Patent Document

This is a divisional of application Ser. No. 09/280,888, filed Mar. 29, 1999, now U.S. Pat. No. 6,218,688. 
    
    
     BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a method for forming semiconductor devices and, more particularly, to a method for forming Schottky diodes in a CMOS process. 
     2. Description of the Related Art. 
     A Schottky diode is a metal-to-semiconductor structure which is physically similar to a metal contact; essentially differing only in that the Schottky diode is formed on a lightly-doped region of the substrate, while the metal contact is formed on a heavily-doped region of the substrate. 
     Although physically similar, the Schottky diode and the metal contact exhibit very different current-to-voltage (I/V) relationships. This difference is due to the different dopant concentrations that are used in the two substrate regions. 
     The Schottky diode, which is formed on the lightly-doped region, has a current-to-voltage (I/V) relationship that is similar to the I/V relationship of a pn diode. That is, when forward biased, a Schottky diode provides a low-resistance current path and, when reverse-biased, a high-resistance current path. On the other hand, the metal contact, which is formed on the heavily-doped region, has a I/V relationship that is linear or resistive. 
     FIG. 1 shows a cross-sectional diagram that illustrates a wafer  100  which has a conventionally formed Schottky diode and a conventionally formed metal contact. As shown in FIG. 1, wafer  100  includes a n-type semiconductor material  110 , such as a substrate or a well, and a plurality of field oxide isolation regions FOX which are formed in material  110 . 
     Wafer  100  also includes a n+ region  112  and a p+ region  114  which are both formed in material  110 , and a n− region  116  which is defined in material  110 . N+ region  112  represents the heavily-doped substrate region of a biasing contact, while p+ region  114  represents the heavily-doped source and drain regions of a CMOS transistor. N− region  116 , in turn, represents the lightly-doped substrate region of a Schokkty diode. 
     As further shown in FIG. 1, wafer  100  also includes a layer of planarized silicon dioxide  120  which is formed over material  110  and the field oxide isolation regions FOX. Layer  120 , in turn, has an opening  122  which exposes n+ region  112 , an opening  124  which exposes p+ region  114 , and an opening  126  which exposes n− region  116 . 
     Wafer  100  additionally includes a layer of titanium  128  which is formed over regions  112 ,  114 , and  116 , and the sidewalls of the openings  122 ,  124 , and  126 , and a layer of titanium nitride  130  which is formed over titanium layer  128 . Titanium layer  128  and titanium nitride layer  130  form a diffusion barrier to prevent junction spiking. (Part of titanium layer  130  is converted into titanium silicide during the heat treatments that are associated with contact formation.) 
     Further, wafer  100  Includes an aluminum or tungsten plug  132  which is formed over titanium nitride layer  130  in opening  122 , an aluminum or tungsten plug  134  which is formed over titanium nitride layer  130  in opening  124 , and an aluminum or tungsten plug  136  which is formed over titanium nitride layer  130  in opening  126 . In addition, a plurality of aluminum lines  138 ,  140 , and  142  are connected to plugs  132 ,  134 , and  136 , respectively, and other lines to realize the underlying electrical circuit. 
     As shown in FIG. 1, a substrate biasing contact  144  is formed by n+ region  112 , barrier layers  128  and  130 , and plug  132 , while a source/drain contact  146  is formed by p+ region  114 , barrier layers  128  and  130 , and plug  134 . Further, a Schottky diode  148  is formed by n-region  116 , barrier layers  128  and  130  (titanium/titanium silicide and titanium nitride), and plug  136 . 
     One of the problems with Schottky diode  148 , however, is that the minimum size of diode  148  is typically determined by the minimum contact size that is available in the photolithographic process. As a result, diode  148  consumes a significant amount of silicon real estate (substrate surface area). Thus, there is a need for a Schottky diode that requires less silicon real estate. 
     SUMMARY OF THE INVENTION 
     Conventionally, Schottky diodes require a significant amount of silicon real estate as the minimum size of the diode is typically limited to the minimum contact size that is available. The present invention eliminates the silicon real estate required by the diode by forming the Schottky diode through a field oxide isolation region. 
     In accordance with the present invention, a wafer, which has a Schottky diode, includes a semiconductor material which has a first conductivity type and a first dopant concentration, and a first region which is formed in the semiconductor material. The first region has a second conductivity type and a second dopant concentration. 
     The wafer also includes a field oxide isolation region which is formed in the semiconductor material, the field oxide isolation region has a first opening that extends through the field oxide isolation region. 
     The wafer further includes a second region which is defined in the semiconductor material to adjoin the first opening in the field oxide isolation region, and a layer of insulation material which is formed over the first region and the field oxide isolation region. The second region has the first conductivity type and the first dopant concentration. 
     The layer of insulation material has a second opening that extends through the layer of insulation material, and a third opening that extends through the layer of insulation material. The second opening adjoins the first region while the third opening adjoins the first opening. 
     The wafer additionally includes a layer of barrier material which is formed on the sidewalls of the second opening, the first region, the sidewalls of the first and third openings, and the second region. Further, a first metal plug is formed in the second opening to contact the layer of barrier material, while a second metal plug is formed in the first and third openings to contact the layer of barrier material. 
     The present invention also includes a method for forming a Schottky diode in a wafer. The wafer has a semiconductor material which has a first conductivity type and a first dopant concentration, and a first region that is formed in the semiconductor material. The first region has a second conductivity type and a second dopant concentration. 
     The wafer also has a field oxide region that is formed in the semiconductor material, a second region which is defined in the semiconductor material below the field oxide region, and a layer of insulation material which is formed over the first region and the field oxide region. 
     The method of the present invention comprises the steps of selectively removing the layer of insulation material to form a first opening that exposes the first region to form an exposed first region, and a second opening that exposes the second region to form an exposed second region. 
     The method also includes the steps of forming a layer of barrier material on the layer of insulation material, the exposed first region, and the exposed second region, and forming a layer of metal over the layer of barrier material. 
     A better understanding of the features and advantages of the present invention will be obtained by reference to the following detailed description and accompanying drawings which set forth an illustrative embodiment in which the principals of the invention are utilized. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a cross-sectional diagram illustrating a prior art wafer  100  which has a conventionally formed Schottky diode and a conventionally formed metal contact. 
     FIG. 2 is a cross-sectional drawing illustrating a wafer  200  which has a Schottky diode in accordance with the present invention. 
     FIG. 3 is a cross-sectional diagram illustrating wafer  200  with applied biasing voltages in accordance with the present invention. 
     FIGS. 4A-4E are cross-sectional diagrams illustrating a method for forming a Schottky diode in accordance with the present invention. 
     FIGS. 5A and 5B are cross-sectional diagrams illustrating a two-step etch process in accordance with the present invention. 
     FIGS. 6A-6D are graphs illustrating the I/V relationships of diodes  290  and  292  when titanium silicide (TiSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226  in accordance with the present invention. 
     FIGS. 7A-7D are graphs illustrating the I/V relationships of diodes  290  and  292  when cobalt silicide (CoSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226  in accordance with the present invention. 
     FIGS. 8A-8D are graphs illustrating the I/V relationships of diodes  290  and  292  when cobalt silicide (CoSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226  in accordance with the present invention. 
     FIGS. 9A-9D are graphs illustrating the I/V relationships of diodes  290  and  292  when cobalt silicide (CoSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226  in accordance with the present invention. 
    
    
     DETAILED DESCRIPTION 
     FIG. 2 shows a cross-sectional drawing that illustrates a wafer  200  which has a Schottky diode in accordance with the present invention. As described in greater detail below, the present invention reduces the silicon real estate that is consumed by a Schottky diode by forming the diode through an isolation region. 
     As shown in FIG. 2, wafer  200  includes a n-well  202  and a p-well  204  which are both formed in a substrate  206 , and a plurality of field oxide isolation regions FOX that include a field oxide isolation region FOX 1  which is formed in well  202 , and a field oxide isolation region FOX 2  which is formed in well  204 . 
     In accordance with the present invention, field oxide isolation region FOX 1  includes an opening  208  which extends through isolation region FOX 1 , while field oxide isolation region FOX 2  includes an opening  210  which extends through isolation region FOX 2 . 
     Wafer  200  also includes a n+ region  212  and a p+ region  214  which are both formed in n-well  202 . Regions  212  and  214 , in turn, may optionally include overlying salicide layers  212   a  and  214   a  which are conventionally formed from titanium silicide (TiSi 2 ) or the Group III silicides such as cobalt silicide (CoSi 2 ). N+ region  212  represents the heavily-doped substrate region of a biasing contact, while p+ region  214  represents the heavily-doped source and drain regions of a p-channel transistor. 
     Wafer  200  further includes a n− region  216  which, in accordance with the present invention, is defined in well  202  below opening  208  in field oxide isolation region FOX 1 . N− region  216  represents the lightly-doped substrate region of a Schottky diode. 
     Similarly, wafer  200  includes a p+ region  222  and a n+ region  224  which are both formed in p-well  204 . Regions  222  and  224  may optionally include overlying salicide layers  222   a  and  224   a  which are conventionally formed from titanium silicide (TiSi 2 ) or the Group III silicides such as cobalt silicide (CoSi 2 ). P+ region  222  represents the heavily-doped substrate region of a biasing contact, while n+ region  224  represents the heavily-doped source and drain regions of a n-channel transistor. 
     Wafer  200  additionally includes a p− region  226  which, in accordance with the present invention, is defined in well  204  below opening  210  in field oxide isolation region FOX 2 . P− region  226  represents the lightly-doped substrate region of a Schokkty diode. 
     As further shown in FIG. 2, wafer  200  also includes a layer of planarized silicon dioxide  230  which is formed over wells  202  and  204  and the field oxide isolation regions FOX, FOX 1 , and FOX 2 . Layer  230  has an opening  232  which exposes n+ region  212 , and an opening  234  which exposes p+ region  214 . In addition, layer  230  also has an opening  236  which is in register with opening  208  in field oxide isolation region FOX 1  to thereby expose n− region  216 . 
     Layer  230  further includes an opening  242  which exposes p+ region  222 , and an opening  244  which exposes n+ region.  224 . In addition, layer  230  further has an opening  246  which is in register with opening  210  in field oxide isolation region FOX 2  to expose p− region  226 . 
     Further, wafer  200  additionally includes a diffusion barrier  250  which is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226 , and on the sidewalls of openings  232 ,  234 ,  236 ,  242 ,  244 , and  246 . Diffusion barrier  250  may include, for example, a layer of titanium (Ti) and an overlying layer of titanium nitride (TiN). Diffusion barrier  250  is used to prevent junction spiking. 
     As additionally shown in FIG. 2, wafer  200  also includes an aluminum or tungsten plug  252  which is formed over barrier  250  in opening  232 , an aluminum or tungsten plug  254  which is formed over barrier  250  in opening  234 , and an aluminum or tungsten plug  256  which is formed over barrier  250  in opening  236 . 
     An aluminum or tungsten plug  262  is formed over barrier  250  in opening  242 , an aluminum or tungsten plug  264  is formed over barrier  250  in opening  244 , and an aluminum or tungsten plug  266  is formed over barrier  250  in opening  246 . In addition, a plurality of aluminum lines  268 ,  270 ,  272 ,  274 ,  276 , and  278  are connected to plugs  252 ,  254 ,  256 ,  262 ,  264 , and  266 , respectively, and other lines to realize the underlying electrical circuit. 
     As shown in FIG. 2, a substrate biasing contact  280  is formed by n+ region  212 , barrier  250 , and aluminum plug  252 , while a substrate biasing contact  282  is formed by p+ region  222 , barrier  250 , and aluminum plug  262 . In addition, a source/drain contact  284  is formed by p+ region  114 , barrier  250 , and aluminum plug  254 , while a source/drain contact  286  is formed by n+ region  224 , barrier  250 , and aluminum plug  264 . 
     Further, a Schottky diode  290  is formed by n-region  216 , barrier  250 , and aluminum plug  256 , while a Schottky diode  292  is formed by p-region  226 , barrier  250 , and aluminum plug  266 . 
     One of the advantages of the present invention is that since Schottky diodes  290  and  292  are formed through the field oxide regions FOX 1  and FOX 2 , respectively, a separate isolated area of the substrate is no longer required to support the diode. As a result, the Schottky diode of the present invention can be formed without consuming any silicon real estate. 
     One example of how Schottky diodes  290  and  292  can be used is shown in FIG.  3 . FIG. 3 is a cross-sectional diagram that illustrates wafer  200  with applied biasing voltages. When ground is applied to plug  252  via line  268 , n-well  202  is biased to ground. As a result, diode  290  prevents line  272  from going more positive than a few tenths of a volt because a positive voltage on line  272  forward biases diode  290 . 
     Similarly, when a positive voltage is applied to plug  262  via line  274 , p-well  204  is biased positive. As a result, diode  292  prevents line  278  from going more negative than a few tenths of a volt because a negative voltage on line  278  forward biases diode  292 . 
     FIGS. 4A-4E show a series of cross-sectional diagrams that illustrate a method for forming a Schottky diode in accordance with the present invention. As shown in FIG. 4A, the method begins with a wafer  400  which is a partially completed version of wafer  200 . 
     In wafer  400 , n-well  202 , p-well  204 , and substrate  206  are conventionally formed. In addition, a plurality of LOCOS-formed field oxide isolation regions FOX are formed in wells  202  and  204 . The field oxide isolation regions FOX include a region FOXA which is formed in well  202 , and a region FOXB which is formed in well  204 . 
     Further, regions  212 ,  214 ,  222 , and  224  are conventionally formed in wells  202  and  204 , and may optionally include salicide layers  212   a ,  214   a ,  222   a , and  224   a , respectively. Wafer  400  also includes a conventionally formed and planarized layer of insulation material  408 , such as silicon dioxide, which is formed over wells  202  and  204 , and field oxide isolation regions FOX, FOXA, and FOXB. 
     As shown in FIG. 4A, the process begins by defining regions  216  and  226  under isolation regions FOXA and FOXB, and then forming a mask  410  on silicon dioxide layer  408 . Mask  410  is then patterned to have unmasked areas over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226 . 
     After this, as shown in FIG. 4B, the unmasked areas of silicon dioxide layer  408  are etched to form an opening  412  that exposes region  212 , an opening  414  that exposes region  214 , and an opening  416  that exposes region  216 . In addition, the etch also forms an opening  422  that exposes region  222 , an opening  424  that exposes region  224 , and an opening  426  that exposes region  226 . 
     As shown in FIG. 4C, the etch exposes regions  212 ,  214 ,  222 , and  224  before exposing regions  216  and  226 . Thus, regions  212 ,  214 ,  222 , and  224  must be overetched by an amount which allows the etch to expose regions  216  and  226 . 
     When regions  212 ,  214 ;  222 , and  224  include salicide layers  212   a ,  214   a ,  222   a , and  224   a , this overetching presents little concern since the silicon dioxide of isolation regions FOXA and FOXB is etched at a much faster rate than salicide layers  212   a ,  214   a ,  222   a , and  224   a.    
     Even when salicide layers  212   a ,  214   a ,  222   a , and  224   a  are not present, this overetching causes little damage since the silicon dioxide in isolation regions FOXA and FOXB is etched with an etchant that has a selectivity of 10:1 or greater with respect to silicon. 
     Further, it is a common practice to overetch contact openings by 50-100% to insure that layer  408  is completely removed. This overetching, in turn, provides more than the needed time for the etching to etch all of the way through the field oxide isolation regions FOXA and FOXB and remove the oxide from the surface of regions  216  and  226 . 
     Alternately, as shown in FIGS. 5A and 5B, a two-step etch process may be used to equalize the amount of layer  408  that must be etched through to form the openings. As shown in FIG. 5A, a first mask  510  is formed so that the first etch forms openings  516  and  526  over regions  216  and  226  which have depths D 1  and D 2  that are approximately equal to the step heights H 1  and H 2  of the isolation regions FOXA and FOXB. 
     As a result, the remaining amount of oxide layer  408  and isolation region FOXA that must be etched away to expose region  216 , and the remaining amount of oxide layer  408  and isolation region FOXB that must be etched away to expose region  226 , are approximately the same as the amount of oxide layer  408  that must be removed to expose regions  212 ,  214 ,  222 , and  224 . 
     Thus, as shown in FIG. 5B, when mask  410  is formed, the second etch forms openings which expose regions  212 ,  214 ,  222 , and  224 , while at the same time completing the openings formed over regions  216  and  226 . 
     As shown in FIG. 4D, once openings  412 ,  414 ,  416 ,  422 ,  424 , and  426  have been formed, mask  410  is removed. Following the removal of mask  410 , the surfaces of regions  212 ,  214 ,  216 ,  222 ,  224 , and  226  are cleaned to remove any native oxide that may have been formed. 
     After this, a layer of titanium (Ti)  430 , which adheres well to silicon dioxide, is formed on the exposed surfaces of silicon dioxide layer  408 , and regions  212 ,  214 ,  216 ,  222 ,  224 , and  226 . Next, a layer of titanium nitride (TiN)  432 , which forms an excellent diffusion barrier against junction spiking, is formed over titanium layer  430 . Alternately, other materials may be used to form a diffusion barrier in lieu of the combination of titanium and titanium nitride. 
     Junction spiking is not a serious problem for Schottky diodes, but primarily is a problem for metal contacts where the conductivity of the substrate contact region is different from the conductivity of the underlying well, e.g., a p+ region in a n-well or substrate, and a n+ region in a p-well or substrate. 
     Junction spiking occurs when aluminum from the to-be-formed metal- 1  layer directly contacts the silicon surface of wells  202  and  204 . When this aluminum-to-silicon interface is subsequently annealed, silicon easily diffuses into the aluminum which, in turn, allows aluminum to diffuse into the silicon. 
     If too much aluminum diffuses into the silicon, the aluminum can extend through the bottom side of the pn junction, thereby shorting out the junction. Thus, junction spiking is a significant concern with current-generation CMOS devices which utilize very shallow junction depths. 
     Returning to the process flow, after the layer of titanium nitride  432  has been formed, a layer of metal- 1   434 , such as aluminum (Al) or tungsten (W), is deposited on the surface of silicon dioxide layer  408  to fill up openings  412 ,  414 ,  416 ,  422 ,  424 , and  426 . The aluminum or tungsten in openings  412 ,  414 ,  416 ,  422 ,  424 , and  426  forms aluminum or tungsten plugs  252 ,  254 ,  256 ,  262 ,  264 , and  266 . 
     Next, wafer  400  is annealed. When salicide layers  212   a ,  214   a ,  222   a , and  224   a  are not used, the annealing step forms a layer of titanium silicide where the titanium contacts the silicon. When salicide layers  212   a ,  214   a ,  222   a , and  224   a  are present, the salicide, titanium, and titanium nitride layers form metal-to-metal interfaces. 
     Next, a mask  436  is formed and patterned on metal- 1  layer  434 . Metal- 1  layer  434  is then etched to define conductive paths which, in part, define the underlying circuit. Following the etch, mask  436  is removed to form the structure shown in FIG.  4 E. 
     Thus, as shown in FIG. 4E, substrate biasing contact  270  is formed by n+ region  212 , barrier layers  430  and  432 , and plug  242 , while substrate biasing contact  272  is formed by p+ region  222 , barrier layers  430  and  432 , and plug  252 . In addition, source/drain contact  274  is formed by p+ region  214 , barrier layers  430  and  432 , and plug  244 , while source/drain contact  276  is formed by n+ region  224 , barrier layers  430  and  432 , and plug  254 . 
     Further, Schottky diode  290  is formed by n-region  216 , barrier layers  430  and  432 , and plug  246 , while Schottky diode  292  is formed by p-region  226 , barrier layers  430  and  432 , and plug  256 . 
     FIGS. 6A-6D show a series of graphs that illustrate the I/V relationships of diodes  290  and  292  when titanium silicide (TiSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 ,  224 , and  226 . FIGS. 7A-7D,  8 A- 8 D, and  9 A- 9 D each show a series of graphs that illustrate the I/V relationships of diodes  290  and  292  when cobalt silicide (CoSi 2 ) is formed over regions  212 ,  214 ,  216 ,  222 , and  226 . 
     It should be understood that various alternatives to the embodiment of the invention described herein may be employed in practicing the invention. Thus, it is intended that the following claims define the scope of the invention and that methods and structures within the scope of these claims and their equivalents be covered thereby.

Technology Category: 5