Patent Number: 054948630
Section: claims

1. A process for nuclear waste disposal comprising: providing a glass forming mixture comprising an aqueous solution of one or more metal alkoxides, alcohol, and 35 wt % up to 85 wt % of solubilized, low level radioactive waste in a true solution and having a pH effective to hydrolyze the one or more metal alkoxides;  converting the one or more metal alkoxides in the glass forming mixture to a network of corresponding one or more metal oxides;  forming a gel from the glass forming mixture containing the network of one or more metal oxides;  drying the gel; and  sintering the dried gel under conditions effective to form a densified glass.  heating the dried gel to a temperature of 550.degree. C. at a rate of 30.degree. C. /hour and  heating at a final sintering temperature of 600.degree. to 700.degree. C.  reducing the pH of the low level radioactive waste to a value of less than 1 before said providing a glass forming mixture.  aging the gel after said forming a gel at a temperature of 20.degree. to 100.degree. C. for a time period of 1 hour to several weeks.  reducing the pH of low level radioactive waste to a value of less than 1 to fully solubilize the waste having a reduced pH is an aqueous solution of one or more metal alkoxides and alcohol to form a glass forming mixture; and  forming a glass from the glass forming mixture using a sol-gel procedure.  adding one or more other glass forming materials to the glass forming mixture after said incorporating. 2. A process according to claim 1, wherein the one or more metal alkoxides is selected from the group consisting of alkoxides of silicon, aluminum, phosphorus, zirconium, boron, germanium, titanium, and mixtures thereof. 3. A process according to claim 2, wherein the one or more metal alkoxides is a mixture comprising an aluminum alkoxide and a silicon alkoxide. 4. A process according to claim 1, wherein the glass forming mixture further comprises compounds containing elements selected from the group consisting of boron, calcium, and mixtures thereof. 5. A process according to claim 1, wherein the low level radioactive waste contains salts of sodium, cesium, molybdenum, strontium, and mixtures thereof. 6. A process according to claim 1, wherein said sintering is carried out at a temperature below that of crystallization onset. 7. A process according to claim 6, wherein said sintering comprises: 8. A process according to claim 1, wherein said forming a gel is carried out at a temperature of 20.degree. to 100.degree. C. 9. A process according to claim 8, wherein said forming a gel is catalyzed by an acid or by a base. 10. A process according to claim 9, wherein said forming a gel is catalyzed by a base. 11. A process according to claim 10, wherein the glass forming mixture comprises N,N-dimethylformamide. 12. A process according to claim 9, wherein said forming a gel is catalyzed by an acid. 13. A process according to claim 12, wherein the glass forming mixture comprises ethylene glycol. 14. A process according to claim 1, wherein said drying is carried out under hypercritical conditions at a temperature of 290.degree. to 310.degree. C. and at a pressure of 136 to 184 atmospheres to form an aerogel. 15. A process according to claim 1, wherein a xerogel forms while temperature of said drying is slowly increased to that of said sintering at substantially atmospheric pressure. 16. A process according to claim 1 further comprising: 17. A process according to claim 1 further comprising: 18. A process for nuclear waste disposal comprising: 19. A process according to claim 18, wherein the one or more metal alkoxides is selected from the group consisting of alkoxides of silicon, aluminum, phosphorus, zirconium, boron, germanium, titanium, and mixtures thereof. 20. A process according to claim 19, wherein the one or more metal alkoxides comprises a mixture of an aluminum alkoxide and a silicon alkoxide. 21. A process according to claim 18, wherein the glass forming mixture further comprises compounds containing elements selected from the group consisting of boron, calcium, and mixtures thereof. 22. A process according to claim 18, wherein the low level radioactive waste contains salts of sodium, cesium, molybdenum, strontium, and mixtures thereof. 23. A process according to claim 18, wherein said reducing comprises adding one or more organic or inorganic acids to the low level radioactive waste. 24. A process according to claim 18 further comprising: