Patent Document

FIELD OF THE INVENTION  
       [0001]     The present invention relates to PEM fuel cells and more particularly to a separator flow field plate in which relatively small pressure drop is required to achieve the necessary flow rates.  
       BACKGROUND OF THE INVENTION  
       [0002]     Fuel cells have been used as a power source in many applications. For example, fuel cells have been proposed for use in electrical vehicular power plants to replace internal combustion engines. In proton exchange membrane (PEM) type fuel cells, hydrogen is supplied as the fuel to the anode of the fuel cell and oxygen is supplied as the oxidant to the cathode. PEM fuel cells include a membrane electrode assembly (MEA) comprising a thin, proton transmissive, non-electrically conductive, solid polymer electrolyte membrane having the anode catalyst on one face and the cathode catalyst on the opposite face. The MEA is sandwiched between a pair of non-porous, electrically conductive elements or plates which (1) serve as current collectors for the anode and cathode, and (2) contain appropriate channels and/or openings formed therein for distributing the fuel cell&#39;s gaseous reactants over the surfaces of the respective anode and cathode catalysts.  
         [0003]     The term “fuel cell” is typically used to refer to either a single cell or a plurality of cells (stack) depending on the context. A plurality of individual cells are typically bundled together to form a fuel cell stack and are commonly arranged in electrical series. Each cell within the stack includes the membrane electrode assembly (MEA) described earlier, and each such MEA provides its increment of voltage. A group of adjacent cells within the stack is referred to as a cluster.  
         [0004]     In PEM fuel cells, hydrogen (H 2 ) is the anode reactant (i.e., fuel) and oxygen is the cathode reactant (i.e., oxidant). The oxygen can be either a pure form (O 2 ) or air (a mixture of O 2  and N 2 ). The solid polymer electrolytes are typically made from ion exchange resins such as perfluoronated sulfonic acid. The anode/cathode typically comprises finely divided catalytic particles, which are often supported on carbon particles, and mixed with a proton conductive resin. The catalytic particles are typically costly precious metal particles. As such these MEAs are relatively expensive to manufacture and require certain conditions, including proper water management and humidification and control of catalyst fouling constituents such as carbon monoxide (CO), for effective operation.  
         [0005]     Traditionally, the electrically conductive plates sandwiching the MEAs contain a reactant flow field for distributing the fuel cell&#39;s gaseous reactants (i.e., hydrogen and oxygen in the form of air) over the surfaces of the respective anode and cathode (referred collectively herein as active area). These reactant flow fields conventionally include a plurality of lands that define a plurality of flow channels therebetween through which the gaseous reactants flow from a supply header at one end of the flow channels to an exhaust header at the opposite end of the flow channels.  
         [0006]     The requirements for a well-performing flow field may be characterized into local requirements and global requirements. A local requirement generally applies to every point on the active area and a global requirement applies to the entire flow field design. To satisfy the local requirements of a well-performing flow field, the flow field should (1) deliver gas and humidification, (2) remove exhaust gases and (3) remove liquid water. To satisfy the global requirements of a well-performing flow field, the flow field should (4) satisfy local requirements at all points on the active area, (5) satisfy local requirements with a reasonably low overall pressure drop, (6) satisfy local requirements consistently over time thus producing stable flow, and (7) satisfy local requirements at all required flow and load conditions.  
         [0007]     The requirement for stable flow (6), is a difficult requirement to meet. Two reasons may be cited for this difficulty. First, it is difficult to determine exactly when stable flow has been achieved because there is more than one condition under which it can be successfully accomplished. Stable flow requires the consistent removal of liquid water. However, water can be removed in more than one way. For example, in some cases gas velocity may be sufficiently high such that collection of liquid water is not possible. In other cases, liquid water may collect and then a pressure build up may occur, causing the liquid water to move out. In some cases low gas velocity and an inability to build pressure cause unfavorable water removal conditions and an unstable gas flow.  
         [0008]     The second reason stable flow is difficult to meet is that in order to satisfy it, other flow field requirements must be compromised. For example, the aspects of a flow field design that satisfy requirements (3) and (6) directly compete with design aspects that satisfy requirements (4) and (5).  
         [0009]     The following three examples demonstrate the difficulty in designing a flow field that can satisfy all requirements concurrently, including establishing either one of the two possible stable flow conditions needed for consistent water removal. In a first example, it is possible to achieve stable flow by establishing a high gas velocity condition. A high gas velocity condition is established by designing a flow path having a high pressure gradient. However, for an averaged-sized active area, the consequence of such a design is a flow field having an unacceptably high overall pressure drop. In this way, requirements (3), (4), and (6) are met while (5) is not satisfied.  
