Patent Number: 
Section: claims

1. A process for separating americium from other metal elements present in a phase P1, which comprises one or more operations each comprising putting the phase P1 in contact with a phase P2 which is not miscible with the phase P1, and then separating the phase P1 from the phase P2, one of the phases P1 and P2 being an acid aqueous phase and the other one of the phases P1 and P2 being an organic phase which comprises at least one extractant in an organic diluent, and in which the acid aqueous phase contains an ethylenediamine derivative fitting the general formula (I) hereafter:wherein A1, A2, A3 and A4, which are identical or different, represent a group of general formula (II) hereafter:wherein:either X represents a nitrogen atom, in which case one of the R1, R2 and R4 represent a complexing group selected from the groups —COOH, —SO3H, —PO3H2, —CONH2 and —CON(CH3)2, while the other ones of R1, R2 and R4 represent independently of each other, a hydrogen atom or a group selected from the groups —OH, —NH2, —N(CH3)2, —COOH, —COOCH3, —CONH2, —CON(CH3)2, —SO3H, —SO3CH3, —PO3H2, —PO(OCH3)2, —O(CH2CH2)n—OH and —O(CH2CH2)n—OCH3 wherein n is an integer equal to or greater than 1;or X represents a carbon atom bearing a hydrogen atom or a group R3, in which case one of R1, R2, R3 and R4 represents a complexing group selected from the groups —COOH, —SO3H, —PO3H2, —CONH2 and —CON(CH3)2, while the other ones of R1, R2, R3 and R4 represent, independently of each other, a hydrogen atom or a group selected from the groups —OH, —NH2, —N(CH3)2, —COOH, —COOCH3, —CONH2, —CON(CH3)2, —SO3H, —SO3CH3, —PO3H2, —PO(OCH3)2, —O(CH2CH2)n—OH and —O(CH2CH2)n—OCH3 wherein n is an integer equal to or greater than 1;or a salt of the ethylenediamine derivative. 2. The process according to claim 1, in which, in general formula (I), A1, A2, A3 and A4 all represent a group of general formula (II) wherein X represents a nitrogen atom, or a carbon atom bearing a hydrogen atom, a group —OH or a group —O(CH2CH2)n—OH wherein n is an integer equal to or greater than 1. 3. The process according to claim 1, in which, in general formula (II), R1 represents a complexing group —COOH. 4. The process according to claim 3, in which, in general formula (II), R2 and R4 represent a hydrogen atom. 5. The process according to claim 1, in which, in the general formula (I), A1, A2, A3 and A4 are identical with each other. 6. The process according to claim 1, in which the ethylenediamine derivative of general formula (I) is selected from:N,N,N′,N′-tetrakis[-carboxypyridin-2-yl)methyl]ethylenediamine;N,N,N′,N′-tetrakis[(6-carboxy-4-hydroxypyridin-2-yl)methyl]ethylene-diamine;N,N,N′,N′-tetrakis[(6-carboxy-4-polyethyleneglycolpyridin-2-yl)methyl]-ethylenediamines; andN,N,N′,N′-tetrakis[(6-carboxypyrazin-2-yl)methyl]ethylenediamine. 7. The process according to claim 1, in which the acid aqueous phase is a nitric aqueous phase comprising from 0.001 to 3 mol/L of nitric acid. 8. The process according to claim 1, in which the ethylenediamine derivative of general formula (I) or salt thereof is present in the acid aqueous phase at a concentration ranging from 10−5 to 10−1 mol/L. 9. The process according to claim 1, in which the extractant(s) present in the organic phase is (are) selected from solvating extractants and cation exchange extractants. 10. The process according to claim 9, in which the extractant(s) is (are) selected from malonamides, N,N,N′,N′-tetraalkyl-3,6-dioxaoctane-diamides, lipophilic diglycolamides, alkylphosphine oxides, carbamoylphosphine oxides, carbamoylphosphonates, dialkyl sulfides, substituted pyridines, 2,2′-dibenzimidazoles, bisphenylphosphonic acid alkyl esters, alkylphosphoric acids, alkyphosphonates, alkylphosphinic acids, lipophilic carboxylic acids, sulfonic acids, thiophosphoric acids, thiophosphonic acids, thiophosphinic acids, thiophosphinic acids, thiophosphorous acids, lipophilic hydroxyoximes and lipophilic β-diketones. 11. The process according to claim 1, in which the organic phase further comprises at least one phase modifying agent. 12. A process for selectively recovering americium from a first acid aqueous phase comprising americium and other metal elements, the process comprising a step of separating americium from the other metal elements present in a phase P1, which comprises one or more operations each comprising putting the phase P1 in contact with a phase P2 which is not miscible with the phase P1, and then separating the phase P1 from the phase P2, one of the phases P1 and P2 being the first acid aqueous phase or a second acid aqueous phase and the other one of the phases P1 and P2 being an organic phase which comprises at least one extractant in an organic diluent, and in which the first or second acid aqueous phase comprises an ethylenediamine derivative fitting general formula (I) hereafter:wherein A1, A2, A3 and A4, which are identical or different, represent a group of general formula (II) hereafter:wherein:either X represents a nitrogen atom, in which case one of the R1, R2 and R4 represent a complexing group selected from the groups —COOH, —SO3H, —PO3H2, —CONH2 and —CON(CH3)2, while the other ones of R1, R2 and R4 represent independently of each other, a hydrogen atom or a group selected from the groups —OH, —NH2, —N(CH3)2, —COOH, —COOCH3, —CONH2, —CON(CH3)2, —SO3H, —SO3CH3, —PO3H2, —PO(OCH3)2, —O(CH2CH2)n—OH and —O(CH2CH2)n—OCH3 wherein n is an integer equal to or greater than 1;or X represents a carbon atom bearing a hydrogen atom or a group R3, in which case one of R1, R2, R3 and R4 represents a complexing group selected from the groups —COOH, —SO3H, —PO3H2, —CONH2 and —CON(CH3)2, while the other ones of R1, R2, R3 and R4 represent, independently of each other, a hydrogen atom or a group selected from the groups —OH, —NH2, —N(CH3)2, —COOH, —COOCH3, —CONH2, —CON(CH3)2, —SO3H, —SO3CH3, —PO3H2, —PO(OCH3)2, —O(CH2CH2)n—OH and —O(CH2CH2)n—OCH3 wherein n is an integer equal to or greater than 1;or a salt of the ethylenediamine derivative. 13. The process according to claim 12, in which the first acid aqueous phase is a nitric aqueous phase which comprises as other metal elements at least curium and fission products including lanthanides, and is free of uranium, plutonium and neptunium or comprises uranium, plutonium and neptunium as trace amounts. 14. The process according to claim 13, in which the nitric aqueous phase is a raffinate stemming from a first purification cycle of a process for processing used nuclear fuels PUREX or COEX. 15. The process according to claim 12, which comprises at least the following steps:a) extraction of the americium and of all or part of the other metal elements from the first acid aqueous phase, the extraction comprising at least one operation in which the first acid aqueous phase is put into contact with an organic phase which is non-miscible with the first acid aqueous phase, the organic phase comprising at least one extractant in an organic diluent, and then the first acid aqueous phase is separated from the organic phase; andb) selective stripping of the americium from the organic phase stemming from step a), the stripping comprising at least one operation in which the organic phase is put into contact with the second acid aqueous phase, the second aqueous phase comprising the ethylenediamine derivative of general formula (I) or the salt thereof, and then the organic phase is separated from the second acid aqueous phase. 16. The process according to claim 15, in which the first acid aqueous phase subject to step a) comprises at least one complexing agent. 17. The process according to claim 15, in which:step a) further comprises, after the separation of the organic phase from the first acid aqueous phase, at least one operation of washing the organic phase with a third acid aqueous phase; and/orstep b) further comprises, after the separation of the organic phase from the second acid aqueous phase, at least one operation of washing the second acid aqueous phase with an organic phase having the same composition as the one organic phase used in step a). 18. The process according to claim 15, which further comprises a step c) of stripping the other metal elements from the organic phase stemming from step b), the stripping comprising at least one operation in which the organic phase is put into contact with a fourth acid aqueous phase and then the organic phase is separated from the fourth acid aqueous phase. 19. The process according to claim 15, in which the organic phase used in step a) comprises a mixture of a malonamide and of an alkylphosphoric acid, or a diglycolamide extractant. 20. The process according to claim 12, which comprises at least one step a) of selective extraction of all the other metal elements from the first acid aqueous phase, the extraction comprising at least one operation in which the first acid aqueous phase is put into contact with an organic phase which is non-miscible with the first acid aqueous phase, the organic phase comprising at least one extractant in an organic diluent, and then the first acid aqueous phase is separated from the organic phase, and the extraction being carried out after or simultaneously to an addition of the ethylenediamine derivative of general formula (I) or the salt thereof to the first acid aqueous phase. 21. The process according to claim 20, in which step a) further comprises, after the separation of the organic phase from the first acid aqueous phases, at least one operation of washing the organic phase, the washing comprising putting the organic phase in contact with a second acid aqueous phase comprising the ethylenediamine derivative of general formula (I) or the salt thereof and then separating the organic phase from the second acid aqueous phase. 22. The process according to claim 20, which further comprises a step b) of stripping the other metal elements from the organic phase stemming from step a), the stripping comprising at least one operation in which the organic phase is put into contact with a third acid aqueous phase, and then the organic phase is separated from this the third acid aqueous phase. 23. The process according to claim 22, in which the third acid aqueous phase used in step b) comprises at least one complexing agent. 24. The process according to claim 20, in which the organic phase used in step a) comprises a mixture of an alkylphosphoric acid extractant and of a phase modifying agent, or a diglycolamide extractant. 25. The process according to claim 12, characterized in that the ethylenediamine derivative of general formula (I) is N,N,N′,N′-tetrakis[(6-carboxypyridin-2-yl)methyl]ethylenediamine. 26. The process according to claim 12, characterized in that the ethylenediamine derivative of general formula (I) or the salt thereof is present in the first or second acid aqueous phase at a concentration ranging from 10−4 to 10−2 mol/L.