Patent Number: 056407017
Section: claims

1. A method for treating material contaminated with soluble radioactive species comprising the steps of: a. providing contaminated soil;  b. introducing into said soil an aqueous extracting solution, said extracting solution having a pH greater than or equal to about 7.5;  c. segregating fine vegetation from said soil;  d. introducing into said soil an acid in an amount sufficient to lower the pH of the extracting solution;  e. separating said soil from said extracting solution; and  f. removing said radioactive species from said extracting solution.  i. floating and/or fluidizing said fine vegetation from said soil; and  ii. gathering said vegetation.  i. treating said soil with a flocculent and/or a coagulant to coagulate substantially all of organic material and said soil, and  ii. then segregating said coagulant from said extracting solution by settling, centrifugation, and/or filtration.  a. providing contaminated soil;  b. introducing into said soil an aqueous extracting solution comprising sodium carbonate and potassium carbonate, or ammonium carbonate, said extracting solution having a pH and being added in an amount sufficient to solubilize, mobilize or disperse at least about 10% by weight of said contaminate into solution;  c. segregating contaminated fine vegetation from said soil;  d. introducing into said extracting solution a mineral acid, said mineral acid being added in an amount sufficient to remove substantially all organic material from said extracting solution;  e. separating clean soil from said extracting solution; and  f. removing said radioactive species from said extracting solution.  a. providing a contaminated process stream used in removing contaminants from contaminated soil, said process stream comprising soil particles, clay and silt particles, humus and fine vegetation;  b. introducing into said process stream an aqueous extracting solution comprising sodium carbonate and potassium carbonate, or ammonium carbonate, said extracting solution having a pH greater or equal to about 7.5;  c. segregating contaminated vegetation from said process stream;  d. introducing into said process stream a mineral acid in an amount sufficient to lower the pH of the extracting solution;  e. separating clean particulate material from said process stream;  f. removing said radioactive species from said process stream. 2. The method of claim 1 wherein said material to be treated contains at least one soluble radioactive species selected from the group consisting of uranium, radium, cesium, cobalt, strontium, americium, thorium, plutonium, cerium, rubidium and mixtures thereof. 3. The method of claim 1 wherein said radioactive species is uranium, radium, or a mixture thereof. 4. The method of claim 1 wherein step (a) comprises providing contaminated soil comprising soil particles, clay and silt particles, humus and fine vegetation. 5. The method of claim 1 wherein step (b) comprises introducing an aqueous extracting solution comprising sodium carbonate and potassium carbonate, or ammonium carbonate. 6. The method of claim 1 wherein said extracting solution has a pH greater than or equal to about 8. 7. The method of claim 6 wherein said pH is greater than or equal to about 8.5. 8. The method of claim 6 wherein said pH is greater than or equal to about 9. 9. The method of claim 1 wherein step (b) comprises introducing an aqueous extracting solution consisting essentially of sodium carbonate and potassium carbonate. 10. The method of claim 1 wherein step (b) comprises introducing an aqueous extracting solution consisting essentially of ammonium carbonate. 11. The method of claim 1 wherein step (c) comprises the steps of: 12. The method of claim 1 wherein step (d) comprises introducing at least one acid selected from the group consisting of hydrochloric acid, nitric acid, sulfuric acid, perchloric acid, or a mixture thereof. 13. The method of claim 12 wherein said acid is hydrochloric acid. 14. The method of claim 1 wherein said acid is added in an amount sufficient to remove substantially all organic material from said extracting solution. 15. The method of claim 1 wherein said acid is added in an amount sufficient to lower the pH of the extracting solution to less than or equal to about 7. 16. The method of claim 1 wherein said acid is added in an amount sufficient to lower the pH of the extracting solution to less than or equal to about 7.5. 17. The method of claim 1 wherein said acid is added in an amount sufficient to lower the pH of the extracting solution to less than or equal to about 8. 18. The method of claim 1 wherein said acid is added in an amount sufficient to lower the pH of the extracting solution to less than or equal to about 8.5. 19. The method of claim 1 wherein said acid is added in an amount sufficient to lower the pH of the extracting solution to less than or equal to about 9. 20. The method of claim 1 wherein step (e) comprises the further steps of: 21. The method of claim 1 wherein step (f) comprises removing said radioactive species from said extracting solution by at least one means selected from ion exchange, precipitation, and zeolitic adsorption. 22. A method for remediating soil contaminated with uranium, or radium, or a mixture thereof, comprising the steps of: 23. The method of claim 22 wherein step (b) comprises introducing into said soil an aqueous extracting solution having a pH greater than or equal to about 7.5. 24. The method of claim 23 wherein said pH is greater than or equal to about 8. 25. The method of claim 23 wherein said pH is greater than or equal to about 8.5. 26. The method of claim 23 wherein said pH is greater than or equal to about 9. 27. The method of claim 23 wherein said pH is greater than or equal to about 9.5. 28. The method of claim 23 wherein said pH is greater than or equal to about 10. 29. The method of claim 22 wherein step (d) comprises introducing said mineral acid in an amount sufficient to lower the pH of said extracting solution to equal to or less than about 7. 30. The method of claim 22 wherein said mineral acid is added in an amount sufficient to lower the pH to equal to or less than about 7.5. 31. The method of claim 22 wherein said mineral acid is added in an amount sufficient to lower the pH to equal to or less than about 8. 32. The method of claim 22 wherein said mineral acid is added in an amount sufficient to lower the pH to equal to or less than about 8.5. 33. The method of claim 22 wherein said mineral acid is added in an amount sufficient to lower the pH to equal to or less than about 9. 34. The method of claim 22 wherein said mineral acid is added in an amount sufficient to lower the pH to equal to or less than about 10. 35. A method for treating material contaminated with soluble radioactive species comprising the steps of: