Patent Number: 
Section: claims

1. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a coolant flow passage in a nuclear reactor, comprising the steps of:forming a base dielectric layer by exposing the conductive surface to a first organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous base dielectric layer on the conductive surface, the base dielectric layer consisting essentially of at least one tantalum (Ta) compound; andforming an outer dielectric layer by exposing the base dielectric layer to a second organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous outer dielectric layer on the base dielectric layer, the outer dielectric layer consisting essentially of at least one titanium (Ti) compound. 2. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a coolant flow passage in a nuclear reactor according to claim 1, wherein:forming the base dielectric layer utilizes a chemical vapor deposition (CVD) process with the conductive surface being maintained at a first deposition temperature of between about 400° C. and about 500° C. and a first deposition pressure of no more than about 20 mTorr; andforming the outer dielectric layer utilizes a CVD process with the base dielectric layer being maintained at a second deposition temperature of between about 400° C. and about 500° C. and a second deposition pressure of no more than about 20 mTorr. 3. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a coolant flow passage in a nuclear reactor according to claim 1, wherein:forming the base dielectric layer utilizes deposition process with the conductive surface being maintained at a first deposition temperature of between about 400° C. and about 500° C. and a first deposition pressure of no more than about 20 mTorr; andforming the outer dielectric layer utilizes a CVD process with the base dielectric layer being maintained at a second deposition temperature of between about 400° C. and about 500° C. and a second deposition pressure of no more than about 20 mTorr. 4. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a coolant flow passage in a nuclear reactor according to claim 1, wherein:the base dielectric layer is formed using a method selected from a group consisting of atomic layer deposition (ALD), chemical vapor deposition (CVD), physical vapor deposition (PVD), plasma enhanced physical vapor deposition (PEPVD), sputtering, plasma spray coating (APS, VPS and LPPS) and high velocity oxy-fuel (HVOF) processes; andthe outer dielectric layer is formed using a method selected from a group consisting of atomic layer deposition (ALD), chemical vapor deposition (CVD), physical vapor deposition (PVD), plasma enhanced physical vapor deposition (PEPVD), sputtering, electric arc spraying (EAS), plasma spray coating (APS, VPS and LPPS) and high velocity oxy-fuel (HVOF) processes. 5. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a coolant flow passage in a nuclear reactor according to claim 2, wherein:the base dielectric layer consists essentially of Ta2O5 and is formed to a first layer thickness Tb of between about 0.1 and about 2 μm; andthe outer dielectric layer consists essentially of TiO2 and is formed to a second layer thickness To of between about 0.5 μm and about 3 μm. 6. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a flow passage within a Boiling Water Reactor (BWR), comprising the steps of:forming a base dielectric layer by exposing the conductive surface to a first organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous base dielectric layer on the conductive surface, the base dielectric layer consisting essentially of at least one tantalum (Ta) compound; andforming an outer dielectric layer by exposing the base dielectric layer to a second organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous outer dielectric layer on the base dielectric layer, the outer dielectric layer consisting essentially of at least one titanium (Ti) compound. 7. A method for reducing deposition of charged particulates on a conductive surface defining a wetted portion of a flow passage, comprising the steps of:forming a base dielectric layer by exposing the conductive surface to a first organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous base dielectric layer on the conductive surface, the base dielectric layer consisting essentially of at least one tantalum (Ta) compound; andforming an outer dielectric layer by exposing the base dielectric layer to a second organometallic precursor compound under conditions sufficient to decompose the precursor compound and form a substantially continuous outer dielectric layer on the base dielectric layer, the outer dielectric layer consisting essentially of at least one titanium (Ti) compound, andwherein the first organometallic precursor compound includes a first metal; and the second organometallic precursor compound includes a second metal, wherein the first metal and the second metal are different metals. 8. The method for reducing deposition of charged particulates on a conductive surface according to claim 7, wherein:the base dielectric layer consists essentially of a first refractory metal oxide and has a thickness of between about 0.1 and about 2 μm; andthe outer dielectric layer consists essentially of a second refractory metal oxide and has a thickness of between about 0.5 μm and about 3 μm, wherein the first and second refractory metals are different. 9. The method for reducing deposition of charged particulates on a conductive surface according to claim 8, wherein:the base dielectric layer consists essentially of Ta2O5 and has a thickness of between about 0.1 and about 2 μm; andthe outer dielectric layer consists essentially of TiO2 and has a thickness of between about 0.5 μm and about 3 μm.