Patent Number: 
Section: claims

1. A mass spectrometer arrangement having a detection system (12) and comprising:a cathode configuration (6) for emitting electrons (21);a reaction zone (3) having an entrance opening (14) for a supply of neutral particles (20), the reaction zone being operatively connected to the cathode configuration (6) for ionization of the neutral particles (20) in an effective region of the reaction zone to form ions (22);an ion extraction system (4) communicating with the effective region of the reaction zone (3);guidance means (1, 10, 11) for guidance of the ions (22) to the detection system (12) within the mass spectrometer arrangement;evacuation means for evacuation of the mass spectrometer arrangement;the cathode configuration (6) comprising a field emission cathode with an emitter surface (7) and, at a short distance from the emitter surface (7), an extraction grid (9) for extraction of electrons (21) away from the emitter surface, the extraction grid substantially covering the emitter surface (7), andthe emitter surface (7) at least partly encompassing a hollow volume (13) to create a tubular structure around the hollow volume (13),wherein the emitter surface (7) is a surface which has been subjected to etching to thereby form a rough surface. 2. The arrangement as claimed in claim 1, wherein the size of the emitter surface (7) is in the range of 0.5 cm2 to 80 cm2. 3. The arrangement as claimed in claim 1, wherein the emitter surface (7) is substantially shaped as a concave inside-facing surface of longitudinal side walls of a cylinder, and wherein the extraction grid is shaped as a second cylinder radially inside the emitter surface cylinder. 4. The arrangement as claimed in claim 1, wherein the emitter surface (7) is a thin layer deposited on a housing wall (2) formed by one of CVD and PVD. 5. The arrangement as claimed in claim 1, wherein the emitter surface (7) is a roughened surface which has been subjected to etching to form a multiplicity of irregularly distributed prominences. 6. The arrangement as claimed in claim 1, wherein the extraction grid (9) is positioned opposite the emitter surface (7) with insulating spacers (8). 7. The arrangement as claimed in claim 1, wherein the extraction grid (9) is biased with respect to the emitter surface (7) with a positive voltage (VG) and that this voltage is in the range from 70 V to 2000 V. 8. The arrangement as claimed in claim 1, wherein the detector system (12) includes a rod system which is part of a quadrupole mass spectrometer. 9. A mass spectrometer arrangement having a detection system (12) and comprising:a cathode configuration (6) for emitting electrons (21);a reaction zone (3) having an entrance opening (14) for a supply of neutral particles (20), the reaction zone being operatively connected to the cathode configuration (6) for ionization of the neutral particles (20) in an effective region of the reaction zone to form ions (22);an ion extraction system (4) communicating with the effective region of the reaction zone (3);guidance means (1, 10, 11) for guidance of the ions (22) to the detection system (12) within the mass spectrometer arrangement;evacuation means for evacuation of the mass spectrometer arrangement;the cathode configuration (6) comprising a field emission cathode with an emitter surface (7) and, at a short distance from the emitter surface (7), an extraction grid (9) for extraction of electrons (21) away from the emitter surface, the extraction grid substantially covering the emitter surface (7), andthe emitter surface (7) consisting essentially of generally planar surface, the emitter surface (7) being curved and at least partly encompassing a hollow volume (13) to create a hollow tubular structure,wherein, adjoining the hollow volume (13) of the cathode configuration (6) is an electron extraction lens (5) and including, in an axial direction of the mass spectrometer arrangement, an ion extraction lens (4), the reaction zone (3) being located between the electron extraction lens (5) and the ion extraction lens (4) to form a volume and the entrance opening (14) for the neutral particles (20) being disposed peripherally upon said volume of the reaction zone (3). 10. The arrangement as claimed in claim 9, wherein the size of the emitter surface (7) is in the range of 0.5 cm2 to 80 cm2. 11. The arrangement as claimed in claim 9, wherein the size of the emitter surface (7) is in the range of 1.0 cm2 to 50 cm2. 12. The arrangement as claimed in claim 9, wherein the emitter surface (7) forms at least arcuate sector elements that are not divided and forms a closed tubular emitter surface (7) wherein the emitter surfaces are concave and face inwards. 