Patent Document

CROSS-REFERENCE TO RELATED APPLICATIONS  
       [0001]     This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2003-316794, filed Sep. 9, 2003, the entire contents of which are incorporated herein by reference.  
       BACKGROUND OF THE INVENTION  
       [0002]     1. Field of the Invention  
         [0003]     The present invention relates to a semiconductor device and a method of manufacturing the same.  
         [0004]     2. Description of the Related Art  
         [0005]     In recent years, there is an increased demand for nonvolatile semiconductor memory devices, such as EEPROMs. A nonvolatile semiconductor memory device has problems in that where adjacent ones of memory cells in the word-line direction are close to each other, the capacitive coupling between the adjacent floating gates inevitably increases.  
         [0006]     To solve this problem, a depression is formed in an isolation insulating film between memory cells, and a control gate line (word line) is formed in the depression (which is disclosed, for example in Jpn. Pat. Appln. KOKAI Publication No. 2001-168306). A method for providing such a structure will be described, referring to  FIGS. 13-15 .  
         [0007]     In  FIG. 13 , reference numeral  101  denotes a semiconductor substrate comprising an isolation trench  103  and an element-forming region  102 . Numeral  104  denotes an isolation insulating. film, numeral  105  denotes a lower gate insulating film (a tunnel insulating film), and numerals  106   a  and  106   b  denote polysilicon films serving as a floating gate. In the process illustrated in  FIG. 13 , the isolation insulating film  104  and polysilicon film  106   a  are overlaid with polysilicon film  106   b , and a silicon oxide film  111  is formed on polysilicon film  106   b . After the silicon oxide film  111  is patterned by lithography and etching, a film used for preparing side spacers is formed on the entire surface of the resultant structure. The film is etched by RIE or the like in such a manner that side spacers  112  are left on the side surfaces of the silicon oxide film  111 . In this manner, the silicon oxide film  111  and the side spacers  112  define an etching mask having an opening portion  113 .  
         [0008]     Next, the polysilicon film  106   b  and the isolation insulating film  104  are etched, using the above-mentioned etching mask. As a result, a hollow portion  114  is defined, as shown in  FIG. 14 .  
         [0009]     As shown in  FIG. 15 , the etching mask is removed, an upper gate insulating film (an ONO film)  107  is formed, and a polysilicon film  108   a  and a WSi film  108   b , serving as control gate lines, are formed. Subsequently, the WSi film  108   b , the polysilicon film  108   a , the upper gate insulating film  107 , the polysilicon films  106   b  and  106   a , are patterned for isolation of memory cells.  
         [0010]     In the prior art described above, the capacitive coupling between the adjacent floating gates (namely, the polysilicon films  106   a  and  106   b ) can be suppressed by filling the hollow portion  114  of the isolation insulating film  104  with the polysilicon film  108   a.    
         [0011]     However, since lithography is used for patterning the silicon oxide film  111  in the prior art described above, there may be an alignment error between the pattern of the silicon oxide film  111  and the pattern of the isolation trench  103  (the isolation insulating film  104 ). In order to form the hollow portion  114  reliably in the isolation insulating. film  104 , the width of the etching mask composed of the silicon oxide film  111  and the side spacers  112  must be provided with a margin. In other words, the width of the opening portion  113  of the etching mask must be less than the width of the isolation trench  103  by the dimension corresponding to the margin. As a result, the width of the hollow portion  114 , which is formed by etching the polysilicon film  106   b  and the isolation insulating film  104 , is naturally less than the width of the isolation trench  103 . Where the adjacent memory cells are arranged at short intervals (in other words, the isolation trench  103  is narrow), it is very difficult to fill the hollow portion  114  with the polysilicon film  108   a . Hence, the capacitive coupling between floating gates is hard to suppress.  
         [0012]     As described above, the prior art has problems in that if the isolation trench has a reduced width, a control gate line cannot be easily formed in the hollow portion  114  of the isolation insulating film, and the capacitive coupling between floating gates is hard to suppress.  
       BRIEF SUMMARY OF THE INVENTION  
       [0013]     A semiconductor device according to a first aspect of the present invention comprises: a semiconductor substrate including first and second element-formation regions which are partitioned by an isolation trench; first and second lower gate insulating films formed on the first and second element-formation regions, respectively; first and second floating gates formed on the first and second lower gate insulating films, respectively; an isolation insulating film which is formed at least in the isolation trench and which has a depression formed in an upper surface thereof; an upper gate insulating film formed on the first and second floating gates; and a control gate line including an opposed portion which is opposed to the first and second floating gates, with the upper gate insulating film being interposed, and a portion located inside the depression, the first floating gate including a side surface which is opposed to the second floating gate and which entirely aligns with a side surface included in the first element-formation region and defined by the isolation trench, and the second floating gate including a side surface which is opposed to the first floating gate and which entirely aligns with a side surface included in the second element-formation region and defined by the isolation trench.  
         [0014]     A method of manufacturing a semiconductor device according to a second aspect of the present invention comprises: forming a lower gate insulating film on a semiconductor substrate; forming a floating gate material film on the lower gate insulating film; patterning the floating gate material film, the lower gate insulating film and the semiconductor substrate to form first and second pattern regions partitioned by a trench; forming a lower insulating film having a first depression in the trench; forming an upper insulating film on the lower insulating film to fill the first depression with the upper insulating film; etching the upper insulating film at an etching rate higher than an etching rate of the lower insulating film to form a second depression corresponding to the first depression in the lower insulating film; forming an upper gate insulating film on the patterned floating gate material films included in the first and second pattern regions; and forming a control gate material film on the upper gate insulating film and in the second depression. 
     
    
     BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING  
       [0015]      FIG. 1  is a plan view schematically showing a semiconductor device according to an embodiment of the present invention.  
         [0016]      FIGS. 2A and 2B  are sectional views schematically illustrating the semiconductor device according to the embodiment of the present invention.  
         [0017]      FIG. 3  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0018]      FIG. 4  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0019]      FIG. 5  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0020]      FIG. 6  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0021]      FIG. 7  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0022]      FIG. 8  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0023]      FIG. 9  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0024]      FIG. 10  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0025]      FIG. 11  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0026]      FIGS. 12A and 12B  are sectional views schematically illustrating part of the semiconductor device-manufacturing process according to the embodiment of the present invention.  
         [0027]      FIG. 13  is a sectional view schematically illustrating part of a semiconductor device-manufacturing process according to the prior art.  
         [0028]      FIG. 14  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the prior art.  
         [0029]      FIG. 15  is a sectional view schematically illustrating part of the semiconductor device-manufacturing process according to the prior art. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0030]     Embodiments of the present invention will now be described with reference to the accompanying drawings.  
         [0031]      FIG. 1  is a plan view schematically showing a semiconductor device (a NAND type nonvolatile semiconductor memory device) according to an embodiment of the present invention.  
         [0032]     As shown in  FIG. 1 , each NAND cell unit comprises a plurality of memory cells MC connected in series, and a selection transistor ST connected to the memory cell MC. The memory cells MC, arrayed in the direction of word line, are connected together by a common control gate line (word line)  26 , and the selection transistors ST are connected together by a common selection gate line  26 ′. Bit lines  42  are connected to the respective selection transistors ST through bit line contacts  43 .  
         [0033]      FIG. 2A  is a sectional view taken along line A-A of  FIG. 1 , and  FIG. 2B  is a sectional view taken along line B-B of  FIG. 1 .  
         [0034]     Referring to  FIGS. 2A and 2B , a semiconductor substrate (a silicon substrate)  11  comprises a plurality of element-formation regions  12 , and the adjacent element-formation regions  12  are partitioned by an isolation trench  13 . The memory cells MC and the selection transistors ST are formed in the element-formation regions  12 . Source/drain diffusion layer  14   a  is owned commonly by the memory cells MC that are adjacent to each other in the direction of bit lines, source/drain diffusion layer  14   b  is owned commonly by the memory cell MC and the selection transistor ST, and source/drain diffusion layer  14   c  is owned commonly by the selection transistors ST that are opposed to each other, with the bit line contact  43  being located therebetween.  
         [0035]     Each memory cell MC comprises a lower gate insulating film (a tunnel insulating film)  21 , a floating gate  22   a , an upper gate insulating film (an ONO film)  23 , and a control gate (a control gate line)  26  made up of a polysilicon film  24   a  and a tungsten silicide film (a WSi film)  25   a . As will be described later, when the isolation trench  13  is patterned, a floating gate material film and the lower gate insulating film  21  are patterned simultaneously. Hence, the floating gate  22   a , the lower gate insulating film  21  and the element-formation regions  12  have their side surfaces (i.e., the side surfaces partitioned by the isolation trench  13 ) aligned with one another.  
         [0036]     An isolation insulating film  31  having a depression is formed in the isolation trench  13 . The isolation insulating film  31  includes a portion extending upward, and this extending portion is in contact with the side surface of the floating gate  22   a . The control gate line  26  (i.e., polysilicon film  24   a  in the illustrated embodiment) is formed in the depression of the isolation insulating film  31 . The control gate line  26  serves to suppress the capacitive coupling between the adjacent floating gates  22   a.    
         [0037]     The films  22   a ′,  23 ′,  24   a ′ and  25   a ′ of selection transistor ST are made of the same films  22   a ,  23 ,  24   a  and  25   a  of memory cell MC, respectively. It should be noted that the selection gate line  26 ′ is connected to the electrode  22   a ′ at a position not illustrated. The gate insulating film  21 ′ is thicker than the lower gate insulating film  21  of memory cell MC.  
         [0038]     The memory cells MC and the selection transistors ST are covered with an interlayer insulating film  41 . A bit line  42  is formed on the interlayer insulating film  41 , and is connected to source/drain diffusion layer  14   c  through the bit line contact  43 .  
         [0039]     A method for manufacturing the semiconductor device of the above embodiment will now be described with reference to  FIGS. 3-12 .  FIGS. 3-11  and  FIG. 12A  correspond to the section taken along line A-A of  FIG. 1 , and  FIG. 12B  corresponds to the section taken along line B-B of  FIG. 1 .  
         [0040]     As shown in  FIG. 3 , a silicon oxide film having a thickness of about 10 nm is formed on the semiconductor substrate (silicon substrate)  11  by thermal oxidation. The silicon oxide film serves as the lower gate insulating film  21 . A gate insulating film should be preferably thicker at positions where selection transistors are to be formed. Subsequently, a polysilicon film having a thickness of about 160 nm is formed by LP-CVD (low-pressure chemical vapor deposition). The polysilicon film serves as the floating gate material film  22 . In addition, a silicon nitride film  27  having a thickness of about 90 nm is formed by LP-CVD. This silicon nitride film  27  serves as a stopper film in the CMP (chemical mechanical polishing) process. Then, a photoresist pattern  28  is formed on the silicon nitride film  27  by use of lithography.  
         [0041]     As shown in  FIG. 4 , the silicon nitride film  27 , the polysilicon film  22 , the lower gate insulating film  21  and the semiconductor substrate  11  are etched, using the photoresist pattern  28  as an etching mask. As a result, a trench  33  and a pattern region  30  are formed. The pattern region  30  is made up of the silicon nitride film  27 , the polysilicon film  22 , the lower gate insulating film  21  and the semiconductor substrate  11 . An element-formation region  12  and an isolation trench  13  (which has a depth of about  220  nm) are formed in the semiconductor substrate  11 . Patterned with the same photoresist pattern  28 , the polysilicon film  22 , the lower gate insulating film  21  and the element-formation region  12  have their side surfaces (i.e., the side surfaces partitioned by the isolation trench  13 ) aligned with one another.  
         [0042]     As shown in  FIG. 5 , a silicon oxide film having a depression  34  is formed by plasma CVD. The silicon oxide film is a lower insulating film  31  serving as an isolation insulating film. The thickness of the silicon oxide film  31  is smaller than half the width of the trench  33 , so that the depression  34  can be formed in the trench  33 . More specifically, the thickness of the silicon oxide film  31  is determined in consideration of the width and depth of the trench  33  in such a manner as to form a desired depression  34 . In the present embodiment, the thickness of the silicon oxide film  31  is controlled to be about 200 nm in flat regions (not shown).  
         [0043]     As shown in  FIG. 6 , the resultant structure is coated with polysilazane, and this material is subject to heat treatment in the vapor-containing oxidizing atmosphere, so as to densify the material. As a result, an upper insulating film  32  formed of polysilazane is obtained. The upper insulating film  32  formed of a coated film such as polysilazane is advantageous in that the depression  34  can be easily filled even if it is deep.  
         [0044]     As shown in  FIG. 7 , the upper insulating film  32  and the lower insulating film  31  are removed by CMP, except for the portions located inside the trench  33 , and the surfaces of the remaining upper and lower insulating films  32  and  31  are flattened. The silicon nitride film  27  functions as a stopper of the CMP process. But for the upper insulating film  32 , polishing particles in the CMP process would stay in the depression  34 . This does not become a problem as long as the depression  34  is filled with the upper insulating film  32 .  
         [0045]     Then, the silicon nitride film  27  is removed to expose the upper surface of the polysilicon film  22 , as shown in  FIG. 8 .  
         [0046]     As shown in  FIG. 9 , the upper insulating film  32  is removed by etching, so as to form a depression  35  corresponding to the depression  34 . This etching is selective etching, wherein the etching rate of the upper insulating film  32  is higher than that of the lower insulating film  31 . In the present embodiment, the etching is executed, using a buffer hydrofluoric acid (i.e., a mixed solution of hydrofluoric acid and ammonium fluoride). The use of the buffer hydrofluoric acid increases the selection ratio of the etching rate of the polysilazane to that of the CVD silicon oxide film. The buffer hydrofluoric acid may be replaced with hydrofluoric acid vapor. Since the etching takes place from the upper portions of the films, the upper portions of the lower insulating film  31  are etched, exposing the side surface of the polysilicon film  22 . How wide the side surface of the polysilicon film  22  is exposed (the exposure width) can be controlled by adjusting the etching conditions.  
         [0047]     As shown in  FIG. 10 , an ONO film having predetermined thickness and serving as the upper gate insulating film  23  is formed by LP-CVD. The ONO film is a film made up of a silicon oxide film, a silicon nitride film and a silicon oxide film, which are stacked in the order mentioned. The upper gate insulating film  23  may be formed at least on the exposed surfaces of the polysilicon film  22 . In the present embodiment, however, since the ONO film is deposited by LP-CVD, the upper gate insulating film  23  includes a portion extended onto the lower insulating film (isolation insulating film)  31 . In regions where selection transistors are to be formed, the upper gate insulating film  23  is partially etched out to expose part of the polysilicon film  22 .  
         [0048]     As shown in  FIG. 11 , a control gate material film  26  is formed on the upper gate insulating film  23 , thereby filling the depression  35  with the control gate material film  26 . To be more specific, a polysilicon film  24  doped with phosphorous and having a thickness of about 80 nm is formed by LP-CVD, and subsequently a tungsten silicide film (a WSi film)  25  having a thickness of about 85 nm is formed by sputtering.  
         [0049]     As shown in  FIGS. 12A and 12B , a silicon nitride film having a thickness of about 300 nm is formed by LP-CVD. Moreover, a resist pattern (not shown) is formed on the silicon nitride film. The silicon nitride film is etched using the resist pattern as a mask. By this etching, a mask pattern  44  of the silicon nitride film is formed. The mask pattern  44  extends in the direction perpendicular to the direction in which the isolation trench  13  extends. Using the mask pattern  44  as an etching mask, the tungsten silicide film  25 , the polysilicon film  24 , the upper gate insulating film  23  and the polysilicon film  22  are patterned. As a result, a floating gate  22   a  is formed by patterning the polysilicon film  22 , and a control gate line  26  is formed by patterning the polysilicon film  24   a  and the tungsten silicide film  25   a.    
         [0050]     Thereafter, source/drain diffusion layers  14   a ,  14   b  and  14   c , an interlayer insulating film  41  and a bit line  43  are formed. In this manner, the semiconductor device shown in  FIGS. 1, 2A  and  2 B is fabricated.  
         [0051]     According to the above embodiment of the present invention, the lower insulating film  31  serving as an isolation insulating film is overlaid with the upper insulating film  32 , and this upper insulating film  32  is removed by selective etching, thereby forming the depression  35 . As can be seen from this, the depression  35  can be formed without using the lithography technology, and no margin is required for forming the depression  35 . The maximal frontage width of the depression  35  can be equal to the width of the isolation trench  13 . In addition, since the entire side surface of the floating gate  22   a  aligns with the side surface of the isolation trench  13  (or the element-formation region  12 ), there is a constant distance between the adjacent ones of the floating gates  22   a , and the floating gates  22   a  do not have any restrictions on the frontage width of the depression  35 . In the present embodiment, therefore, the depression  35  can have an increased frontage width, and the control gate line  26  can be formed inside the depression  35  easily and reliably. The control gate line  26  formed in the depression  35  is effective in suppressing the capacitive coupling between the floating gates.  
         [0052]     If the uppermost portion of the isolation insulating film (lower insulating film)  31  is lower than the lower surface of the floating gate  22   a , then the upper gate insulating film (ONO film)  23  is the only element located between the control gate line  26  and the semiconductor substrate  11 . In this case, it is likely that the capacitive coupling between the control gate line  26  and the semiconductor substrate  11  will become a problem. Therefore, the uppermost portion of the isolation insulating film  31  should be preferably higher than the lower surface of the floating gate  22   a , as shown in  FIGS. 2A and 2B .  
         [0053]     If the uppermost portion of the isolation insulating film  31  is higher than the upper surface of the floating gate  22   a , the isolation insulating film  31  covers the entire side surface of the floating gate  22   a . In this case, the floating gate  22   a  is not much exposed, and it is hard to increase the capacitance between the floating gate  22   a  and the control gate line  26 . As shown in  FIGS. 2A and 2B , therefore, the uppermost portion of the isolation insulating film  31  should be preferably lower than the upper surface of the floating gate  22   a.    
         [0054]     If the lowermost portion of the control gate line  26  is higher than the lower surface of the floating gate  22   a , the capacitive coupling between the adjacent floating gates  22   a  may not be sufficiently suppressed by the control gate line  26 . Therefore, the lowermost portion of the control gate line  26  (the lowermost portion substantially corresponding to the bottom portion of the depression  35  of the isolation insulating film) should preferably be lower than the lower surface of the floating gate  22   a.    
         [0055]     In the embodiment described above, selective etching is performed with respect to the upper insulating film  32  and the lower insulating film (isolation insulating film)  31 , so as to form the depression  35 . Therefore, desirable positional relationships described above can be obtained by controlling the conditions under which the selective etching is performed.  
         [0056]     In the embodiment described above, the depression  35  is completely filed with the control gate line  26 , as shown in  FIGS. 2A and 2B . However, the control gate line  26  may be formed in such a manner as to extend along the surface of the depression  35 . In this case as well, the capacitive coupling between the adjacent floating gates  22   a  can be suppressed. In order to prevent disconnection of the control gate line  26 , it is preferable that the depression  35  be completely filled with the control gate line  26 .  
         [0057]     The lower insulating film  31  and the upper insulating film  32  are so selected as to make the etching rate of the upper insulating film  32  higher than that of the lower insulating film  31 . Where the lower insulating film  31  is a CVD insulating film, and the upper insulating film  32  is a coating film, a high etching selection ratio can be set to facilitate the selective etching of the upper insulating film  32 .  
         [0058]     Additional advantages and modifications will readily occur to those skilled in the art. Therefore, the invention in its broader aspects is not limited to the specific details and representative embodiments shown and described herein. Accordingly, various modifications may be made without departing from the spirit or scope of the general inventive concept as defined by the appended claims and their equivalents.

Technology Category: 5