         [0010]     In a second example, in order to reduce the overall pressure drop, Example 1 may be modified to have more parallel flow paths that are shorter in length. However, in reaching an acceptably low pressure drop, gas velocities become reduced to a level where liquid water is allowed to build up. Then, with the establishment of many parallel flow paths, removal of liquid water by a pressure build-up is no longer possible because a pressure build-up cannot be raised. Accordingly, requirements (4) and (5) are met while (3) and (6) remains unsatisfied.  
         [0011]     In a third example, in order to facilitate liquid removal by a pressure build-up, Example 2 may be modified by taking away some of the parallel flow paths. However, if the requirement of a low overall pressure drop is to be maintained, the length that can be added to each flow path to compensate for removing flow paths is limited. In this case, all the requirements are met except the one requiring the flow field to cover the entire active area. Specifically, requirements (3), (5) and (6) are met and (4) is not satisfied.  
       SUMMARY OF THE INVENTION  
       [0012]     The present invention is directed to a flow field design for achieving stable gas flows in the presence of liquid water, as well as for heightening the oxygen partial pressure in the catalyst layer in order to raise cell performance. The flow field design includes an intake manifold and an exhaust manifold which are configured in two offset planes. A relatively short passage extends from the intake manifold to the exhaust manifold and terminates at a diffusion medium such that fluid communication is provided from the intake manifold through the passage and the diffusion medium to the exhaust manifold. Thus, the present invention may be employed to establish convective, interdigitated-like flow through a diffusion medium in order to raise the oxygen partial pressure at the catalyst layer.  
         [0013]     In one aspect, the present invention is directed to a fuel cell having an first manifold defined between an membrane electrode assembly (MEA) and a first gas-impermeable element with a set of spacers disposed in the first manifold. A second manifold is defined between the first planar element and a second gas-impermeable element. The first gas-impermeable element and the spacers have an orifice formed therethrough such that a flow path is established from the first manifold across a reactive face of the MEA to the second manifold.  
         [0014]     In another aspect, the present invention is directed to a fuel cell having an MEA, a first separator sheet disposed in spaced relation to the diffusion medium sheet to define a first manifold therebetween and a first set of spacers disposed in the first manifold, each of the first set of spacers having an orifice transverse to the first manifold formed therein. A second separator sheet is disposed in spaced relation to the first separator sheet to define a second manifold therebetween transverse to the orifice, and a second set of spacers are disposed in the second manifold. A flow path is defined between the first manifold and the second manifold through the orifice across the reactive face of the MEA.  
         [0015]     In yet another aspect, the present invention is directed to a method of making a separator plate for a fuel cell in which a first conductive sheet is laminated onto a first film sheet, and a portion of said first conductive sheet is removed from the first film sheet such that a remaining portion of the first conductive sheet defines a first array of spacers. A passage is formed through each of the spacers in the first array of spacers and the first film sheet to establish a series of parallel flow paths. A second conductive sheet is laminated onto a second film sheet, and a portion of the second conductive sheet is removed from the second film sheet such that a remaining portion of the second conductive sheet defines a second array of spacers. The second array of spacers are laminated to the first film sheet opposite the first array of spacers such that a first manifold is formed between the first film sheet and the second film sheet.  
         [0016]     Further areas of applicability of the present invention will become apparent from the detailed description provided hereinafter. It should be understood that the detailed description and specific examples, while indicating the preferred embodiment of the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention. 
     
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0017]     The present invention will become more fully understood from the detailed description and the accompanying drawings, wherein:  
         [0018]      FIG. 1  is an isometric exploded view of a fuel cell including a pair of complimentary spring seals in a PEM fuel cell stack;  
         [0019]      FIG. 2  is a partial exploded perspective view of the bipolar plate illustrated in  FIG. 1 ;  
         [0020]      FIG. 3A  is a plan view of the exhaust side of a separator plate according to a preferred embodiment of the present invention;  
         [0021]      FIG. 3B  is a plan view of the inlet side of the separator plate of  FIG. 3A ;  
         [0022]      FIG. 4A  is a partial cross-sectional view of the separator plate of  FIG. 3A  taken along line  4 - 4 ;  
         [0023]      FIG. 4B  is a partial cross-sectional view of the separator plate of  FIG. 4A  illustrating the respective delivery, active area and exhaust legs of the flow path;  
         [0024]      FIG. 4C  is a detail of the inlet side of the separator plate;  
         [0025]      FIG. 4D  is a detail of the exhaust side of the separator plate;  
         [0026]      FIG. 5A  is a partial plan view of the inlet side of a separator plate according to an alternate embodiment of the present invention;  
         [0027]      FIG. 5B  is a partial plan view of the inlet side of a separator plate according to another alternate embodiment of the present invention;  
         [0028]      FIG. 6A  is a cross-sectional view of a bipolar plate taken through the inlet header;  
         [0029]      FIG. 6B  is a cross-sectional view of a bipolar plate taken through the exhaust header; and  
         [0030]      FIG. 7  is a flow diagram illustrating steps for making a separator plate according to the present invention. 
