Source: http://www.google.com/patents/US20040198858?dq=U.S.+Patent+No.+4,528,643)
Timestamp: 2015-09-01 14:54:38
Document Index: 385341696

Matched Legal Cases: ['Application No. 60', 'Application No. 60', 'Application No. 60', 'Application No. 60', 'Application No. 60', 'Application No. 60']

Patent US20040198858 - Increasing thermal conductivity of host polymer used with laser engraving ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsthe invention provides a composition having laser engraving properties, comprising a host material and a laser enhancing additive. The host material comprises a material, such as a polymer, modified by a first process, whereby the host material as modified by the first process has increased thermal conductivity...http://www.google.com/patents/US20040198858?utm_source=gb-gplus-sharePatent US20040198858 - Increasing thermal conductivity of host polymer used with laser engraving methods and compositionsAdvanced Patent SearchPublication numberUS20040198858 A1Publication typeApplicationApplication numberUS 10/677,092Publication dateOct 7, 2004Filing dateSep 30, 2003Priority dateDec 20, 2002Also published asUS7728048, US7980596, US20100181754, WO2005029654A2, WO2005029654A3Publication number10677092, 677092, US 2004/0198858 A1, US 2004/198858 A1, US 20040198858 A1, US 20040198858A1, US 2004198858 A1, US 2004198858A1, US-A1-20040198858, US-A1-2004198858, US2004/0198858A1, US2004/198858A1, US20040198858 A1, US20040198858A1, US2004198858 A1, US2004198858A1InventorsBrian LabrecOriginal AssigneeBrian LabrecExport CitationBiBTeX, EndNote, RefManPatent Citations (99), Referenced by (20), Classifications (21), Legal Events (5) External Links: USPTO, USPTO Assignment, EspacenetIncreasing thermal conductivity of host polymer used with laser engraving methods and compositions
US 20040198858 A1Abstract
the invention provides a composition having laser engraving properties, comprising a host material and a laser enhancing additive. The host material comprises a material, such as a polymer, modified by a first process, whereby the host material as modified by the first process has increased thermal conductivity as compared to the host material before the first process. The laser enhancing additive comprises a first quantity of at least one of copper potassium iodide (CuKI3), Copper Iodide (CuI), potassium iodide (KI), sodium iodide (NaI), and aluminum iodide (AlI), and a second quantity of at least one substance selected from the group consisting of zinc sulfide (ZnS), barium sulfide (BaS), alkyl sulfonate, and thioester. Images(13) Claims(24)
RELATED APPLICATION DATA [0001] The present application is related to U.S. patent application Ser. No. 09/747,735, filed Dec. 22, 2000, Ser. No. 09/602,313, filed Jun. 23, 2000, and Ser. No. 10/094,593, filed Mar. 6, 2002, U.S. Provisional Patent Application No. 60/358,321, filed Feb. 19, 2002, as well as U.S. Pat. No. 6,066,594. Each of the above U.S. Patent documents is herein incorporated by reference. The present application also is related to the following U.S. patent application documents: [0002] Systems, Compositions, and Methods for Full Color Laser Engraving of ID Documents (application Ser. No. 10/330,034, Attorney Docket No. P0734D, filed Dec. 24, 2002—Inventor Robert Jones); [0003] Laser Etched Security Features for Identification Documents and Methods of Making Same (application Ser. No. 10/330,033, Attorney Docket No. P0736D, filed Dec. 24, 2002-Inventors George Theodossiou and Robert Jones); [0004] Identification Document and Related Methods (Application No. 60/421,254, Attorney Docket No. P0703-Inventors: Geoff Rhoads, et al); [0005] Identification Document and Related Methods (Application No. 60/418,762, Attorney Docket No. P0696-Inventors: Geoff Rhoads, et al); [0006] Enhanced Shadow Reduction System and Related Technologies for Digital Image Capture (Application No. 60/447,502, Attorney Docket No. P0789D, filed Feb. 13, 2003-Inventors Scott D. Haigh, Tuan A. Hoang, Charles R. Duggan, David Bohaker, and Leo M. Kenen); [0007] Enhanced Shadow Reduction System and Related Technologies for Digital Image Capture (Application No. not yet assigned, Attorney Docket No. P0883D, filed Sep. 15, 2003-Inventors Scott D. Haigh, Tuan A. Hoang, Charles R. Duggan, David Bohaker, and Leo M. Kenen); CROSS REFERENCE TO RELATED APPLICATION [0008] The present application is a continuation in part of “Laser Engraving Methods and Compositions, and Articles Having Laser Engraving Thereon”, Ser. No. 10/326,886, Attorney Docket No. P0724D, file Dec. 20, 2002—Inventors Brian Labrec and Robert Jones. [0009] This application claims the priority of the following United States Provisional Applications, the contents of which are incorporated hereby by reference in their entirety: [0010] Identification Document (Application No. 60/471,429, Attorney Docket No. P0833D, filed May 16, 2003-Inventors Robert Jones, Brian Labrec, Daoshen Bi, and Thomas Regan); [0011] Laser Engraving Methods and Compositions, and Articles Having Laser Engraving Thereon (Application No. not yet assigned, Attorney Docket No. P0888D, filed Sep. 19, 2003-Inventors Brian Labrec and Robert Jones); and [0012] Identification Document with Optical Memory and Related Method of Manufacture (Application No. 60/500,204, Attorney Docket No. P0878D, filed Sep. 3, 2003-Inventor Robert Jones).
