Patent Number: 042750458
Section: claims

1. A method of extraction, trapping and storage of radioactive iodine contained in irradiated nuclear fuels, comprising the steps of: dissolving the fuels in a nitric acid medium;  passing the vapors resulting from this dissolution and consisting essentially of water, nitrogen oxides and elemental iodine into a condenser;  passing the vapors coming out of the condenser into a first absorption column for the absorption of the nitrous vapors, in which column is formed recombined nitric acid containing elemental iodine and nitrous ions;  separating out the iodine contained in the recombined acid from the acid in the presence of NO.sub.2.sup.- ions in the recombined acid, and  recovering the iodine in a storable form.  dissolving the fuels in a nitric acid medium;  passing into a condenser the vapors resulting from this dissolution and consisting essentially of water, nitrogen oxides and iodine;  passing the vapors issuing from the condenser into a first column for the absorption of the nitrous vapors, in which column is formed recombined nitric acid containing nitrous ions and iodine;  passing the recombined acid into a desorption column in counterflow to a carrier gas which is thereby loaded with iodine;  circulating said gas in a second absorption column in counterflow to an alkaline solution in which a reducing agent is added in said second absorption column, and  providing to the alkaline solution which leaves the second absorption column an addition of a metal salt, selected from the group consisting of soluble lead salts and soluble copper salts, which precipitates the iodine in the form of the corresponding iodide. 2. A method according to claim 1, wherein separation of the iodine contained in the recombined acid is carried out by passing the recombined acid solution into a desorption column in counterflow to a carrier gas which is thereby loaded with iodine and the iodine thus trapped in said gas is then recovered in a second absorption column. 3. A method according to claim 2, wherein the iodine is extracted from the carrier gas in said second absorption column by circulating said gas in counterflow to an alkaline solution to which is added a reducing agent. 4. A method according to claim 10, wherein the alkaline solution which leaves the second absorption column receives an addition of a lead salt which precipitates the iodine in the form of lead iodide. 5. A method according to claim 10, wherein the alkaline solution which leaves the second absorption column receives an addition of a copper salt which precipitates the iodine in the form of copper iodide. 6. A method according to claim 2, wherein the iodine-loaded carrier gas is passed through a second absorption column containing a solid adsorbent exchanged with silver and chosen from the zeolites, the molecular sieves, and the catalytic supports. 7. A method acording to claim 1, wherein in order to separate the iodine contained in the recombined acid, the recombined acid solution which leaves the first absorption column is passed into a distitllation unit and the iodine is then distilled off in the presence of nitrous ions contained in the solution and is thereafter separated out by cooling and wherein the iodine crystals formed at the time of cooling are separated from the distillate for the purpose of long-term storage. 8. A method according to claim 7, wherein the iodine crystals are dissolved in an alkaline solution to which is added a reducing agent in order to transfer this solution to the effluent treatment station. 9. A method according to claim 1, wherein, in order to separate the iodine contained in the recombined acid, the recombined acid solution which leaves the first absorption column is passed into a distillation unit and the iodine is then distilled off in the presence of nitrous ions contained in the solution and is thereafter separated-out by cooling, and wherein the iodine crystals formed by the cooling step are dissolved in an alkaline solution and wherein said alkaline solution containing the dissolved iodine then receives an addition of a lead salt so as to precipitate the lead iodide, which is then conditioned for long-term storage. 10. A method of extraction, trapping and storage of radioactive iodine contained in the irradiated nuclear fuels, comprising the steps of: