Source: https://patents.google.com/patent/JP4409291B2/en
Timestamp: 2020-02-22 07:56:13
Document Index: 535210366

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JP4409291B2 - Thermoforming mold for optical lens made of thermoplastic material and process thereof - Google Patents
Thermoforming mold for optical lens made of thermoplastic material and process thereof Download PDF
JP4409291B2
JP4409291B2 JP2003552526A JP2003552526A JP4409291B2 JP 4409291 B2 JP4409291 B2 JP 4409291B2 JP 2003552526 A JP2003552526 A JP 2003552526A JP 2003552526 A JP2003552526 A JP 2003552526A JP 4409291 B2 JP4409291 B2 JP 4409291B2
JP2003552526A
JP2005511367A (en
ハオ−ウェン チュー
シンジン ヤン
マシュー ロックウッド
2001-12-17 Priority to US10/015,587 priority Critical patent/US6884369B2/en
2002-12-17 Application filed by エシロール アンテルナショナル コムパニー ジェネラル ドプテイク filed Critical エシロール アンテルナショナル コムパニー ジェネラル ドプテイク
2002-12-17 Priority to PCT/FR2002/004386 priority patent/WO2003051616A2/en
2005-04-28 Publication of JP2005511367A publication Critical patent/JP2005511367A/en
2010-02-03 Publication of JP4409291B2 publication Critical patent/JP4409291B2/en
Y10S425/246—Mold heating
The present invention relates to suitable plastic molding of thermoplastic materials such as polymethyl methacrylate, polycarbonate or polycarbonate copolymers, polynorbornene, polystyrene, cyclic polyolefins or one of its copolymers, etc. For the production of optical lenses made of plastic materials such as ophthalmic lenses or instrument lenses obtained by
In the production of an optical lens by this kind of process, it is known to effectively utilize the ability of a plastic material that is deformed by heat in order to give the lens the required shape. From a standard shaped thermoplastic mass (commonly referred to as a parison) or from a specific preform with a shape close to the desired shape, this shaping operation is applied to two materials that are applied by pressing onto a material that has been previously heated to a plastic state. This is done by pressure molding between the mother dies. Each of the master plates, typically made of stainless steel, has a master surface that has an optical polishing surface that has one or more appropriate curvatures corresponding to those to be applied to the finished lens and is similar to the gloss of a mirror. Presenting.
In order to obtain a lens with optical quality that meets its application, certain precautions during manufacture, in particular to avoid the presence of irregular deformations or internal stresses that create undesirable anisotropy or aberrations. Must be taken.
In this regard, special care is taken for the production of the molding master. In addition, it is often recommended to proceed with the production in two successive stages. That is, a stage in which a blank is manufactured by injection molding, molding or machining, and then the blank is finished by thermoforming.
For these precautions regarding molds and working modes, it is appropriate to add measures that target the heating of the plastic material and mold during molding. Usually, heating is ensured by the master itself, which is arranged to contain a heating fluid or gas or electrical resistance. The heat supplied by hot fluid circulation or electrical resistance spreads in the matrix mass and is transferred through the matrix wall to the plastic material being shaped.
This heating mode has practical disadvantages.
First of all, this does not guarantee the heating of the plastic material in a regular and homogeneous form that would be desirable to avoid internal stresses. Different parts of the matrix and thus the material to be processed reach the required molding temperature only in a progressive and unequal form. This lack of heat transfer uniformity is also seen in post-molding cooling.
As a result of this heating and cooling inequality at different points in the processed material, the resulting optical lens maintains deformation and stress, so that often the lens is unsuitable for its intended optical application. It becomes a thing.
On the other hand, according to the normal arrangement, the mother mold intended to accommodate the heating and cooling device is fixed on the press, and the pipe joint with the heating fluid or current supply is taken into account this arrangement. Maintained. In this type of equipment, the mounting and disassembling work of the mother mold is complicated and time consuming.
Another heating mode aimed at correcting these drawbacks consists of using heating means separated from the mold itself, in particular the mother mold. The mold containing the preform or parison is thus heated separately from the press before being placed on the press for the molding operation. Nonetheless, the fact that the mold is heated separately from the press by external means can certainly release the master from all fluid or electrical connections, but the mold must be manipulated every cycle, which increases production speed. There is a major drawback of significantly lowering. Moreover, the temperature of the mold cannot be controlled during molding, and no cooling of the mold after molding is provided, which does not require external means that require supplementary operations, such as heating. Can only be considered using.
In order to be able to transport the mold from the heating station to the molding station (ie press), the mold has sleeves that enclose the mother mold, in which these mother molds are mounted in a sliding manner. ing. The sleeve then serves to ensure the mechanical integrity of the mold by providing a mechanical link between the two molds independent of the press.
In accordance with the present invention, an optical lens thermoforming mold made of a thermoplastic material having two master molds mounted in the sleeve for sliding along the axis of the sleeve and presenting molding surfaces facing each other. In the mold, a thermoforming mold has been proposed in which two mother molds and a sleeve are provided with inherent bifunctional means (heating and cooling) for heat transfer.
For example, the heat transfer means has an internal circuit for circulating the coolant.
Thus, two advantages are combined. First of all, the quality, in particular the uniformity, of the heating or cooling of the mold and thus the thermoplastic material can be improved by enclosing the mold in a sleeve that is self-regulating heat. Thus, the sleeve serves as a thermal enclosure that is optionally added to its role as a mechanical guide for the two dies to each other. Moreover, by integrating the bifunctional heat transfer means into the main part of the mold, i.e. the master and the sleeve, there is no need to move the mold to be subjected to the action of external heating and / or cooling means, According to the optimized heat regulation law, it is possible to ensure not only heating of the mold but also cooling.
According to one advantageous feature of the invention, each mold (1,2) is
A bed plate having at least a part of said type of heat transfer means and means for connecting them to a heat regulation source;
-It consists of a removable insert that is mounted afterwards on the bed plate and supports the molding surface.
The inserts are thus interchangeable, so that they can be selected from a pre-set set or even custom-made according to the surface definition desired for the lens. Installation / disassembly of the insert on the mold is easy and quick in that the connection to the heat regulation source is made via an adapter and therefore does not need to be disassembled.
In this case, advantageously, each master bed plate accommodates all of the heat transfer means of the master mold, and the inserts without such means are thermally regulated exclusively by heat transfer with the bed plate. Yes. Thus, the attachment of the insert does not include a hydraulic or electrical connection with either the thermal conditioning source or the bed plate.
Similarly, according to the present invention, in the thermoforming process of an optical lens made of a thermoplastic material using the above-described mold,
Placing a thermoplastic parison or preform between two molds and enclosing the assembly in a sleeve;
-Heating the mold and the sleeve using its inherent heat transfer means to the molding temperature;
-Bringing the dies close together to process the material by plastic deformation to a predetermined relative position corresponding to the desired thickness of the lens;
-Cooling the master and sleeve using their inherent heat transfer means to the mold release temperature;
-Removing the finished lens (L) from the mold;
Preferably, the molding temperature is above the glass transition temperature of the thermoplastic material utilized. The superior results are more precisely, molding temperatures between 16.6-66.6 ° C. (ie 30-120 ° F.), preferably above the glass transition temperature by about 25 ° C. (45 ° F.). It is obtained by.
Conversely, the mold release temperature is preferably much lower than the glass transition temperature. For example, defining a glass transition temperature that defines a difference between the glass transition temperature and 11.1-27.7 ° C. (ie, 20-50 ° F.) and preferably about 19.4 ° C. (35 ° F.). it can. In fact, it is advantageous not to overcool the mold so that the duration of each cycle is as short as possible.
According to another advantageous feature of the invention, the sleeve has an annular pocket that opens inward and communicates with a gap space defined by the molding surfaces of the two molds. The purpose of this annular pocket is to accommodate excess plastic material that forms a peripheral burr in a state that it protrudes laterally from the matrix after molding.
The gap space defined by the molding surfaces of the two molds forms a sealed internal volume with the annular pocket that is connected to the exterior by at least one suction passage that traverses the sleeve and leads to the annular pocket, for example.
