Patent Document

CROSS-REFERENCE TO RELATED APPLICATION(S) 
       [0001]    This application claims priority to Taiwan Patent Application No. 096100946 filed on 10 Jan. 2007, the disclosure of which is incorporated herein by reference in its entirety. 
       BACKGROUND 
       [0002]    1. Field of the Invention 
         [0003]    The present invention relates to a method for forming a gate structure with a local pulled-back conductive layer. In particular, a contact window that avoids the disadvantage of the prior art, such as short circuiting between the bit line contact and gate conductor (CBGC short), broken bit line contacts (CB open) and/or short circuiting of the bit line contacts (CBCB short), is formed. 
         [0004]    2. Descriptions of the Related Art 
         [0005]    A metal oxide semiconductor (MOS) device is normally composed of a metal layer, a silicon oxide layer, and a substrate. Because the adhesion between the metal and oxide is poor, a polysilicon material is often used as a substitution for metal when forming the conductive layer of an MOS device. 
         [0006]    It is known that the resistance of a polysilicon material is higher than that of metal. Although impurities are doped onto the polysilicon layer for reducing resistance, the conductivity is still not high enough for good conductivity in a gate structure. Typically, a metal silicide layer, such as a tungsten silicide (WSi) layer, is added onto the polysilicon layer to improve the conductivity of the gate structure. 
         [0007]    A contact window is formed alongside of the gate structure to form electrical connects between the metal layer of the bit line and substrate. A conventional method for forming a contact window will be described as follows. First, in reference to  FIG. 1A , a substrate  102  is provided. A gate structure  103  is formed on the substrate  102 , wherein the gate structure  103  comprises a first conductive layer  104 , a second conductive layer  106 , an insulation layer  108  and spacers  110 . Then, a dielectric layer  112  is formed to cover the entire substrate  102  and gate structure  103 . The first conductive layer  104  can be a polysilicon layer or an amorphous silicon layer, while the second conductive layer  106  can be a metal silicide layer. 
         [0008]    In  FIG. 1B , a selected portion of the dielectric layer  112  is removed by performing lithographic and etching processes until the surface of the substrate  102  has been exposed. As a result, a contact window  114  is formed. In  FIG. 1C , a metal layer  116  is deposited over the dielectric layer  112 , and the side walls and bottom of the contact window  114  to form a metal contact. 
         [0009]    If the insulation layer  108  and the spacer  110  were overly etched due to improper control, the deposition of the metal layer would expose the second conductive layer  106  under the insulation layer  108 . In addition, the second conductive layer  106  may be exposed if the second conductive layer  106  pierces the spacer  110  due to thermal strain caused by a subsequent thermal process. Thus, in reference to  FIG. 1D , the exposed second conductive layer  106  connects to the metal layer  116  and forms an electrical connection  118  (as shown in the dotted line area) thereto, and thus, causes a short circuit between the bit line contact and gate conductor (CBGC short). 
         [0010]    To solve the above-mentioned problem of an exposed second conductive layer  106 , a method is disclosed in U.S. Pat. No. 5,989,987. In  FIG. 2A , a substrate  202  is provided where a gate structure  203  is formed on the substrate  202 . The gate structure  203  comprises a first conductive layer  204 , a second conductive layer  206 , and an insulation layer  208 . The first conductive layer  204  can be a polysilicon layer or an amorphous silicon layer. Next, a pull back process is conducted by using an etchant to etch the second conductive layer  206 , wherein the etchant is a mixture of NH 4 OH, H 2 O 2  and H 2 O. 
         [0011]    In  FIG. 2B , spacers  210  are formed on the sides of the gate structure  203 . Then,  FIG. 2C  shows a dielectric layer  212  that covers the entire substrate  202  and gate structure  203 . A selected portion of the dielectric layer  212  is removed by performing lithographic process and etching processes to expose a portion of the surface of the substrate  202 . As a result, a contact window  214  is formed. 
         [0012]    In  FIG. 2D , a metal layer  216  is formed to cover the dielectric layer  212  and the side walls and bottom of the contact window  214 . In this way, a metal contact is formed. 
         [0013]    In the method disclosed in U.S. Pat. No. 5,989,987, the second conductive layer  206  of the gate structure is etched globally. In other words, portions of the second conductive layer  206  that do not need to be removed for forming the contact window are also etched away. This etching is disadvantageous in several ways. First, because the second conductive layer  206  is oxidized and has an increased thickness during rapid thermal oxidation, the reduced space in the contact window can cause the bit line contact to break. Second, a short circuit between the bit line contacts may occur. This occurs when the space between the adjacent gate structures, not used for forming the contact window, are increased by the global etching. While the space is filled with a dielectric material, cavities may be formed in the dielectric material. Such cavities may be filled with conductive material when the conductive material is deposited into the contact windows for forming contact plugs. As a result, short circuiting may occur. Third, the resistance of the gate conductive is increased because the cross-sectional area of the conductive layer of the gate structure is reduced. Fourth, because the contact area between the first conductive layer  204  and the second conductive layer  206  is reduced, peeling will be induced in subsequent processes. 
