Source: https://patents.justia.com/patent/8138614
Timestamp: 2019-07-18 23:40:54
Document Index: 781956664

Matched Legal Cases: ['Application No. 2005', 'art 221', 'art 221', 'art 221', 'art 221', 'art 221', 'art 221', 'Application No. 07002102', 'Application No. 10010109']

US Patent for Semiconductor device having an antenna with anisotropic conductive adhesive Patent (Patent # 8,138,614 issued March 20, 2012) - Justia Patents Search
Justia Patents With Adhesive MeansUS Patent for Semiconductor device having an antenna with anisotropic conductive adhesive Patent (Patent # 8,138,614)
Semiconductor device having an antenna with anisotropic conductive adhesive
Feb 5, 2007 - Semiconductor Energy Laboratory Co., Ltd.
It is an object to provide a semiconductor device capable of transmitting and receiving data with a reader/writer and reducing breakdown or interference due to static electricity. A semiconductor device includes a semiconductor integrated circuit, a conductive layer serving as an antenna that is connected to the semiconductor integrated circuit, and a substrate interposing the semiconductor integrated circuit and the conductive layer, where at least one of a layer forming the semiconductor integrated circuit, a layer covering the semiconductor integrated circuit, and the substrate is formed from a conductive polymer. In accordance with the above structure, wireless communication with a reader/writer is possible, and breakdown or malfunction in the semiconductor integrated circuit due to static electricity is reduced.
A semiconductor device including an antenna and a semiconductor integrated circuit electrically connected to the antenna has been attracted attention as an RFID tag. A manufacturing method of an RFID tag has been proposed, in which a plurality of antennas is provided over a flexible substrate, and a semiconductor integrated circuit is electrically connected to the plurality of antennas (refer to Patent Document 1: Japanese Published Patent Application No. 2005-115646).
The present invention has a feature in that a semiconductor integrated circuit, a conductive layer serving as an antenna that is electrically connected to the semiconductor integrated circuit, and one or a plurality of substrates that is provided to cover the semiconductor integrated circuit and the conductive layer are included, and in that at least one of a layer forming the semiconductor integrated circuit, a layer covering the semiconductor integrated circuit, and the substrate is formed from a conductive polymer.
One aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a conductive layer serving as an antenna that is electrically connected to the semiconductor integrated circuit, where one or a plurality of substrates that is provided to cover the semiconductor integrated circuit and the conductive layer, and at least one of the substrates is formed from a conductive polymer.
It is to be noted that the substrate interposing the semiconductor integrated circuit and the conductive layer may be formed from cellulosic fiber and conductive polymer fiber.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a conductive layer serving as an antenna that is electrically connected to the semiconductor integrated circuit, one or a plurality of substrates that is provided to cover the semiconductor integrated circuit and the conductive layer, and an adhesive bonding the semiconductor integrated circuit and the substrate, where the adhesive is formed from a composition having a conductive polymer.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a conductive layer serving as an antenna that is electrically connected to the semiconductor integrated circuit, and a layer covering the semiconductor integrated circuit, where the layer covering the semiconductor integrated circuit is formed from a conductive polymer.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a conductive layer serving as an antenna that is electrically connected to the semiconductor integrated circuit, and a layer covering the semiconductor integrated circuit and the antenna, where the layer covering the semiconductor integrated circuit and the antenna is formed from a conductive polymer.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a connection terminal electrically connected to the semiconductor integrated circuit, a layer covering part of the connection terminal, which is formed over the semiconductor integrated circuit, a substrate provided with a conductive layer serving as an antenna, and an anisotropic conductive adhesive including a conductive particle that electrically connects the connection terminal and the conductive layer serving as an antenna and that bonds the substrate and the semiconductor integrated circuit, where the layer covering part of the connection terminal is formed from a conductive polymer. Further, a plurality of connection terminals is provided, the layer covering part of the connection terminal is divided, and the divided layer covering part of the connection terminal is not necessary to be connected to two or more of connection terminals.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a connection terminal electrically connected to the semiconductor integrated circuit, a substrate provided with a conductive layer serving as an antenna, a layer covering part of the conductive layer serving as an antenna, and an anisotropic conductive adhesive including a conductive particle that electrically connects the connection terminal and the conductive layer serving as an antenna and that bonds the substrate and the semiconductor integrated circuit, where the layer covering part of the conductive layer serving as an antenna is formed from a conductive polymer.
Another aspect of the present invention is a semiconductor device including a semiconductor integrated circuit, a connection terminal electrically connected to the semiconductor integrated circuit, a substrate provided with a conductive layer serving as an antenna, and an anisotropic conductive adhesive including a conductive particle that electrically connects the connection terminal and the conductive layer serving as an antenna and that bonds the substrate and the semiconductor integrated circuit, where the anisotropic conductive adhesive is formed from a composition having a conductive polymer.
It is to be noted that volume resistivity of the conductive polymer is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
A semiconductor device of the present invention includes a substrate or a layer over one side surface or both side surfaces of the semiconductor integrated circuit, using a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. Therefore, the semiconductor device of the present invention is capable of wireless communication with a reader/writer, and breakdown or malfunction in the semiconductor integrated circuit due to static electricity are reduced.
Further, a semiconductor device of the present invention includes a layer over one side surface or both side surfaces of the semiconductor integrated circuit, using a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. Therefore, the semiconductor device of the present invention is thin and capable of wireless communication with a reader/writer, and breakdown or malfunction in the semiconductor integrated circuit due to static electricity are reduced. Moreover, the number of substrates and the amount of adhesive can be reduced, and then cost can be reduced.
FIG. 5 is a cross-sectional view showing a semiconductor device of the present invention.
FIG. 6 is a cross-sectional view showing a semiconductor device of the present invention.
FIG. 17 is a cross-sectional view showing a semiconductor device of the present invention.
As shown in FIG. 1A, in a semiconductor device of this embodiment mode, a chip 100 including a semiconductor element and a substrate 104 formed from a conductive polymer are attached to each other with an adhesive 103, and the substrate 104 formed from a conductive polymer is provided to cover the chip including a semiconductor element.
The conductive polymer forming the substrate 104 is formed from an organic compound having conductivity of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 10 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. As the organic compound having conductivity of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm, polythiophene, polypyrrole, polyaniline, polyphenylenevinylene, polyacene, polyacetylene, polyacrylonitrile, polyperinaphthalene, or the like can be used. The substrate 104 formed from a conductive polymer may have flexibility.
When a substrate formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm is provided to cover the chip including a semiconductor element, wireless communication between the semiconductor device and a reader/writer is possible without interrupting an electric wave or an electromagnetic wave. In addition, when a substrate formed from a conductive polymer of which volume resistivity is less than or equal to 1012 Ω·cm is provided to cover the chip including a semiconductor element, breakdown of the semiconductor device due to static electricity can be prevented.
Further, in the semiconductor device shown in FIG. 1A, the insulating layer 115 and the antenna 116 of the chip 100 including a semiconductor element and the substrate 104 formed from a conductive polymer are bonded with the adhesive 103. Thus, the substrate 104 formed from a conductive polymer is provided to cover the chip including a semiconductor element.
A substrate where an adhesive organic resin (such as an acrylic resin, an epoxy resin, a silicone resin, or a phenolic resin) as a layer formed from a thermoplastic material is stacked over the plastic substrate can be used. In this case, the substrate 104 formed from a conductive polymer is attached to the chip 100 including a semiconductor element by thermo-compression with the use of a thermal bonding method. Then, part of the substrate 104 (an adhesive organic resin as a layer formed from a thermoplastic material) is melted and then cooled, whereby the substrate 104 can be bonded to the chip 100 including a semiconductor element.
The insulating layer 115 can be formed as a similar way to the insulating layer 113. Alternatively, the insulating layer 115 may be formed using an organic compound such as an acrylic resin, a polyimide resin, a melamine resin, a polyester resin, a polycarbonate resin, a phenolic resin, an epoxy resin, a diallylphthalate resin, by a coating method. In addition, the insulating layer 115 may be formed using the following: an inorganic siloxane polymer including a Si—O—Si bond among compounds including silicon, oxygen, and hydrogen formed by using a siloxane polymer-based material as a starting material, which is typified by silica glass; or an organic siloxane polymer in which hydrogen bonded to silicon is substituted by an organic group such as methyl or phenyl, which is typified by an alkylsiloxane polymer, an alkylsilsesquioxane polymer, a silsesquioxane hydride polymer, or an alkylsilsesquioxane hydride polymer.
FIGS. 15A to 15C show top views of an antenna that can be applied to the present invention. In a case of applying an electromagnetic coupling method or an electromagnetic induction method (e.g., 13.56 MHz band) as a signal transmission method in the semiconductor device, a shape of a conductive layer serving as an antenna can be a rectangular coiled shape 271 as shown in FIG. 15A or a circular coiled shape (e.g., a spiral antenna) in order to utilize electromagnetic induction caused by changes in the density of a magnetic field. Alternatively, the antenna can have a rectangular-loop shape 272 as shown in FIG. 15B or a circular-loop shape.
In a case of applying a microwave method (e.g., UHF band (860 to 960 MHz band), 2.45 GHz band, or the like), the shape (e.g., length) of a conductive layer serving as an antenna may be determined appropriately by taking into consideration the wavelength of electromagnetic waves that are used for signal transmission. For example, a linear-dipole shape 273 as shown in FIG. 15C, a curved dipole shape, or a plane shape (e.g., a patch antenna) can be used.
Furthermore, the substrate 104 formed from a conductive polymer may be further provided as shown in FIG. 1A over a surface of the substrate 111. The semiconductor integrated circuit is interposed by the substrates formed from a conductive polymer, whereby breakdown of the semiconductor integrated circuit or interference of information transmission and reception due to static electricity from plural directions can be avoided.
It is to be noted that a chip 101 including a semiconductor element may be used, in which the substrate 111 is removed from the chip 100 including a semiconductor element as shown in FIG. 1A. Specifically, as shown in FIG. 1B, an insulating layer 113, a semiconductor integrated circuit 112 formed over the insulating layer 113, and an antenna 116 connected to a wiring 117 of a thin film transistor 114 forming the semiconductor integrated circuit 112 through an insulating layer 115 may be used.
Moreover, as shown in FIG. 1C, a silicon chip using a silicon substrate may be used as a chip 102 including a semiconductor element. Typically, the silicon chip includes a semiconductor integrated circuit 120 including a semiconductor element such as a MOS transistor, a capacitor, a resistor, and a diode over a surface of a silicon wafer, and an antenna 124 electrically connected to the semiconductor element of the semiconductor integrated circuit 120 (here, a MOS transistor 122) through an insulating layer 123.
In the semiconductor device shown in FIG. 1C, substrates 104a and 104b are bonded to the chip 102 including a semiconductor element with an adhesive 103, and the substrates 104a and 104b are provided to cover the chip 102 including a semiconductor element, which is similar to the semiconductor device shown in FIG. 1B. Here, the adhesive 103 is provided to surround the chip 102 including a semiconductor element. Further, a substrate formed from a conductive polymer is used for the both substrates 104a and 104b bonded to plural surfaces of the chip 102 including a semiconductor element.
Instead of the semiconductor devices shown in FIGS. 1A to 1C, a semiconductor device as shown in FIG. 17 may be used. The semiconductor device has substrates 192 and 193 and a chip 101 including a semiconductor element, in which one of the substrates 192 and 193 is bonded to the chip 101 including a semiconductor element with an adhesive 103, and the substrates 192 and 193 are bonded to each other with the adhesive 103 at outer edges of the chip 101 including a semiconductor element. Here, the both substrates 192 and 193 are provided to cover the chip 101 including a semiconductor element. In addition, a substrate formed from a conductive polymer is used for the substrates 192 and 193. It is to be noted that the chips 100 and 102 including a semiconductor element shown in FIGS. 1A and 1C may be applied instead of the chip 101 including a semiconductor element.
As an adhesive that bonds a chip 100 including a semiconductor element and a substrate 131 as shown in FIG. 2A, an adhesive 132 formed from a conductive polymer can be used, of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
Similarly to the semiconductor device shown in FIG. 2A, a chip 101 including a semiconductor element without a substrate shown in FIG. 2B may be bonded between two substrates 131a and 131b with the use of an adhesive 132 formed from a conductive polymer. Here, since the adhesive 132 is provided to surround the chip 101 including a semiconductor element, breakdown and interference due to static electricity in all directions can be prevented.
Similarly to the semiconductor devices shown in FIGS. 2A and 2B, a chip 102 including a semiconductor element that is made of a silicon chip with a silicon substrate as shown in FIG. 2C may be bonded between two substrates 131a and 131b with the use of an adhesive 132 formed from a conductive polymer. Here, since the adhesive 132 is provided to surround the chip 102 including a semiconductor element, breakdown and interference due to static electricity in all directions can be prevented.
Further, in FIGS. 2B and 2C, the substrate 131a may be attached to only one of surfaces of the chips 101 and 102 each including a semiconductor element with the use of the adhesive 132 formed from a conductive polymer as shown in FIG. 2A. Further, the substrate 131a may be attached to one of surfaces of the chips 101 and 102 each including a semiconductor element with the use of the adhesive 132 formed from a conductive polymer, and the substrate 111 may be attached to another surface of the chips 101 and 102 each including a semiconductor element with the use of the adhesive 103 shown in FIGS. 1A to 1C.
Moreover, in the semiconductor devices shown in FIGS. 2A to 2C, a substrate formed from a conductive polymer may be used for the substrates 131, 131a, and 131b as similar to the adhesive 132.
As described above, the semiconductor device of this embodiment mode has the chip including a semiconductor element provided with the substrate or the adhesive formed from a conductive polymer. Therefore, the semiconductor device of this embodiment mode can communicate with a reader/writer without interruption of an electric wave or an electromagnetic wave, and breakdown or interference in a semiconductor integrated circuit due to static electricity can be prevented.
As shown in FIG. 3A, the chip 100 including a semiconductor element of this embodiment mode has a substrate 111, a semiconductor integrated circuit 112 formed over the substrate 111 with an insulating layer 113 interposed therebetween, and an antenna 116 electrically connected to a thin film transistor 114 forming the semiconductor integrated circuit 112 through a layer 141. The layer 141 is provided to cover the semiconductor integrated circuit 112. The layer 141 is formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
As shown in FIG. 3B, a chip 100 including a semiconductor element of this embodiment mode may have a substrate 111, a semiconductor integrated circuit 112 formed over a substrate 111 with the insulating layer 113 interposed therebetween, an antenna 116 electrically connected to a thin film transistor 114 forming the semiconductor integrated circuit 112 through an insulating layer 115, and a layer 142 covering the antenna 116 and the insulating layer 115. The layer 142 is formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
In this embodiment mode, as the chip 100 including a semiconductor element, the chip including a semiconductor element that has the semiconductor integrated circuit 112 formed using the thin film transistor 114 over the substrate and the antenna as shown in FIG. 1A is shown. However, the present invention is not limited thereto. The present invention can be applied to the chip 101 including a semiconductor element without a substrate as shown in FIG. 1B and the chip 102 including a semiconductor element that is made of a silicon chip as shown in FIG. 1C.
