Source: http://patents.com/us-10011736.html
Timestamp: 2018-12-10 03:58:51
Document Index: 630233121

Matched Legal Cases: ['Application No. 2008102131717', 'Application No. 2009801023012', 'Application No. 2008', 'Application No. 08003475', 'Application No. 201080032749', 'Application No. 10160331', 'Application No. 10156454', 'Application No. 10156454']

US Patent # 1,001,1736. Powder coating compositions capable of having a substantially non-zinc containing primer - Patents.com
United States Patent 10,011,736
Lucas July 3, 2018
Corrosion and chip-resistant coatings for high tensile steel components, such as automotive coil springs, can be formed from a coating composition comprising a primer having an epoxy resin with the proviso that the epoxy resin does not have an EEW of about 860 to about 930, a polyhydroxyl functional phenolic curing agent having a HEW of about 200 to about 500, and a platy filler. The primer contains less than 20 wt % zinc. The topcoat includes an epoxy resin having an epoxy equivalent weight of about 450 to about 1400, an elastomer-modified epoxy resin having an epoxy equivalent weight of about 1000 to about 1600, a foaming agent and a reinforcing fiber.
Lucas; Chad (Newburgh Heights, OH)
Lucas; Chad
Family ID: 43529753
13/387,431
PCT/EP2010/060907
WO2011/012627
US 20120258316 A1 Oct 11, 2012
61229565 Jul 29, 2009
Sep 3, 2009 [EP] 09169332
Current CPC Class: C08G 59/621 (20130101); C09D 5/038 (20130101); C09D 5/106 (20130101); C09D 163/00 (20130101); C09D 5/031 (20130101); C09D 7/70 (20180101); C09D 7/69 (20180101); C09D 7/62 (20180101); C09D 163/00 (20130101); C09D 163/00 (20130101); C08K 3/34 (20130101); C08L 63/00 (20130101); C08L 67/00 (20130101); C08L 2205/02 (20130101); C08K 3/40 (20130101); Y10T 428/31529 (20150401); C08L 2666/14 (20130101); C08L 2666/18 (20130101)
Current International Class: C09D 5/03 (20060101); C23C 26/00 (20060101); C08G 59/62 (20060101); C09D 7/62 (20180101); C09D 7/40 (20180101); C09D 163/00 (20060101); C09D 163/02 (20060101); C09D 5/10 (20060101); C08L 63/00 (20060101); B32B 15/092 (20060101); C08K 3/04 (20060101); C08K 3/40 (20060101); C08K 3/34 (20060101); C09D 161/10 (20060101); C09D 167/00 (20060101); C09D 5/00 (20060101); C08L 67/00 (20060101)
3245925 April 1966 Watson
3756984 September 1973 Klaren et al.
3769069 October 1973 Sawyer
3817946 June 1974 Ree
3860557 January 1975 Millar et al.
3947522 March 1976 Shelley et al.
4186036 January 1980 Elms et al.
4237037 December 1980 Takahashi
4313837 February 1982 Vukasovich et al.
4316939 February 1982 Guyomard
4345004 August 1982 Miyata et al.
4381334 April 1983 Balk et al.
4491554 January 1985 Hamel et al.
4572868 February 1986 Hosaka et al.
4581293 April 1986 Saunders
4804581 February 1989 Geary et al.
4933382 June 1990 Kitagawa et al.
5030285 July 1991 Vallvey et al.
5062284 November 1991 Kubo et al.
5063095 November 1991 Kitagawa et al.
5137567 August 1992 Vallvey et al.
5196261 March 1993 Ono et al.
5248400 September 1993 Franks et al.
5264503 November 1993 Marx
5334631 August 1994 Durand
5338347 August 1994 Rohr et al.
5342885 August 1994 St Clair
5461112 October 1995 Masse et al.
5468461 November 1995 Hosoda et al.
5562989 October 1996 Statz
5569687 October 1996 Sanborn et al.
5614323 March 1997 Chang
5677367 October 1997 Savin
5686185 November 1997 Correll et al.
5789482 August 1998 Eldin et al.
5789498 August 1998 Ohnishi et al.
5981086 November 1999 Siminski
6022927 February 2000 Decker et al.
6025438 February 2000 Hinterwaldner et al.
6069221 May 2000 Chasser et al.
6184311 February 2001 O'Keffe et al.
6254751 July 2001 Reiter et al.
6284846 September 2001 Ambrose et al.
6294610 September 2001 Daly et al.
6346292 February 2002 Grubb et al.
6403222 June 2002 Harrison
6521706 February 2003 Desai et al.
6537610 March 2003 Springer et al.
6663968 December 2003 Grubb et al.
6677032 January 2004 Grubb et al.
6770702 August 2004 Muller et al.
7018716 March 2006 Grubb et al.
7244780 July 2007 Robinson et al.
7473717 January 2009 Muenz et al.
2001/0002274 May 2001 Lessmeister et al.
2001/0046555 November 2001 Lessmeister et al.
2001/0051227 December 2001 Jung et al.
2003/0124248 July 2003 Tullos et al.
2004/0009300 January 2004 Shimakura et al.
2004/0048954 March 2004 Thieben
2004/0101670 May 2004 Grubb et al.
2004/0266899 December 2004 Muenz et al.
2007/0116963 May 2007 Sakakibara
2007/0172665 July 2007 Kunita et al.
2009/0110934 April 2009 Cinoman
2009/0176903 July 2009 Muenz et al.
2009/0270533 October 2009 Umehara et al.
2010/0255296 October 2010 Kunita et al.
2010/0256282 October 2010 Breidenstein et al.
2012/0258316 October 2012 Lucas
1120253 Mar 1982 CA
1198690 Nov 1998 CN
101033364 Sep 2007 CN
101952374 Jan 2011 CN
3018765 Nov 1981 DE
10020481 Oct 2001 DE
0040243 Nov 1981 EP
0292771 Nov 1988 EP
0440292 Aug 1991 EP
0500009 Aug 1992 EP
0525870 Feb 1993 EP
0526153 Feb 1993 EP
0631536 Jan 1995 EP
0846710 Jun 1998 EP
0882101 Dec 1998 EP
0994141 Apr 2000 EP
1165712 Jan 2002 EP
1972672 Sep 2004 EP
1726621 Nov 2006 EP
1407851 Sep 1975 GB
1565379 Apr 1980 GB
49039625 Apr 1974 JP
58047064 Mar 1983 JP
58-114767 Jul 1983 JP
58114766 Jul 1983 JP
58168619 Oct 1983 JP
59029154 Feb 1984 JP
59193970 Nov 1984 JP
61148274 Jul 1986 JP
3000785 Jan 1991 JP
3-170523 Jul 1991 JP
6-9903 Jan 1994 JP
06329955 Nov 1994 JP
7026119 Jan 1995 JP
07-216297 Aug 1995 JP
8-10686 Jan 1996 JP
9012926 Jan 1997 JP
09272820 Oct 1997 JP
H11-188309 Jul 1999 JP
2000143938 May 2000 JP
2000-176373 Jun 2000 JP
2000190422 Jul 2000 JP
2002105393 Apr 2002 JP
2003286435 Oct 2003 JP
2004-352994 Dec 2004 JP
2006096905 Apr 2006 JP
2006096928 Apr 2006 JP
4020557 Oct 2007 JP
2007-313475 Dec 2007 JP
2007314762 Dec 2007 JP
WO91/14745 Oct 1991 WO
WO92/11324 Jul 1992 WO
WO93/17851 Sep 1993 WO
WO00/55268 Sep 2000 WO
WO2003/093375 Nov 2003 WO
WO2004/046245 Jun 2004 WO
WO2005/028580 Mar 2005 WO
WO2006/005136 Jan 2006 WO
WO2006/038491 Apr 2006 WO
2006/129827 Dec 2006 WO
WO2007/025007 Mar 2007 WO
WO2007/138396 Dec 2007 WO
WO2009/129088 Oct 2009 WO
WO2011/012627 Feb 2011 WO
Machine translation of JP 2000190422 A, retrieved Jul. 25, 2014. cited by examiner .
Translation of JP 58-114767. cited by examiner .
Epikote Resin Data Sheet (no date). cited by examiner .
Abstract of JP 58047064 A. cited by examiner .
English Abstract of JP58168619A. cited by applicant .
English Abstract of JP59193970A. cited by applicant .
English Abstract of JP59029154A. cited by applicant .
English Abstract of JP61148274. cited by applicant .
English Abstract of JP2000143938A. cited by applicant .
English Abstract of JP2000190422. cited by applicant .
English Abstract of JP2002105393. cited by applicant .
English Abstract of JP2003286435A. cited by applicant .
English Abstract of JP2006096905A. cited by applicant .
English Abstract of JP2006096928. cited by applicant .
English Machine Translation of DE10020481. cited by applicant .
English Machine Translation of DE3018765A1. cited by applicant .
English Abstract of JP3170523A. cited by applicant .
English Abstract of JP3000785A. cited by applicant .
English Abstract of JP06329955-A. cited by applicant .
English Abstract of JP7026119A. cited by applicant .
English Abstract of JP9012926A. cited by applicant .
English Abstract of JP09272820. cited by applicant .
English Abstract of JP9039625. cited by applicant .
Derwent English Abstract of JP58114766A. cited by applicant .
English Abstract of JP2007314762. cited by applicant .
English Abstract of JP4020557. cited by applicant .
Polymer Science Dictionary, 2nd Ed., Mark Alger, Apr. 7, 1999, pp. 5-6. cited by applicant .
Polymer Preprints, Vo. 32, No. 3, Aug. 1991, American Chemical Society, Aug. 12, 1991, pp. 358-359. cited by applicant .
Encyclopedia of Polymer Science and Engineering, vol. 3, Cellular Materials to Composites, 1985, pp. 552, 575-577. cited by applicant .
Encyclopedia of Polymer Science and Engineering, vol. 6, Emulsion Polymerization to Fibers, Manufacture, 1985, pp. 362-367. cited by applicant .
Rubber Modified Powder Coating Resin, KR-102, Kukdo Chemical Co., Ltd. Jul. 10, 2000, pp. 1-3. cited by applicant .
General Motors Engineering Standards, Materials and Processes--Procedures, Chip Resistance of Coating GM9508P, Jul. 1991, p. 1-8. cited by applicant .
General Motors Engineering Standards, Materials and Processes--Procedures, Scab Corrosion Creepback of Elp Paint Systems on Metal Substrates, GM9511P, Oct. 1986, p. 1-2. cited by applicant .
General Motors Engineering Standards, Materials and Processes--Procedures, Cass Test, Copper-Accelerated ACetic Acid Salt Spray Test (FOG), GM4476P, Nov. 1988, p. 1-5. cited by applicant .
Polymer Wax and the Use Thereof in Powder Coatings, Zhong Jianghai, et al, pp. 1-5, Dec. 31, 2002. cited by applicant .
Powder Coatings Foaming Agents, Dr. Tina Grubb, Computerized Literature Search, Jan. 7, 1997. cited by applicant .
Elastomer-Modified Epoxy Powder Coatings: A Review, Ralph Drake, BF Goodrich Specialty Chemicals, Apr. 13, 1994, vol. 184, No. 4347, pp. 151-154. cited by applicant .
Shell Chemicals Systems & Solutions Newsletter, Apollo and Resins & Versatics Join Forces, Jack Christenson, Jul. 2000, vol. 2, Issue 3, pp. 1-3. cited by applicant .
Paint Additives Recent Developments, G.B. Rothenberg, Noyes Data Corporation, 1978, pp. 175-177. cited by applicant .
Dow Epoxy Powder Coatings, Hardeners, Oct. 2001, pp. 1-6. cited by applicant .
Bulletin of the American Physical Society, Programme of the Mar. 1956 Meeting at Pittsburgh, PA, No. 3, Mar. 15-17, 1956, pp. 122-123. cited by applicant .
English Translation of Chinese Application No. 2008102131717 Office Action dated Jan. 31, 2011. cited by applicant .
English Translation of Chinese Patent Application No. 2009801023012 Office Action, dated Jul. 24, 2012. cited by applicant .
English Translation of Japanese Patent Application No. 2008-208848 Office Action dated Oct. 5, 2011. cited by applicant .
European Patent Application No. 08003475.4 Search Report, dated Jun. 23, 2008. cited by applicant .
International Patent Application No. PCT/EP2009/050738 Preliminary Report on Patentability dated Feb. 8, 2010. cited by applicant .
International Patent Application No. PCT/EP2009/050738 Search Report and Written Opinion dated May 8, 2009. cited by applicant .
International Patent Application No. PCT/EP2010/060907 Search Report dated Mar. 22, 2011. cited by applicant .
English Abstract of JP07-216297. cited by applicant .
English Abstract of JP58-114767. cited by applicant .
English Abstract of JP2000-176373. cited by applicant .
English Translation of Mexico Patent Application No. MX/a/2008/013642 Office Action dated Mar. 19, 2013. cited by applicant .
English Translation of Chinese Patent Application No. 201080032749.4 Office Action dated Jul. 26, 2013. cited by applicant .
QPatent Abstract for Chinese Patent Publication 101033364A. cited by applicant .
QPatent Abstract for Japanese Patent Publication 06-009903A. cited by applicant .
QPatent Abstract for Japanese Patent Publication 8-010686A. cited by applicant .
QPatent Abstract for Japanese Patent Publication 2004-352994A. cited by applicant .
European Search Report frin related EP Application No. 10160331.4 dated Oct. 6, 2010. cited by applicant .
European Search Report from related EP Applicaton No. 08250931.6 dated Jul. 7, 2009. cited by applicant .
European Search Report from related EP Application No. 10156454.0 dated Jul. 22, 2010. cited by applicant .
European Examination Report dated Nov. 23, 2010 for related EP Application No. 10156454.0. cited by applicant .
NERAC (computerized literature search) performed by Jeffrey Casavant, Sep. 29, 1998. cited by applicant .
Barbara Bieganska et al., Influence of Barrier Pigments on the Performance of Protective Organic Coatings, Progress in Organic Coatings, 16 (1988) pp. 219-229, Elsevier Sequoia, Netherlands. cited by applicant.
Attorney, Agent or Firm: McDonnell Boehnen Hulbert & Berghoff LLP Patel; Nirav P.
1. A composite coating system comprising: a corrosion resistant primer formed from an epoxy thermoset primer composition that includes an epoxy resin with the proviso that the epoxy resin does not have an EEW of 860 to 930, and a polyhydroxyl functional phenolic curing agent having a HEW of 200 to 500, a platy filler, wherein said epoxy thermoset primer is substantially zinc-free; and a topcoat, and wherein the topcoat is formed from an epoxy thermoset topcoat composition that includes an epoxy resin having an EEW of 450 to 1400, an elastomer-modified epoxy resin having an EEW of 1000 to 1600, a foaming agent that is p,p'-oxybis(benzenesulfonylhydrazide), activated azodicarbonamide based compositions, or a p-toluenesulfonylhydrazide based foaming agents, and a reinforcing fiber, wherein the epoxy resin in the epoxy resin thermoset topcoat composition is a bisphenol A epoxy resin present in an amount from 10 to 85 parts per hundred resin.
2. The composite coating system of claim 1, wherein the epoxy topcoat further comprises a carboxyl functional polyester resin with an acid number of 25 to 85 mg KOH/g.
3. A high tensile steel alloy coated by the composite coating of claim 2.
4. The composite coating system of claim 1, wherein the epoxy resin of the epoxy thermoset primer composition has an EEW of between 730 and 1400 with proviso that the epoxy resin of the epoxy thermoset primer composition does not have an EEW of between 860 and 930 or wherein the epoxy resin of the epoxy thermoset primer composition has an EEW of between 780 and 900 with the proviso that the epoxy resin of the epoxy thermoset primer composition does not have an EEW of between 860 and 930.
5. The composite coating system of claim 1, wherein the epoxy resin of the epoxy thermoset primer composition has an EEW of between 730 and 820, an EEW of between 1250 and 1400, an EEW of between 750 and 850.
6. The composite coating system of claim 1, further comprising a cure accelerator that includes 2-methylimidazole.
7. The composite coating system of claim 1, wherein the platy filler includes complex aluminosilicate (mica), or magnesium silicate (talc), or a combination thereof.
8. The composite coating system of claim 7, wherein the platy filler includes complex aluminosilicate (mica) present in an amount from 10 to 40 phr and with a median particle size of from 10 to 35 microns.
9. The composite coating system of claim 7, wherein the platy filler further includes glass flakes having a nominal thickness of 1.3-2.3 microns.
10. The composite coating system of claim 7, wherein the platy filler includes magnesium silicate (talc) present in an amount of from 10 to 40 phr and with a median particle size of from 10 to 35 microns.
11. The composite coating system of claim 1, wherein said elastomer-modified epoxy resin comprises a bisphenol A epoxy resin present in an amount from 5 to 35 parts per hundred resin.
12. The composite coating system of claim 1, wherein the epoxy thermoset primer contains zero zinc.
13. The composite coating system of claim 1, wherein said reinforcing fiber comprises aluminosilicate, wollastonite, aramid, carbon, or a combination thereof.
14. A high tensile steel alloy coated by the composite coating of claim 1.
The invention relates to corrosion and chip resistant coating compositions that can be used for highly stressed steel such as automotive springs, and to highly stressed steel coated with the coating compositions.
Compositions for coating steel are generally well known in the art. U.S. Pat. No. 5,334,631 discloses a coating composition comprising an epoxy resin, a curing agent, lamellar zinc and zinc dust. A second layer may be applied as a topcoat coating, such as a powder coating composition based on a polyester resin as a binder and an epoxy group containing component, such as trisglycidylisocyanurate, as a curing agent. Stated applications for this coating are metals such as iron, steel, copper and aluminum, with examples showing use on the outside of a gas tank.
U.S. Pat. No. 7,018,716 discloses a coating comprising an epoxy resin that contains zinc, either as a single coat or as a primer coat, with a topcoat that does not contain zinc, and is reinforced by the addition of fibers and/or by a foaming agent which renders it porous. Stated applications for this coating include high tensile stress steel, such as coil springs.
U.S. Pat. No. 4,804,581 discloses a metal substrate coated with an elastomer-modified epoxy-containing coating primer and a carboxyl-functional material, such as a carboxyl-functional polyester resin, as a top-coat. The coating composition is said to be useful in automotive applications to provide desired anti-chip protection, but the examples show use on grounded steel panels, not highly stressed steel items, such as springs.
For the protection of high tensile strength springs, earlier coating systems used most preferably a combination of a zinc-rich epoxy thermoset primer for exceptional corrosion resistance with an overlying coating of a thermoplastic topcoat applied at a high film thickness to provide superior chip resistance (U.S. Pat. No. 5,981,086). In some cases, epoxy electrocoat was substituted for the zinc-rich primer.
Although typically poorer in chip resistance and cold temperature physical properties, U.S. Pat. No. 7,018,716 reports an epoxy thermoset topcoat with competing performance to the thermoplastic topcoat at reduced cost. Changes in the marketplace with respect to increased demand for zinc metal and associated higher prices have made zinc containing coatings less attractive. The applied cost of zinc containing coatings has also been also hurt by their relatively high density which equates to higher material usage in relation to area coated. Accordingly, there is a need for substantially non-zinc containing coatings for applications such as highly stressed steel.
The present invention relates to corrosion and chip resistant dual-coat powder coating systems, in which an epoxy thermoset primer primarily provides for corrosion resistance and an epoxy thermoset topcoat primarily provides for chip resistance. The present invention also relates to single-coat powder coating systems, in which an epoxy thermoset primer is applied without a topcoat. In some embodiments, the coating systems are useful for high tensile steel alloys such as automotive suspension springs.
In one embodiment of the invention, a coating composition comprises: (I) an epoxy thermoset primer comprising: (i) an epoxy resin; (ii) a polyhydroxyl functional phenolic curing agent having a HEW of about 200 to about 500; and (iii) a platy filler, wherein said epoxy thermoset primer contains less than 20 wt % zinc.
In some embodiments of the invention, the coating composition comprises an epoxy resin with the proviso that the epoxy resin does not have an epoxy equivalent weight (EEW) of about 860 to about 930.
In some embodiments of the invention, the coating composition further comprises an epoxy thermoset topcoat comprising: (i) an epoxy resin having an EEW of about 520 to about 1300; (ii) an elastomer-modified epoxy resin having an EEW of about 1000 to about 1600; (iii) a foaming agent; and (iv) a reinforcing fiber.
Other embodiments of the invention include methods for applying coating compositions to high tensile steel alloys, and high tensile steel alloys such as springs coated with the compositions.
Other than in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties sought to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should be construed in light of the number of significant digits and ordinary rounding approaches. Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical values, however, inherently contain certain errors necessarily resulting from the standard deviation found in their respective testing measurements. Unless stated otherwise, all percentages, ratios and proportions herein are by weight and particularly unless otherwise specifically stated, the proportions of the components in the compositions described are given in percentage pertaining to the total mass of the mixture of these components.
Also herein, "a," "an," "the", "at least one", and "one or more" are used interchangeably.
Also herein, the term "comprises" and variations thereof do not have a limiting meaning where these terms appear in the description and claims.
The terms "for example" and the like, as well as the exemplary compounds, ranges, parameters and the like disclosed throughout the application and claims are intended to identify embodiments of the invention in a non-limiting manner. Other compounds, ranges, parameters and the like can be employed by those skilled in the art without departing from the spirit and scope of the invention.
Driven by design considerations and lighter weight components to aid in fuel economy, automobile manufacturers are increasingly employing lighter weight, high tensile strength suspension springs in their vehicle designs. These springs with their lower metal mass achieve the strength of more massive springs through a combination of the specific steel alloy used in conjunction with other processing aspects.
Offsetting some of the advantages, the highly engineered properties of these springs are achieved at some cost in terms of their overall potential for breakage. Typically, since such springs are much harder and operate with much higher internal stresses, relatively little metal mass loss produced by corrosion pitting for example can cause spring breakage. Since vehicle suspensions can be subjected to extremely corrosive environments, particularly in northerly climates with the use of various road salts, protective coatings with exceptional chip resistance to flying gravel and corrosion resistance must be used to thoroughly protect high tensile strength springs.
