Source: https://patents.google.com/patent/AU2008254000B9/en
Timestamp: 2019-07-16 03:29:14
Document Index: 524356424

Matched Legal Cases: ['art 5', 'arts 60', 'arts 60', 'arts 60', 'arts 60', 'arts 60', 'arts 60', 'art 70', 'art 10']

AU2008254000B9 - Hollow fiber membrane module, process for manufacturing the same, hollow fiber membrane module assembly and method of purifying suspended water with use thereof - Google Patents
Hollow fiber membrane module, process for manufacturing the same, hollow fiber membrane module assembly and method of purifying suspended water with use thereof Download PDF
AU2008254000B9
AU2008254000B9 AU2008254000A AU2008254000A AU2008254000B9 AU 2008254000 B9 AU2008254000 B9 AU 2008254000B9 AU 2008254000 A AU2008254000 A AU 2008254000A AU 2008254000 A AU2008254000 A AU 2008254000A AU 2008254000 B9 AU2008254000 B9 AU 2008254000B9
AU2008254000A
AU2008254000B2 (en
AU2008254000A1 (en
Yuzuru Ishibashi
2007-05-22 Priority to JP2007134951 priority Critical
2007-05-22 Priority to JP2007-134951 priority
2008-05-21 Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
2008-05-21 Priority to PCT/JP2008/059366 priority patent/WO2008143292A1/en
2008-11-27 Publication of AU2008254000A1 publication Critical patent/AU2008254000A1/en
2010-11-25 Publication of AU2008254000B2 publication Critical patent/AU2008254000B2/en
2011-05-12 Application granted granted Critical
2011-05-12 Publication of AU2008254000B9 publication Critical patent/AU2008254000B9/en
C02F1/445—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by forward osmosis
100/16 1 DESCRIPTION HOLLOW FIBER MEMBRANE MODULE, PROCESS FOR MANUFACTURING THE SAME, HOLLOW FIBER MEMBRANE MODULE ASSEMBLY AND METHOD OF PURIFYING SUSPENDED WATER WITH USE THEREOF 5 TECHNICAL FIELD [00011 The present invention relates to an external pressure type hollow fiber membrane that can be used in various fields but is particularly suitable for fields 10 of water treatment such as clarification of river water, lake water, river-bed water, and the like. Moreover, the present invention relates to a hollow fiber membrane module having an increased effective length contributing to permeation through the hollow 15 fiber membrane, the improved effective utilization factor of a membrane area, and enhanced permeation performance per unit area, and a process for manufacturing the hollow fiber membrane module, a hollow fiber membrane module assembly, and a method of 20 purifying suspended water using the hollow fiber membrane module assembly. BACKGROUND ART [0002] 2 Hollow fiber membrane modules can provide a large membrane area per unit volume. The hollow fiber membrane modules are thus applied in many fields of fluid treatment, for example, demineralization of 5 brackish water and sea water using a reverse osmosis membrane, primary purification treatment of ultrapure water, removal of low molecular-weight organisms such as agricultural chemicals and polysaccharides using a nanofilter, concentration and demineralization of 10 enzymes using a ultrafiltration membrane, manufacture of water for injection, recovery of electroplating coats, final filtration of ultrapure water, waste water treatment, clarification of river water, lake water, and river-bed water, purification, sterilization, and 15 clarification of chemicals using a microfiltration membrane, and oxygen separation, nitrogen separation, hydrogen separation, and carbon dioxide gas separation using a gas separation membrane. [00031 20 In recent years, in allowing river water, river-bed water, and the like to be used as purified water, hollow fiber membranes and hollow fiber membrane modules have been more widely used as a clarification method instead of coagulating sedimentation and sand 25 filtration. Thus, new, high-performance hollow fiber membranes and hollow fiber membrane modules have been proposed. [0004] 3 Most conventional external pressure-type hollow fiber membrane modules pressurizing raw water via a hollow fiber membrane to obtain permeated water are constructed as follows. Hollow portions are sealed 5 to an adhesive fixing portion positioned at the bottom of the module and partitioning hollow fiber membranes from a module housing in a liquid-tight manner. A plurality of raw water introduction holes are formed in the adhesive fixing portion so that raw water can be 10 fed parallel to the hollow fiber membranes through the holes. Permeated water is sampled through the opening of each of the hollow fiber membranes in the end surface thereof located at the top of the module. Concentrated water containing suspended substances is 15 discharged through a concentrated water discharge nozzle on a side surface of the upper portion of the module (See PATENT DOCUMENTS 