Patent Number: 045129215
Section: claims

1. A method of removing corrosion products from the coolant system of a water-cooled nuclear reactor comprising the steps of: (a) adding at least one soluble weak-acid organic complexing agent selected from the group consisting of oxalic acid, citric acid, nitrilotriacetic acid and hydroxyethylethylenediaminetriacetic acid to the coolant to form a decontamination solution;  (b) adjusting the pH of the decontamination solution to from 2.5 to 4.0;  (c) circulating and decontamination solution at a temperature of from 60.degree. to 100.degree. C. throughout the coolant system to dissolve the corrosion products to form a complexed ion solution of Fe.sup.+2, Fe.sup.+3, .sup.60 Co.sup.+2, and other metal ion complexes; and  (d) removing the Fe.sup.+2, Fe.sup.+3 and .sup.60 Co.sup.+2 complexes from the complexed ion solution and regenerating the decontamination solution by passing the complexed ion solution through an anion exchange resin, said anion exchange resin having been presaturated with the anions of the weak-acid organic complexing agent of the decontamination solution such that the concentration of the agents on the resin is substantially the same concentration of the agents in the decontamination solution and having the same pH of the decontamination solution.  (a) adding at least one soluble weak-acid organic complexing agent selected from the group consisting of oxalic acid, citric acid, nitrilotriacetic acid and hydroxyethylethylenediaminetriacetic acid to the coolant to form a decontamination solution;  (b) adjusting the pH of the decontamination solution to from 2.5 to 4.0;  (c) circulating the decontamination solution at a temperature of from 60.degree. to 100.degree. C. throughout the coolant system to dissolve the corrosion products to form a complexed ion solution of Fe.sup.+2, Fe.sup.+3, .sup.60 Co.sup.+2, and other metal ion complexes; and  (d) passing the complexed ion solution through a cation exchange resin; 2. The method of claim 1 wherein the decontamination solution contains from 0.2 to 4.0 ppm dissolved oxygen. 3. The method of claim 2 wherein the weak-acid organic complexing agents comprise from 0.005 to 0.02M in oxalic acid and from 0.002 to 0.01M in citric acid. 4. The method of claim 1 wherein the nuclear reactor is a boiling water reactor. 5. The method of claim 1 further comprising the step of recirculating the regenerated decontamination solution through the coolant system. 6. In the method of removing corrosion products from the coolant system of a water-cooled nuclear reactor by: 7. The method of claim 6 further comprising the step of recirculating the regenerated decontamination solution through the coolant system. 8. The method of claim 5 or 7 further comprising the step of purifying the coolant system to remove the organic complexing agents and any metal ion complexes remaining in the system by passing the regenerated decontamination solution through a mixed-bed of anion and cation exchange resins.