Patent Number: 
Section: claims

1. A method for remediating non-homogeneous radioactive waste, wherein the waste contains low boiling temperature/high vapor pressure components and heavy metal/transuranic components, the method comprising: isolating the waste in a reaction vessel;  providing an inert atmosphere within the reaction vessel;  reducing the pressure within the reaction vessel;  raising the temperature within the reaction vessel to a temperature necessary to vaporize the low boiling temperature/high vapor pressure components to form a gaseous waste portion;  removing the gaseous waste portion from the reaction vessel;  treating the gaseous waste portion for disposal;  raising the temperature within the reaction vessel to a temperature necessary to cause pyrolysis of the heavy metal/transuranic components to form gaseous nitrogen oxides and solid metal oxide ash;  treating the gaseous metal oxides for disposal;  separating the solid metal oxide ash into a sodium containing fraction and a sodium free fraction; and  remediating the sodium fraction and the sodium free fraction for storage. 2. The method of  claim 1  wherein the reaction vessel is shielded to prevent leakage of radioactivity. claim 1 3. A method for treating non-homogeneous radioactive waste, wherein the waste contains an aqueous portion and a solid/sludge portion, the solid/sludge portion contains low boiling organic components, volatile metal components, and heavy metal/transuranic components, the method comprising: decanting the aqueous portion from the solid/sludge portion;  remediating the aqueous portion for disposal;  isolating the solid/sludge portion in a reaction vessel;  providing an inert atmosphere within the reaction vessel;  reducing the pressure within the reaction vessel;  raising the temperature within the reaction vessel to a first temperature at which the low boiling organic components are converted to a gaseous state;  maintaining the first temperature until essentially all the low boiling organic components are converted to a gaseous state;  removing the gaseous low boiling organic components from the reaction vessel;  remediating the gaseous low boiling organic components for disposal;  raising the temperature within the reaction vessel to a second temperature at which the volatile metal components are converted to a gaseous state;  maintaining the second temperature until essentially all the volatile metal components are converted to a gaseous state;  removing the gaseous volatile metal components;  remediating the gaseous volatile metal components for disposal;  raising the temperature within the reaction vessel to a third temperature at which pyrolysis of the heavy metal/transuranic components occurs;  maintaining the third temperature until the heavy metal/transuranic components are converted to gaseous nitrogen oxides and solid metal oxide ash, wherein the metal oxide ash contains water soluble metal oxide components and water insoluble metal oxide components;  removing the gaseous nitrogen oxides from the reaction vessel;  remediating the gaseous nitrogen oxides for disposal;  removing the metal oxide ash from the reaction vessel;  separating the metal oxide ash into at least two fractions, at least one fraction being essentially sodium and at least one fraction being essentially sodium free;  remediating the at least one sodium fraction for disposal; and  remediating the at least one sodium free fraction for disposal. 4. The method of  claim 3  wherein the remediation of the at least one sodium fraction comprises vitrifying the sodium fraction into sodium aluminum silicate glass. claim 3 5. The method of  claim 3  wherein the remediation of the at least one sodium free fraction comprises vitrifying the sodium free fraction into borosilicate glass. claim 3 6. The method of  claim 3  further including shielding the reaction vessel to prevent leakage of radiation from the reaction vessel. claim 3 7. The method of  claim 3  wherein remediating the gaseous organic components comprises: claim 3 catalytically oxidizing the gaseous low boiling organic components to form carbon dioxide and hydrogen halides; and  scrubbing the carbon dioxide and hydrogen halides through sodium hydroxide to form sodium halide and sodium carbonate. 