Source: https://patents.google.com/patent/JP4167521B2/en
Timestamp: 2019-11-15 01:43:54
Document Index: 392336482

Matched Legal Cases: ['arts 23', 'art 24', 'art 40', 'art 50', 'art 40', 'art 23']

JP4167521B2 - Gas storage tank and manufacturing method thereof - Google Patents
Gas storage tank and manufacturing method thereof Download PDF
JP4167521B2
JP4167521B2 JP2003081706A JP2003081706A JP4167521B2 JP 4167521 B2 JP4167521 B2 JP 4167521B2 JP 2003081706 A JP2003081706 A JP 2003081706A JP 2003081706 A JP2003081706 A JP 2003081706A JP 4167521 B2 JP4167521 B2 JP 4167521B2
JP2003081706A
JP2004286178A (en
丈裕 仁藤
大五郎 森
嘉宏 磯貝
誠 都築
2003-03-25 Application filed by トヨタ自動車株式会社, 株式会社豊田自動織機 filed Critical トヨタ自動車株式会社
2003-03-25 Priority to JP2003081706A priority Critical patent/JP4167521B2/en
2004-03-22 Priority claimed from KR20040019235A external-priority patent/KR100620303B1/en
2004-10-14 Publication of JP2004286178A publication Critical patent/JP2004286178A/en
2008-10-15 Publication of JP4167521B2 publication Critical patent/JP4167521B2/en
The present invention relates to a gas storage tank for storing gas.
Conventionally, various gas storage tanks for storing gas have been proposed. As one of the methods for storing gas, a method for storing and adsorbing gas in a predetermined storage / adsorption material is known. For example, Patent Document 1 discloses a hydrogen storage alloy improved so that more hydrogen can be stored, and a hydrogen storage tank including a hydrogen storage alloy inside.
Japanese Patent Laid-Open No. 2002-53926 [0004]
In the case of using a gas storage tank equipped with an occlusion / adsorption material, the operation of occluding and adsorbing gas can be promoted by increasing the gas supply pressure to the gas storage tank. In addition to increasing the gas supply pressure to the gas storage tank, the storage / adsorption material absorbs / adsorbs gas, and in the space formed in the gas storage tank, more gas is compressed as gas. It can be stored. When the pressure in the gas storage tank is increased as described above, it is necessary to further increase the strength of the gas storage tank. However, sufficient investigation has not been made on the configuration of a gas storage tank that is filled with a gas storage / adsorption material and can store a higher-pressure gas.
The present invention has been made to solve the above-described conventional problems, and an object of the present invention is to provide a gas storage tank that has a gas storage / adsorption material and can store a higher-pressure gas.
To achieve the above object, the first gas storage tank of the present invention is a gas storage tank for storing gas,
A tank container having at least one opening formed therein;
A storage unit stored in the tank container;
The storage unit is disposed between the tank container and the storage unit, and the storage unit is disposed in the tank container so that an entire space formed between the tank container and the storage unit communicates with the opening. The gist of the present invention is to provide a supporting portion to support.
With such a configuration, since the entire space formed between the tank container and the storage portion communicates with at least one opening formed in the tank container, water can be easily poured into the tank container. It becomes possible to circulate, and when the heat treatment with water cooling is performed on the tank container, the tank container can be cooled sufficiently rapidly. And the intensity | strength of a gas storage tank can be improved by performing the heat processing accompanying such water cooling to a tank container.
In the first gas storage tank of the present invention, the storage portion may be filled with a storage / adsorption material that stores and / or adsorbs the gas. With such a configuration, when manufacturing a gas storage tank having a storage portion filled with a storage / adsorption material, heat treatment with water cooling for improving the strength of the tank container can be performed satisfactorily. It becomes.
