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Patent US20030024439 - Colorant dispersing liquid, ink composition for ink jet and method for ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsA colorant dispersing liquid and an ink composition for ink jet that is made from a colorant dispersing liquid is described. The colorant dispersing liquid comprises at least a colorant, a dispersing agent and water, wherein the dispersing agent includes at least one compound selected from the compounds...http://www.google.com/patents/US20030024439?utm_source=gb-gplus-sharePatent US20030024439 - Colorant dispersing liquid, ink composition for ink jet and method for forming pictureAdvanced Patent SearchPublication numberUS20030024439 A1Publication typeApplicationApplication numberUS 10/082,080Publication dateFeb 6, 2003Filing dateFeb 26, 2002Priority dateFeb 27, 2001Also published asUS6702889Publication number082080, 10082080, US 2003/0024439 A1, US 2003/024439 A1, US 20030024439 A1, US 20030024439A1, US 2003024439 A1, US 2003024439A1, US-A1-20030024439, US-A1-2003024439, US2003/0024439A1, US2003/024439A1, US20030024439 A1, US20030024439A1, US2003024439 A1, US2003024439A1InventorsHatada Shigeo, Taniguchi KeishiOriginal AssigneeHatada Shigeo, Taniguchi KeishiExport CitationBiBTeX, EndNote, RefManPatent Citations (5), Referenced by (4), Classifications (13), Legal Events (3) External Links: USPTO, USPTO Assignment, EspacenetColorant dispersing liquid, ink composition for ink jet and method for forming picture
US 20030024439 A1Abstract
A colorant dispersing liquid and an ink composition for ink jet that is made from a colorant dispersing liquid is described. The colorant dispersing liquid comprises at least a colorant, a dispersing agent and water, wherein the dispersing agent includes at least one compound selected from the compounds with formula (1a) or (1b): The ink for ink jet is formulated with the colorant dispersing liquid and at least one additive selected from the group consisting of water, a water-soluble organic solvent, a surfactant and a preservative. Images(11) Claims(33)
What is claimed is: 1. A colorant dispersing liquid comprising a colorant, a dispersing agent and water, wherein the dispersing agent includes at least one compound with a general formula (1a) or (1b): wherein R1 is H, a C1˜C20 alkyl, allyl or aralkyl group, phenyl, substituted phenyl or naphthyl; k is an integer of 0˜7; A1 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene; A2 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene; i, j≧0 and (i+j) ranges from 30 to 100; M1 is selected from the group consisting of H, Li, Na, K, and N30 R2 R3 R4 R5, wherein each of R2, R3, R4 and R5 is either H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl; and p, q<1 and (p+q)=3. 2. The colorant dispersing liquid of claim 1, further comprising a compound selected from the group consisting of compounds expressed by formulae (2), (3), and (4), respectively
R6—(A3)m—OH (2)
R12O—(A4)x—CH2COOM3 (4)
wherein in formula (2), R6 is C8˜C14 alkyl, A3 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, and m is an integer of 3˜16; in formula (3), M2 is selected from the group consisting of H, Li, Na, K and N+R8 R9 R10 R11, wherein each of R8, R9, R10, and R11 is either H, methyl, ethyl, 2-hydroxyethyl or 3hydroxypropyl, and R7 is C1˜C20 alkyl; and in formula (4), R12 is C1˜C20 alkyl, A4 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, x is an integer of 1˜12, and M3 is selected from the group consisting of H, Li, Na, K and N+R13 R14 R15 R16, wherein each of R13, R14, R15, and R16 is either H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl. 3. The colorant dispersing liquid of claim 2, wherein a weight ratio of the dispersing agent to the compound of formula (2) ranges from 99.99/0.01 to 60/40. 4. The colorant dispersing liquid of claim 2, wherein a weight ratio of the dispersing agent to the compound of formula (3) ranges from 99.99/0.01 to 60/40. 5. The colorant dispersing liquid of claim 2, wherein a weight ratio of the dispersing agent to the compound of formula (4) ranges from 99.99/0.01 to 60/40. 6. The colorant dispersing liquid of claim 1, wherein the colorant comprises Pigment Yellow 138 and/or Pigment Red 122. 7. The colorant dispersing liquid of claim 1, wherein the colorant comprises a colorant selected from the group consisting of Pigment Blue 15, Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3 and Pigment Blue 15:4. 8. The colorant dispersing liquid of claim 1, wherein a ratio of the colorant to the dispersing agent ranges from 1/15 to 1. 9. The colorant dispersing liquid of claim 1, wherein a mean grain size of the colorant ranges from 20 nm to 200 nm. 10. The colorant dispersing liquid of claim 1, wherein a concentration of the colorant ranges from 5 wt % to 30 wt %. 11. An ink composition for ink jet, comprising the colorant dispersing liquid of any one of the claims 1˜10 and at least one additive selected from the group consisting of water, a water-soluble solvent, a surfactant and a preservative. 12. The ink composition of claim 11, wherein a mean grain size of the colorant ranges from 20 nm to 200 nm. 13. The ink composition of claim 11, wherein a concentration of the colorant ranges from 1 wt % to 8 wt %. 14. A method for forming a picture, comprising using the ink composition of any one of the claims 11˜13 to print a picture with a piezo-type ink jet printer. 15. A method for forming a picture, comprising using an ink composition of any one of the claims 11˜13 to print a picture with a thermal-type ink jet printer. 16. A colorant dispersing liquid comprising a colorant, a dispersing agent, and water, wherein the dispersing agent includes at least one compound with a general formula (1b′): formula (1b′) wherein R1 is H, a C1˜C20 alkyl, allyl or aralkyl group, phenyl, substituted phenyl or naphthyl; k is an integer of 0˜7; and n ranges from 30 to 100. 