TECHNICAL FIELD [0013] The invention generally relates to methods and compositions for laser marking or engraving that contain one or more laser enhancing additives, as well as methods for conveying information, images, and security features on data carriers through laser engraving and marking, including laser engraving and marking using such compositions. In particular, the invention relates to techniques and methods for decreasing the marking speeds of images using a laser for marking of ID documents by increasing the thermal conductivity of the host polymer and its' interpenetrating network (IPN). BACKGROUND AND SUMMARY [0014] Identification documents (hereafter “ID documents”) play a critical role in today's society. One example of an ID document is an identification card (“ID card”). ID documents are used on a daily basis—to prove identity, to verify age, to access a secure area, to evidence driving privileges, to cash a check, and so on. Airplane passengers are required to show an ID document during check in, security screening, and prior to boarding their flight. In addition, because we live in an ever-evolving cashless society, ID documents are used to make payments, access an ATM, debit an account, or make a payment, etc. [0015] Many types of identification cards and documents, such as driving licenses, national or government identification cards, bank cards, credit cards, controlled access cards and smart cards, carry thereon certain items of information which relate to the identity of the bearer. Examples of such information include name, address, birth date, signature and photographic image; the cards or documents may in addition carry other variant data (i.e., data specific to a particular card or document, for example an employee number) and invariant data (i.e., data common to a large number of cards, for example the name of an employer). All of the cards described above will hereinafter be generically referred to as “ID documents”. [0016] In the production of images useful in the field of identification documentation, it is oftentimes desirable to embody into a document (such as an ID card, drivers license, passport or the like) data or indicia representative of the document issuer (e.g., an official seal, or the name or mark of a company or educational institution) and data or indicia representative of the document bearer (e.g., a photographic likeness, name or address). Typically, a pattern, logo or other distinctive marking representative of the document issuer will serve as a means of verifying the authenticity, genuineness or valid issuance of the document. A photographic likeness or other data or indicia personal to the bearer will validate the right of access to certain facilities or the prior authorization to engage in commercial transactions and activities. [0017] Identification documents, such as ID cards, having printed background security patterns, designs or logos and identification data personal to the card bearer have been known and are described, for example, in U.S. Pat. No. 3,758,970, issued Sep. 18, 1973 to M. Annenberg; in Great Britain Pat. No. 1,472,581, issued to G. A. O. Gesellschaft Fur Automation Und Organisation mbH, published Mar. 10, 1976; in International Patent Application PCT/GB82/00150, published Nov. 25, 1982 as Publication No. WO 82/04149; in U.S. Pat. No. 4,653,775, issued Mar. 31, 1987 to T. Raphael, et al.; in U.S. Pat. No. 4,738,949, issued Apr. 19, 1988 to G. S. Sethi, et al.; and in U.S. Pat. No. 5,261,987, issued Nov. 16, 1993 to J. W. Luening, et al. All of the aforementioned documents are hereby incorporated by reference. [0018] The advent of commercial apparatus (printers) for producing dye images by thermal transfer has made relatively commonplace the production of color prints from electronic data acquired by a video camera. In general, this is accomplished by the acquisition of digital image information (electronic signals) representative of the red, green and blue content of an original, using color filters or other known means. These signals are then utilized to print an image onto a data carrier. For example, information can be printed using a printer having a plurality of small heating elements (e.g., pins) for imagewise heating of each of a series of donor sheets (respectively, carrying sublimable cyan, magenta and yellow dye). The donor sheets are brought into contact with an image-receiving element (which can, for example, be a substrate) which has a layer for receiving the dyes transferred imagewise from the donor sheets. Thermal dye transfer methods as aforesaid are known and described, for example, in U.S. Pat. No. 4,621,271, issued Nov. 4, 1986 to S. Brownstein and U.S. Pat. No. 5,024,989, issued Jun. 18, 1991 to Y. H. Chiang, et al. Each of these patents is hereby incorporated by reference. [0019] Commercial systems for issuing ID documents are of two main types, namely so-called “central” issue (CI), and so-called “on-the-spot” or “over-the-counter” (OTC) issue. [0020] CI type ID documents are not immediately provided to the bearer, but are later issued to the bearer from a central location. For example, in one type of CI environment, a bearer reports to a document station where data is collected, the data are forwarded to a central location where the card is produced, and the card is forwarded to the bearer, often by mail. Another illustrative example of a CI assembling process occurs in a setting where a driver passes a driving test, but then receives her license in the mail from a CI facility a short time later. Still another illustrative example of a CI assembling process occurs in a setting where a driver renews her license by mail or over the Internet, then receives a drivers license card through the mail. [0021] Centrally issued identification documents can be produced from digitally stored information and generally comprise an opaque core material (also referred to as “substrate”), such as paper or plastic, sandwiched between two layers of clear plastic laminate, such as polyester, to protect the aforementioned items of information from wear, exposure to the elements and tampering. The materials used in such CI identification documents can offer the ultimate in durability. In addition, centrally issued digital identification documents generally offer a higher level of security than OTC identification documents because they offer the ability to pre-print the core of the central issue document with security features such as “micro-printing”, ultra-violet security features, security indicia and other features currently unique to centrally issued identification documents. Another security advantage with centrally issued documents is that the security features and/or secured materials used to make those features are centrally located, reducing the chances of loss or theft (as compared to having secured materials dispersed over a wide number of “on the spot” locations). [0022] In addition, a CI assembling process can be more of a bulk process facility, in which many cards are produced in a centralized facility, one after another. The CI facility may, for example, process thousands of cards in a continuous manner. Because the processing occurs in bulk, CI can have an increase in efficiency as compared to some OTC processes, especially those OTC processes that run intermittently. Thus, CI processes can sometimes have a lower cost per ID document, if a large volume of ID documents are manufactured. [0023] In contrast to CI identification documents, OTC identification documents are issued immediately to a bearer who is present at a document-issuing station. An OTC assembling process provides an ID document “on-the-spot”. (An illustrative example of an OTC assembling process is a Department of Motor Vehicles (“DMV”) setting where a driver's license is issued to person, on the spot, after a successful exam.). In some instances, the very nature of the OTC assembling process results in small, sometimes compact, printing and card assemblers for printing the ID document. [0024] OTC identification documents of the types mentioned above can take a number of forms, depending on cost and desired features. Some OTC ID documents comprise highly plasticized polyvinyl chloride (PVC) or have a composite structure with polyester laminated to 0.5-2.0 mil (13-51 .mu.m) PVC film, which provides a suitable receiving layer for heat transferable dyes which form a photographic image, together with any variant or invariant data required for the identification of the bearer. These data are subsequently protected to varying degrees by clear, thin (0.125-0.250 mil, 3-6 .mu.m) overlay patches applied at the print head, holographic hot stamp foils (0.125-0.250 mil 3-6 .mu.m), or a clear polyester laminate (0.5-10 mil, 13-254 .mu.m) supporting common security features. These last two types of protective foil or laminate sometimes are applied at a laminating station separate from the print head. The choice of laminate dictates the degree of durability and security imparted to the system in protecting the image and other data. [0025]FIGS. 1 and 2 illustrate a front view and cross-sectional view (taken along the A-A line), respectively, of an exemplary prior art identification (ID) document 10. In FIG. 1, the prior art ID document 1 includes a photographic image 12, a bar code 14 (which may contain information specific to the person whose image appears in photographic image 12 and/or information that is the same from ID document to ID document), variable personal information 16, such as an address, signature, and/or birthdate, and biometric information 18 associated with the person whose image appears in photographic image 12 (e.g., a fingerprint). Although not illustrated in FIG. 1, the ID document 10 can include a magnetic stripe (which, for example, can be on the rear side (not shown) of the ID document 10), and various security features, such as a security pattern (for example, a printed pattern comprising a tightly printed pattern of finely divided printed and unprinted areas in close proximity to each other, such as a fine-line printed security pattern as is used in the printing of banknote paper, stock certificates, and the like). [0026] Referring to FIG. 2, the ID document 10 comprises a pre-printed core 20 (such as, for example, white PVC material) that is, for example, about 25 mil thick. The core 20 is laminated with a transparent material, such as clear PVC material 22, which, by way of example, can be about 1-5 mil thick. The composite of the core 20 and clear PVC material 22 form a so-called “card blank” 25 that can be up to about 30 mils thick. Information 26 a-c is printed on the card blank 25 using a method such as Dye Diffusion Thermal Transfer (“D2T2”) printing (described further in commonly assigned U.S. Pat. No. 6,066,594, which is incorporated hereto by reference in its entirety.) The information 26 a-c can, for example, comprise an indicium or indicia, such as the invariant or nonvarying information common to a large number of identification documents, for example the name and logo of the organization issuing the documents. The information 26 a-c may be formed by any known process capable of forming the indicium on the specific core material used. [0027] To protect the information 26 a-c that is printed, an additional layer of overlaminate 24 can be coupled to the card blank 25 and printing 26 a-c using, for example, 1 mil of adhesive (not shown). The overlaminate 24 can be substantially transparent. Materials suitable for forming such protective layers are known to those skilled in the art of making identification documents and any of the conventional materials may be used provided they have sufficient transparency. Examples of usable materials for overlaminates include biaxially oriented polyester or other optically clear durable plastic film. [0028] The above-described printing techniques are not the only methods for printing information on data carriers such as ID documents. Laser beams, for example can be used for marking, writing, bar coding, and engraving many different types of materials, including plastics. Lasers have been used, for example, to mark plastic materials to create indicia such as bar codes, date codes, part numbers, batch codes, and company logos. It will be appreciated that laser engraving or marking generally involves a process of inscribing or engraving a document surface with identification marks, characters, text, tactile marks—including text, patterns, designs (such as decorative or security features), photographs, etc. [0029] One way to laser mark thermoplastic materials involves irradiating a material, such as a thermoplastic, with a laser beam at a given radiation. The area irradiated by the laser absorbs the laser energy and produces heat which causes a visible discoloration in the thermoplastic. The visible discoloration serves as a “mark” or indicator; it will be appreciated that laser beams can be controlled to form patterns of “marks” that can form images, lines, numbers, letters, patterns, and the like. Depending on the type of laser and the type of material used, various types of marks (e.g., dark marks on light backgrounds, light marks on dark backgrounds, colored marks) can be produced. Some types of thermoplastics, such as polyvinylchloride (PVC), acrylonitrile butadiene styrene (ABS), and polyethylene terephthalate (PET), are capable of absorbing laser energy in their native states. Some materials which are transparent to laser energy in their native state, such as polyethylene, may require the addition of one or more additives to be responsive to laser energy. [0030] For additional background, various laser marking and/or engraving techniques are disclosed, e.g., in U.S. Pat. Nos. 6,022,905, 5,298,922, 5,294,774, 5,215,864 and 4,732,410. Each of these patents is herein incorporated by reference. In addition, U.S. Pat. Nos. 4,816,372, 4,894,110, 5,005,872, 5,977,514, and 6,179,338 describe various implementations for using a laser to print information, and these patents are incorporated herein in their entirety. [0031] Using laser beams to write or engrave information to ID cards presents a number of advantages over conventional printing. For example, the foaming of the thermoplastic that can occur with some types of laser engraving can be adapted to provide an indicium having a tactile feel, which is a useful authenticator of a data carrier that also can be very difficult to counterfeit or alter. In addition, laser engraving generally does not require the use of ink, which can reduce the cost of consumables used to manufacture an ID card. Laser engraving can also be more durable than ink printing, and more resistant to abrasion (which can be particularly useful if a counterfeiter attempts to “rub off” an indicium on an ID card). The resolution and print quality of laser engraving often can be higher than that of conventional ink-based printing. Laser engraving also can be a more environmentally friendly manufacturing process than printing with ink, especially because solvents and other chemicals often used with ink generally are not used with laser engraving. [0032] Despite the advantages of laser engraving, certain limitations still exist. Even when using known laser-enhancing additives, laser marking of some types of materials does not produce an adequate contrast for all applications. Some types of materials, such as silica filled polyolefin, TESLIN core ID documents and TESLIN composite structures (TESLIN is available from PPG Industries, Inc., Pittsburgh, Pa.) using conventional over-laminate materials, are not easily laser engraved. Further, even with use of known laser additives, laser engraving can take too much time and/or too much laser energy to be useful in some manufacturing environments. [0033] Another limitation of laser engraving has been marking speeds. The ability to mark a ra