The second gas storage tank of the present invention is a gas storage tank for storing gas,
A filling portion filled with an occlusion / adsorption material that occludes and / or adsorbs the gas;
A tank container in which the filling portion is housed and an opening is formed in at least one of longitudinal end portions;
It is formed by a plurality of thin plates disposed substantially parallel to the longitudinal direction of the tank container, and is in contact with the tank container on one of the longitudinal end surfaces of the thin plate, and in contact with the filling portion on the other of the longitudinal end surfaces. A gist of the present invention is to provide a support portion that supports the filling portion in the tank container while forming a space communicating with the opening between the tank container and the filling portion.
With such a configuration, the space formed in the tank container is formed by a thin plate disposed substantially parallel to the longitudinal direction, so that the tank container can be opened from the opening provided at the longitudinal end of the tank container. When water is introduced into the interior, the introduced water is guided to the thin plate and can quickly pass through the space. Therefore, when performing heat treatment with water cooling on the tank container, the tank container can be cooled sufficiently rapidly. And the intensity | strength of a gas storage tank can be improved by performing the heat processing accompanying such water cooling to a tank container. Each of the plurality of thin plates does not have to be formed separately from each other, and one thin plate may be folded into, for example, a corrugated shape as long as it has the above shape as a whole.
In the first or second gas storage tank of the present invention,
The said tank container is good also as having an aperture | diaphragm | squeeze part where the area of a cross section becomes smaller near the opening part formed in an edge part.
With such a configuration, it is easy to secure the air tightness of the tank while withstanding the pressure of the gas stored inside by providing the throttle part and sufficiently reducing the size of the opening of the tank container. Become. And in order to set it as such a structure, when storing a filling part in a tank container, after performing a drawing process etc. to a tank container and forming a squeezing part, when performing heat treatment with water cooling after that, By providing the support portion, it is possible to efficiently perform water cooling while preventing the filling portion from obstructing the flow of water.
The tank container preferably has a configuration in which two openings are formed at opposing positions.
With such a configuration, when the tank container is water-cooled, water introduced into the tank container from one opening is quickly discharged from the other opening. Can be done more quickly.
The tank container is formed in a substantially cylindrical shape,
The support portion may be formed by a thin plate disposed substantially parallel to the cylindrical axial direction.
By setting it as such a shape, it can be set as the gas storage tank suitable for storing a higher pressure gas. In addition, by forming the support portion with a thin plate substantially parallel to the axial direction, the total area of the support portion is reduced in the cross section of the gas storage tank, and a sufficiently wide water flow path can be secured during water cooling.
The gas storage tank is a tank for storing hydrogen,
The storage / adsorption material includes at least a hydrogen storage alloy,
The tank container may be formed of a metal containing aluminum.
Aluminum has excellent thermal conductivity and is lightweight, and even when high-pressure hydrogen is stored inside an aluminum (aluminum alloy) container, hydrogen molecules do not leak to the outside and constitute a hydrogen storage tank. Excellent material for tank containers. And when forming a tank container with such a metal containing aluminum, the fatigue strength of a tank container can be improved by performing the heat processing accompanying water cooling.
In the first or second gas storage tank of the present invention, the support portion may be made of metal.
By forming the support part from metal, the heat transfer between the filling part and the tank container can be improved. Thereby, the heat generated in the hydrogen storage alloy at the time of hydrogen filling can be transmitted from the filling portion to the tank container, and absorbed by the tank container and the member capable of transmitting heat from the tank container, or released to the outside. As described above, the heat generated in the hydrogen storage alloy during hydrogen filling can be efficiently processed, so that the amount of hydrogen stored in the gas storage tank can be increased or the hydrogen storage operation can be performed more quickly. It becomes possible. In addition, since the heat generated in the hydrogen storage alloy during hydrogen filling can be efficiently processed, the refrigerant flow path provided in the filling portion for discharging the heat can be reduced in size or made unnecessary.
In addition, this invention is realizable with various forms other than the above, for example, it is realizable with forms, such as a manufacturing method of a gas storage tank.
A. Structure of the hydrogen storage tank 10:
B. Manufacturing process of the hydrogen storage tank 10:
C. Operation of hydrogen storage and release:
FIG. 1 is an explanatory diagram showing an outline of the configuration of a hydrogen storage tank 10 which is a preferred embodiment of the present invention, and FIG. 2 is an explanatory diagram showing a state of a section 2-2 in FIG. The hydrogen storage tank 10 includes a tank container 20, a heat exchanger 30 accommodated in the tank container 20, and a support portion 40 disposed between the heat exchanger 30 in the tank container 20. Yes.
The tank container 20 is a hollow container formed in a substantially cylindrical shape. In this embodiment, the tank container 20 is formed of an aluminum alloy. Both ends of the tank container 20 are opened as connection ports 21 and 22, respectively, and the cross section of the vicinity of the connection ports 21 and 22 is compared to the middle cross section of the tank container 20. It is formed to be a smaller, substantially circular shape.
Connection portions 23 and 24 are fitted in these connection ports 21 and 22, respectively. The connection parts 23 and 24 are structures for ensuring the airtightness of the tank container 20 at the connection ports 21 and 22, thereby preventing hydrogen gas stored in the tank container 20 from leaking to the outside. . Further, in the connection portion 23, a hydrogen supply / discharge port 23 a for supplying and discharging hydrogen gas to and from the tank container 20 is provided open to the outside.
The heat exchanger 30 includes a heat exchanger case 34 that is a substantially cylindrical container having a smaller cross section than the tank container 20, and a hydrogen storage alloy filled in the heat exchanger case 34. Further, three sets of refrigerant flow paths 35 are provided so as to penetrate the inside of the heat exchanger 30 in the longitudinal direction so that heat exchange is possible between the filled hydrogen storage alloy and a predetermined refrigerant. . All of the three sets of refrigerant flow paths 35 have a U-shape. In each of these U-shaped refrigerant flow paths 35, both end portions extend from the inside of the tank container 20 to the outside via connection portions 24 fitted into the connection ports 22. Each refrigerant channel 35 protrudes from the heat exchanger case 34 at the end on the connection port 21 side, and forms a U-turn structure outside the heat exchanger case 34. Thus, when the refrigerant is supplied to each refrigerant channel 35, the refrigerant is introduced into the refrigerant channel 35 from one of the end portions that extend to the outside at the connection portion 24, and the inside of the refrigerant channel 35. In the longitudinal direction of the heat exchanger 30. In this way, the refrigerant guided in the refrigerant flow path 35 reverses the direction of flow in the U-turn structure provided so as to protrude from the heat exchanger case 34, and is directly guided toward the connection portion 24 side to be connected. In the part 24, it discharges | emits out of the hydrogen storage tank 10 from the other edge part extended outside.
A support 40 is disposed between the tank container 20 and the heat exchanger 30 so as to surround the outer periphery of the heat exchanger 30. The support portion 40 has a corrugated shape in which a thin plate of a metal material such as an aluminum alloy, stainless steel, or a clad material including these is folded in a staggered direction at a predetermined interval (see FIG. 2). By having such a structure, the support portion 40 holds the heat exchanger 30 in the tank container 20 while absorbing expansion / contraction in the heat exchanger 30 accompanying temperature increase / decrease. That is, since the whole support part 40 functions as an elastic body by being formed in the waveform shape as described above, the heat exchanger 30 can be held by the generated pressure. Further, the support portion 40 has a function of ensuring heat transfer between the heat exchanger 30 and the wall surface of the tank container 20. The heat exchanger 30 may be held in the tank container 20 by joining the support portion 40 to the tank container 20 and the heat exchanger 30 to improve such heat transfer.
In addition, by forming the support portion 40 in a corrugated shape as described above, a holding space 32 that is a space penetrating in the longitudinal direction of the tank container 20 is provided between the inner wall surface of the tank container 20 and the heat exchanger 30. Are formed (see FIG. 2). In addition, an end space 33 that is a space not through the support portion 40 is formed between the inner wall surface of the tank container 20 and the heat exchanger 30 and in the vicinity of both ends in the longitudinal direction of the tank container 20. (See FIG. 1). The hydrogen supplied to the hydrogen storage tank 10 is stored in the hydrogen storage alloy filled in the heat exchanger 30 and also compressed hydrogen in the space between the hydrogen storage alloy powder, the holding space 32 and the end space 33. Stored as. Further, as will be described later, when the hydrogen storage tank 10 is manufactured, the tank container 20 is subjected to heat treatment with water cooling, and the plurality of holding spaces 32 serve as water passages during the water cooling. .
