Patent Number: 054611857
Section: claims

1. A process for the conversion of solid radioactive waste comprising providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing elemental metal and carbon in a radioactive waste while the metal of the sacrificial oxide is reduced to elemental metal which has limited solubility in said molten glass;  introducing solid radioactive waste into said bath of molten glass containing said sacrificial metal oxide, and converting elemental metal in said waste into oxides of said metal which are solubilized in said molten glass, and the metal of the sacrificial metal oxide into a recoverable solid or molten byproduct elemental metal, while dissolving any metal oxides in said waste into said molten glass, the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the elemental metal and any oxidizable carbon in the radioactive waste;  separating and recovering molten glass containing metal oxides derived from said waste from the bath, and  removing byproduct elemental metal from the sacrificial oxide from the bath.  providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing elemental metal and carbon in a radioactive waste while the metal of said sacrificial oxide is reduced and forms a metal oxide soluble in said molten glass;  introducing a solid radioactive waste into said bath of molten glass containing said sacrificial metal oxide, and converting elemental metal in the waste into oxides of said metal which are solubilized in said molten glass, and the sacrificial metal oxide into a reduced metal oxide soluble in the molten glass, while dissolving any oxides in said waste, the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the elemental metal and any oxidizable carbon in the radioactive waste; and recovering molten glass containing said reduced metal oxides and dissolved metal oxides derived from the waste from the bath.  providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing plutonium and carbon while the metal of the sacrificial oxide is reduced to elemental metal which has limited solubility in said molten glass;  introducing weapons grade plutonium into said bath of molten glass containing said sacrificial metal oxide, and converting plutonium into plutonium oxide which is solubilized in said molten glass, and the metal of the sacrificial metal oxide into a recoverable solid or molten byproduct elemental metal;  the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the plutonium and any carbon present; separating and recovering molten glass containing plutonium oxide from the bath, and  removing byproduct elemental metal from the sacrificial oxide from the bath.  providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing plutonium and carbon while the metal of said sacrificial oxide is reduced and forms a metal oxide soluble in said molten glass;  introducing weapons grade plutonium into said bath of molten glass containing said sacrificial metal oxide, and converting plutonium into plutonium oxide which is solubilized in said molten glass, and the metal of the sacrificial metal oxide into a reduced metal oxide soluble in the molten glass, the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the plutonium and any carbon present; and recovering molten glass containing said reduced metal oxide and plutonium oxide from the bath.  providing a first bath of molten glass containing a sacrificial metal oxide capable of oxidizing elemental metal and carbon in the radioactive waste while the metal of the sacrificial oxide is reduced to elemental metal which has limited solubility in said molten glass;  introducing solid radioactive waste into said first bath of molten glass containing said sacrificial metal oxide, and converting elemental metal in said waste into oxides of said metal which are solubilized in said molten glass, and the metal of the sacrificial metal oxide into a recoverable solid or molten elemental metal, while dissolving oxides in said waste into said molten glass, the sacrificial oxide being provided in the molten glass in each bath in at least stoichiometric amount with respect to any elemental metal and/or carbon added or present from the radioactive waste;  separating molten glass containing dissolved metal oxides from the waste from the first bath, and adding separated molten glass to a second molten glass bath containing a sacrificial metal oxide capable of oxidizing elemental metal and carbon in the radioactive waste while the metal of the sacrificial oxide is reduced to elemental metal which has limited solubility in said molten glass;  adding one or more components selected from radioactive waste, glass, precursors of glass, or sacrificial metal oxide to the second glass bath in amount to produce a metal oxides containing molten glass mixture of desired composition; and  recovering metal oxides containing molten glass mixture of desired composition.  providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing carbon in radioactive waste material containing carbon while the metal of the sacrificial oxide is reduced to elemental metal which has limited solubility in said molten glass;  introducing radioactive waste material containing carbon into said bath of molten glass containing said sacrificial metal oxide, and converting carbon in said waste into carbon dioxide, and the metal of the sacrificial metal oxide into a recoverable solid or molten byproduct elemental metal, while dissolving any metal oxides in said waste into said molten glass, the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the oxidizable carbon in the radioactive waste;  separating carbon dioxide from the bath and separating and recovering molten glass containing metal oxides derived from said waste from the bath, and  removing byproduct elemental metal from the sacrificial oxide from the bath.  providing a bath of molten glass containing a sacrificial metal oxide capable of oxidizing carbon in the radioactive waste material containing carbon while the metal of said sacrificial oxide is reduced and forms a metal oxide soluble in said molten glass;  introducing radioactive waste material containing carbon into said bath of molten glass containing said sacrificial metal oxide, and converting carbon in the waste into carbon dioxide and the sacrificial metal oxide into a reduced metal oxide soluble in the molten glass, while dissolving any oxides in said waste, the sacrificial oxide being provided in the molten glass in at least stoichiometric amount with respect to the oxidizable carbon of the radioactive waste;  separating carbon dioxide from the bath and recovering molten glass containing said reduced metal oxides and dissolved metal oxides derived from the waste from the bath. 2. The process of claim 1 wherein the removed byproduct elemental metal from the sacrificial oxide is oxidized to a recoverable metallic oxide, and the recoverable metallic oxide is recovered and sent to the molten bath as the sacrificial metal oxide. 3. The process of claim 2 wherein the sacrificial metal oxide is PbO. 4. The process of claim 1 wherein oxidizable carbon is present in the radioactive waste and carbon dioxide is separated from the molten glass bath. 5. The process of claim 1 wherein the radioactive waste comprises spent nuclear reactor fuel. 6. The process of claim 5 wherein the removed byproduct metal is oxidized to a recoverable metallic oxide, and recoverable metallic oxide is recovered and sent to the molten bath as the sacrificial metal oxide. 7. The process of claim 6 wherein the sacrificial metal oxide is PbO. 8. The process of claim 5 wherein the spent fuel is fed to molten glass bath in the form of rods, the rods being clad with a cladding metal, the cladding metal being converted by the sacrificial oxide to an oxide in the glass bath. 9. A process for the conversion of solid radioactive waste comprising 10. The process of claim 9 wherein the radioactive waste comprises spent nuclear reactor fuel. 11. The process of claim 10 wherein the spent fuel is fed to molten glass bath in the form of rods, the rods being clad with a metal, the metal being converted by the sacrificial oxide to an oxide in the glass bath. 12. The process of claim 9 wherein the sacrificial metal oxide is Fe.sub.2 O.sub.3. 13. The process of claim 9 wherein oxidizable carbon is present in the radioactive waste and carbon dioxide is separated from the molten glass bath. 14. A process for the conversion of weapons grade plutonium comprising 15. The process of claim 14 wherein spent fuel is also introduced into the molten glass bath, the ratio of spent fuel to weapons grade plutonium being at least 6, and the sacrificial oxide is provided in the molten glass in at least stoichiometric amount with respect to the amount of elemental metal and any carbon introduced. 16. The process of claim 14 wherein removed elemental metal from the sacrificial oxide is oxidized to a recoverable metallic oxide, and the recoverable metallic oxide is recovered and sent to the molten bath as the sacrificial metal oxide. 17. The process of claim 16 wherein the sacrificial metal oxide is PbO. 18. A process for the conversion of weapons grade plutonium comprising 19. The process of claim 18 wherein spent fuel containing an amount of elemental metal is also introduced into the molten glass bath, the ratio of spent fuel to weapons grade plutonium being at least 6, and the sacrificial oxide is provided in the molten glass in at least a stoichiometric amount with respect to the amount of plutonium and elemental metal and any carbon introduced. 20. The process of claim 19 wherein the sacrificial metal oxide is Fe.sub.2 O.sub.3. 21. A process for the conversion of solid radioactive waste comprising 22. The process of claim 21 wherein elemental metal from the sacrificial oxide from the first bath is recovered and is oxidized to a recoverable metallic oxide, and the recoverable metallic oxide is recovered and sent to the first molten bath as the sacrificial metal oxide. 23. The process of claim 22 wherein the sacrificial metal oxide is PbO. 24. The process of claim 21 wherein oxidizable carbon is present in the radioactive waste and carbon dioxide is separated from the first molten glass bath. 25. A process for the conversion of radioactive waste material containing carbon comprising 26. A process for the conversion of radioactive waste material containing carbon comprising 27. The process of claim 25 wherein carbon dioxide is separated from the molten glass bath. 28. The process of claim 26 wherein carbon dioxide is separated from the molten glass bath.