With a mold exhibiting this feature, it is advantageous to use a suction channel to access the sealed interior of the mold prior to and / or at the same time as the approach of the master for the purpose of processing the material by plastic deformation. Work can proceed in such a way that a relative vacuum is created in the volume.
Best results are obtained with a relative vacuum of less than 0.25 bar and preferably comprised between 0 and 0.1 bar.
According to another advantageous feature of the invention, the mold has a deburring crown that is slidably mounted in the sleeve and optionally associated with a lip that borders the annular pocket.
Using a mold exhibiting this feature, advantageously, after complete processing of the material due to the approach of the matrix, the deburring crown is formed by the surrounding burrs formed by excess material protruding laterally from the matrix. The work can be carried out in such a way that it can be activated to cut off.
According to yet another advantageous feature of the invention, the sleeve, on the one hand, introduces a preform or parison between the two dies, in particular for the purpose of taking out the finished lens at the end of the molding. Same as the mold, between an open configuration providing direct access to the interstitial space defined by the molding surface and a closed configuration where the two parts are in contact by the joining surface along the transverse dividing line It has two parts that are mounted to slide in relation to each other along a sliding axis.
In this case, the annular pocket of the sleeve is advantageously implemented in the form of reinforcing at least one interface of the two parts of the sleeve and preferably in the form of a slot in a drafted state.
Other features and advantages of the present invention will become apparent upon reading the following description of specific embodiments given as non-limiting examples.
Referring to the drawings, an optical lens thermoforming mold made of thermoplastic material according to the present invention is mounted in a slidable manner in a sleeve 3 and presents two master molds presenting molding surfaces 4, 5 facing each other. have. The sleeve 3 has a central axis 6 that defines the relative sliding direction of the dies 1 and 2.
More precisely, the sleeve 3 provides, on the one hand, an open configuration illustrated by FIG. 1 and 2 on the other side, providing direct access to the gap space defined by the two mold surfaces 4, 5. Between the closed configurations illustrated in FIGS. 2 to 4, in which the two parts 7, 8 are in contact by the joining surfaces 9, 10 along the transverse dividing line J, in relation to each other along the axis 6 In order to slide, it has two parts 7, 8 mounted on an external support (not shown), for example tied to a press framework.
Each of the two mother dies 1, 2 is composed of bed plates 11, 12 and removable inserts 13, 14 that are retrofitted onto the bed plate and support the molding surfaces 4, 5.
The two master dies 1 and 2 and the sleeve 3 are provided with inherent heat transfer means which are bifunctional, ie capable of both heating and cooling. These heat transfer means can be implemented, for example, in the form of an internal circuit for the circulation of a coolant such as oil, as in the example shown. Thus, in the parts 7, 8 of the sleeve 3, in this case the spiral circuits 15, 16 provided in the parts 7, 8 of the sleeve 3, and on the other hand, the bed plates 11 of the mother dies 1, 2 , 12 are identified as spiral circuits 19, 20.
Accordingly, each mother mold bed plate 113, 124 accommodates all of the mother mold heat transfer means, and the inserts 13, 14 without such means are exclusively for heat transfer with the bed plate. Is controlled by heat.
The two parts 7 and 8 of the sleeve 3 and the master bed plates 11 and 12 are suitable for circuits 15, 16 and 19, 20 and a common external heat source S or different parts of the mold independently of each other. Pipe fittings 17, 18 and 21, 22 are provided which allow connection to a plurality of completely different independent heat control sources for adjustment. In particular, on the one hand, the circuit 15, 16 of the sleeve 3 is connected to a first thermal regulation source assigned to the thermal regulation of the two parts 7, 8 of the sleeve 3, and on the other hand, a matrix independent of the sleeve 3. It can be envisaged that the circuit blocks 19, 20 of the master plates 1, 2 are connected to a second heat control source assigned to the heat control of the base plate 1.
The lower part 7 of the sleeve 3 presents an annular slot 23 provided to reinforce the joining surface 9 of the lower part 7 of the sleeve 3. This slot 23 is adjacent to the inner surface of the portion 7 of the sleeve 3 and is bordered on the inside by a circular rim 24 forming a deburring lip, as will be better explained below. The slot 23 is slightly drafted.