Further, a reinforcing layer 26 is provided on the outer periphery of the tank container 20. The reinforcing layer 26 is for improving the strength of the tank container 20 that stores high-pressure hydrogen therein, and is formed of carbon fiber reinforced plastic (CFRP).
FIG. 3 is a process diagram illustrating a method for manufacturing the hydrogen storage tank 10. 4 and 5 are explanatory diagrams showing the state of main processes when manufacturing the hydrogen storage tank 10.
When manufacturing the hydrogen storage tank 10, first, the heat exchanger case 34, which is a hollow cylindrical container, is prepared (step S100). Then, three sets of refrigerant flow paths 35 are assembled to the heat exchanger case 34 (step S110, FIG. 4A). To assemble, a hole through which the refrigerant flow path 35 penetrates is made in advance in the heat exchanger case 34, and both ends of the U-shaped refrigerant flow path 35 are inserted from the outside of one end of the heat exchanger case 34. The refrigerant channel 35 may be penetrated into the heat exchanger case 34 so as to protrude from the other end. The refrigerant flow path 35 penetrating the heat exchanger case 34 may be fixed to the heat exchanger case 34 by welding, thereby closing the gap between the refrigerant flow path 35 and the heat exchanger case 34. In step S110, the refrigerant flow path 35 protruding from the other end of the heat exchanger case 34 is further bent, and the six refrigerant flow paths 35 protruding from the other end are The heat exchanger case 34 is bundled from the central axis (see FIG. 4A). In the heat exchanger case 34, the central portion of the surface (cylindrical bottom surface) on the side where the U-shaped bent portion of the heat exchanger case 34 protrudes is preliminarily filled with a hydrogen storage alloy. A hole 31 is formed. In FIG. 4A, the position where the hole 31 is provided is indicated by an arrow.
Next, a substantially columnar outer wall portion 50 having both ends opened for forming the tank container 20 and a corrugated plate member 52 for forming the support portion 40 are prepared (step S120). FIG. 4B shows the appearance of the outer wall portion 50, and FIG. 4C shows the appearance of the corrugated plate material 52. And the heat exchanger case 34 which assembled | attached the refrigerant | coolant flow path 35 and the corrugated board | plate material 52 are accommodated in the prepared outer wall part 50 (step S130). At this time, the corrugated plate member 52 is disposed between the outer wall portion 50 and the heat exchanger case 34 so that both end portions of the outer wall portion 50 communicate with each other and a plurality of substantially parallel spaces are formed. To do. Thus, the support part 40 is formed by the corrugated plate material 52 by disposing the corrugated plate material 52 between the heat exchanger case 34 and the outer wall portion 50 (FIG. 5A).
Next, drawing processing (mouth drawing processing) is performed on both ends of the outer wall portion 50 (step S140). That is, the outer wall portion 50 is processed to form the tank container 20 so that the opening portions at both ends of the outer wall portion 50 become the connection ports 21 and 22 which are smaller opening portions (FIG. 5B). At this time, the opening on the side where the end of the refrigerant flow path 35 protrudes to the outside becomes the connection port 22, and the opening on the opposite side becomes the connection port 21.
Thereafter, heat treatment is performed on the tank container 20 (step S150). This heat treatment is a treatment for improving the fatigue strength of the aluminum alloy constituting the tank container 20. In the hydrogen storage tank 10, the constituent members expand and contract as the temperature rises and falls, and the internal pressure rises and falls as the hydrogen is charged and discharged. With such expansion / contraction of the constituent members and increase / decrease in internal pressure, the shape of the tank container 20 is distorted at a predetermined rate. By repeatedly generating such strain, the aluminum alloy constituting the tank container 20 gradually causes metal fatigue. The heat treatment enhances resistance to fatigue, and in this example, the well-known T6 treatment applied to the aluminum alloy was performed. In this heat treatment, for example, the aluminum alloy is solidified by heating to 515 to 550 ° C., and then rapidly cooled by water cooling. In the case of water cooling, the holding space 32 formed inside the tank container 20, that is, between the inner wall surface of the tank container 20 and the heat exchanger case 34 is also provided so that the cooling can be performed sufficiently rapidly. Cool through water.
After the heat treatment, the heat exchanger case 34 is filled with hydrogen storage alloy powder (step S160). The operation in step S160 is performed by introducing a hydrogen storage alloy into the heat exchanger case 34 through the hole 31 provided in the heat exchanger case 34 through the connection port 21 of the tank container 20 (FIG. 5B ) See the arrow in the middle). And the hole 31 is closed and the heat exchanger 30 is completed in the tank container 20 (step S170). When the hole 31 is closed in step S170, a gas permeable porous member 37 formed of sintered metal is fitted into the hole 31 (see FIG. 5B). As such a porous member 37, a member capable of holding the hydrogen storage alloy filled in the heat exchanger 30 without substantially entering the inside is used. Thereby, the hydrogen storage alloy filled in the heat exchanger 30 can be prevented from spilling to the outside. The hole 31 in which the porous member 37 is fitted serves as a passage for hydrogen when the hydrogen storage alloy in the heat exchanger 30 stores hydrogen in the hydrogen storage tank 10 or when hydrogen is taken out from the hydrogen storage alloy. work.
Thereafter, the connection portion 23 is attached to the connection port 21, and the connection portion 24 is attached to the connection port 22 (step S180). In this embodiment, the connection portion 23 includes a pressure reducing valve together with an electromagnetic valve that is an on-off valve. ing. Then, by introducing high-pressure hydrogen gas into the hydrogen supply / discharge port 23a, hydrogen can be stored in the hydrogen storage tank 10, and hydrogen depressurized by the pressure reducing valve is supplied from the hydrogen storage tank 10 to the hydrogen supply tank 23a. It is possible to discharge through the discharge port 23a. In addition, the connection portion 24 is held so that both ends of the three sets of refrigerant flow paths 35 extend out of the tank container 20 while ensuring airtightness between the inside and outside of the tank container 20.
Furthermore, the reinforcement layer 26 is formed in the outer periphery of the tank container 20 (step S190), and the hydrogen storage tank 10 is completed. The reinforcing layer 26 is formed by, for example, winding a carbon fiber impregnated with an epoxy resin or the like around the outer periphery of the tank container 20 and then curing the impregnated resin.
When hydrogen is stored in the hydrogen storage tank 10, high-pressure hydrogen is introduced into the hydrogen storage tank 10 through the hydrogen supply / discharge port 23a. The hydrogen introduced from the hydrogen supply / discharge port 23 a is guided to the holding space 32 and the end space 33 in the hydrogen storage tank 10, and further inside the heat exchanger 30 through the porous member 37 fitted in the hole 31. Into the hydrogen storage alloy. The amount of hydrogen stored in the hydrogen storage alloy is determined by the hydrogen pressure and temperature, and the type of the hydrogen storage alloy. When hydrogen is supplied at a predetermined pressure, the hydrogen storage alloy is heated up while storing hydrogen until the predetermined temperature is reached. When hydrogen is stored in this way, the inside of the hydrogen storage tank 10 is cooled by supplying and discharging the refrigerant to each of the three sets of refrigerant flow paths 35 and allowing the refrigerant to pass through the refrigerant flow paths 35. Accelerate the operation of hydrogen storage by hydrogen storage alloy. After the hydrogen storage alloy is heated to a predetermined temperature, the holding space 32 and the end space 33 are filled with hydrogen gas at a pressure corresponding to the hydrogen pressure supplied to the hydrogen storage tank 10, The hydrogen storage tank 10 is fully filled.
When taking out hydrogen from the hydrogen storage tank 10, hydrogen decompressed to a predetermined pressure is released from the hydrogen supply / discharge port 23a. When taking out hydrogen, first, it is released from the compressed hydrogen in the holding space 32 and the end space 33, and then the hydrogen stored in the hydrogen storage alloy is further released. Since the hydrogen storage alloy absorbs heat as hydrogen is released, the operation of releasing hydrogen from the hydrogen storage alloy by passing a predetermined high-temperature refrigerant through the refrigerant flow path and heating the hydrogen storage alloy is continued. can do.
When hydrogen is stored in the hydrogen storage alloy, part of the heat generated in the hydrogen storage alloy during the hydrogen storage operation is transferred to the tank container 20 via the heat exchanger case 34 and the support portion 40. It is transmitted and discharged from the tank container 20 to the outside.
According to the hydrogen storage tank 10 configured as described above, a space that allows the connection port 21 and the connection port 22 that are openings of the tank container 20 to communicate with each other between the tank container 20 and the heat exchanger 30. Since it is formed by the support portion 40, water can be easily circulated in the tank container 20, and the operation of water cooling the tank container 20 can be performed sufficiently rapidly. In particular, in the present embodiment, the support portion 40 is disposed so as to surround the outer periphery of the heat exchanger 30, and the entire space formed between the tank container 20 and the heat exchanger 30 is connected to the connection ports 21 and 22. Because of the communication, the entire tank container 20 can be quickly cooled from the inside during water cooling.
As described above, the fatigue strength of the aluminum alloy can be improved by heat-treating the aluminum alloy, and a higher pressure of hydrogen, for example, 1 MPa, is contained in the hydrogen storage tank 10 (the holding space 32 and the end space 33). It becomes possible to store hydrogen at the above pressure. By providing the reinforcing layer 26 as in the present embodiment, it is possible to store higher pressure hydrogen, for example, it is possible to store hydrogen at a pressure of 25 MPa or more, or 35 MPa or more. Thus, when storing higher pressure hydrogen, it is necessary to make the opening of the tank container 20 as small as possible in order to sufficiently secure the airtightness of the tank while withstanding the pressure of the internal hydrogen. . Further, in order to store the heat exchanger 30 in the tank container 20, at the time of storing the heat exchanger 30, the opening of the tank container 20 has a size that allows the heat exchanger 30 to pass. It is necessary to be. Therefore, it is necessary to perform drawing processing on the tank container 20 after the heat exchanger 30 is accommodated therein as in the present embodiment. Also, if the heat treatment process with water cooling is performed before drawing, the effect of improving the fatigue strength by heat treatment may be impaired by performing drawing, so the heat treatment with water cooling is It must be done after drawing. As described above, the heat treatment with water cooling is preferably performed after the process of housing the heat exchanger 30 in the tank container 20 and the process of drawing, but the support for supporting the heat exchanger in the tank container 20 is performed. If the section hinders the flow of water, it may be difficult to perform water cooling sufficiently rapidly. As in this embodiment, the space is formed by the support portion 40 so as to communicate with the openings formed at both ends of the tank container 20, so that water cooling can be performed sufficiently rapidly.
The support provided between the tank container and the heat exchanger may have a shape different from that of the above embodiment. In the above embodiment, the support portion 40 is formed by using the corrugated plate material 52 having substantially the same length as the length of the heat exchanger case 34 in the longitudinal direction, but for example, a corrugated plate material having a shorter length is used. A plurality of windings may be wound around the outer periphery of the heat exchanger case 34 to form the support portion. An example of such a hydrogen storage tank is shown in FIG. In FIG. 6, the two support portions 40 a and 40 b are provided. However, it is also possible to provide more divided support portions. By disposing the support portion, if the entire space formed between the tank container and the heat exchanger communicates with the opening of the tank container, the cooling water can be passed through the entire tank container. A similar effect can be obtained in that the container can be rapidly cooled. In particular, it is desirable for the efficiency of water cooling that the shape of the support portion is formed so that the space formed by the support portion is parallel to the longitudinal direction of the tank container.
In the embodiment, since the tank container 20 has openings (connection ports 21 and 22) at both ends thereof, water can be easily passed through the tank container 20 during water cooling to quench the tank container 20 rapidly. However, it is desirable that at least one opening is provided. If the entire space between the tank container and the heat exchanger communicates with the opening due to the shape of the support part, it is possible to perform water cooling from the inside of the tank container during the heat treatment.
In the embodiment, since the support portion 40 is formed of a metal thin plate, it is desirable to ensure a wider water distribution space between the tank container and the heat exchanger. You may form a support material by. By providing the support portion, if the entire space between the tank container and the heat exchanger communicates with the opening, it is possible to perform water cooling from the inside of the tank container during the heat treatment.
In the embodiment, the hydrogen storage alloy is filled from the hole 31 formed at the end of the tank container 20, and the hole 31 is further used for supplying and discharging hydrogen. However, the hole used for filling the hydrogen storage alloy is used. And holes used for supplying and discharging hydrogen may be provided separately. In this case, the porous member 37 may be fitted into the hole for supplying and discharging hydrogen prior to housing the heat exchanger case 34 in the tank container 20. Then, after filling with the hydrogen storage alloy, the hole used for filling may be completely closed by welding or the like.
In the embodiment, the tank container 20 in which the heat exchanger case 34 is accommodated is drawn and heat-treated and then filled with a hydrogen storage alloy. However, before the heat exchanger case 34 is accommodated in the tank container 20, heat exchange is performed. The case 34 may be filled with a hydrogen storage alloy. Thus, when performing heat treatment with water cooling on the tank container housing the heat exchanger 30 filled with the hydrogen storage alloy, the water storage alloy is not wetted by water cooling. It is desirable to ensure sufficient sealing performance of the heat exchanger 30. For example, after filling with a hydrogen storage alloy, a detachable lid may be attached to the heat exchanger 30 and the lid removed after heat treatment with water cooling.
In the embodiment, a tank container made of an aluminum alloy is used. However, a tank container made of a different material may be used instead of such a tank container. For example, the tank container may be formed of stainless steel. Even when other types of metals are used, the same effect can be obtained by applying the present invention when adopting a manufacturing method in which heat treatment such as solid solution treatment with water cooling is employed.
As a filling part filled with a hydrogen storage alloy, various deformation | transformation are possible other than the heat exchanger shown in the Example. For example, it is good also as using the filling part which provided heat-transfer parts, such as a fin, inside. By providing metal fins in the filling portion so as to be in contact with both the hydrogen storage alloy and the refrigerant flow path, the efficiency of cooling and heating of the hydrogen storage alloy can be improved. Further, by providing fins in the filling portion so as to be in contact with both the hydrogen storage alloy and the tank container, heat dissipation can be promoted during hydrogen storage. Alternatively, the refrigerant flow path may not be provided in the interior as long as the cooling when hydrogen is occluded and the heating when hydrogen is released are sufficiently performed. In any case, when the filling portion (or the case for forming the filling portion) is stored in the tank container and then heat treatment with water cooling is performed, the present invention is applied to improve water cooling. Can be performed.
In the embodiment, the hydrogen storage alloy is filled in the heat exchanger as the filling portion, but other kinds of occlusion / adsorption materials may be used. Alternatively, another type of occlusion / adsorption material may be further provided. For example, in addition to the hydrogen storage alloy, activated carbon or carbon nanotubes may be further provided.
Further, in place of a filling portion filled with an occlusion / adsorption material that occludes and / or adsorbs hydrogen, a predetermined storage portion not filled with such an occlusion / adsorption material may be accommodated in the tank container. . That is, in a gas storage tank that stores some storage unit in the tank container, the same effect can be obtained by using the support unit of the present invention to support the storage unit in the tank container.
E10. Modification 10:
In the above embodiment, the hydrogen storage tank for storing hydrogen is used. However, the same effect can be obtained by applying the present invention to manufacturing a tank for storing high-pressure gas other than hydrogen.
FIG. 1 is an explanatory diagram showing an outline of the configuration of a hydrogen storage tank 10;
FIG. 2 is an explanatory diagram illustrating a state of a section 2-2 in FIG.
FIG. 3 is a process diagram illustrating a method for manufacturing the hydrogen storage tank 10.
FIG. 4 is an explanatory diagram showing a state of main processes when manufacturing the hydrogen storage tank 10;
FIG. 5 is an explanatory diagram showing the state of main processes when manufacturing the hydrogen storage tank 10;
FIG. 6 is an explanatory diagram showing a state of a hydrogen storage tank according to a modification.
DESCRIPTION OF SYMBOLS 10 ... Hydrogen storage tank 20 ... Tank container 21, 22 ... Connection port 23, 24 ... Connection part 23a ... Hydrogen supply / exhaust port 26 ... Reinforcement layer 30 ... Heat exchanger 31 ... Hole 32 ... Holding space 33 ... End part space 34 ... Heat exchanger case 35 ... refrigerant flow path 37 ... porous member 40 ... support portions 40a, 40b ... support portion 50 ... outer wall portion 52 ... corrugated plate material
A gas storage tank for storing gas,
A tank container in which the filling part is housed, and openings are formed at both ends in the longitudinal direction;
The tank is formed into a corrugated shape by folding metal thin plates in alternate directions, and in contact with the tank container on one surface of the corrugated shape, and in contact with the filling portion on the other surface of the corrugated shape, A support part for supporting the filling part in the tank container while forming a plurality of spaces between the container and the filling part and being substantially parallel to the longitudinal direction of the tank container and communicating with the opening part; Gas storage tank comprising.
The gas storage tank according to claim 1,
The said tank container has a throttle part where the area of a cross section becomes smaller near the opening part formed in an edge part. Gas storage tank.
The gas storage tank according to claim 1 or 2,
In the tank container, two openings are formed at opposing positions. Gas storage tank.
A gas storage tank according to any one of claims 1 to 3,
The support part forms a plurality of spaces substantially parallel to the cylindrical axial direction between the tank container and the filling part. Gas storage tank.
A gas storage tank according to any one of claims 1 to 4,
The tank container is formed of a metal containing aluminum.
A method for manufacturing a gas storage tank for storing gas, comprising:
(A) In a tank container in which openings are formed at both ends in the longitudinal direction , a filling part filled with a storage / adsorption material for storing and / or adsorbing the gas is stored, and the tank container While forming a plurality of spaces that are substantially parallel to the longitudinal direction and communicating with the opening, the metal thin plates are folded in a staggered direction so as to support the filling portion in the tank container to have a corrugated shape. Disposing the formed support portion between the tank container and the filling portion;
(B) A method of manufacturing a gas storage tank, comprising: after the step (a), performing a heat treatment with water cooling on the tank container.
JP2003081706A 2003-03-25 2003-03-25 Gas storage tank and manufacturing method thereof Expired - Fee Related JP4167521B2 (en)
JP2003081706A JP4167521B2 (en) 2003-03-25 2003-03-25 Gas storage tank and manufacturing method thereof
KR20040019235A KR100620303B1 (en) 2003-03-25 2004-03-22 Gas storage tank and its manufacturing method
US10/806,163 US7418782B2 (en) 2003-03-25 2004-03-23 Method of manufacturing a gas storage tank
DE200410014144 DE102004014144B4 (en) 2003-03-25 2004-03-23 Process for producing a gas storage tank
US12/149,369 US7946446B2 (en) 2003-03-25 2008-04-30 Gas storage tank and method of manufacturing the same
JP2004286178A JP2004286178A (en) 2004-10-14
JP4167521B2 true JP4167521B2 (en) 2008-10-15
ID=33295165
JP2003081706A Expired - Fee Related JP4167521B2 (en) 2003-03-25 2003-03-25 Gas storage tank and manufacturing method thereof
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