Patent Number: 052924564
Section: claims

1. A method for decontamination and reclamation of materials contaminated with radionuclides, metals, or mixtures thereof comprising: (i) contacting the material with an organic complexing agent comprising citric acid, a citrate salt or mixture thereof in an aqueous solution to remove said radionuclides, metals or mixtures thereof from the material and yield a radionuclide and/or metal-citrate complex-containing solution;  (ii) treating the radionuclide and/or metal-citrate complex-containing solution with a bacterial culture containing Pseudomonas fluorescens ATCC No. 55241 wherein a nutrient carbon source for the bacteria consists substantially of citrate in the form of the radionuclide and/or metal-citrate complexes, said treatment resulting in the precipitation or incorporation into biomass of the radionuclides and/or metals; and  (iii) if the material being decontaminated and reclamated contains the radionuclide uranium, exposing the uranium citrate complex-containing solution to light resulting in the breakdown of the complex and precipitation of uranium as a polymer; so that the radionuclides and/or metals are recovered in a concentrated form. 2. The method of claim 1 wherein the material is selected from a group consisting of soil, sediment, sludge and aquatic environments. 3. The method of claim 1 wherein the step (ii) treating is at a temperature of from about 18.degree. C. to about 32.degree. C., at an initial pH of from about 4 to about 8. 4. The method of claim 1 wherein citric acid, a citrate salt or mixture thereof is added in a concentration in excess of the concentration of the radionuclides and/or metals in the contaminated material. 5. The method of claim 1 wherein the concentration of the citric acid, citrate salt or mixture thereof is from about 0.01M to about 1.0M. 6. The method of claim 1 further comprising adding a supplemental carbon source in step (ii). 7. The method of claim 6 wherein the supplemental carbon source is glucose. 8. The method of claim 1 wherein the solution in step (iii) has an initial pH of from about 2 to about 8, and is exposed to daylight for a time of at least 12 hours. 9. The method of claim 1 further comprising adding supplemental photoreactive compound to the solution of step (iii). 10. The method of claim 9 wherein the photoreactive compound is ferric iron. 11. The method of claim 1 wherein the solution in step (iii) is exposed to sunlight. 12. The method of claim 1 wherein step (ii) is carried out after step (iii). 13. The method of claim 1 wherein step (ii) is carried out concurrently with step (iii).