Patent Document

CLAIM OF PRIORITY 
       [0001]    The present application claims priority from Japanese application serial no. 2006-263714 filed on Sep. 28, 2006, the content of which is hereby incorporated by reference into this application. 
       BACKGROUND OF THE INVENTION 
       [0002]    1. Field of the Invention 
         [0003]    The present invention relates to a polymer electrolyte fuel cell. 
         [0004]    2. Description of Related Art 
         [0005]    In order to obtain a fuel cell with a high power density, it is efficient that components and/or regions in the fuel cell without direct contribution to power generation are trimmed down as possible so as to reduce the entire volume of the fuel cell. It is considered that reducing the amount of coolant in a fuel cell is one of possible means to satisfy above requirement. As described in JP-A-2005-235727, there is a method to reduce the amount of coolant by utilizing a latent heat cooling instead of a sensible heat cooling. The latent heat cooling utilizes the heat of vaporization of coolant, and the sensible heat cooling utilizes the specific heat of coolant. In the latent heat cooling, 2% of the amount of coolant used in the sensible heat cooling is enough theoretically to obtain a comparable cooling effect. 
         [0006]    For effective latent heat cooling, it makes the coolant be fine droplets to increase a surface area per unit volume of the coolant so as to facilitate vaporization. Moreover, the generated fine droplets of coolant are carried to a cooling place and made to hit against a member to be cooled. A gas can carry the fine droplets of coolant because the settling rate of the fine droplets is extremely low in the gas. However, at a bent portion of a pipe or another place where the acceleration works on a fluid to bend, the fine droplets of coolant are easy to separate from the carrier gas, thereby hitting against the pipe wall. As a result, there is a problem that the coolant is wasted at places where cooling is not needed. 
         [0007]    Furthermore, the reaction gas before a power generation reaction in a fuel cell usually includes water vapor. The vapor pressure is already near the saturated vapor pressure. Thus, even though the fine droplets of coolant are added to the reaction gas, it is difficult to vaporize due to the saturated vapor pressure, thereby decreasing the cooling effect. In addition, there is a problem that excessive moisture makes it difficult to remove water generated by the cell reaction. 
         [0008]    By the way, in a fuel cell, hydrogen is used as an anode gas (referred to below as the AN gas) and oxygen in the air is used as a cathode gas (referred to below as the CA gas). These gases are consumed as in a chemical equation below, generating water, heat and electric power. 
         [0000]      2H 2 +O 2 →2H 2 O+(heat)+(electric power) 
         [0009]    This reaction occurs during a flow from the upstream to the downstream along the flow fields in a fuel cell, so the reaction gas is consumed as the flow proceeds. While, water vapor generated by a cell reaction flows into the CA gas; and also water flows to the AN gas side on the basis of diffusion and electroosmosis, thereby increasing the water vapor concentration in the both sides (cathode and anode). When the water vapor exceeds the saturated concentration, condensed water generates and is easy to block the flow field. This condensed water then causes insufficiency of the reaction gas and flooding, thereby lowering the cell voltage and shortening a life of the cell. 
         [0010]    Furthermore, the condensed water releases latent heat and thereby a temperature of the fuel cell rises locally (uneven temperature distribution occurs). In order to protect the membrane electrode assembly (MEA), however, the maximum temperature must be limited; therefore fuel utilization ratio should be controlled to lower. As a result, the output of the entire cell decreases. 
         [0011]    On the contrary, in order to provide a fuel cell with a high power density and a low cost, it is desirable to raise the fuel utilization ratio to almost 100%. It is also desirable to reduce the regions such as manifolds of a separator and other parts without direct contribution to power generation so as to reduce the entire volume. In order to achieve above conditions, it is necessary that cooling performance is improved and that a uniform temperature distribution is attained. Moreover, it is also important to suppress a flooding phenomenon. 
       SUMMARY OF THE INVENTION 
       [0012]    Under these circumstances, it is an object of the present invention to provide a fuel cell that has a cooling efficiency higher than the cooling efficiencies of the conventional fuel cells. It is further object of the present invention to provide a fuel cell that has a uniform temperature distribution. It is further object of the present invention to provide a fuel cell that can suppress a flooding phenomenon. 
         [0013]    According to an aspect of the present invention, a fuel cell comprises a membrane electrode assembly, a bipolar plate for guiding a reaction gas to the membrane electrode assembly, a first coolant flow field adjacent to the bipolar plate, a second coolant flow field, and a member having permeability or a jet orifice so as to allow a coolant to pass through; wherein the member is disposed between the first and the second coolant flow fields. 
         [0014]    In a fuel cell in a preferred embodiment of the present invention, fine droplets of coolant are generated through coolant jet orifices of a interlayer separation plate into a first coolant flow field by flowing a pressured coolant in a second coolant flow field. The resulting latent heat due to vaporization of the fine droplets of coolant is used for cooling the fuel cell. Furthermore, although there is no restriction on the coolant in the present invention, it is preferable to use water as a coolant in the viewpoint of cost reduction. 
       ADVANTAGES OF THE INVENTION 
       [0015]    According to the present invention, it is possible to provide a fuel cell that has a high cooling efficiency by utilizing the latent heat cooling, thereby reducing the amount of coolant and entire volume of the fuel cell than in the case of the sensible heat cooling. Furthermore, it is possible to provide a fuel cell that has a compact size, thereby also reducing an auxiliary device power. Furthermore, it is possible to provide a fuel cell with a high cooling efficiency, which enables to increase the fuel utilization ratio. Accordingly, the fuel cell can perform high power operation. 
     
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0016]      FIG. 1  is a schematic illustration showing a plan view of a second coolant flow field and a bipolar plate in a fuel cell according to a first embodiment of the present invention. 
           [0017]      FIG. 2  is a schematic illustration showing a plan view of a first coolant flow field and the bipolar plate in the fuel cell according to the first embodiment of the present invention. 
           [0018]      FIG. 3  is a schematic illustration showing a cross sectional view cutting along A-A line in  FIG. 1  as well as a partial magnified view of the cross section. 
           [0019]      FIG. 4  is a schematic illustration showing a plan view of a second coolant flow field and a bipolar plate in a fuel cell according to a second embodiment of the present invention. 
           [0020]      FIG. 5  is a schematic illustration showing a plan view of a first coolant flow field and the bipolar plate in the fuel cell according to the second embodiment of the present invention. 
           [0021]      FIG. 6  is a schematic illustration showing a cross sectional view cutting along B-B line in  FIG. 4  as well as a partial magnified view of the cross section. 
           [0022]      FIG. 7  is a schematic illustration showing a plan view of a second coolant flow field and a bipolar plate in a fuel cell according to a third embodiment of the present invention. 
           [0023]      FIG. 8  is a schematic illustration showing a plan view of a first coolant flow field and the bipolar plate in the fuel cell according to the third embodiment of the present invention. 
           [0024]      FIG. 9  is a schematic illustration showing a cross sectional view cutting along C-C line in  FIG. 7 . 
           [0025]      FIG. 10  is a schematic illustration showing a transparent plan view of a reaction gas flow field and the bipolar plate of the fuel cell according to the third embodiment of the present invention. 
           [0026]      FIG. 11  is a schematic illustration showing a plan view of a second coolant flow field and a bipolar plate in a fuel cell according to a fourth embodiment of the present invention. 
           [0027]      FIG. 12  is a schematic illustration showing a plan view of a first coolant flow field and the bipolar plate in the fuel cell according to the fourth embodiment of the present invention. 
           [0028]      FIG. 13  is a schematic illustration showing a cross sectional view cutting along D-D line in  FIG. 11 . 
           [0029]      FIG. 14  is a schematic illustration showing a transparent plan view of a gas flow field in the fuel cell and the bipolar plate according to the fourth embodiment of the present invention. 
           [0030]      FIG. 15  is a schematic illustration showing a fuel cell according to the present invention in which the bipolar plate with two layers of coolant flow fields in any of the first, third, and fourth embodiments is stacked. 
       
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
       [0031]    Preferred embodiments of the present invention will be described below with reference to the drawings. However, the present invention is not limited to the embodiments described herein. 
       First Embodiment 
       [0032]      FIG. 1  is a schematic illustration showing a plan view of a second coolant flow field  2  and a bipolar plate  1  in a fuel cell according to a first embodiment of the present invention; and  FIG. 2  is a schematic illustration showing a plan view of a first coolant flow field  3  and the bipolar plate  1  in the fuel cell according to the first embodiment. The first coolant flow field  3  of two layers of coolant flow fields is adjacent to the bipolar plate  1 ; and the second coolant flow field  2  is far from the bipolar plate  1 . In  FIG. 2 , a coolant jet orifice  12 , which is invisible in practice, is indicated to clarify the positional relation between the coolant jet orifice  12  and a flow control block  13 .  FIG. 3  is a schematic illustration showing a cross sectional view cutting along A-A line in  FIG. 1  as well as a partial magnified view of the cross section.  FIG. 3  shows the relationship among components shown in  FIGS. 1 and 2 , a reaction gas flow field  4 , a gas diffusion layer (GDL)  5 , and a membrane electrode assembly (MEA)  6 . However, in order to simplify below explanation and indicate individual members in the drawing, the positions of the coolant jet orifices  12  and the positions of the flow control blocks  13  are mutually displaced. The magnified view is a partial magnified cross sectional view of a portion indicated by a dot-dash circle in a jet cooling device  7  comprising two layers of coolant flow fields. As shown in  FIG. 3 , the bipolar plate  1  is a plate made of a dense solid material, which is adjacent to the GDL  5  with reaction gas flow guide walls  18 . The reaction gas may be the AN gas or the CA gas in  FIG. 3 . The reaction gas flow field  4  is formed between the bipolar plate  1  and the GDL  5 ; the bipolar plate  1  supports the jet cooling device  7  and the reaction gas flow guide walls  18 . The jet cooling device  7  has a two-layer structure comprising the second coolant flow field  2  and first coolant flow field  3  separated by an interlayer separation plate  11 . 
         [0033]    As shown in  FIG. 1 , the bipolar plate  1  has inlet manifolds for the CA gas, AN gas, and coolant to be distributed into cells and also includes outlet manifolds. Of these manifolds, a coolant inlet manifold  8  and a coolant outlet manifold  9  relate to the jet cooling device  7  used for latent heat cooling; the coolant inlet manifold distributes the coolant for each cell, and the coolant outlet manifold collects and discharges the coolant distributed and then used for heat removal. Flow field guide walls  10  are disposed in the second coolant flow field  2  to equalize the flow of the coolant and to reduce a coolant flow to the vicinity of a seal  16 . Formed in the interlayer separation plate  11  are coolant jet orifices  12  through which the coolant is jetted into the first coolant flow field  3 . In the second coolant flow field, a flow field connecting to the coolant outlet manifold  9  is blocked by part of the flow field guide walls  10 , as shown in  FIG. 1 . 
         [0034]    On the other hand, as shown in  FIG. 2  of the first coolant flow fields  3 , many flow control blocks  13  are provided upstream of the coolant jet orifices  12 , instead of the flow field guide walls  10  disposed in the second coolant flow fields  2 . In the first coolant flow field  3 , part of flow field guide walls  15  blocks the coolant inlet manifold  8 . The seal  16  is attached to the same bipolar plate  1 , and seal the two layers (the first and second coolant flow fields) together. In order to facilitate fine coolant droplets&#39; movement and evaporation, the coolant jet orifice  12  is preferably designed so that the diameters of the fine coolant droplets are 30 μm or less. 
         [0035]    Next, the cooling process will be described. The coolant supplied from the coolant inlet manifold  8  is controlled by the flow field guide walls  10  and expands in the second coolant flow field  2 . Since the coolant outlet manifold  9  is blocked, the coolant passes through the coolant jet orifices  12 , and is jetted into the first coolant flow field  3 , generating coolant droplets  17 . The coolant droplets  17  then hit against the bipolar plate  1  and absorb the heat of the bipolar plate  1 ; and part of the coolant droplets  17  evaporates. A resulting mixed fluid of coolant and coolant vapor is ejected to the coolant outlet manifold  9 , which is not blocked. In this case, the flow control blocks  13  arrange the flow so that the mixed fluid of coolant and coolant vapor proceeding to the coolant outlet manifold  9  does not disturb the hitting of other coolant droplets against the bipolar plate  1  and their evaporation. The flow control block  13  also functions as a fin for increasing the actual surface area (heat transfer area) of the bipolar plate  1 . 
         [0036]    According to Heat Transfer Engineering Handbook (Dennetsu-Kogaku-Binran, in Japanese), when water is used as a coolant, it is usually expected that a heat transfer coefficient increases to five to ten times in coolant droplet cooling with the same amount of coolant. 
         [0037]    In the structure as described above, the amount of coolant can be reduced to 10 to 20%, as compared with the conventional sensible heat cooling, so the size of the coolant manifold can be reduced. Accordingly, the polymer electrolyte fuel cell can be made compact and have a high power density, and the auxiliary device in the cooling system can be also made compact. 