13. The arrangement as claimed in claim 9, wherein the emitter surface (7) is substantially shaped as a concave inside-facing surface of longitudinal side walls of a cylinder, and wherein the extraction grid is shaped as a second cylinder radially inside the emitter surface cylinder. 14. The arrangement as claimed in claim 9, wherein the diameter of the hollow volume (13) is between 0.5 cm and 8.0 cm and its length in the axial direction is between 2.0 em and 8.0 cm. 15. The arrangement as claimed in claim 9, wherein the diameter of the hollow volume (13) is between 0.5 cm and 6.0 cm and its length in the axial direction is between 2.0 cm and 8.0 cm. 16. The arrangement as claimed in claim 9, wherein the emitter surface (7) comprises at least on the surface a layer comprising at least one of the materials selected from the group consisting of: carbon; a metal; a metal mixture; a semiconductor; a carbide; and mixtures thereof. 17. The arrangement as claimed in claim 16, wherein the emitter surface (7) is substantially comprised of at least one of molybdenum, tantalum and corrosion-resistant steel. 18. The arrangement as claimed in claim 16, wherein the emitter surface (7) is a thin layer deposited on a housing wall (2) formed by one of CVD and PVD. 19. The arrangement as claimed in claim 9, wherein the emitter surface (7) is comprised of at least a portion of the surface of one housing wall (2), wherein the housing wall (2) is comprised of one of: metal, metal alloy, and corrosion resistant steel. 20. The arrangement as claimed in claim 9, wherein the emitter surface (7) is a roughened surface which has been subjected to etching to form a multiplicity of irregularly distributed prominences. 21. The arrangement as claimed in claim 9, wherein the emitter surface (7) is a roughened surface that is roughened by one of: mechanically roughened; plasma etching; and chemical etching. 22. The arrangement as claimed in claim 9, wherein the distance between the extraction grid (9) and the emitter surface (7) is in the range from 1.0 μm and 2 mm. 23. The arrangement as claimed in claim 9, wherein the distance between the extraction grid (9) and the emitter surface (7) is in the range from 5.0 μm and 200 μm. 24. The arrangement as claimed in claim 9, wherein the extraction grid (9) has a grid structure with high transmission factor and is made of wire cloth. 25. The arrangement as claimed in claim 9, wherein the extraction grid (9) is positioned opposite the emitter surface (7) with insulating spacers (8). 26. The arrangement as claimed in claim 9, wherein the extraction grid (9) is biased with respect to the emitter surface (7) with a positive voltage (VG) and that this voltage is in the range from 70 V to 2000 V. 27. The arrangement as claimed in claim 9, wherein the extraction grid (9) is biased with respect to the emitter surface (7) with a positive voltage (VG) and that this voltage is in the range from 70 V to 200 V. 28. The arrangement as claimed in claim 9, wherein the detector system (12) includes a rod system which is part of a quadrupole mass spectrometer. 29. The arrangement as claimed in claim 9, wherein the emitter surface comprises roughened generally planar surface which has been roughened by mechanical grinding. 30. A mass spectrometer arrangement having a detection system (12) and comprising:a cathode configuration (6) for emitting electrons (21);a reaction zone (3) having an entrance opening (14) for a supply of neutral particles (20), the reaction zone being operatively connected to the cathode configuration (6) for ionization of the neutral particles (20) in an effective region of the reaction zone to form ions (22);an ion extraction system (4) communicating with the effective region of the reaction zone (3);guidance means (1, 10, 11) for guidance of the ions (22) to the detection system (12) within the mass spectrometer arrangement;evacuation means for evacuation of the mass spectrometer arrangement;the cathode configuration (6) comprising a field emission cathode with an emitter surface (7) and, at a short distance from the emitter surface (7), an extraction grid (9) for extraction of electrons (21) away from the emitter surface, the extraction grid substantially covering the emitter surface (7), andthe emitter surface (7) consisting essentially of generally planar surface, the emitter surface (7) being curved and at least partly encompassing a hollow volume (13) to create a hollow tubular structure,wherein the reaction zone (3) is formed within the hollow volume (13) of the cathode configuration (6) so that the hollow volume (13) is delimited on one side by an ion extraction lens (4) and on an opposite side is located the entrance opening (14) for the neutral particles (20). 31. The arrangement as claimed in claim 30, wherein the size of the emitter surface (7) is in the range of 0.5 cm2 to 80 cm2. 32. The arrangement as claimed in claim 30, wherein the emitter surface (7) is substantially shaped as a concave inside-facing surface of longitudinal side walls of a cylinder, and wherein the extraction grid is shaped as a second cylinder radially inside the emitter surface cylinder. 33. The arrangement as claimed in claim 30, wherein the emitter surface (7) is a thin layer deposited on a housing wall (2) formed by one of CVD and PVD. 34. The arrangement as claimed in claim 30, wherein the emitter surface (7) is a roughened surface which has been subjected to etching to form a multiplicity of irregularly distributed prominences. 35. The arrangement as claimed in claim 30, wherein the extraction grid (9) is positioned opposite the emitter surface (7) with insulating spacers (8). 36. The arrangement as claimed in claim 30, wherein the extraction grid (9) is biased with respect to the emitter surface (7) with a positive voltage (VG) and that this voltage is in the range from 70 V to 2000 V. 37. The arrangement as claimed in claim 30, wherein the detector system (12) includes a rod system which is part of a quadrupole mass spectrometer. 38. The arrangement as claimed in claim 30, wherein the emitter surface comprises roughened generally planar surface which has been roughened by mechanical grinding. 39. A mass spectrometer arrangement having a detection system (12) and comprising:a cathode configuration (6) for emitting electrons (21);a reaction zone (3) having an entrance opening (14) for a supply of neutral particles (20), the reaction zone being operatively connected to the cathode configuration (6) for ionization of the neutral particles (20) in an effective region of the reaction zone to form ions (22);an ion extraction system (4) communicating with the effective region of the reaction zone (3);guidance means (1, 10, 11) for guidance of the ions (22) to the detection system (12) within the mass spectrometer arrangement;evacuation means for evacuation of the mass spectrometer arrangement;the cathode configuration (6) comprising a field emission cathode with an emitter surface (7) and, at a short distance from the emitter surface (7), an extraction grid (9) for extraction of electrons (21) away from the emitter surface, the extraction grid substantially covering the emitter surface (7), andthe emitter surface (7) consisting essentially of generally planar but also rough surface, the emitter surface (7) being curved and at least partly encompassing a hollow volume (13) to create a hollow tubular structure,wherein the reaction zone (3) is located on a longitudinal axis of the mass spectrometer arrangement and is encompassed by a wall which includes, in a radial direction toward the axis, an extraction opening which forms the electron extraction lens (5), and the extraction opening communicating with the hollow volume (13) of the cathode configuration (6), the cathode configuration (6) being positioned orthogonally with respect to the axis and to the reaction zone (3) for a radial feeding of the electrons into the reaction zone (3), and in the wall at least one entrance opening (14) is provided for the introduction of neutral particles (20). 40. The arrangement as claimed in claim 39, wherein the size of the emitter surface (7) is in the range of 0.5 cm2 to 80 cm2. 41. The arrangement as claimed in claim 39, wherein the emitter surface (7) is substantially shaped as a concave inside-facing surface of longitudinal side walls of a cylinder, and wherein the extraction grid is shaped as a second cylinder radially inside the emitter surface cylinder. 42. The arrangement as claimed in claim 39, wherein the emitter surface (7) is a thin layer deposited on a housing wall (2) formed by one of CVD and PVD. 43. The arrangement as claimed in claim 39, wherein the emitter surface (7) is a roughened surface which has been subjected to etching to form a multiplicity of irregularly distributed prominences. 44. The arrangement as claimed in claim 39, wherein the extraction grid (9) is positioned opposite the emitter surface (7) with insulating spacers (8). 45. The arrangement as claimed in claim 39, wherein the extraction grid (9) is biased with respect to the emitter surface (7) with a positive voltage (VG) and that this voltage is in the range from 70 V to 2000 V. 46. The arrangement as claimed in claim 39, wherein the detector system (12) includes a rod system which is part of a quadrupole mass spectrometer. 47. The arrangement as claimed in claim 39, wherein the emitter surface comprises roughened generally planar surface which has been roughened by mechanical grinding.