Source: http://www.google.com/patents/US8034508?ie=ISO-8859-1
Timestamp: 2015-05-28 06:37:56
Document Index: 500121327

Matched Legal Cases: ['Application No. 08164095', 'Application No. 07250814', 'Application No. 08104319', 'Application No. 08157494', 'Application No. 08164096', 'Application No. 08166328', 'Application No. 08168081', 'Application No. 08168404', 'Application No. 08168032', 'Application No. 08168404', 'Application No. 2006', 'Application No. 06254551']

Patent US8034508 - Polybenzoxazine-based compound, electrolyte membrane including the same, and ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsA crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant of a first monofunctional benzoxazine-based monomer or a second multifunctional benzoxazine-based monomer with a crosslinkable compound, an electrolyte membrane including the crosslinked object, a method of preparing...http://www.google.com/patents/US8034508?utm_source=gb-gplus-sharePatent US8034508 - Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membraneAdvanced Patent SearchPublication numberUS8034508 B2Publication typeGrantApplication numberUS 11/514,254Publication dateOct 11, 2011Filing dateSep 1, 2006Priority dateSep 3, 2005Fee statusPaidAlso published asCN101684180A, CN101684180B, EP1760110A1, EP1760110B1, EP2218748A1, EP2218748B1, US8349515, US8426081, US20070141426, US20120070765, US20120071611Publication number11514254, 514254, US 8034508 B2, US 8034508B2, US-B2-8034508, US8034508 B2, US8034508B2InventorsSeong-Woo Choi, Hee-young Sun, Myung-Jin Lee, Woo-sung JeonOriginal AssigneeSamsung Sdi Co., Ltd.Export CitationBiBTeX, EndNote, RefManPatent Citations (78), Non-Patent Citations (52), Classifications (24), Legal Events (2) External Links: USPTO, USPTO Assignment, EspacenetPolybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US 8034508 B2Abstract
A crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant of a first monofunctional benzoxazine-based monomer or a second multifunctional benzoxazine-based monomer with a crosslinkable compound, an electrolyte membrane including the crosslinked object, a method of preparing the electrolyte membrane, and a fuel cell employing the electrolyte membrane including the crosslinked object. The crosslinked object has a strong acid trapping capability with respect to the benzoxazine-based compound and high mechanical properties due to the crosslinking. The crosslinked object is very stable chemically because of elimination of solubility in polyphosphoric acid. The electrolyte membrane including the crosslinked object has excellent phosphoric acid supplementing capacity at a high temperature and mechanical and chemical stability. Specifically, even when an impregnated amount of a proton carrier, such as phosphoric acid, is increased to increase proton conductivity, the electrolyte membrane maintains excellent mechanical and chemical stability. Accordingly, the electrolyte membrane can be used in a fuel cell for high temperature and no humidity.
1. An electrolyte membrane, comprising a crosslinked polybenzoxazine-based material that is a polymerized resultant product of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below with a crosslinkable compound:
wherein R1 is hydrogen, a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C4-C20 cycloalkyl group or a substituted or nonsubstituted C2-C20 heterocyclic group, a halogen atom, a hydroxyl group, or a cyano group; and
R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group;
wherein, R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group; and
R3 is a substituted or nonsubstituted C1-C20 alkylene group, a substituted or nonsubstituted C1-C20 alkenylene group, a substituted or nonsubstituted C1-C20 alkynylene group, a substituted or nonsubstituted C6-C20 arylene group, a substituted or nonsubstituted C2-C20 heteroarylene group, —C(═O)—, or —SO2—.
2. The electrolyte membrane of claim 1, further comprising a proton conductor.
3. The electrolyte membrane of claim 2, wherein the proton conductor is at least one selected from the group consisting of phosphoric acid and C1-C10 alkyl phosphoric acid; and the amount of the proton conductor is in a range of 100 to 1,000 parts by weight based on 100 parts by weight of the crosslinked polybenzoxazine-based material.
4. The electrolyte membrane of claim 1, wherein R1 of Formula 1 is a C1-C10 alkyl group, an allyl group, a C6-C20 aryl group, a tertbutyl group, a C1-C10 alkenyl group, or a C1-C10 alkynyl group.
5. The electrolyte membrane of claim 1, wherein R2 of Formulas 1 and 2 is —CH2-CH═CH2,
6. The electrolyte membrane of claim 1, wherein R3 of Formula 2 is —C(CH3)2—, —C(CF3)2—, —C(═O)—, —SO2—, —CH2—, —C(CCl3)—, —CH(CH3)—, —CH(CF3)—, or
, wherein, R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group.
7. The electrolyte membrane of claim 1, wherein Formula 1 is represented by Formulas 3 through 12 below:
8. The electrolyte membrane of claim 1, wherein Formula 2 is selected from the group consisting of Formulas 13 through 17 below:
R2 is —CH2—CH═CH2,
9. The electrolyte membrane of claim 1, wherein an amount of the crosslinkable compound is in a range of 5 to 95 parts by weight based on 100 parts by weight of the first benzoxazine-based monomer or the second benzoxazine-based monomer.
10. An electrolyte membrane, comprising a crosslinked polybenzoxazine-based material that is a polymerized resultant product of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below:
11. The electrolyte membrane of claim 10, wherein Formula 1 is represented by Formulas 3 through 12 below:
12. A membrane electrode assembly (MEA) comprising:
an anode support, and
an anode catalyst layer on the support;
a cathode support, and
a cathode catalyst layer on the support; and
the electrolyte membrane of claim 3,
wherein the anode is laminated on one side of the electrolyte membrane and the cathode is laminated on the other side of the electrolyte membrane.
13. The MEA of claim 12, wherein the anode catalyst layer comprises a platinum-cobalt alloy having a platinum loading at and between 2.2 to 3.5 mg/cm3.
14. A high temperature no humidity fuel cell comprising the MEA of claim 12; and a bipolar plate attached to each side of the MEA.
15. A fuel cell employing an electrolyte membrane, comprising the crosslinked polybenzoxazine-based material of claim 1.
16. The electrolyte membrane of claim 10, wherein R3 of Formula 2 is —C(CH3)2—, —C(CF3)2—, —C(═O)—, —SO2—, —CH2—, —C(CCl3)—, —CH(CH3)—, —CH(CF3)—, or
wherein, R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group.
17. The electrolyte membrane of claim 10, further comprising a proton conductor.
18. The electrolyte membrane of claim 17, wherein the proton conductor is at least one selected from the group consisting of phosphoric acid and C1-C10 alkyl phosphoric acid; and an amount of the proton conductor is in a range of 100 to 1,000 parts by weight based on 100 parts by weight of the crosslinked polybenzoxazine-based material.
19. A fuel cell employing an electrolyte membrane, comprising the crosslinked polybenzoxazine-based material of claim 10.
20. The electrolyte membrane of claim 10, wherein R1 of Formula 1 is a C1-C10 alkyl group, an aryl group, a C6-C20 aryl group, a tertbutyl group, a C-C10 alkenyl group, or a C1-C10 alkynyl group.
21. The electrolyte membrane of claim 10, wherein R2 of Formula 1 and R2 of Formula 2 are independently —CH2—CH═CH2,
22. The electrolyte membrane of claim 10, wherein Formula 2 is selected from the group consisting of Formulas 13 through 17 below:
23. A membrane electrode assembly (MEA) comprising:
the electrolyte membrane of claim 17;
an anode catalyst layer on the support; and
a cathode catalyst layer on the support;
24. The MEA of claim 23, wherein the anode catalyst layer comprises a platinum-cobalt alloy having a platinum loading at or between 2.2 to 3.5 mg/cm3.
25. A high temperature no humidity fuel cell comprising the MEA of claim 23; and a bipolar plate attached to each side of the MEA.
This application claims the benefit of Korean Patent Application Nos. 2005-81994 and 2005-81995, both filed Sep. 3, 2005, in the Korean Intellectual Property Office, the disclosures of which are incorporated herein in their entirety by reference.
Aspects of the present invention relate to a polybenzoxazine-based compound, an electrolyte membrane including the same, and a fuel cell employing the same, and more particularly, to a novel polybenzoxazine-based compound, an electrolyte membrane of a fuel cell for a high temperature and no humidity, and a fuel cell employing the electrolyte membrane.
In conventional ionic conductors, ions are moved by applying a voltage. Ionic conductors are widely used in electrochemical devices, such as fuel cells, electrochemical sensors, and the like.
For example, in terms of energy generating efficiency, system efficiency, and component durability, fuel cells require a proton conductor that shows long-term stable proton conductivity at an operating temperature of 100 to 300� C. under zero humidity conditions or low-humidity conditions with a relative humidity of less than 50%.
The above requirements have been considered in the development of conventional solid polymer-type fuel cells. However, solid polymer-type fuel cells that include a perfluorocarbonsulfonic acid membrane as an electrolyte membrane generate insufficient energy at an operating temperature of 100 to 300� C. in a relative humidity of 50% or less.
Conventional fuel cells include fuel cells using an electrolyte membrane containing a proton conducting agent, fuel cells using a silica diffusion membrane, fuel cells using an inorganic-organic composite membrane, fuel cells using a phosphoric acid-doped graft membrane, and fuel cells using an ionic liquid composite membrane.
In addition, a solid polymer electrolyte membrane formed of polybenzimidazole (PBI) in which a strong acid, such as a phosphoric acid or the like, is doped is disclosed (in U.S. Pat. No. 5,525,436). In such an electrolyte membrane, ionic conductivity is increased by phosphoric acid doping, but the phosphoric acid doping causes mechanical properties of the electrolyte membrane to deteriorate. In particular, PBI doped with a strong acid such as a phosphoric acid lacks mechanical strength and chemical stability at high temperatures, and liquid supplementing capability of the phosphoric acid decreases.
Aspects of the present invention provide a polybenzoxazine-based compound having excellent acid trapping capacity, mechanical and chemical stability, and phosphoric acid supplementing capacity at a high temperature, an electrolyte membrane including the same, and a method of preparing the electrolyte membrane. Aspects of the present invention also provide a fuel cell having excellent fuel efficiency and generation efficiency by employing the above electrolyte membrane.
According to an aspect of the present invention, there is provided a crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant product of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below with a crosslinkable compound:
wherein R1 is hydrogen, a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C4-C20 cycloalkyl group or a substituted or nonsubstituted C2-C20 heterocyclic group, a halogen atom, a hydroxyl group, or a cyano group; and R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group;
wherein, R2 is a substituted or nonsubstituted C1-C20 alkyl group, a substituted or nonsubstituted C1-C20 alkenyl group, a substituted or nonsubstituted C1-C20 alkynyl group, a substituted or nonsubstituted C6-C20 aryl group, a substituted or nonsubstituted C7-C20 arylalkyl group, a substituted or nonsubstituted C2-C20 heteroaryl group, a substituted or nonsubstituted C2-C20 heteroarylalkyl group, a substituted or nonsubstituted C4-C20 carbocyclic group, a substituted or nonsubstituted C4-C20 carbocyclic alkyl group, a substituted or nonsubstituted C2-C20 heterocyclic group, or a substituted or nonsubstituted C2-C20 heterocyclic alkyl group; and R3 is a substituted or nonsubstituted C1-C20 alkylene group, a substituted or nonsubstituted C1-C20 alkenylene group, a substituted or nonsubstituted C1-C20 alkynylene group, a substituted or nonsubstituted C6-C20 arylene group, a substituted or nonsubstituted C2-C20 heteroarylene group, —C(═O)—, or —SO2—.
According to another aspect of the present invention, there is provided a crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant product of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below:
According to another aspect of the present invention, there is provided an electrolyte membrane including the crosslinked object of the benzoxazine-based compound described above.
According to another aspect of the present invention, there is provided a method of preparing an electrolyte membrane including a crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below with a crosslinkable compound, the method including: mixing the first benzoxazine-based monomer of Formula 1 or the second benzoxazine-based monomer of Formula 2 with the crosslinkable compound; and curing the resultant mixture, and then impregnating the resultant with a proton conductor:
According to another aspect of the present invention, there is provided a method of preparing an electrolyte membrane including a crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant product of a first benzoxazine-based monomer represented by Formula 1 below or a second benzoxazine-based monomer represented by Formula 2 below with a crosslinkable compound, the method including: mixing the first benzoxazine-based monomer of Formula 1 or the second benzoxazine-based monomer of Formula 2 with the crosslinkable compound; and forming a membrane on a supporter using the resultant mixture, then curing the resultant, and then impregnating the cured resultant with a proton conductor:
While not required in all aspects, the forming of the membrane may be performed by tape casting the resultant mixture on the supporter. Altenatively, the forming of the membrane is performed by casting the resultant mixture on the supporter.
While not required in all aspects, the method may further include detaching the cured resultant from the supporter to remove the supporter.
While not required in all aspects, the proton conductor may be at least one of phosphoric acid and C1-C10 alkyl phosphoric acid; and an amount of the proton conductor is in a range of 100 to 1,000 parts by weight based on 100 parts by weight of the crosslinked object of the polybenzoxazine-based compound.
According to another aspect of the present invention, there is provided a fuel cell employing an electrolyte membrane, including any of the various crosslinked objects of the polybenzoxazine-based compound described above.
FIGS. 1A and 1B are drawings illustrating curing reactions of benzoxazine-based monomers and polybenzimidazole according to embodiments of the present invention;
FIGS. 1C and 1D are drawings illustrating reaction mechanisms of benzoxazine-based monomers and polybenzimidazole according to other embodiments of the present invention;
FIGS. 2 through 4 are graphs illustrating ionic conductivity of electrolyte membranes according to embodiments of the present invention;
FIGS. 5 through 7 are graphs illustrating cell performances of fuel cells according to embodiments of the present invention;
FIG. 8 is a graph illustrating cell performance with respect to time of a fuel cell according to an embodiment of the present invention;
FIGS. 9 through 11 are graphs showing 1H-NMR data of polybenzoxazine monomers according to embodiments of the present invention;
FIG. 12 is a graph illustrating ionic conductivity of electrolyte membranes according to embodiments of the present invention;
FIGS. 13 through 15 are graphs illustrating cell performance of fuel cells according to embodiments of the present invention;
FIGS. 16A, 16B and 16C are nuclear magnetic resonance (NMR) spectra, respectively, of a benzoxazine monomer, polybenzimidazole, and a crosslinked object of a polybenzoxazine-based compound according to an embodiment of the present invention;
FIG. 17 is a Diffusion-Ordered NMR Spectroscopy (DOSY-NMR) spectrum of a mixture of benzoxazine and polybenzimidazole; and
FIG. 18 is an NMR spectrum of a heat-treated mixture of benzoxazine-polybenzimidazole.
According to an embodiment of the present invention, an electrolyte membrane is provided, having excellent mechanical and chemical stability even when the amount of impregnated proton carrier, such as a phosphoric acid, etc., is at a maximum capacity or greater, by preparing the electrolyte membrane using a crosslinked object of a polybenzoxazine-based compound formed by polymerizing a first benzoxazine-based monomer of Formula 1 below or a second, multifunctional, benzoxazine-based monomer of Formula 2 below with a crosslinkable compound:
According to another embodiment of the present invention, an electrolyte membrane is provided, having excellent mechanical and chemical stability even when the amount of impregnated proton carrier, such as a phosphoric acid, etc., is at a maximum capacity or greater, by preparing the electrolyte membrane using a crosslinked object of a polybenzoxazine-based compound formed by polymerizing a first benzoxazine-based monomer of Formula 1 above or a second, multifunctional, benzoxazine-based monomer of Formula 2 above.
R1 of Formula 1 above may preferably be a tertiarybutyl group. R2 of Formulas 1 and 2 may be a phenyl group, —CH2—CH═CH2,
When R3 of Formula 2 is —C(CH3)2—, —C(CF3)2—, —C(═O)—, —SO2—, —CH2—, —C(CCl3)—, —CH(CH3)—, or —CH(CF3)—, Formula 2 is a difunctional benzoxazine-based compound containing 2 benzoxazine rings. When R3 of Formula 2 is a group represented by the formula below, Formula 2 is a trifunctional benzoxazine-based compound containing 3 benzoxazine rings:
The first benzoxazine-based monomer of Formula 1, for example, may be a compound represented by Formulas 3 through 12:
The second benzoxazine-based monomer of Formula 2, for example, may be a compound represented by Formulas 13 through 17:
wherein, R3 is —C(CH3)2—, —C(CF3)2—, —C(═)—, —SO2—, —CH2—, —C(CCl3)—, —CH(CH3)—, —CH(CF3)—, or
and R2 is a phenyl group, —CH2—CH═CH2,
The crosslinkable compound according to the current embodiment of the present invention may be any compound that is crosslinkable with the benzoxazine-based monomer. The crosslinkable compound, for example, may include at least one selected from the group consisting of polybenzimidazole, polybenzthiazole, polybenzoxazole, and polyimide, but is not limited thereto.
A process of synthesizing the crosslinked object of the polybenzoxazine-based compound, which is the polymerized resultant product of the first benzoxazine-based monomer of Formula 1 above or the second benzoxazine-based monomer of Formula 2 above with the crosslinkable compound, will now be described.
The first benzoxazine-based monomer of Formula 1 above or the second benzoxazine-based monomer of Formula 2 above is mixed with the crosslinkable compound in a prescribed mixing ratio. Here, an amount of the crosslinkable compound may be in a range of 5 to 95 parts by weight based on 100 parts by weight of the first benzoxazine-based monomer of Formula 1 or the second benzoxazine-based monomer of Formula 2.
Generally, when the amount of the crosslinkable compound is less than 5 parts by weight, phosphoric acid cannot be impregnated thereby decreasing proton conductivity. Generally, when the amount of the crosslinkable compound is greater than 95 parts by weight, the crosslinked object is dissolved in polyphosphoric acid, thereby allowing gas penetration.
When the resultant mixture is cured, the crosslinked object of the polybenzoxazine-based compound can be obtained through an intercrosslinking reaction as shown in FIG. 1A or FIG. 1B. In other words, through the intercrosslinking reaction of the resultant mixture, the crosslinked object of the polybenzoxazine-based compound can be obtained. That is, the first or second benzoxazine-based monomer is polymerized (cured) with the crosslinkable compound, such as polybenzimidazole, using a thermal ring opening polymerization process to form a polymer matrix. The thermal ring opening polymerization process is performed by regulating temperature gradually. Generally the reaction time should be at least 1 hour, so that the polymer matrix has developed a network structure.
FIGS. 1C and 1D are drawings to describe reaction mechanisms of the first benzoxazine-based monomer and polybenzimidazole; and the second benzoxazine-based monomer and polybenzimidazole respectively according to other embodiments of the present invention.
Referring to FIGS. 1C and 1D, oxazine rings of the first and second benzoxazine-based monomers open due to heat and then the resultant combines with the ortho-sites of phenyl rings of polybenzimidazole (n is a number in the range of 100 to 10,000). Accordingly, intercrosslinking reactions having the same growing directions as in FIGS. 1C and 1D take place.
The curing reaction temperature may differ according to the type, etc., of the first benzoxazine-based monomer, the second benzoxazine-based monomer, and the crosslinkable compound, but may be in a range of 50 to 250� C. Generally, when the curing reaction temperature is lower than 50� C., a curing reaction cannot take place. Generally, when the curing reaction temperature is higher than 250� C., undesirable side reaction substances are obtained.
The curing reaction time depends on the curing reaction temperature, and may be at least 1 hour in the above temperature range. Specifically, the curing reaction time may be in the range of 8 to 20 hours.
The chemical and physical properties of the crosslinked object of the polybenzoxazine-based compound, which is the polymerized resultant of the first benzoxazine-based monomer of Formula 1 or the second benzoxazine-based monomer of Formula 2 and the crosslinkable compound will now be described.
The crosslinked object of the polybenzoxazine-based compound according to aspects of the present invention has thermosetting properties, and so the crosslinked object does not dissolve in any organic solvent, an acid, or a base. Accordingly, molecular weight cannot be measured using Gel Permeation Chromatography (GPC), which is a conventional method of obtaining information on molecular weight of a polymer.
The crosslinked object of the polybenzoxazine-based compound generated from the first or second benzoxazine monomer via polymerization is a thermosetting resin as described above. Accordingly, once the polymerization is performed, the crosslinked object is not soluble in any organic solvents. Moreover, the crosslinked object does not have a glass transition temperature like other polymers. Thus, the crosslinked object cannot be analyzed using a conventional method. Also, even when a thermosetting resin forms a copolymer with a thermoplastic resin, the overall properties of the copolymer will be similar to the thermosetting resin. Thus, it is impossible to prove copolymer formation between the first or second benzoxazine-based monomer and the polybenzimidazole using a conventional method. Accordingly, to prove the copolymer formation, an experiment described below was performed.
As described above, the product of the polymerization reaction of a thermosetting resin has a solubility problem and thus it cannot be analyzed. Thus, the initial product of the polymerization reaction is analyzed to check the bond forming between the first or second benzoxazine-based monomer and the polybenzimidazole. That is, to check the bond forming, a very small portion of the first or second benzoxazine-based monomer is combined with the polybenzimidazole during the initial polymerization. When the overall polymeric properties of the polybenzimidazole are not changed, it is deemed that the first or second benzoxazine-based monomer and the polybenzimidazole formed a copolymer.
FIGS. 16A, 16B and 16C show, respectively, nuclear magnetic resonance (NMR) spectra of the benzoxazine-based monomer, the polybenzimidazole, and the crosslinked object of a polybenzoxazine-based compound prepared by mixing the first benzoxazine-based monomer and the polybenzimidazole in a predetermined ratio, and then heating the resultant mixture at 100� C. for 30 min. As shown in FIGS. 16A and 16B, the first benzoxazine-based monomer and the polybenzimidazole are confirmed by the position of the peaks of each component except the peaks corresponding to solvents. That is, (a) to (d) of FIG. 16A, denoting proton peaks of the first benzoxazine-based monomer, are in different positions from FIG. 16B, illustrating the NMR spectrum of polybenzimidazole. Thus, the existence of the first benzoxazine-based monomer and the polybenzimidazole can be confirmed even when they are mixed in FIG. 16C.
Specifically, (a) in FIG. 16A is a peak of (—C(CH3)3) of a tertiary-butyl group combined with a phenyl group of (t-BuPh-a) of the benzoxazine-based monomer according to the current embodiment of the present invention. Even a small amount of (—C(CH3)3) can be detected because the (—C(CH3)3) has an integrated value corresponding to 9 hydrogen atoms. Consequently, this peak has been used in analyzing the combination of the first benzoxazine-based monomer with polybenzimidazole.
A Diffusion-Ordered NMR Spectroscopy (DOSY-NMR) is a recent NMR measurement method which can classify the spectrum of each component by the difference (or diffusion coefficient) of a hydrodynamic volume of components dissolved in a solution. Using the DOSY-NMR, a polymer compound can easily be analyzed, because the DOSY-NMR can classify solutions in the polymer compound without specific pretreatment. (References: B. Antalek, Concepts in Magnetic Resonance, 14(4), 225-258 (2002); S. Viel, D. Capitani, L. Mannina, A. Segre, Biomacromolecules, 4, 1843-1847 (2003); D. A. Jayawickrama, C. K. Larive, E. F. Macord, D. C. Roe, Magn. Reson. Chem., 36, 755-760 (1998); K. Nishinari, K. Kohyama, P. A. Williams, G. O. Phillips, W. Burchard, K. Ogino, Macromolecules, 24, 5590-5593 (1991); C. M. Leon, V. Gorkom, T. M. Hancewicz, J. Magn. Reson., 130,125-130 (1998); and A. Chen, D. Wu, C. S. Johnson, Jr., J. Am. Chem. Soc. 117, 7965-7970 (1995)).
The formation of the benzoxazine-polybenzimidazole (benzoxazine-PBI) copolymer according to the current embodiment of the present invention was confirmed using the DOSY-NMR. FIG. 17 is a DOSY-NMR spectrum of the mixture of benzoxazine and polybenzimidazole during the initial polymerization reaction. Similar-sized molecules or molecules connected to each other by a combination reaction appear on an identical line of a Y-axis of an NMR spectrum, based on the well accepted theory of the DOSY-NMR. As shown in FIG. 17, the peaks represented by (a), are set by solvents, such as water, DMSO, DMAc, etc., which have very small molecular sizes. Accordingly, these peaks have values of between −9.0 to −9.2 on the Y-axis. The first benzoxazine-based monomers before the reaction, represented by (b) in FIG. 17, are on a same line (e) between about −9.5 to −9.6. Accordingly, using the DOSY-NMR, the types and sizes of the molecules can be classified through the peaks on the one-dimensional NMR spectrum shown in FIGS. 16A, 16B and 16C.
On the one hand, (c), which are the peaks resulting from the polybenzimidazole (PBI), are on about −10.6 which is much smaller than the −9.5 to −9.6 value of the first benzoxazine-based monomer. However, based on the DOSY-NMR principle, a value on the Y-axis corresponds to the diffusion coefficient, and as the molecular size increases, the value on the Y-axis increases in the negative direction. Accordingly, the polybenzimidazole, which is a polymer, has a bigger negative value than the benzoxazine before the reaction, which is a single molecule. The proton peak corresponding to the tertbutyl group (marked by an asterisk) of the benzoxazine-based monomer is on the same line as the polybenzimidazole (dotted d line). This shows that the benzoxazine and the polybenzimidazole combine together to form the copolymer according to the current embodiment of the present invention.
FIG. 18 shows a comparison of a proton-nuclear magnetic resonance (1H-NMR) spectrum obtained using a pulsed field gradient (PFG) technique with a gradient strength of 98% and a spectrum from a normal technique of the heat-treated mixture of benzoxazine-PBI to reconfirm the DOSY-NMR spectrum results. Since the peaks set by molecules smaller than the polybenzimidazole molecules disappear, peaks corresponding to the first benzoxazine-based monomer and the solvent are not shown in (A) of FIG. 18. However, the proton peak corresponding to the tertbutyl group (marked by an asterisk) can still be confirmed, with the peaks corresponding to the polybenzimidazole (marked in (a)) in (A) of FIG. 18, although they are very small. Compared to (B) of FIG. 18, the tertbutyl group shown in (A) of FIG. 18 is not only formed during the initial reaction with a discernible amount in (B) of FIG. 18, but also shifted to an upper field by 0.2 ppm due to reaction with polybenzimidazole. Such a chemical shift in an NMR spectrum is a typical phenomenon which occurs during a chemical reaction. Also, this phenomenon cannot take place with the benzoxazine-based monomer only existing around the polybenzimidazole. Consequently, polybenzoxazine-co-polybenzimidazole (PBOA-co-PBI), which is a copolymer of benzoxazine and polybenzimidazole is confirmed using the method described above.
FIGS. 9 through 11 are graphs showing 1H-NMR data of the first benzoxazine monomers according to the current embodiment of the present invention.
The polymerized resultant described above can be used in an electrolyte membrane of a fuel cell. There are various methods of preparing the electrolyte membrane according to embodiments of the present invention, two such methods will be described. Here, polybenzimidazole is used as a crosslinkable compound.
According to the first method, the first benzoxazine-based monomer of Formula 1 above or the second benzoxazine-based monomer of Formula 2 above is blended with the crosslinkable compound, such as polybenzimidazole. The resultant is cured at 50 to 250� C., preferably 80 to 220� C. Then a proton conductor, such as an acid, is impregnated in the cured resultant to form an electrolyte membrane.
According to the second method, the first benzoxazine-based monomer of Formula 1 above or the second benzoxazine-based monomer of Formula 2 above is mixed with the crosslinkable compound, such as polybenzimidazole, and the resultant mixture is used to form a membrane on a supporter. Then the resultant is cured, and impregnated with a proton conductor. The membrane can be formed using a tape casting method or a conventional coating method. The conventional coating method, for example, may be performed by casting the resultant mixture on a supporter using a doctor blade. Here, the doctor blade may have a 250 to 500 μm gap.
When the casting method using the doctor blade is used during the forming of the membrane, separating the membrane from the supporter after the curing of the resultant, and before the impregnating of the cured resultant may further be performed. The separating of the membrane may be performed at 60 to 80� C. in distilled water.
Any supporter may be used which can support the electrolyte membrane. Examples of the supporter include a glass substrate, a polyimide film, etc. When the tape casting method is used, the membrane is separated from the supporter, such as polyethylene terephthalate, before the curing of the resultant, and then the membrane is put into an oven for curing. Accordingly, removing of the supporter is not required. Also, when the tape casting method is used, the resultant mixture may be filtered. Accordingly, the resultant is cured by heat treatment, and then the cured resultant is impregnated with the proton conductor, such as an acid, to form the electrolyte membrane.
The proton conductor, for example, may be phosphoric acid, C1-C10 alkylphosphoric acid, or the like, but is not limited thereto. Examples of C1-C10 alkylphosphoric acid include ethylphosphoric acid, etc.
An amount of the proton conductor may be in a range of 300 to 1,000 parts by weight based on 100 parts by weight of the electrolyte membrane. The density of the proton conductor is not specifically limited, but when phosphoric acid is used, an 85 wt % aqueous phosphoric acid solution is preferably used. The impregnation time in phosphoric acid may be 2.5 to 14 hours at 80� C.
When only the first or second benzoxazine-based monomer is used in preparing the electrolyte membrane, the same conditions as above are applied, except that the crosslinkable compound, such as polybenzimidazole, is not used.
The electrolyte membrane can be used as a hydrogen ion conducting membrane of a fuel cell. A method of manufacturing a membrane electrode assembly (MEA) using such a hydrogen ion conducting membrane is as follows. The term “MEA” used herein refers to a structure in which electrodes including a catalyst layer and a diffusion layer are laminated on both sides of an electrolyte membrane.
In the MEA, an electrode having a catalyst layer is disposed on each side of the electrolyte membrane according to an embodiment of the present invention. Then the MEA can be formed by binding the electrodes to the electrolyte membrane at a high temperature and high pressure. Alternatively, an MEA can be formed by coating a metal catalyst which causes an electrochemical catalyst reaction on each side of the electrolyte membrane and binding a fuel diffusion layer to the metal catalyst. In either instance, the temperature for the binding may be sufficient to soften the electrolytic membrane, and the pressure may be 0.1 to 3 ton/cm2, for example, 1 ton/cm2.
To manufacture a fuel cell, a bipolar plate is attached to the MEA. The bipolar plate has grooves for supplying fuel, and functions as a collector. While preparing the MEA, the catalyst may be platinum alone, or an alloy or a mixture of platinum and at least one metal selected from the group of metals consisting of gold, palladium, rhodium, iridium, ruthenium, tin, molybdenum, cobalt, nickel, and chrome. The fuel cell is not specifically limited in use, but is preferably used as a polymer electrolyte membrane fuel cell (PEMFC).
The preparation process of the first benzoxazine-based monomer of Formula 1 above will now be described referring to Reaction Scheme 1 below:
wherein, R1 and R2 are as described above.
R1 of Reaction Scheme 1 may be a tertiary butyl group, and R2 may be a phenyl group, —CH2—CH═CH2, .
Referring to Reaction Scheme 1, a phenol compound (A), a p-formaldehyde, and an amine derivative (B) are mixed. The mixture is heated without a solvent or refluxed with a solvent. Accordingly, the resultant undergoes a work-up process to obtain the benzoxazine-based monomer of Formula 1.
Examples of the solvent include 1,4-dioxane, chloroform, dichloromethane, toluene, tetrahydrofuran (THF), etc. Also, during the refluxing, the temperature is regulated to between 50 and 90� C., and specifically about 80� C.
A detailed example of the amine derivative (B) is a compound where R2 is represented by one from the group consisting of
The preparation process of the second benzoxazine-based monomer of Formula 2 above will now be described referring to Reaction Scheme 2 below:
wherein, R2 and R3 are as described above, and specifically, R3 may be —C(CH3)2—, —C(CF3)2—, —C(═O)—, —SO2—, —CH2—, —C(CCl3)—, —CH(CH3)—, —CH(CF3)—,
R2 may be a phenyl group, —CH2—CH═CH2,
Referring to Reaction Scheme 2, a phenol compound (A′), a p-formaldehyde, and an amine derivative (B) are mixed. The mixture is heated without a solvent or refluxed with a solvent. Accordingly, the resultant undergoes a work-up process to obtain the benzoxazine-based monomer of Formula 2. Examples of the solvent include 1,4-dioxane, chloroform, dichloromethane, toluene, THF, etc. Also, during the refluxing, the temperature is regulated to between 50 and 90� C., and specifically about 80� C. A detailed example of the amine derivative (B) is as described above.
Substituents used in Formulas 1 and 2 will now be described.
Detailed examples of the nonsubstituted C1-C20 alkyl group may be methyl, ethyl, propyl, isobutyl, sec-butyl, pentyl, iso-amyl, hexyl, etc. At least one hydrogen atom in the alkyl can be substituted by a halogen atom, a C1-C20 alkyl group substituted with a halogen atom (for example, CCF3, CHCF2, CH2F, CCl3, or the like), a hydroxyl group, a nitro group, a cyano group, an amino group, an amidino group, a hydrazine, a hydrazone, a carboxyl group or a base thereof, a sulfonic acid group or a base thereof, a phosphoric acid or a base thereof, a C1-C20 alkyl group, a C2-C2-arkenyl group, a C2-C20 arkynyl group, a C1-C20 heteroalkyl group, a C6-C20 aryl, a C6-C20 arylalkyl group, a C6-C20 heteroaryl group, or a C6-C20 heteroarylalkyl group.
Detailed examples of the nonsubstituted C1-C20 alkenyl group include vinylene, allyene, etc. Also, at least one hydrogen atom in the alkenyl can be substituted by the same substituents as the alkyl group above.
Detailed examples of the nonsubstituted C1-C20 alkynyl group include acetylene, etc. Also, at least one hydrogen atom in the alkynyl can be substituted by the same substituents as the alkyl group above.
Detailed examples of the nonsubstituted C1-C20 alkylene group include methylene, ethylene, propylene, isobutylene, sec-butylene, pentylene, iso-amylene, hexylene, etc. Also, at least one hydrogen atom in the alkylene can be substituted by the same substituents as the alkyl group above.
Detailed examples of the nonsubstituted C1-C20 alkenylene group include an aryl group, etc. Also, at least one hydrogen atom in the alkenylene can be substituted by the same substituents as the alkyl group above.
Detailed examples of the nonsubstituted C1-C20 alkynylene group include an acetylene group, etc. Also, at least one hydrogen atom in the alkynylene can be substituted by the same substituents as the alkyl group above.
The aryl group may be used alone or in combination of at least two types, and is a C6-C20 carbocyclic aromatic system including at least one ring. The rings may be adhered or fused together using a pendant method. The aryl group includes an aromatic radical, such as phenyl, naphthyl, and tetrahydronaphthyl. The aryl group may have a substituent, such as haloalkaline, nitro, cyano, alkoxy, and low alkylamino. Also, at least one hydrogen atom in the aryl can be substituted by the same substituents as the alkyl group above.
The arylene group may be used alone or in combination of at least two types, and is a C6-C20 carbocyclic aromatic system including at least one ring. The rings may be adhered or fused together using a pendant method. The arylene group includes an aromatic radical, such as phenylene, naphthylene, and tetrahydronaphthylene. The aryl group may have a substituent, such as haloalkylene, nitro, cyano, alkoxy, and low alkylamino. Also, at least one hydrogen atom in the arylene can be substituted by the same substituents as the alkyl group above.
The arylalkyl group is a substituent where a plurality of hydrogen atoms in the aryl group described above are substituted by radicals, such as low alkyl, methyl, ethyl, and propyl. Examples include benzyl, phenylethyl, etc. Also, at least one hydrogen atom in the arylalkyl can be substituted by the same substituents as the alkyl group above.
The heteroaryl group includes 1, 2, or 3 hetero atoms selected from the group consisting of N, O, P, and S. Also, the heteroaryl group has a monovalent monocyclic structure having 5-30 ring atoms, wherein the rest of the ring atoms are carbon, or a noncyclic aromatic bivalent organic compound. Also, at least one hydrogen atom on the hetero atom can be substituted by the same substituents as the alkyl group above.
The heteroarylene group includes 1, 2, or 3 hetero atoms selected from the group consisting of N, O, P, and S. Also, the heteroarylene group has a monovalent monocyclic structure having 1-20 carbon atoms, wherein the rest of the ring atoms are carbon, or a noncyclic aromatic bivalent organic compound. Also, at least one hydrogen atom on the hetero atom can be substituted by the same substituents as the alkyl group above.
The heteroarylalkyl group is a substituent where a plurality of hydrogen atoms in the heteroaryl group are substituted by alkyl groups. Also, at least one hydrogen atom in the heteroarylalkyl can be substituted by the same substituents as the alkyl group above.
The carbocyclic group is a ring group including 5-10 carbon atoms, like a cyclohexyl group. Also, at least one hydrogen atom in the carbocyclic group can be substituted by the same substituents as the alkyl group above.
The carbocyclic alkyl group is a substituent where a plurality of hydrogen atoms in the carbocyclic group are substituted by alkyl groups. Also, at least one hydrogen atom in the carbocyclic alkyl can be substituted by the same substituents as the alkyl group above.
The heterocyclic group is a ring group formed of 5-10 atoms containing hetero atoms, such as nitrogen, sulfur, phosphorus, oxygen, etc. Also, at least one hydrogen atom in the heterocyclic group can be substituted by the same substituents as the alkyl group above.
The heterocyclic alkyl group is a substituent where a plurality of hydrogen atoms in the heterocyclic alkyl group are substituted with alkyl groups. Also, at least one hydrogen atom in the heterocyclic alkyl group can be substituted with the same substituents as the alkyl group above.
Preparation of Benzoxazine-based Monomer of Formula 3
1 mol of phenol, 2.2 mol of p-formaldehyde, and 1.1 mol of aniline were mixed, and the mixture was stirred at 110� C. for 1 hour to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 3 (yield=95%).
Preparation of Benzoxazine-based Monomer of Formula 4
1 mol of tertiarybutylphenol, 2.2 mol of p-formaldehyde, and 1.1 mol of aniline were mixed, and the mixture was stirred at 110� C. for 1 hour without any solvent to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 4 (yield=95%).
Preparation of Benzoxazine-based Monomer of Formula 5
1 mol of tertiarybutylphenol, 2.2 mol of p-formaldehyde, and 1.1 mol of 3-aminopropylimidazole were mixed, and the mixture was stirred at 110� C. for 1 hour without any solvent in a melted state to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 5 (yield=95%).
Preparation of Benzoxazine-based Monomer of Formula 13 (R2=aniline)
1 mol of bisphenol A (BP), 4.4 mol of p-formaldehyde, and 2.2 mol of aniline were mixed, and the mixture was stirred at 110� C. for 1 hour to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer (R2=aniline) of Formula 13 (yield=95%).
Preparation of Benzoxazine-based Monomer of Formula 14 (R2=aniline)
1 mol of 4,4′-hexafluoroisopropylidene diphenol (4,4′-HFIDPH), 4.4 mol of p-formaldehyde, and 2.2 mol of aniline were mixed, and the mixture was stirred at 110� C. for 1 hour to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 14 (yield=96%).
Preparation of Benzoxazine-based Monomer of Formula 15 (R2=3-aminopropyl-imidazole)
1 mol of 4,4′-dihydroxybenzophenone, 2.2 mol of p-formaldehyde, and 1.1 mol of 3-aminopropylimidazole were mixed, and the mixture was stirred at 110� C. for 1 hour without any solvent in a melted state to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 15 (yield=80%).
Preparation of Benzoxazine-based Monomer of Formula 16 (R2=1-(3- aminopropyl)imidazole)
1 mol of bisphenol S (BS), 4.4 mol of p-formaldehyde, and 2.2 mol of 1-(3-aminopropyl) imidazole were mixed, and the mixture was stirred at 110� C. for 1 hour without any solvent in a melted state to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 16 (yield=98%).
Preparation of Benzoxazine-based Monomer of Formula 17 (R2=allvlamine)
1 mol of 1,1,1-tris(4-hydroxyphenyl) ethane, 6.6 mol of p-formaldehyde, and 3.3 mol of allylamine were mixed, and the mixture was stirred at 110� C. for 1 hour without any solvent in a melted state to prepare a crude product.
The crude product was cleaned twice in an aqueous 1N NaOH solution, and then once in distilled water. The cleaned crude product was then dried using magnesium sulfate. Subsequently, the resultant was filtered, and then the solvent was removed therefrom. Next, the resultant product was vacuum dried to obtain a benzoxazine-based monomer of Formula 17 (yield=95%).
Preparation of Electrolyte Membrane and Fuel Cells Employing the Same
65 parts by weight of the benzoxazine monomer of Formula 3 prepared in Synthetic Example 1 and 35 parts by weight of polybenzimidazole were blended. The resultant was heated to 220� C. at 20� C./hr. At 220� C., the heated resultant was cured, to synthesize a crosslinked object of the polybenzoxazine-based compound.
The crosslinked object of the polybenzoxazine-based compound was impregnated in an 85 wt % phosphoric acid at 80� C. for 2 hours and 30 min to prepare an electrolyte membrane. Here, the amount of the phosphoric acid was about 500 parts by weight based on 100 parts by weight of the electrolyte membrane.
The electrolyte membrane formed of the crosslinked object of the polybenzoxazine-based compound, impregnated with the phosphoric acid, was placed between electrodes to obtain a membrane electrode assembly (MEA). Three types of electrodes were used as described below.
First, a first electrode was used as a cathode and an anode. The first electrode was prepared by preparing a slurry for forming a catalyst layer by mixing polybenzimidazole, polyvinylidenefluoride, and platinum, and coating the slurry for forming a catalyst layer on a carbon paper, coated with a microporous layer, using a bar coater. The platinum loading amount of the first electrode was 1.0 to 2.0 mg/cm2. The first electrode was used without impregnation. In the following descriptions of aspects of the present invention, “PBI electrode” denotes the first electrode.
Second, an electrode for a phosphoric acid type fuel cell (manufactured by E-TEK) was used as a cathode and an anode. The platinum loading amount of the electrode for a phosphoric acid type fuel cell was 2.0 mg/cm2. The electrode for a phosphoric acid type fuel cell was impregnated in 110 parts by weight of phosphoric acid based on 100 parts by weight of the electrode for a phosphoric acid type fuel cell at 110� C., for 1 hour, in a vacuum, and then again at 110� C. for 10 hours, under a normal pressure.
Third, the first electrode was used as an anode and a second electrode was used as a cathode. The second electrode was prepared by preparing a slurry for forming a catalyst layer by mixing a platinum-cobalt alloy and polyvinylidenefluoride, and coating the slurry for forming a catalyst layer on a carbon paper coated with a microporous layer, using a doctor blade. The platinum loading amount of the second electrode was 2.2 to 3.5 mg/cm2. The second electrode was used without impregnation.
An electrolyte membrane and fuel cells employing the same were prepared in the same manner as in Example 1, except that the benzoxazine monomer of Formula 4 prepared in Synthetic Example 2 was used instead of the benzoxazine monomer of Formula 3.
An electrolyte membrane and fuel cells employing the same were prepared in the same manner as in Example 1, except that the benzoxazine monomer of Formula 5 prepared in Synthetic Example 3 was used instead of the benzoxazine monomer of Formula 3.
65 parts by weight of the benzoxazine monomer of Formula 13 prepared in Synthetic Example 4 and 35 parts by weight of polybenzimidazole were blended. The resultant was heated to 220� C. at 20� C./hr. At 220� C., the heated resultant was cured, to synthesize a crosslinked object of the polybenzoxazine-based compound.
The crosslinked object of the polybenzoxazine-based compound was impregnated in an 85 wt % phosphoric acid at 80� C. for 2 hours and 30 min to prepare an electrolyte membrane. Here, the amount of the phosphoric acid was about 500 parts by weight based on 100 parts by weight of the electrolyte membrane. Three types of electrodes were used, as described below.
First, a first electrode was used as acathode and an anode. The first electrode was prepared by preparing a slurry for forming a catalyst layer by mixing polybenzimidazole, polyvinylidenefluoride, and platinum, and coating the slurry for forming a catalyst layer on a carbon paper, coated with a microporous layer, using a bar coater. The platinum loading amount of the first electrode was 1.0 to 2.0 mg/cm2. The first electrode was used without impregnation. In the following description of aspects of the present invention, “PBI electrode” denotes the first electrode.
Third, the first electrode was used as an anode and a second electrode was used as a cathode. The second electrode was prepared by preparing a slurry for forming a catalyst layer by mixing a platinum-cobalt alloy and polyvinylidenefluoride, and coating the slurry for forming a catalyst layer on a carbon paper, coated with a microporous layer, using a doctor blade. The platinum loading amount of the second electrode was 2.2 to 3.5 mg/cm2. The second electrode was used without impregnation.
An electrolyte membrane and fuel cells employing the same were prepared in the same manner as in Example 4, except that the benzoxazine monomer of Formula 14 prepared in Synthetic Example 5 was used instead of the benzoxazine monomer of Formula 13.
An electrolyte membrane and fuel cell employing the same were prepared in the same manner as in Example 4, except that the benzoxazine monomer of Formula 15 prepared in Synthetic Example 6 was used instead of the benzoxazine monomer of Formula 13.
An electrolyte membrane and a fuel cell employing the same were prepared in the same manner as in Example 4, except that the benzoxazine monomer of Formula 16 prepared in Synthetic Example 7 was used instead of the benzoxazine monomer of Formula 13.
An electrolyte membrane and a fuel cell employing the same were prepared in the same manner as in Example 4, except that the benzoxazine monomer of Formula 17 prepared in Synthetic Example 8 was used instead of the benzoxazine monomer of Formula 13.
A polybenzimidazole membrane was prepared using PBI CELAZOLE (manufactured by Celanese Corp.), and the polybenzimidazole membrane was impregnated in an 85 wt % phosphoric acid for 4 hours at room temperature.
An MEA was prepared by placing the PBI CELAZOLE poybenzimidazole membrane impregnated with the 85 wt % phosphoric acid between a pair of the first electrodes prepared as in Example 1.
An MEA was prepared by placing the PBI CELAZOLE poybenzimidazole membrane impregnated with the 85 wt % phosphoric acid between a pair of the electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) as described in Example 1.
Ionic conductivity with respect to time at a high temperature was measured to analyze a high temperature stability of the electrolyte membranes obtained according to Examples 1-3. In the high temperature ionic conductivity tests, stainless steel metal electrodes were used with the electrolyte membranes obtained in Examples 1-3.
The ionic conductivity was measured as follows. At a frequency in a range of 1 Hz to 1 MHz, a 10 mV (vs. open circuit potential or O.C.V.) voltage bias was applied while measuring resistance. Stainless steel metal electrodes were initially used, and to evaluate reproducibility of the electrolyte membranes, platinum electrodes were subsequently used.
FIGS. 2 through 4 are graphs illustrating ionic conductivity of the electrolyte membranes of Examples 1 through 3 respectively. Referring to FIGS. 2 through 4, crosslinked objects prepared in the same manner as in Example 1, using 15 to 85 parts by weight of the benzoxazine-based compound with respect to the amount of polybenzimidazole had higher proton conductivity than pure polybenzimidazole. When the amount of the benzoxazine-based compound was 85 parts by weight, the crosslinked object obtained had the highest proton conductivity which was at least ten times better than the proton conductivity of a PBI-H3PO4 electrolyte membrane. The ideal crosslinked object in terms of balancing mechanical strength and conductivity was prepared by using 65 parts by weight of the benzoxazine-based compound and 35 parts by weight of the polybenzimidazole.
SYRI PBI in FIG. 2 is the pure polybenzimidazole without the benzoxazine-based compound. 15PBXZN-85PBI is a polymer electrolyte prepared by using 15 parts by weight of the benzoxazine-based monomer and 85 parts by weight of polybenzimidazole. 75PBXZN-25PBI is a polymer electrolyte prepared by using 75 parts by weight of the benzoxazine-based monomer and 25 parts by weight of polybenzimidazole. Phenol aniline was used as a benzoxazine-based monomer in FIG. 2, tertiary butyl phenol aniline was used as the benzoxazine-based monomer in FIG. 3, and tertiary butyl phenol amino-imidazole was used as the benzoxazine-based monomer in FIG. 4.
Performances of the fuel cells prepared in Examples 2-4 and Comparative Examples 1-2 were analyzed by evaluating the initial properties of the fuel cells and re-evaluating the fuel cells after operating at 0.2 A/cm2 for 16 hours. In fuel cells of Examples 2-4, a pair of the first electrodes, the first electrode as an anode and the second electrode as a cathode, and a pair of the electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) were respectively used.
Here, performances were analyzed by measuring voltage with respect to current density for each fuel cell. Also, resistance was analyzed by measuring alternating current resistance at 1 kHz. The resistance performance analyses of the fuel cells were performed without supplying hydrogen fuel or air, while maintaining the fuel cell temperature at 150� C. When the polybenzimidazole electrode or the air electrode including the PtCo catalyst as prepared in Example 4 was used in the fuel cell, current-voltage properties were measured at 100 ccm (cm3/min) of hydrogen flow rate and 200 ccm of air flow rate. When the electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) was used in the fuel cell, current-voltage properties were measured at 100 ccm of hydrogen flow rate and 300 ccm of air flow rate.
FIGS. 5 through 7 are graphs illustrating cell performances of fuel cells prepared in Example 1 and Comparative Examples 1 and 2. In fuel cells of Example 1, a pair of the first electrodes, the first electrode as an anode and the second electrode as a cathode, and a pair of the electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) were used, as mentioned above.
Referring to FIGS. 5 through 7, the fuel cell employing the polymer electrolyte membrane, prepared using tertiary butyl phenol aniline as the benzoxazine-based monomer compound, had excellent MEA performance compared to the fuel cell employing the PBI—H3PO4 electrolyte membrane. The fuel cell employing the polymer electrolyte membrane, using tertiary butyl phenol amino-imidazole, had a similar MEA performance compared to the fuel cell employing the PBI-phosphoric acid electrolyte membrane. When the MEA performances were analyzed using the fuel cells employing the E-TEK electrodes impregnated with polyphosphoric acid (105wt % phosphoric acid), current-voltage performance were superior in both polymer electrolyte membranes using tertiary butyl phenol aniline and tertiary butyl phenol amino-imidazole as benzoxazine-based monomer compounds. The low MEA performance of the PBI-phosphoric acid Comparative Example 2 is due to gas permeation, which is caused because polyphosphoric acid in the electrode dissolves polybenzimidazole. Because E-TEK electrodes are treated to repulse water, phosphoric acid is inhibited from migration to the electrodes, and as a result, excess phosphoric acid remains in the electrolyte membrane. As the temperatures rises, excess phosphoric acid is changed into polyphosphoric acid which dissolves the PBI membrane.
Using the E-TEK electrode impregnated with polyphosphoric acid, a chemical stability of the electrolyte membrane can be analyzed. Accordingly, the polymer electrolyte membrane including the crosslinked object of the polybenzoxazine-based compound has excellent chemical stability in polyphosphoric acid.
Reference (PBI electrolyte membrane/PBI electrode) in FIGS. 5 and 6 is the MEA employing the PBI electrode and the PBI-phosphoric electrolyte membrane prepared in Comparative Example 1. Also, another reference (PBI electrolyte membrane/E-TEK electrode) in FIGS. 5 and 6 is the MEA prepared in Comparative Example 2. In FIG. 5, t-BuPh-a/PBI electrode (process #1) is the electrode prepared in Example 2. In FIG. 6, t-BuPh-AIMDZ/PBI electrode (process #1) is the electrode prepared in Example 3.
In FIG. 7, Reference (PBI electrolyte membrane/E-TEK electrode) is the MEA prepared in Comparative Example 2. t-BuPh-AIMDZ/E-TEK electrode (process #2) is the MEA employing the polymer electrolyte membrane prepared in Example 3 and the electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) having a platinum loading amount of 2 mg/cm2 as hydrogen and air electrodes. t-BuPh-a/E-TEK electrode (process #2) is the MEA employing the polymer electrolyte prepared in Example 2 and electrodes for a phosphoric acid type fuel cell (manufactured by E-TEK) having a platinum loading amount of 2 mg/cm2 as hydrogen and air electrodes.
FIG. 8 is a graph of cell performance with respect to time of the fuel cell prepared in Example 4.
Referring to FIG. 8, by including the platinum-cobalt catalyst in the air electrode, the cell performance of the fuel cell has improved by 150 mV or more. Also, the open circuit potential continuously increased for 7 days and then stabilized. That is, an electric potential reduction due to gas permeation was not observed for at least 150 hours. Accordingly, the crosslinked object including polybenzoxazine had superior chemical stability. Also, the fuel cell exhibits an excellent performance of 0.7 V cell potential at 0.3 A/cm2 current density under high temperature and non humidity conditions.
FIG. 12 is a graph illustrating ionic conductivity of the electrolyte membranes prepared in Examples 4 through 8. Here, in Examples 4 through 8, stainless steel metal electrodes were used. Referring to FIG. 12, most of the electrolyte membranes including the various crosslinked objects of the polybenzoxazine-based compounds had relatively high proton conductivity compared to the polybenzimidazole electrolyte membrane. In FIG. 12, □ BP-a is when bisphenol A-aniline was used, ∘ 4,4-HFIDPH-a is when 44′-hexafluoroisopropylidene diphenol-aniline was used, Δ 4,4O-a is when 44′-dihydroxybenzophenone-aniline was used, ⋄ 4,4O-aa is when 44′- dihydroxybenzophenone-arylamine was used, ● BS-aa is when bisphenol S-allyl amine was used, ▪ BP-aa is when bisphenol A-allyl amine was used, ● 4,4-HFIDPH-aa is when 44′-hexafluoroisopropylidene diphenol-allyl amine was used, ▴ 4,4O-AIMDZ is when 44′-44′-dihydroxybenzophenone-1-(3-aminopropyl) imidazole was used, ♦ BS-AIMDZ is when bisphenol S-1-(3-aminopropyl) imidazole was used, and ▪ THPE-a is when (1,1,1-Tris(4-hydroxyphenyl) ethane(THPE)-aniline) was used to synthesize the crosslinked object of the poly benzoxazine based compound.
Performances of the fuel cells prepared in Examples 5-8 and Comparative Examples 1-2 were analyzed by evaluating the initial properties of the fuel cells and re-evaluating the fuel cells after operating at 0.3 A/cm2 for 16 hours. Here, performances were analyzed by measuring voltage with respect to current density. Also, resistance was analyzed by measuring alternating current resistance at 1 kHz. The resistance performance analyses of the fuel cells were performed without supplying hydrogen fuel and air, while maintaining the fuel temperature at 150� C. When the polybenzimidazole electrode or the air electrode including the PtCo catalyst as given in Example 4 was used in the fuel cells, current-voltage properties were measured at a hydrogen flow rate of 100 ccm (cm3/min) and an air flow rate of 200 ccm.
FIGS. 13 through 15 are graphs showing cell performance of fuel cells prepared in Example 5 and Comparative Example 1. In FIGS. 13 and 14 a pair of the first electrodes was used, and in FIG. 15, the first electrode as an anode and the second electrode as a cathode was used in the fuel cell of Example 5.
Referring to FIGS. 13 and 14, the MEAs prepared using 44HFIDPh-a monomer and 44HFIDPh-aa BOA monomer had the same or relatively superior cell performance at 150� C. compared to the PBI electrode MEA which was set as a reference. FIG. 15 is a graph showing cell performance of the fuel cell with respect to operating time, where the fuel cell was formed using the crosslinked compound of polybenzimidazole and the polymerized resultant of the 44HFIDPh-a monomer, and specifically, by using the air electrode of PtCo and polyvinylindenefluoride.
Referring to FIGS. 13 through 15, the fuel cell prepared in Example 5 had excellent performance compared to the fuel cell prepared in Comparative Example 1.
The fuel cell prepared in Example 5 had superior performance at 0.3 A/cm2 with an operating voltage of 0.67 V for 330 hours. Also, the fuel cell prepared in Example 5 had excellent durability without any voltage drop.
The crosslinked object of the polybenzoxazine-based compound has a large acid trapping capacity with respect to the benzoxazine-based compound and high mechanical properties due to the crosslinking. Also, the crosslinked object is no longer soluble in polyphosphoric acid, and thus the crosslinked object is very stable chemically. The electrolyte membrane including the crosslinked object has excellent phosphoric acid supplementing capacity at a high temperature and mechanical and chemical stability. The crosslinked object of the polybenzoxazine-based compound can be obtained by a simple polymerization process using heat instead of using a polymerization initiator or a cross-linking agent. Also, an additional cross-linking agent is not needed, and thus mass production is possible. Also, the costs of the starting materials used when synthesizing the crosslinked object are reasonable, and thus expenses are reasonable.
The electrolyte membrane including the crosslinked object of the polybenzoxazine-based compound according to aspects of the present invention can be used in a fuel cell for a high temperature and no humidity.
Patent CitationsCited PatentFiling datePublication dateApplicantTitleUS5098985May 8, 1990Mar 24, 1992The Dow Chemical CompanyCopolymers containing polybenzoxazole, polybenzothiazole and polybenzimidazole moietiesUS5152939Mar 12, 1991Oct 6, 1992Edison Polymer Innovation Corp.Composite densification with benzoxazinesUS5410012Mar 5, 1993Apr 25, 1995The United States Of America As Represented By The Administrator Of The National Aeronautics And Space AdministrationPoly(N-arylenebenzimidazoles) via aromatic nucleophilic displacementUS5525436 *Nov 1, 1994Jun 11, 1996Case Western Reserve UniversityProton conducting polymers used as membranesUS5637670Jan 20, 1995Jun 10, 1997The United States Of America As Represented By The Administrator, National Aeronautics And Space AdministrationPolybenzimidazoles via aromatic nucleophilic displacementUS5945233Jul 16, 1997Aug 31, 1999Avents Research & Technologies Gmbh & Co. KgProcess for producing polybenzimidazole pastes and gels for use in fuel cellsUS6042968Jul 16, 1997Mar 28, 2000Aventis Research & Technologies Gmbh & Co. KgProcess for producing polybenzimidazole fabrics for use in fuelUS6482946Nov 3, 2000Nov 19, 2002Dow Global Technologies Inc.High char yield benzoxazine compositionsUS6620905Feb 23, 2002Sep 16, 2003National Starch And Chemical Investment Holding CorporationCurable compositions containing benzoxazineUS6746792 *Mar 1, 2002Jun 8, 2004Nisshinbo Industries, Inc.Fuel cell separator composition, fuel cell separator and method of manufacture, and solid polymer fuel cellUS7157509Jun 27, 2003Jan 2, 2007Henkel CorporationCurable compositionsUS7371480 *Mar 24, 2004May 13, 2008Fujifilm CorporationSilica sol composition, membrane electrode assembly with proton-exchange membrane, and fuel cellUS7388035Oct 26, 2004Jun 17, 2008Samsung Sdi Co., Ltd.Method for preparing poly(2,5-benzimidazole)US20020127474Jan 9, 2001Sep 12, 2002E.C.R.-Electro-Chemical Research Ltd.Proton-selective conducting membranesUS20020164516Mar 1, 2002Nov 7, 2002Shun HasegawaFuel cell separator composition, fuel cell separator and method of manufacture, and solid polymer fuel cellUS20030190516Apr 7, 2003Oct 9, 2003Fumio TannoFuel cell separator and method of manufactureUS20040005493Jul 3, 2003Jan 8, 2004Nisshinbo Industries, Inc.Fuel cell separator and method of manufactureUS20040028976Aug 7, 2002Feb 12, 2004Israel CabassoModified polybenzimidazole (PBI) membranes for enhanced polymer electrochemical cellsUS20040074651Oct 10, 2002Apr 22, 2004International Business Machines CorporationConformal coating enhanced to provide heat detectionUS20040206953Apr 16, 2003Oct 21, 2004Robert MorenaHermetically sealed glass package and method of fabricationUS20040231143Nov 26, 2003Nov 25, 2004The Regents Of The University Of CaliforniaMethod of making a layered composite electrode/electrolyteUS20040241522 *Mar 24, 2004Dec 2, 2004Fuji Photo Film Co., Ltd.Silica sol composition, membrane electrode assembly with proton-exchange membrane, and fuel cellUS20040261660Jun 27, 2003Dec 30, 2004Henkel Loctite CorporationCurable compositionsUS20050074651Jan 23, 2002Apr 7, 2005Masayuki KidaiPolymer electrolyte film and method for preparation of the same, and solid polymer type fuel cell using the sameUS20050084728Aug 27, 2004Apr 21, 2005Hae-Kyoung KimPolymer nanocomposite membrane and fuel cell using the sameUS20050089744Oct 18, 2004Apr 28, 2005Hyoung-Juhn KimComposite material for bipolar plateUS20050130006Sep 17, 2004Jun 16, 2005Asahi Kasei Kabushiki KaishaMembrane electrode assembly for polymer electrolyte fuel cellUS20050142413Mar 10, 2003Jun 30, 2005Sansho Kakou Co., Ltd.Separator for fuel cell, method for producing the same, and fuel cell using the sameUS20050247908Sep 10, 2003Nov 10, 2005Holger KellerCuring agents for epoxy resins, use thereof and epoxy resin cured therewithUS20060078774Oct 2, 2003Apr 13, 2006Pemeas GmbhProton-conducting polymer membrane containing polyazole blends and application thereof in fuel cellsUS20070020507Jun 23, 2005Jan 25, 2007Hyoung-Juhn KimBinder composition for fuel cell, membrane-electrode assembly for fuel cell, and method for preparing the membrane-electrode assemblyUS20070184323Sep 5, 2006Aug 9, 2007Samsung Sdi Co., Ltd.Electrolyte membrane using polybenzoxazine based compound and method of manufacturing the sameUS20070200994Feb 26, 2007Aug 30, 2007Casio Computer Co., Ltd.Liquid crystal display apparatus comprising spacersUS20070275285May 3, 2007Nov 29, 2007Samsung Sdi Co., Ltd.Polybenzoxazines, electrolyte membrane comprising the same, and fuel cell employing the electrolyte membraneUS20080020264Jun 19, 2007Jan 24, 2008Samsung Sdi Co., Ltd.Electrode for fuel cell and fuel cell employing the electrodeUS20080045688Aug 16, 2007Feb 21, 2008National Chunghsing UniversityProcesses of synthesizing aromatic amine-based benzoxazine resinsUS20080118817Sep 6, 2007May 22, 2008Samsung Sdi Co., Ltd.Additive of electrode for fuel cell, electrode for fuel cell including the same, manufacturing method thereof, and fuel cell using the sameUS20080145743Sep 17, 2007Jun 19, 2008Samsung Sdi Co., Ltd.Electrode for fuel cell, method of manufacturing the electrode, and fuel cell employing the electrodeUS20090075147Jun 6, 2006Mar 19, 2009Kota KitamuraSulfonic acid group-containing polymer, method for producing the same, resin composition containing such sulfonic acid group-containing polymer, polymer electrolyte membrane, polymer electrolyte membrane/electrode assembly, and fuel cellCN101220153ADec 11, 2007Jul 16, 2008山东大学Production method for dihydric phenol type high fire-retardancy benzoxazine resin containing phosphorDE2034887A1Jul 14, 1970Jan 20, 1972 Phosphorylated 2-hydroxy 2,2'-dihydroxy biphenyl - derivs insecticides fungicides flame retardants antioxidantsDE60302673T2Sep 10, 2003Aug 3, 2006Schill + Seilacher AgH�rter f�r epoxidharze, verwendung davon und damit geh�rtetes epoxidharzEP1247844A2Apr 2, 2002Oct 9, 2002Nippon Paint Co., Ltd.Coating composition containing benzoxazine compoundsEP1247884A2Mar 11, 2002Oct 9, 2002Retech AktiengesellschaftDevice for measuring the temperature of a heated rollerEP1253661A1Dec 6, 1999Oct 30, 2002Hitachi Chemical Company, Ltd.Fuel cell, fuel cell separator, and method of manufacture thereofEP1760110A1Aug 31, 2006Mar 7, 2007Samsung SDI Co., Ltd.Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membraneEP1881549A1Feb 27, 2007Jan 23, 2008Samsung SDI Co., Ltd.Electrode for fuel cell and fuel cell employing the electrodeJP2001270891A Title not availableJP2002260682A Title not availableJP2003012747A Title not availableJP2003012924A Title not availableJP2003286320A Title not availableJP2004043547A Title not availableJP2004103494A Title not availableJP2004149779A Title not availableJP2004179514A Title not availableJP2005041936A Title not availableJP2005082690A Title not availableJP2005283082A Title not availableJP2006339065A Title not availableJPH1025343A Title not availableJPH1197011A Title not availableJPH05283082A Title not availableJPH11503262A Title not availableKR20060011831A Title not availableKR20060055291A Title not availableKR20070025626A Title not availableKR20070025627A Title not availableKR20070102579A Title not availableWO1996013872A1Oct 31, 1995May 9, 1996Univ Case Western ReserveProton conducting polymersWO2002014334A1Aug 9, 2001Feb 21, 2002Kuboki KenichiPhenol compounds, resin compositions and products of curing thereofWO2002057279A1Nov 20, 2001Jul 25, 2002Magendie FranckFlame-proofing agentsWO2003072638A1Jan 10, 2003Sep 4, 2003Nat Starch Chem InvestCurable compositions containing benzoxazineWO2004009708A1Jul 19, 2002Jan 29, 2004Nobuyuki FurukawaCurable resin compositionWO2004024791A1Sep 10, 2003Mar 25, 2004Udo GlaunerCuring agents for epoxy resins, use thereof and epoxy resin cured therewithWO2004101509A2Apr 19, 2004Nov 25, 2004Ishida HatsuoFunctionalized benzoxazines, polymers and copolymers thereofWO2005000955A1Jun 24, 2004Jan 6, 2005Henkel CorpHeat curable compositions comprising a benzoxazine component and an acrylonitrile-butadiene copolymer having secondary amine terminal groups as a toughenerWO2006132207A1Jun 6, 2006Dec 14, 2006Toyo BosekiSulfonic acid group-containing polymer, method for producing same, resin composition containing such sulfonic acid group-containing polymer, polymer electrolyte membrane, polymer electrolyte membrane/electrode assembly, and fuel cell* Cited by examinerNon-Patent CitationsReference1A. Chen et al. "Determination of Molecular Weight Distributions for Polymers by Diffusion-Ordered NMR.", J. Am. Chem. Soc. (1995) vol. 117, pp. 7965-7970.2B.Antalek. "Using Pulsed Gradient Spin Echo NMR for Chemical Mixture Analysis: How to Obtain Optimum Results.", Concepts in Magnetic Resonance (2002) vol. 14(4), pp. 225-258.3Beletskaya et al., "Arylation of 6H-Dibenzo[c,e][1,2 lambda5]oxaphosphinine 6-Oxide", Russian Journal of Organic Chemistry, vol. 40, No. 12, 2004, pp. 1782-1786.4Beletskaya et al., "Arylation of 6H-Dibenzo[c,e][1,2 λ5]oxaphosphinine 6-Oxide", Russian Journal of Organic Chemistry, vol. 40, No. 12, 2004, pp. 1782-1786.5Choi et al., "Synthesis, characterization and thermal degradation of functional benzoxazine monomers and polymers containing phenylphosphine oxide", Polymer Degradation and Stability, vol. 91, No. 5, May 1, 2006, pp. 1166-1178.6D. A. Jayawickrama et al. "Polymer additives mixture analysis using pulsed-field gradient NMR spectroscopy.", Magn.Reson. Chem (1998), vol. 36, pp. 755-760.7European Office Action in EP 10163034.1-2115, dated Jul. 19, 2010 (Choi, et al.), European Office Action from prosecution of corresponding European application.8European Office Action issued in corresponding EP Application No. 08164095.5 on Dec. 4, 2008.9European Office Action issued in corresponding European Patent Application No. 07250814.6 on Oct. 30, 2007.10European Search Report issued in European Patent Application No. 08104319.2 on Oct. 13, 2008.11European Search Report issued in European Patent Application No. 08157494.9 on Nov. 24, 2008.12European Search Report issued in European Patent Application No. 08164096.3 on Jan. 20, 2009.13European Search Report issued in European Patent Application No. 08166328.8 on Jan. 22, 2009.14European Search Report issued in European Patent Application No. 08168081.1 on Jan. 28, 2009.15European Search Report issued in European Patent Application No. 08168404.5 on Feb. 10, 2009.16Extended European Search Report issued in European Patent Application No. 08168032.4 on Feb. 3, 2009.17Extended European Search Report issued in European Patent Application No. 08168404.5 on Apr. 23, 2009.18Hajime Kimura et al. "Epoxy Resin Cured by Bisphenol A Based Benzoxazine.", Journal of Applied Polymer Science (1998), vol. 68, pp. 1903-1910.19Hirai et al., "Air-Induced anti-Markovnikov Addition of Secondary Phosphine Oxides and H-Phosphinates to Alkenes", National Institute of Advanced Industrial Science and Technology, Organic Letters 2007, vol. 9, No. 1, pp. 53-55.20Human translation of JP 2003-286320, A. Takeichi et al., Oct. 2003.21Human translation of JP 2004-103494, Kimura et al., Apr. 2004.22Ishida, et al.; Regioselectivity of the Ring-Opening Polymerization of Monofunctional Alkyl-Substituted Aromatic Amine-Based Benzoxazines; Polymer; Jun. 12, 2000; 3115-3125; 42 Elsevier; Cleveland, OH, USA.23K. Nishinari et al. "Soulution Properties of Pullulan.", Macromolecules (1991) vol. 24, pp. 5590-5593.24Kim, H.J., et al. "Synthesis and Thermal Characterization of Polybenzoxazines Based on Acetylene-functional Monomers". Polymer, vol. 40, No. 23. Nov. 1999. pp. 6565-6573.25Kim, Hyoung-Juhn et al. Polybenzimidazoles for High Temperature Fuel Cell Application. Macromol. Rapid Commun. 2004, vol. 25, pp. 1410-1413.26Kimura, et al.; Epoxy Resin Cured by Bisphenol A Based Benzoxazine; Oct. 18, 1997; 1903-1910; Osaka Municipal Technical Research Institute; Osaka, Japan.27Kimura, et al.; Epoxy Resin Cured by Bisphenol A Based Benzoxazine; Oct. 18, 1997; 1903—1910; Osaka Municipal Technical Research Institute; Osaka, Japan.28L. Van Gorkom et al. "Analysis of DOSY and GPC-NMR Experiments on Polymers by Multivariate Curve Resolution.", Journal of Magnetic Resonance (1998) vol. 130, pp. 125-130.29Lin et al., "Synthesis and Properties of Flame-Retardant Benzoxazines by Three Approaches", Journal of Polymer Science, Part A: Polymer Chemistry, vol. 44, 2006, pp. 3454-3468.30Low, Hong Yee, et al. "Structural Effects of Phenols on the Thermal and Thermo-oxidative Degradation of Polybenzoxazines". Polymer, vol. 40, No. 15. Jul. 1999. pp. 4365-4376.31Machine translation of JP 2004-149779, Sakaguchi et al., May 2004.32Office Action issued by Japanese Patent Office in Japanese Patent Application No. 2006-239572 on Mar. 2, 2009.33Pu, H., et al., "Proton Transport in Polybenzimidazole Blended with H3PO4 or H2SO4", J. Polymer Science, Part B: Polymer Physics, vol. 40, 2002, pp. 663-669.34S. Viel et al. "Diffusion-Ordered NMR Spectroscopy: A Versatile Tool for the Molecular Weight Determination of Uncharged Polysaccharides.", Biomacromolecules (2003) vol. 4, pp. 1843-1847.35Schuster, Martin F.H., et al., "Anhydrous Proton-Conducting Polymers", Annu. Rev. Mater. Res., vol. 33, 2003, pp. 233-261.36Search Reports issued in European Patent Application No. 06254551.2-2115 on Nov. 21, 2006.37Shen, Shyan Bob, et al. "Synthesis and Characterization of Polyfunctional Naphthoxazines and Related Polymers". Journal of Applied Polymer Science vol. 61, No. 9. 1996, pp. 1595-1605.38U.S. Appl. No. 11/514,831, filed Sep. 5, 2006, Myung-jin Lee et al., Samsung Electronics Co., Ltd.39U.S. Appl. No. 11/743,778, filed May 3, 2007, Seong-woo Choi et al., Samsung Electronics Co., Ltd.40U.S. Appl. No. 11/765,033, filed Jun. 19, 2007, Hee-young Sun et al., Samsung Electronics Co., Ltd.41U.S. Appl. No. 11/765,056, filed Jun. 19, 2007, Kyung-jung Kwon et al., Samsung Electronics Co., Ltd.42U.S. Appl. No. 11/856,350, filed Sep. 17, 2007, Seong-woo Choi et al., Samsung Electronics Co., Ltd.43U.S. Appl. No. 11/947,011, filed Nov. 29, 2007, Seong-woo Choi et al., Samsung Electronics Co., Ltd.44U.S. Appl. No. 12/208,492, filed Sep. 11, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.45U.S. Appl. No. 12/208,664, filed Sep. 11, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.46U.S. Appl. No. 12/247,388, filed Oct. 8, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.47U.S. Appl. No. 12/262,854, filed Oct. 31, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.48U.S. Appl. No. 12/263,011, filed Oct. 31, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.49U.S. Appl. No. 12/266,039, filed Nov. 6, 2008, Seong-woo Choi et al., Samsung Electronics Co., Ltd.50Ueda, Mitsuru et al. Poly(benzimidazole) Synthesis by Direct Reaction of Methoxyphthalic Acids and Tetramine. J. Poly. Sci. Part A: Polym. Chem, 27 pp. 2815-2818 (1989).51Yamada et al., "A Novel Synthesis of 6-Hydroxyalkyl- and 6-Hydroxy-aralkyl-6H-dibenz[c,e][1,2]oxaphosphorin 6-Oxides", vol. 27, 1990, pp. 845-850.52Yamada, M. et al., "Anhydrous proton conducting polymer electrolytes based on poly(vinylphosphonic acid)-heterocyclic composite material", Polymer, vol. 46, No. 9, 2005, pp. 2986-2992.Classifications U.S. Classification429/492, 429/491, 528/423International ClassificationH01M8/10, C08G73/06Cooperative ClassificationH01M8/1004, H01M8/103, C08G73/18, H01M8/1072, C08G73/06, H01M8/1048, H01M4/921, H01M8/0234, Y10T156/10, Y02E60/521, H01M8/1027, H01M8/1032European ClassificationH01M8/10E2B10, H01M8/10E2P2, H01M8/10E2B6, C08G73/18, C08G73/06, H01M8/10E2B8, H01M8/10E2F4BLegal EventsDateCodeEventDescriptionApr 1, 2015FPAYFee paymentYear of fee payment: 4Sep 1, 2006ASAssignmentOwner name: SAMSUNG SDI CO., LTD., KOREA, REPUBLIC OFFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CHOI, SEONG-WOO;SUN, HEE-YOUNG;LEE, MYUNG-JIN;AND OTHERS;REEL/FRAME:018262/0366Effective date: 20060831RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services