Patent Number: 
Section: claims

1. A method of fabrication, by batch-processing, of a plurality of device structures each comprising a high aspect-ratio diffractive optic having a specified diffractive line pattern for photons or particle beams of a prescribed wavelength or energy, comprising:providing a first substrate having a planar front surface and back surface;performing an anisotropic etch process comprising patterning of the front surface of the substrate and removal of material of the substrate to define a precursor structure comprising an array of a plurality of precursor forms comprising one of:a) mesas having sidewalls of predetermined vertical and lateral dimensions and sidewall angle;b) mesas within holes or trenches, the mesas having sidewalls of predetermined vertical and lateral dimensions and sidewall angle; andc) a combination thereof;smoothing sidewalls of the mesas to a predetermined sidewall surface roughness;depositing thereon a sequence of layers defining the specified diffractive line pattern comprising a plurality of m layer stacks, each layer stack comprising at least a pair of layers comprising a layer of a first material (M1) and a layer of a second material (M2), said layer stacks being deposited by an isotropic deposition process providing conformal layers of controlled layer thicknesses on sidewalls of each mesa in sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)m,each of said first and second materials having a different selected complex refractive index at the prescribed wavelength or energy,wherein each mesa forms a core of one of the diffractive optics and said step of depositing comprises controlling the layer thickness of each pair of layers (M1, M2) of the sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)m to define diffractive lines of the specified diffractive line pattern around each mesa;after forming the sequence of layers, providing a planarization layer thereon filling remaining surface voids;performing a first planarization to remove parts of the planarization layer and the sequence of layers and exposing a planarized front-side surface comprising a first surface of each mesa, of the diffractive lines around each mesa and surrounding parts of the planarization layer and the first substrate;attaching a carrier substrate to the planarized front-side surface;performing a second planarization to thin the backside of first substrate and remove part of the first substrate and the sequence of layers to provide a planarized back-side surface exposing a second surface each mesa, of the diffractive lines around each mesa and first substrate; andremoving at least part of the carrier substrate to expose the first surface of the diffractive lines defining the specified diffractive line pattern around each mesa, thereby producing an array of a plurality of diffractive optics supported by remaining parts of the first substrate and the carrier substrate;wherein, for photons or particles of the prescribed wavelength or energy, an axial height h between the first surface and second surface of each of the diffractive lines of each diffractive optic, in a propagation direction, provides at least one of:a required absorption difference between adjacent diffractive lines,a phase shift difference of π between adjacent diffractive lines, anda phase shift difference of a designed fraction of π between adjacent diffractive lines;and wherein the aspect ratio of the axial height h and the layer thickness of a thinnest layer of the sequence of layers of the diffractive line pattern is greater than 10:1. 2. The method of claim 1, wherein smoothing sidewalls of the mesas to a predetermined sidewall surface roughness comprises, prior to depositing the sequence of layers of M1 and M2, providing a sidewall smoothing layer, the sidewall smoothing layer having an RMS surface roughness no greater than a fraction of the thickness of a thinnest layer of the ordered sequence of layers of M1 and M2 of the diffractive line patterns. 3. The method of claim 2, wherein the RMS surface roughness of the smoothing layer is no greater than half the thickness of the thinnest layer. 4. The method of claim 2, wherein providing a sidewall smoothing layer comprises depositing a conformal layer of a reflowable material and heat treating the reflowable material to reduce surface roughness. 5. The method of claim 2, wherein providing a sidewall smoothing layer comprises depositing a layer of a smoothing material having a thickness that is greater than the peak to peak surface roughness of the sidewall of the hole before smoothing, and heat treating or chemically treating the smoothing layer, to reduce surface roughness. 6. The method of claim 1, wherein the step of depositing of at least thinner layers of the sequence of layers comprises Atomic Layer Deposition (ALD). 