Patent Number: 046541837
Section: description

DESCRIPTION OF THE PREFERRED EMBODIMENTS At the outset, it should be understood that the novel process of the invention involves the principle that H.sup.- ions can be produced with spin polarized protons. Utilizing selective laser neutralization of only one proton spin state of such a multi-ampere H.sup.- ion beam, while the beam is subjected to a magnetic field, results in an H.sup.- ion beam and an atomic hydrogen beam that has polarized protons. Those two beam states are then easily separated from one another by bending the H.sup.- ions with a curved magnetic field, as will be more full described below. Such an essentially one-step process has the obvious advantage that multi-ampere H.sup.- ion beams can be produced having either pulse or steady state. Furthermore, commercially available lasers can be used in the process to achieve essentially 100 percent efficiency in the neutralization of the H.sup.- beam. It should be understood that negative deuterium, D.sup.-, ions can be produced with spin polarized protons, using the principles of the invention, as they are disclosed herein with particular reference to H.sup.- ions. Accordingly, for fusion application requiring D.sup.- ions, the present invention is of particular value. FIGS. 1 and 2 illustrate alternative arrangements of various commercially available components that are used in practicing the preferred process of the invention. Considering first the arrangement shown in FIG. 1, it will be seen that a suitable negative ion source 1 is arranged to produce a multi-ampere beam of H.sup.- ions through an adjacent trimmer and focusing means 2. The ion beam is then introduced into a magnetic field, which is arranged in conventional manner to define a suitable magnetic field line 3, that is shown schematically by the curved arrows in FIG. 1. A commercial available laser 4, which will be more fully described below, is positioned to direct a beam of laser light 4A through an apperture 5A in convex mirror 5 and against the convex mirror 6. The beam of laser light 4A is oriented co-linear with the vertical section of the magnetic field line 3 to define a reflecting cavity, as shown in FIG. 1. As will be more fully discussed below, the magnetic field line 3 is bent in the area 3A, so that the magnetic field is effective to bend H.sup.- ions in an intense ion beam away from the H.sup.o atoms that are shown by the depicited arrow in FIG. 1 as being directed in a beam that maintains its alignment with the vertical portion of the magnetic field line 3. A suitable conventional particle accelerator 7 is positioned to receive the H.sup.- beam and to focus and accelerate it for any desired high energy research experimentation purpose. The arrangement of components used in practicing the process of the invention shown in FIG. 2 is quite similar to that illustrated in FIG. 1, thus the same call-out numbers will be used in FIG. 2, for designating essentially identical component parts. There is shown in FIG. 2 a suitably grounded negative ion source 1 that directs a multi-ampere beam 1A of H.sup.- ions through a focusing and trimming device 2 into a magnetic field line designated by the arrowed line 3. In this arrangement of the process of the invention, a laser 4 is positioned to direct a beam of laser light 4A in a direction that causes it to intersect the beam of each H.sup.- ions at an angle transverse thereto. Thus, the convex mirrors 5 and 6 are positioned to define a cavity that has its longitudinal axis essentially perpendicular to the vertical section of the magnetic field line 3. Otherwise, the process implemented with the component parts shown in FIG. 2 is arranged to operate in essentially the same manner as that shown in FIG. 1. Accordingly, H.sup.- ions are bent by the curved section 3A of the magnetic field line 3, thereby to direct the spin polarized H.sup.- ions in an intense beam toward the accelerator 7, as explained above with reference to FIG. 1. From the foregoing description of the process of the invention it should be apparent that a variety of suitable conventional components can be used for the negative ion source 1, the focusing and trimming means 2, the means for defining the magnetic field line 3, the laser 4 and associated laser cavity mirrors 5 and 6, as well as for the accelerator 7, as discussed above. However, particular examples of the types of lasers that are most useful in practicing the invention will be set forth more fully below. The magnetic field line 3 used in either arrangement shown in FIGS. 1 and 2, in practicing the preferred process of the invention, is formed as a uniform solenoidal magnetic field by use of any well known conventional array of suitable permanent or electro-magnets. When H.sup.- ions are provided in the multi-ampere beam of H.sup.