17. The colorant dispersing liquid of claim 16, further comprising a compound of formula (2) formula (2) R6—(A3)m—OH (2) wherein R6 is C8˜C14 alkyl, A3 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, and m is an integer of 3˜16. 18. The colorant dispersing liquid of claim 17, wherein a weight ratio of the dispersing agent to the compound of formula (2) ranges from 99.99/0.01 to 60/40. 19. The colorant dispersing liquid of claim 16, further comprising a compound with a general formula (3) formula (3) wherein M2 is selected from the group consisting of H, Li, Na, K and N+R8 R9 R10 R11, wherein each of R8, R9, R10, and R11 is either H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl, and R7 is C1˜C20 alkyl. 20. The colorant dispersing liquid of claim 19, wherein a weight ratio of the dispersing agent to the compound of formula (3) ranges from 99.99/0.01 to 60/40. 3. 21. The colorant dispersing liquid of claim 16, further comprising a compound with a general formula (4) formula (4) R12O—(A4)x—CH2COOM3 (4) wherein R12 is C1˜C20 alkyl, A4 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, x is an integer of 1˜12, and M3 is selected from the group consisting of H, Li, Na, K and N+R13 R14 R15 R16, wherein each of R13, R14, R15, and R16 is eitther H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl. 22. The colorant dispersing liquid of claim 21, wherein a weight ratio of the dispersing agent to the compound of formula (4) ranges from 99.99/0.01 to 60/40. 23. The colorant dispersing liquid of claim 16, wherein the colorant comprises Pigment Yellow 138. 24. The colorant dispersing liquid of claim 16, wherein the colorant comprises Pigment Red 122. 25. The colorant dispersing liquid of claim 16, wherein the colorant comprises Pigment Blue 15. 26. The colorant dispersing liquid of claim 16, wherein the colorant comprises carbon black. 27. The colorant dispersing liquid of claim 16, wherein a ratio of the colorant to the dispersing agent ranges from 1/15 to 1. 28. The colorant dispersing liquid of claim 16, wherein a mean grain size of the colorant ranges from 20 nm to 200 nm. 29. The colorant dispersing liquid of claim 16, wherein a concentration of the colorant ranges from 5 wt % to 30wt %. 30. An ink composition for ink jet, comprising the colorant dispersing liquid of any one of the claims 16˜29 and at least one additive selected from the group consisting of water, a water-soluble solvent, a surfactant and a preservative. 31. The ink composition of claim 30, wherein a mean grain size of the colorant ranges from 20 nm to 200 nm. 32. The ink composition of claim 30, wherein a concentration of the colorant ranges from 1 wt % to 8 wt %. 33. A method of forming a picture, comprising using an ink composition of any one of the claims 30˜32 to print a picture with an ink jet printer.
CROSS-REFERENCE TO RELATED APPLICATION [0001] This application claims the priority benefit of Japanese application serial no. 2001-052720, filed Feb. 27, 2001. BACKGROUND OF THE INVENTION [0002] 1. Field of Invention [0003] The present invention relates to a colorant dispersing liquid for printed matter having improved light stability, color visibility, discharge stability, liquid-phase stability and stability in colorant grain size, an ink composition for ink jet using the colorant dispersing liquid, and a method for forming a picture with the ink composition. [0004] 2. Description of Related Art [0005] The ink jet printing method has many advantages over other printing methods because it is simpler in process and can be configured easily for full-color printing, and allows the use of a simple apparatus to obtain a high resolution picture. The ink composition for ink jet can be a dye-system ink composition, which is usually fabricated by dissolving various water-soluble dyes in water or in a mixture of water and a water-soluble organic solvent, as described in the official gazettes of Japanese Patent Applications Laid Open No. Sho 63-51485, Sho 63-56575 and Hei 1-198671. The dye-system ink has improved color visibility but has poor light stability and poor water resistance for printed matters. [0006] On the other hand, the color-system ink with carbon black or various organic colorants dispersed therein is widely studied now since it has higher light stability and better water resistance over the dye-system ink, as described in the official gazettes of Japanese Patent Applications Laid Open No. Sho 57-10660, Sho 57-10661, Hei 2-255875 and Hei 2-276876, and in Japanese Patent Publication No. Hei 1-15542. The causes of high light stability and high water resistance of the color-system ink are explained as follows. [0007] When a color-system ink composition dries on a printed material, the colorant left as a coloring agent does not dissolve in water like a dye does and therefore will not effuse. [0008] On other hand, since the light reactivity of a colorant is lower than that of a dye, the light stability of a colorant is higher than that of a dye. [0009] The color-system ink is prepared by dispersing a mixture consisting of a colorant, a liquid medium and dispersing agents with a dispersing apparatus, such as a ball mill or a sand mill. However, the color-system ink easily causes a nozzle jam and to its detriment provides a narrower color gamut as compared with the dye-system ink. In order to prevent a nozzle jam and to broaden the color gamut, the colorant grains in the colorant dispersing liquid, used as a component of the ink for ink jet recording, usually have a size smaller than 200 nm, preferably smaller than 150 nm. This also ensures the visibility of the picture printed with the ink and the secondary color reproducibility and the transparency of the ink. Therefore, it is necessary to atomize the colorant grains in the colorant dispersing liquid and to promote the long-time stability in mean grain size. The atomization of the colorant grains needs to be finished in a short period in order to reduce the price for industrial production. [0010] Moreover, it is required that the colorant grain size in the colorant dispersing liquid be maintained even after a long period and/or under a high temperature or a low temperature, so as to prevent a nozzle jam of the printer. [0011] Moreover, in order to atomize the colorant particles in a short period and to reduce the variation of the colorant grain size after a long period, the colorant dispersing agent is preferably used together with some additives. [0012] Nevertheless, the ink compositions for ink jet currently used have the drawbacks of larger mean grain size, low stability in mean grain size and low discharge stability. Such ink compositions include those using styrene-acryl copolymer, styrene-maleic acid copolymer (Japanese Patent Applications Laid Open No. Sho56-147863) and naphthalenesulfonic acid/sodium formalin condensate (Japanese Patent Applications Laid Open No. Sho 61-083267) as polymer colorant dispersing agents, and using polyethylene glycol alkylphenyl ether (Japanese Patent Applications Laid Open No. Hei 5-105837), polyethylene glycol alkylphenyl ether sulfate (Japanese Patent Applications Laid Open No. Hei 10-168367) and polyethylene glycol alkylphenyl ether phosphate (Japanese Patent Applications Laid Open No. Hei 10-88050) as surfactants. SUMMARY OF THE INVENTION [0013] In view of the above-mentioned problems, this invention provides a colorant dispersing liquid and an ink composition for ink jet that has a small mean colorant grain size, high stability in mean grain size and high discharge stability. Meanwhile, the colorant grains can be atomized in a short period during the preparation of the colorant dispersing liquid and the size variation over a long time of the colorant grains in the colorant dispersing liquid or in the ink can be reduced. [0014] After studying the above-mentioned problems, the inventor provides an ink composition that contains a dispersing agent expressed by formula (1a) or (1b) below and preferably further contains specific additives including at least one of the compounds expressed by formulae (2), (3) and (4), respectively. [0015] wherein [0016] R1 is H, a C1˜C20 alkyl, allyl or aralkyl group, phenyl, substituted phenyl or naphthyl; [0017] k is an integer of 0˜7; [0018] A1 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene; [0019] A2 is oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, [0020] i, j≧0 and (i+j) range from 30 to 100; [0021] M1 is selected from the group consisting of H, Li, Na, K and N+R2 R3 R4 R5, wherein each of R2, R3, R4, and R5 is either H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl; [0022] p, q≧1 and (p+q)=3. [0023] The group R1 with a carbon number exceeding 20 will lower the dispersion stability and increase the viscosity of the colorant dispersing liquid. The value of (i+j) preferably ranges from 30 to 100, more preferably from 30 to 80. When (i+j) is larger than 100, the viscosity of the dispersing liquid or the ink increases and the stability in mean grain size becomes lower. In addition, p and q can be set as a combination of p=1 and q=2, or as another combination of p=2 and q=1. [0024] The formulae (2), (3) and (4) are as follows.
R6—(A3)m—OH (2) R12O—(A4)x—CH2COOM3 (4)
[0025] wherein [0026] In formula (2), R6 is C8˜C14 alkyl, A3 is oxyethylene, oxypropylene, or a blend of oxyethylene and oxypropylene, and m is an integer of 3˜16; [0027] In formula (3), M2 is selected from the group consisting of H, Li, Na, K and N+R8 R9 R10 R11, wherein each of R8, R9, R10, and R11 is either H, methyl, ethyl, 2-hydroxyethel, or 3-hydroxypropyl, and R7 is C1˜C20 alkyl; and [0028] In formula (4), R12 is C1˜C20 alkyl; A4 is oxyethylene, oxypropylene, or a blend of oxyethylene and oxypropylene; x is an integer of 1˜12; and M3 is selected from the group consisting of H, Li, Na, K and N+R13 R14 R16, wherein each of R13, R14, R15, and R16 is either H, methyl, ethyl, 2-hydroxyethyl or 3-hydroxypropyl. [0029] The group R6 in the compound of formula (2) is preferably a C8˜C14 alkyl group. When the carbon number is less than 7 or larger than 15, the stability in mean grain size is lowered. In addition, m is preferably an integer of 3˜16. When m is less than 2 or larger than 17, the stabilizing effect for the grain size becomes weaker. The group R7 in the compound of formula (3) is preferably a C1˜C20 alkyl group. When R7 is H or its carbon number exceeds 21, the stability in the mean grain size is lowered. Moreover, when the group R12 in the compound of formula (4) is H or its carbon number exceeds 21, the stabilizing effect for the colorant grain size in the colorant dispersing liquid becomes weaker. In addition, A4 is suitably oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, and x is preferably an integer from 1 to 12. When x is equal to 0 or is larger than 13, the stability in the mean grain size is lowered. [0030] This invention also provides a colorant dispersing liquid, which comprises at least a colorant, a dispersing agent and water, wherein the dispersing agent includes at least one compound with a general formula (1a) or (1b). [0031] The colorant dispersing liquid may further comprise at least one compound selected from the group consisting of compounds expressed by formulae (2), (3), and (4), respectively. The weight ratio of the dispersing agent to the compound of formula (2) ranges from 99.99/0.01 to 60/40. The weight ratio of the dispersing agent to the compound of formula (3) ranges from 99.99/0.01 to 60/40. The weight ratio of the dispersing agent to the compound of formula (4) also ranges from 99.99/0.01 to 60/40. [0032] The colorant in the colorant dispersing liquid may comprise Pigment Yellow 138 and/or Pigment Red 122. Besides, the colorant may comprise at least one colorant selected from the group consisting of Pigment Blue 15, Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3 and Pigment Blue 15:4. In addition, the colorant may comprise carbon black. [0033] Moreover, in the colorant dispersing liquid of this invention, the ratio of the colorant to the dispersing agent ranges from 1/15 to 1 and the mean grain size of the colorant ranges from 20 nm to 200 nm. In addition, the concentration of the colorant ranges from 5 wt % to 30 wt %. [0034] This invention further provides an ink composition for ink jet, which comprises the above-mentioned colorant dispersing liquid and at least one additive selected from the group consisting of water, a water-soluble solvent, a surfactant and a preservative. In the ink composition, the mean grain size of the colorant ranges from 20 nm to 200 nm and the concentration of the colorant ranges from 1 wt % to 8 wt %. [0035] This invention also provides a method for forming a picture, which comprises using the above-mentioned ink composition to print a picture with a piezo-type ink jet printer or a thermal-type ink jet printer. [0036] Some preferred embodiments of this invention will be described hereinafter. However, it is to be understood that both the foregoing general description and the following detailed description of the preferred embodiments of this invention are exemplary, and are intended to provide further explanation of the invention as claimed. DESCRIPTION OF THE PREFERRED EMBODIMENTS [0037] Composition of Colorant Dispersing Liquid/Ink [0038] In the preferred embodiments of this invention, the colorant dispersing liquid contains a colorant and a dispersing agent, which includes at least one compound with a general formula (1a) or (1b) mentioned above. The colorant dispersing liquid is suitably used in an ink composition for ink jet. The colorant dispersing liquid preferably further contains at least one additive selected from the groups consisting of the above-mentioned compounds expressed by formula (2), (3) and (4), respectively. By using the colorant dispersing agent of this invention, the colorant dispersing liquids of this invention can have small mean grain size and high stability in mean colorant grain size. Therefore, the ink compositions made from the colorant dispersing liquids of this invention have small mean grain size and high discharge stability. [0039] In the colorant dispersing liquid, the weight ratio of the compound of formula (1a) or (1b) to the compound of formula (2) preferably ranges from 99.99/0.01 to 60/40. When the ratio exceeds 99.99/0.01, the effect of adding the compound of formula (2) is barely seen and the stabilizing effect for the colorant grain size in the colorant dispersing liquid is little improved. When the ratio is less than 60/40, the stabilizing effect for the colorant grain size is also little improved. [0040] Moreover, in the colorant dispersing liquid, the weight ratio of the compound of formula (1a) or (1b) to the compound of formula (3) or formula (4) also preferably ranges from 99.99/0.01 to 60/40 for the same reasons mentioned above. [0041] The colorants used in the colorant dispersing liquid have no specific restriction, but the preferred examples of the colorants are listed below. [0042] As a black colorant, the colorant includes carbon black species, such as furnace black, lamp black, acetylene black and channel black; metal species, such as copper, iron and titanium oxide; and organic colorants, such as o-nitroaniline. [0043] As a yellow colorant, the colorant includes Pigment Yellow 1, Pigment Yellow 2, Pigment Yellow 3, Pigment Yellow 12, Pigment Yellow 13, Pigment Yellow 14, Pigment Yellow 16, Pigment Yellow 17, Pigment Yellow 73, Pigment Yellow 74, Pigment Yellow 75, Pigment Yellow 83, Pigment Yellow 93, Pigment Yellow 95, Pigment Yellow 97, Pigment Yellow 98, Pigment Yellow 114, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 129, Pigment Yellow 138, Pigment Yellow 150, Pigment Yellow 151, Pigment Yellow 154, Pigment Yellow 155 and Pigment Yellow 180, for example. [0044] As a magenta colorant, the colorant includes Pigment Red 5, Pigment Red 7, Pigment Red 12, Pigment Red 48(Ca), Pigment Red 48(Mn), Pigment Red 57(Ca), Pigment Red 57:1, Pigment Red 112, Pigment Red 122, Pigment Red 123, Pigment Red 168, Pigment Red 184, Pigment Red 202 and Pigment Violet 19, for example. [0045] As a cyan colorant, the colorant includes Pigment Blue 1, Pigment Blue 2, Pigment Blue 3, Pigment Blue 15, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Blue 16, Pigment Blue 22, Pigment Blue 60, Bat Blue 4 and Bat Blue 60, for example. Particularly, carbon black, Pigment Yellow 138, Pigment Red 122, and Pigment Blue 15 (or 15:3) are preferably used as the black colorant, the yellow colorant, the magenta colorant, and the cyan colorant, respectively, in order to obtain an ink composition having better color tone, higher light stability, higher dispersing stability and color tone reproducibility and capability of attaining a color balance. Particularly, Pigment Red 122 can be treated on the surface with colorant derivatives to acquire better dispersing stability and is therefore preferably used. [0046] Other colorants include toluidine red, permanent carmine FB, first yellow AAA, disazo orange PMP, lake red C, brilliant carmine 6B, phthalocyanine blue, quinacridon red, dioxane violet, Victoria Pure Blue, alkali blue toner, first yellow 10G, disazo yellow AAMX, disazo yellow AAOT, disazo yellow AAOA, yellow ferric oxide, disazo yellow HR, o-nitroaniline orange, dinitroaniline orange, Balkan Orange, toluidine red, chlorinated paranitraniline red, Brilliant First Scarlet Red, naphthol red 23, pyrazolone red, barium