     
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT  
       [0031]     The following description of the preferred embodiment is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses.  
         [0032]      FIG. 1  schematically depicts a partial PEM fuel cell stack  10  having membrane-electrode-assemblies (MEAs)  14 ,  16  separated from each other by a non-porous, electrically-conductive bipolar plate  20 . The MEAs  14  and  16  and bipolar plate  20  are stacked together between non-porous, electrically-conductive, bipolar plates  22  and  24 . Flow-interfering media  26 ,  28 ,  30  and  32  which are porous, gas-permeable, and electrically conductive sheets press up against the electrode faces of the MEAs  14  and  16  and serve as primary current collectors for the electrodes. The flow-interfering media  26 ,  28 ,  30  and  32  also provide mechanical supports for the MEAs  14  and  16 , especially at locations where the MEAs are otherwise unsupported in the flow field. The flow-interfering media  26 ,  28 ,  30  and  32  further provide a fluid transport mechanism from the inlet manifold across the reactive face of the MEA to the exhaust manifold.  
         [0033]     Bipolar plates  22  and  24  press up against the primary current collector  26  on the reactive cathode face  14 c of the MEA  14  and the primary current collector  32  on the reactive anode face  16   a  of the MEA  16 . The bipolar plate  20  presses up against the diffusion medium  28  on the reactive anode face  14   a  of the MEA  14  and against the primary current collector or diffusion medium  30  on the reactive cathode face  16   c  of the MEA  16 . An oxidant gas such as oxygen or air is supplied to the cathode side of the fuel cell stack  10  from an oxygen or air source  38  via appropriate supply plumbing  40 . Similarly, a fuel such as hydrogen is supplied to the anode side of the fuel cell stack  10  from a hydrogen source  48  via appropriate plumbing  50 .  
         [0034]     With reference now to  FIGS. 2, 3A ,  3 B and  4 A a separator plate  60  according to the present invention will be described in greater detail. The separator plate  60  is configured to carry one of the reactant gases to a respective face of the MEA  16 . It is appreciated that each bipolar plate  20 ,  22  and  24  comprise two separator plates  60  lying in a back to back orientation ( FIGS. 5A and 5B ). Separator plate  60  includes a first array of electrically conductive spacers or disks  64  arranged along a gas-impermeable sheet  66 . An orifice  72  is formed through spacer  64  and sheet  66 . Separator plate  60  also includes a second array of electrically conductive spacers or pillars  68  arranged along a gas-impermeable sheet  76 . As best seen in  FIGS. 6A and 6B , an inlet header  80 A,  80 C communicates reactant gas from the appropriate supply plumbing  40 ,  50  into the separator plate  60 . An exhaust header  82 A,  82 C removes exhausted gas from the separator plate  60  as will be described.  
         [0035]     As presently preferred, the spacers  64  in the first array are circular disks having a diameter of approximately 0.375″ which are disposed on the first sheet  66  in a nested array such that the center of spacers  64  in adjacent rows/columns are offset with respect to one another. The orifice  72  formed through spacer  64  is about 0.050″ (50 mils). Spacers  64  are distributed on first sheet  66  at a density of about 6.25 spacers per square inch. As presently preferred, the pillars  68  in the second array are also circular disks having a diameter of approximately 0.125″ which are disposed on the first sheet  66  such that a subset of four pillars  68  are equiangularly superposed over at least a portion of the area defined by a subjacent spacer  64 . Pillars  68  are distributed on first sheet  66  in a density of about 25 pillars per square inch.  
         [0036]     While the above-described configuration of spacers  64  and pillars  68  are presently preferred, one skilled in the art will recognize that the size, shape, density, distribution and location of the spacers and pillars within the fuel cell may be selected in accordance with the specification and operational parameters of a given fuel cell application. For example, as illustrated in  FIG. 5A , spacers  64 ′ are configured as nested hexagons with an orifice  72 ′ formed therethrough. A set of pillars  68 ′ are configured as triangles with a subset of six triangles superposed over a portion of the area defined by a subjacent spacer  64 ′. In another example illustrated in  FIG. 5B , spacers  64 ″ are configured as nested squares with an orifice  72 ″ formed therethrough. A set of pillars  68 ″ are configured as squares with a subset of four squares superposed over an area defined by multiple subjacent spacers  64 ″. The terms superposed and subjacent are used in relative terms herein, and one skilled in the art should recognize that the order of adjacent components within the fuel cell  60  may be inverted.  