1 and 2). [0005] An example of the structure of such an 20 external pressure-type hollow fiber membrane module is shown in Fig. 17. In Fig. 17, a large number (in this case, for simplification, three) hollow fiber membranes 105 are housed in a module case 104. At the top of the case, the hollow fiber membranes and the module case 25 are adhesively fixed together in a liquid-tight manner by an adhesive fixing portion 106. The terminals of the hollow fiber membranes are open so as to enable a liquid to pass through. Permeated water is collected 4 in a cap 101 and pumped upward through a permeated water sampling port 112 for sampling. [00061 On the other hand, at the bottom of the case, 5 the hollow fiber membranes are adhesively fixed to the module case in a liquid-tight manner by an adhesive fixing portion 107. The terminals of the hollow fiber membranes are closed. A plurality of raw-water introduction holes 108 are open in the lower adhesive 10 fixing portion 107 so that any one of raw water, compressed air, and a mixed flow of raw water and compressed air can be fed through the holes 108. Here, a liquid flow during normal filtration will be described. Raw water flows from a raw-water supply 15 port 110 formed in a lower cap 103, via the raw-water introduction holes 108 into the module case. Most of the raw water permeates the hollow fiber membranes 105. The resulting permeated water flows through the upper openings of the hollow fiber membranes via the cap 101 20 and sampled through the permeated water sampling port 112. Furthermore, part of the raw water is concentrated, and the concentrated water is discharged through a concentrated water discharge nozzle 111 on the side surface of the upper portion. At this time, 25 depending on the quality of the raw water, a method can be adopted which discharges the concentrated water only during physical washing such as flushing, back washing, or aeration flushing rather than continuously 5 discharging the concentrated water. [00071 When miniaturized in order to evaluate the performance of the membranes or check for filtration 5 stability, a hollow fiber membrane module constructed as described above may have an effective membrane length of about 1 m. Furthermore, if the hollow fiber membrane module is used for an actual large-scale water 10 clarification treatment, the effective length of the hollow fiber membranes is normally set to a larger value of about 2 m in order to reduce the installation area of an arrangement rack in which the membrane module is arranged or to increase the area of the 15 hollow fiber membranes per unit volume. However, since the conventional hollow fiber membranes exhibit low permeation performance, a pressure drop in the hollow portion on the permeated water side is small. The conventional module is thus used without posing a 20 problem in a practical sense. [0008] However, recently, with an increase in the number of applications of membrane filtration modules for purified water, the permeation performance of the 25 hollow fiber membranes has been improved. On the other hand, what is called one-sided water collection modules have frequently failed to offer a level of permeation performance otherwise exhibited by the hollow fiber 6 membranes; in the one-sided water collection module, permeated water is sampled only through the openings of the hollow fiber membranes located at the top of the module. 5 [0009] Thus, a structure is known which has a module structure with a communication portion through which permeated water flows from one side to the other side in order to improve the effective utilization factor of 10 the hollow fiber membranes; in this structure, permeated water can be sampled through the opposite ends of the hollow fiber membrane module (see, for example, PATENT DOCUMENTS 3 to 6). Figs. 4, 5, and 9 in PATENT DOCUMENT 3 show that compressed air is 15 introduced through a lower air introduction hole 19 to vibrate the hollow fiber membranes. [00101 Such an introduction structure enables a fluid with a relatively low viscosity such as 20 compressed air to be evenly distributed with a relatively low pressure drop. However, a viscous fluid such as water containing suspended substances results in a very heavy drop in the pressure required for a necessary supply. The mere feeding of the fluid into 25 the hollow fiber membrane module requires at least 100 KPa. This supply pressure is equivalent to or higher than that required for the normal supply of raw water, that is, 50 to 100 KPa. Thus, it is unpractical to 7 apply the structure with the introduction holes for air only to water without change. [0011] Moreover, in a method for manufacturing the 5 module structure, as described in PATENT DOCUMENT 4, a plurality of holes are formed along the outer circumference of the module case, and a partitioning plate with holes formed therein and a hollow fiber membrane bundle are housed in the module case at a 10 time. Moreover, the holes in the partitioning plate are placed opposite the corresponding holes in the module case. The partitioning plate and the module case are adhesively fixed together using bolts with flexible tubes. Moreover, the bolts with the flexible 15 tubes are removed. The method thus requires a very complicated assembly operation. It is thus difficult to apply the method to, for example, a membrane filtration process for river water which allows permeated water to be inexpensively obtained. 20 [0012] PATENT DOCUMENT 5 discloses a structure similar to those in PATENT DOCUMENTS 3 and 4. However, in this case, unless as seen in a sectional view, the air introduction holes are formed symmetrically with 25 respect to a center axis and at equal intervals, the supply of air or water is not uniform. The symmetric arrangement at the equal intervals requires a complicated assembly operation as is the case with 8 PATENT DOCUMENT 4. [0013] Furthermore, PATENT DOCUMENT 6 discloses a structure in which a large number of raw water introduction holes extend from a site corresponding to a supply source pipe portion for raw water drilled from the substantial center of the outer end surface of one adhesive fixing portion, directly to the other adhesive fixing portion so as to-allow raw water to be fed perpendicularly to the hollow fiber membranes. In this case, the raw water is fed perpendicularly outward from the center of the hollow fiber membrane bundle. Thus, disadvantageously, suspended substances are accumulated between the central hollow fiber membranes, preventing the raw water from being fed to the outer circumference of the bundle. PATENT DOCUMENT 1: JP-A-07-171354 PATENT DOCUMENT 2: JP-A-09-220446 PATENT DOCUMENT 3: JP-U-63-111901 PATENT DOCUMENT 4: JP-A-64-090005 PATENT DOCUMENT 5: JP-U-03-119424 PATENT DOCUMENT 6: JP-A-53-035860 [0013a] Any discussion of documents, devices, acts or knowledge in this specification is included to explain the context of the invention. It should not be taken as an admission that any of the material formed part of the prior art base or the common general knowledge in 9 the relevant art in Australia on or before the priority date of the claims herein. DISCLOSURE OF THE INVENTION [0014] It would be desirable to provide a hollow fiber membrane module offering an improved effective utilization factor in the length direction of hollow fiber membranes and the stabilized amount of permeated water per unit membrane area, the hollow fiber membrane module suffering a reduced pressure drop and enabling water to be sampled with reduced energy, the hollow fiber membrane module being easily manufactured and being easy to produce in a reduced number of manufacture steps, as well as a hollow fiber membrane module assembly using the hollow fiber membrane module. [0015] The present invention exerts more significant effects through the application of high-permeation performance membranes. [0016] In accordance with a first aspect of the present invention there is provided a hollow fiber membrane module including a cylindrical module case, a bundle of a large number of hollow fiber membranes housed in the module case, adhesive fixing portions fixing respective opposite ends of the bundle in the module case so as to allow a raw fluid to pass through the hollow fiber membranes, a permeated fluid 10 communication portion connecting opposite outer end surfaces of the adhesive fixing portions together via a pipe with a larger equivalent diameter than each of the hollow fiber membranes, and a raw-fluid distributive supply portion located at one of the adhesive fixing portion to enable the raw fluid to be fed into the module case, wherein the raw-fluid distributive supply portion includes one supply source pipe portion drilled from a center of the outer end surface of the one of the adhesive fixing portions in a length direction of the module case and a raw-fluid supply branching portion evenly distributing the supplied raw fluid in a direction of a cross section of the hollow fiber membrane module, and has a plurality of raw-fluid introduction holes drilled in a gap between the hollow fiber membranes so as to enable the raw fluid to be fed along a longitudinal direction of the hollow fiber membranes. [0017] Preferably, a plurality of the raw-fluid supply branching portions following the supply source pipe portion are drilled therein, each having an acute forward angle advancing from the supply source pipe portion along the