Patent Number: 059603682
Section: claims

1. A process for preparing radioactive, hazardous, or mixed waste for storage, comprising: (A) contacting radioactive, hazardous, or mixed waste starting material comprising at least one organic carbon-containing compound and at least one radioactive or hazardous waste component with nitric acid and phosphoric acid for a period of time sufficient to oxidize at least a portion of said organic carbon-containing compound to gaseous products, thereby producing a residual concentrated waste product comprising substantially all of said radioactive or hazardous metal waste components; and  (B) immobilizing said residual concentrated waste product in a solid phosphorus-containing ceramic or glass form.  (A) contacting radioactive, hazardous, or mixed waste starting material comprising at least one organic carbon-containing compound and at least one radioactive or hazardous waste component with nitric acid and phosphoric acid for a period of time sufficient to oxidize at least a portion of said organic carbon-containing compound to gaseous products, thereby producing a residual concentrated waste product comprising substantially all of said radioactive or hazardous metal waste components; and  (B) immobilizing said residual concentrated waste product in a solid form, wherein said solid form comprises a glass or ceramic matrix selected from the group consisting of iron phosphate glass, ferric phosphate ceramic, and magnesium phosphate ceramic. 2. The process according to claim 1, wherein said radioactive, hazardous, or mixed waste starting material comprises low level radioactive waste or low level mixed waste. 3. The process according to claim 2, wherein said low level radioactive waste or low level mixed waste comprises material selected from the group consisting of job control waste, ion exchange resins, and reactor coolant system cleaning streams. 4. The process according to claim 3, wherein said organic carbon-containing compound is selected from the group consisting of neoprene, cellulose, EDTA, tributylphosphate, polyethylene, polypropylene, polyvinylchloride, polystyrene, oils, resins, and mixtures thereof. 5. The process according to claim 1, wherein said radioactive or hazardous waste component contains an element selected from the group consisting of U, Th, Cs, Sr, Am, Co, Tc, Hg, Pu, Ba, As, Cd, Cr, Pb, Se, Ag, Zn, and Ni. 6. The process according to claim 5, wherein said radioactive waste component is Pu. 7. The process according to claim 1, wherein said nitric acid and said phosphoric acid are present in molar quantities of about 0.03 to about 2.0 moles of HNO.sub.3 and of about 12.8 to 14.77 moles of H.sub.3 PO.sub.4. 8. The process according to claim 1, wherein oxygen is provided by introducing air into a mixture of said radioactive, hazardous, or mixed waste starting material, said nitric acid and said phosphoric acid. 9. The process according to claim 1, wherein said contacting temperature is in the range of about 140.degree. C. to about 210.degree. C. 10. The process according to claim 1, wherein said organic carbon-containing compound is selected from the group consisting of polyethylene, polypropylene, and polyvinylchloride, said contacting temperature is in the range of about 185.degree. C. to about 190.degree. C., and wherein said contacting is carried out at a pressure in the range of about 10 to about 15 psig. 11. The process according to claim 1, wherein said gaseous products comprise carbon oxides, water, and nitrogen oxides. 12. The process according to claim 11, further comprising oxidizing said nitrogen oxides to form nitric acid and recycling said nitric acid to said contacting step. 13. The process according to claim 11, wherein said carbon oxides comprise carbon monoxide and carbon dioxide, and wherein said carbon monoxide formation is suppressed by the presence of a catalytic amount of a Pd.sup.+2 containing catalyst. 14. The process according to claim 1, wherein said immobilizing said residual concentrated waste product in a solid phosphorus-containing ceramic or glass form comprises preparing an iron-phosphate waste glass comprising said radioactive or hazardous waste component stabilized in a matrix of iron-phosphate glass. 15. The process according to claim 14, wherein preparing said iron-phosphate waste glass comprises mixing said residual concentrated waste product, iron oxide, and a glass former, and vitrifying said mixture at a temperature between about 1050.degree. C. and about 1300.degree. C. 16. The process according to claim 1, wherein said immobilizing said residual concentrated waste product in a solid phosphorus-containing ceramic or glass form comprises preparing a magnesium phosphate ceramic from said residual concentrated waste product. 17. The process according to claim 16, wherein said preparing said magnesium phosphate ceramic comprises mixing said residual concentrated waste stream with magnesium oxide and boric acid to form a slurry, and allowing the slurry to set. 18. The process according to claim 1, wherein said immobilizing said residual concentrated waste product in a solid phosphorus-containing ceramic or glass form comprises preparing a ferric phosphate ceramic from said residual concentrated waste product. 19. The process according to claim 1, wherein substantially all of said organic carbon-containing compound is oxidized into gaseous components. 20. A process for preparing radioactive, hazardous, or mixed waste for storage, comprising: