Patent Document

CROSS-REFERENCE TO RELATED APPLICATION  
         [0001]    This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2002-367110, filed on Dec. 18, 2002, the entire contents of which are incorporated herein by reference.  
         BACKGROUND OF THE INVENTION  
         [0002]    1. Field of the Invention  
           [0003]    This invention relates to a semiconductor device and its manufacturing method.  
           [0004]    2. Related Background Art  
           [0005]    The distance between wirings used in semiconductor devices is becoming narrower and narrower along with microminiaturization of semiconductors. In order to form contacts between narrow wirings to connect to conductors underlying the wirings, SACs (self-aligned contacts) have been used. For example, SACs are frequently used as contacts passing between adjacent word lines without contacting them for connection to a semiconductor device underlying the word lines.  
           [0006]    [0006]FIGS. 4A and 4B are cross-sectional views of word lines and their periphery of conventional DRAM  200 . FIG. 4A shows an aspect before contacts holes for SACs are formed. A plurality of word lines  20  are formed on the top surface of a semiconductor substrate  10 . Each word line  20  is composed of two different layers, namely, polysilicon layer  22  and silicide layer  24 . A top protection layer  30  is formed on the top surface of each word line  20 , and thin thermal oxide films  40  are formed on side surfaces of each word line  20 . Side protection films  50  are formed on side surfaces of each word line  20  and side surfaces of each top protection film  30  to cover the thermal oxide films  40 . Furthermore, an inter-layer insulation film  60  is deposited on the semiconductor substrate  10  to fill in the area between adjacent side protection films  50 . A photo-resist  70  is formed on the top surface of the inter-layer insulation film  60  and patterned by photolithography.  
           [0007]    [0007]FIG. 4B shows an aspect after formation of contact holes  80  for SACs. The inter-insulation film  60  is anisotropically etched by RIE (reactive ion etching), for example. The inter-layer insulation film  60  is made of a material having a higher etching rate than the top protection layer  30  and the side protection layer  50 . Therefore, the inter-layer insulation film  60  can be etched in self-alignment along the side protection films  50  down to the top surface of the substrate  10 . As a result, the contact holes  80  are formed to extend from the top surface of the inter-layer insulation film  60 , passing between adjacent word lines  20  and reaching the semiconductor substrate  10 .  
           [0008]    Thereafter, the photo resistor  70  is removed, and a conductor material for contact fills in the contact hole. Thereby, SACs (not shown) connecting to the top surface of the semiconductor substrate  10  between adjacent word lines  20  are completed.  
           [0009]    Since the top protection layers  30  and the side protection films  50  have a slower etching rate than the inter-layer insulation film  60 , they can function as etching stoppers for protecting the word lines  20 . Therefore, SACs filling in the contact holes  80  will not short circuit with the word lines  20 .  
           [0010]    However, edges of the top protection layers  30  and the side protection films  50  are physically weak and subject to erosion by anisotropic etching. Therefore, the top protection layers  30  and/or the side protection films  50  covering upper edges of the word lines  20  are thinned. If the top protection layers  30  and the side protection films  50  become significantly thin, the conductor in the contact holes  80  will short circuit with the word lines  20 .  
           [0011]    This has created a demand for a semiconductor device in which SACs connecting to the semiconductor substrate between adjacent wirings are prevented from short-circuiting with the wirings.  
         SUMMARY OF THE INVENTION  
         [0012]    A semiconductor device comprises a substrate; a plurality of wirings mounted on the substrate; a top protection layer mounted on a top surface of each the wiring; a side protection film mounted on each side surface of the top protection layer; an inter-layer insulation filling a space between the wirings and covering the top protection layer; and a contact hole penetrating the inter-layer insulation film between the wirings and reaching the substrate, the contact hole having a edge portion on inner wall of the contact hole, the edge portion being in a level higher than above the wirings and projecting upward away from the substrate in a position.  
           [0013]    A semiconductor device comprises a substrate having an electrically conducting portion; a plurality of wirings lying above the electrically conducting portion and insulated from the electrically conducting portion; a first top protection layer formed on the top surface of each said wiring; a second top protection layer made of a material higher in etching rate than the first top protection layer, said second top protection layer being formed on the top surface of each said first top protection layer; a side protection film formed on each side surface of the first top protection layer, the second protecting layer and said wiring; an inter-layer insulation film made of a material with a higher etching rate than the first top protection layer, said inter-layer insulation film filling a space between the wirings and covering the second top protection layers; and a contact hole penetrating the inter-layer insulation film between the wirings and reaching said electrically conducting portion, said contact hole having step portion formed on inner walls of said contact hole due to projections of the side protection films.  
           [0014]    A manufacturing method of a semiconductor device, comprises forming a plurality of wirings on a substrate; forming first top protection layers protecting top surfaces of the wirings; forming second top protection layers on the top surfaces of the first top protection layers, said second top protection layers being higher in etching rate than the first top protection layers; forming side protection films on each side surfaces of the wirings, the first top protection layers and the second top protection layers; depositing an inter-layer insulation film to fill between adjacent said wirings and to cover the second top protection layers, said inter-layer insulation film being made of a material higher in etching rate than the first top protection layers; and locally etching the inter-layer insulation film between adjacent said wirings in substantial self-alignment by using the second top protection layers and the side protection film. 
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0015]    [0015]FIG. 1 is a cross-sectional view of DRAM  100  according to an embodiment of the invention;  
         [0016]    [0016]FIG. 2A is a diagram showing a manufacturing method of DRAM  100 ;  
         [0017]    [0017]FIG. 2B is a diagram showing a process next to FIG. 2A of the manufacturing method of DRAM  100 ;  
         [0018]    [0018]FIG. 2C is a diagram showing a process next to FIG. 2B of the manufacturing method of DRAM  100 ;  
         [0019]    [0019]FIG. 3A is a diagram showing a process next to FIG. 2C of the manufacturing method of DRAM  100 ;  
         [0020]    [0020]FIG. 3B is a diagram showing a process next to FIG. 3A of the manufacturing method of DRAM  100 ;  
         [0021]    [0021]FIG. 3C is a diagram showing a process next to FIG. 3B of the manufacturing method of DRAM  100 ;  
         [0022]    [0022]FIG. 4A is a cross-sectional view of a part of DRAM  200  including word lines; and  
         [0023]    [0023]FIG. 4B is a cross-sectional view of the same part of DRAM  200  under a process next to FIG. 4A. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0024]    An embodiment of the invention will now be explained below with reference to the drawings. The embodiment, however, should not be construed to limit the invention.  
         [0025]    [0025]FIG. 1 is a cross-sectional view of DRAM  100  according to an embodiment of the invention. A plurality of word lines  120  are mounted on the top surface of a semiconductor substrate  110 . For better understanding of the embodiment, FIG. 1 shows two adjacent word lines  120 . In this embodiment, each word line  120  is composed of two different layers, namely, polysilicon layer  122  and silicide layer  124 . A first top protection layer  130  is mounted to cover the top surface of each word line  120 . Thin thermal oxide films  140  are mounted to cover the side surfaces of each word line  120 . A second top protection layer  200  is mounted to cover the top surface of the first protection layer  130 . Side protection films  150  are mounted to cover the side surfaces of each word line  120 , the side surfaces of the first top protection film  130  and the side surfaces of the second top protection film  200 . The upper end of side protection film  150  is higher than the top surface of first top protection layer  130 . Furthermore, an inter-layer insulation film  160  is mounted to cover the second protection film  200  and the side protection films  150 .  
         [0026]    Moreover, a contact hole  180  is formed in self-alignment between two adjacent word lines  120 . A conductor  190  is filled in the contact hole  180  to connect to a semiconductor substrate  110 . Hereunder, each contact hole  180  and the conductor  190  in combination are called SAC (self-aligned contact)  180 ,  190  as well.  
         [0027]    Each contact hole  180  is composed of an upper opening portion  180   a , a step portion  180   b  and a lower opening portion  180   c . The upper opening portion  180   a  extends from the top surface of the inter-layer insulation film  160  to an intermediate level of the first top protection layer  130 , and opens by a distance wider than the distance do between adjacent two word lines  120 . The lower opening portion  180   c  is in communication with the upper opening portion  180   a , and opens by a distance narrower than the distance do. The lower opening portion  180   c  reaches to the semiconductor substrate  110 . The step portion  180   b  is formed between the upper opening portion  180   a  and the lower opening portion  180   c . In the step portion  180   b , edges&#39; E of the side protection films  150  project upward away from the top surface of the semiconductor substrate  110  and is a level higher than above the wirings. FIG. 1 shows the boundary between the upper opening portion  180   a  and the step portion  180   b  and the boundary between the step portion  180   b  and the lower opening portion  180   c  by dot-and-dash lines.  
         [0028]    To form the contact hole  180  in self-aligned manner, the first top protection layer  130  and the side protection films  150  have lower etching rates than the inter-layer insulation film  160  and the second top protection layer  200 . In other words, a ratio of the etching rate of the inter-layer insulation film  160  and the second top protection layer  200  with respect to the etching rate of the first top protection layer  130  and the side protection films  150  (selectivity) is larger than 1.  
         [0029]    The first top protection layer  130  and the side protection films  150  may be made of different materials, but they are preferably made of the same material. For example, both the first top protection layer  130  and the side protection films  150  may be silicon nitride films. If the first top protection layer  130  and the side protection films  150  are silicon nitride films, they can be joined integrally by annealing after forming the first top protection layer  130  and the side protection films  150 . Therefore, as shown in FIG. 1, the boundary between the first top protection layer  130  and the side protection films  150  is represented by a broken line.  
         [0030]    The inter-layer insulation film  160  and the second top protection layer  200  may be made of different materials, but they are preferably made of the same material. For example, both of the inter-layer insulation film  160  and the second top protection layer  200  may be TEOS (Si(OC 2 H 5 ) 4 ) or BRSG. If the inter-layer insulation film  160  and the second top protection layer  200  are made of the same material, they can be joined integrally by annealing after forming the inter-layer insulation film  160  and the second top protection layer  200 . Therefore, as shown in FIG. 1, the boundary between the inter-layer insulation film  160  and the second top protection layer  200  is represented by a broken line.  
         [0031]    The conductor  190  is made of an electrically conductive material such as doped silicon or metal.  
         [0032]    According to the instant embodiment, the ends E of the side protection films  150  project upward in the step portion  180   b  of the contact hole  180  away from the semiconductor substrate as shown in FIG. 1. As a result, upper edges of the word lines  120  nearer to the center of the contact hole  180  are covered thicker by the side protection films  150  and the first top protection layer  130  than in conventional devices. It is therefore possible to reliably prevent SAC  180 ,  190  from short-circuiting with the word line  120 .  
         [0033]    [0033]FIGS. 2A through 3C are diagrams showing a manufacturing method of DRAM  100  according to the embodiment in the order of its process steps. Here is omitted illustration of a diffusion layer to be formed on the top surface of the semiconductor substrate  110 .  
         [0034]    First, the polysilicon layer  122  is deposited on the top surface of the semiconductor substrate  110 . The silicide layer  124  is next formed on the polysilicon layer  122 . Then, a silicon nitride film is deposited as the top protection layer  130  on the silicide layer  124 . Further, the second top protection layer  200  of TEOS or BPSG is deposited on the first top protection layer  130 .  
         [0035]    Subsequently, the first top protection layer  130  and the second top protection layer  200  are patterned by photolithography and RIE. Thereafter, using the first top protection layer  130  and the second protection layer  200  as a mask, the polysilicon layer  122  and the silicide layer  124  are patterned. As a result, the word lines  120 , the first top protection layers  130  and the second top protection layer  200  are made out as shown in FIG. 2A. After that, the word lines  120  are oxidized to form the thin thermal oxide layers  140  on side surfaces of the word lines  120 .  
         [0036]    As shown in FIG. 2B, a silicon nitride film is deposited as the side protection film  150 .  
         [0037]    Subsequently, the side protection film  150  is anisotropically etched by RIE or another appropriate technique. Thereby, the side protection films  150  are formed on side surfaces of the word lines  120 , first top protection layers  130  and second top protection layers  200  as shown in FIG. 2C. Since the second protection layers  200  overlie the first top protection layers  130 , side protection films  150  are formed to stand higher than the top surface of the first top protection layers  130 . The side protection films  150  are used, not only to protect side surfaces of the word lines  120 , but also to function as spacers when LDDs (lightly diffused drains) (not shown) are formed in the semiconductor substrate  110 .  
         [0038]    In the next step, TEOS or BPSG is deposited as the inter-layer insulation film  160  to bury the space between adjacent word lines  120 .  
         [0039]    As shown in FIG. 3A, the top surface of the inter-layer insulation film  160  is planarized by CMP, for example.  
         [0040]    As shown in FIG. 3B, deposition of TEOS or BPSG is resumed. As a result, the inter-layer insulation film  160  having the planarized top surface and fully covering the second top protection layer  200  is obtained. Thereafter, a photo resist is coated on the top surface of the inter-layer insulation film  160 , and patterned by lithography to form a photo resist layer  170 . The photo resist layer  170  locally exposes the top surface of the inter-layer insulation film  160  between adjacent word lines by a width larger than the distance do between the word lines.  
         [0041]    As shown in FIG. 3C, the inter-layer insulation film  160  is next etched by RIE using the photo resist layer  170  as a mask. This etching process is explained in greater detail with reference to FIG. 1. In this etching process, the inter-layer insulation film  160  and the second top protection layer  200  are etched following the pattern of the photo resist layer  170  to make a hole of a width d 1  wider than the distance do between adjacent word lines.  
         [0042]    As already explained, the etching rate of the inter-layer insulation film  160  is higher than those of the first top protection layers  130  and the side protection layers  150 . Therefore, after the etching progresses to the fist top protection layers  130  and the side protection films  150 , the inter-layer insulation film  160  is etched along the side of the side protection layers  150 . That is, the inter-layer insulation film  160  is etched to make a hole of a width d 2  narrower than the distance do between adjacent word lines, after the etching progresses to the fist top protection layers  130  and the side protection films  150 . When the inter-layer insulation film  160  is etched to the depth locally exposing the top surface of the semiconductor substrate  110 , the contact hole  180  is obtained.  
         [0043]    In this etching process, although the first top protection layers  130  and the side protection layers  150  have an etching rate lower than the etching rate of the inter-layer insulation film  160 , the first top protection layers  130  and the side protection layers  150  are etched as well to a certain extent. However, since the side protection films  150  extend higher than the top surfaces of the first top protection layers  130 , projections E remain after the contact hole  180  is formed.  
         [0044]    In the next process, doped polysilicon  190  is filled in the contact hole  180 , and it is patterned to obtain DRAM  100  shown in FIG. 1.  
         [0045]    The etching process for forming the contact hole  180  may be the same as that of the conventional technique. Since the side protection films  150  project higher than the top surface of the first top protection layers  130 , the etching process identical to the conventional etching technique can be used to reliably cover the upper end portions of the word lines  120  thicker by the first top protection layers  130  and the side protection films  150 . As a result, the embodiment can reliably prevents a short circuit between the word lines  120  and SAC  180 ,  190 .  
         [0046]    The embodiment has been explained by way of DRAM; however, the invention is applicable to other products using SACs.  
         [0047]    To cope with problems involved in the conventional technique, it may seem effective to increase the thickness of the top protection layer  30  shown in FIG. 4. However, the top protection layer  30  will become difficult to process. Additionally, since the ratio of the height of the side protection films  50  relative to the distance between adjacent word lines  20  (also called the aspect ratio hereinafter) increases, residue of the etching is liable to remain on the bottom of the contact hole  80 . If the etching duration is extended to remove the residue, then the upper end portions of the top protection layers  30  will become as thin as those of the conventional technique.  
         [0048]    To cope with problems involved in the conventional technique, it may seem effective to increase the ratio of the etching rate of the inter-layer insulation film  60  relative to the etching rate of the top protection layers  30  and the side protection films  50 . In this case, however, the top protection layer  30  and the side protection films  50  will become difficult to process.  
         [0049]    Furthermore, if those two methods are employed in combination, there occurs the problem that conditions for etching in the etching process must be changed upon forming the contact hole  80 .  
         [0050]    As such, the semiconductor device according to the embodiment of the invention can reliably prevent SACs connecting to the semiconductor substrate between adjacent wirings from short-circuiting with the wirings.

Technology Category: h