         [0037]     With reference again to FIGS.  2 ,  3 A- 3 B and  4 A- 4 D and  FIG. 6A-6B , the separator plate  60  will be described in greater detail. An inboard major face  84  of the first sheet  66  and an inboard major face  88  of the second sheet  76  define an inlet manifold  90  therebetween. Fluid communication between the inlet manifold  90  and the inlet header  80  is established by a plurality of runners  92  formed in frame  122 . The height of the inlet manifold  90  is defined by the height of the pillars  68 . An exhaust manifold  100  is defined between an outer face  104  of the first sheet  66  and an adjacent face  108  of the diffusion medium  30 . In this manner, the inlet manifold  90  and the exhaust manifold  100  function as a plenum throughout which the pressure is substantially constant, i.e., very little pressure differential within the manifold areas. Fluid communication from the exhaust manifold  100  to the outside of the stack is achieved by direct connection of this manifold to the atmosphere. In other words, manifold  100  is open to atmosphere all along its perimeter. The height of the exhaust manifold  100  is defined by the height of the disks  64 . As presently preferred, the inlet header  80  is formed along one margin of the separator plate  60 . No exhaust header, other than the direct connection of the manifold  100  to the atmosphere exists. However, one skilled in the art will recognize that the inlet header and exhaust header may be configured in any suitable manner to provide fluid communication of the reactant gas into and out of the flow field.  
         [0038]     Electrically conductive connectors  110  are disposed through vias  112  formed through the first sheet  66 , the pillars  68  and the second sheet  76 . The connectors  110  are aligned to electrically connect the pillars  68  with the corresponding disks  64 .  
         [0039]     The connectors  110  provide electrical continuity from the diffusion medium  30  to an outside face  116  of the second sheet  76 , thereby allowing current to be carried across the entire thickness of the separator plate  60  and consequently across the entire fuel cell stack  10 . The connectors  110  may comprise vias having conductive material disposed entirely therein or alternatively on an inner circumferential wall thereof for example. The conductive material may comprise graphite for example.  
         [0040]     With continued reference to  FIGS. 4B-4D  and  6 A- 6 B, the operation of the separator plate  60  will be described. The flow path of the reactant gas is characterized in three distinct flow segments namely, a delivery leg (D), an active area leg (A) and an exhaust leg (E). During the delivery leg (D), the reactant gas enters the separator plate  60  at the inlet header  80  and flows through the inlet manifold  90 . The reactant gas flows relatively freely (i.e., with no significant pressure drop and no predetermined path) around the respective pillars  68  and is contained within a lateral boundary ( FIG. 3 ) in the inlet manifold  90  defined by the interior edge  120  of a frame  122 . From the inlet manifold  90 , the reactant gas is directed through the respective orifices  72  in the disks  64  and the first sheet  66 .  
         [0041]     The active area leg (A) is designed to have a controlled pressure drop. Because the active area leg (A) accounts for nearly all the pressure drop of the flow path, it includes a flow-interfering medium that has a well-controlled permeability, length and cross-sectional area. The flow-interfering medium has lower permeability relative to empty space in the inlet/exhaust manifolds  90 ,  100  in order to guarantee that the pressure drop of the active area leg (A) is significantly higher than the delivery leg (D) and exhaust leg (E). During the active area leg (A), the reactant gas enters the flow-interfering-medium  30  from the orifice  72  passes across the face of the MEA (not shown) and exits the flow-interfering medium  30  at an outer boundary  126  ( FIG. 4A ) of the spacer  64 .  
         [0042]     As shown in  FIGS. 2 and 4 D, the active area leg (A) is radial from the orifice  72  adjacent the surface of spacer  64 . In this manner, a planar or 2-dimensional flow field, as compared with a channeled or 1-dimensional flow field, is provided which enables a differential flow distribution across the reactive face of the MEA. The dimension of the spacer  64  establishes the length of the flow path (A). The number of spacers  64  establishes the number of parallel paths. Thus, the planar flow field is similar to an interdigitated channel flow field but is much less susceptible to water blockage since the reactant gas is not constrained to flow in one dimension within the channel. This interdigitated-like flow field is beneficial because oxygen is carried through the primary current collectors by convection rather than diffusion allowing for significantly lower mass transport losses.  