       Second Embodiment 
       [0038]      FIG. 4  is a schematic illustration showing a plan view of a second coolant flow field  2 ′ and a bipolar plate  1  in a fuel cell according to a second embodiment of the present invention.  FIG. 5  is a schematic illustration showing a plan view of a first coolant flow field  3 ′ and the bipolar plate  1  in the fuel cell according to the second embodiment.  FIG. 6  is a schematic illustration showing a cross sectional view cutting along B-B line in  FIG. 4  as well as a partial magnified view of the cross section. This embodiment differs from the first embodiment in that a porous interlayer separation plate  19  is used instead of the interlayer separation plate  11  made of a dense solid material and that the coolant jet orifices  12  are eliminated. Alternatively, the porous material of the porous interlayer separation plate  19  has an average pore diameter of about 30 μm. The porous interlayer separating plate  19  has preferably undergone a water-repellent treatment. The coolant passes through the pores that are randomly distributed, is jetted by the coolant pressure, and appears as a coolant droplet  27  in the first coolant flow field  3 ′. The coolant droplet is easily separated from the porous interlayer separation plate  19  due to the water-repellent treatment and hits against the bipolar plate  1 , thereby cooling the bipolar plate  1 . Concurrently, a part of coolant vaporizes directly from the porous interlayer separation plate  19 , so the bipolar plate  1  can be also cooled indirectly through the flow control blocks  13 ′. 
         [0039]    The above structure of the second embodiment further improves the cooling effect of the fuel cell entirely as compared with the first embodiment. In addition, the amount of coolant used can be further reduced. 
       Third Embodiment 
       [0040]      FIG. 7  is a schematic illustration showing a plan view of a second coolant flow field  32  and a bipolar plate  1  in a fuel cell according to a third embodiment of the present invention.  FIG. 8  is a schematic illustration showing a plan view of a first coolant flow field  33  and the bipolar plate  1  in the fuel cell according to the third embodiment.  FIG. 9  is a schematic illustration showing a cross sectional view cutting along C-C line in  FIG. 7 . Furthermore, in order to assist understanding of features in this embodiment, the CA gas to be supplied is indicated expediently by using arrows in  FIG. 9  (of course, the CA gas does not flow in the directions of the arrows). And also, only a seal that determines each flow field is described in each figure for easy understanding. This embodiment mainly differs from the first embodiment in that part of the CA gas is introduced into the first coolant flow fields  33 . Therefore, the cooling effect is enhanced by active ejection of the coolant. 
         [0041]    As shown in  FIG. 7 , the second coolant flow fields  32  are separated from a coolant outlet manifold  9  by a seal  26 . Accordingly, the coolant supplied from a coolant inlet manifold  8  fills the second coolant flow fields  32 ; after that the coolant is jetted to the first coolant flow fields  33  through a plurality of jet orifices  12 . 
         [0042]    On the other hand, as shown in  FIG. 8 , a seal  36  seals a CA gas inlet manifold  50  on the left side in the drawing as well as the coolant outlet manifold  9  and a CA gas outlet manifold  51  on the right side. 
         [0043]    In the first coolant flow field  33 , a flow field guide wall  35  guides the coolant and the CA gas to the coolant outlet manifold  9  and the CA gas outlet manifold  51 , respectively. 
         [0044]      FIG. 10  is a schematic illustration showing a transparent plan view of a reaction gas flow field  34  and the bipolar plate  1  of the fuel cell according to the third embodiment of the present invention. In order to facilitate understanding of the positional relationship between  FIGS. 7 ,  8  and  10 ,  FIG. 10  is drawn perspectively as viewed from  FIGS. 7 and 8  (when the reaction gas flow field  34  is viewed from the MEA  6  side, the right and left sides in  FIG. 10  should be inverted). A gas layer (the reaction gas flow field  34 , reaction gas flow guide walls  38  and so on) is formed between the bipolar plate  1  and the GDL  5 . The reaction gas flow field  34  is controlled by the reaction gas flow guide walls  38  (see  FIG. 9 ). In this gas layer, the CA gas introduced from the CA gas inlet manifold  50  is guided to the CA gas outlet manifold  51 . 
         [0045]    As mentioned above, the coolant supplied from the coolant inlet manifold  8  fills the second coolant flow field  32 , enters into the first coolant flow field  33  through the plurality of jet orifices  12 , and hits against the bipolar plate  1  so that cooling is carried out. Concurrently, the CA gas is fed from the CA gas inlet manifold  50  into the first coolant flow field  33 ; and a mixed fluid of the coolant, the coolant vapor resulting from heat removal and the CA gas flows downstream. Accordingly, the mixed fluid is ejected to the coolant outlet manifold  9 . At this time, the acceleration works on the mixed fluid to bend due to the positional relationship between the coolant outlet manifold  9  and the CA gas outlet manifold  51 , thereby most of the coolant is discharged from the coolant outlet manifold  9 . Most of the CA gas and the remaining coolant vapor are discharged from the CA gas outlet manifold  51 . In the reaction gas flow field  4 , the CA gas is fed from the CA gas inlet manifold  50 , passes through the GDL  5 , and causes an electrochemical reaction in the MEA  6 . Oxygen in the CA gas is then lost; the remaining CA gas and generated water vapor due to the cell reaction flow downstream and are discharged to the CA gas outlet manifold  51 . 
         [0046]    In the structure as described above, the coolant supplied for cooling and the resulting coolant vapor can be ejected actively by part of the supplied CA gas, so the cooling effect can be further enhanced. Accordingly, the polymer electrolyte fuel cell can be made compact and have a high power density. 
       Fourth Embodiment 
       [0047]      FIG. 11  is a schematic illustration showing a plan view of a second coolant flow field  42  and a bipolar plate  41  in a fuel cell according to a fourth embodiment of the present invention.  FIG. 12  is a schematic illustration showing a plan view of a first coolant flow field  43  and the bipolar plate  41  in the fuel cell according to the fourth embodiment.  FIG. 13  is a schematic illustration showing a cross sectional view cutting along D-D line in  FIG. 11 .  FIG. 14  is a schematic illustration showing a transparent plan view of a gas flow field in the fuel cell and the bipolar plate according to the fourth embodiment.  FIG. 14  is drawn perspectively as viewed from  FIGS. 11 and 12 , in the same manner of  FIG. 10 . Furthermore, only a seal that determines each flow field is described in each figure for easy understanding. 
         [0048]    This embodiment is a variation of the third embodiment; the direction in which the CA gas flows is opposite to that of the coolant flow in the second coolant flow field  42 ; and the CA gas outlet manifold  61  is commonly used for the coolant outlet manifold as shown in  FIGS. 12 and 14 . In this embodiment, heat exchange with the coolant in an upstream area, in which the temperature of the coolant is lowest, can be performed in a downstream area of the CA gas, in which the temperature of the CA gas is highest. Therefore, the temperature distribution in the fuel cell can be minimized. 
         [0049]    The above structure can further improve uniformity of the temperature distribution (can suppress a local temperature rise) in the fuel cell, so it becomes possible to raise the fuel utilization ratio. Accordingly, the polymer electrolyte fuel cell can be made compact and have a high power density. 
       Fifth Embodiment 
       [0050]      FIG. 15  is a schematic illustration showing a fuel cell  200  according to the present invention in which the bipolar plate with two layers of coolant flow fields in any of the first, third, and fourth embodiments is stacked. This embodiment can be also applied with necessary changes to the second embodiment because the second embodiment differs only in that a porous material is used instead of the coolant jet orifices. 
         [0051]    The fuel cell  200  generally comprises current collecting plates  113  disposed at both ends of a stack  100 , which externally supply current, insulating plates  109  disposed outward of the current collecting plates  113 , and end plates  114  and  115  that hold both ends of the insulating plates  109 . The end plate  114  has an AN gas supply port  112 , a CA gas supply port  111 , and a coolant supply port  110 . The end plate  115  has an AN gas discharge port  104 , a CA gas discharge port  108 , and a coolant discharge port  107 . The stack  100  comprises a plurality of unit cells, which are stacked so that jet cooling devices  121  according to the present invention face each other; and the unit cell is formed by holding a power generation portion  105  with a pair of bipolar plates  101 . In the power generation portion  105 , an MEA comprising an electrolyte membrane  102  and electrodes  103  is disposed between gas diffusion layers  106 . The power generation portion  105  is brought into contact with an AN gas flow field  120  and a CA gas flow field  122  of the bipolar plate  101 , along which hydrogen and oxygen are supplied to the power generation portion  105 . Current and heat are then generated. The jet cooling devices  121  disposed at the backsides of the gas flow fields  120  and  122  can absorb the heat generated from the power generation portion  105 . 
         [0052]    The above structure according to the present invention can reduce the amount of coolant flowing in the fuel cell. Furthermore, because the temperature distribution over the entire stack can be made uniform, the fuel efficiency can be increased. Accordingly, a compact polymer electrolyte fuel cell with a high power density can be provided. 
         [0053]    Although the invention has been described with respect to the specific embodiments for complete and clear disclosure, the appended claims are not to be thus limited but are to be construed as embodying all modifications and alternative constructions that may occur to one skilled in the art which fairly fall within the basic teaching herein set forth.

Technology Category: 5