red 2B, barium-lithium red, Pigment Scarlet Red 3B lake, Lake Bordeaux 10B, anthosine 3B lake, anthosine 5B lake, rhodamine 6G lake, eosin lake, Indian Red, Fanatol Red FGR, rhodamine B lake, methylviolet lake, dioxazine violet, basic blue 5B lake, basic blue 6G lake, first scaw blue, alkali blue R toner, peacock blue lake, Prussian Blue, ultramarine blue, reflex blue 2G, reflex blue R, brilliant green lake, diamond green thioflavin lake, phthalocyanine green G, green gold, phthalocyanine green Y, ferric oxide powder, rust, zinc white, titanium oxide, calcium carbonate, clay, barium sulfate, alumina, alumina white, aluminium powder, bronze powder, daylight fluorescent color, pearl color, naphthol carmine FB, naphthol red M, permanent carmine FB, first yellow G, disazo yellow AAA, dioxane violet and alkali blue G toner. Still other colorants include processed colorants like grafting carbon, of which the surface is treated with a material such as a resin. In such situations, it is possible to mix more than two colorants. [0047] In the colorant dispersing liquid of the preferred embodiments, the ratio of the colorant to the dispersing agent preferably ranges from 1/15 to 1. If the ratio is less than 1/15, the storage stability of the dispersing liquid and the ink is poor, which easily causes a jam of the nozzle. If the ratio exceeds 1, the viscosity of the dispersing liquid or the ink is high and using the ink for ink jet is therefore difficult. [0048] The mean colorant grain size in the dispersing liquid or in the ink preferably ranges from 20 nm to 200 nm. If the mean grain size exceeds 200 nm, a nozzle jam easily occurs and the color visibility is poor. If the mean size is less than 20 nm, the colorant dispersion process is difficult, the cost is high and the storage stability and the light stability are poor. The mean grain size is measured by using Microtrack UPA manufactured by Nikkiso Co., Ltd. [0049] Moreover, the colorant concentration in the dispersing liquid preferably ranges from 5 wt % to 30 wt %. If the colorant concentration is less than 5 wt %, much dispersing liquid is needed to formulate the ink with a required colorant concentration and the productivity is therefore lowered. If the colorant concentration exceeds 30 wt %, the viscosity of the dispersing liquid is high and the colorant dispersion process becomes difficult. [0050] Except for water, the additives in the dispersing liquid includes water-soluble organic media, various non-ion, anion, cation or amphoteric surfactants and preservatives, for example. The water-soluble organic media includes, for example, C1˜C4 alcohols, amide compounds and ether. The C1˜C4 alcohol includes methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol and isobutyl alcohol. The amide compounds include dimethylformamide and dimethyl-acetamide. The ether includes tetrahydrofuran and dioxane. [0051] The water-soluble organic media further includes polyalkylene glycol, C2˜C6 alkylene glycol and triol. The polyalkylene glycol includes polyethylene glycol and polypropylene glycol. The C2˜C6 alkylene glycol includes ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1,2-propandiol, 1,2-butandiol, 1,3-butandiol, thiodiglycol and hexyleneglycol. The triol includes glycerol and 1,2,6-1,4-butandiol, hexantriol. [0052] The water-soluble organic media further includes ether compounds consisting of a polyol and a lower alkyl group, pyrrolidone derivatives, ketone compounds and alkanolamine. The ether compounds includes ethylene glycol monomethyl (or ethyl) ether, diethylene glycol methyl (or ethyl) ether, triethylene glycol monomethyl (or ethyl) and monoether/diether derivatives produced from the condensation reactions of the polyol and the alcohol mentioned above. The pyrrolidone derivatives include N-methylpyrrolidone and 2-pyrrolidone. The ketone compounds include acetone and methylethylketone. The alkanolamine includes monoethanolamine, diethanolamine and triethanolamine. Besides, the water-soluble organic media can be 1,3-dimethyl-2-imidaxolidinone. [0053] Among the water-soluble organic media mentioned above, the poly alcohol (e.g., diethylene glycol) and the ether consisting of a polyol and a lower alkyl group (e.g., triethylene glycol mono-methyl (or ethyl) ether) are preferably used. [0054] Furthermore, the colorant concentration in the ink preferably ranges from 1 wt % to 8 wt %. When the colorant concentration is less than 1 wt %, the visibility of the printed material is poor since the picture concentration is low. If the colorant concentration exceeds 8 wt %, the viscosity of the ink is high and a nozzle jam easily occurs. In addition, the additives in the ink are those used in the dispersing liquid, for example. Moreover, the amount of the water-soluble organic solvent in the ink preferably ranges from 0 to 50 wt %. [0055] Fabrication and Use of Colorant Dispersing Liquid/Ink [0056] To fabricate the colorant dispersing liquid, a colorant, a dispersing agent and a mixture of water and a water-soluble organic solvent are mixed by using a well-known dispersing apparatus, such as a sand mill, a ball mill, a dinomill, a roll mill, a nanomizer or a homogenizer, etc. Moreover, the ink is fabricated by stirring and mixing the colorant dispersing liquid, water, a water-soluble organic solvent and a surfactant, followed by removing large grains in the mixture with a filter or a centrifugal separation apparatus, and then degassing the mixture. [0057] The compounds of formulae (2), (3) and (4) that serve as the additives of the ink composition can be added together with the dispersing agent during the dispersing process of the colorant. However, it is also feasible to add them into the composition during formulation of the ink composition with the colorant dispersing liquid. [0058] The group R6 in the compound of formula (2) is preferably a C8˜C14 alkyl group. When the carbon number is less than 7 or larger than 15, the stability in mean grain size is lowered. In addition, m is preferably an integer of 3˜16. When m is less than 2 or larger than 17, the stabilizing effect for the grain size become weaker. [0059] The group R7 in the compound of formula (3) is preferably a C1˜C20 alkyl group. When R7 is H or it s carbon number exceeds 21, the stability in the mean grain size is lowered. [0060] Moreover, when the group R12 in the compound of formula (4) is H or its carbon number exceeds 21, the stabilizing effect for the colorant grain size in the colorant dispersing liquid becomes weaker. In addition, A4 is suitably oxyethylene, oxypropylene or a blend of oxyethylene and oxypropylene, and x is preferably an integer from 1 to 12. When x is equal to 0 or is larger than 13, the stability in the mean grain size is lowered. [0061] The printing method using the ink includes continuous jet-type printing and on-demand-type printing, for example. The on-demand-type printing method includes piezo method, thermal ink jet method, bubble jet method, and electrostatic method, for example. [0062] The following embodiments and examples are provided to further demonstrate the effects of this invention in detail, but not to restrict the scope of this invention. In the examples, the amounts of the components are all expressed by parts in weight. [0063] First Embodiment [0064] For the examples in the first embodiment of this invention, the colorant dispersing agent is the compound of formula (1a) mentioned above. EXAMPLE 1 [0065] In this case, a colorant dispersing liquid (A) is prepared using the formula 1, of which the components are listed below. Formula 1 Pigment Red 122 30 parts (Toner Magenta E02 produced by Clariant International Ltd.) Compound of formula (1a) 15 parts (k = 0, i = 40, j = 0, A1 = oxyethylene, M1 = K, p = 1 and q = 2) heptaethylene glycol mono (5-tridecyl) ether [Compound of formula (2) with R6 being a C10 branched 0.2 part alkyl group, A3 being oxyethylene, and m = 7] distilled water 155 parts [0066] All of the components are premixed and then loaded into a vessel of 1 liter. Subsequently, zirconia beads with a diameter of 0.3 mm are loaded into the vessel with an amount of 900 g. A batch-type desktop sand mill manufactured by Kanpe Hapio Corporation is used to disperse the mixture for 48 hours to obtain the colorant dispersing liquid (A). EXAMPLE 2 [0067] A colorant dispersing liquid (B) is obtained in this example with the same method as described in Example 1 except that the formula 2 described below is used to replace the formula 1. Formula 2 Pigment Blue 15:3 30 parts (LIONOL BLUE FG-7351 by TOYO INK MFG. CO., LTD.) Compound of formula (1) (R1 = CH(CH3)2, k = 1, i = 80, 15 parts j = 0, A1 = oxyethylene, M1 = NH4, p = 1, q = 2) sodium dioctylsulfosuccinate (Compound of formula (3) 0.2 part with M2 = Na and R7 = a C8 branched alkyl group) distilled water 155 parts EXAMPLE 3 [0068] A colorant dispersing liquid (C) is obtained in this example with the same method as described in Example 1 except that the formula 3 described below is used to replace the formula 1. Formula 3 Pigment Yellow 138 30 parts (LIONOGEN YELLOW 1010 by TOYO INK MFG. CO., LTD.) compound of formula (1) (k = 0, i = 12, j = 48, 15 parts A1 = oxypropylene, A2 = oxyethylene, M1 = Na, p = 1 and q = 2) sodium polyoxyethylene (3) alkyl (C13) ether acetate 0.2 part (Compound of formula (4) with R12 being a C13 normal alkyl group, A4 being oxyethylene, x = 3 and M3 being Na) distilled water 155 parts EXAMPLE 4 [0069] A colorant dispersing liquid (D) is obtained in this example with the same method as described in Example 1 except that the formula 4 described below is used to replace the formula 1. Formula 4 Pigment Yellow 138 30 parts (LIONOGEN YELLOW 1010 by TOYO INK MFG. CO., LTD.) Compound of formula (1) 15 parts (k = 0, i = 70, j = 0, A1 = oxyethylene, M1 = K, p = 1, q = 2) distilled water 155 parts EXAMPLE 5 [0070] A colorant dispersing liquid (E) is obtained in this example with the same method as described in Example 1 except that Pigment Red 122 takes 15 parts and the distilled water takes 170 parts. EXAMPLE 6 [0071] A colorant dispersing liquid (F) is obtained in this example with the same method as described in Example 1 except that Pigment Red 122 takes 50 parts, the compound of formula (1) takes 12 parts and the distilled water takes 138 parts. Comparative Example 1 [0072] A colorant dispersing liquid (G) is obtained in this example with the same method as described in Example 1 except that the formula 5 described below is used to replace the formula 1. Formula 5 Pigment red 122 30 parts (Toner Magenta E02 by Clariant International Ltd.) polyvinylpyrrolidone (mean molecular weight = 25000) 15 parts sodium polyoxyethylene (3) alkyl (C13) ether acetate 0.2 part (Compound of formula (4) with R12 being a C13 normal alkyl group, A4 being oxyethylene, x = 3 and M3 being Na) distilled water 155 parts Comparative Example 2 [0073] A colorant dispersing liquid (H) is obtained in this example with the same method as described in Example 1 except that the formula 6 described below is used to replace the formula 1. Formula 6 Pigment Red 122 30 parts (Toner Magenta E02 by Clariant International Ltd.) polyoxyethylene alkyl ether phosphate ester 15 parts (PLYSURF A219B by Dai-ichi Kogyo Seiyaku Co., Ltd.) distilled water 155 parts Comparative Example 3 [0074] A colorant dispersing liquid (I) is obtained in this example with the same method as described in Example 1 except that the formula 7 described below is used to replace the formula 1. Formula 7 Pigment red 122 30 parts (Toner Magenta E02 by Clariant International Ltd.) Compound of formula (1) 15 parts (k = 0, i = 20, j = 0, A1 = oxyethylene, M1 = Na, p = 1, q = 2) Pionin A-51-B (by Takemoto Oil & Fat Co., Ltd.) 0.2 part distilled water 155 parts Comparative Example 4 [0075] A colorant dispersing liquid (J) is obtained in this example with the same method as described in Example 1 except that the formula 8 described below is used to replace the formula 1. Formula 8 Pigment Red 122 30 parts (Toner Magenta E02 by Clariant International Ltd.) Compound of formula (1) 15 parts (k = 0, i = 130, j = 0, A1 = oxyethylene, M1 = NH4, p = 1, q = 2) Pionin A-51-B (by Takemoto Oil & Fat Co., Ltd.) 0.2 part distilled water 155 parts [0076] The dispersing liquids (A)˜(J) are then used to formulate ink compositions (a)˜(j), respectively, with an ink formula 1 described below. The mixture is stirred for 30 min and then filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum. The samples that cannot be filtered are directly measured without filtration. Ink Formula 1 Colorant dispersing liquid 40 parts Glycerol 7.50 parts Diethyleneglycol 22.50 parts 2-pyrrolidone 3.00 parts sodium polyoxyethylene (3) alkyl (C13) ether acetate 0.45 part distilled water 76.55 parts [0077] The colorant dispersing liquid (A)˜(J) and the ink compositions (a)˜(j) are measured for their mean grain sizes. Being aged for seven days under 70� C., the ink compositions (a)˜(j) are measured again for their mean grain sizes and are used for ink-jet printing with EPSON Ink Jet Printer MJ-930C (piezo-type) and HP Ink Jet Printer DeskJet 880C (thermal-type), whereby the discharge stability is evaluated. The results are listed in Table 1 and Table 2. TABLE 1 Colorant Dispersing Mean Grain size Mean Grain size Liquid (before aging, nm) (after aging, nm) (A) 140.6 146.1 (B) 109.2 111.3 (C) 90.9 89.7 (D) 124.8 129.6 (E) 115.6 117.3 (F) 145.3 149.7 (G) 220.5 270.3 (H) 223.1 245.4 (I) 210.6 230.2 (J) 270.7 265.3 [0078] TABLE 2 Mean Grain size Discharge Discharge (before Mean Grain size Stability Stability Ink aging, nm) (after aging, nm) (MJ-930C) (DeskJet 880C) (a) 142.8 143.3 O O (b) 107.6 108.0 O O (c) 86.1 84.7 O O (d) 125.2 128.8 O O (e) 118.4 120.5 O O (f) 145.6 150.9 O O (g) 225.8 266.0 X X (h) 222.1 262.3 X X (i) 205.6 248.4 X X (j) 261.2 270.8 X X [0079] As that shown in Table 1 & 2, the colorant dispersing liquids and the ink compositions made from the colorant dispersing liquids of this invention have small mean colorant grain sizes, higher stability in mean colorant grain size and higher discharge stability. Moreover, by using the ink compositions of this invention the color tone of the printout is good. [0080] Second Embodiment [0081] In this embodiment, the colorant dispersing agent is the compound of formula (1b′) shown below, which is a specific form of the compound of formula (1b) with A1=A2=oxyethylene and (i+j)=n (30≦n≦100). [0082] The compound of formula (1b′) includes: EXAMPLE 7 [0083] In this example, a colorant dispersing liquid (A) is prepared from a mixture (A), of which the components are listed below. Mixture (A) Pigment Red 122 24 parts (Toner Magenta E02 by Clariant International Ltd.) 10 wt % aqueous solution of POE (n = 40) β-naphthol ether 120 parts (dispersing agent of formula (lb′)) ion-exchanged water 16 parts [0084] The mixture (A) is loaded into a beaker of 500 ml and then stirred for 3 hours with a Teflon-coated stirrer. [0085] The mixture (A) having been stirred is loaded into a sand mill (batch-type desktop sand mill manufactured by Kanpe Hapio Corporation) and then lots of zirconia beads with a diameter of 0.3 mm are used to disperse the mixture (A) for 48 hours to obtain the colorant dispersing liquid (A) with a mean grain size of 120.5 nm (measured by using Microtrack UPA150 manufactured by Nikkiso Co., Ltd.) [0086] The colorant dispersing liquid (A) obtained is then use to formulate an ink composition for ink jet with a formula (a) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain ink composition (a) for ink jet. Ink Formula (a) Colorant dispersing liquid (A) 40 parts Glycerol 7.50 parts Diethyleneglycol 22.50 parts 2-pyrrolidone 3.00 parts sodium polyoxyethylene (3) alkyl (C13) ether acetate 1.45 part (Compound of formula (4) with M2 being Na, R12 being a C13 normal alkyl group and x = 3) ion-exchanged water 75.55 parts [0087] The ink composition (a) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean grain size of the ink is measured to be 121.1 nm. EXAMPLE 8 [0088] In this example, a colorant dispersing liquid (B) is prepared from a mixture (B), of which the components are listed below. Mixture (B) Pigment Red 122 (FASTOGEN SUPER MAGENTA RG 24 parts by DAINIPPON INK AND CHEMICALS, INCORPORATED) 10 wt % aqueous solution of POE (n = 40) β-naphthol ether 120 parts (dispersing agent of formula (lb′) heptaethylene glycol mono (5-decyl) ether (compound of 0.2 part formula (2) with R6 being a C10 normal alkyl group, A3 being oxyethylene and n = 7) ion-exchanged water 15.8 pats [0089] The mixture (B) is dispersed with the same method as described in Example 7, and the mean grain size is measured to be 118.7 nm. The colorant dispersing liquid (B) obtained is then use to formulate an ink composition for ink jet with an ink formula (b) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain an ink composition (b) for ink jet. Ink Formula (b) Colorant dispersing liquid (B) 40 parts Glycerol 7.50 parts Diethyleneglycol 22.50 parts 2-pyrrolidone 3.00 parts ion-exchanged water 77 parts [0090] The ink composition (b) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean grain size of the ink is measured to be 119.1 nm. EXAMPLE 9 [0091] In this example, the colorant dispersing liquid (A) is use to formulate an ink composition for ink jet with an ink formula (c) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain an ink composition (c) for ink jet. Ink Formula (c) Colorant dispersing liquid (A) 40 parts Glycerol 7.50 parts Diethyleneglycol 22.50 parts 2-pyrrolidone 