         [0043]     The perimeter of spacer  64  multiplied by the diffusion medium thickness establishes the cross sectional area of the flow path (A). The permeability of the diffusion medium establishes the permeability of the flow path. Hence, these parameters establish the pressure gradient and overall pressure drop of the active area leg (A) depending on the number of parallel paths over the active area. The degree to which an even flow distribution over each parallel path is achieved is determined by tolerances to which these parameters can be held. Because the dimensional variations (radius and thickness) are most likely small compared with the variation in diffusion medium permeability, the permeability of the diffusion medium determines how evenly flow becomes distributed. The flow field of the present invention is very effective at removing water since the pressure drop is concentrated over a relatively short active area leg. As a result, the gas velocity in this segment of the flow path is very high so that liquid water will be forcefully moved away from the velocity of the MEA and into the exhaust manifold where it can be expelled from the fuel cell.  
         [0044]     Returning now to  FIGS. 4B and 4D , the exhaust path (E) is defined from the point at which the reactant flow leaves the flow-interfering medium  30  at the edge  126  of the spacer  64  to the point the flow exits the separator plate  60  through the exhaust header  82 . The exhaustive flow negotiates relatively freely (i.e., with no significant pressure drop or predetermined path) around the outer boundaries  126  of the spacer  64  and is contained within a frame or seal  130  ( FIG. 2 ).  
         [0045]     Turning now to  FIGS. 6A and 6B , two separator plates  60 , as described herein, are arranged in a back to back configuration and make up the bipolar plate  20 . It is appreciated that the second sheet  76  as represented in  FIG. 4A  may comprise a single sheet when arranged in the bipolar plate  20 . For clarity, a second separator plate is shown having like components and are referenced by numerals incremented by  200 . In the configuration as shown, the separator plate  60  is arranged to deliver cathode reactant to the flow-interfering medium  30  and the separator plate  260  is arranged to deliver anode reactant to the flow-interfering medium  28 . The electrical connectors  110  align with complementary electrical connectors  210  to provide electrical communication between adjacent MEAs  14  and  16 .  
         [0046]     With reference now to  FIG. 7 , a method of making the separator plate  60  is graphically present in a flow chart generally at reference  300 . Construction of the flow field is accomplished using flex-circuit materials and fabrication techniques. In step  302 , a first sheet of conductive material is laminated onto a gas impermeable polymeric film such as a polyimide film. The conductive material is preferably stainless steel having a thickness of 0.010″ (10 mils) for example. The polyimide film is preferably 0.002″ (2 mils) thick sheets of material. A suitable polyimide film includes Kapton® manufactured by the E.I. DuPont Corporation. In step  304 , the conductive material is etched into a desired pattern such as an array of disks. After etching, the array of disks preferably extend 0.010″ from the polyimide.  
         [0047]     In step  306 , the passages are formed in the disks. The passages may be formed by any suitable technique such as etching. In step  308 , a second sheet of conductive material is laminated onto a second sheet of gas-impermeable polymeric film. As presently preferred, the second sheet of conductive material is 0.010″ (10 mils) stainless steel and the second sheet of polymeric film is 0.002″ (2 mils) Kapton® film. In step  312 , the conductive layer is etched to form the pillars in a similar manner as described with respect to the disks. In step  318 , the pillar side of the second sheet of polyimide film is laminated onto the first sheet of polyimide film on a surface opposite the disks. The space created between the first and second polyimide sheets defines the delivery path or inlet manifold. In step  324  vias are incorporated into the separator plate and extend through the second sheet of polyimide, through each of the pillars and through the first sheet of polyimide.  
         [0048]     In step  330 , electrically conductive material is disposed through the vias to form electrically conductive paths. The electrically conductive paths may be formed by filling the vias entirely with conductive material or by coating the circumferential wall of the vias with conductive material. The electrically conductive paths allow current to be carried across the entire flow field as well as between adjacent separator plates and ultimately the fuel cell stack as a whole.  
         [0049]     Those skilled in the art can now appreciate from the foregoing description that the broad teachings of the present invention can be implemented in a variety of forms. For example, the number of spacers  64  shown on the separator plate  60  establishes the number of parallel flow paths and may be configured with fewer or greater disks. The geometrical configuration of the spacers  64  may alternatively comprise other shapes such as rectangles, triangles or trapezoids for example. Moreover, the pillars  68  defining the height of the inlet manifold  90  may comprise alternate shapes as described above. In addition, while it is shown that four pillars  68  compliment a single spacer  64 , other ratios may similarly be employed. Therefore, while this invention has been described in connection with particular examples thereof, the true scope of the invention should not be so limited since other modifications will become apparent to the skilled practitioner upon a study of the drawings, the specification and the following claims.

Technology Category: h