7. The method of claim 6, wherein the step of depositing further comprises Chemical Vapor Deposition (CVD) for deposition of at least some of thicker layers of the sequence of layers. 8. The method of claim 1, wherein for two dimensional diffractive optics, the mesas comprise cylindrical columns having substantially vertical sidewalls. 9. The method of claim 8, wherein each column is formed within a surrounding hole or recess, the sidewall of the surrounding hole or recess being spaced from sidewalls of the column and wherein adjacent surrounding holes or recesses are spaced from each other by intervening reinforcing regions of the first substrate. 10. The method of claim 9, wherein a group of a plurality of columns is formed within each hole or recess. 11. The method of claim 1, wherein for two dimensional diffractive optics, the mesas comprise columns having a predetermined sidewall angle. 12. The method of claim 1, wherein for one dimensional diffractive optics, the mesas comprise linear forms formed within trenches, said linear forms comprising one or more of linear ridges, rectangular mesas, and square mesas, having substantially vertical sidewalls. 13. The method of claim 1, wherein for one dimensional diffractive optics, the mesas comprise linear forms formed within trenches, said linear forms comprising one or more of linear ridges, rectangular mesas, and square mesas, having a predetermined sidewall angle a relative to surfaces of the substrate. 14. The method of claim 1, wherein performing the first planarization comprises any one of: mechanical polishing, chemical polishing, chemical-mechanical polishing, ion beam polishing and a combination thereof. 15. The method of claim 1, wherein removing at least part of the carrier substrate to expose the first surface of the diffractive lines defining each of the diffractive line patterns comprises opening a plurality of windows in the carrier substrate aligned to each of the plurality of diffractive optics of the array or groups thereof. 16. The method of claim 1, wherein the carrier substrate is bonded to the planarized first surface with at least one intermediate layer, and wherein removing at least part of the carrier substrate to expose the first surface of the diffractive lines defining each of the diffractive line patterns comprises opening windows in the carrier substrate aligned to each diffractive optic to expose said intermediate layer, the at least one intermediate layer acting as a membrane support for each diffractive optic. 17. The method of claim 1, wherein performing the second planarization comprises any one of: grinding, mechanical polishing, chemical polishing, chemical-mechanical polishing, ion beam polishing and a combination thereof. 18. The method of claim 1, further comprising providing one or a plurality of additional layers on one or both of the first and second surfaces of each diffractive optic, comprising any one of:a) providing one or more support layers or stress reduction layers for improved mechanical properties;b) providing one or more thermal dissipation layers;c) providing one or more electrically conductive layers;d) providing a separation layer for constructing other planar optical devices atop of the diffractive device; ande) a combination thereof. 19. The method of claim 1, further comprising post-processing by any one of ion implantation, etching and heat treatment, for at least one of reshaping, trimming, stress engineering, adjusting functionality or fine tuning of optical properties of the diffractive optics. 20. The method of claim 1, wherein the first substrate comprises a crystalline silicon wafer. 21. The method of claim 1, further comprising a step of device singulation comprising substrate dicing or cleaving, to form a plurality of device structures, each comprising one or a plurality of diffractive optic elements. 22. The method of claim 1, wherein the first material M1 comprises at least one of platinum, iridium, tungsten, rhodium, osmium, zinc oxide, titanium oxide, hafnium oxide and compounds, alloys or mixtures thereof, and wherein the second material M2 comprises at least one of boron nitride, carbon, silicon dioxide, silicon nitride, aluminum oxide and compounds, or mixtures thereof. 23. The method of claim 1 wherein each layer stack comprises a sequence of N layers of materials M1, M2, . . . MN, where N is ≥3, the materials M1, M2, . . . MN having an ordered sequence of different complex indexes of refraction at the prescribed wavelength or energy, the sequence of layers being deposited to form the sequence of m layer stacks (M1, M2, . . . MN)1, . . . (M1, M2, . . . MN)m with specified layer thicknesses to define an Nth-order diffractive optic. 