a multitude of pores formed in the decontamination vessel 22. As shown in FIGS. 5 and 6, the decontamination vessel 22 is formed as a cylindrical body formed of wedge wires 25, which are supported by support bars 26 such that slits are defined between these wedge wires. These slits constitute the pores 19. Thus, in this invention, the term "pores" includes "slits". Numeral 28 indicates an end plate. Numeral 20 indicates an opening, and numeral 21 indicates an opening/closing cover having a multitude of pores 19 like the decontamination vessel 22. The pores 19 have a width or size that is smaller than that of the shot blasting grit. Referring to FIG. 4, numeral 29 indicates rotating members, which consist, for example, of racing rollers. These rotating members support decontamination vessel 22. The decontamination vessel 22 is driven by a driving device 23. Further, the decontamination vessel 22 has a suspension lug 30, by means of which the decontamination vessel 22 can be suspended from an overhead travelling hoist (not shown) so that it can be moved to another main vessel 18 (not shown). Referring to FIG. 1, numeral 5 indicates a solvent supply device, which comprises a solvent vessel 31 containing, for example, methylene chloride, and a first pump 32. The solvent is circulated by way of the spray device 1 and the solvent filtering device 2. Numeral 6 indicates a solvent purifying device which purifies the solvent by heating, vaporizing, and cooling. The solvent purifying device 6 has a second pump 33 and is connected to a rinse solvent supply device 7 comprising rinse solvent vessel 34 for rinsing and a third pump 35. Numeral 36 indicates a fourth pump. Numeral 8 indicates a chelate liquid supply device, which circulates the chelate liquid by way of a chelate liquid vessel 37, a fifth pump 38, the spray device 1, and the chelate liquid filtering device 3, and, then, back to the chelate liquid vessel 37. Numeral 10 indicates an electrolytic processing device for electrolyzing the chelate liquid which contains metal ions. In the electrolytic processing device 10, the chelate liquid is electrolyzed to thereby lose its chelating property. In a precipitating device 11, a precipitant is added to the chelate liquid which has lost its chelating property, thereby generating floes in the liquid. These flocs are removed by filtering the liquid by a filtering device Examples of the precipitant include sodium hydroxide, aqueous ammonia, potassium hexacyanoferrate, and high-molecular coagulant. The water generated in the filtering device 9 is supplied to an ion exchange device 39, where it becomes clean water. A chelating agent is added to the clean water in a chelating agent supply device 12 and the resulting solution is supplied to the chelate liquid vessel 37 again. Numerals 38, 40, and 42 indicate fifth, sixth. seventh and eighth pumps, respectively. The clean water generated in the ion exchange device 39 may be discharged. In FIG. 1, numeral 55 indicates a storage vessel, and, in FIG. 2, numeral 56 indicates an oscillating sieve for removing foreign matter from the grit. Numeral 13 indicates a hot air generator, which comprises a heater 43 and a compressed air generator 44 and supplies hot air to the main vessel 18. Referring to FIG. 7, numeral 46 indicates an apparatus for inspecting substances contaminated with radioactivity, mainly used to inspect shot blast radioactivity and also available for inspection of other objects, for example, machine parts. Numeral 47 indicates a belt conveyor, which is made to intermittently run in the direction indicated by the arrow A47. Numeral 48 indicates a scintillation counter, which is formed as an elongated, band-like component extending perpendicular to the belt conveyor 47 so as to cover the entire width of the conveyor 47. The scintillation counter 48 is connected to a computerized control unit 49, which has a memory bank and is connected to a change-direction device 50 provided on the belt conveyor 47. Numeral 51 indicates a hopper. Numeral 52 indicates a defective-item receiver, and numeral 53 indicates a non-defective-item receiver. The shot blasting grit fed from the hopper 51 is intermittently moved in the direction of the arrow A47 by the belt conveyor 47, and is inspected for radioactivity, block by block each movement. A block in which radioactivity has been detected is memorized in the computerized control unit 49, and is removed by being changed in direction by the change-direction device 50 upon reaching the same. In this way, shot blasting grit free from radioactivity is collected. The operation of the apparatus of this invention will now be described. First, grit contaminated with radioactivity and a polishing-cleaning material are fed into the decontamination vessel 22. An example of the polishing-cleaning material is a ceramic material. Then, the opening 20 is closed, and the opening 16 of the main vessel 18 is also closed. The decontamination vessel 22 is then rotated, and methylene chloride is ejected from the spray device 1, with the gas collecting device 14 being actuated. The grit is washed by the methylene chloride, and any radioactive paint or the like coexisting with the grit is removed therefrom, thereby decontaminating the grit. Such contaminated paint or the like is removed through filtration by the solvent filtering device 2. Next, this methylene chloride is drained from the main vessel 18, and the grit is dried by hot air supplied from the hot air generator 13. Subsequently, chelate