length direction. [0018] Further, the raw-fluid distributive supply portion may include raw-fluid introduction holes drilled so as to follow the raw-fluid supply branching portions and extend to an inner end surface of the adhesive fixing portion, and a sectional area of the 11 plurality of raw-fluid supply branching portions increases along a forward flow direction of the raw water. [0018a] Further, the raw-fluid supply branching portions may be plate-like voids substantially parallel to the length direction, and a plurality of the raw fluid supply branching portions may be radially arranged in the raw-fluid distributive supply portion around the supply source pipe portion serving as a substantial center axis. [0018b] Further, the plurality of raw-fluid supply branching portions may be 3 to 9 raw-fluid supply branching portions branching from the supply source pipe portion. [0018c] Further, a plurality of the raw-fluid introduction holes can be formed in each of the raw fluid supply branching portions, and a sum of equivalent diameters of the plurality of raw-fluid introduction holes may be smaller than a maximum equivalent diameter of the plurality of raw-fluid supply branching portions. [0018d] Further, when each of the raw-fluid supply branching portions is divided into a central side and an outer side at a position of a half radius outward from the center of the raw-fluid supply branching portion, the sum of the equivalent diameters of the raw-fluid introduction holes formed in the outer-side division may be larger than that of the raw-fluid 12 introduction holes formed in the central-side division. [0019] Further, the plurality of raw-fluid introduction holes can be drilled at equal intervals. [0019a] Further, the equivalent diameter of the raw fluid introduction hole may increase with decreasing distance to an outer circumference of the module case. [0019b] Further, the permeated fluid communication portion can be at least one communication pipe contained in the hollow fiber membrane bundle. [0019c] Further, a number of the communication pipes may be one to four. [0019d] Further, the module case can be an irregular shaped double pipe including a first portion having a relatively large inner sectional area and a second portion having a relatively small inner sectional area, and the hollow fiber membrane bundle is housed in the first portion, whereas the permeated fluid communication portion is provided in the second portion. [0019e] Further, the inner end surface of each of the adhesive fixing portions can be substantially flush with an inner end surface of an adhesive used to form the adhesive fixing portion. [0019f] A process for manufacturing the hollow fiber membrane module set forth above, includes molding at least a part of a raw-fluid distributive supply portion using a material which is easily dissolved into, or easily absorbed and dispersed in water, hot water, or 13 an organic solvent not affecting a member including a hollow fiber membrane module, placing an inner end surface of the molded raw-fluid distributive supply portion inside the adhesive fixing portion, then adhesively fixing the raw-fluid distributive supply portion, a hollow fiber membrane, a permeated fluid communication portion, and a module case together, and then allowing at least a part of the raw-fluid distributive supply portion to be dissolved into or absorbed and dispersed in any of the water, the hot water, and the organic solvent to form the raw-fluid distributive supply portion. [0019g] A hollow fiber membrane module assembly includes a first cup (i) shaped like a cup including a permeated fluid supply port and (ii) having a permeated fluid holding space inside the cup shape, the first cup being fixed to an outside of an outer end surface of an adhesive fixing portion at a circumferential end side of the cup shape in a liquid-tight manner, the adhesive fixing portion including the raw-fluid distributive supply portion of the hollow fiber membrane module set forth above and a second cup (a) shaped like a cup including a permeated fluid sampling port and (b) having a permeated fluid holding space inside the cup shape, the second cup being fixed to an outside of an outer end surface of another adhesive fixing portion at a circumferential end side of the cup shape in a liquid-tight manner, iii) the first cup including a 14 nozzle extending continuously from the raw-fluid supply port in a liquid-tight manner and projecting into the permeated fluid holding space, and iv) the nozzle being coupled to the supply source pipe portion in a liquid tight manner. [0019h] A method of purifying suspended water wherein a raw fluid is water and a product of a turbidity of the water and TOC (Total Organic Carbon) is 10,000 degree x mg/liter or less and wherein water with a turbidity of at most 100 degrees and a TOC of 100 mg/liter or less and the hollow fiber membrane module set forth above is used to obtain filtrate. [0019i] In accordance with a further aspect of the invention there is provided a hollow element for forming a raw-fluid distributive supply portion including a supply source pipe portion for supplying raw water, compressed air, or a mixed flow of raw water and compressed air; a plurality of raw-fluid supply branching portion for evenly distributing the supplied raw water, the supplied compressed air or the supplied mixed flow of raw water and compressed air; and a raw fluid introduction hole for introducing the distributed raw water, the distributed compressed air or the distributed mixed flow of raw water and compressed air. [0019j] Further, a sectional area of the plurality of raw-fluid supply branching portions may increase along a forward flow direction of the raw water, the compressed air, or the mixed flow of raw water and 15 compressed air. [0019k] Further, the raw-fluid supply branching portions may be plate-like voids substantially parallel to the length direction, and the plurality of the raw fluid supply branching portions can be radially arranged in the raw fluid distributive supply portion around the supply source pipe portion serving as a substantial center axis. [00191] Further, the plurality of raw-fluid supply branching portions can be 3 to 9 raw-fluid supply branching portions branching from the supply source pipe portion. [0019m] Further, a plurality of the raw-fluid introduction holes can be formed in each of the raw fluid supply branching portions, and a sum of equivalent diameters of the plurality of raw-fluid introduction holes may be smaller than a maximum equivalent diameter of the plurality of raw-fluid supply branching portions. [0019n] Further, when each of the raw-fluid supply branching portions is divided into a central side and an outer side at a position of a half radius outward from the center of the raw-fluid supply branching portion, the sum of the equivalent diameters of the raw-fluid introduction holes formed in the outer-side division may be larger than that of the raw-fluid 15a introduction holes formed in the central-side division. [00190] Further, the plurality of raw-fluid introduction holes can be drilled at equal intervals. [0020] The description in the application uses names indicative of functions, such as a raw-fluid (raw water) supply port, a raw-fluid (raw-water) distributive supply portion, a raw-fluid (raw-water) supply source pipe, a raw-fluid (raw-water) supply branching portion, a raw-fluid (raw-water) introduction hole, and a concentrated water discharge port. However, the names are used to make the contents of the present invention more easily understood, and are not limited to the functions. [0020a] Comprises/comprising and grammatical variations thereof when used in this specification are to be taken to specify the presence of stated features, integers, steps or components or groups thereof, but do not preclude the presence or addition of one or more other features, integers, steps, components or groups thereof. ADVANTAGES OF THE INVENTION [0021] The hollow fiber membrane module according to the present invention feeds and filters raw water parallel to the hollow fiber membranes. The hollow fiber membrane module according to the present invention thus enables a stable filtration operation and allows suspended components to be properly 15b discharged during physical washing. Furthermore, permeated water can be sampled from the opposite sides. This improves the effective utilization factor of the hollow fiber membranes and enables a stable amount of permeated water to be sampled per unit membrane area with reduced energy. In this regard, significant performance can be achieved by applying high- 16 permeation-performance membranes. Even with membranes with a conventional level of performance applied, the present invention limits a possible pressure drop during operation to a low range. This allows the 5 hollow fiber membrane module to be operated with a relatively low operating pressure. Moreover, for example, the raw-water distributive supply portion can be easily and accurately positioned in the module case. Thus, the hollow fiber membrane module can be easily 10 manufactured in simple manufacture steps. Furthermore, the hollow fiber membrane module according to the present invention can be mounted without change in a membrane filtration facility in which a hollow fiber membrane module to which raw water is fed through the 15 bottom thereof and from which permeated water is sampled