24. The method of claim 1, wherein the materials and dimensions of the diffractive line pattern for each diffractive optic are selected for focusing of electromagnetic radiation having a prescribed wavelength or energy, said electromagnetic radiation comprising x rays having a prescribed energy in the range from 5 keV to hundreds of keV, and gamma rays having a prescribed energy of hundreds of keV. 25. The method of claim 1, wherein for fabricating two dimensional diffractive optics, each mesa comprises a cylindrical column, and wherein:each cylindrical column comprises:a diameter sized in a range from ˜1 μm to ˜2000 μm to form a core for the sequence of layers defining the diffractive line patterns;a side wall angle not more than 5 degrees from vertical;a height in a range from ˜1 μm to ˜200 μm, such that after planarization, the diffractive optical has a required axial height h in the direction of propagation;the thickness of the thinnest deposited layers of the sequence layers is between 0.2 and 100 nm; andwherein the aspect ratio of said axial height h to said thickness of the thinnest deposited layers is between 10:1 and 100,000:1. 26. The method of claim 1, wherein for forming one dimensional (linear) optics, each mesa comprises a linear ridge; and wherein:each ridge comprises:a width in the range from few μm to hundreds of μm and length from tens of μm to few mm, to form a core for the sequence of layers defining the diffractive line pattern;a height between 1 μm and 200 μm, such that after planarization, the diffractive optical has the required axial height h in the direction of propagation;the thickness of thinnest deposited layers of the sequence of layers is between 0.2 and 100 nm; andwherein the aspect ratio of said axial height h to said thickness of the thinnest deposited layers is between 10:1 and 100,000:1. 27. The method of claim 26, wherein sidewalls of the ridges are substantially vertical, and in cross-section, the ridge has a rectangular cross-section. 28. The method of claim 26, wherein each ridge has a sidewall angle a relative to planar surfaces of the substrate and wherein, in vertical cross-section, the ridge has a trapezoid cross-section. 29. The method of claim 1, wherein for a binary diffractive optic wherein in each layer stack is a pair of layers M1 and M2, and M1 has a higher absorption or refractive index than M2 at the prescribed wavelength or energy, the sequence of m layer stacks is deposited as one of:a) a sequence of m layer stacks (M1, M2)1, (M1, M2)2, . . . (M1, M2)m; orb) a sequence of m layer stacks (M2, M1)1, (M2, M1)2, . . . (M2, M1)m. 30. The method of claim 1, wherein smoothing sidewalls of the mesas to a predetermined sidewall surface roughness comprises smoothing sidewalls to an RMS surface roughness of <1 nm. 31. A method of fabrication, by batch-processing, of a plurality of device structures each comprising a high aspect-ratio diffractive optic having a specified diffractive line pattern for photons or particle beams of a prescribed wavelength or energy, comprising:providing a first substrate having a planar front surface and back surface;performing an anisotropic etch process comprising patterning of the front surface of the substrate and removal of material of the substrate to define a precursor structure comprising an array of a plurality of precursor forms comprising one of:a) mesas having sidewalls of predetermined vertical and lateral dimensions and sidewall angle;b) mesas within holes or trenches, the mesas having sidewalls of predetermined vertical and lateral dimensions and sidewall angle; andc) a combination thereof;smoothing sidewalls of the mesas to a predetermined sidewall surface roughness;depositing thereon a sequence of layers defining the specified diffractive line pattern comprising a plurality of m layer stacks, each layer stack comprising at least a pair of layers comprising a layer of a first material (M1) and a layer of a second material (M2), said layer stacks being deposited by an isotropic deposition process providing conformal layers of controlled layer thicknesses on sidewalls of each mesa in sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)m,each of said first and second materials having a different selected complex refractive index at the prescribed wavelength or energy,wherein each mesa forms a core of one of the diffractive optics and said step of depositing comprises controlling the layer thickness of each pair of layers (M1, M2) of the sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)m to define diffractive lines of the specified diffractive line pattern around each mesa;after forming the sequence of layers, providing a planarization layer thereon filling remaining surface voids;performing