liquid, supplied from the chelate liquid supply device 8, is ejected from the spray device 1, and the decontamination vessel 22 is rotated. The chelate liquid removes the radioactive metal ions in the grit, and is filtered by the chelate liquid filtering vessel before it returns to the chelate liquid vessel 37 to be circulated for decontamination. The chelate liquid is then electrolyzed by the electrolytic processing device 10 to thereby lose its chelating property. Then a precipitant is added to the chelate liquid, thereby forming floes in the liquid. These floes are removed by filtering the liquid by the filtering device 9. Then, the liquid is turned into clean water by the ion exchange device 39, supplied with fresh chelating agent from the chelating agent supply device 12 to be regenerated, and then returned to the chelate liquid supply device 8. Part of the methylene chloride is transferred from the solvent vessel 31 to the solvent purifying device 6, where it is heated to be gasified and then cooled to be liquefied, whereby the methylene chloride is purified, and thereafter transferred to the rinse solvent vessel 34. Next, the chelate liquid is drained from the main vessel 18, and hot air is supplied from the hot air generator for drying of the grit. The temperature of this hot air is 70.degree. C., which is much higher than the boiling point of methylene chloride. Accordingly, the temperature of the grit is raised to approximately 70.degree. C. However, even after the above draining, some chelate liquid still remains in the grit, so that the drying process takes time and is difficultto perform. In this condition, a rinse solvent consisting of methylene chloride is supplied. This rinse solvent is then rapidly vaporized, and, by the force of this vaporization, the remaining chelate liquid is separated from the grit. The liquid is then brought to the filtering device 2 by the subsequently fed rinse solvent, and is filtered by the filtering device 2 before it is recovered. The rinse solvent containing the chelate liquid is separated therefrom by an oil water separator 46, which effects separation through difference in specific weight, and is recovered in the solvent vessel 31. The grit in the main vessel 18 has been heated, so that the remaining methylene chloride is immediately vaporized to effect drying of the grit, with the result that the removal of the chelate liquid takes place quickly. Advantages of the method of this invention will now be described. In the method of this invention, constructed as described above, the chelate liquid containing contaminated metal ions and remaining on the substance contaminated with radioactivity and adhering thereto, is separated from the contaminated substance by a rapid vaporization of the solvent, and then drained along with the subsequently supplied solvent, thereby effectively decontaminating the substance. Further, the draining of the solvent immediately results in a dried state, so that the bothersome operation of removing the remaining chelate liquid by drying process can be eliminated. This can be achieved very effectively when the solvent is methylene chloride. When the contaminated substance is shot blasting grit, which consists of fine particles, it is possible to quickly and effectively perform the difficult operations of separating and removing the remaining and adhering chelate liquid. Next, advantages of the apparatus of this invention will be described. In the apparatus of this invention, constructed as described above, a single apparatus can perform all of the following processes: decontamination using a solvent, decontamination using a chelate liquid, rinsing using the solvent, in which rapid separation and removal of remaining chelate liquid is effected, drying of the grit, and so on. The chelate liquid is electrolyzed by an electrolytic device, and in the precipitating device a precipitant is supplied to the chelate liquid which has lost its chelating property by the electrolysis, thereby forming flocs in the liquid. These floes are removed by filtering the liquid by the filtering device. Then, the liquid is turned into clean water by the ion exchange device. By supplying some chelating agent to this clean water, the liquid can be recycled. Thus, a single apparatus can perform all of the decontamination processes. Accordingly, the installation space for the apparatus can be reduced. Further, there is no need to provide complicated devices for moving the contaminated substance between a number of decontaminating apparatuses, nor is it necessary to perform the bothersome operation of moving the contaminated substance from one apparatus to another. In addition, since the pores 19 of the decontamination vessel 22 have a size or width which is smaller than that of the grit, it is possible for the grit to be decontaminated effectively. Further, since the decontamination vessel 22 has a polishing-cleaning material, polishing and cleaning can be conducted simultaneously with the so-called running-liquid washing using the solvent and the chelate liquid, thereby conducting decontamination effectively. Further, in an aspect of the invention where the decontamination vessel 22 is detachably formed with respect to the main vessel 18, and a plurality of main vessels 18 and a plurality of decontamination vessels 22 are formed, it is possible to separately conduct a process requiring a long time and that requiring a relatively short time, thereby achieving an improvement in operational efficiency.