8. The method of  claim 3  wherein remediating the gaseous volatile metal components comprises: claim 3 scrubbing the gaseous volatile metal components through water to create a metal ion solution;  concentrating the metal ion solution by reverse osmosis of the metal ion solution through a membrane; and  immobilizing the concentrated metal ion solution in a radiation shielding polymer matrix. 9. The method of  claim 8  wherein the reverse osmosis membrane is a polymeric membrane having a molecular weight cut off of about 50. claim 8 10. The method of  claim 8  wherein the radiation shielding polymer matrix comprises: claim 8 about 25 to 75% at least one aromatic isocyanate monomer;  about 20 to 70% at least one phenolic resin, the phenolic resin being produced by polycondensation of a phenol compound with formaldehyde;  about 3 to 10% at least one halogenated phosphate ester flame retardant; and  about 0 to 1.0% at least one catalyst. 11. The method of  claim 8  wherein the radiation shielding polymer matrix comprises; claim 8 about 40% diphenylmethane 4,4xe2x80x2-diisocyanate;  about 53.85 to 54% phenolic resin, the phenolic resin being produced by polycondensation of phenol with formaldehyde;  about 6% halogenated phosphate ester retardant; and  about 0 to 0.15% phenypropyl pyridine. 12. The method of  claim 3  wherein the remediation of the gaseous nitrogen oxides comprises: claim 3 reducing the nitrogen oxides to ammonia; and  scrubbing the ammonia through phosphoric acid to form ammonium phosphate. 13. The method of  claim 3  wherein the remediation of the metal oxide ash comprises: claim 3 washing the metal oxide ash with water to form a metal ion solution of the water soluble metal oxide components, wherein the water soluble metal oxide components contain sodium, strontium, technetium and cesium;  filtering the metal ion solution to remove the water insoluble metal oxide components;  bubbling carbon dioxide through the filtered metal ion solution to form strontium carbonate precipitate;  adding hydrazine hydrate to the metal ion solution to reduce the technetium;  decanting the metal ion solution from the precipitate;  adding the precipitate to the water insoluble metal oxide components;  drying the precipitate and water insoluble metal oxide components;  diluting the metal ion solution with water;  removing the sodium from the diluted metal ion solution by reverse osmosis through a membrane, whereby the sodium is removed from a retentate solution and added to a filtrate solution;  repeating the diluting and removing steps until the retentate solution is essentially sodium free;  drying the filtrate solution to recover the sodium;  vitrifying the sodium to produce sodium aluminum silicate glass;  removing metal ions from the retentate solution by running the retentate solution through an ion exchange medium, whereby the metal ions are retained by the ion exchange medium;  drying the ion exchange medium; and  vitrifying the ion exchange medium and the water insoluble metal oxide components into borosilicate glass. 14. The method of  claim 13  wherein the reverse osmosis membrane is a polymeric nanofiltration membrane. claim 13 15. A method for treating non-homogeneous radioactive waste, wherein the waste contains an aqueous portion and a solid/sludge portion, the solid/sludge portion contains low boiling organic components, volatile metal components, and heavy metal/transuranic components, the method comprising: decanting the aqueous portion from the solid/sludge portion;  isolating the solid/sludge portion in a reaction vessel;  flushing the reaction vessel with an inert gas;  reducing the pressure within the reaction vessel;  raising the temperature within the reaction vessel to a first temperature at which the low boiling organic components are converted to a gaseous stage;  maintaining the first temperature until essentially all the low boiling organic components are converted to a gaseous state;  removing the gaseous organic components from the reaction vessel;  catalytically oxidizing the gaseous organic components to form carbon dioxide and hydrogen halides;  scrubbing the carbon dioxide and hydrogen halides through sodium hydroxide to form sodium halide and sodium carbonate;  raising the temperature within the reaction vessel to a second temperature at which the volatile metal components are converted to a gaseous state;  maintaining the second temperature until essentially all the volatile metal components are converted to a gaseous state;  removing the gaseous volatile metal components from the reaction vessel;  scrubbing the gaseous volatile metal components