Source: http://www.google.com/patents/US5726137?dq=7,446,777
Timestamp: 2014-07-10 06:26:49
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Matched Legal Cases: ['art 1', 'art 1', 'art 2', 'art 2', 'art 2', 'art 3', 'art 4', 'art 4', 'art 5', 'art 5', 'art 5', 'art 1', 'art 2', 'art 3', 'art 4', 'art 5']

Patent US5726137 - Low silicone hair conditioning shampoo and non-silicone hair conditioning ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign in<nobr>Advanced Patent Search</nobr>PatentsA mild, non-irriatating hair conditioning shampoo is disclosed comprising an aqueous dispersion of a water-insoluble lipid phase, an anionic hair cleansing surfactant, an amphoteric surfactant present at a level of at least about 0.75 parts by weight per part by weight of said anionic surfactant, at...http://www.google.com/patents/US5726137?utm_source=gb-gplus-sharePatent US5726137 - Low silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampooAdvanced Patent SearchPublication numberUS5726137 APublication typeGrantApplication numberUS 08/714,928Publication dateMar 10, 1998Filing dateSep 27, 1996Priority dateJun 21, 1989Fee statusLapsedPublication number08714928, 714928, US 5726137 A, US 5726137A, US-A-5726137, US5726137 A, US5726137AInventorsAmrit Patel, Clarence R. RobbinsOriginal AssigneeColgate-Palmolive CompanyExport CitationBiBTeX, EndNote, RefManPatent Citations (32), Non-Patent Citations (4), Referenced by (29), Classifications (59), Legal Events (4) External Links: USPTO, USPTO Assignment, EspacenetLow silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampooUS 5726137 AAbstract A mild, non-irriatating hair conditioning shampoo is disclosed comprising an aqueous dispersion of a water-insoluble lipid phase, an anionic hair cleansing surfactant, an amphoteric surfactant present at a level of at least about 0.75 parts by weight per part by weight of said anionic surfactant, at least one hair conditioning, film forming, polycationic polymer soluble in the aqueous dispersion and 0-6% by weight, based on the weight of the shampoo, of a water-insoluble, non-volatile hair conditioning silicone, the water-insoluble lipid phase comprising at least one lipid soluble, emulsifiable, monocationic, quaternary ammonium compound or amine solubilized in a water-insoluble long chain lipid compound, the weight ratio of monocationic compound to the lipid compound in the lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble cationic compound is greater than 2:1. The shampoo having no silicone possesses a high degree of style control properties. The shampoo containing silicone has a high degree of hair conditioning properties.
We claim: 1. A hair conditioning shampoo composition comprising, by weight, an aqueous dispersion of:a) about 1% to about 16% of a water-insoluble lipid phase comprising a long chain aliphatic alcohol having an average of from about 24 to about 50 carbon atoms and from 0 to about 40 ethoxy units; b) at least about 0.7% of a water-insoluble, monocationic conditioner compound dissolved in said lipid phase, said monocationic compound being selected from the group consisting of an alkyl amine having a pKa of at least 7.5 selected from the group consisting of distearylamine, distearyl methylamine, behenylamine, behenylmethylamine, behenyldimethylamine, dicetylamine, dicetylmethylamine and tricetylamine; c) about 3% to about 25% of a water-soluble, anionic, hair cleansing organic surfactant; d) an amphoteric betaine or sulfobetaine surfactant containing a C8 -C18 alkyl or C8 -C18 alkanolamido C2 -C3 alkylene group in its molecular structure, present in said dispersion at a level of at least 0.75 to 1.25 parts by weight per one part by weight of said anionic surfactant; e) from 0 to about 6% of a water-insoluble, non-volatile silicone hair conditioning agent; and f) 0.2% to 3% of at least one hair conditioning, water-soluble, film-forming polycationic polymer; the weight ratio of said monocationic conditioner compound to said lipid compound in said lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble, monocationic compound being in the range of 2:1 to 50:1. 2. The shampoo according to claim 1 containing no silicone hair conditioning agent and possessing a high degree of hair conditioning and hair damage repair properties.
RELATED APPLICATIONS This is a continuation of application Ser. No. 08/440,572 filed May 15, 1995 abandoned which is a CIP of copending U.S. Ser. No. 08/155,251, filed Nov. 19, 1993, which is a CIP of copending U.S. Ser. No. 07/984,786 filed Dec. 3, 1992, now U.S. Pat. No. 5,346,642 which is a CIP of U.S. Ser. No. 07/507,335 filed Apr. 9, 1990, now U.S. Pat. No. 5,213,716 which is a CIP of U.S. Ser. No. 07/369,361 filed Jun. 21, 1989 (Abandoned), U.S. Ser. No. 07/369,389 filed Jun. 21, 1989 (abandoned), U.S. Ser. No. 07/432,644 filed Nov. 7, 1989, now U.S. Pat. No. 5,051,250, and U.S. Ser. No. 07/432,952 filed Nov. 7, 1989 (abandoned).
BACKGROUND OF THE INVENTION FIELD OF THE INVENTION The present invention relates to hair conditioning shampoos containing little-or no water-insoluble silicone hair conditioning agents.
DISCUSSION OF THE PRIOR ART So-called two-in-one hair conditioning shampoos which achieve hair conditioning as well as hair cleansing with one product have been formulated to overcome the disadvantages associated with the necessity for sequentially applying separate compositions to the hair to achieve these purposes; one is a shampoo to cleanse the hair and the other is a separate hair conditioner to condition the hair.
U.S. Pat. No. 5,104,642 describes the use in a hair styling composition of a polymer comprising up to 50% of a first polymerizable hydrophilic monomer and the remainder a second polymerizable hydrophilic monomer, the resulting polymer having a molecular weight of 5,000 to 1,000,000, a glass transition temperature, Tg, of greater than -20� C. and a solubility parameter of 8.5 to 12.0. International Application No. PCT/US91/02170, published Oct. 17, 1991, discloses the incorporation of these types of polymers in a hair shampoo formulation.
SUMMARY OF THE INVENTION These and other objects are realized by the present invention which relates to an aqueous dispersion of a water insoluble lipid phase, about 3 to 25% by weight an anionic hair cleansing surfactant, an amphoteric surfactant present in said dispersion at a level of at least about 0.75 parts by weight per part by weight of said anionic surfactant, at least one hair conditioning, film-forming, polycationic polymer and 0-6% by weight, based on the weight of the shampoo, of a water-insoluble, non-volatile silicone hair conditioning agent; said polycationic polymer being soluble in said aqueous detergents; said water-insoluble lipid phase comprising at least one lipid-soluble, emulsifiable, monocationic quaternary ammonium compound or amine solubilized in a water-insoluble, long chain lipid compound, the weight ratio of monocationic compound to said lipid compound in said lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble cationic compound is greater than 2:1, preferably from about 2:1 to about 50:1 and most preferably from about 5:1 to about 30:1.
DETAILED DESCRIPTION OF THE INVENTION The invention is predicated on the discovery that in an aqueous hair conditioning shampoo containing anionic surfactants and detergent-soluble polycationic conditioning agents and relatively low amounts of a water-insoluble, nonvolatile silicone hair conditioning agents, the presence in the shampoo of a water-insoluble lipid phase having dissolved therein a monocationic, lipid soluble hair conditioning agent results in a hair conditioning shampoo with enhanced hair conditioning and hair cleansing properties, while avoiding many of the instability and reduced effectiveness drawbacks associated with conventional two-in-one shampoo formulations.
The essentially non-volatile polyalkyl siloxanes that may be used include, for example, polydimethyl siloxanes with viscosities ranging from about 5 to about 100,000 centi-stokes at 25� C. These siloxanes are available, for example, from the General Electric Company as the Vicasil series and from Dow Corning as the Dow Corning 200 series. The viscosity can be measured by means of a glass capillary viscometer as set forth in Dow Corning Corporate Test Method CTMO004 (Jul. 20, 1970).
The essentially non-volatile polyalkylaryl siloxanes that may be used include, for example, polymethylphenylsiloxanes having Niscosities of about 15 to about 85 centistokes at 25� C. These siloxanes are available, for example, from the General Electric Company as SF-1075 methyl phenyl fluid or from Dow Corning as 558 Cosmetic Grade Fluid.
The essentially non-volatile polyether siloxane copolymer that may be used is, for example, a dimethyl polyoxyalkylene ether copolymer fluid having a nominal viscosity of about 1,200 to about 1,500 centistokes at 25� C. This copolymer is available, for example, from the General Electric Company as SF-1066 organosilicone surfactant. Preferred compounds of this type are polypropylene oxide modified dimethylpolysiloxanes (e.g., Dow Corning DC-1248), although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used.
EXAMPLE I A hair conditioning shampoo having the following formulation was prepared:
__________________________________________________________________________Part    Ingredient   Supplier, Tradename                             Wt. %__________________________________________________________________________1   Deionized Water               13.750    Ammonium Lauryl Sulfate            Henkel's Standepol A, 28%                             16.000    Sodium Deceth-3 Sulfate            Vista's Novel 10-44 E.S. Na, 30%                             15.000    Sodium Cumene Sulfonate            Stepan's Stepanate SCS, 43%                             7.000    Na4 EDTA            Rhone-Poulenc's Cheelox SF-78                             �0.100    Na2 HPO4            Sodium Phosphate Dibesic                             0.200    Cocamidopropyl Betaine #3            Goldschmidt's Tego Betaine L-7, 30%                             30.0002   Deionized water               5.000    Polyquaternium-10            Amerchol's Polymer JR-30M                             0.5003   Polyquaternium-7            Calgon's Merquat-550, 8%                             2.5004   Isosteareth-2+            Sherex's Varonic 66-E2 (1.5 EO)                             2.000    Compound 909*            Petrolite's C-7138 Polymer                             4.000    Distearyl Dimonium Chloride            Sherex's Arosurf TA-100                             1.0005   Yellow Color (1% solution)    0.250    Perfume                       1.200    Preservative, 50% aqueous     1.000    solution    Sodium Cumene Sulfonate            Stepan's Stepante SCS, 43%                             �0.500TOTAL                             100.000__________________________________________________________________________ + Isosteareth2 is ethoxylated isostearyl alcohol (1.5 EO units). *Compound 909 is a C20 -C40 aliphatic alcohol.
To the main mixing vessel was charged Part 1 formula amount of deionized water and mixing begun. In order, Part 1 formula amounts of ammonium lauryl sulfate, sodium deceth sulfate, sodium cumene sulfonate, Na4, sodium phosphate dibasic and cocoamidopropyl betaine were added to the main mixing vessel, allowing sufficient time for each ingredient to completely dissolve before adding the next and taking care not to promote foam formation. The batch was mixed for at least 15 minutes before continuing. The batch was heated with mixing to 85�-87� C.
To a separate, dry, clean container, Part 2 formula amount of deionized water was charged. With mixing, Part 2 formula amount of Polyquaternium-10 was dispersed in the deionized water and mixed well until the premix was free of lumps, but not longer than 5 minutes just prior to addition, to avoid gelling. Part 2 premix was added to the main mixing vessel with mixing, taking care not to promote foam formation. The batch was mixed for at least 15 minutes before continuing. Mixing was continued with heating to 85�-87� C.
Part 3 formula amount of Polyquaternium-7 was added to the main mixer with mixing, taking care not to promote foam formation. The batch was mixed for at least 15 minutes before continuing. Mixing was continued with heating to 85�-87� C.
To a third, separate, heatable container, the formula amounts of all ingredients of the Part 4 oil phase were charged and heating begun. The ingredients were mixed well until all the material was melted and uniform at a temperature of 90�-92� C. When liquid and uniform, the mixture will not necessarily be clear; it may be translucent. When the batch was at 85�-87� C., Part 4 premix was added to the main mixing vessel with high-speed mixing, taking care not to promote foam formation. Heating was discontinued and the batch was mixed at temperature for at least 15 minutes. Then the batch was cooled with mixing.
Part 5 colors were added at any time during the cooling of the batch. When the batch was at 52� C., Part 5 formula amount of perfume was added to the batch and mixing and cooling were continued. When the batch was at or below 38� C. Part 5 formula amount of preservative was added to the batch with continued mixing and cooling.
Specifications were checked on a batch sample cooled to 25� C. and, if necessary, sodium cumene sulfonate was added to the main mixing vessel to reduce viscosity.
EXAMPLE 2 The following shampoo formulation was prepared according to the procedure of Example 1:
__________________________________________________________________________Ingredient     Tradename  Supplier                             Wt. %__________________________________________________________________________Part AFiltered Deionized Irradiated Water                             QSHydroxyethyl Cellulose          Natrosol 250-HHR                     Aqualon 0.200Part BAmmonium Lauryl Sulfate          Standapol A, 28%                     Henkel  67.858Sodium Phosphate Monobasic          NaH2 PO4                     J.T. Baker                             0.200Sodium Phosphate Dibasic          Na2 HPO4                     J.T. Baker                             0.200Sodium Cumene Sulfonate          Naxonate SC, 98%                     Reutgers-Nease                             �1.000Cocomidopropyl Betaine          Tego Betaine L-7 30%                     Goldschmidt                             13.334Part CPropylene Glycol USP          Propylene Glycol USP                             1.000Polyquaternium-10          Polymer JR-30M                     Amerchol                             0.300Quaternized Guar Gum          Cosmedia Guar C-261                     Henkel  0.300Part DParaffin Wax 128� F.          Boler 1070 Boler Petroleum                             1.000C20-40 Alcohol          Unilin 425 Petrolite                             2.000Stearyl Alcohol          Adol 62    Sherex  2.000Tricetyl Ammonium Chloride          TC-90-F    Sherex  2.000Distearyl Dimonium Chloride          Arosurf TA-100                     Sherex  0.500Behenyl C22 -quat          Genamin KDM-F                     BASF    0.500Laureth-4      Brij-30    ICI     0.500Hydrogenated Castor Oil          Cremophor RH-40                     BASF    0.500Part EPerfume                           1.200Preservative                      0.750Blue Color (1% solution)          0.021Green Color (1% solution)         0.168TOTAL                             100.000__________________________________________________________________________
EXAMPLE 3 The following formulation was prepared according to the procedure of Example 1:
EXAMPLE 4 The following formulations were prepared according to the above procedure and tested:
EXAMPLE 5 The following shampoo compositions were prepared according to the above-described procedure:
__________________________________________________________________________           LevelIngredients     1    2   3    4   5__________________________________________________________________________Part 1Filtered Irradiated Deionized Water           QS   QS  QS   QS  QSHydroxyethyl Cellulose No. 2           0.7  0.7 0.6  0.3 --Ammonium Lauryl Sulfate, 28%           12.0 12.0                    12.0 12.0                             12.0Sodium Deceth-3 Sulfate, 30%           15.0 15.0                    15.0 15.0                             15.0Na4 EDTA   0.1  0.1 0.1  0.1 0.1Sodium Cumene Sulfonate, 43.3%           4.5  4.5 4.5  5.0 6.5Cocoamidopropyl Betaine, 30%           30.0 30.0                    30.0 30.0                             30.0Sodium Phosphate Dibasic           �0.2                �0.2                    �0.2                         �0.2                             �0.2Part 2Filtered Irradiated Deionized Water           3.0  3.0 5.0  8.0 10.0Polyquaternium-10           0.2  0.3 0.3  0.6 0.9Part 3Isosteareth-2   0.8  0.8 0.8  0.8 0.8Compound 909 (Unilin)           4.0  4.0 4.0  4.0 4.0Distearyl Dimonium Chloride           1.0  1.0 1.0  1.0 1.0Part 4Dimethicone/Polydimethyl Siloxane           1.0  2.25                    3.5  4.0 4.0Part 5Blue Color (1% aqueous solution)           0.021                0.021                    0.021                         0.021                             0.021Green Color (1% aqueous solution)           0.168                0.168                    0.168                         0.168                             0.168Perfume         1.2  1.2 1.2  1.2 1.2Preservative (50% aqueous solution)           1.0  1.0 1.0  1.0 1.0Sodium Cumene Sulfonate, 93%           �0.5                �0.5                    �0.5                         �0.5                             �0.5TOTALS:         100% EACH__________________________________________________________________________
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