Patent Number: 06297419&
Section: claims

1. A process for the treatment of zirconium based metal waste, the process including the steps of converting at least some of said zirconium based metal to an oxide thereafter forming a mixture of said oxide with a sol or a solution of a suitable gel forming material producing a green body from the mixture, and sintering said green body into a sintered body. 2. A process according to claim 1 wherein said material hardens by hydrolysis. 3. A process according to claim 2 wherein said gel forming material comprises a metal salt. 4. A process according to claim 3 wherein said salt is an alkoxide. 5. A process according to claim 4 wherein said alkoxide is aluminum secondary butoxide or aluminum isopoxide. 6. A process according to claim 1 wherein the gel forming material is treated with a modifying agent. 7. A process according to claim 6 wherein said modifying agent is an alkanolamine. 8. A process according to claim 7 wherein said alkanolamine is triethanolamine. 9. A process according to claim 1 wherein the zirconium oxide is mixed with a hydrolyzed zirconium salt or other metal salt. 10. A process according to claim 1 wherein the green body is dried prior to sintering. 11. A process according to claim 1 wherein the green body is formed in a desired shape by casting in a mold or by extrusion. 12. A process according to claim 1 wherein additional metal oxides are present in said green body to stabilize the chemical phases of said sintered body. 13. A process according to claim 1 wherein the sintering temperature is in the region of 1400.degree. C. 14. A process according to claim 1 wherein said zirconium based metal is brought into solution by chemical or by electrochemical dissolution. 15. A process according to claim 14 wherein said oxide includes at least some zirconium oxide formed directly as a result of said dissolution. 16. A process according to claim 14 wherein said oxide includes at least some zirconium oxide formed by conversion from said zirconium based metal in solution. 17. A process according to claim 14 wherein the metal solution is in the form of a nitrate. 18. A process according to claim 17 wherein the nitrate is thermally treated to decompose the nitrate to the oxide. 19. A process according to claim 14 wherein the zirconium based metal is brought into solution by means of dissolution of a fluoride. 20. A process according to claim 1 wherein the zirconium based metal waste is derived from the cladding of a nuclear fuel rod. 21. A process according to claim 20 wherein the zirconium based metal is derived from whole fuel rods comprising irradiated fuel. 22. A process according to claim 21 wherein said zirconium based metal is brought into solution by chemical or by electrochemical dissolution, said oxide includes at least some zirconium oxide formed by conversion from said zirconium based metal in solution, and fuel constituents of the solution are separated prior to said conversion of the solution to the oxide. 23. A process according to claim 22 wherein at least some fission product constituents remain with the zirconium solution and the resulting oxide. 24. A process according to claim 1 wherein the sintered body is hot pressed to densify it. 25. The process for the treatment of zirconium based metal waste of claim 1 further comprising the step of storing said sintered body. 26. A process for the treatment of zirconium based metal waste, the process including the steps of converting at least some of said zirconium based metal to an oxide, thereafter forming a mixture of said oxide with a suitable material which gels and harden by heat, producing a green body from the mixture, and sintering said green body. 27. A process according to claim 26 wherein said material is selected from the group consisting of zirconium acetate, zirconium acetate combined with citric acid, zirconium nitrate combined with citric acid and zirconium acrylamide. 28. The process for the treatment of zirconium based metal waste of claim 26 further comprising the step of storing said sintered green body. 29. A process for the treatment of zirconium based metal waste, the process including the steps of converting at least some of said ziconium based metal to an oxide, thereafter forming a mixture of said oxide with a sol which gel and is freeze-castable, producing a green body from the mixture, and sintering said green body. 30. A process according to claim 29 wherein the sol comprises a silica sol or a zirconia sol, and the mixture thereof with the said oxide is solidified by freeze-casting to form a solid, handleable green body for sintering. 31. A process according to claim 29 wherein filler powder is included in said mixture. 32. A process according to claim 29 wherein said mixture is frozen at a temperature in the region of -50.degree. C. 33. A process according to claim 29 wherein the green body is thawed prior to sintering. 34. The process for the treatment of zirconium based metal waste of claim 29 further comprising the step of storing said sintered green body.