through water to create a volatile metal ion solution;  concentrating the volatile metal ion solution by reverse osmosis of the volatile metal ion solution through a first membrane;  immobilizing the concentrated volatile metal ion solution in a radiation shielding polymer;  raising the temperature within the reaction vessel to a third temperature at which pyrolysis of the heavy metal/transuranic components occurs;  maintaining the third temperature until the heavy metal/transuranic components are converted to gaseous nitrogen oxides and solid metal oxide ash, wherein the metal oxide ash contains water soluble metal oxide components and water insoluble metal oxide components;  removing the gaseous nitrogen oxides from the reaction vessel;  reducing the nitrogen oxides to ammonia;  scrubbing the ammonia through phosphoric acid to form ammonium phosphate;  removing the solid metal oxide ash from the reaction vessel;  washing the metal oxide ash with water to form a heavy metal ion solution of the water soluble metal oxide components, wherein the water soluble metal oxide components contain sodium, strontium, technetium and cesium;  adding the decanted aqueous portion to the heavy metal ion solution;  bubbling carbon dioxide through the heavy metal ion solution to precipitate the strontium as strontium carbonate;  adding hydrazine hydrate to the heavy metal ion solution to reduce the technetium;  decanting the heavy metal ion solution from the water insoluble metal oxide components;  drying the water insoluble metal oxide components;  diluting the heavy metal ion solution with water;  removing the sodium from the diluted heavy metal ion solution by reverse osmosis through a second membrane, whereby the sodium is removed from a retentate solution and added to a filtrate solution;  repeating the diluting and removing steps until the retentate solution is essentially sodium free;  drying the filtrate solution to recover the sodium;  vitrifying the sodium to produce sodium aluminum silicate glass;  removing metal ions from the retentate solution by running the retentate solution through an ion exchange medium, whereby the metal ions are retained by the ion exchange medium;  drying the ion exchange medium; and  vitrifying the ion exchange medium and the water insoluble metal oxide components into borosilicate glass. 16. The method of  claim 15  wherein the inert gas is selected from the group consisting of helium, neon, and argon. claim 15 17. The method of  claim 15  wherein the pressure is reduced to about 0.1 atmospheres. claim 15 18. The method of  claim 15  wherein the first temperature is about 30 to 40xc2x0 C. at 0.1 atmospheres. claim 15 19. The method of  claim 15  wherein the second temperature is about 60 to 70xc2x0 C. at 0.1 atmospheres. claim 15 20. The method of  claim 15  wherein the third temperature is about 200 to 300xc2x0 C. at 0.1 atmospheres. claim 15 21. The method of  claim 15  wherein the first reverse osmosis membrane is a polymeric membrane having a molecular weight cut off of about 50. claim 15 22. The method of  claim 15  wherein the second reverse osmosis membrane is a polymeric nanofiltration membrane. claim 15 23. The method of  claim 15  wherein the ion exchange medium is at least one zeolite. claim 15 24. The method of  claim 15  wherein the radiation shielding polymer comprises: claim 15 about 25 to 75% at least one aromatic isocyanate monomer;  about 20 to 70% at least one phenolic resin, the phenolic resin being produced by polycondensation of a phenol compound with formaldehyde;  about 3 to 10% at least one halogenated phosphate ester flame retardant; and  about 0 to 1.0% at least one catalyst. 25. The method of  claim 15  wherein the radiation shielding polymer comprises; claim 15 about 40% diphenylmethane 4,4xe2x80x2-diisocyanate;  about 53.85 to 54% phenolic resin, the phenolic resin being produced by polycondensation of phenol with formaldehyde;  about 6% halogenated phosphate ester retardant; and  about 0 to 0.15% phenypropyl pyridine. 26. A method for treating non-homogeneous radioactive waste, wherein the waste contains heavy metal/transuranic components, the method comprising: pyrolyzing the waste, whereby the heavy metal/transuranic components are converted to gaseous nitrogen oxides and solid metal oxide ash, wherein the metal oxide ash contains water soluble metal oxide components and water insoluble metal oxide components;  removing the gaseous nitrogen oxides from the reaction vessel;  remediating the gaseous nitrogen oxides for disposal; and  separating the metal oxide ash into at least two fractions, at least one fraction being essentially sodium, and at least one fraction being essentially sodium free;  remediating the sodium fraction and the sodium free fraction for storage. 27. The method of  claim 26  wherein the remediation of the gaseous nitrogen oxides comprises: claim 26 reducing the nitrogen oxides to ammonia; and  scrubbing the ammonia through phosphoric acid to form ammonium phosphate. 28. The method of  claim 26  wherein the separation of the metal oxide ash comprises: claim 26 washing the metal oxide ash with water to form a metal ion solution of the water soluble metal oxide components, wherein the water soluble metal oxide components contain sodium, strontium, technetium and cesium;  filtering the metal ion solution to remove the water insoluble metal oxide components;  bubbling carbon dioxide through the metal ion solution to form strontium carbonate precipitate;  adding hydrazine hydrate to the metal ion solution to reduce the technetium;  decanting the metal ion solution from the precipitate;  adding the precipitate to the water insoluble metal oxide components;  drying the water insoluble metal oxide components;  diluting the decanted metal ion solution with water;  removing the sodium from the diluted metal ion solution by reverse osmosis through a membrane, whereby the sodium is removed from a retentate solution and added to a filtrate solution;  repeating the diluting and removing steps until the retentate solution is essentially sodium free;  drying the filtrate solution to recover the sodium;  vitrifying the sodium to produce sodium aluminum silicate glass;  removing metal ions from the retentate solution by running the retentate solution through an ion exchange medium, whereby the metal ions are retained by the ion exchange medium;  drying the ion exchange medium; and  vitrifying the ion exchange medium and the water insoluble metal oxide components into borosilicate glass. 29. The method of  claim 26  wherein the reverse osmosis membrane is a polymeric nanofiltration membrane. claim 26 30. A method for treating non-homogeneous radioactive waste, wherein the waste contains heavy metal/transuranic components, the method comprising: pyrolyzing the waste, whereby the heavy metal/transuranic components are converted to gaseous nitrogen oxides and solid metal oxide ash, wherein the metal oxide ash contains water soluble metal oxide components and water insoluble metal oxide components;  removing the gaseous nitrogen oxides from the reaction vessel;  reducing the nitrogen oxides to ammonia;  scrubbing the ammonia through phosphoric acid to form ammonium phosphate;  removing the solid metal oxide ash from the reaction vessel;  washing the metal oxide ash with water to form a metal ion solution of the water soluble metal oxide components, wherein the water soluble metal oxide components contain sodium, strontium, technetium and cesium;  filtering the metal ion solution to remove the water insoluble metal oxide components;  bubbling carbon dioxide through the filtered metal ion solution to form strontium carbonate precipitate;  adding hydrazine hydrate to the metal ion solution to reduce the technetium;  decanting the metal ion solution from the precipitate;  adding the precipitate to the water insoluble metal oxide components;  drying the water soluble metal oxide components;  diluting the metal ion solution with water;  removing the sodium from the diluted metal ion solution by reverse osmosis through a membrane, whereby the sodium is removed from a retentate solution and added to a filtrate solution;  repeating the diluting and removing steps until the retentate solution is essentially sodium free;  drying the filtrate solution to recover the sodium;  vitrifying the sodium to produce sodium aluminum silicate glass;  removing metal ions from the retentate solution by running the retentate solution through an ion exchange medium, whereby the metal ions are retained by the ion exchange medium;  drying the ion exchange medium; and  vitrifying the ion exchange medium and the water insoluble metal oxide components into borosilicate glass. 31. The method of  claim 30  wherein the reverse osmosis membrane is a polymeric nanofiltration membrane. claim 30 32. The method of  claim 30  wherein the ion exchange medium is at least one zeolite. claim 30