         [0014]    TW 544787 describes another method. First,  FIG. 3A  illustrates a substrate  302  in which the gate structures  303  are formed on the substrate  302 . Each gate structure  303  comprises a first conductive layer  304 , a second conductive layer  306  and an insulation layer  308 , wherein the first conductive layer  304  can be a polysilicon layer or an amorphous silicon layer. A photoresist layer  309  is deposited over the substrate  302  and gate structures  303 . 
         [0015]    Next,  FIG. 3B  illustrates a bit line contact node mask or a bit line contact mask used to perform a lithographic and etching process to remove a portion of the photoresist layer  309  between the adjacent gate structures  303 . As a result, an opening is formed. Then, an etching process is applied using an etchant to pull back the exposed second conductive layer  306 . 
         [0016]    In  FIG. 3C , the photoresist layer  309  is removed and spacers  310  are formed on the sides of the gate structures  303 . Then, in  FIG. 3D , a dielectric layer  312  is formed to cover the substrate  302  and gate structures  303 . Lithographic and etching processes are performed to remove a selected portion of the dielectric layer  312  to expose the substrate  302 . In this way, a contact window  314  between adjacent gate structures  303  is formed. 
         [0017]    Lastly, in reference to  FIG. 3E , a metal layer  316  is formed to cover the dielectric layer  312  and the side walls and bottom of the contact window  314  to provide a metal contact. 
         [0018]    As described above, the method of TW 544787 comprises a step of locally etching the second conductive layer  306  of the gate structure  303 . Accordingly, the portion of the second conductive layer  306 , on which a contact window is not going to be formed, will not be etched away. This method can solve the aforementioned problems, such as short circuiting between the bit line contacts and peeling. Nevertheless, the method of TW 544787 still has several disadvantages. 
         [0019]    Specifically, in TW 544787, after the contact window is formed, the second conductive layer  306  will be oxidized during subsequent processes, such as rapid thermal oxidation, and will result in a thicker layer  306 . A thickened layer  306  will decrease the space of the contact window and thus, causes a broken bit line contacts (CB open). Furthermore, the method has to increase the number of masks or change the thermal budget to provide additional patterns for the lithographic and etching process illustrated in  FIG. 3B  to pull-back the second conductive layer  306 . Moreover, the lithographic and etching process illustrated in  FIG. 3B  involve a wet and high temperature procedure that is performed over a long period of time using a photoresist as the hard mask. However, the photoresist becomes relatively weak due to the exposure to high temperatures and moisture during the lengthy process. In other words, the photoresist can be easily damaged during high temperature and/or wet processes. Hence, the etchant used in the etching process may permeate into the gate structure along the interface between the photoresist and the gate structure, and thereby, etching others portions that need not to be etched. 
         [0020]    Given the above descriptions, it is important to find an effective process that will not result in short circuiting between the bit line contact and gate conductor (CBGC short), a broken bit line contact (CB open) and/or short circuiting between the bit lines contacts (CBCB short) for gate structures with a pulled-back conductive layer. 
       SUMMARY OF THE INVENTION 
       [0021]    An objective of the present invention is to provide a method of forming a gate structure with a local pulled-back conductive layer. The method comprises the following steps: providing a substrate having a gate structure, wherein the gate structure has a first side wall and a second side wall and comprises the following layers from bottom to top: a first conductive layer, a second conductive layer, and an insulation layer; forming a protection layer on the first and second sidewalls of the gate structure to cover the first conductive layer and the second conductive layer; removing a portion of the protection layer from the first side wall to expose the second conductive layer; and performing an etching to pull-back the exposed second conductive layer. 
         [0022]    Another objective of the present invention is to provide a method for forming a contact window structure with a local pull back conductive layer. The method comprises the following steps: providing a substrate with a plurality of gate structures, wherein each of the gate structures comprises the following layers from bottom to top: a first conductive layer, a second conductive layer, and an insulation layer; forming a protection layer on a side wall of the each gate structure to cover the first conductive layer and the second conductive layer; removing a portion of the protection layer from each of the adjacent side walls of the selected adjacent gate structures to expose the second conductive layer of each of the selected adjacent gate structures; performing an etching to pull-back the exposed second conductive layer, forming a spacer on each side of each selected adjacent gate structures, and forming a dielectric layer to cover the substrate and the gate structures; and removing a portion of the dielectric layer located at a position between the selected adjacent gate structures. 