In this embodiment mode, a semiconductor device in which a chip including a semiconductor element and a substrate provided with an antenna are bonded to each other will be explained with reference to FIGS. 4A to 4D, FIG. 5, and FIG. 6. The chip including a semiconductor element of this embodiment mode has no antenna, which is different from the chips 100 to 102 including a semiconductor element described in Embodiment Mode 1 or 2.
As shown in FIG. 4A, in the semiconductor device of this embodiment mode, a chip 150 including a semiconductor element and a substrate 152 provided with an antenna 151 are bonded with an anisotropic conductive adhesive 153. A connection terminal 118 provided in the chip 150 including a semiconductor element and the antenna 151 are electrically connected through a conductive particle 154 dispersed in the anisotropic conductive adhesive 153.
As formation of the layer 155 through which the connection terminal 118 and the thin film transistor 114 are connected, a composition including a conductive polymer, such as polythiophene, polypyrrole, polyaniline, polyphenylenevinylene, polyacene, polyacetylene, polyacrylonitrile, or poly-perinaphthalene, of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm, is applied and baked. In a case where the connection terminal 118 is covered with the composition including a conductive polymer when the composition is applied, the connection terminal 118 may be partially etched so as to be exposed after the composition is baked so that the layer 155 through which the connection terminal 118 and the thin film transistor 114 are connected is formed.
As the anisotropic conductive adhesive 153 that is an adhesive resin including the dispersed conductive particle 154 (the grain size is several nm to several tens μm, preferably, about 3 to 7 μm), an epoxy resin, a phenolic resin, or the like can be given. The conductive particle 154 is formed from one or more elements selected from gold, silver, copper, palladium, and platinum. The conductive particle 154 may have a multi-layer structure of these elements. Further, the conductive particle in which a thin film formed from one or more elements selected from gold, silver, copper, palladium, and platinum is formed over a surface of a particle formed from a resin may be used.
As shown in FIG. 4B, a chip 156 including a semiconductor element of this embodiment mode has a substrate 111, a semiconductor integrated circuit 112 formed over the substrate 111 with an insulating layer 113 interposed therebetween, a connection terminal 118 electrically connected to a thin film transistor 114 forming the semiconductor integrated circuit 112 through an insulating layer 115, and a layer 157 covering part of the connection terminal 118 and the insulating layer 115. The layer 157 covering part of the connection terminal 118 and the insulating layer 115 is provided to cover the semiconductor integrated circuit 112 and formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
Here, FIGS. 4C and 4D show top views of the connection terminal 118 side of the chips 150 and 156 including a semiconductor element shown in FIGS. 4A and 4B. As shown in FIG. 4C, the layers 155 and 157 may be provided so as to be in contact with the connection terminal 118 and a connection terminal 119 that are different from each other. Alternatively, as shown in FIG. 4D, layers 155a, 155b, 157a, and 157b that are divided may be provided so as to be in contact with only one of the connection terminals 118 and 119 that are different from each other.
The layers 155 and 157 in the chips 150 and 156 including a semiconductor element of the semiconductor devices shown in FIGS. 4A to 4C are formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. Therefore, short-circuited of the different connection terminals 118 and 119 can be avoided even if the layers 155 and 157 are in contact with the different connection terminals 118 and 119. The layers 155 and 157 in the chips 150 and 156 including a semiconductor element of the semiconductor devices shown in FIGS. 4A to 4D can protect the semiconductor integrated circuit 112 from damage due to static electricity from external.
Instead of the structure in which the layer or the insulating layer 115 through which the connection terminal 118 and the thin film transistor 114 are connected is formed over the semiconductor integrated circuit 112 and a connection terminal is formed thereover as shown in FIGS. 4A and 4B, a chip 158 including a semiconductor element as shown in FIG. 5 may be used, which has connection terminals 162 and 163 in a semiconductor integrated circuit 161. In this case, a layer 164 covering part of a wiring of the semiconductor integrated circuit 161 is formed from a conductive polymer. The layer 164 covering part of a wiring of the semiconductor integrated circuit 161 is provided to cover the thin film transistor 114.
Further, a semiconductor device in which a chip 170 including a semiconductor element has no layer formed from a conductive polymer and a layer 171 covering part of an antenna 151 is formed on a substrate 152 provided with the antenna 151 may be used as shown in FIG. 6. The layer 171 is provided to cover a semiconductor integrated circuit 112 and formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
Typically, the chip 170 including a semiconductor element and the substrate 152 provided with the antenna 151 and the layer 171 covering part of the antenna are bonded with an anisotropic conductive adhesive 153. The chip 170 including a semiconductor element has a substrate 111, the semiconductor integrated circuit 112 formed over the substrate 111 with an insulating layer 113 interposed therebetween, and a connection terminal 118 connected to a thin film transistor 114 forming the semiconductor integrated circuit 112 through an insulating layer 115. Further, the thin film transistor 114 in the semiconductor integrated circuit 112 and the antenna 151 are electrically connected through a conductive particle 154 dispersed in the anisotropic conductive adhesive 153 and the connection terminal 118. The layer 171 covering part of the antenna 151 is formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 ∩·cm.
Further, as shown in FIG. 7A, a substrate 172 provided with an antenna 151 may be formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
It is to be noted that the semiconductor device shown in FIG. 18A is an example in which the chip including a semiconductor element of the semiconductor device shown in FIG. 4A is assumed as the chip 195 including a semiconductor element without a substrate. The chip 195 including a semiconductor element without a substrate can be applied to the semiconductor devices shown in FIG. 4B, FIG. 5, FIG. 6, and FIGS. 7A and 7B without being limited to the above.
It is to be noted that the semiconductor device shown in FIG. 18B is an example in which the chip including a semiconductor element of the semiconductor device shown in FIG. 4A is assumed as the chip 196 including a semiconductor element made of a silicon chip. The chip 196 including a semiconductor element made of a silicon chip can be applied to the semiconductor devices shown in FIG. 4B, FIG. 5, FIG. 6, and FIGS. 7A and 7B without being limited to the above.
In the semiconductor devices shown in Embodiment Modes 2 and 3, a layer formed from a conductive polymer or a substrate formed from a conductive polymer may be additionally provided on a side opposite to the layers 141, 142, 155, 157, 164, and 171 formed from a conductive polymer through the semiconductor integrated circuits 112 and 161. Further, a layer formed from a conductive polymer, a substrate formed from a conductive polymer, or an anisotropic conductive adhesive using a conductive polymer may be additionally provided on a side opposite to the substrate 172 or the anisotropic conductive adhesive 173 formed from a conductive polymer through the semiconductor integrated circuits 112 and 161. As a specific example, the semiconductor device of FIG. 3A is used for explanation; however, the semiconductor devices shown in FIG. 3B and FIGS. 4A to 4D, FIG. 5, FIG. 6, and FIGS. 7A and 7B can be applied.
In the chip 100 including a semiconductor element shown in FIG. 3A, a layer 181 formed from a conductive polymer may be provided between the substrate 111 and the insulating layer 113 as shown in FIG. 8A. Specifically, a chip 180 including a semiconductor element may be made, which has the substrate 111, the layer 181 formed from a conductive polymer provided over the substrate 111, the insulating layer 113 and the semiconductor integrated circuit 112 provided over the layer 181, and the antenna 116 electrically connected to the thin film transistor 114 forming the semiconductor integrated circuit 112 through the layer 141. The layers 141 and 181 are provided to cover the semiconductor integrated circuit 112 and formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
The layer 181 is formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. Typically, a composition including polythiophene, polypyrrole, polyaniline, polyphenylenevinylene, polyacene, polyacetylene, polyacrylonitrile, poly-perinaphthalene, or the like is applied and baked for formation of the layer 181.
Further, the semiconductor integrated circuit 112, the layer 141 formed from a conductive polymer, and the antenna 116 formed over the insulating layer 113 may be bonded to the substrate 111 with an adhesive formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm. As a result, the adhesive formed from a conductive polymer becomes the layer 181. As for the adhesive formed from a conductive polymer, the adhesive 132 formed from a conductive polymer shown in Embodiment Mode 1 can be applied.
Further, in the chip 100 including a semiconductor element shown in FIG. 3A, a substrate 182 formed from a conductive polymer of which volume resistivity is greater than or equal to 10−3 Ω·cm and less than or equal to 1012 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm may be provided on a surface of the substrate 111 as shown in FIG. 8B. Specifically, a chip 100 including a semiconductor element may be made, which has the substrate 182 formed from a conductive polymer, the substrate 111 provided over the substrate 182, the insulating layer 113 and the semiconductor integrated circuit 112 provided over the substrate 111, and the antenna 116 electrically connected to the thin film transistor 114 forming the semiconductor integrated circuit 112 through the layer 141. It is to be noted that the substrate 182 and the layer 141 are formed from a conductive polymer.
Furthermore, in the chip 100 including a semiconductor element shown in FIG. 3A, a substrate 131 may be provided with the use of an adhesive 183 formed from a conductive polymer of which volume resistivity is greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm, preferably greater than or equal to 1 Ω·cm and less than or equal to 109 Ω·cm further preferably, greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm on a surface of the substrate 111 as shown in FIG. 8C. Specifically, a chip 100 including a semiconductor element may be made, which has the substrate 131, the substrate 111 bonded over the substrate 131 with the adhesive 183, the insulating layer 113 and the semiconductor integrated circuit 112 provided over the substrate 111, and the antenna 116 electrically connected to the thin film transistor 114 forming the semiconductor integrated circuit 112 through the layer 141. It is to be noted that the adhesive 183 and the layer 181 are formed from a conductive polymer.
In this embodiment, a manufacturing process of a semiconductor device capable of transmitting data wirelessly will be explained with reference to FIGS. 9A to 9E, FIGS. 10A to 10D, and FIGS. 1A to 11C.
As shown in FIG. 9A, a peeling layer 202 is formed over a substrate 201, an insulating layer 203 is formed over the peeling layer 202, a thin film transistor 204 and an interlayer insulating layer 205 that insulates a conductive layer forming the thin film transistor 204 are formed over the insulating layer 203, and a source electrode and drain electrode 206 connected to a semiconductor layer of the thin film transistor 204 are formed. Then, an insulating layer 207 covering the thin film transistor 204, the interlayer insulating layer 205, and the source electrode and drain electrode 206 is formed, and a conductive layer 208 connected to the source electrode or drain electrode 206 through the insulating layer 207 is formed.
Tungsten oxide is represented by WOx where x is in the range of 2≦x≦3. The x may be 2 (WO2), 2.5 (W2O5), 2.75 (W4O11), 3 (WO3), or the like.
When a crystallization process at a heat-resistance temperature (approximately 600° C.) or lower of the glass substrate is used for the above crystallization step, a glass substrate having a large size can be used. Therefore, a large quantity of semiconductor devices can be manufactured per substrate, and costs can be reduced.
Further, the semiconductor layer may be formed by performing a crystallization step by heating at the temperature of heat resistance of the glass substrate or more. Typically, a quartz substrate is used for the substrate 201 with an insulating surface, and an amorphous or microcrystalline semiconductor is heated at 700° C. or more, whereby the semiconductor layer is formed. As a result, a semiconductor having high crystallinity can be formed. Therefore, a thin film transistor of which properties such as response speed and mobility are favorable and which is capable of high speed operation can be provided.
Next, as shown in FIG. 9B, a conductive layer 211 is formed over the conductive layer 208. Here, a composition that includes gold particles is printed by a printing method, and then, heating is performed at 200° C. for 30 minutes to bake the composition, whereby the conductive layer 211 is formed.
Subsequently, as shown in FIG. 9C, a layer 212 for covering the insulating layer 207 and an edge portion of the conductive layer 211 is formed from a conductive polymer. Here, the layer 212 covering the insulating layer 207 and the edge portion of the conductive layer 211 is formed using an epoxy resin and polyaniline. After a composition of an epoxy resin and polyaniline is applied by a spin coating method, the composition is heated at 160° C. for 30 minutes. Then, the layer at a portion where the conductive layer 211 is covered is removed so as to expose the conductive layer 211, and the layer 212 is formed, as well, with a thickness of 1 to 20 μm, preferably, 5 to 10 μm. Here, a stacked body including the insulating layer 203 to the layer 212 is referred to as an element formation layer 210.
Then, as shown in FIG. 9D, in order to perform a subsequent peeling step easily, the insulating layers 203, 205, and 207 and the layer 212 are irradiated with laser light 213 to form an opening 214 as shown in FIG. 9E. Subsequently, an adhesive 215 is attached to the layer 212. As the laser light used for forming the opening 214, laser light having a wavelength that is absorbed by the insulating layers 203, 205, and 207 or the layer 212 is preferably used. Typically, laser light in the UV region, the visible region, or the infrared region is appropriately selected for irradiation.
As a laser oscillator capable of oscillating such laser light, an excimer laser oscillator such as a KrF, ArF, or XeCl laser oscilllator; a gas laser oscillator such as a He, He—Cd, Ar, He—Ne, HF, or CO2 laser oscillator; a solid laser oscillator such as a crystal laser oscillator in which a crystal such as YAG, GdVO4, YVO4, YLF, or YAlO3 is doped with Cr, Nd, Er, Ho, Ce, Co, Ti, or Tm, a glass laser oscillator, or a ruby laser oscillator; or a semiconductor laser oscillator such as a GaN, GaAs, GaALAs, or InGaAsP laser oscillator can be used. In the solid laser oscillator, the fundamental wave to the fifth harmonic wave may be appropriately used. As a result, the insulating layers 203, 205, and 207 and the layer 212 are melted by absorbing the laser light laser light to form the opening.
Next, as shown in FIG. 10A, a part 221 of the element formation layer is peeled from the substrate 201 having the peeling layer by a physical means by dividing a metal oxide layer formed in the interface between the peeling layer 202 and the insulating layer 203. The physical means refers to a dynamic means or a mechanical means, which changes some dynamic energy (mechanical energy). The typical physical means refers to mechanical power addition (for example, peeling by a human hand or grip tool or separation treatment by rolling a roller).
In this embodiment, the layer that does not contract in heat treatment is the peeling layer 202, the layer that contracts in heat treatment is the insulating layer 203 or the layer 212, and the layer in the intermediate state of the layer that does not contract and the layer that contracts in heat treatment is the layer formed in the interface of the peeling layer 202 and the insulating layer 203. As typical examples, a tungsten layer is used for the peeling layer 202, oxidized silicon or nitrided silicon is used for the insulating layer 203, and a composition of an epoxy resin and polyaniline is used for the layer 212. Consequently, the peeling layer 202 does not contract, but the insulating layer 203 and the layer 212 contract in heat treatment such as crystallization of the amorphous silicon film, activation of an impurity, or dehydrogenation. In addition, a tungsten oxide layer (WOx 2≦x≦3) is formed in the interface of the peeling layer 202 and the insulating layer 203. Since the tungsten oxide layer is brittle, the layer is easily separated by the above physical means. As a result, the portion 221 of the element formation layer can be peeled from the substrate 201 by the above physical means.
In FIG. 9E, the following method can be used: a fluoride halogen gas such as NF3, BrF3, or ClF3 is introduced into the opening 214 before the adhesive 215 is attached to the layer 212; after the peeling layer is etched with a fluoride halogen gas and removed, the adhesive 215 is attached to the layer 212; and the element formation layer 210 is peeled from the substrate.
Next, as shown in FIG. 10B, a flexible substrate 222 is attached to the insulating layer 203 of the part 221 of the element formation layer, and the adhesive 215 is peeled from the part 221 of the element formation layer. Here, a film formed from polyaniline by a cast method is used as the flexible substrate 222.
Subsequently, as shown in FIG. 10C, the flexible substrate 222 is attached to a UV sheet 231 of a dicing frame 232. Since the UV sheet 231 has adhesiveness, the flexible substrate 222 is fixed over the UV sheet 231. Thereafter, the conductive layer 211 is irradiated with laser light to enhance adhesion between the conductive layer 211 and the conductive layer 208.
Next, as shown in FIG. 11A, the part 221 of the element formation layer is divided into parts. Here, the part 221 of the element formation layer and the flexible substrate 222 are irradiated with laser light 234 to divide the part 221 of the element formation layer into a plurality as shown in FIG. 11B. As for the laser light 234, the laser light that is described for the laser light 213 can be applied by being appropriately selected. Laser light that can be absorbed by the insulating layers 203, 205, and 206, the layer 212, and the flexible substrate 222 is preferably selected. Although the part of the element formation layer is divided into a plurality by using a laser cut method here, a dicing method, a scribing method, or the like can be appropriately used instead of this method. As a result, the divided element formation layer is referred to as thin film integrated circuits 242a and 242b.
Subsequently, as shown in FIG. 11C, the UV sheet of the dicing frame 232 is irradiated with UV light to lower the adhesiveness of the UV sheet 231, and then, the UV sheet is supported by an expander frame 244. At this time, the UV sheet 231 is supported by the expander frame 244 while being extended, whereby the width of a groove 241 formed between the thin film integrated circuits 242a and 242b can be expanded. It is to be noted that the size of an expanded groove 246 preferably corresponds to the size of an antenna substrate attached to the thin film integrated circuits 242a and 242b in a subsequent step.
Next, as shown in FIG. 12A, a flexible substrate 256 having conductive layers 252a and 252b each serving as an antenna and the thin film integrated circuits 242a and 242b are attached with anisotropic conductive adhesives 255a and 255b. Openings are provided in the flexible substrate 256 having the conductive layers 252a and 252b each serving as an antenna so as to expose part of the conductive layers 252a and 252b. Therefore, the conductive layers 252a and 252b each serving as an antenna and each of the connection terminals of the thin film integrated circuits 242a and 242b are attached while being aligned so as to be connected to each other through conductive particles 254a and 254b included in the anisotropic conductive adhesives 255a and 255b, respectively.
According to the above steps, semiconductor devices 262a and 262b capable of transmitting data wirelessly can be manufactured as shown in FIG. 12C.
Alternatively, a semiconductor device 264 shown in FIG. 12D may be manufactured by the following steps: providing a flexible substrate so as to seal the flexible substrate 256 having the conductive layers 252a and 252b each serving as an antenna and the thin film integrated circuits 242a and 242b after the flexible substrate 256 and the thin film integrated circuits 242a and 242b are attached with the use of the anisotropic conductive adhesives 255a and 255b as shown in FIG. 12A; and irradiating the region where the conductive layers 252a and 252b each serving as an antenna and the thin film integrated circuits 242a and 242b are not formed with the laser light 261 as shown in FIG. 12B. In this case, the thin film integrated circuit is sealed with the divided flexible substrate 256 and a divided flexible substrate 263; therefore, deterioration of the thin film integrated circuit can be suppressed.
A structure of the semiconductor device capable of transmitting data wirelessly of the above embodiment will be explained with reference to FIG. 13.
The semiconductor device capable of transmitting data wirelessly as shown the above embodiment is acceptable for a wide range of products. For example, the semiconductor device can be applied to bills, coins, securities, bearer bonds, identification certificates (a driver's license, a certificate of residence, and the like, refer to FIG. 14A), containers for package (wrapping paper, bottles, and the like, refer to FIG. 14C), recording media (DVD software, video tapes, and the like, refer to FIG. 14B), vehicles (bicycles and the like, refer to FIG. 14D), personal belongings (bags, glasses, and the like), foods, plants, animals, human bodies, clothes, commodities, electronic appliances, baggage tags (refer to FIGS. 14E and 14F), and the like. The electronic appliances include a liquid crystal display device, an EL display device, a television device (also referred to as simply a TV, a TV receiver, or a television receiver), a cellular phone, and the like.
This application is based on Japanese Patent Application serial no. 2006-031720 filed in Japan Patent Office on Feb. 8 in 2006, the entire contents of which are hereby incorporated by reference.
a connection terminal electrically connected to the semiconductor integrated circuit;
a conductive polymer substrate provided with an antenna that comprises a conductive layer; and
an anisotropic conductive adhesive including a conductive polymer and a conductive particle for electrically connecting the connection terminal and the antenna, wherein a volume resistivity of the conductive polymer is greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
2. A semiconductor device according to claim 1, wherein, the semiconductor device is one selected from the group consisting of an IC card, an RFID tag, an IC tag, an ID tag, a transponder, an IC chip, and an ID chip.
3. A semiconductor device according to claim 1, wherein, the semiconductor device is incorporated in one selected from the group consisting of an identification certificate, a recording media, a container for package, a vehicle, and a baggage tag.
a conductive polymer substrate provided with an antenna that comprises a conductive layer over the semiconductor integrated circuit; and
an anisotropic conductive adhesive including a conductive polymer and a conductive particle for electrically connecting the connection terminal and the antenna,
wherein a volume resistivity of the conductive polymer is greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
5. A semiconductor device according to claim 4, wherein, the semiconductor device is one selected from the group consisting of an IC card, an RFID tag, an IC tag, an ID tag, a transponder, an IC chip, and an ID chip.
6. A semiconductor device according to claim 4, wherein, the semiconductor device is incorporated in one selected from the group consisting of an identification certificate, a recording media, a container for package, a vehicle, and a baggage tag.
wherein a volume resistivity of each of the conductive polymer substrate and the conductive polymer is greater than or equal to 103 Ω·cm and less than or equal to 106 Ω·cm.
8. A semiconductor device according to claim 7, wherein, the semiconductor device is one selected from the group consisting of an IC card, an RFID tag, an IC tag, an ID tag, a transponder, an IC chip, and an ID chip.
9. A semiconductor device according to claim 7, wherein, the semiconductor device is incorporated in one selected from the group consisting of an identification certificate, a recording media, a container for package, a vehicle, and a baggage tag.
11. A semiconductor device according to claim 10, wherein, the semiconductor device is one selected from the group consisting of an IC card, an RFID tag, an IC tag, an ID tag, a transponder, an IC chip, and an ID chip.
12. A semiconductor device according to claim 10, wherein, the semiconductor device is incorporated in one selected from the group consisting of an identification certificate, a recording media, a container for package, a vehicle, and a baggage tag.
4278510 July 14, 1981 Chien et al.
4642263 February 10, 1987 Culbertson
6153726 November 28, 2000 Kathirgamanathan et al.
6919215 July 19, 2005 Yamazaki et al.
6937153 August 30, 2005 Redlin
7141451 November 28, 2006 Tsunoda et al.
7183928 February 27, 2007 Redlin
7243421 July 17, 2007 Bentley et al.
20030213939 November 20, 2003 Narayan et al.
20040001000 January 1, 2004 Redlin
20040080048 April 29, 2004 Haruta et al.
20040162397 August 19, 2004 Lee et al.
20050035805 February 17, 2005 Tanada
20050130397 June 16, 2005 Bentley et al.
20050134463 June 23, 2005 Yamazaki
20050134464 June 23, 2005 Redlin
20050148121 July 7, 2005 Yamazaki et al.
20060117554 June 8, 2006 Herrmann et al.
20060134318 June 22, 2006 Hudd et al.
20060290501 December 28, 2006 Hammad et al.
0 921 147 June 1999 EP
1 522 956 April 2005 EP
05-091044 December 1993 JP
05334912 December 1993 JP
2005-115646 April 2005 JP
WO 03/085681 October 2003 WO
WO-2004/068389 August 2004 WO
WO-2005/044451 May 2005 WO
WO-2005/045095 May 2005 WO
WO-2005/056875 June 2005 WO
Partial European Search Report (Application No. 07002102.7) Dated May 11, 2007.
European Search Report (Application No. 10010109.6), dated Sep. 5, 2011.
Patent number: 8138614
Filed: Feb 5, 2007
Patent Publication Number: 20070181875
Inventors: Shunpei Yamazaki (Setagaya), Koji Dairiki (Isehara)
Application Number: 11/702,085
Current U.S. Class: With Adhesive Means (257/783); In Array Having Structure For Use As Imager Or Display, Or With Transparent Electrode (257/72); Including Resistive Element (257/536); Combined With Electrical Contact Or Lead (257/734); Substrate Comprising Other Than A Semiconductor Material, E.g. Insulating Substrate Or Layered Substrate Including A Non-semiconductor Layer (epo) (257/E27.111)
International Classification: H01L 23/48 (20060101); H01L 29/40 (20060101); H01L 29/04 (20060101);