Patent Number: 054950627
Section: claims

1. A method of decontaminating soil containing nuclear waste, which comprises the steps of: (a) mixing a liquid ammonia with a soil contaminated with nuclear waste in a closed vessel to form an ammonia-nuclear waste-containing soil dispersion or slurry;  (b) allowing soil particles to selectively precipitate from the dispersion or slurry of step (a) to form a lower solid phase of soil particulates while forming an upper liquid-solid phase comprising soil fines dispersed in said liquid ammonia, the soil particulates of said lower phase having greater bulk density relative to the soil fines of said upper liquid-solid phase;  (c) separating said upper liquid-solid phase from said lower solid phase of soil particulates, the lower solid phase being sufficiently free of said nuclear waste, and  (d) separating the ammonia from the soil fines containing the nuclear waste material for disposal or further treatment of said fines.  (a) mixing a liquid ammonia with a soil contaminated with nuclear waste in a closed vessel to form an ammonia-nuclear waste-containing soil dispersion or slurry;  (b) treating the dispersion or slurry of step (a) with solvated electrons by contacting with a reactive metal;  (c) allowing soil particles to selectively precipitate from the dispersion or slurry of step (b) to form a lower solid phase of soil particulates while forming an upper liquid-solid phase comprising soil fines dispersed in said liquid ammonia, the soil particulates of said lower phase having a greater bulk density relative to the soil fines of said upper phase;  (d) separating said upper liquid-solid phase from said lower solid phase of soil particulates, the lower solid phase being sufficiently free of said nuclear waste, and  (e) separating the ammonia from the soil fines containing the nuclear waste material for disposal or further treatment of said fines. 2. The method of claim 1 including the step of recovering and recycling the ammonia from step (d). 3. The method of claim 1 wherein the liquid ammonia of step (a) is anhydrous liquid ammonia or an ammonia-containing solution. 4. The method of claim 3 wherein the nuclear waste comprises at least one radionuclide, and the soil comprises at least one member selected from the group consisting of clay, disintegrated rock and organic matter. 5. The method of claim 3 wherein the nuclear waste contaminated soil comprises mainly sand. 6. The method of claim 4 wherein the soil of step (a) comprises a radionuclide selected from the group consisting of uranium, plutonium and mixtures thereof. 7. The method of claim 5 wherein the sand comprises a radionuclide selected from the group consisting of uranium, plutonium and mixtures thereof. 8. The method of claim 1 including the step of separating the ammonia from the soil fines of step (d) by distillation means. 9. A method of decontaminating soil containing nuclear waste, which comprises the steps of: 10. The method of claim 9 including the step of recovering and recycling the ammonia from step (e). 11. The method of claim 9 wherein the liquid ammonia is anhydrous liquid ammonia and the reactive metal is a member selected from the group consisting of alkali metal and alkaline earth metal. 12. The method of claim 11 wherein step (b) is performed by circulating at least a portion of the ammonia-containing slurry through a by-pass containing the reactive metal where it dissolves and the slurry is recirculated to the closed vessel for treating the balance of the slurry with solvated electrons. 13. The method of claim 11 wherein the liquid ammonia of step (a) is anhydrous liquid ammonia or an ammonia-containing solution. 14. The method of claim 13 wherein the nuclear waste comprises at least one radionuclide, and the soil comprises at least one member selected from the group consisting of clay, disintegrated rock and organic matter. 15. The method of claim 13 wherein the nuclear waste contaminated soil comprises mainly sand. 16. The method of claim 14 wherein the soil of step (a) comprises a radionuclide selected from the group consisting of uranium, plutonium and mixtures thereof. 17. The method of claim 15 wherein the sand of step (a) comprises a radionuclide selected from the group consisting of uranium, plutonium and mixtures thereof. 18. The method of claim 9 including the step of separating the ammonia from the soil fines of step (e) by distillation means.