         [0023]    The detailed technology and preferred embodiments implemented for the subject invention are described in the following paragraphs accompanying the appended drawings for people skilled in this field to well appreciate the features of the claimed invention. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0024]      FIG. 1A  to  FIG. 1D  illustrate the steps of a conventional method for forming a contact window; 
           [0025]      FIG. 2A  to  FIG. 2D  illustrate the steps of another conventional process for forming a contact window; 
           [0026]      FIG. 3A  to  FIG. 3E  illustrate the steps of yet another conventional process for forming a contact window; 
           [0027]      FIGS. 4 ,  5 ,  6 A to  6 C,  7 A and  7 B illustrate an embodiment according to the present invention; and 
           [0028]      FIG. 8  is a top view showing the pulled-back conductive layer of an embodiment of the present invention. 
       
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENT 
       [0029]    First, as shown in  FIG. 4 , a substrate  402  with a plurality of gate structures  403  is provided. Each structure  403  has two side walls  405  and comprises the following layers from bottom to top: a first conductive layer  404 , a second conductive layer  406 , and an insulation layer  408 . The first conductive layer  404  can be a polysilicon layer or an amorphous silicon layer. The second conductive layer  406  can be a metal silicide layer, such as a tungsten silicide layer. The insulation layer  408  can be a silicon nitride layer. 
         [0030]    In  FIG. 5 , a protection layer  411  is formed on the side walls  405  of the gate structure  403  to cover the first conductive layer  404  and the second conductive layer  406 . The protection layer  411  can be an oxide layer formed by rapid thermal oxidation. 
         [0031]    Thereafter, a portion of the protection layer  411  is removed from each of the adjacent side walls  405  of the adjacent gate structures  403  to expose the second conductive layer  406 . For instance, as shown in  FIG. 6A , a photoresist layer  409  is deposited over the substrate  402  and the gate structures  403 . Next, as shown in  FIG. 6B , lithographic and etching processes are performed to remove a portion of the photoresist layer  409  from the region between the adjacent gate structures  403  and to form an opening  413 , wherein the height of the photoresist layer  409  in the opening is not higher than the first conductive layer  404 . Optionally, an anti-reflective layer (not shown) is deposited prior to the deposition of the photoresist layer  409 . In this case, the anti-reflective layer or both the anti-reflective layer and photoresist layer  409  are remained in the opening. In  FIG. 6C , an appropriate etchant, such as diluted HF, is used to etch away a portion of the protection layer  411  that is not covered by the photoresist layer  409  or the anti-reflective layer (if present) from the adjacent side walls  405 . As a result, a portion of the protection layer  411  is removed from the adjacent side walls  405  of the adjacent gate structures  403  and the second conductive layer  406  is exposed. 
         [0032]    In  FIG. 7A , the photoresist layer  409  (and anti-reflective layer, if present) is removed from the substrate  402 . Then, an isotropic etching process is performed using an etchant whose etching rate is higher in the second conductive layer  406  than in the insulation layer  408 , protection layer  404 , and first conductive layer  411 . The exposed second conductive layer  406  is then etched so that the gate structure  403  has a local pulled-back conductive layer. For instance, an HA solution (NH 4 OH+H 2 O 2 +H 2 O) can serve as the etchant to perform the isotropic etching process, in which the insulation layer  408  is a silicon nitride layer, the first conductive layer  404  is a polysilicon layer and the second conductive layer  406  is a tungsten silicide layer. In  FIG. 7B , spacers  415  are formed on the sides of the gate structure  403  and a dielectric layer  412  is deposited over the substrate  402  and the gate structure  403 . Lithographic and etching processes are performed to remove portions of the dielectric layer  412  from the region where the bit line contact window will be formed until the substrate  402  is exposed. As a result, a contact window is formed. Optionally, a self-aligned etching process can be adopted to form a self-aligned contact window in this step. 
         [0033]      FIG. 8  illustrates a top view of the second conductive layer  406 , showing the local pulled-back profile of the second conductive layer  406 . 
         [0034]    As illustrated above, the method of the present invention involves a local pull-back process after rapid thermal oxidation. Specifically, an oxide layer, which is formed by the rapid thermal oxidation, is used as a hard mask for forming a gate structure with a local pulled-back conductive layer. Thus, this method not only prevents short circuiting between the conductive layer of the gate structure, bit line contact window, and contact plugs, but also, prevents a CB open and peeling between the conductive layers of the gate structures. In addition, further lithographic and etching processes are not required, thereby, decreasing the thermal budget. 
         [0035]    The above disclosure is for illustrating the principles and effects of the present invention and for explaining the inventive features of the invention. People skilled in this field may proceed with a variety of modifications and replacements based on the disclosures and suggestions of the invention as described without departing from the characteristics thereof. Nevertheless, although such modifications and replacements are not fully disclosed in the above descriptions, they have substantially been covered in the following claims as appended.

Technology Category: h