When the sleeve 3 is in a closed configuration with its two parts joined by its joint surfaces 9, 10, the slot 23 is at least partially covered by the joint surface 10 of the upper part of the sleeve 3 and is annular A pocket 23 is formed. However, the top of the lip 24 is slightly retracted from the dividing line J, so that a gap still remains, through which the pocket 23 opens to the inside of the sleeve and the two preforms or parisons P are placed. It communicates with the gap space defined by the molding surfaces 4 and 5 of the dies 1 and 2.
The space defined by the molding surfaces 4, 5 of the two dies 1, 2 thus forms with the annular pocket 23 a single sealed internal volume. A single suction path 25 is provided in the lower portion of the sleeve 3 and extends laterally from the annular pocket 23 to the outer surface of the sleeve portion 7 to connect the internal volume with the outside. A fitting 26 is provided on the outer surface of the sleeve portion 7 to connect the flow path 25 to a vacuum pump (not shown) for the purpose of creating a relative vacuum in the internal volume.
The mold further has a deburring crown 30 slidably mounted in the upper part 8 of the sleeve 3. More precisely, in the illustrated example, the crown 30 allows the upper matrix 2, the crown 30 and the upper part 8 of the sleeve 30 to be guided precisely along the axis 6 in relation to each other. In the form of a part of the tube with the axis 6 placed between the upper part 8 of the sleeve and the upper master 2, leaving a small lateral play. The deburring function of the crown is described in more detail below.
In order to perform thermoforming of an optical lens made of a thermoplastic material using the mold described above, the work proceeds as follows.
A parison or preform P is placed between the two mother dies 1,2. For this purpose, on the one hand the mother dies 1, 2 are separated from one another so that a preform or parison P can be introduced between their molding surfaces 4, 5, while on the other hand the two parts 7, 8 of the sleeve 3 are open. Starting from the initial form illustrated in FIG. 1, which allows the direct introduction of preforms or parisons P between the dies without the need to separate the dies 1, 2 of the sleeve 3 To do.
The parison or preform P is composed of a thermoplastic material such as polymethyl methacrylate, polycarbonate or polycarbonate copolymer, polynorbornene, polystyrene, cyclic polyolefin or one of its copolymers.
The two parts 7 and 8 of the sleeve 3 are then closed against each other at their joining surfaces 9 and 10 as illustrated in FIG. Thus, the sleeve 3 totally encloses the two master dies.
The mother dies 1 and 2 and the sleeve 3 are then heated or preheated to the molding temperature by their inherent heat transfer means. For this purpose, in the example shown here, the coolant is heated by one or more external conditioning sources S and circulated in the circuits 15, 16, 19, 20.
Preferably, the molding temperature is above the glass transition temperature of the thermoplastic material utilized. Excellent results, more precisely, at a matrix temperature above the glass transition temperature by a difference of 16.6-66.6 ° C. (ie 30-120 ° F.), preferably 250 ° C. (45 ° F.). can get.
It will be appreciated that during this heating, the presence of an inherent heat transfer means means that the temperature variation can be regulated and adjusted according to the law of temperature variation as a function of time suitable for reducing internal stress. .
Once the desired temperature is reached, the molds 1 and 2 are placed in a predetermined relative position corresponding to the desired thickness of the lens, as illustrated in FIG. Up to each other for processing by plastic deformation.
Prior to and / or simultaneously with the approach of the dies 1 and 2 for the purpose of processing the material by plastic deformation, using a vacuum pump (not shown) connected to the pipe joint 26 using the suction channel 25 Thus, a relative vacuum is created within the enclosed internal volume of the mold described above.
The best results were obtained with a relative vacuum contained below 0.25 bar, preferably between 0 and 0.1 bar.
Formed by extra material overflowing sideways from the flow molds 1 and 2 after compression after the material is completely processed by bringing the mold close to a predetermined compression rate (form of Fig. 3) The deburring crown 30 is activated in order to cut the surrounding burr. For this purpose, the deburring crown 30 is associated with a lip 24 that rims the annular pocket in the manner of a nipper (as illustrated) or alternatively a shear.
