Patent Number: 046817050
Section: claims

1. A method of decontaminating mixtures of radioactively contaminated water and radioactively contaminated water-immiscible organic liquids to produce a decontaminated organic liquid which can be disposed of in a conventional manner, said method comprising: (a) separating a discontinuous mixture of radioactively contaminated water and a radioactively contaminated water-immiscible organic liquid in which the organic liquid comprises a continuous phase into a waste water fraction carrying metal radionuclides and an organic liquid fraction carrying metal radionuclides;  (b) decontaminating said waste water fraction;  (c) mixing said radioactively contaminated organic liquid fraction with a sufficient amount of an aqueous solution of a water-soluble chelating agent until water-soluble metal-chelate complexes form between said chelating agent and substantially all of said metal radionuclides carried by said organic liquid fraction;  (d) separating said aqueous solution from said organic liquid fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said organic liquid fraction, making said organic liquid substantially free of radionuclides and safely disposable by conventional methods; and  (e) decontaminating said aqueous solution.  heating said mixture of radioactively contaminated water and radioactively contaminated water-immiscible organic liquid, thereby enhancing said separation of said mixture into said radioactively contaminated water fraction and said radioactively contaminated organic liquid fraction.  (a) separating a discontinuous mixture of radioactively contaminated water and a radioactively contaminated water-immiscible organic liquid in which the organic liquid comprises a continuous phase into a waste water fraction and an organic liquid fraction carrying metal radionuclides;  (b) mixing said radioactively contaminated organic liquid fraction with a sufficient amount of an aqueous solution of a water-soluble chelating agent until water-soluble metal-chelate complexes form between said chelating agent and substantially all of said metal radionuclides carried by said organic liquid; and  (c) separating said aqueous solution from said organic liquid fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said organic liquid fraction, making said organic liquid substantially free of radionuclides and safely disposable by conventional methods.  (a) heating an emulsion of radioactively contaminated water and radioactively contaminated lubricating oil to a temperature of about 180.degree. F.;  (b) centrifugally separating said heated emulsion into a radioactively contaminated waste water fraction carrying metal radionuclides and a radioactively contaminated oil fraction carrying metal radionuclides;  (c) decontaminating and disposing of said waste water fraction;  (d) filtering said radioactively contaminated oil fraction thereby removing any fine particulate suspended material therefrom;  (e) centrifugally mixing and heating said radioactively contaminated oil fraction with an aqueous solution of ethylenediamine tetraacetic acid in an amount and for a time period sufficient for water-soluble metal-chelate complexes to form between said ethylenediamine tetraacetic acid and substantially all of said metal radionuclides carried by said oil fraction while maintaining a pH of about 10.5;  (f) separating said aqueous solution from said oil fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said oil fraction making said oil fraction safely disposable by conventional methods;  (g) decontaminating said water fraction thereby removing substantially all of the radionuclides therefrom; and  (h) disposing of said oil fraction in a conventional manner.  (a) separating a mixture of radioactively contaminated particulate material and an emulsion of radioactively contaminated water and a radioactively contaminated water immiscible organic liquid into an emulsion portion and a particulate portion;  (b) disposing of said particulate portion;  (c) separating said emulsion into a radioactively contaminated waste water fraction carrying metal radionuclides and a radioactively contaminated organic liquid fraction carrying metal radionuclides;  (d) mixing said radioactively contaminated organic liquid fraction with an amount of an aqueous solution of a water-soluble chelating agent in a manner and for a time period sufficient for water-soluble metal-chelate complexes to form between said chelating agent and substantially all of said metal radionuclides carried by said organic liquid;  (e) separating said aqueous solution from said organic liquid fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said organic liquid;  (f) decontaminating said water fraction thereby removing substantially all of the radionuclides therefrom; and  (g) disposing of said oil fraction in a conventional manner.  (a) separating a mixture of radioactively contaminated particulate material and an emulsion of radioactively contaminated water and radioactively contaminated lubricating oil into an emulsion portion and a particulate portion;  (b) disposing of said particulate portion;  (c) heating said emulsion of radioactively contaminated water and radioactively contaminated lubricating oil to a temperature of about 180.degree. F.;  (d) centrifugally separating said heated emulsion into a radioactively contaminated waste water fraction carrying metal radionuclides and a radioactively contaminated oil fraction carrying metal radionuclides;  (e) filtering said radioactively contaminated oil fraction thereby removing any fine particulate suspended material therefrom;  (f) centrifugally mixing and heating said radioactively contaminated oil fraction with a sufficient amount of an aqueous solution of ethylenediamine tetraacetic acid for a time period sufficient for water-soluble metal-chelate complexes to form between said ethylenediamine tetraacetic acid and substantially all of said metal radionuclides carried by said oil fraction while maintaining a pH of about 10.5;  (g) separating said aqueous solution from said oil fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said oil fraction;  (h) filtering said separated oil fraction; and  (i) decontaminating said aqueous solution thereby removing substantially all of the radionuclides therefrom; and  (j) disposing of said oil fraction in a conventional manner.  (a) separating a discontinuous mixture of radioactively contaminated water and a radioactively contaminated water-immiscible organic liquid in which the organic liquid comprises a continuous phase into a waste water fraction carrying metal radionuclides and an organic liquid fraction carrying metal radionuclides;  (b) decontaminating said waste water fraction;  (c) mixing said radioactively contaminated organic liquid fraction with a sufficient amount of an aqueous solution of a water-soluble chelating agent and an inorganic precipitating agent in a manner and for a time period sufficient for water-soluble metal-chelate complexes to form between said chelating agent and a portion of said metal radionuclides carried by said organic liquid fraction and for insoluble metal-salt precipitates to form between said inorganic precipitating agent and the remainder of said radionuclides carried by said organic liquid fraction;  (d) separating said aqueous solution and said metal-salt precipitate from said organic liquid fraction thereby removing said water-soluble metal-chelate complexes containing substantially all of the radionuclides from said organic liquid fraction, making said organic liquid substantially free of radionuclides and safely disposable by conventional methods;  (e) separating said metal-salt precipitates from said aqueous solution;  (f) decontaminating said aqueous solution; and  (g) disposing of said organic liquid fraction in a conventional manner. 2. A method according to claim 1 in which said water-immiscible organic liquid comprises waste lubricating oil from a nuclear powered electric generating plant. 3. A method according to claim 1 further comprising: 4. A method according to claim 1 wherein said separating of said mixture into said waste water and organic liquid fractions comprises centrifugal separation. 5. A method according to claim 1 further comprising the step of filtering said radioactively contaminated organic liquid fraction after said separation from said mixture thereby removing any fine particulate suspended matter therefrom. 6. A method according to claim 1 wherein said mixing of said radioactively contaminated organic liquid fraction and said aqueous solution of a water soluble chelating agent comprises centrifugal mixing. 7. A method according to claim 1 wherein said manner of mixing includes heating the mixture of said organic liquid and said aqueous solution. 8. A method according to claim 1 further comprising maintaining the mixture of said radioactively contaminated liquid fraction and said aqueous solution of a water soluble chelating agent at a pH which enhances the chelation of the chelating agent with the radionuclides to be removed. 9. A method according to claim 1 further comprising maintaining the mixture of said radioactively contaminated organic liquid fraction and said aqueous solution of a water soluble chelating agent at a pH greater than 7. 10. A method according to claim 1 wherein said water soluble chelating agent has a greater solubility in water than in the water-immiscible organic liquid. 11. A method according to claim 1 wherein said separation of said aqueous solution from said organic liquid fraction comprises centrifugal separation. 12. A method according to claim 1 further comprising filtration of said separated organic liquid fraction. 13. A method according to claim 1 in which said chelating agent comprises ethylenediamine tetraacetic acid. 14. A method according to claim 1 further comprising disposing of said organic liquid in a conventional manner following said separation from said water-soluble metal-chelate complexes. 15. A method according to claim 14 in which said disposal comprises combustion of said organic liquid. 16. A method according to claim 1 wherein the mixture of water and radioactively contaminated water-immiscible organic liquid comprises an emulsion. 17. A method according to claim 1 wherein the water soluble chelating agent is selected from among the group consisting of: nitrilotriacetic acid, alpha-nitroso beta-naphthol, 1,2-cyclohexane dionedioxime, disodium dihydrogen EDTA, ethylene diaminetetraacetate dihydrate, tetrasodiumethylenediamine tetraacetate, N-hydroxethylethylene-diaminetriacetic acid, and 4-(2-pyridylazo)-resorcinol. 18. A method of decontaminating the organic liquid portions of mixtures of water and radioactively contaminated water-immiscible organic liquids to produce a decontaminated organic liquid which can be disposed of in a conventional manner, said method comprising: 19. A method of decontaiminating emulsions of radioactively contaminated water and radioactively contaminated lubricating oil to produce decontaminated lubricating oil which can be disposed of in a conventional manner, said method comprising: 20. A method according to claim 19 further comprising combustion of said separated filtered decontaminated oil. 21. A method according to claim 20 in which said lubricating oil comprises radioactively contaminated lubricating oil formed during the normal operations of a nuclear powered electric generating plant. 22. A method according to claim 21 in which said amount of aqueous solution of ethylenediamine tetraacetic acid comprises a 0.125 molar solution added to form a mixture in which said aqueous solution is present 8% by weight in said lubricating oil. 23. A method of decontaminating mixtures of radioactively contaminated particulate material and emulsions of radioactively contaminated water and radioactively contaminated water-immiscible organic liquids, thereby producing a decontaminated organic liquid which can be disposed of in a conventional manner, said method comprising: 24. A method of decontaminating mixtures of radioactively contaminated particulate material and emulsions of radioactively contaminated water and radioactively contaminated lubricating oil to produce decontaminated lubricating oil which can be disposed of in a conventional manner, said method comprising: 25. A method of decontaminating mixtures of radioactively contaminated water and radioactively contaminated water-immiscible organic liquids to produce a decontaminated organic liquid which can be disposed of in a conventional manner, said method comprising: 26. A method according to claim 25 wherein the inorganic precipitating agent is selected from among the group consisting of: NH.sub.4 OH, H.sub.2 S, (NH.sub.4).sub.2 S, (NH.sub.4).sub.2 HPO.sub.4, H.sub.2 SO.sub.4, H.sub.2 PtCl.sub.6, H.sub.2 C.sub.2 O.sub.4, (NH.sub.4).sub.2 MnO.sub.4, HCLAgNO.sub.3, (NH.sub.4).sub.2 CO.sub.3, NH.sub.4 SCN, NaHCO.sub.3, HNO.sub.3, H.sub.5 IO.sub.6, NaCl, Pb(NO.sub.3).sub.2, BaCl.sub.2, MgCl.sub.2, and NH.sub.4 Cl.