Source: https://patents.google.com/patent/US9966512B2/en
Timestamp: 2019-11-20 21:00:54
Document Index: 312735034

Matched Legal Cases: ['§ 371', 'Application No. 09160613', 'Application No. 09160613', 'Application No. 2011151606', 'Application No. 2012', 'Application No. 201080021909', 'Application No. 201080021909', 'Application No. 10', 'Application No. 2012', 'Application No. 10726270', 'Application No. 10726270', 'Application No. 201080021909']

US9966512B2 - Light scattering and conversion plate for LEDs - Google Patents
Light scattering and conversion plate for LEDs Download PDF
US9966512B2
US9966512B2 US15/337,435 US201615337435A US9966512B2 US 9966512 B2 US9966512 B2 US 9966512B2 US 201615337435 A US201615337435 A US 201615337435A US 9966512 B2 US9966512 B2 US 9966512B2
US15/337,435
US20170047491A1 (en
2009-05-19 Priority to EP09160613.7 priority Critical
2009-05-19 Priority to EP09160613 priority
2010-05-17 Priority to PCT/IB2010/052167 priority patent/WO2010134011A2/en
2011-11-16 Priority to US201113320803A priority
2014-03-25 Priority to US14/224,120 priority patent/US9482411B2/en
2016-10-28 Priority to US15/337,435 priority patent/US9966512B2/en
2016-10-28 Application filed by Koninklijke Philips NV filed Critical Koninklijke Philips NV
2017-02-16 Publication of US20170047491A1 publication Critical patent/US20170047491A1/en
2018-03-09 Assigned to KONINKLIJKE PHILIPS N.V. reassignment KONINKLIJKE PHILIPS N.V. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KONINKLIJKE PHILIPS ELECTRONICS N V
2018-03-14 Assigned to LUMILEDS LLC reassignment LUMILEDS LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KONINKLIJKE PHILIPS N.V.
2018-05-08 Publication of US9966512B2 publication Critical patent/US9966512B2/en
238000000149 argon plasma sintering Methods 0 abstract claims description title 23
229910009491 Y3Al5O12 Inorganic materials 0 claims description 2
The invention relates to an illumination system having a light scattering and conversion plate comprising a non-converting but scattering layer and a thinner converting layer. By separating scattering and conversion, the characteristics of the illumination system can greatly be increased.
The present application is a continuation of U.S. patent application Ser. No. 14/224,120 filed on Mar. 25, 2014, titled “LIGHT SCATTERING AND CONVERSION PLATE FOR LEDS”, issuing as U.S. Pat. No. 9,482,411 on Nov. 1, 2016, which is a continuation of U.S. patent application Ser. No. 13/320,803 filed on Nov. 16, 2011, issued as U.S. Pat. No. 8,721,098 on May 13, 2014, which is a § 371 application of International Application No. PCT/IB2010/052167 filed on May 17, 2010, which claims priority to European Patent Application No. 09160613.7 filed on May 19, 2009. U.S. patent application Ser. Nos. 14/224,120 and 13/320,803, International Application No. PCT/IB2010/052167, and European Patent Application No. 09160613.7 are incorporated herein.
The present invention is directed to novel luminescent materials and compounds for light emitting devices, especially to the field of LEDs
In recent years, several new techniques and setups have been developed for LEDs, amongst them the introduction of ceramic converter plates and layers. In this regard, reference is made e.g. to the US 2004/0145308 which is incorporated by reference.
However, there is still the continuing need for converter plates and layers which show good emitting and scattering properties.
This object is solved by an illumination system according to claim 1 of the present invention. Accordingly, an illumination system is proposed comprising at least one light scattering and conversion plate comprising
a) a first layer having scattering properties and no conversion properties and
b) a second layer having conversion properties
whereby the thickness A of the first layer and the thickness B of the second layer match
A≥3*B
Preferably A and B match A≥4*B, more preferred A≥7*B.
The term “layer” and/or “plate” especially mean and/or include an object which extends in one dimension (i.e. the height) to ≤40%, more preferred ≤20% and most preferred ≤10% than in any of the other dimensions (i.e. width and length).
The term “scattering” especially means and/or includes the change of the propagation direction of light.
The term “converting” especially means and/or includes the physical process of absorption of light and emitting of light in another wavelength area, e.g. due to radiative transitions that involve at least one ground state and at least one excited state and that may be described with a configurational coordinate diagram showing the potential energy curves of absorbing and emitting centers as a function of the configurational coordinate.
The term “no conversion properties” especially means and/or includes that ≥95%, more preferred ≥97%, more preferred ≥98% and most preferred ≥99% of all transmitted light passes the plate without being converted.
The surprising result of one of the basic ideas underlying the present invention, i.e. separating scattering and converting is that for most application both a good forward emission together with an angular stability of the emission profile can be found.
The overall setup of the illumination system can be kept simple and small
The lifetime of the illumination system is considerably extended because of improved heat dissipation properties and improved chemical stability
additional functional layers can be applied on one layer only eliminating the risk of damaging the more expensive other layer.
According to a preferred embodiment, the second layer is in the optical path in between the primary light source and the first layer.
The primary light source will in most applications be a blue LED; however, any devices known in the field to the skilled person in the art may be used.
According to a preferred embodiment, the first and/or second layer are essentially made out of a ceramic material.
The term “essentially” in the sense of the present invention especially means ≥90 (wt.)-%, more preferably ≥95 (wt.)-%, yet more preferably ≥98 (wt.)-% and most preferred ≥99 (wt.)-%.
According to a preferred embodiment, the ceramic material has a volume of ≥0.005 mm3 to ≤8 mm3, more preferred ≥0.03 mm3 to ≤1 mm3 and most preferred ≥0.08 mm3 to ≤0.18 mm3.
According to a preferred embodiment, the ceramic material has a density of ≥90% and ≤100% of the theoretical density. This has been shown to be advantageous for a wide range of applications within the present invention since then the luminescent properties of the at least one ceramic material may be increased.
More preferably the ceramic material has a density of ≥97% and ≤100% of the theoretical density, yet more preferred ≥98% and ≤100%, even more preferred ≥98.5% and ≤100% and most preferred ≥99.0% and ≤100%.
According to a preferred embodiment of the present invention, the surface roughness RMS (disruption of the planarity of a surface; measured as the geometric mean of the difference between highest and deepest surface features) of the surface(s) of the ceramic material is ≥0.001 μm and ≤1 μm.
According to an embodiment of the present invention, the surface roughness of the surface(s) of the at least one ceramic material is ≥0.005 μm and ≤0.8 μm, according to an embodiment of the present invention ≥0.01 μm and ≤0.5 μm, according to an embodiment of the present invention ≥0.02 μm and ≤0.2 μm and according to an embodiment of the present invention ≥0.03 μm and ≤0.15 μm.
According to a preferred embodiment of the present invention, the specific surface area of the ceramic material is ≥10−7 m2/g and ≤0.1 m2/g.
According to a preferred embodiment, the thickness B of the second layer is ≥5 μm and ≤80 μm. This has been shown to be advantageous for many applications within the present invention since by doing so the packing efficiency and side emission of the light scattering and conversion plate may greatly be increased and reduced, respectively.
Preferably the thickness B of the second layer is ≥10 μm and ≤50 μm.
According to a preferred embodiment, the thickness A of the first layer is ≥50 μm and ≤1000 μm. This has been shown to be advantageous, since by doing so, for many applications, the scattering features and the uniformity of the light emitting profile of the light scattering and conversion plate may greatly be increased.
Preferably the thickness A of the first layer is ≥100 μm and ≤300 μm.
According to a preferred embodiment, the scattering coefficient of the first layer is >0 and ≤1000 cm−1.
The scattering coefficient s is determined by measurement of the reflectance R0 and/or the transmittance T0 of a thin layer with thickness A according to the equations:
sA = 1 b ⁢ Arc ⁢ ⁢ tgh ⁡ ( 1 - kR 0 bR 0 ) sA - 1 b ⁢ ( Ar ⁢ sinh ⁢ b T 0 - Ar ⁢ sinh ⁢ b ) With ⁢ ⁢ b = k 2 - 1 ⁢ ⁢ and ⁢ ⁢ k = s + a s
(a is the absorption coefficient of the layer)
In case of a=0 equations simplify to
sA = R 0 1 - R 0 sA = 1 - T 0 T 0
Preferably the scattering coefficient of the first layer is ≥100 and ≤500 cm−1.
According to a preferred embodiment, the mean refractive index n of the first layer is ≥1.3 and ≤2.5.
According to a preferred embodiment, the difference Δn in refractive index between the refractive index of the first layer and the second layer is ≥0.03 and ≤1. This has been shown to be advantageous for mixing the light from the primary light source and the converted light from the second layer for many applications. Preferably Δn is ≥0.3 and ≤0.5.
According to a preferred embodiment, the first layer is essentially made out of a material selected from the group comprising glass, Al2O3, Y3Al5O12, RE3Al5O12 (RE=rare earth metal), Y2O3, ZnS, AlON, AlPON, AlN, MgAl2O4, SiC, SiO2, Si3N4 or mixtures thereof.
According to a preferred embodiment, the second layer is essentially made out of a material selected from the group comprising LubYcGddCeeAl5O12 with b+c+d+e=3, 0.09≤e≤0.24, Ca1−x−y−z−0.5uMxSi1+u−v−zAl1−u+v+zN3−vOv:Euy,Cez with 0≤u<0.2, 0<v<0.05, 0≤x<1, 0.001≤y≤0.01, 0.002≤y≤0.04, and M=Sr, Ba, Mg or mixtures thereof.
According to a preferred embodiment, the plate comprises a third layer provided in between the first and second layer and essentially made out of an adhesive material, preferably a silicone glue.
This invention furthermore relates to method of producing a light scattering and conversion plate comprising the steps of
a) Providing a first and second layer, whereby the thickness of the second layer is larger than desired
b) Connecting the first and second layer, optionally by use of a third layer provided in between the first and second layer and essentially made out of an adhesive material
c) Mechanically reducing the thickness of the second layer, e.g. by grinding
By doing so, it has been shown for many applications that a light scattering and conversion plate according to the present invention can be made easily and effectfully even for small thicknesses of the second layer.
An illumination system according to the present invention may be of use in a broad variety of systems and/or applications, amongst them one or more of the following:
FIG. 1 shows a very schematic setup of an illumination system according to one embodiment of the present invention.
FIG. 2 shows a detailed very schematic view of the light scattering and converting plate of FIG. 1
FIG. 3 shows a photograph of a detail of a light scattering and converting plate according to Example I of the present invention.
FIG. 4 shows a photograph of a detail of a light scattering and converting plate according to Example II of the present invention.
FIG. 5 shows the spatial radiation pattern of two LEDs according to Example I and II of the present invention and a comparative example
FIG. 6 shows the Emission spectra of the two LEDs according to Example I and II of the present invention and the comparative example; and
FIG. 7 shows a CIE 1931 Chromaticity chart showing the Planckian locus of the two LEDs according to Example I and II of the present invention and the comparative example
FIG. 1 shows a very schematic setup of an illumination system according to one embodiment of the present invention. Most of FIG. 1 is prior art and known to the skilled person and will therefore described only briefly. It is apparent that the illumination system of FIG. 1 is exemplarily only and the skilled person may use different parts or replace it at lib.
The illumination system 1 comprises a thin film chip blue LED 20 upon which a light scattering and converting plate 10 is provided; both are covered by a lens 30.
FIG. 2 shows a detailed very schematic view of the light scattering and converting plate of FIG. 1. The plate 10 comprises a first layer 12 (with a thickness A), a second layer 14 (with a thickness B) and in between a silicon glue layer 16. FIG. 2 is highly schematic and in most applications the actual dimensions will be much different. It is noted that the plate 10 is provided in the illumination system 1 so that the second layer 12 is in the optical path between the blue chip LED 20 and the second layer 14.
The invention will be further understood by the following Examples I and II which in a merely illustrative fashion shows several illumination systems of the present invention.
In the examples a Y2.88Ce0.012Al5O12 layer (i.e. the second layer 14) was ground from both sides from a 1.1 mm thick wafer after sintering to 300 μm thickness. Also a 1 mm thick polycrystalline Al2O3 layer (PCA, the first layer 12) with a mass density of 99.98 percent of the crystalline Al2O3 was ground to 150 μm. Then the first layer was coated with a Silicone layer (Shin Etsu KJR-9222A and KJR-9222A, mixing ratio 1:1), the second layer was attached and the silicone layer was hardened at a temperature of 100° C. for one hour and cured at 150° C. for 2 hours.
After the gluing, the second layer 14 was further ground to a thickness of 17 (Example I) and 30 μm (Example II), respectively.
Then both plates were diced to 0.99×0.99 mm2, mount on a blue TFFC LED emitting at about 450 nm and lensed. LED packaging was done in the same was as for Lumiramic phosphor converted LEDs.
Furthermore, a comparative Example I was made in analogy to the inventive Examples. In this comparative example, the second layer was set to a thickness of 120 μm and made out of Y2.842Gd0.15Ce0.008Al5O12 (i.e. a lower Cerium-Content to match the higher thickness)
FIG. 3 shows a photograph of a detail of a light scattering and converting plate according to Example I of the present invention. The light scattering and converting plate has an overall thickness of about 205 μm, whereby the first layer is about 140 μm thick, the second layer about 30 μm and the silicon layer about 35 μm.
FIG. 4 shows a photograph of a detail of a light scattering and converting plate according to Example II of the present invention. By chance, the light scattering and converting plate has also an overall thickness of about 205 μm; however, here the first layer is about 146 μm thick, the second layer about 17 μm and the silicon layer about 42 μm.
FIG. 5 shows the spatial radiation pattern of the two LEDs according to Example I and II of the present invention and a comparative example. Due to emission from the faces of the Lumiramic converter plate of the comparative example the radiative flux under large emission angle is higher compared to the flux under large angles emitted by LEDs with converter plates of Example I and Example II of the present invention.
FIG. 6 shows the Emission spectra of the two LEDs according to Example I and II of the present invention and the comparative example. For the comparative example (120 μm) the total conversion strength is low and the peak of the emitted blue light is much larger than the maximum of the converted light. For the 30 μm Example both peaks are about equal, which shows the high efficacy of the light scattering and conversion plate.
FIG. 7 shows a CIE 1931 Chromaticity chart showing the Planckian locus and the color points of the two LEDs according to the Example I and II of the present invention and the comparative example. It can be seen that due to the inventive scattering and light emitting plate a low color temperature of about 4000K has been realized with the 30 μm Example, whereas only a small change in size of the conversion layer 12 (i.e. to 17 μm) leads to a dramatic increase of color temperature to about 10000K. Variation of thickness and Cerium concentration gives access to white LED production of a color temperature ranging from above 10 000K to 4000K and below.
The particular combinations of elements and features in the above detailed embodiments are exemplary only; the interchanging and substitution of these teachings with other teachings in this and the patents/applications incorporated by reference are also expressly contemplated. As those skilled in the art will recognize, variations, modifications, and other implementations of what is described herein can occur to those of ordinary skill in the art without departing from the spirit and the scope of the invention as claimed. Accordingly, the foregoing description is by way of example only and is not intended as limiting. In the claims, the word “comprising” does not exclude other elements or steps, and the indefinite article “a” or “an” does not exclude a plurality. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage. The invention's scope is defined in the following claims and the equivalents thereto. Furthermore, reference signs used in the description and claims do not limit the scope of the invention as claimed.
a light scattering and conversion plate disposed in a path of light emitted by the light emitting diode, the light scattering and conversion plate comprising:
a first layer having scattering properties and essentially no conversion properties and having a thickness A; and
a second layer having conversion properties and having a thickness B, the thickness A of the first layer being greater or equal to three times the thickness B of the second layer; and
a lens disposed over the light scattering and conversion plate.
2. The device of claim 1 wherein the light emitting diode is a blue-emitting, thin film flip chip light emitting diode.
3. The device of claim 1 wherein the first layer is polycrystalline Al2O3.
4. The device of claim 1 wherein the second layer is a garnet comprising Y, Al, and O.
5. The device of claim 1 wherein the second layer is a ceramic.
6. The device of claim 1 wherein the first and second layer are connected by a silicone layer.
7. A device comprising a light scattering and conversion plate comprising:
a first layer having scattering properties and essentially no conversion properties and having a thickness A, the first layer selected from the group consisting of glass, Al2O3, Y3Al5O12, RE3Al5O12 (RE=rare earth metal), Y2O3, ZnS, AlON, AlPON, AlN, MgAl2O4, SiC, SiO2, Si3N4 and mixtures thereof; and
a second layer having conversion properties and having a thickness B, the thickness A of the first layer being greater or equal to three times the thickness B of the second layer.
8. The device of claim 7 wherein the second layer is LubYcGddCeeAl5O12 wherein b+c+d+e=3, 0.09≤e≤0.24.
9. The device of claim 7 wherein the second layer is Ca1−x−y−z−0.5uMxSi1+u−v−zAl1−u+v+zN3−vOv:Euy,Cez wherein 0≤u<0.2, 0<v<0.05, 0≤x<1, 0.001≤y≤0.01, 0.002≤y≤0.04, and M=Sr, Ba, Mg.
10. The device of claim 7 further comprising an adhesive disposed between the first and second layers.
11. The device of claim 7 wherein a scattering coefficient of the first layer is ≥100 and ≤500 cm−1.
12. The device of claim 7 wherein a mean refractive index n of the first layer is ≥1.3 and ≤2.5.
13. The device of claim 7 wherein a difference in refractive index between the refractive index of the first layer and the second layer is ≥0.03 and ≤1.
14. A device comprising a light scattering and conversion plate comprising:
a second layer having conversion properties and having a thickness B, the second layer selected from the group consisting of LubYcGddCeeAl5O12 wherein b+c+d+e=3, 0.09≤e≤0.24, Ca1−x−y−z−0.5uMxSi1+u−v−zAl1−u+v+zN3−vOv:Euy,Cez wherein 0≤u<0.2, 0<v<0.05, 0≤x<1, 0.001≤y≤0.01, 0.002≤y≤0.04, and M=Sr, Ba, Mg; and mixtures thereof;
wherein the thickness A of the first layer is greater or equal to three times the thickness B of the second layer.
15. The device of claim 14 wherein the second layer is a ceramic.
16. The device of claim 14 wherein the second layer has a volume density larger than 90 percent of a main constituent, the main constituent consisting of more than 80 percent of single crystal domains, with each domain being larger than 0.5 μm in diameter and having different crystallographic orientations.
17. The device of claim 16 wherein the single crystal domains are connected by one of amorphous material, glassy material, and additional crystalline constituents.
18. The device of claim 14 wherein the second layer is a ceramic having a surface roughness ≥0.005 μm and ≤0.8 μm.
US15/337,435 2009-05-19 2016-10-28 Light scattering and conversion plate for LEDs Active US9966512B2 (en)
EP09160613.7 2009-05-19
EP09160613 2009-05-19
PCT/IB2010/052167 WO2010134011A2 (en) 2009-05-19 2010-05-17 Light scattering and conversion plate for leds
US201113320803A true 2011-11-16 2011-11-16
US14/224,120 US9482411B2 (en) 2009-05-19 2014-03-25 Light scattering and conversion plate for LEDs
US15/337,435 US9966512B2 (en) 2009-05-19 2016-10-28 Light scattering and conversion plate for LEDs
US14/224,120 Continuation US9482411B2 (en) 2009-05-19 2014-03-25 Light scattering and conversion plate for LEDs
US20170047491A1 US20170047491A1 (en) 2017-02-16
US9966512B2 true US9966512B2 (en) 2018-05-08
ID=42983411
US13/320,803 Active 2031-05-08 US8721098B2 (en) 2009-05-19 2010-05-17 Light scattering and conversion plate for LEDs
US14/224,120 Active 2031-01-10 US9482411B2 (en) 2009-05-19 2014-03-25 Light scattering and conversion plate for LEDs
US15/337,435 Active US9966512B2 (en) 2009-05-19 2016-10-28 Light scattering and conversion plate for LEDs
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