Patent Number: 048719110
Section: summary

The invention relates to an electron beam apparatus comprising, arranged inside an evacuatable housing, an electron source which comprises an electron emitter for generating an electron beam having a comparatively high emission current density and an electron-optical lens system. In an electron beam apparatus such as, for example, electron microscopes, electron beam writers and similar apparatus, it is often desirable to have an electron source available which source is capable of supplying an electron beam having a high current density, sufficient stability and attractive properties in relation to the electron-optical system of the apparatus. Electron beam apparatus comprising a conventional thermal cathode or a cathode made of LaB.sub.6, such as described in U.S. Pat. No. 3,631,290, supply an electron beam whose brightness is insufficient for many applications. Maximum current densities which can be achieved in this respect are, for example, approximately 5 a/cm.sup.2 or 30 A/cm.sup.2, respectively. The emissive surface of such electron source which is of relevance for the electron-optical system is too large in relation to the electron-optical properties of the apparatus, so that optimum beam formation, spot formation or imaging cannot be achieved. Electron beam apparatus comprising a field emission source as described in U.S. Pat. No. 3,631,291 are capable of supplying electron beams having a comparatively high current density, but such a source has several drawbacks such as instability of emissive power, positioning and geometry of the emitter. Moreover, such sources are not suitable for the supply of the frequently desired large total beam currents. From an electron-optical point of view, the dimension of the cathode and hence in this case of the virtual object of such a source is too small to obtain sufficiently high current densities. This is mainly due to the necessarily limited geometry of the emitter. Moreover the energy spread of the electrons in an electron beam produced by the described sources is comparatively large so that chromatic errors which are inadmissibly large are liable to occur in the electron-optical image. An electron source as described in U.S. Pat. No. 4,419,561 has succeeded in mitigating some of the drawbacks of the field-emission source, but the dimensions, positioning and the energy spread again render this source less suitable for many applications. The drawbacks of these sources relative to the heating of the emission wire and the positioning thereof have been partly solved by means of an electron source as described in Netherlands Patent Application 8302275, corresponding to U.S. Pat. No 4,591,753. However, the temperature threshold, the comparatively fast evaporation of the cathode wire and the resultant contamination of the apparatus as well as the non-adapted object dimensions and the large energy spread are still drawbacks of this source. It is the object of the present invention to mitigate these drawbacks; and to achieve this, an electron beam apparatus of the kind set forth is characterized in that the electron emitter comprises a semi-conductor element in which there is provided, parallel to an emissive surface, a p-n junction which is to be connected in the reverse direction and whose dimensions define surface dimensions of the emissive surface to electron optical properties of the apparatus with the current density and the current intensity of an electron beam to be emitted being optimized at the same time. Because an electron beam apparatus in accordance with the invention uses a cold cathode as the electron emitter, the known thermal problems are avoided in this apparatus. Using this electron emitter, electron beams having a sufficiently high current density and current intensity can be readily achieved and the dimensions of the emissive surface defined by the transverse dimensions of the p-n junction enable optimum beam and spot shaping and electron-optical imaging. The semiconductor electron emitter is constructed so as to operate with a p-n junction which is connected in the reverse direction. Due to the use of a source comprising a p-n junction connected in the reverse direction, so-called hot electrons are emitted. This means that the electrons to be emitted must overcome a potential gradient when they emerge from the emissive surface. Known drawbacks of the use of an electron emitter having a negative electron affinity (NEA) for generating so-called cold electrons are now avoided. An important one of these drawbacks is the high susceptibility of the emissive surface to external disturbances of the emission. For specific properties of a semiconductor element which emits hot electrons and which is connected in the reverse direction, reference is made to an article by Bartelink et al in Physical Review, Vol. 130. No. 3, May 1963, pp 972-985. In a preferred embodiment of an electron beam apparatus in accordance with the invention, the largest transverse dimension of a consecutive emissive surface is limited to a maximum of, for example