Thereafter, the mother dies 1 and 2 and the sleeve 3 are cooled to the mold release temperature using their inherent heat transfer means. For this purpose, in the example shown here, the coolant is cooled by one or more external conditioning sources S and circulated in the circuits 15, 16, 19, 20.
The mold release temperature is preferably much lower than the glass transition temperature. For example, a mold release temperature less than one half of the glass transition temperature can be assumed. During this cooling, it can be seen that, as in the case of heating, the temperature fluctuation can be regulated by the inherent heat transfer means and can be adjusted according to the law of temperature fluctuation according to the time suitable for the reduction of internal stress. right.
All that remains is only to take out the finished lens L from the mold. For this purpose, the two parts 7, 8 of the sleeve 3 are separated from each other as well as the two dies 1, 2. Thus, direct access to the space between the dies 1 and 2 and the finished lens L resting on the lower dies 1 is provided. At this time, it is only necessary to capture the lens L using a gripping tool such as a clamp attached to a manual type or automatic operation arm.
Similarly, it is necessary to take out the peripheral burr cut by the deburring crown 30 from the annular pocket.
The mold described above is
-This type for molding a small number of lenses, and also individually (or in pairs), i.e. for custom-made production for the purpose of fulfilling prescription orders, or-simultaneously to mold the number of lenses corresponding to each cycle In a mass production unit with multiple molds,
It should be noted that several variations and additions can be considered starting from the main features and stages of the mold and process of the present invention. These variants and additions mentioned below can be carried out separately or in combination with each other for the purpose of directly obtaining a coated or at least treated finished or semi-finished lens.
According to an additional first feature, the preform or parison P can advantageously be pre-coated with a single or multi-layer coating before being placed between the two dies.
According to a second additional feature, a thermoplastic film is placed between the parison or preform and at least one of the two masters before heating the master to the sleeve. This thermoplastic film is then commonly referred to as hot rolling or layering during the forming stage in a manner similar to the process described in document WO 99/24243, incorporated herein by reference. Is attached to the corresponding surface of the lens and self-welded. Advantageously, the film can be coated with a single or multilayer coating. Alternatively, or in combination with a coating associated with the film, the film may be of a photochromic type and / or a type that is polarized in a manner that provides physical properties corresponding to the lens. The film may be dyed and / or colored.
According to an additional third feature, a single or multilayer coating can be applied on at least one of the two molds before heating. This coating is then hot-transferred to the corresponding surface of the lens during the molding stage, preferably in a manner similar to the process described in document US Pat. No. 5,458,820 contained herein.
In general, the invention is not limited to the specific embodiments described above, but encompasses any variant that recapitulates its basic features by equivalent means. In particular, although a specific heat transfer means has been described and illustrated for a mold that is implemented entirely in the form of an internal circulation circuit of a coolant, particularly with respect to the heating function using electrical resistance, It would also be possible to implement the heat transfer means in any other known form by frequency current induction or even infrared or ultraviolet heating.
It is sectional drawing of the thermoforming metal mold | die of the optical lens of embodiment of this invention, and shows the open state of a metal mold | die. It is sectional drawing of the thermoforming metal mold | die of the optical lens of embodiment of this invention, and shows the closing start state of a metal mold | die. It is sectional drawing of the thermoforming metal mold | die of the optical lens of embodiment of this invention, and shows the closed state of a metal mold | die. It is sectional drawing of the thermoforming metal mold | die of the optical lens of embodiment of this invention, and shows a deburring state.
It has two matrixes (1, 2) that are mounted in this sleeve (3) for sliding along the axis (6) of the sleeve (3) and present molding surfaces (4, 5) that face each other. In the thermoforming mold of the optical lens made of a thermoplastic material, the heat transfer means (15, 16) having a heating function and a cooling function inside the two mother molds (1, 2) and the sleeve (3). , 19, 20). A thermoforming mold characterized by the above.
Each matrix (1, 2)
A bed plate (11, 12) having at least a part of said matrix heat transfer means and means (17, 18, 21, 22) connecting them to a heat transfer source (S);
Mold according to claim 1, consisting of a removable insert (13, 14) that is mounted on the bed plate (11, 12) and supports the molding surface.
Each matrix bed plate (11, 12) houses all of the matrix heat transfer means (19, 20), and inserts (13, 14) without such means are exclusively bed plates (11, 12). The mold according to claim 2, wherein the mold is heat-controlled by heat transfer to and from.
The sleeve (3) has an annular pocket (23) that opens inward and communicates with a gap space defined by the molding surfaces (4, 5) of the two master dies (1, 2). The metal mold | die of any one of -3.
A gap space defined by the molding surfaces (4, 5) of the two dies (1, 2) is externally provided by the annular pocket (23) and at least one suction channel (25) across the sleeve (3). The mold according to claim 4, forming a connected closed internal volume.
The mold according to claim 5, wherein the suction channel (25) leads to an annular pocket (23).
7. A mold according to any one of claims 4 to 6, having a deburring crown (30) mounted in a sliding manner in the sleeve (3).
The mold according to claim 7, wherein the deburring crown (30) abuts against the lip (24) bordering the annular pocket (23).
On the one hand, an open configuration that provides direct access to the gap space defined by the molding surfaces (4, 5) of the two molds, and on the other hand, the two parts (7, 8) are in the transverse dividing line (J). Two parts (slidably mounted in relation to each other along the same sliding axis (6) as the mother mold between closed forms which are contacted by the joint surfaces (9, 10) along The mold according to any one of claims 4 to 8, wherein the sleeve has 7 and 8).
Mold according to claim 9, wherein the annular pocket (23) of the sleeve (3) is a groove in the joining surface (9) of at least one (7) of the two parts of the sleeve (3).
11. Mold according to claim 10, wherein the groove (23) is in a drafted state.
12. A mold according to any one of the preceding claims, wherein the heat transfer means has an internal circulation circuit (15, 16, 19, 20) for the coolant.
In a thermoforming process of an optical lens made of a thermoplastic material using the mold according to any one of claims 1 to 12,
-Placing the thermoplastic material parison or preform (P) between two matrixes (1, 2), between the matrix (1, 2) and the two matrices (1, 2); Confining an assembly consisting of a parison or preform (P) of said thermoplastic material disposed in a sleeve (3);
-Heating the mold (1, 2) and the sleeve (3) using the heat transfer means (15, 16, 19, 20) having the heating and cooling functions to the molding temperature;
-Bringing the master dies (1, 2) closer together to process the material by plastic deformation to a predetermined relative position corresponding to the desired thickness of the lens;
-Cooling the master mold (1, 2) and the sleeve (3) using the heat transfer means (15, 16, 19, 20) having the heating function and the cooling function to the mold release temperature;
Process comprising.
14. A molding process according to claim 13, wherein the molding temperature is equal to or higher than the glass transition temperature of the thermoplastic material utilized.
The molding process according to claim 14, wherein the molding temperature is higher than the glass transition temperature of the thermoplastic material utilized, the difference being between 16.6 and 66.6 ° C.
Higher than the glass transition temperature of the thermoplastic material forming temperature is utilized, the difference is 2 5 ° C., the molding process of claim 15.
The molding process according to any one of claims 13 to 16, wherein a mold release temperature is lower than a glass transition temperature.
The molding process of claim 17, wherein the mold release temperature defines the difference between the glass transition temperature and 11.1-27.7 ° C.
The molding process of claim 18, wherein the mold release temperature defines the difference between the glass transition temperature and 19.4 ° C.
When the mother dies (1, 2) for the purpose of processing the material by plastic deformation approach each other, the suction path (25) is used to bring the inside of the sealed internal volume of the mold to a pressure lower than the external pressure. The molding process according to any one of claims 13 to 19, wherein the mold according to claim 5 is used.
21. A molding process according to claim 20, wherein the difference between the atmospheric pressure in the sealed internal volume of the mold and the external atmospheric pressure is less than 0.25 bar.
22. Molding process according to claim 21, wherein the difference between the pressure in the sealed internal volume of the mold and the external pressure is comprised between 0 and 0.1 bar.
After complete processing of the material by the approach of the master mold (1, 2), the deburring crown (30) removes the surrounding burrs formed by excess material protruding laterally from the master mold (1, 2). 23. A molding process as claimed in any one of claims 13 to 22 using a mold as claimed in claim 7 which is activated to cut.
14. The molding process according to claim 13, wherein the preform or parison can advantageously be provided with a single or multilayer coating before being placed between the two master dies (1, 2).
Before heating the matrix (1,2) and the sleeve (3), a thermoplastic film is placed between the parison or preform (P) and at least one of the two matrices (1,2), 14. A molding process according to claim 13, wherein the thermoplastic film is then affixed to the corresponding surface of the lens and self-welded during the molding stage.
26. A molding process according to claim 25, wherein the film is provided with a single or multilayer coating.
26. A molding process according to claim 25, wherein the film is of the photochromic type.
26. A molding process according to claim 25, wherein the film is of the polarizing type.
26. A molding process according to claim 25, wherein the film is dyed and / or colored.
14. A single layer or multilayer coating is disposed on at least one of the two molds prior to heating the mold, after which the coating is hot transferred to the corresponding surface of the lens during the molding stage. Molding process.
JP2003552526A 2001-12-17 2002-12-17 Thermoforming mold for optical lens made of thermoplastic material and process thereof Expired - Fee Related JP4409291B2 (en)
US10/015,587 US6884369B2 (en) 2001-12-17 2001-12-17 Mold and a method of hot-forming a thermoplastic lens
PCT/FR2002/004386 WO2003051616A2 (en) 2001-12-17 2002-12-17 Mould and method for the hot forming of a thermoplastic optical lens
JP2005511367A JP2005511367A (en) 2005-04-28
JP4409291B2 true JP4409291B2 (en) 2010-02-03
ID=21772305
JP2003552526A Expired - Fee Related JP4409291B2 (en) 2001-12-17 2002-12-17 Thermoforming mold for optical lens made of thermoplastic material and process thereof
US (2) US6884369B2 (en)
EP (1) EP1456006B1 (en)
JP (1) JP4409291B2 (en)
AT (1) AT367260T (en)
AU (1) AU2002364997A1 (en)
DE (1) DE60221280T2 (en)
WO (1) WO2003051616A2 (en)
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WO2014095993A1 (en) * 2012-12-18 2014-06-26 Essilor International (Compagnie Generale D'optique) Method of manufacturing an ophthalmic lens
GB201302268D0 (en) * 2013-02-08 2013-03-27 Ocutec Ltd Molding Apparatus and Method
KR101558056B1 (en) * 2013-11-21 2015-10-06 삼성전기주식회사 Mold device for forming lens
CN107030947B (en) * 2017-05-05 2019-04-02 应达工业（上海）有限公司 A kind of silicon-controlled jacket mould group
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2001-12-17 US US10/015,587 patent/US6884369B2/en active Active
2002-12-17 AT AT02804933T patent/AT367260T/en not_active IP Right Cessation
2002-12-17 AU AU2002364997A patent/AU2002364997A1/en not_active Abandoned
2002-12-17 WO PCT/FR2002/004386 patent/WO2003051616A2/en active IP Right Grant
2002-12-17 DE DE2002621280 patent/DE60221280T2/en active Active
2002-12-17 EP EP20020804933 patent/EP1456006B1/en active Active
2002-12-17 JP JP2003552526A patent/JP4409291B2/en not_active Expired - Fee Related
2005-02-24 US US11/063,566 patent/US20050142240A1/en not_active Abandoned
DE60221280T2 (en) 2008-04-03
EP1456006A2 (en) 2004-09-15
EP1456006B1 (en) 2007-07-18
US20050142240A1 (en) 2005-06-30
AT367260T (en) 2007-08-15
WO2003051616A2 (en) 2003-06-26
JP2005511367A (en) 2005-04-28
WO2003051616A9 (en) 2004-07-01
US20030111747A1 (en) 2003-06-19
WO2003051616A3 (en) 2004-06-03
DE60221280D1 (en) 2007-08-30
AU2002364997A1 (en) 2003-06-30
US6884369B2 (en) 2005-04-26
CN1231341C (en) 2005-12-14 Method for partial crystallation of amorphous plastic articles and apparatus thereof
RU2297914C2 (en) 2007-04-27 Method and device for treatment of blanks
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