- ions 1A that enters the magnetic field line 3 and is subjected to the uniform solenoidal magnetic field therein, one of the electrons in each H.sup.- ion will have its spin aligned in the direction of the magnetic field, while the other electron in each H.sup.- ion will have its spin aligned in the opposite direction. The proton spin in each of the H.sup.- ions will also be aligned either with, or opposite to, the magnetic field. For magnetic fields below 10.sup.8 Gauss, the H.sup.- ions have only one bound state, accordingly, there will be two populations of H.sup.- ions between which the sole difference is the orientation of their respective proton spins. The principle applied in practicing the method of the invention is to selectively neutralize only one population, or given spin polarized group, of H.sup.- ions, thereby forming a population of H.sup.- ions each of which has its proton spin down, and a second group or population of H.sup.o atoms having proton spin up. After such selective neutralization of the two groups of ions is achieved, the negative ions in one group are readily separated from the neutral ions in the other group by passing the polarized ion beam through the curvature of an appropriately arranged magnetic field, such as through the bent portion 3A of the magnetic field line 3 shown in FIGS. 1 and 2. The desired selective neutralization of ions works when there are proton spin dependent states that are preferentially formed, i.e., selective neutralization of H.sup.- ions will be the result of selective formation of H.sup.o atoms. Various possibilities could be explored in perfecting alternative arrangements of the method of the invention, for example, formation of H.sup.o atoms in the ground state, and formation of excited hydrogen atoms, in the n=2 level. A major advantage of operating near the threshold, i.e. with H.sup.o atoms in the ground state, is the more ready commercial availability of suitable lasers; however, for such atoms the photodetachment cross section is low. On the other hand, while the cross section for the formation of excited hydrogen atoms is 11 orders of magnitude higher, presently available commercial lasers that operate at that wavelength of 1135 .ANG. have short pulses. To further explain the preferred embodiment of the inventive process disclosed herein, the description of the process will now consider photodetachment of H.sup.- ions which result in ground state H.sup.o atoms, because more data exists for that case, including experimental clarification of it. As pointed out above, it will be seen that D.sup.- ions can also be as readily formed by practicing the invention as taught herein. There exists in the prior art extensive data about photodetachment of H.sup.- ions, but the effects of an external magnetic field on the photodetachment cross section has not been incorporated in that pre-existing data, as was done with respect to the photodetachment of S.sup.- in the presence of a magnetic field, per the explanation in the above referenced paper by Blumberg et al. Selective neutralization for achieving nuclear polarized beams has not been discussed anywhere, so far as the present inventor is aware. The main difference realized between achieving photodetachment in the presence of a magnetic field, versus achieving such photodetachment in the absence of a magnetic field, is the resultant quantization of the energy of the free electrons formed in a magnetic field into the well known Landau levels. When photodetachment is effected in a magnetic field, the electron dipole magnetic moment .mu. and the external magnetic field B combined to produce an energy shift from each Landau level of .mu..B. Accordingly, in each such shifted level, there can be either an electron spin up from one Landau level, or an electron spin down from a higher Landau level. Because the lowest energy level in the ground state hydrogen atom H.sup.o is produced with electron spin down and proton spin up, the lowest energy state of the detached H.sup.- ion is an H.sup.o ion with electron spin down, proton spin up, and a free electron spin up. Referring to FIG. 3(a,b), it will be seen that there is shown combined energy levels of a stripped H.sup.- ion in a magnetic field of a few hundred Gauss. These illustrated combined energy levels show the added energy levels of the free electron and the H.sup.o atom in the ground state. The depicted Landau levels refer to the energy levels of a free electron in a magnetic field, with the levels being quantized perpendicular to the field. As the term "degenerate levels" is used in FIGS. 3a and 3b, it means that the depicted levels are either truly degenerate, or are very closely spaced. As shown by the equations in FIGS. 3a and 3b, energy levels of a stripped electron and an H.sup.o atom is the total energy of a free electron, which is shown to equal the sum of the Landau levels, the Zeeman energy and the energy of the H.sup.o atom. FIG. 3a shows those energy levels for magnetic fields below the critical field, whereas those energy levels are shown in FIG. 3b for magnetic fields above the critical field. As shown by FIGS. 3a and 3b and the foregoing discussion, there exists the possibility of selectively detaching a spin up electron from H.sup.