Source: https://patents.google.com/patent/US8390121B2/en
Timestamp: 2019-05-23 17:12:25
Document Index: 312068514

Matched Legal Cases: ['art 24', 'art 24', 'art 24', 'art 24', 'art 24', 'art 24', 'art 24', 'art 24', 'art 24', 'Application No. 2010', 'Application No. 10', 'Application No. 10']

US8390121B2 - Semiconductor device and method of manufacture thereof - Google Patents
US8390121B2
US8390121B2 US13/025,633 US201113025633A US8390121B2 US 8390121 B2 US8390121 B2 US 8390121B2 US 201113025633 A US201113025633 A US 201113025633A US 8390121 B2 US8390121 B2 US 8390121B2
US13/025,633
US20110303992A1 (en
2010-06-09 Priority to JP2010-131964 priority
2011-02-11 Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
2011-02-11 Assigned to MITSUBISHI ELECTRIC CORPORATION reassignment MITSUBISHI ELECTRIC CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: YAMAGUCHI, YASUO, MURAKAMI, TAKESHI, OKUMURA, MIKA
2011-12-15 Publication of US20110303992A1 publication Critical patent/US20110303992A1/en
2013-03-05 Publication of US8390121B2 publication Critical patent/US8390121B2/en
A semiconductor device includes a substrate, an element formed on the substrate, a nitride film formed on the substrate, a anti-peel film formed on the nitride film, and a molded resin covering the anti-peel film and the element. The anti-peel film has residual compressive stress.
The present invention relates to a semiconductor device including a molded resin and to a method of manufacturing the device.
Some semiconductor devices include an element, or component, formed on a substrate, and a molded resin covering both the substrate and the element. The molded resin serves to protect the element from external moisture and foreign matter. It should be noted that the molded resin covering the substrate and the element typically extends over the nitride film formed on the substrate or the element, which film serves as a surface protective film. Japanese Laid-Open Patent Publication No. 2006-310508 discloses a semiconductor device including a molded resin over such a nitride film. In this case, the molded resin is preferably in close contact with the nitride film so that there is no space between them.
Nitride films are widely used as surface protective films, since they have superior moisture resistance and mechanical strength. It has been found, however, that since nitride films have high residual tensile stress, the molded resin, if any, covering the films may peel off.
The present invention has been made to solve this problem. It is, therefore, an object of the present invention to provide a semiconductor device which includes a molded resin over a nitride film serving as a surface protective film and which has a construction preventing the peeling of the molded resin. Another object of the present invention is to provide a method of manufacturing such a semiconductor device.
According to one aspect of the present invention, a semiconductor device includes a substrate, an element formed on the substrate, a nitride film formed on the substrate, a anti-peel film formed on the nitride film, and a molded resin covering the anti-peel film and the element. The anti-peel film has residual compressive stress.
According to another aspect of the present invention, a method of manufacturing a semiconductor device, includes the steps of forming a nitride film on a substrate, forming polysilicon on the nitride film, forming a sacrificial film on the nitride film, the sacrificial film being etchable by hydrofluoric acid, forming a conductor by use of the sacrificial film, removing the sacrificial film with hydrofluoric acid, and molding a resin onto the polysilicon.
FIG. 3 is a flowchart illustrating a method of manufacturing a semiconductor device in accordance with the first embodiment;
FIG. 4 is a diagram showing the polysilicon after being formed on the nitride film;
FIG. 5 is a diagram showing the sacrificial film after it is formed;
FIG. 6 is a diagram showing the moving part, the supports, and the sealing member after they are formed;
FIG. 7 is a diagram showing the electrode pads after being formed;
FIG. 8 is a diagram showing the structure after the sacrificial film is etched away by the hydrofluoric acid;
FIG. 9 is a diagram showing the glass cap after being mounted;
FIG. 10 is a plan view of a variation of the semiconductor device of the first embodiment;
FIG. 11 is a plan view of another variation of the semiconductor device of the first embodiment; and
FIG. 1 is a cross-sectional view of a semiconductor device 10 according to a first embodiment of the present invention. This semiconductor device 10 is an acceleration sensor. The semiconductor device 10 includes an Si plate 12. An insulating film 14 is formed over the Si plate 12. A wiring layer 16 is formed in the surface of the insulating film 14. The surface of the insulating film 14 and the surface of the wiring layer 16 form a continuous non-irregular surface. It should be noted that the Si plate 12, the insulating film 14, and the wiring layer 16 may be hereinafter referred to collectively as the substrate 18.
A nitride film 20 is formed on the insulating film 14 and on the wiring layer 16. The nitride film 20 has openings exposing portions of the wiring layer 16. Polysilicon 22 is formed on the nitride film 20. The polysilicon 22 has residual compressive stress.
The semiconductor device 10 includes a moving part 24 also serving as a beam of the acceleration sensor. Supports 26 are formed to support the moving part 24. The supports 26 extend through openings of the nitride film 20 and are in contact with the wiring layer 16. A sealing member 28 is formed on the nitride film 20 and surrounds the moving part 24 and the supports 26. A glass cap 30 is fixed to the top of the sealing member 28. The sealing member 28 and the glass cap 30 define a space 34. The moving part 24 and the supports 26 are encapsulated within the space 34. It should be noted that the moving part 24, the supports 26, the sealing member 28, and the glass cap 30 may be hereinafter referred to collectively as the sensor unit.
Electrode pads 32 are formed on the nitride film 20. The electrode pads 32 are used to make electrical connection to an external device. Portions of the electrode pads 32 extend through openings of the nitride film 20 and are in contact with the wiring layer 16. Therefore, the electrode pads 32 are electrically connected to the supports 26 through the wiring layer 16. A molded resin 36 covers the polysilicon 22, the sensor unit, and the electrode pads 32. The molded resin 36 serves to protect the sensor unit and the electrode pads 32 from moisture and foreign matter.
FIG. 2 is a plan view of the semiconductor device of the first embodiment. The molded resin 36 is omitted from FIG. 2. As shown in FIG. 2, the polysilicon 22 is formed between the sensor unit and the electrode pads 32 and between the electrode pads 32.
FIG. 3 is a flowchart illustrating a method of manufacturing a semiconductor device in accordance with the first embodiment. The method of manufacturing the semiconductor device 10 will be described with reference to FIG. 3. The method begins by forming the polysilicon 22 on the nitride film 20 (step 50). FIG. 4 is a diagram showing the polysilicon 22 after being formed on the nitride film 20.
Next, a sacrificial film 70 is formed on the nitride film 20 (step 52). The sacrificial film 70 is used to define the shapes of the moving part 24, the supports 26, and the sealing member 28. The sacrificial film 70 is removed after use. FIG. 5 is a diagram showing the sacrificial film 70 after it is formed.
The moving part 24, the supports 26, and the sealing member 28 are then formed (step 54). The moving part 24, the supports 26, and the sealing member 28 are conductors. FIG. 6 is a diagram showing the moving part 24, the supports 26, and the sealing member 28 after they are formed. Next, the electrode pads 32 are formed (step 56). FIG. 7 is a diagram showing the electrode pads 32 after being formed.
The sacrificial film 70 is then removed (step 58). Specifically, the sacrificial film 70 is removed by etching in hydrofluoric acid. At that time, the polysilicon 22 remains since it is not etched by the hydrofluoric acid treatment. FIG. 8 is a diagram showing the structure after the sacrificial film 70 is etched away by the hydrofluoric acid.
Next, the glass cap 30 is mounted on the sealing member 28 (step 60). FIG. 9 is a diagram showing the glass cap 30 after being mounted. Lastly, the molded resin portion 36 is formed (step 62). Thus the method manufactures the semiconductor device 10 shown in FIG. 1.
Incidentally it has been found that since nitride films have high residual tensile stress, the molded resin, if any, covering the films may peel off. However, the construction of the semiconductor device 10 of the first embodiment prevents peeling of the molded resin. Specifically, since the polysilicon 22 is formed on the nitride film 20, the residual tensile stress in the nitride film 20 is offset or reduced by the residual compressive stress in the polysilicon 22. With this arrangement, the molded resin 36 is provided to cover the polysilicon 22, which has relatively low stress. Therefore, this construction of the semiconductor device 10 prevents peeling of the molded resin 36 covering the nitride film 20.
The polysilicon 22 is formed between the sensor unit and the electrode pads 32 and between the electrode pads 32, as described above with reference to FIG. 2. Therefore, in the semiconductor device 10 of the first embodiment, peeling of the molded resin between the sensor unit and the electrode pads 32 is prevented, thus preventing shorting between the sensor unit and the electrode pads 32. Further, peeling of the molded resin between the electrode pads 32 is also prevented, thus preventing shorting between these electrode pads.
In order to prevent peeling of the molded resin, care must also be taken in selecting the coefficients of linear expansion of the molded resin and the materials in contact with the molded resin. In the semiconductor device 10 of the first embodiment, the molded resin 36, the polysilicon 22, and the nitride film 20 have coefficients of linear expansion of approximately 17 ppm/K, 2.5 ppm/K, and 2.8 ppm/K, respectively. Thus the coefficient of linear expansion of the molded resin 36 is close to those of the polysilicon 22 and the nitride film 20 in contact with the molded resin 36, thus eliminating the possibility of peeling of the molded resin 36 due to the difference in coefficient of linear expansion between the molded resin 36 and the adjacent materials.
The polysilicon 22 is not etchable by hydrofluoric acid, allowing the polysilicon 22 to be formed before the hydrofluoric acid treatment. This means that the polysilicon 22 can be formed on the surface of the nitride film 20 right after the formation of the film, when the surface is substantially flat. This facilitates the processing of the polysilicon 22, such as patterning of the polysilicon 22.
FIG. 10 is a plan view of a variation of the semiconductor device of the first embodiment. In this semiconductor device, polysilicon 72 is formed to surround the electrode pads 32. This prevents peeling of the molded resin around the electrode pads 32. FIG. 11 is a plan view of another variation of the semiconductor device of the first embodiment. In this semiconductor device, polysilicon 74 is formed to surround the sensor unit and the electrode pads 32. This prevents peeling of the molded resin around the sensor unit and around the electrode pads 32.
Although the semiconductor device 10 is an acceleration sensor, it is to be understood that the present invention is not limited to this particular type of semiconductor device. That is, the present invention may be used in a wide variety of other applications where a molded resin is provided over a nitride film. Further, the sensor unit of the first embodiment may be implemented using any suitable device.
Although in the semiconductor device 10 of the first embodiment the polysilicon 22 is used as an anti-peel film for preventing peeling of the molded resin 36, it is to be understood that the present invention is not limited to this particular material. It should be noted that the anti-peel film must have the following properties: having residual compressive stress; having a coefficient of linear expansion close to those of the nitride film and the molded resin; and being not etchable by hydrofluoric acid. Therefore, any type of anti-peel film having these properties may be used. For example, the anti-peel film may be an amorphous silicon film. It should be further noted that the anti-peel film may be made of material etchable by hydrofluoric acid if the film need not be formed before the hydrofluoric acid treatment.
FIG. 12 is a cross-sectional view of a semiconductor device 76 according to a second embodiment of the present invention. The following description of this semiconductor device 76 will be directed only to the differences from the semiconductor device 10 of the first embodiment, since these semiconductor devices have many features in common. The semiconductor device 76 includes polysilicon 78. The polysilicon 78 is formed not only between the sensor unit and the electrode pads 32 but also immediately under the sealing member 28. This means that both the nitride film 20 and the polysilicon 78 are formed between the sealing member 28 and the wiring layer 16.
In the semiconductor device of the second embodiment, even if the nitride film 20 has defects such as pinholes, they are covered by the high resistance polysilicon 78, which is formed after the formation of the nitride film 20. This reliably prevents shorting between the sealing member 28 and the wiring layer 16, although the wiring layer 16 lies directly below the sealing member 28. It should be noted that the semiconductor device 76 is susceptible of alterations which are the same as or correspond to those that can be made to the semiconductor device of the first embodiment.
Thus the present invention makes it possible to prevent peeling of the molded resin covering a nitride film which is formed as a surface protective film.
The entire disclosure of a Japanese Patent Application No. 2010-131964, filed on Jun. 9, 2010 including specification, claims, drawings and summary, on which the Convention priority of the present application is based, are incorporated herein by reference in its entirety.
an element formed on said substrate;
a nitride film formed on said substrate;
an anti-peel film formed on and in direct contact with said nitride film;
a plurality of electrode pads formed on said substrate; and
a molded resin covering said anti-peel film, said electrode pads and said element and in direct contact with said anti-peel film;
wherein said anti-peel film has residual compressive stress and is formed between said element and said plurality of electrode pads and between said plurality of electrode pads;
wherein said anti-peel film is formed to surround said plurality of electrode pads and said element.
said element is a sensor unit of an acceleration sensor;
said substrate has a wiring layer formed therein;
said sensor unit is electrically connected to said plurality of electrode pads by said wiring layer; and
said anti-peel film is not etchable by hydrofluoric acid.
said element includes a conductor formed on said anti-peel film; and
said substrate has formed therein a wiring layer lying directly below said conductor.
4. The semiconductor device according to claim 1, wherein said anti-peel film is polysilicon or amorphous silicon.
wherein said element is a sensor unit of an acceleration sensor;
wherein said element includes a conductor formed on said anti-peel film; and
US13/025,633 2010-06-09 2011-02-11 Semiconductor device and method of manufacture thereof Active US8390121B2 (en)
JP2010-131964 2010-06-09
US20110303992A1 US20110303992A1 (en) 2011-12-15
US8390121B2 true US8390121B2 (en) 2013-03-05
US13/025,633 Active US8390121B2 (en) 2010-06-09 2011-02-11 Semiconductor device and method of manufacture thereof
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Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:OKUMURA, MIKA;YAMAGUCHI, YASUO;MURAKAMI, TAKESHI;SIGNINGDATES FROM 20110120 TO 20110121;REEL/FRAME:025797/0670