a first planarization to remove parts of the planarization layer and the sequence of layers and exposing a planarized front-side surface comprising a first surface of each mesa, of the diffractive lines around each mesa and surrounding parts of the planarization layer and the first substrate;performing a second planarization to thin the backside of first substrate and remove part of the first substrate and the sequence of layers to provide a planarized back-side surface exposing a second surface each mesa, of the diffractive lines around each mesa and first substrate;wherein, for photons or particles of the prescribed wavelength or energy, an axial height h between the first surface and second surface of each of the diffractive lines of each diffractive optic, in a propagation direction, provides at least one of:a required absorption difference between adjacent diffractive lines,a phase shift difference of π between adjacent diffractive lines, anda phase shift difference of a designed fraction of π between adjacent diffractive lines;and wherein the aspect ratio of the axial height h and the layer thickness of a thinnest layer of the sequence of layers of the diffractive line pattern is greater than 10:1; andperforming device singulation comprising at least one of substrate dicing and cleaving, to form a plurality of individual device structures, each comprising one or a plurality of said diffractive optics. 32. A method of fabrication, by batch-processing, of a plurality of device structures each comprising a high aspect-ratio Fresnel zone plate having a specified Fresnel zone pattern for photons or particle beams of a prescribed wavelength or energy, comprising:providing a first substrate having a planar front surface and back surface;performing an anisotropic etch process comprising patterning of the front surface of the substrate and removal of material of the substrate to define a precursor structure comprising an array of a plurality of mesas comprising cylindrical columns, each formed within a surrounding hole or recess, said mesas having sidewalls of predetermined vertical and lateral dimensions and sidewall angle;smoothing sidewalls of the mesas to a predetermined sidewall surface roughness;depositing thereon a sequence of layers comprising a plurality of m layer stacks, each layer stack comprising at least a pair of layers comprising a layer of a first material (M1) and a layer of a second material (M2),each of said first and second materials having a different selected complex refractive index at the prescribed wavelength or energy,said layer stacks being deposited by an isotropic deposition process providing conformal layers of controlled layer thicknesses on sidewalls of each mesa in sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)mwherein each mesa forms a central non-diffractive area of one of the Fresnel zone plates and said step of depositing comprising controlling the layer thickness of each pair of layers (M1, M2) of the sequence (M1, M2)1, (M1, M2)2. . . (M1, M2)m to define diffractive zones of said specified Fresnel zone pattern around each mesa;after forming the sequence of layers, providing a planarization layer thereon filling remaining surface voids;performing a first planarization to remove parts of the planarization layer and the sequence of layers and exposing a planarized front-side surface comprising a first surface of each mesa, of the diffractive zones around each mesa and surrounding parts of the planarization layer and the first substrate;attaching a carrier substrate to the planarized front-side surface;performing a second planarization to thin the backside of first substrate and remove part of the first substrate and the sequence of layers to provide a planarized back-side surface exposing a second surface each mesa, of the diffractive zones around each mesa and first substrate; andremoving part of the carrier substrate to expose the first surface the Fresnel zones around each mesa, thereby producing an array of a plurality of Fresnel zone plates supported by remaining parts of the first substrate and the carrier substrate;wherein, for photons or particles of the prescribed wavelength or energy, an axial height h between the first surface and second surface of each of the diffractive lines of each diffractive optic, in a propagation direction, provides at least one of:a required absorption difference between adjacent diffractive lines,a phase shift difference of π between adjacent diffractive lines, anda phase shift difference of a designed fraction of π between adjacent diffractive lines;and wherein the aspect ratio of the axial height h and the layer thickness of a thinnest layer of the sequence of layers of the diffractive line pattern is greater than 10:1.