Patent Number: 047724315
Section: claims

1. A process for the immobilization of nuclear waste in a borosilicate glass, wherein: the following are mixed simulataneously:  with vigorous stirring, mixing taking place at between about 20.degree. and 80.degree. C., in proportions corresponding to the desired composition of the glass, the said mixture having an acid pH; and  the said mixture is dried, calcined at between 300.degree. and 500.degree. C. and then melted.  A. simultaneously mixing glass-forming materials in an aqueous system, the ingredients comprising:  B. drying the resultant solidified material mixture;  C. calcining the dried mixture of Step B at a temperature of about 300.degree. to 500.degree. C.;  D. melting the calcined product of Step C to form a melted glass; and  E. solidifying the melted glass to form a borosilicate glass that encapsulates the nuclear waste material. 2. The process as claimed in claim 1, wherein mixing is effected with a stirrer which rotates at more than about 500 rpm. 3. The process as claimed in claim 1 in which the mixing is at about 65.degree. to 70.degree. C. 4. The process as claimed in claim 1, wherein the gel precursor is a sol. 5. The process as claimed in claim 1, wherein the gel precursor is alkaline colloidal silica. 6. The process as claimed in claim 1, wherein the gel precursor is acid colloidal silica. 7. The process as claimed in claim 1, wherein the boron compound is ammonium tetraborate. 8. The process as claimed in claim 1, wherein the boron compound is boric acid. 9. A process for immobilizing nuclear waste in the form of a liquid aqueous solution as a waste material, the process comprising the steps of: 10. A process as defined in claim 9 in which other constituents of the final glass are added in Step A, the adding being simultaneous with the glass forming materials, the other constituents comprising a solution of an aluminum compound that forms A1203 in the final glass. 11. A process as defined in claim 10 in which the other constituents comprises solutions of glass-forming compounds that form Na.sub.2 O, ZnO, C.sub.a O and ZrO.sub.2 in the final glass. 12. A process as defined in claim 9 in which Step A is performed at about 65.degree. to 70.degree. C. 13. A process as defined in claim 12 in which the aqueous system of Step A has a pH of about 2.5 to 3.5. 14. A process as defined in claim 9 in which the drying Step B is about 100.degree. to 105.degree. C. 15. A process as defined in claim 9 in which Step C is conducted at about 350.degree. to 450.degree. C. 16. A process as defined in claim 9 in which the silica gel precursor is alkaline colloidal silical that provides a gel to provide the solidified mixture of Step A. 17. A process as defined in claim 9 in which the aqueous solution of 1 and 2 in Step A are concentrated in which the solutions are at least about 75% of their saturation concentrations.