Patent Document

BACKGROUND OF THE INVENTION  
         [0001]    1. Technical Field  
           [0002]    The present invention relates to the area of semiconductors and semiconductor processing and more particularly to methods and structures that provide low dielectric constant interconnects for integrated circuits.  
           [0003]    2. Description of Related Art  
           [0004]    Interconnect structures of integrated circuits (ICs) generally take the form of patterned metallization lines that are used to electrically interconnect devices and to provide interconnection with external circuitry. By way of example, IC devices may include metal oxide semiconductor (“MOS”) devices having diffused source and drain regions separated by channel regions, and gates located over the channel regions. In practice, an IC chip may include thousands or millions of devices such as MOS transistors.  
           [0005]    Conventionally, a dielectric layer is deposited over the devices and via holes are formed through the dielectric layer to the devices below. After the via holes are etched through the dielectric layer, a metallization layer is deposited over the dielectric surface filling the via holes with metal vias. After the first metallization layer has been deposited, it is patterned to form interconnect metallization lines. AS is well known in the art, “patterning” may be accomplished by depositing a photoresist layer, selectively exposing the photoresist to light, developing the photoresist to form an etch mask, and etching the exposed metallization to pattern the metallization layer, and removing the etch mask. This process may then be repeated if additional layers of metallization lines are desired.  
           [0006]    As IC technology scales, the performance of ultra large scale integrated (ULSI) chips is increasingly limited by the capacitance of the interconnects. The capacitance of the interconnects contributes to RC delay, AC power (CV 2 f) dissipation, and cross-talk. The use of air-gaps formed between metal lines during SiO 2  deposition has been shown to reduce the capacitance of tightly spaced interconnects by as much as 40% compared to homogeneous SiO 2  (see Shieh, B. , et al.,  IEEE Electron Device Letters ., 19, no. 1, pp. 16-18.). This capacitance reduction is better than the reduction obtained using low-k materials such as polymers in a homogeneous scheme.  
           [0007]    However, significant problems exist with present methods of forming air-gaps between interconnects. Many existing methods are specific only to Al or AlCu interconnects (see U.S. Pat. No. 5,798,559 issued to Bothra et al.) or require the development of new backend processes (see U.S. Pat. Nos. 5,798,559 issued to Bothra et al. and 5,530,290 issued to Aitken et al.). Other methods of introducing air-gaps between interconnects are not compatible with chemical mechanical polishing (CMP) processes in multilevel interconnect systems because those methods can trap slurry in the gaps (see Shieh, B. P., et al., “Integration and Reliability Issues for Low Capacitance Air-Gap Interconnect Structures,” Proceedings of the International Interconnect Technology Conference, San Francisco, pp. 125-27, June 1998).  
           [0008]    Therefore, it would be advantageous to have a method of introducing air-gaps between interconnects that does not require the development of new backend processes, that is compatible with many types of interconnect metals, and is compatible with CMP processes in multilevel interconnect systems.  
         SUMMARY OF THE INVENTION  
         [0009]    The present invention provides a method of fabricating an integrated circuit having air-gaps between interconnect levels. in a preferred embodiment, an integrated circuit its partially fabricated. The partially fabricated integrated circuit includes a top layer, interconnect structures having a cladding layer, dielectric layers, and an etch stop layer resistant to certain first types of etchants. The top layer of the integrated circuit is etched with a second type of etchant. The dielectric layers are then etched with one of the first types of etchants until the etch stop layer is reached. Thus, portions of the interconnect structures are exposed to create interconnect islands surrounded by air. A cover is mechanically placed over the exposed interconnect islands to protect the integrated circuit from dust particles.  
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0010]    The novel features believed characteristic of the invention are set forth in the appended claims. The invention itself, however. as well as a preferred mode of use, further objectives and advantages thereof, will best be understood by reference to the following detailed description of an illustrative embodiment when read in conjunction with the accompanying drawings, wherein:  
         [0011]    [0011]FIG. 1 depicts an SOI CMOS device with cladded copper interconnects;  
         [0012]    FIGS.  2 A- 2 D depicts different phases of a dual-damascene process;  
         [0013]    [0013]FIG. 3 depicts a flow chart of a preferred embodiment of the present invention;  
         [0014]    FIGS.  4 A- 4 G depicts a SOI CMOS device, in cross sectional view, during various stages of the process for creating air-gaps in accordance with the present invention; and  
         [0015]    [0015]FIG. 5 depicts a mask view of a chip illustrating the placement of oxide supports.  
     
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT  
       [0016]    The processes, steps, and structures described below do not form a complete process flow for manufacturing integrated circuits. The present invention can be practiced in conjunction with integrated circuit fabrication techniques currently used in the art, and only so much of the commonly practiced process steps are included as necessary for an understanding of the present invention. The figures represent cross sections of a portion of an integrated circuit during fabrication and are not drawn to scale, but instead are drawn so as to illustrate important features of the invention.  
         [0017]    The present invention provides for the creation of air dielectric interconnections by post-processing standard CMOS wafers using advanced etching techniques popular in micromachining literature. However, the process may be applied to most interconnection systems for other devices such as bipolar transistors, bulk CMOS, and DRAM memory cells to name but a few. An example of a standard CMOS wafer is depicted in cross section view in FIG. 1. In this particular example, an SOI CMOS wafer  100  is depicted. Wafer  100  has a buried oxide layer  105  formed over a silicon substrate  102 . Silicon-on-insulator (“SOI”) transistors  107  and  109  have been formed in buried oxide layer  105  as shown. Local interconnections have been formed from layers of tungsten metallization  190 ,  191 ,  192 , and  193 . Dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  separated by thin silicon nitride layers  131 ,  132 ,  133 ,  134 ,  135 ,  136 ,  137 ,  138 ,  139 ,  140 ,  141 , and  142  have been formed over the SOI transistors  107  and  109 . Interconnects  151 ,  153 ,  155 ,  157 ,  159 , and  161  provide connections to various devices at different levels in the wafer  100 . A thick nitride layer  143  has been formed over dielectric layer  123 . A polyimide layer  145  covers thick nitride layer  143 . A C4 flip-chip solder  161  has been processed on the active substrate as shown. Typically flip-chip solder  161  is a lead/tin (“Pb/Sn”) solder over nickel (“Ni”) plated copper (“Cu”). However, various kinds of solders can be used depending on the Indium (“In”) and bismuth (“Bi”) content.  
         [0018]    In the present example, dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  are silicon oxide. However, other dielectrics may be used in place of silicon oxide as will be obvious to one skilled in the appropriate art. Examples of other dielectrics include but are not limited to fluorinated silicon dioxide, spun-on glass (“SOG”), and silicon dioxide/polymers.  
         [0019]    The interconnections  151 ,  153 ,  155 ,  157 ,  159 , and  161  in the present example are copper. However, other metals can be used for these interconnects as will be obvious to one skilled in the art. The copper interconnections  151 ,  153 ,  155 ,  157 ,  159 , and  161  include a cladding layer (not shown) that acts as a chemical barrier layer between the copper and the silicon oxide. Electrical connections  171  between interconnections  151 ,  153 ,  155 ,  157 ,  159  and  161  are typically constructed of the same material as interconnections  151 ,  153 ,  155 ,  157 ,  159 , and  161 , which in this case is copper. Thin silicon nitride layers  131 ,  132 ,  133 ,  134 ,  135 ,  136 ,  137 ,  138 ,  139 ,  140 ,  141 , and  142  have been formed as a result of the dual-damascene copper electroplating process, which is described in further detail below.  
         [0020]    For CMOS wafer  100  given as an example, interconnections  159  and  161  as well as dielectric layers  119 ,  120 ,  121 , and  122  are typically between 0.3 microns and 3 microns thick. Thin silicon nitride layers  131 ,  132 ,  133 ,  134 ,  135 ,  136 ,  137 ,  138 ,  139 ,  140 ,  141 , and  142  are typically around 0.1 microns thick. Silicon nitride layer  143  is typically about 0.3 microns thick. Polyimide layer  145  is typically about 3 microns thick. Dielectric layer  123  is typically around 0.5 microns thick. Metallization layers  151 ,  153 ,  155 , and  157  and dielectric layers  112 ,  113 ,  114 ,  115 ,  116 ,  117 , and  118  are typically around 0.5 microns thick. These dimensions are given merely as examples of appropriate thickness for the layers used in wafer  100  which is given merely as an example of a wafer. Other dimensions appropriate for other examples will be obvious to one skilled in the art.  
         [0021]    FIGS.  2 A- 2 D illustrate the dual-damascene copper electroplating process used in forming each of interconnections  151 ,  153 ,  155 ,  157 ,  159 , and  161  illustrated in FIG. 1. The dual-damascene copper electroplating process is merely exemplary of a process for forming interconnections and other processes for achieving the same result will be obvious to one skilled in the art. Furthermore, other conductors other than copper may be used. Copper is merely shown as an example.  
         [0022]    [0022]FIG. 2A shows a cross-section of a portion of a wafer with silicon nitride layers  211 ,  213 , and  215  separated by silicon oxide layers  221  and  223 . Line and via definition are etched into nitride layers  211 ,  213 , and  215  and oxide layers  221  and  223  as depicted in FIG. 2B. Barrier layer  231  and seed layer  233  are formed as depicted in FIG. 2C. Typical barrier layer  231  materials are TiN/Ti, Tantalum (“Ta”), or electroless Cobalt (“Co”). Typical seed layers  233  include thin sputtered copper (“Cu”) or chemical vapor deposition (“CVD”) Cu. More detail regarding the dual-damascene process is described in C.-K. Hu and J. M. E. Harper, “Copper Interconnections and Reliability,” Mater. Chem. Phys. vol. 52, pp. 5-12, 1998, which is hereby incorporated by reference. Finally, chemical mechanical polishing (“CMP”) is performed to planarize the surface of the interconnect. The result of the CMP is depicted in FIG. 2D.  
         [0023]    The process for post processing a CMOS wafer to produce air-gap dielectric interconnects will be illustrated with reference to FIG. 3, which shows a flow chart of a preferred embodiment of the present invention. After a CMOS wafer, such as wafer  100  depicted in FIG. 1, has been formed, the top polyimide layer  145  is etched out (step  310 ) using, for example, a plasma etch. FIG.  4 A depicts CMOS wafer  100  after this step. Next, the dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  are removed. In a preferred embodiment, the silicon oxide dielectric is removed (step  320 ) using a wet etching technique, such as a 49% HF etch or a CHF 3 /O 2  reactive-ion etch (“RIE”) for steep profiles. This etch removes the silicon oxide dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  from the desired areas and leaves behind copper interconnects  151 ,  153 ,  155 ,  157 ,  159 , and  161  supported by oxide islands  420 . Silicon nitride layers  131 ,  132 ,  133 ,  134 ,  135 ,  136 ,  137 ,  138 ,  139 ,  140 ,  141 , and  142  are used as an etch-stop such that the appropriate areas of the silicon oxide dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  are removed layer by layer. This results in controlled removal of the silicon oxide debris. Thus, FIG. 4B depicts CMOS wafer  100  after the thick nitride layer  143  has been removed. FIG. 4C depicts CMOS wafer  100  after selected portions of dielectric layers  123  and  122  have been removed. FIG. 4D depicts CMOS wafer  100  after selected portions of dielectric layers  120  and  119  have been removed. FIG. 4E depicts CMOS wafer  100  after selected portions of dielectric layers  118  and  117  have been removed.  
         [0024]    The placement of the oxide layer is important in design because the island supports have to guarantee structural stability and be small in size. For example, the islands can be introduced at a pitch of 10 microns if the size of the oxide islands is 2 microns. This results in a dielectric constant reduction from the silicon oxide dielectric by a factor of 2.5, i.e., effective dielectric constant of 1.6. This reduction is much larger than methods introducing advanced low-k dielectrics that reduce the dielectric constant from 3.9 to 3.0.  
         [0025]    If the copper cladding material is stable to air (step  330 ), then a separate low-k dielectric sheet cover can be introduced over the oxide islands  420  to protect the chip against dust particles or permit the use of underfills in a flip-chip process (step  360 ).  
         [0026]    If the cladding material (copper cladding material in this example) is not stable to air, then the interconnects  151 ,  153 ,  155 ,  157 ,  159 , and  161  can be etched (step  340 ), preferably using sulfuric acid, to produce a clean standardized surface. In the present example, etching the copper cladding material with 10% sulfuric acid plate will produce a clean standardized surface. This clean surface can then be coated with a thin layer of material that is stable in air (step  350 ). In the present example, a thin layer of nickel (“Ni”)  415  has been applied to the clean standardized surfaces by electroplating. FIG. 4F depicts CMOS wafer  100  after the layer of nickel  415  has been applied. By introducing this thin layer of material that is stable in air, the long-term reliability of the exposed interconnects will be increased. Following this coating, the low-k dielectric sheet cover is mechanically introduced over the islands to protect the chip (step  360 ).  
         [0027]    Wafer  100 , after post-processing to produce air-gaps, is depicted in a cross-sectional view in FIG. 4G. The silicon oxide dielectric has been replaced, in selected areas, by air  410 . Cladded copper interconnects  151 ,  153 ,  155 ,  157 ,  159 , and  161  have been coated with a nickel plating  415  wherever the interconnects  151 ,  153 ,  155 ,  157 ,  159 , and  161  would be exposed to the air  410 . Other materials which could be used in place of nickel plating  415  include but are not limited to cobalt (“Co”) or platinum (“Pt”) or any refractory material such as Tungsten (“W”), Niobium (“Nb”) or Tantalum (“Ta”). Selected portions of the dielectric layers  111 ,  112 ,  113 ,  114 ,  115 ,  116 ,  117 ,  118 ,  119 ,  120 ,  121 ,  122  and  123  remain as dielectric supports  420  to support the interconnect islands  425 . A low-k dielectric cover  430  lies over the islands to cover and protect wafer  100 .  
         [0028]    [0028]FIG. 5 depicts a mask view of wafer  100 . By reference to FIG. 5, the orientation of the dielectric supports  420  in relation to the interconnects can more readily be appreciated and understood. For clarity and illustration purposes, only certain aspects of wafer  100  are depicted in this view. Interconnects  159  and  161  are shown with dielectric supports  420 . Via connections  510  are also shown. The effective dielectric constant is determined by the pitch of the support structures  420 . Speed-critical paths may be selectively tailored.  
         [0029]    Although the present invention has been illustrated primarily with reference to an SOI CMOS wafer, the present invention may be applied to various semiconductor devices on other types of substrates containing interconnects as will be apparent to one skilled in the art. Such devices include but are not limited to bipolar devices, bulk transistor devices, and memory chips such as DRAMs. The processes of the present invention also may be applied to other substrates other than SOI substrates, such as, for example, silicon substrates, silicon on sapphire (SOS) substrates, and gallium arsenide substrates. Furthermore, the present invention has been illustrated by way of example with reference to silicon oxide dielectrics and silicon nitride etch stop layers. However, the present invention is applicable to other dielectrics and etch stops as will be readily apparent to one skilled in the art. Additionally, materials other than copper may be used as the interconnect material. The only requirement for the interconnect material being that it be conductive to electricity. Also, materials other than nickel may be used as the coating for the cladding material. All of these modifications will be readily apparent to one skilled in the art and are, accordingly, part of the scope of the present invention.  
         [0030]    The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art. The embodiment was chosen and described in order to best explain the principles of the invention, the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated.

Technology Category: h