Patent Number: 
Section: claims

1. Lead-free radiation protection material in the energy range of an X-ray tube having a voltage of from 60 to 125 kV, having a layer structure of at least two layers with different shielding properties, said at least two layers comprising a secondary radiation layer and a barrier layer, wherein the secondary radiation layer comprises tin in an amount of from 50 to 90 wt. % and at least one further element and/or compound(s) thereof of atomic numbers 39 to 60 in an amount of from 10 to 50 wt. %. 2. Lead-free radiation protection material according to claim 1, wherein the element is selected from tin, iodine, caesium, barium, lanthanum, cerium, praseodymium, neodymium and compounds thereof. 3. Lead-free radiation protection material according to claim 1, wherein the secondary radiation layer comprises tin and cerium or a compound thereof. 4. Lead-free radiation protection material in the energy range of an X-ray tube having a voltage of from 60 to 125 kV, having a layer structure of at least two layers with different shielding properties, said at least two layers comprising a secondary radiation layer and a barrier layer, wherein the barrier layer comprises at least one element of atomic numbers greater than 71 or a compound thereof and wherein said at least one element is selected from bismuth, tungsten and compounds thereof and wherein the barrier layer further comprises at least one element of atomic numbers 61 to 71 or compounds thereof. 5. Lead-free radiation protection material according to claim 4, wherein the element is selected from the group erbium, holmium, dysprosium, terbium, gadolinium, europium, samarium, lutetium, ytterbium and thulium and compounds thereof. 6. Lead-free radiation protection material according to claim 5, wherein the element is gadolinium. 7. Lead-free radiation protection material according to claim 4, wherein at least one element of atomic numbers 61 to 71 or compounds thereof is present in the form of an intermediate layer which is arranged between the secondary radiation layer and the barrier layer. 8. Lead-free radiation protection material according to claim 4, wherein the barrier layer further comprises elements of atomic numbers greater than 71 and/or their compounds in an amount of up to 80 wt. %. 9. Lead-free radiation protection material according to claim 8, wherein the amount is in a range of from 20 to 70 wt. %. 10. Lead-free radiation protection material in the energy range of an X-ray tube having a voltage of from 60 to 125 kV, having a layer structure of at least two layers with different shielding properties, said at least two layers comprising a secondary radiation layer and a barrier layer, wherein the barrier layer comprises tungsten or compounds thereof in an amount of from 0 to 30 wt. % and/or bismuth or compounds thereof in an amount of at least 30 wt. %. 11. Lead-free radiation protection material according to claim 7, wherein the secondary radiation layer and/or the intermediate layer and/or the barrier layer comprise(s) at least one pure-material layer. 12. Lead-free radiation protection material according to claim 11, wherein the pure-material layers are greatly compressed. 13. Lead-free radiation protection material according to claim 12, wherein the pure-material layers are compressed to more than 75 vol. %. 14. Lead-free radiation protection material according to claim 13, wherein the pure-material layers are compressed to more than 90 vol. %. 15. Lead-free radiation protection material according to claim 14, wherein the greatly compressed pure-material layers are in the form of metal foils. 16. Lead-free radiation protection material according to claim 15, wherein the metal foils have a thickness of from 0.005 to 0.25 mm. 17. Lead-free radiation protection material according to claim 16, wherein the metal foils are foil strips or foil plates. 18. Lead-free radiation protection material according to claim 11, wherein the at least one pure-material layer has a carrier layer on one side. 19. Lead-free radiation protection material according to claim 11, wherein the at least one pure-material layer has a carrier layer on both sides. 20. Lead-free radiation protection material according to claim 18, wherein the carrier layers are formed by a polymer. 21. Lead-free radiation protection material according to claim 20, wherein the polymer is a latex or elastomer polymer. 22. Lead-free radiation protection material according to claim 20, wherein the carrier layers have a thickness of from 0.01 to 0.4 mm. 23. Lead-free radiation protection material according to claim 18, wherein the carrier layers comprise small amounts of protective substances. 24. Lead-free radiation protection material according to claim 11, wherein the pure-material layers of the protective foil are so composed that the layers are arranged according to increasing secondary radiation. 25. Lead-free radiation protection material according to claim 11, wherein each layer having high secondary radiation has on both sides a layer having low secondary radiation. 26. Radiation protection clothing of a lead-free radiation protection material according to claim 1. 27. Radiation protection clothing according to claim 26 in the form of an apron. 28. Radiation protection clothing of a lead-free radiation protection material according to claim 4. 29. Radiation protection clothing according to claim 28 in the form of an apron. 30. Radiation protection clothing of a lead-free radiation protection material according to claim 10. 31. Radiation protection clothing according to claim 30 in the form of an apron.