approximately 10 .mu.m. Using semiconductor techniques, such as ion implantation, for example it is comparatively easy to realize a p-n junction having such a dimension. This offers major advantages for an electron beam apparatus because the dimensions of the emissive surface is thus adapted to electron-optical requirements to be imposed relative to the electron-optical lens system of the apparatus. Surprisingly, it has been found that by using dimensions of a customary order of magnitude a very effective emitter can indeed be realized. Even with an amply high current density for a source with these dimensions no problems are encountered relative to discharge of non-emitted electrons, so that no disturbing internal heating occurs in the semiconductor element and no potential distribution is generated which would adversely affect the current density distribution of the emitted electron beam. For some applications, for example, for beam writers, it may be attractive to use an elongated emissive surface, for example having a length/width radio of, for example from 5:1 to 10:1. Thus, a beam having an elongated cross-section can be realized and spaced charge problems can be reduced. Moreover, by using a line-shaped beam-splitting system, a row of 10 separate spots can be formed, for example. For optimizing the images use may be made, if desired, of a non-rotationally symmetrical electron-optical lens. Such an elongated emissive surface is preferably rectangular but may also be, for example, substantially elliptical, to realize a particularly narrow spot (see U.S. Pat. No. 3,881,136). A rectangularly emissive surface may notably form a square which may be attractive, for example, for beam writers because this allows for the formation of an electron beam having a rectangular cross-section and hence a similar shaped writing electron spot. In such an apparatus for the manufacture of integrated circuits, it may be advantageous to use a regular polygon in view of the manufacturing properties. Using known techniques, for example as described in U.S. Pat. No. 4,419,561, it is then also possible to apply beam shaping. In apparatus such as electron microscopes, it will usually be advantageous to use a round emissive surface in view of the customary rotationally-symmetrical electron-optical lens system. In all these cases dimensions of the emissive surface can be optimally adapted to the electron-optical system. In a preferred embodiment transverse dimensions of a singular emissive surface are limited to a maximum of 10 .mu.m, for example and usually preferably to a value of between, for example 0.5 .mu.m and 5 .mu.m. It is also comparatively simple to realize composite emissive surfaces, such as a central emissive surfaces, which is surrounded by an annular second surface, or an array or a matrix of several surfaces. When a sufficiently large distance is chosen between the sub-regions of a composite emmisive surface, the emission of each of these surfaces can be simply and independently controlled. The p-n junction in the electron emitter is preferably located at a depth of from approximately 0.01 .mu.m to 0.05 .mu.m below the emissive surface. Because at the surface no difference occurs in the semiconductor material of the emissive surface and that of the surrounding cathode surface, no edge problems will occur. The semiconductor element of a preferred embodiment consists of Si; and very good results have been obtained by means of this material also in relation to service life. However, it is alternatively possible to use, for example SiC, Si--SiO.sub.2 combinations, GaAs or similar group III-V combinations. Actually, the choice of the material is not relevant for the invention since as long as the requirements relation to a high current density together with emissive surface dimensions which are adapted to the apparatus are satisfied and a sufficiently long service life can be achieved. In order to achieve a further increase of the emission density, in a further embodiment the semiconductor element is provided at the area of the emissive surface with a substantially monomolecular layer of an appropriate material such as Cs, Ba, AgO, PtO, MiO, CO.sub.2, C etc.; good results have been obtained notably with Cs and Ba. The method of manufacturing a semiconductor electron emitter makes it comparatively simple to construct the emitter as a matrix or an array of emissive elements, for example, a series of 10 elements or an orthogonal matrix of 10.times.10 elements. Using multi-systems as described in U.S. Pat. No. 3,491,236, U.S. Pat No. 4,524,278 or U.S. Pat. No. 4,568,833, it is comparatively simple to render beams of each of these elements separately controllable because direct cathode control of at least the beam current is now possible, and a large part of the beam splitting system of the apparatus can now be dispensed with. Such a multi-beam apparatus is excellently suitable, for example, for the production of integrated circuits, notably those circuits where the electron beam writes directly in the semiconductor material i.e. without intermediate masks.