Conventional powder coating systems include primers which typically contain zinc in amounts in excess of 50 wt % in order to provide corrosion resistance. The primers of the present invention satisfy the corrosion and chip resistance standards of the automotive industry, yet the primers may contain less than 20 wt % zinc. In some embodiments of the invention, the primer contains zinc in an amount of less than 20 wt %. In some embodiments, the primer contains zinc in an amount of less than about 15 wt %. In some embodiments, the primer contains zinc in an amount of less than about 10 wt %. In some embodiments, the primer contains zinc in an amount of less than about 5 wt %. In some embodiments, the primer is substantially zinc-free. In some embodiments, the primer contains zero zinc. In such embodiments, the zinc content includes any amount of zinc that may comprise a platy filler. A primer that contains less than 20 wt % zinc, less than about 15 wt % zinc, less than about 10 wt % zinc, or less than about 5 wt % zinc includes a primer that is substantially zinc-free and also includes a primer that contains zero zinc. The topcoats of the invention may contain zinc, may contain zinc in an amount of less than about 50 wt %, may contain zinc in an amount of less than about 25 wt %, may contain zinc in an amount of less than about 5 wt %, may be substantially zinc-free, or may contain zero zinc. Similarly, a topcoat that contains less than about 50 wt % zinc, less than about 25 wt % zinc, or less than about 5 wt % zinc includes a topcoat that is substantially zinc-free and a topcoat that contains zero zinc.
Although the use of primers and topcoats of the invention fulfill a need in terms of lower cost protective coatings for highly stressed steel and particularly high tensile strength suspension springs, discrete primers and topcoats may be selected due to the somewhat contrary properties of corrosion resistance and chip resistance. Those primers and topcoats which possess good corrosion resistance do not always have the best chip resistance and vice versa.
One of the main functions of the primers of the present invention which may be applied over zinc phosphate pretreated steel is to provide corrosion resistance. In addition, some measure of chip resistance may also be provided by the primer to accommodate those cases where less than ideal topcoat thickness is used. Accordingly, the primers of the present invention provide corrosion and chip resistance by containing an epoxy resin, a polyhydroxyl functional phenolic curing agent having a hydroxyl equivalent weight (HEW) of about 200 to about 500, and a platy filler.
Epoxy resins for use in the present invention may be obtained from The Dow Chemical Company and can be identified by their EEW range. Some epoxy resins may have overlapping EEW ranges but are nonetheless distinguishable. For example, The Dow Chemical Company supplies the epoxy resin D.E.R..TM. 671 having an EEW of about 475 to about 550 as well as the epoxy resin D.E.R..TM. 661 having an EEW of about 450 to about 560.
In some embodiments, an epoxy resin is selected such that the EEW is between a lower limit of about 730 and an upper limit of about 1400. In some embodiments, the primer comprises an epoxy resin with the proviso that the epoxy resin does not have an EEW of about 860 to about 930. In some embodiments, an epoxy resin is selected such that the EEW is between a lower limit of about 730 and an upper limit of about 1400, with the proviso that the epoxy resin does not have an EEW of about 860 to about 930. An epoxy resin having an EEW of about 860 to about 930 is available from The Dow Chemical Company as D.E.R..TM. 664UE. For non-limiting example, an epoxy resin such as D.E.R..TM. 6155 having an EEW of about 1250 to about 1400 is an example of an epoxy resin having an EEW between the lower limit of about 730 and the upper limit of about 1400. Also, for non-limiting example, the epoxy resin D.E.R..TM. 6330-A10 available from The Dow Chemical Company having an EEW of about 780 to about 900 is not considered to be an epoxy resin having an EEW of about 860 to about 930, even though the EEW ranges overlap.
The epoxy resin may be, for non-limiting example, a bisphenol A epoxy resin having an EEW of about 730 to about 820, a bisphenol A epoxy resin having an EEW of about 1250 to about 1400, a bisphenol A epoxy resin having an EEW of about 780 to about 900, a bisphenol A epoxy resin having an EEW of about 750 to about 850, a bisphenol A epoxy resin having an EEW of about 730 to about 840, a bisphenol A epoxy resin having an EEW of about 1150 to about 1300, or a combination thereof. Such epoxy resins are available from The Dow Chemical Company as D.E.R..TM. 663U, D.E.R..TM. 6155, D.E.R..TM. 6330-A10, and D.E.R..TM. 672U and from The Kukdo Chemical Company as KD213 and KD214M, respectively.
As used herein and further illustrated in the examples, the term "an effective amount" of an epoxy resin, an "effective amount" of a polyhydroxyl functional phenolic curing agent, and an "effective amount" of a filler material respectively describe amounts of epoxy resin, polyhydroxyl functional phenolic curing agent and filler material that contribute to a primer which satisfies industrially acceptable corrosion resistance standards for the intended application, such as in the case of high tensile suspension springs GM specification GMW14656.
Some embodiments employ an effective amount of an epoxy resin for use in the primers of the present invention including, for non-limiting example, epoxy resins based on 2,2-bis-(4-hydroxyphenol)-propane with softening points of between about 80.degree. C. and about 125.degree. C. For non-limiting example, the softening point is between about 90.degree. C. and about 115.degree. C. The epoxy resin may be chosen from a variety of epoxy resins useful for coating powders, such as, without limitation, those produced by the reaction of epichlorohydrin or polyglycidyl ether and an aromatic polyol such as, without limitation, bisphenol, e.g., bisphenol A. The epoxy resin may have an epoxy functionality greater than 1.0, and alternatively greater than 1.9.
Such epoxy resins may be produced, for non-limiting example, by an etherificiation reaction between an aromatic or aliphatic polyol and epichlorohydrin or dichlorohydrin in the presence of an alkali such as, without limitation, caustic soda. The aromatic polyol may be, for non-limiting example, bis(4-hydroxyphenyl)-2,2-propane (i.e. bisphenol A), bis(4-hydroxyphenyl)-1,1-ethane, bis(4-hydroxyphenyl)-1,1-isobutane, bis(4-hydroxy-t-butylphenyl)-2,2-propane, bis(2-hydroxynaphthyl)methane, 4,4'-dihdyroxybenzophenone or 1,5-pentanediol, 1,6-hexanediol, diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, dipropylene glycol, a diglycidyl ether or a condensed glycidyl ether of a diol. Oxirane group-containing polymers that can be used as the epoxy resin in primers according to this invention include, without limitation, polyglycidyl-functional acrylic polymers or epoxy novolac resins.
Other epoxy resins for use in the primer include, for non-limiting example, epoxidized phenol-novolac resins with a softening point between about 80.degree. C. and about 125.degree. C. In some embodiments, the softening point is between about 90.degree. C. and about 115.degree. C. In some embodiments, a diglycidyl ether of bisphenol-A (DGEBA) novolac modified epoxy resin is used.
In some embodiments of the invention, the bisphenol A epoxy resin is obtained, for non-limiting example, from condensation polymerization of bisphenol A with epichlorohydrin. Other resin chemistries can be employed such as, without limitation, a bisphenol A epoxy resin cured with dicyandiamine or co-reacted with a carboxy functional polyester (hybrid).
The amount of the epoxy resin or combination of epoxy resins in the primer may vary in relation to the amounts of the additives and fillers. For non-limiting example, per the phr (parts per hundred resin) formula convention, the resin and curing agent total is set at 100 parts. The percent of the total epoxy resin in the formulation then varies as a function of additives and filler phr level. In some embodiments, the epoxy resin or combination of epoxy resins is present in an amount from about 35 to about 95 parts of the available 100 parts.
In some embodiments of the invention, the primer contains an effective amount of a polyhydroxyl phenolic curing agent. The polyhydroxyl functional phenolic curing agent may contain 2-methylimidazole. In some embodiments, the polyhydroxyl functional phenolic curing agent has a hydroxyl equivalent weight (HEW) of from about 200 to about 500. The polyhydroxyl functional phenolic curing agent may be formed from bisphenol A termination of low molecular weight diglycidyl ethers of bisphenol A. In some embodiments, the curing agent is a phenolic curing agent having a HEW of about 240 to about 270 and contains about 2% of a 2-methylimidazole cure accelerator.
The amount of the curing agent or combination of curing agents may vary in relation to the amounts of the additive and filler. For non-limiting example, per the phr (parts per hundred resin) formula convention, the resin and curing agent total is set at 100 parts. The percent of the total curing agent in the formulation then varies as a function of additive and filler phr level. In some embodiments, the curing agent or combination of curing agents is present in an amount from about 5 to about 65 parts of the available 100 parts.
The primers of the present also include an effective amount of a platy filler material. Platy filler materials for use in the present invention include, for non-limiting example, about a 10 to about 35 .mu.m median particle size complex aluminosilicate (muscovite mica), about a 10 to about 35 um median particle size magnesium silicate (talc), about a 150 to about 200 um median particle size C modified composition glass flake, and combinations thereof. Theses fillers have platy particle geometry and tend to orient parallel to the primer coating layer which improves corrosion resistance through improved barrier properties. The median particle size for the muscovite mica, talc and glass flake has been established by sedigraph (sedimentation analysis) and is used in some embodiments at about 10 to about 40 phr (parts per hundred of resin). In some embodiments, the platy filler may comprise lamellar zinc in an amount less than 20 wt %. As noted above, in such an embodiment, the less than 20 wt % zinc content includes any amount of zinc that may comprise a platy filler.
In some embodiments of the invention, the primer may include fillers, such as without limitation complex aluminosilicate (muscovite mica), calcium metasilicate (wollastonite), micronized magnesium silicate (talc), zinc oxide powder, zinc dust, quartz powder, aluminum silicates, calcium silicates, magnesium silicates, calcium carbonate, barium sulphate, calcium sulphate, aluminum oxide, glass flake, C modified composition glass flake, and combinations thereof.
Some embodiments of the invention include about a 2 to about 15 .mu.m median particle size calcium metasilicate (wollastonite), and/or about a 0.5 to about 3.0 .mu.m median particle size micronized magnesium silicate (talc). These fillers function to improve corrosion resistance through a combination of pH regulation and moisture absorption properties. Median particle sizes for the wollastonite and micronized talc have been established by laser diffractive technique and are used in some embodiments at about 10 to about 40 phr and about 1 to about 8 phr respectively.
In some embodiments, the topcoat includes an effective amount of an epoxy resin having an EEW of about 520 to about 1300. The epoxy resin may be, for non-limiting example, a bisphenol A epoxy resin having an EEW of about 730 to about 820, a bisphenol A epoxy resin having an EEW of about 860 to about 930, a bisphenol A epoxy resin having an EEW of about 520 to about 560, a bisphenol A epoxy resin having an EEW of about 730 to about 840, or a bisphenol A epoxy resin having an EEW of about 1150 to about 1300. Such epoxy resins are available from The Dow Chemical Company and from The Kukdo Chemical Company.
As used herein, the term "an effective amount" of an epoxy resin, an "effective amount" of an elastomer-modified epoxy resin, an "effective amount" of a carboxyl functional polyester resin, an "effective amount" of a foaming agent, and an "effective amount" of a reinforcing fiber respectively describe an amount of epoxy resin, elastomer-modified epoxy resin, carboxyl functional polyester resin, foaming agent, and reinforcing fiber that contribute to a topcoat which satisfies industrially acceptable standards for the intended application, such as in the case of high tensile suspension springs, GM specification GMW14656. Non-limiting examples of epoxy resins for use in the topcoat include epoxy resins based on 2,2-bis-(4-hydroxyphenol)-propane with softening points of between about 80.degree. C. and about 125.degree. C.
The amount of the epoxy resin or combination of epoxy resins in the topcoat may vary in relation to the amounts of the additive and reinforcing fiber. For non-limiting example, per the phr (parts per hundred resin) formula convention, the epoxy resin, the elastomer-modified epoxy resin and, optionally, the carboxyl functional polyester resin total is set at 100 parts. The percent of the total epoxy resin in the formulation then varies as a function of additives and reinforcing fiber phr level. In some embodiments, the epoxy resin or combination of epoxy resins is present in an amount from about 10 to about 85 parts of the available 100 parts.
The epoxy resin may be chosen from a variety of epoxy resins useful for coating powders, such as, without limitation, those produced by the reaction of epichlorohydrin or polyglycidyl ether and an aromatic polyol such as, without limitation, bisphenol, e.g., bisphenol A. The epoxy resin may have an epoxy functionality greater than 1.0, and alternatively greater than 1.9. Generally, the epoxy equivalent weight may be from about 450 to about 1400, and alternatively from about 520 to about 1300.
Epoxy resins may be produced, for non-limiting example, by an etherificiation reaction between an aromatic or aliphatic polyol and epichlorohydrin or dichlorohydrin in the presence of an alkali such as, without limitation, caustic soda. The aromatic polyol may be, for non-limiting example, bis(4-hydroxyphenyl)-2,2-propane (i.e. bisphenol A), bis(4-hydroxyphenyl)-1,1-ethane, bis(4-hydroxyphenyl)-1,1-isobutane, bis(4-hydroxy-t-butylphenyl)-2,2-propane, bis(2-hydroxynaphthyl)methane, 4,4'-dihdyroxybenzophenone or 1,5-pentanediol, 1,6-hexanediol, diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, dipropylene glycol, a diglycidyl ether or a condensed glycidyl ether of a diol. Oxirane group-containing polymers that can be used as the epoxy resin in the topcoats according to this invention include, without limitation, polyglycidyl-functional acrylic polymers or epoxy novolac resins. In some embodiments, a diglycidyl ether of bisphenol-A (DGEBA) novolac modified epoxy resin is used.
The topcoat includes an effective amount of an elastomer-modified epoxy resin having an EEW of about 1000 to about 1600. In some embodiments of the invention, the elastomer-modified epoxy resin is a bisphenol A epoxy resin which has been adducted with CTBN (carboxyl terminated butadiene acrylonitrile) rubber producing a composite resin with an EEW of about 1250 to about 1500 g/eq or about 1100 to about 1300 g/eq. In some embodiments, the Tg is about 30 to about 50.degree. C. Tg is the Glass Transition Temperature which is the critical temperature at which a non-crystalline material changes its behavior from a `glassy` to `rubbery` state. `Glassy` in this context means hard and brittle (and therefore relatively easy to break), while `rubbery` means elastic and flexible.
The amount of the elastomer-modified epoxy resin or combination of elastomer-modified epoxy resins in the topcoat may vary in relation to the amounts of the additives and reinforcing fiber. For non-limiting example, per the phr (parts per hundred resin) formula convention, the epoxy resin, the elastomer-modified epoxy resin and the carboxyl functional polyester resin total is set at 100 parts. The percent of the total elastomer-modified epoxy resin in the formulation then varies as a function of additive and reinforcing fiber phr level. In some embodiments, the elastomer-modified epoxy resin or combination of elastomer-modified epoxy resins is present in an amount from about 5 to about 35 parts of the available 100 parts.
In some embodiments of the invention, the topcoat also includes an effective amount of a carboxy functional polyester resin with an acid number of about 25 to about 85 mg KOH/g or from about 45 to about 75 mg KOH/g for enhanced chip resistance.
The amount of the carboxy functional polyester resin or combination of carboxy functional polyester resins in the topcoat may vary in relation to the amounts of the additives and reinforcing fiber. For non-limiting example, per the phr (parts per hundred resin) formula convention, the epoxy resin, the elastomer-modified epoxy resin and the carboxyl functional polyester resin total is set at 100 parts. The percent of the total carboxy functional polyester resin in the formulation then varies as a function of additives and reinforcing fiber phr level. In some embodiments, the carboxy functional polyester resin or combination of carboxy functional polyester resins is present in an amount from about 30 to about 85 parts of the available 100 parts.
The carboxyl-functional polyester resins can be prepared by any commonly known method, such as for non-limiting example, condensation reactions between aliphatic di- or poly-hydric alcohols and cycloaliphatic, acyclic or aliphatic di- or poly-carboxylic acids or anhydrides thereof, or between aliphatic dihydric alcohols and aromatic di- or poly-carboxylic acids or anhydrides thereof. For non-limiting example, the carboxyl-functional polyester resins can be prepared from aliphatic di- or poly-hydric alcohols, particularly lower aliphatic diols such as, without limitation, ethylene glycol, 1,2-propane diol, 1,3-propane diol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,2-dimethyl propane-1,3-diol (i.e., neopentyl glycol), 1,6-hexanediol, 2,3-hexanediol, 2,5-hexanediol, diethylene glycol or dipropylene glycol. Polyols such as, without limitation, trimethylolpropane or the like can also be used to prepare the carboxyl-functional polyesters. Examples of suitable di- or poly-carboxylic acids and anhydrides include, without limitation, phthalic acid, isophthalic acid, terephthalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetrahydrophthalic acid, hexahydrophthalic acid, and maleic acid and anhydrides of such acids. In some embodiments, the carboxyl-functional polyester resin is an aromatic containing polyester, for non-limiting example, a polyester prepared from aromatic carboxylic acid such as, without limitation, phthatic acid, isophthalic acid or terephthalic acid and a polyol such as, without limitation, neopentyl glycol.
An effective amount of a foaming/blowing agent additive is present in the topcoat to establish a porous structure within the coating film. The porous structure imparts physical properties to the coating such as the ability to absorb impact energy without fracturing.
In other embodiments of the invention, commercially desirable porosity for high tensile suspension springs is achieved when the cured topcoat exhibits about a 15% to about 50% reduction in density from that of the theoretical topcoat density without porosity. The cured topcoat density is calculated by the ratio of measured coating weight on a coated panel to coating volume on the same panel. Coating volume on the coated panel is arrived at in an integrative fashion by deriving the average coating thickness with multiple measurements taken across the subdivided panel which is then multiplied by panel area. In some embodiments, the foaming and blowing agents are used at about 0.2 to about 2.0 phr (parts per hundred of resin). Foaming agents with p,p'-oxybis(benzenesulfonylhydrazide) and activated azodicarbonamide based compositions are employed in some embodiments. Other foaming agents include, without limitation, p-toluenesulfonylhydrazide based foaming agents
An effective amount of a reinforcing fiber is present in the topcoat to recover any loss of strength caused by the presence of a foaming/blowing agent. For non-limiting example, a range of aluminosilicate glass fibers or natural mined calcium metasilicate (wollastonite) fibers can be employed. An average diameter of about 3 to about 15 um and an average aspect ratio (within the context of coatings fillers, aspect ratio is defined as the ratio of a filler particle's largest dimension to its smallest) of about 5 to about 20 is employed in some embodiments. Other reinforcing fibers such as, without limitation, aramid and carbon could be used as well. Reinforcing fibers in the amount of about 20 to about 70 phr are employed in some embodiments of the invention. In some embodiments, the reinforcing fiber is the E-glass silane treated glass fibers with a diameter of 16 microns and a length of 150 microns, commercially available from Fibertec.
The primers and topcoats can also include additives, such as, without limitation, pigments, catalysts/curing agents, degassing agents, flow control agents and antioxidants.
Pigments for use in the primer and topcoat compositions of the invention include, for non-limiting example, titanium dioxide, iron oxide (yellow, brown, red, black), carbon black and organic pigments. These pigments can be added in conventional amounts known to those in the art.
In addition to the phenolic curing agents described above present in the primer, the coating composition can include catalyst/curing agent additives such as for non-limiting example, quaternary ammonium salts, quaternary phosphonium salts, phosphines, imidazoles metal salts, and combinations thereof. Examples of such additives include, without limitation, tetrabutylammonium chloride, tetrabutylammonium bromide or tetrabutylammonium iodide, ethyltriphenyl phosphonium acetate, triphenylphosphine, 2-methyl imidazole, dibutyltin dilaurate, and combinations thereof. The catalyst/curing agent, when used in some embodiments, is present in the composition in amounts of between about 0 and about 5 weight percent, and alternatively from about 0.2 to about 2 percent by weight based on total weight of the coating composition.
The topcoat may include an effective amount of a curing agent in some embodiments of the invention. The curing agent may be a polyhydroxyl functional phenolic curing agent that contains 2-methylimidazole. In some embodiments, the polyhydroxyl functional phenolic curing agent has a hydroxyl equivalent weight (HEW) of from about 200 to about 500. The polyhydroxyl functional phenolic curing agent may be formed from bisphenol A termination of low molecular weight diglycidyl ethers of bisphenol A. In some embodiments, the curing agent is a phenolic curing agent having a HEW of about 230 to about 260 and contains a 2-methylimidazole cure accelerator.
The amount of the curing agent or combination of curing agents may vary in relation to the amounts of the additives and the reinforcing fiber. For non-limiting example, per the phr (parts per hundred resin) formula convention, the elastomer-modified epoxy resin and the carboxyl functional polyester resin total is set at 100 parts. The percent of the total curing agent in the formulation then varies as a function of additives and reinforcing fiber phr level. In some embodiments, the curing agent or combination of curing agents is present in an amount from about 5 to about 65 parts of the available 100 parts.
A degassing agent can be added to the composition to allow any volatile material present to escape from the film during baking. Benzoin is a degassing agent and when used in some embodiments can be present in amounts from about 0.5 to about 3.0 percent by weight based on total weight of a powder coating composition.
Flow control agents include, without limitation, lower molecular weight acrylic polymers, for non-limiting example, acrylic polymers, such as without limitation acrylic polymers having a number average molecular weight from about 1000 to about 50,000, such as, without limitation, polylauryl acrylate, polybutyl acrylate, poly(2-ethylhexyl)acrylate, poly(ethylacrylate-2-ethylhexylacrylate), polylauryl methacrylate and polyisodecyl methacrylate, and fluorinated polymers such as, without limitation, the esters of polyethylene glycol or polypropylene glycol and fluorinated fatty acids. Polymeric siloxanes of molecular weights over about 1,000 may also be used as a flow control agent, for non-limiting example, poly(dimethylsiloxane) or poly(methylphenyl)siloxane. Flow control agents can aid in the reduction of surface tension during heating of the coating powder and in elimination of crater formation. In some embodiments, the flow control agent when used is present in amounts of from about 0.05 to about 5.0 percent by weight based on the total weight of a powder coating composition.
Antioxidants include, without limitation, phenolic, phosphite, phosphonite and lactone-type antioxidants, as well as combinations thereof. In some embodiments, the antioxidants are present in an amount of from about 0 to about 3 wt %.
The coating compositions of the present invention are especially suitable for application to metals, such as, without limitation, automotive springs. However, it is also possible to apply the coating compositions to carbon, wood, glass, polymers and other substrates.
Application of the above described primer and topcoat compositions to high tensile steel can be accomplished by any known techniques, such as, without limitation, the following Methods 1 through 3. Regardless of the application technique used, the composite coating (primer & topcoat) formed on the high tensile steel alloy may contain a discrete primer, for non-limiting example from about 1.5 to about 4.0 mils thick, in contact with the pretreated steel surface. The topcoat of the composite coating may also form a discrete topcoat, for non-limiting example from about 10 to about 35 mils thick, which is bonded to the underlying primer layer. The coating composition may also be applied with a primer and without a topcoat.
1. Method 1--The steel is heated to about 220 to about 380.degree. F. for more ideal deposition followed by successive application of the primer and topcoat. The coated steel is then heated again to create a composite coating layer and achieve full property development on the coating system. 2. Method 2--The primer is applied to ambient temperature high tensile steel alloy followed by heating to about 220 to about 380.degree. F. to fuse or partially cure the coating. The topcoat is applied to the hot steel using ideally residual heat remaining from the primer heating. The coated steel is then heated again to create a composite layer and achieve full property development on the coating system. 3. Method 3--The primer and topcoat are applied successively to ambient temperature high tensile steel in a "dry on dry" powder fashion followed by a single heat cycle of about 220 to about 380.degree. F. to create a composite coating layer and achieve full property development on the coating system.
Seventeen primer and nine topcoat compositions were prepared in accordance with the above Method 1 from the following mixtures of ingredients:
TABLE-US-00001 Primer Examples Comp Comp Comp Comp Component 1 2 3 4 5 6 7 8 Bisphenol A Epoxy Resin A.sup.1A 75.14 73.24 71.72 71.17 55.42 Bisphenol A Epoxy Resin B.sup.1A 86.33 29.13 83.19 Bisphenol A Epoxy Resin C.sup.1A 16.30 Bisphenol A Epoxy Resin D.sup.1A 8.56 10.46 11.98 12.53 11.98 13.70 12.08 16.81 (Contains Acronal 4F Flow Modifier) Carboxyl Polyester Resin A.sup.2A 58.79 Phenolic Curing Agent.sup.3 16.30 16.30 16.30 16.30 16.30 (Contains 2-Methylimidazole) Casamid 710.sup.4 Epikure P-108.sup.5 5.00 5.45 2-Methylimidazole 0.38 Benzoin.sup.6 0.36 0.44 0.51 0.53 0.51 0.53 0.53 Black Pearls 800.sup.7 0.31 0.38 0.44 0.46 0.44 0.46 0.46 Tiona 595t.sup.8 3.12 3.80 4.36 4.56 4.36 4.56 7.64 Muscovite Mica Filler.sup.9 22.20 25.42 26.58 25.42 26.69 Calcium Metasilicate 14.52 15.19 14.52 41.77 15.24 (Wollastonite) Filler.sup.10 K-White TC720.sup.11 4.56 4.56 4.57 AZO77H.sup.12 29.13 9.17 Zinc Dust 64.sup.13 183.39 Weight Totals 103.79 126.82 145.25 151.88 145.25 151.88 152.44 305.65 Primer Examples Comp Comp Comp Component 9 10 11 12 13 14 15 16 17 Bisphenol A Epoxy Resin A.sup.1A 55.16 55.16 53.05 43.67 43.67 55.10 Bisphenol A Epoxy Resin B.sup.1A 69.35 29.13 Bisphenol A Epoxy Resin C.sup.1A 16.30 16.30 73.44 16.33 Bisphenol A Epoxy Resin D.sup.1A 12.24 12.24 12.24 12.24 12.24 12.08 12.08 12.08 12.24 (Contains Acronal 4F Flow Modifier) Bisphenol A Epoxy Resin H.sup.1B 16.30 (Novolac Modifed) Carboxyl Polyester Resin B.sup.2B 44.25 44.25 58.79 Phenolic Curing Agent.sup.3 16.30 16.30 18.41 14.32 18.41 16.33 (Contains 2-Methylimidazole) Tetrabutylammonium Bromide 0.20 0.20 0.20 Benzoin.sup.6 0.53 0.53 0.53 0.53 0.53 0.53 0.53 0.53 0.52 Black Pearls 800.sup.7 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.45 Tiona 595t.sup.8 4.56 4.56 4.56 4.56 4.56 4.56 4.56 7.64 4.45 Irganox 1076.sup.16 0.45 Muscovite Mica Filler.sup.9 26.58 26.58 26.58 26.58 24.12 Calcium Metasilicate 15.19 15.19 15.19 15.19 15.19 41.77 15.19 14.84 (Wollastonite) Filler.sup.10 Glass Flake (Modified C 26.58 Type).sup.14 Magnesium Silicate (Talc) 26.58 Filler.sup.15 K-White TC720.sup.11 4.56 4.56 4.56 4.56 4.56 4.56 4.56 3.60 Zinc Dust 64.sup.13 183.39 Weight Totals 151.88 151.88 151.88 151.88 151.88 152.08 152.08 291.76 148.- 43 .sup.1ABisphenol A epoxy resins A, B, C and D have EEW of 860-930, 730-820, 1250-1400, and 780-900 respectively and are commercially available from The Dow Chemical Company. .sup.1BBisphenol A epoxy resin H is novolac modified having an EEW of 750-850 and is commercially available from The Dow Chemical Company. .sup.2ACarboxyl functional polyester resin with acid number of 46-51 mg KOH/g and Tg of ~50.degree. C. commercially available from Cytec Industries Inc. .sup.2BCarboxyl functional polyester resin with acid number of 68-74 mg KOH/g and Tg of ~58.degree. C. commercially available from Cytec Industries Inc. .sup.3Phenolic curing agent with HEW of 240-270 and containing 2% of a 2-Methylimidazole cure accelerator commercially available from The Dow Chemical Company. .sup.4Casamid 710 is a substituted dicyandiamine curing agent commercially available from the Thomas Swan & Co., Ltd. .sup.5Epikure P-108 is an accelerated dicyandiamine commercially available from Hexion Speciality Chemicals. .sup.6Benzoin is a degassing agent commercially available from Aceto Corporation. .sup.7Black Pearls 800 is a carbon black pigment commercially available from Cabot Corporation. .sup.8Tiona 595 is a titanium dioxide pigment commercially available form Millennium Chemicals. .sup.9Muscovite mica filler with average median particle size of 20 um commercially available from Fibertec, Inc. .sup.10Calcium metasilicate (wollastonite) filler with 3.5 um median particle size and aspect ratio of 3 commercially available NYCO Minerals. .sup.11K-White TC720 is a magnesium silicate (talc) anti-corrosive pigment commercially available from the Tayca Corporation. .sup.12AZO77H is a zinc oxide pigment commercially available from U.S. Zinc. .sup.13Zinc dust 64 is zinc powder manufactured by Zinc Corporation of America and distributed through The Cary Company. .sup.14Modified C composition glass flake with nominal thickness of 1.3-2.3 um and 65% between 50-300 um in length commercially available Glass Flake, Ltd. .sup.15Magnesium silicate (talc) filler with 13 um median particle size and top-end particle size of 45 um commercially available from Rio Tinto Minerals. .sup.16Irganox 1076 is a phenolic antioxidant commercially available from BASF.
TABLE-US-00002 Topcoat Examples Comp Comp Comp Comp Comp Component 1 2 3 4 5 6 7 8 9 Bisphenol A Epoxy Resin E.sup.1 50.00 40.00 Bisphenol A Epoxy Resin F.sup.1 45.00 Bisphenol A Epoxy Resin G.sup.1 30.00 30.00 30.00 30.00 30.00 Bisphenol A Epoxy Resin H.sup.12 17.86 Bisphenol A Epoxy Resin I.sup.12 62.50 CTBN Modified Bisphenol A 10.00 10.00 10.00 10.00 10.00 Epoxy Resin A.sup.2 CTBN Modified Bisphenol A 10.71 Epoxy Resin B.sup.13 Carboxyl Polyester Resin A.sup.3 50.00 Carboxyl Polyester Resin B.sup.4 60.00 55.00 60.00 60.00 60.00 60.00 60.00 Phenolic Curing Agent.sup.14 8.93 2-methylimidazole 0.27 Substituted Dicyandiamide.sup.15 0.54 Benzoin 0.54 Polytetrafluoroethylene 2.68 Polyethylene Wax 0.89 Hindered Amine Tinuvin 144.sup.16 0.54 Flow Agent PL-200.sup.17 0.89 Carbon Black Pigment 1.43 Benzyltriethylammonium 0.25 0.34 0.34 0.29 0.32 0.34 0.34 0.34 chloride Bentone 38.sup.5 0.69 0.69 0.69 0.69 0.75 0.81 0.81 0.81 Lanco TF1778.sup.6 1.10 1.11 1.11 1.11 1.20 1.30 1.30 1.30 p,p'-oxybis(benzenesulfonyl- 1.13 1.22 1.22 hydrazide) Foaming Agent.sup.7 Azodicarbonamide Foaming Agent.sup.8 1.05 p-toluenesulfonyl hydrazine 1.07 Forming Agent.sup.22 Black Pearls 800 1.38 1.38 1.38 1.38 1.50 1.62 1.62 1.62 Calcium Metasilicate 48.66 48.58 (Wollastonite) Fibers.sup.9 Aluminosilicate Fibers.sup.10 48.66 E-Glass Fibers.sup.18 35.71 Nepheline Syenite.sup.19 8.93 Barium Sulfate.sup.20 15.95 Calcium Carbonate.sup.21 8.93 Atomite.sup.11 34.51 34.56 34.56 34.53 45.00 8.11 8.11 8.10 Weight Totals 138.03 138.22 138.22 138.12 150.03 162.21 162.21 161.95 178.- 37 Theoretical Coating N/A N/A N/A N/A 1.45 1.53 1.50 1.52 N/A Density(g/cm.sup.3) Porous Coating Density(g/cm.sup.3) N/A N/A N/A N/A 0.98 1.10 0.95 0.92 N/A % Density Reduction N/A N/A N/A N/A 32.40 28.10 36.7 39.5 N/A .sup.1Bisphenol A epoxy resins E, F and G have an EEW of 730-820, 860-930, and 520-560 respectively and are commercially available from The Dow Chemical Company. .sup.2CTBN modified epoxy resin with an EEW of 1250-1500 commercially available from CVC Specialty Chemicals, Inc. .sup.3Carboxyl functional polyester resin with an acid number of 46-51 mg KOH/g and Tg of ~50.degree. C. commercially available from Cytec Industries Inc. .sup.4Carboxyl functional polyester resin with an acid number of 68-74 mg KOH/g and Tg of ~58.degree. C. commercially available from Cytec Industries Inc. .sup.5Bentone 38 is an organoclay rheological modifier commercially available from Elementis Specialties. .sup.6Lanco TF1778 is a polyethylene/PTFE based wax commercially available from Lubrizol Advanced Materials, Inc. .sup.7The p,p'-oxybis(benzenesulfonylhydrazide) foaming agent has a decomposition point of 320.degree. F. with a gas yield of 125 cc/g and is commercially available through Chemtura Corporation. .sup.8The azodicarbonamide foaming agent has decomposition point of 329-356.degree. F. with a gas yield of 180 cc/g and is commercially available through Chemtura Corporation. .sup.9The calcium metasilicate (wollastonite) fibers have an average particle size of 3 um with an aspect ratio of 9 and are commercially available through Fibertec, Inc. .sup.10The aluminosilicate fibers are silane treated and have an average length of 125 .+-. 25 um and are commercially available form Lapinus Fibers. .sup.11Atomite is a calcium carbonate filler commercially available from Imerys Performance Minerals. .sup.12Bisphenol A epoxy resins H and I have an EEW of 730-840 and 1150-1300 respectively and are commercially available from The Kukdo Chemical Company. .sup.13CTBM modified epoxy resin with an EEW 1100-1300 commercially available from The Kukdo Chemical Company. .sup.14Phenolic curing agent with a HEW of 230-260 commercially available from The Kukdo Chemical Company. .sup.15Casamid 710 substituted dicyandiamide commercially available from Thomas Swan & Co., Ltd. .sup.16Commercially available from BASF. .sup.17Commercially available from Estron. .sup.18Silane treated glass fibers with a diameter of 16 microns and a length of 150 microns, commercially available from Fibertec. .sup.19Nepheline Syenite with an average particle size of 2.1 microns, commercially available from Unimin. .sup.20Barium sulfate with an average particle size 1.2-1.5 microns. .sup.21Calcium carbonate with an average particle size 1.7 microns, commercially available from Omya. .sup.22p-toluenesulfonyl hydrazine foaming agent with a decomposition point of 145.degree. C., commercially available from Dongjin Semichem.
Primer Examples Test Data & Comparatives
TABLE-US-00003 Primer 30 Cycles SAE J2334 Cyclic Corrosion (Creep) SAE J400 Chip Resistance Example Min. (mm) Max. (mm) Avg. (mm) Method B-(Rating) Comp. 1 (non-zinc) 4 6 5.3 8A 2 (non-zinc) 1 3 2.4 8A 3 (non-zinc) 0 2 1.3 8A 4 (non-zinc) 0 1 0.4 8A 5 (non-zinc) 1 3 1.9 8A Comp. 6 (non-zinc) 2 5 3.9 8B Comp. 7 (zinc) 2 4 3.2 7B Comp. 8 (zinc) 0 2 1.4 9B Comp. 14 (non-zinc) 3 7 5.4 8A Comp. 15 (non-zinc) 2 6 2.3 8B Comp. 16 (zinc) 1 4 2.1 8B
Topcoat Examples Test Data (with Primer Example 4)
*Testing to Ford specification WSS-M2P177-B1 for high tensile suspension springs which allows no chipping of coating to metal on SAE J400. The chip rating must be a 10.
TABLE-US-00004 Topcoat SAE J400 Chip Resistance-Method B Example Rating Failure Point Pass/Fail Comp. 1 8C Substrate to Primer Fail Comp. 2 8B Substrate to Primer Fail Comp. 3 8B Substrate to Primer Fail Comp. 4 8A-8B Substrate to Primer Fail Comp. 5 8A Substrate to Primer Fail 6 10 N/A Pass 7 10 N/A Pass 8 10 N/A Pass
Substrate: Zinc phosphate pretreated steel panels formed to simulate suspension springs Primer: Example 4 (2.5-3.0 mils) Dual-coat Film Thickness: 15.0-20.0 mils GM Cyclic Corrosion (GMW14782) & GM Impact Resistance (GMW14700) Test Procedure: GMW14782 (Method B) Evaluation Procedure: GM 15282 (Method A) Requirements: 6 mm maximum average creepback and no chipping greater than 3 mm
TABLE-US-00005 GMW14782 (Method B) Primer Example Impact Resistance Maximum Avg. (with Topcoat 6) GMW 14700 Creepback (mm) Pass/Fail Comp. 1 No Chipping Total Adhesion Loss Fail 2 No Chipping 4.6 Pass 3 No Chipping 2.4 Pass 4 No Chipping 1.6 Pass 5 No Chipping 3.9 Pass 9 No Chipping 2.7 Pass 10 No Chipping 2.4 Pass 11 No Chipping 2.6 Pass 12 No Chipping 2.3 Pass 13 No Chipping 2.6 Pass
Topcoat Examples and Test Data (with Primer Example 17)
Test Procedure: GM9984164 specification for dual coat springs.
Substrate: Zinc phosphate pretreated panels formed to simulate suspension springs
Primer: Example 17
Topcoat: Example 9
Dual Coat Film Thickness: 17-23 mils
TABLE-US-00006 Salt Spray ASTM B-117 Scribe Hours GM Requirement Creep Blistering Rusting Pass/Fail 1000 No blistering or face rust 0 None None Pass 2000 Not a GM requirement 0 None None Pass 3000 Not a GM requirement 0 None None Pass
Test Procedure: GM9984164 specification for dual coat springs. Substrate: Zinc phosphate pretreated panels formed to simulate suspension springs Primer: Example 17 Topcoat: Example 9 Dual Coat Film Thickness: 14-16 mils
TABLE-US-00007 Duration Result Pass/Fail 5 cycles No visible stress cracking, corrosion, loss of Pass (10 weeks) adhesion or objectionable changes in appearance
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