- ions with a proton spin up. In terms of frequency units, the energy difference between hydrogen atoms with proton spin down and those with proton spin up (with the electron spin down), is over 400 MHz, for magnetic fields of a few hundred Gauss up to fields of about 1000 Gauss. Thus, it can be seen that from a qualitative standpoint a resolution of about 100 MHz is sufficient to achieve such selective detachment. Presently available commercial lasers have much better resolutions than 100 MHz. Because the beam of laser light 4A that is used in the process of the invention, can be made arbitrarily narrow, the effective Doppler broadening of the laser beam, as seen by H.sup.- ions due to their thermal spread, becomes a limiting factor. In the absence of any acceleration, the Doppler width of a beam from a conventional H.sup.- ion source is much larger than any hyperfine separation or splitting attainable, e.g. at one electron volt the Doppler width is about 8.5.times.10.sup.9 Hz. However, if the beam is accelerated a phenomenom known as kinematic compression occurs. In other words, there is a reduction in Doppler width due to Doppler shift, which can be easily compensated for by adjusting the laser frequency. The factor by which Doppler width is reduced, R=1/2(kT/eU).sup.1/2 where T is the beam temperature and U is the accelerating potential. Accordingly, the reduced Doppler width becomes .DELTA.V=.DELTA.V (O) R. In the case of a typical currently available H.sup.- ion source, such as that available from the accelerator now in operation at Brookhaven National Laboratory, Upton, N.Y., which produces H.sup.- ions having a thermal spread of about 4 eV, extracted at 20 kV, .DELTA.V approximates 120 MHz. Such Doppler broadening is already acceptable for use in the process of the present invention, and it can readily be further reduced if desired. In practicing the preferred arrangement of the process of the invention, a Penning source whose thermal spread is about 1 eV is used. Thus, the selective neutralization effected in the process can be done by making the H.sup.- ion beam 1A from the negative ion source 1 shown in FIGS. 1 and 2 have energy of about 1 KeV. To select a suitable laser, for the laser 4 used in practicing the preferred arrangement of the process of the invention, as shown in FIGS. 1 and 2 it should be understood that the photon flux i.e., P (photon/cm.sup.2 /second) can be estimated from the equation: EQU p.perspectiveto..phi.Pt (1) Where, .phi. is the photodetachment cross-section and t is the intersection time. At one KeV for an intersection region of about 4 meters, t approximates 10.sup.-5 second. At the threshold, the photodetachment cross section when extrapolated from experimental and theoretical results is seen to be only 10.sup.-24 cm.sup.2. Solution of equation (1) yields P approximately 10.sup.29 photons/cm.sup.2 /sec. Assuming a beam cross section A approximating 0.1 cm.sup.2, the required Power for 0.75 eV photons is: EQU Power=APhv=10.sup.11 watts (2) In the foreseeable future there seems little hope of achieving such a Power level. The purpose of showing this calculation is to indicate that the primary problem in this case of a single photon absorption stems from low cross section near threshold while it peaks at about 1.5 eV photons. By contrast, the double photon absorbtion cross section, which requires the use of a 3.2 micron laser, peaks at threshold. Since the H.sup.- ion has a very high degree of dynamic polarizability, the cross section for double photon absorption must be high at threshold. An alternative approach is to use 10.93 eV photons (i.e. use a 1135 .ANG. laser), whose photo detachment products are a free electron and an H.sup.o atom excited in the n=2 level. At this photon energy, the photodetachment cross section has a very sharp resonance whose magnitude is 1.4.times.10.sup.