Patent Number: 047642815
Section: claims

1. A method of treating a heavy metal radioisotope-bearing liquid to remove a substantial portion of the metal radioisotope metals therefrom without substantial sludge formation comprising: contacting said liquid with a water-insoluble carboxylated cellulose in an amount sufficient to cause precipitation of a substantial portion of the heavy metal radioisotope in the liquid.  contacting said liquid with a water-insoluble carboxylated cellulose in an amount sufficient to cause precipitation of a substantial portion of the heavy metal radioisotope in the liquid.  contacting said liquid with a water-insoluble carboxylated cellulose in an amount sufficient to cause precipitation of a substantial portion of the heavy metal radioisotope in the liquid; and  adding sodium diethyldithiocarbamate to said liquid in an amount sufficient to reduce precipitation time. 2. The method of claim 1 wherein the water-insoluble carboxylated cellulose is a salt of carboxymethylcellulose. 3. The method of claim 2 wherein the water-insoluble salt of carboxymethylcellulose is aluminum carboxymethylcellulose or chromium carboxymethylcellulose. 4. The method of claim 3 wherein the water-insoluble salt of carboxymethylcellulose is aluminum carboxymethylcellulose. 5. The method of claim 1 wherein the metal precipitated from said liquid is a radioactive metal selected from the group consisting of radium, radon, rhenium, molybdenum, praseodymium, polonium, lead, astatine, bismuth, thallium, mercury, zirconium, barium, promethium, uranium, cesium, strontium, ruthenium, neptunium, technetium, iodine, thorium, niobium, cerium, rubidium, palladium, curium, plutonium, tellurium, samarium, americium, protactinium, lanthanum, indium, neodymium, lutetium, rhodium or mixtures thereof. 6. The method of claim 5 wherein the metal precipitated from said liquid comprises radium, uranium, cesium, stontium, ruthenium, rhenium, neptunium, technetium or rhodium. 7. The method of claim 1 wherein the said liquid includes an aqueous liquid. 8. The method of claim 7 wherein the said aqueous liquid comprises natural waters, wastewaters, manufacturing effluents, or water-containing mixtures. 9. The method of claim 7 including adjusting the pH of said liquid above 6.0 and below 9.0 before contacting said liquid with the insoluble carboxylated cellulose. 10. The method of claim 9 wherein the insoluble carboxylated cellulose is a salt of carboxymethylcellulose. 11. The method of claim 1 further comprising initially treating said liquid with an oxidizing agent to destroy one or more interfering ions. 12. The method of claim 11 wherein said oxidizing agent is selected from the group consisting of ozone (O.sub.3), chlorine gas (Cl.sub.2) and hypochlorite ion (OCl.sup.-). 13. The method of claim 11 wherein said interfering ion is cyanide (CN.sup.-). 14. A method of treating a heavy metal radioisotope-bearing liquid containing a non-aqueous liquid, to remove a substantial portion of the metal radioisotope metals therefrom without substantial sludge formation comprising: 15. The method of claim 14 wherein the said non-aqueous liquid comprises oil, petroleum distillates or lubricants. 16. A method of treating a heavy metal radioisotope-bearing liquid to remove a substantial portion of the metal radioisotope metals therefrom without substantial sludge formation comprising: