Source: https://patents.google.com/patent/WO2011100716A2/en
Timestamp: 2018-10-15 17:20:44
Document Index: 260110441

Matched Legal Cases: ['Application No. 12', 'Application No. 12', 'Application No. 12', 'Application No. 12', 'Application No. 61', 'Application No. 61', 'Application No. 12', 'Application No. 61', 'Application No. 61', 'Application No. 61']

WO2011100716A2 - Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods - Google Patents
WO2011100716A2
WO2011100716A2 PCT/US2011/024796 US2011024796W WO2011100716A2 WO 2011100716 A2 WO2011100716 A2 WO 2011100716A2 US 2011024796 W US2011024796 W US 2011024796W WO 2011100716 A2 WO2011100716 A2 WO 2011100716A2
PCT/US2011/024796
WO2011100716A3 (en )
REACTORS FOR CONDUCTING THERMOCHEMICAL PROCESSES WITH SOLAR HEAT INPUT, AND ASSOCIATED
CROSS-REFERENCE TO RELATED APPLICATIONS [0001] The present application claims priority to pending U.S. Provisional Application 61/304,403, filed February 13, 2010 and incorporated herein by reference. To the extent the foregoing application and/or any other materials incorporated herein by reference conflict with the disclosure presented herein, the disclosure herein controls. TECHNICAL FIELD
[0002] The present technology is directed generally to reactors for conducting thermochemical processes with solar heat input, and associated systems and methods. In particular embodiments, such reactors can be used to produce clean- burning, hydrogen-based fuels from a wide variety of feedstocks, and can produce structural building blocks from carbon and/or other elements that are released when forming the hydrogen-based fuels.
[0003] Renewable energy sources such as solar, wind, wave, falling water, and biomass-based sources have tremendous potential as significant energy sources, but currently suffer from a variety of problems that prohibit widespread adoption. For example, using renewable energy sources in the production of electricity is dependent on the availability of the sources, which can be intermittent. Solar energy is limited by the sun's availability (i.e., daytime only), wind energy is limited by the variability of wind, falling water energy is limited by droughts, and biomass energy is limited by seasonal variances, among other things. As a result of these and other factors, much of the energy from renewable sources, captured or not captured, tends to be wasted. [0004] The foregoing inefficiencies associated with capturing and saving energy limit the growth of renewable energy sources into viable energy providers for many regions of the world, because they often lead to high costs of producing energy. Thus, the world continues to rely on oil and other fossil fuels as major energy sources because, at least in part, government subsidies and other programs supporting technology developments associated with fossil fuels make it deceptively convenient and seemingly inexpensive to use such fuels. At the same time, the replacement cost for the expended resources, and the costs of environment degradation, health impacts, and other by-products of fossil fuel use are not included in the purchase price of the energy resulting from these fuels.
[0005] In light of the foregoing and other drawbacks currently associated with sustainably producing renewable resources, there remains a need for improving the efficiencies and commercial viabilities of producing products and fuels with such resources BRIEF DESCRIPTION OF THE DRAWINGS
[0006] Figure 1 is a partially schematic, partial cross-sectional illustration of a system having a solar concentrator configured in accordance with an embodiment of the present technology.
[0007] Figure 2 is a partially schematic, partial cross-sectional illustration of an embodiment of the system shown in Figure 1 with the solar concentrator configured to emit energy in a cooling process, in accordance with an embodiment of the disclosure.
[0008] Figure 3 is a partially schematic, partial cross-sectional illustration of a system having a movable solar concentrator dish in accordance with an embodiment of the disclosure.
[0009] Figure 4 is a partially schematic, isometric illustration of a system having a trough-shaped solar concentrator in accordance with an embodiment of the disclosure.
[0010] Figure 5 is a partially schematic illustration of a system having a Fresnel lens concentrator in accordance with an embodiment of the disclosure. [0011] Figure 6 is a partially schematic illustration of a reactor having a radiation control structure and redirection components configured in accordance with an embodiment of the present technology.
[0012] Several examples of devices, systems and methods for conducting reactions driven by solar energy are described below. Reactors in accordance with particular embodiments can collect solar energy during one phase of operation and use the collection device to reject heat during another phase of operation. Such reactors can be used to produce hydrogen fuels and/or other useful end products. Accordingly, the reactors can produce clean-burning fuel and can re-purpose carbon and/or other constituents for use in durable goods, including polymers and carbon composites. Although the following description provides many specific details of the following examples in a manner sufficient to enable a person skilled in the relevant art to practice, make and use them, several of the details and advantages described below may not be necessary to practice certain examples of the technology. Additionally, the technology may include other examples that are within the scope of the claims but are not described here in detail.
[0013] References throughout this specification to "one example," "an example," "one embodiment" or "an embodiment" mean that a particular feature, structure, process or characteristic described in connection with the example is included in at least one example of the present technology. Thus, the occurrences of the phrases "in one example," "in an example," "one embodiment" or "an embodiment" in various places throughout this specification are not necessarily all referring to the same example. Furthermore, the particular features, structures, routines, steps or characteristics may be combined in any suitable manner in one or more examples of the technology. The headings provided herein are for convenience only and are not intended to limit or interpret the scope or meaning of the claimed technology. [0014] Certain embodiments of the technology described below may take the form of computer-executable instructions, including routines executed by a programmable computer or controller. Those skilled in the relevant art will appreciate that the technology can be practiced on computer or controller systems other than those shown and described below. The technology can be embodied in a special-purpose computer, controller, or data processor that is specifically programmed, configured or constructed to perform one or more of the computer- executable instructions described below. Accordingly, the terms "computer" and "controller" as generally used herein refer to any data processor and can include internet appliances, hand-held devices, multi-processor systems, programmable consumer electronics, network computers, mini-computers, and the like. The technology can also be practiced in distributed environments where tasks or modules are performed by remote processing devices that are linked through a communications network. Aspects of the technology described below may be stored or distributed on computer-readable media, including magnetic or optically readable or removable computer discs as well as media distributed electronically over networks. In particular embodiments, data structures and transmissions of data particular to aspects of the technology are also encompassed within the scope of the present technology. The present technology encompasses both methods of programming computer-readable media to perform particular steps, as well as executing the steps. [0015] A reactor system in accordance with a particular embodiment includes a reactor having a reaction zone, a reactant source coupled in fluid communication with the reaction zone, and a solar collector having a least one concentrator surface positionable to direct solar energy to a focal area. The system can further include an actuator coupled to the solar concentrator to move the solar concentrator relative to the sun, and a controller operatively coupled to the actuator to control its operation. The controller can be programmed with instructions that, when executed, direct the actuator to position the solar concentrator to focus the solar energy on the reaction zone when the solar energy is above a threshold level (e.g. during the day). When the solar energy is below the threshold level, the controller can direct the actuator to position the solar concentrator to point to a location in the sky having relatively little radiant energy to cool an object positioned at the focal area. [0016] A system in accordance with another embodiment of the technology includes a reactor, a reactant source, a solar concentrator, and a first actuator coupled to the solar concentrator to move the solar concentrator relative to the sun. The system can further include a radiation control structure positioned between a concentrator surface of the solar concentrator and its associated focal area. The radiation control structure has first surface and a second surface facing away from the first surface, each with a different absorptivity and emissivity. In particular, the first surface can have a first radiant energy absorptivity and a first radiant energy emissivity, and the second surface can have a second radiant energy absorptivity less than the first radiant energy absorptivity, and a second radiant energy emissivity greater than the first radiant energy emissivity. The system can further include a second actuator coupled to the radiation control structure to change the structure from a first configuration in which the first surface faces toward the concentrator surface, and a second configuration in which the second surface faces toward the concentrator surface. In particular embodiments, the system can still further include a controller that directs the operation of the radiation control structure depending upon the level of solar energy directed by the solar concentrator.
[0017] A method in accordance with a particular embodiment of the technology includes concentrating solar energy with a solar concentrator, directing the concentrated solar energy to a reaction zone positioned at a focal area of the solar concentrator, and at the reaction zone, dissociating a hydrogen donor into dissociation products via the concentrated solar energy. From the dissociation products, the method can further include providing at least one of a structural building block (based on at least one of carbon, nitrogen, boron, silicon sulfur, and a transition metal) and hydrogen-based fuel. In further particular embodiments, the method can further include taking different actions depending upon whether the solar energy is above or below a threshold level. For example, when the solar energy is above a threshold level, it can be directed to the reaction zone, and when it is below the threshold level, the solar concentrator can be pointed away from the sun to a location in the sky having relatively little radiative energy to cool the structural building block and/or the hydrogen based fuel. 2. Representative Reactors and Associated Methodologies
[0018] Figure 1 is a partially schematic, partial cross-sectional illustration of a system 100 having a reactor 110 coupled to a solar concentrator 120 in accordance with the particular embodiment of the technology. In one aspect of this embodiment, the solar concentrator 120 includes a dish 121 mounted to pedestal 122. The dish 121 can include a concentrator surface 123 that receives incident solar energy 126, and directs the solar energy as focused solar energy 127 toward a focal area 124. The dish 21 can be coupled to a concentrator actuator 125 that moves the dish 121 about at least two orthogonal axes in order to efficiently focus the solar energy 126 as the earth rotates. As will be described in further detail below, the concentrator actuator 125 can also be configured to deliberately position the dish 121 to face away from the sun during a cooling operation.
[0019] The reactor 1 10 can include one or more reaction zones 1 1 1 , shown in Figure 1 as a first reaction zone 111a and second reaction zone 111 b. In a particular embodiment, the first reaction zone 11 1a is positioned at the focal area 124 to receive the focused solar energy 127 and facilitate a dissociation reaction or other endothermic reaction. Accordingly, the system 100 can further include a distribution/collection system 140 that provides reactants to the reactor 1 10 and collects products received from the reactor 1 10. In one aspect of this embodiment, the distribution/collection system 140 includes a reactant source 141 that directs a reactant to the first reaction zone 1 1 1a, and one or more product collectors 142 (two are shown in Figure 1 as a first product collector 142a and a second product collector 142b) that collect products from the reactor 1 10. When the reactor 110 includes a single reaction zone (e.g. the first reaction zone 1 1 1a) the product collectors 142a, 142b can collect products directly from the first reaction zone 1 11 a. In another embodiment, intermediate products produced at the first reaction zone 1 1a are directed to the second reaction zone 1 1 1 b. At the second reaction zone 1 1b, the intermediate products can undergo an exothermic reaction, and the resulting products are then delivered to the product collectors 142a, 142b along a product flow path 154. For example, in a representative embodiment, the reactant source 141 can include methane and carbon dioxide, which are provided (e.g., in an individually controlled manner) to the first reaction zone 1 1 1a and heated to produce carbon monoxide and hydrogen. The carbon monoxide and hydrogen are then provided to the second reaction zone 1 1 1b to produce methanol in an exothermic reaction. Further details of this arrangement and associated heat transfer processes between the first reaction zone 111 a and second reaction zone 11 1 b are described in more detail in co-pending U.S. Application No. titled "REACTOR
VESSELS WITH PRESSURE AND HEAT TRANSFER FEATURES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS" (Attorney Docket No. 69545.8616US) filed concurrently herewith and incorporated herein by reference. [0020] In at least some instances, it is desirable to provide cooling to the reactor 10, in addition to the solar heating described above. For example, cooling can be used to remove heat produced by the exothermic reaction being conducted at the second reaction zone 1 1 1 b and thus allow the reaction to continue. When the product produced at the second reaction zone 1 1 1 b includes methanol, it may desirable to further cool the methanol to a liquid to provide for convenient storage and transportation. Accordingly, the system 100 can include features that facilitate using the concentrator surface 123 to cool components or constituents at the reactor 1 10. In a particular embodiment, the system 100 includes a first heat exchanger 150a operatively coupled to a heat exchanger actuator 151 b that moves the first heat exchanger 150a relative to the focal area 124. The first heat exchanger 150a can include a heat exchanger fluid that communicates thermally with the constituents in the reactor 1 10, but is in fluid isolation from these constituents to avoid contaminating the constituents and/or interfering with the reactions taking place in the reactor 1 10. The heat exchanger fluid travels around a heat exchanger fluid flow path 153 in a circuit from the first heat exchanger 150a to a second heat exchanger 150b and back. At the second heat exchanger 150b, the heat exchanger fluid receives heat from the product (e.g. methanol) produced by the reactor 110 as the product proceeds from the second reaction zone 111b to the distribution/collection system 140. The heat exchanger fluid flow path 153 delivers the heated heat exchanger fluid back to the first heat exchanger 150a for cooling. One or more strain relief features 152 in the heat exchanger fluid flow path 153 (e.g., coiled conduits) facilitate the movement of the first heat exchanger 150a. The system 100 can also include a controller 190 that receives input signals 191 from any of a variety of sensors, transducers, and/or other elements of the system 100, and, in response to information received from these elements, delivers control signals 192 to adjust operational parameters of the system 100.
[0021] Figure 2 illustrates one mechanism by which the heat exchanger fluid provided to the first heat exchanger 150a is cooled. In this embodiment, the controller 190 directs the heat exchanger actuator 151 to drive the first heat exchanger 150a from the position shown in Figure 1 to the focal area 124, as indicated by arrows A. In addition, the controller 190 can direct the concentrator actuator 125 to position the dish 121 so that the concentrator surface 123 points away from the sun and to an area of the sky having very little radiant energy. In general, this process can be completed at night, when it is easier to avoid the radiant energy of the sun and the local environment, but in at least some embodiments, this process can be conducted during the daytime as well. A radiant energy sensor 193 coupled to the controller 190 can detect when the incoming solar radiation passes below a threshold level, indicating a suitable time for positioning the first heat exchanger 150a in the location shown in Figure 2.
[0022] With the first heat exchanger 150a in the position shown in Figure 2, the hot heat transfer fluid in the heat exchanger 150a radiates emitted energy 128 that is collected by the dish 121 at the concentrator surface 123 and redirected outwardly as directed emitted energy 129. An insulator 130 positioned adjacent to the focal area 124 can prevent the radiant energy from being emitted in direction other than toward the concentrator surface 123. By positioning the concentrator surface 123 to point to a region in space having very little radiative energy, the region in space can operate as a heat sink, and can accordingly receive the directed emitted energy 129 rejected by the first heat exchanger 150a. The heat exchanger fluid, after being cooled at the first heat exchanger 150a returns to the second heat exchanger 150b to absorb more heat from the product flowing along the product flow path 154. Accordingly, the concentrator surface 123 can be used to cool as well as to heat elements of the reactor 1 10. [0023] In a particular embodiment, the first heat exchanger 150a is positioned as shown in Figure 1 during the day, and as positioned as shown in Figure 2 during the night. In other embodiments, multiple systems 100 can be coupled together, some with the corresponding first heat exchanger 150a positioned as shown in Figure 1 , and others with the first heat exchanger 150a positioned as shown in Figure 2, to provide simultaneous heating and cooling. In any of these embodiments, the cooling process can be used to liquefy methanol, and/or provide other functions. Such functions can include liquefying or solidifying other substances, e.g., carbon dioxide, ethanol, butanol or hydrogen.
[0024] In particular embodiments, the reactants delivered to the reactor 1 10 are selected to include hydrogen, which is dissociated from the other elements of the reactant (e.g. carbon, nitrogen, boron, silicon, a transition metal, and/or sulfur) to produce a hydrogen-based fuel (e.g. diatomic hydrogen) and a structural building block that can be further processed to produce durable goods. Such durable goods include graphite, graphene, and/or polymers, which may produced from carbon structural building blocks, and other suitable compounds formed from hydrogenous or other structural building blocks. Further details of suitable processes and products are disclosed in the following co-pending U.S. Patent Applications:
titled "CHEMICAL PROCESSES AND REACTORS FOR EFFICIENTLY
PRODUCING HYDROGEN FUELS AND STRUCTURAL MATERIALS, AND ASSOCIATED SYSTEMS AND METHODS" (Attorney Docket No. 69545.8601 US);
titled "ARCHITECTURAL CONSTRUCT HAVING FOR EXAMPLE A PLURALITY OF ARCHITECTURAL CRYSTALS" (Attorney Docket No.
69545.8701 US); and titled "CARBON-BASED DURABLE GOODS AND
RENEWABLE FUEL FROM BIOMASS WASTE DISSOCIATION" (Attorney Docket No. 69545.9002US), all of which are filed concurrently herewith and incorporated herein by reference. [0025] Figure 3 illustrates a system 300 having a reactor 310 with a movable dish 321 configured in accordance another embodiment of the disclosed technology. In a particular aspect of this embodiment, the reactor 310 includes a first reaction zone 311a and a second reaction zone 311 b, with the first reaction zone 311a receiving focused solar energy 127 when the dish 321 has a first position, shown in solid lines in Figure 3. The dish 321 is coupled to a dish actuator 331 that moves the dish 321 relative to the reaction zones 31 1 a, 31 1 b. Accordingly, during a second phase of operation, the controller 190 directs the dish actuator 331 to move the dish 321 to the second position shown in dashed lines in Figure 3. In one embodiment, this arrangement can be used to provide heat to the second reaction zone 311 b when the dish 321 is in the second position. In another embodiment, this arrangement can be used to cool the second reaction zone 31 1b. Accordingly, the controller 190 can direct the concentrator actuator 125 to point the dish 321 to a position in the sky having little or no radiant energy, thus allowing the second reaction zone 31 1 b to reject heat to the dish 321 and ultimately to space, in a manner generally similar to that described above with reference to Figures 1 and 2.
[0026] In other embodiments, the systems can include solar collectors having arrangements other than a dish arrangement. For example, Figure 4 illustrates a system 400 having a reactor 410 that is coupled to a solar concentrator 420 in the form of a trough 421. The trough 421 is rotated by one or more trough actuators 431 , and includes a concentrator surface 423 that directs incident solar energy 126 toward the reactor 410 for heating. In a particular embodiment shown in Figure 4, the reactor 410 can include a first reaction zone 411a and a second reaction zone 41 1 b that can operate in a manner generally similar to that described above with reference to Figures 1 and 2. The system 400 can further include a first heat exchanger 450a that can be moved toward or away from a focal area 424 provided by the trough 421 at the underside of the reactor 410. Accordingly, the first heat exchanger 450a can be positioned as shown Figure 4 when the incident solar energy 126 is directed to the first reaction 41 1 a for heating, and can be moved over the focal area 424 (as indicated by arrows A) to reject heat in a manner generally similar to that described above with respect to Figures 1 and 2. The reactor 410 can include an insulator 430 positioned to prevent heat losses from the reactor 410 during heating. The insulator 430 can also prevent heat from leaving the reactor 410 other than along the emitted energy path 128, in manner generally similar to that described above.