-15 cm.sup.2. Using this value of cross section in equation (1), above, and a hv of 10.93 eV in equation (2) the Power needed becomes: EQU Power=12.5 watts (3) Lyman Alpha lasers are available having Power levels of 100 watts in pulses of 10's of nanoseconds. Utilization of such a laser for the laser 4 shown in FIG. 2 is the preferred arrangement for practicing the process of the invention. In alternative arrangements of the process of the invention, a commercial 32000 .ANG. laser can be used for the laser 4 shown in FIGS. 1 and 2, in a double photon absorption case having a large cross section, i.e. where the H.sup.o atom is left in the n=1 level. In a further alternative process, a 1135 .ANG. laser could be used for the laser 4 shown in FIG. 2, with the resulting H.sup.o atom in the n=2 level. With presently available commerical lasers, the latter approach would limit use of the process to short pulses in the 10's of nanoseconds. If free electron lasers become available in the future, the limits of the process would be greatly expanded. The operation of the preferred arrangements of the process of the invention, as illustrated for example in FIGS. 1 and 2, will now be briefly summarized to better explain the steps of the process. To achieve selective neutralization of H.sup.- ions in a magnetic field, thereby to produce an intense negative hydrogen ion beam with spin polarized protons, it will be understood from the foregoing description of the invention that a first step of the process, as it is illustrated in FIG. 4, is to provide a suitable multi-ampere beam 1A of H.sup.- ions from the negative ion source 1, which may comprise any suitable source, such as one of the available H.sup.- ion beam lines now in operation at Brookhaven National Laboratory. In the next step of the process a beam of laser light 4A is provided from a suitable laser 4. As explained above, such a suitable laser 4 is a 1135 .ANG. laser whose photodetachment products are a free electron and an H.sup.o atom excited in the n=2 level, in the most preferred arrangement of the process of the invention. In alternative arangements of the process, the beam of laser light 4A is produced by a 32,000 .ANG. laser, or in still other alternatives of the process, the laser 4 that is used is in the range of 1135 .ANG. to 32,000 .ANG.. Furthermore, if the laser light beam 4A is polarized other advantageous selection rules apply; thus, for 1135 .ANG. and 16,000 .ANG. polarized laser light the process works well without requiring a finely tuned laser. In the next step of the preferred process, a uniform solenoid magnetic field, as indicated by the magnetic field line 3 in FIGS. 1 and 2, is provided around a portion of the beam of H.sup.- ions 1A, to effectively spin polarize the H.sup.- ions in that beam and thereby to produce a first group of ions having their proton spin aligned with the magnetic field designated by magnetic field line 3, and to produce a second group of ions with their proton spin opposite to the magnetic field. Then, the beam of laser light 4A is directed through the spin polarized H.sup.- ions, either co-axially therewith as shown in FIG. 1, or transverse thereto as shown in FIG. 2, in order to selectively neutralize a majority of the ions in one of the above mentioned groups of ions, without neutralizing the ions in the other group. Finally, one of the groups of ions is separated from the other group of ions and then directed in an intense H.sup.- ion beam toward a predetermined objective, such as the accelerator 7 shown in FIGS. 1 and 2. Of course, the ion beam may be further directed by the accelerator 7 to a desired end use. In the most preferred process of the invention, as mentioned above, the arrangement of components shown in FIG. 2 is utilized, and the magnetic field designated by the magnetic field line 3 is below 10.sup.8 Gauss. Most preferably, that magnetic field is at least 200 Gauss and is sufficiently strong to result in Zeeman hyperfine splitting of the H.sup.- ion beam into two energy states that are solely dependent on the polarization of the respective nuclei of the H.sup.- ion beam. Also, in the most preferred arrangement of the process of the invention, the selected negative ion source 1 is operable to produce an intense beam of H.sup.- ions 1A that is a multi-ampere beam. In such an arrangement of the process of the invention, the first group of H.sup.- ions is preferably neutralized, while the second group of H.sup.- ions is separated from that first group of ions and formed into an intense beam of H.sup.- ions that is then directed into the accelerator 7. In that operation of the invention, the second group of ions is separated from the first group of ions by curving the longitudinal axis of the magnetic field line 3, as shown by the bend 3A therein, in order to bend the intense beam of H.sup.- ions in a path that diverts the second group of ions away from the neutralized ions, which are shown by the symbol H.sup.o and the associated arrow in FIG. 2, so that the H.sup.- ions, as shown by the symbols adjacent the accelerator 7 in FIG. 2, are directed into that accelerator. From the foregoing description it will be recognized that further alternatives and modifications of the invention may be practiced without departing from its true scope. Accordingly, it is my intention to include all such alternatives and modifications within the limits and spirit of the following claims.