3.00 parts sodium dioctylsulfosuccinate (compound of formula (3) 0.5 part with M2 being Na and R7 being a C8 normal alkyl group) ion-exchanged water 75.55 parts [0092] The ink composition (c) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean grain size of the ink composition (c) is measured to be 120.7 nm. EXAMPLE 10 [0093] In this example, a colorant dispersing liquid (C) is prepared from a mixture (C), of which the components are listed below. Mixture (C) Pigment Yellow 138 (LIONOGEN YELLOW 1010 by 24 parts TOYO INK MFG. CO., LTD.) 10 wt % aqueous solution of POE (n = 40) α-naphthol ether 120 parts (dispersing agent of formula No. 2) ion-exchanged water 16 parts [0094] The mixture (C) is dispersed with the same method as described in Example 7, and the mean grain size is measured to be 70.2 nm. [0095] The colorant dispersing liquid (C) obtained is then used to formulate an ink composition for ink jet with the ink formula (d) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain an ink composition (d) for ink jet. Ink Formula (d) Colorant dispersing liquid (C) 40.0 parts Glycerol 7.5 parts Diethyleneglycol 22.5 parts 2-pyrrolidone 3.0 parts ion-exchanged water 77.0 parts [0096] The ink composition (d) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean grain size of the ink (d) is measured to be 71.6 nm. EXAMPLE 11 [0097] In this example, the colorant dispersing liquid (A) is use to formulate an ink composition for ink jet with the ink formula (e) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain an ink composition (e) for ink jet. Ink Formula (e) Colorant dispersing liquid (A) 40.0 parts Glycerol 7.5 parts Diethyleneglycol 22.5 parts 2-pyrrolidone 3.0 parts ion-exchanged water 77.0 parts [0098] The ink composition (e) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean grain size of the ink (e) is measured to be 145.6 nm. EXAMPLE 12 [0099] In this example, a colorant dispersing liquid (D) is prepared from a mixture (D), of which the components are listed below. Mixture (D) Pigment Blue 15:3 (LIONOL BLUE FG-7351 by TOYO INK 24 parts MFG. CO., LTD.) 10 wt % aqueous solution of POE (n = 40) β-naphthol ether 120 parts (dispersing agent of formula No. 1) ion-exchanged water 16 parts [0100] The mixture (D) is dispersed with the same method as described in Example 7, and the mean grain size is measured to be 97.1 nm. The colorant dispersing liquid (D) obtained is then use to formulate an ink composition (f) for ink jet with the ink formula (f) described below. After being stirred for 30 minutes, the mixture is filtered with a membrane filter having a pore size of 0.8 μm and then degassed in vacuum to obtain the ink composition (f) for ink jet. Ink Formula (f) Colorant dispersing liquid (D) 40.0 parts Glycerol 7.5 parts Diethyleneglycol 22.5 parts 2-pyrrolidone 3.0 parts ion-exchanged water 77.0 parts [0101] The ink composition (f) for ink jet is placed in an airtight polymer container and then aged for 1 week under 70� C. Thereafter, the mean particle size of the ink is measured to be 96.7 nm. Comparative Example 5 [0102] In this example, a colorant dispersing liquid (E) is prepared from a mixture (E), of which the components are listed below. Mixture (E) Pigment Red 122 (Toner Magenta E02 by Clariant 24 parts International Ltd.) 10 wt % aqueous solution of styrene-acrylic acid copolymer 120 parts (JONCRYL HDP71 aqueous solution by Johnson Polymer Co.) ion-exchanged water 16 parts [0103] The mixture (E) is dispersed with the same method as in Example 7, and the mean grain size is measured to be 210.8 nm. [0104] As shown by Examples 1˜12 and Comparative Example 1˜5, the colorant dispersing liquids and the ink compositions made from the colorant dispersing liquids of this invention both have small mean grain sizes and high stability in mean colorant grain size. Therefore, the reliability of the ink for ink jet of this invention is high and there is no need to worry about a jam of the ink jet head. [0105] It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the present invention covers modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents. Patent CitationsCited PatentFiling datePublication dateApplicantTitleUS2151733May 4, 1936Mar 28, 1939American Box Board CoContainerCH283612A * Title not availableFR1392029A * Title not availableFR2166276A1 * Title not availableGB533718A Title not available* Cited by examinerReferenced byCiting PatentFiling datePublication dateApplicantTitleUS6786959 *Apr 18, 2003Sep 7, 2004Ricoh Company LimitedPigment dispersion, method for preparing the pigment dispersion, inkjet ink using the pigment dispersion, method for preparing the inkjet ink, ink cartridge containing the inkjet ink, image forming method and apparatus using the inkjet ink, and print image produced by the image forming method and apparatusUS6814792 *Jun 19, 2002Nov 9, 2004Ricoh Company, Ltd.Pigment dispersion, inkjet ink composition using the pigment dispersion, method of manufacturing the inkjet ink composition and image forming method using the inkjet ink compositionUS7815301 *Mar 15, 2006Oct 19, 2010Ricoh Company, Ltd.Water-based pigment dispersion, production method thereof, water-based pigment ink, production method thereof, ink record, inkjet recording apparatus, and inkjet recording methodEP2272924A1 *Apr 22, 2009Jan 12, 2011Kao CorporationAqueous ink for inkjet recording* Cited by examinerClassifications U.S. Classification106/503, 106/31.58, 106/31.86International ClassificationC09D11/322, C09D11/326, C09D11/38, C09D11/00, C09D17/00, B41M5/00, C09B67/20, B41J2/01Cooperative ClassificationC09D11/326European ClassificationC09D11/326Legal EventsDateCodeEventDescriptionDec 5, 2003ASAssignmentAug 17, 2007FPAYFee paymentYear of fee payment: 4Sep 2, 2011FPAYFee paymentYear of fee payment: 8RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services