[0027] Figure 5 is a partially schematic illustration of a system 500 that includes a solar concentrator 520 having a Fresnel lens 521 positioned to receive incident solar energy 126 and deliver focused solar energy 127 to a reactor 510. This arrangement can be used in conjunction with any of the systems and components described above for heating and/or cooling constituents and/or components of the reactor 510.
[0028] Figure 6 is partially schematic illustration of a system 600 having a reactor 610 that receives radiation in accordance with still further embodiments of the disclosed technology. In one aspect of these embodiments, the reactor 610 can have an overall layout generally similar to that described above with reference to Figures 1 and 2. In other embodiments, the reactor can be configured like those shown in any of Figures 3-5, with the components described below operating in a generally similar manner. [0029] The reactor 610 can include a transmissive component 612 that allows focused solar energy 127 to enter a first reaction zone 61 1a. In one embodiment, the transmissive component 112 includes glass or another material that is highly transparent to solar radiation. In another embodiment, the transmissive component 612 can include one or more elements that absorb energy (e.g., radiant energy) at one wavelength and re-radiate energy at another wavelength. For example, the transmissive component 612 can include a first surface 613a that receives incident solar energy at one wavelength and a second surface 613b that re-radiates the energy at another wavelength into the first reaction zone 61 1 a. In this manner, the energy provided to the first reaction zone 611 a can be specifically tailored to match or approximate the absorption characteristics of the reactants and/or products placed within the first reaction zone 61 1a. For example, the first and second surfaces 613a, 613b can be configured to receive radiation over a first spectrum having a first peak wavelength range and re-radiate the radiation into the first reaction zone 61 1a over a second spectrum having a second peak wavelength range different than the first. The second peak wavelength range can, in particular embodiments be closer than the first to the peak absorption of a reactant or product in the first reaction zone 61 1 a. Further details of representative re-radiation devices are described in co-pending U.S. Patent Application No. titled "CHEMICAL
REACTORS WITH RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS" (Attorney Docket No. 69545.8603US) filed concurrently herewith and incorporated herein by reference. [0030] In particular embodiments, the system can also include a radiation control structure 660 powered by a control structure actuator 661. The radiation control structure 660 can include multiple movable elements 662, e.g. panels that pivot about corresponding pivot joints 664 in the manner of a Venetian blind. One set of elements 662 is shown in Figure 6 for purposes of illustration - in general, this set is duplicated circumferentially around the radiation-receiving surfaces of the reactor 610. Each movable element 662 can have a first surface 663a and a second surface 663b. Accordingly, the radiation control structure 660 can position one surface or the other to face outwardly, depending upon external conditions (e.g. the level of focused solar energy 127), and/or whether the reactor 610 is being used in a heating mode or a cooling mode. In a particular aspect of this embodiment, the first surface 663a can have a relatively high absorptivity and a relatively low emissivity. This surface can accordingly readily absorb radiation during the day and/or when the focused solar energy 127 is above a threshold level, and can transmit (e.g., by conduction) the absorbed energy to the second surface 663b. The second surface 663b can have a relatively low absorptivity and a relatively high emissivity can accordingly emit energy conducted to it by the first surface 663a. In one orientation, this effect can operate to heat the first reaction zone 61 1a, and in the opposite orientation, theis effect can operate to cool the first reaction zone 61 1 a (or another component of the reactor 1 10, e.g. the first heat exchanger 150a described above), for example, at night. Accordingly, the radiation control structure 660 can enhance the manner in which radiation is delivered to the first reaction zone 61 1a, and the manner in which heat is removed from the reactor 610.
[0031] In still further embodiments, the reactor 610 can include a redirection component 670 coupled to a redirection actuator 671 to redirect radiation that "spills" (e.g. is not precisely focused on the transmissive component 612) due to collector surface aberrations, environmental defects, non-parallel radiation, wind and/or other disturbances or distortions. In a particular embodiment, the redirection 670 can include movable elements 672 that pivot about corresponding pivot joints 674 in a Venetian blind arrangement generally similar to that discussed above. Accordingly, these elements 672 can be positioned circumferentially around the radiation- receiving surfaces of the reactor 610. In one aspect of this embodiment, the surfaces of the movable elements 672 are reflective in order to simply redirect radiation into the first reaction zone 61 1a. In other embodiments, the surfaces can include wavelength-shifting characteristics described above and described in copending U.S. Patent Application No. titled "CHEMICAL REACTORS WITH
RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS" (Attorney Docket No. 69545.8603) previously incorporated by reference.
[0032] One feature of embodiments of the systems and processes described above with reference to Figures 1-6 that they can use a solar collector or concentrator surface to provide cooling as well heating, in effect, operating the concentrator surface in reverse. This arrangement can provide a useful heat transfer process for cooling products and/or other constituents produced by the reactor, while reducing or eliminating the need for separate elements (e.g., refrigeration systems) to provide these functions.
[0033] Another feature of at least some of the foregoing embodiments is that they can include surfaces specifically tailored to enhance the absorption and/or emission of radiation entering or rejected by the system. These elements can provide further thermodynamic efficiencies and therefore reduce the cost of producing the reactants described above.
[0034] Certain aspects of the technology described in the context of particular embodiments may be combined or eliminated in other embodiments. For example, particular embodiments were described above in the context of a reactor having two reaction zones. In other embodiments, similar arrangements for rejecting heat can be applied to reactors having a single reaction zone, or more than two reaction zones. The reaction zone(s) can be used to process constituents other than those described above in other embodiments. The solar concentrators described above can be used for other cooling processes in other embodiments. The solar concentrators can have other configurations (e.g., heliostat configurations) in other embodiments. In at least some embodiments, the reaction zone(s) can move relative to the solar concentrator, in addition to or in lieu of the solar concentrator moving relative to the reaction zone(s). The redirection component and radiation control structures described above can be used alone, in combination with each other, and/or in combination with any of the arrangements described above in association with Figures 1-5. [0035] Further, while advantages associated with certain embodiments of the technology have been described in the context of those embodiments, other embodiments may also exhibit such advantages, and not all embodiments need necessarily exhibit such advantages to fall within the scope of the present disclosure. Accordingly, the present disclosure and associated technology can encompass other embodiments not expressly shown or described herein.
[0036] To the extent not previously incorporated herein by reference, the present application incorporates by reference in their entirety the subject matter of each of the following materials: U.S. Patent Application No. 12/857,553, filed on August 16, 2010 and titled SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED PRODUCTION OF RENEWABLE ENERGY, MATERIALS RESOURCES, AND NUTRIENT REGIMES; U.S. Patent Application No. 12/857,553, filed on August 16, 2010 and titled SYSTEMS AND METHODS FOR SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED FULL SPECTRUM PRODUCTION OF RENEWABLE ENERGY; U.S. Patent Application No. 12/857,554, filed on August 16, 2010 and titled SYSTEMS AND METHODS FOR SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED FULL SPECTRUM PRODUCTION OF RENEWABLE MATERIAL RESOURCES USING SOLAR THERMAL; U.S. Patent Application No. 12/857,502, filed on August 16, 20 0 and titled ENERGY SYSTEM FOR DWELLING SUPPORT; Attorney Docket No. 69545-8505. USOO, filed on February 14, 2011 and titled DELIVERY SYSTEMS WITH IN-LINE SELECTIVE EXTRACTION DEVICES AND ASSOCIATED METHODS OF OPERATION; U.S. Patent Application No. 61/401 ,699, filed on August 16, 2010 and titled COMPREHENSIVE COST MODELING OF AUTOGENOUS SYSTEMS AND PROCESSES FOR THE PRODUCTION OF ENERGY, MATERIAL RESOURCES AND NUTRIENT REGIMES; Attorney Docket No. 69545-8601. USOO, filed on February 14, 201 1 and titled CHEMICAL PROCESSES AND REACTORS FOR EFFICIENTLY PRODUCING HYDROGEN FUELS AND STRUCTURAL MATERIALS, AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8602.US00, filed on February 14, 201 1 and titled REACTOR VESSELS WITH TRANSMISSIVE SURFACES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8603.US00, filed on February 14, 2011 and titled CHEMICAL REACTORS WITH RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8604.US00, filed on February 14, 2011 and titled THERMAL TRANSFER DEVICE AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8605. US00, filed on February 14, 2011 and titled CHEMICAL REACTORS WITH ANNULARLY POSITIONED DELIVERY AND REMOVAL DEVICES, AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8608.US00, filed on February 14, 2011 and titled INDUCTION FOR THERMOCHEMICAL PROCESS, AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8611.US00, filed on February 14, 2011 and titled COUPLED THERMOCHEMICAL REACTORS AND ENGINES, AND ASSOCIATED SYSTEMS AND METHODS; U.S. Patent Application No. 61/385,508, filed on September 22, 2010 and titled REDUCING AND HARVESTING DRAG ENERGY ON MOBILE ENGINES USING THERMAL CHEMICAL REGENERATION; Attorney Docket No. 69545-8616. US00, filed on February 14, 2011 and titled REACTOR VESSELS WITH PRESSURE AND HEAT TRANSFER FEATURES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS; Attorney Docket No. 69545-8701. US00, filed on February 14, 2011 and titled ARCHITECTURAL CONSTRUCT HAVING FOR EXAMPLE A PLURALITY OF ARCHITECTURAL CRYSTALS; U.S. Patent Application No. 12/806,634, filed on August 16, 2010 and titled METHODS AND APPARATUSES FOR DETECTION OF PROPERTIES OF FLUID CONVEYANCE SYSTEMS; Attorney Docket No. 69545-8801. US01 , filed on February 14, 2011 and titled METHODS, DEVICES, AND SYSTEMS FOR DETECTING PROPERTIES OF TARGET SAMPLES; Attorney Docket No. 69545-9002. US00, filed on February 14, 20 1 and titled SYSTEM FOR PROCESSING BIOMASS INTO HYDROCARBONS, ALCOHOL VAPORS, HYDROGEN, CARBON, ETC.; Attorney Docket No. 69545- 9004.US00, filed on February 14, 2011 and titled CARBON RECYCLING AND REINVESTMENT USING THERMOCHEMICAL REGENERATION; Attorney Docket No. 69545-9006.US00, filed on February 14, 2011 and titled OXYGENATED FUEL; U.S. Patent Application No. 61/237,419, filed on August 27, 2009 and titled CARBON SEQUESTRATION; U.S. Patent Application No. 61/237,425, filed on August 27, 2009 and titled OXYGENATED FUEL PRODUCTION; Attorney Docket No. 69545-9102.US00, filed on February 14, 2011 and titled MULTI-PURPOSE RENEWABLE FUEL FOR ISOLATING CONTAMINANTS AND STORING ENERGY; U.S. Patent Application No. 61/421 ,189, filed on December 8, 2010 and titled LIQUID FUELS FROM HYDROGEN, OXIDES OF CARBON, AND/OR NITROGEN; AND PRODUCTION OF CARBON FOR MANUFACTURING DURABLE GOODS; and Attorney Docket No. 69545-9105.US00, filed on February 14, 2011 and titled ENGINEERED FUEL STORAGE, RESPECIATION AND TRANSPORT.
2. The system of claim 1 , further comprising a heat exchanger carrying a heat exchanger fluid, and wherein the heat exchanger is positionable at the focal area when the solar energy is below the threshold level to discharge heat from the heat exchanger fluid via the solar concentrator.
5. The system of claim 1 wherein the solar concentrator includes a dish- shaped concentrator.
6. The system of claim 1 wherein the solar concentrator includes a trough-shaped concentrator.
7. The system of claim 1 wherein the solar concentrator includes a Fresnel lens.
8. The system of claim 1 , further comprising a reactant carried by the reactant source, and wherein the reactant includes a hydrogen donor having at least one of carbon, boron, nitrogen, silicon, a transition metal, and sulfur as a constituent.
second actuator coupled to the radiation control structure to change the structure from a first configuration in which the first surface faces toward the concentrator surface, and a second configuration in which the second surface faces toward the concentrator surface.
0. The system of claim 9, further comprising:
controller operatively coupled to the first and second actuators, the controller being programmed with instructions that, when executed: direct the first actuator to position the solar concentrator to focus the solar energy on the reaction zone when the solar energy is above a threshold level;
direct the first actuator to position the solar concentrator to point to a location in the sky away from the sun and having relatively little radiant energy to cool an object positioned at the focal area when the solar energy is below the threshold level; and direct the second actuator to position the radiation control structure in the second configuration when the solar energy is below the threshold level.
15. The system of claim 13 wherein the movable surfaces include a re- radiation component positioned to receive radiation over a first spectrum having a first peak wavelength range and re-radiate the radiation into the reaction zone over a second spectrum having a second peak wavelength range different than the first.
a first product collector coupled to the reaction zone to receive a hydrogen- based fuel produced by dissociating the hydrogen donor at the reaction zone;
an actuator coupled to the solar concentrator to move the solar concentrator relative to the sun; and a controller operatively coupled to the actuator, the controller being programmed with instructions that, when executed:
direct the solar concentrator to point toward the sun and focus the solar energy on the reaction zone during daylight hours; and direct the solar concentrator to point to a location in the sky having relatively little radiation energy to cool an object positioned at the focal area after daylight hours.
19. A method for processing a hydrogen donor, comprising:
concentrating solar energy with a solar concentrator;
directing the concentrated solar energy to a reaction zone positioned at a focal area of the solar concentrator;
at the reaction zone, dissociating a hydrogen donor into dissociation products via the concentrated solar energy; and
from the dissociation products, providing at least one of:
(a) a structural building block based on at least one of carbon, nitrogen, boron, silicon, a transition metal, and sulfur; and
(b) a hydrogen-based fuel.
20. The method of claim 19 wherein the hydrogen donor includes methane, and wherein providing includes providing hydrogen and at least one of carbon, carbon dioxide and carbon monoxide.
21. The method of claim 19 wherein the hydrogen donor includes a hydrocarbon.
22. The method of claim 19 wherein the hydrogen donor includes a nitrogenous compound.
23. The method of claim 19, further comprising operating a radiation control structure positioned between the solar concentrator and the focal area by: positioning a first surface of the radiation control structure having a first radiant energy absorptivity and a first radiant energy emissivity to face toward the solar concentrator when the solar energy is above a threshold value; and
positioning a second surface of the radiation control structure having a second radiant energy absorptivity less than the first radiant energy absorptivity and a second radiant energy emissivity greater than the first radiant energy emissivity to face toward the focal area when the solar energy is below the threshold value.
when the solar energy is above a threshold level:
pointing the solar concentrator toward the sun; and
directing the concentrated solar energy to the reaction zone; and when the solar energy is below the threshold level:
placing at least one of the structural building block and the hydrogen- based fuel in thermal communication with the focal area; and dispersing heat at the focal area by pointing the solar concentrator away from the sun and to a location in the sky having relatively little radiative energy to cool the at least one of the structural building block and the hydrogen-based fuel.
25. The method of claim 24 wherein placing at least one of the structural building block and the hydrogen-based fuel in thermal communication with the focal area includes:
aligning a heat exchanger with the focal area; and
directing a heat exchange fluid from the heat exchanger to the at least one of the structural building block and the hydrogen-based fuel.
26. A method for processing a reactant, comprising:
when solar energy proximate to a reactor is above a threshold level:
concentrating the solar energy at a focal area of a solar concentrator by pointing the solar concentrator toward the sun;
directing the concentrated solar energy to the reaction zone;
directing the reactant to the reaction zone; and
performing an endothermic reaction with the reactant at the reaction zone; and
when solar energy proximate to the reactor is below the threshold level:
dispersing heat at the focal area of the solar concentrator by pointing the solar concentrator away from the sun and to a location in the sky having relatively little radiative energy.
27. The method of claim 26, further comprising, from the dissociation products, providing at least one of:
28. The method of claim 26 wherein dissociating the hydrogen donor includes performing an endothermic reaction at the reaction zone, and wherein dispersing heat includes dispersing heat from an exothermic reaction.
29. The method of claim 26 wherein dispersing heat includes liquefying methanol.
30. The method of claim 26 wherein dispersing heat includes liquefying carbon dioxide.
31. The method of claim 26 wherein dispersing heat includes dispersing heat from a heat exchanger carrying a heat exchanger fluid, by moving at least one of the heat exchanger and the solar concentrator relative to the other to align the heat exchanger with the focal area.
PCT/US2011/024796 2010-02-13 2011-02-14 Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods WO2011100716A3 (en)
KR20127023737A KR101364785B1 (en) 2010-02-13 2011-02-14 Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods
EP20110742983 EP2533891A4 (en) 2010-02-13 2011-02-14 Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods
CA 2788433 CA2788433C (en) 2010-02-13 2011-02-14 Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods
CN 201180009275 CN102892493A (en) 2010-02-13 2011-02-14 Chemical reactors with annularly positioned delivery and removal devices, and associated systems and methods
JP2012553087A JP5722917B2 (en) 2010-02-13 2011-02-14 Reactor, and associated systems and methods for performing thermochemical processes using solar heat input
WO2011100716A2 true true WO2011100716A2 (en) 2011-08-18
WO2011100716A3 true WO2011100716A3 (en) 2011-12-29
PCT/US2011/024796 WO2011100716A3 (en) 2010-02-13 2011-02-14 Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods
ES2087424T3 (en) * 1991-12-26 1996-07-16 Yeda Res & Dev Gasification solar solid carbonaceous materials in liquid dispersion.
EP0944843B1 (en) * 1996-12-12 2005-04-27 POULEK, Vladislav An apparatus for orientation of solar radiation collectors
See also references of EP2533891A2 *
US8187550B2 (en) 2012-05-29 grant
Charvin et al. 2008 Analysis of solar chemical processes for hydrogen production from water splitting thermochemical cycles
Osinga et al. 2003 Experimental investigation of the solar carbothermic reduction of ZnO using a two-cavity solar reactor
Chen et al. 2010 Hydrogen production by biomass gasification in supercritical water using concentrated solar energy: System development and proof of concept
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