through the top thereof is mounted, with concentrated water discharged from the side surface of the top; conventional purification treatment based on external-pressure hollow fiber membrane filtration 20 mostly uses the latter hollow fiber membrane module. BEST MODE FOR CARRYING OUT THE INVENTION [0022] The best mode for carrying out the present invention will be described below in detail with 25 reference to the drawings. In the description below, by way of example, a hollow fiber membrane module assembly is vertically located. Furthermore, raw water 17 or compressed air is fed through the bottom of the hollow fiber membrane module assembly. Thus, the forward flow direction of raw water during a normal membrane treatment is upward from the bottom. However, 5 of course, the hollow fiber membrane module assembly may be placed horizontally or obliquely. Furthermore, here, the hollow fiber membrane module refers to a container which is filled with a large number of hollow fiber membranes; the opposite ends of each of the 10 hollow fiber membranes are fixed with an adhesive, and a liquid can be passed through the hollow fiber membranes. The hollow fiber membrane module assembly refers to the hollow fiber membrane module with caps attached to the respective ends thereof. Each of the 15 caps allows permeated water to be held therein and sampled therefrom or allows raw water to be fed therethrough. [00231 A module structure will be described below 20 with reference to an example of an external pressure type hollow fiber membrane module in which a straight pipe in the module is applied as a permeated water communication portion. A sectional view of the example of the structure of an assembly of such hollow fiber 25 membrane modules is shown in Fig. 1 (for easy understanding, some lines are omitted). [0024] A hollow fiber membrane module 20 uses a 18 cylindrical module case 21 having an open top surface and an open bottom surface, and a concentrated water or air discharge port 22 (hereinafter referred to as a discharge port 22) formed in the upper part of the side 5 surface of the module case 21 and extending in the horizontal direction. Typically, the module case 21 preferably has a diameter selected from the range of 30 mm to 800 mm and a length selected from the range of 300 mm to 3,000 mm. Examples of available materials 10 for the module case 21 include fluorine resins such as polytetrafluoroethylene, a tetrafluoroethylene hexafluoropropylene copolymer resin, an ethylene tetrafluoroethylene copolymer resin, and polyvinylidene-fluoride, polyolefins such as 15 polyethylene, polypropylene, and polybutene, various polymer compounds such as polyvinyl chloride, an ABS (Acrylonitrile Butadiene Styrene) resin, an AS (Acrylonitrile Styrene) resin, polyester, polysulphone, polyether sulphone, and polyphenylene ether, and metals 20 such as stainless steel and an aluminum alloy. A portion of the module case 21 having the concentrated water discharge port 22 may be separately molded and combined with another pipe-like portion. The portion having the concentrated water discharge port 22 may 25 particularly be called a head portion. [0025] A large number of hollow fiber membranes 24 (for simplification, only one hollow fiber membrane is 19 illustrated) are housed in the module case. The hollow fiber membrane in the specification is not particularly limited provided that the membrane can be used for fluid treatment. Examples of materials for the hollow 5 fiber membrane include polyacrylonitrile, polysulphone, polyether ketones, polyether sulphone, polyphenylene sulfide, polyvinylidene-fluoride, celluloses, polyvinyl alcohol, polyamide, polyimide, sulfonated polyphenylene ether, polyethylene, polypropylene, polybutene, poly4 10 methylpentene, polyorganosiloxane, polyethylene fluoride, and ethylene-tetrafluoroehylene copolymer, or a mixture or compound thereof. Furthermore, the types of membranes include an ultrafiltration filter with a molecular cutoff of 1,000 to 500,000 daltons and a 15 microfiltration membrane with a pore diameter of 0.01 to 1 pm. Moreover, the available hollow fiber membrane is shaped so as to have an inner diameter of 50 to 3000 jtm and an inner/outer diameter ratio of 0.3 to 0.8. [0026] 20 The opposite ends of the hollow fiber membrane are fixed in the module case by adhesive fixing portions 26 and 27, respectively, so that a liquid can be passed into the hollow fiber membrane through the opposite ends. Furthermore, the adhesive 25 fixing portions 26 and 27 separates the exterior and interior of the module from each other in a liquid tight manner. An adhesive may be used for the adhesive fixation. The type of the available adhesive may be 20 appropriately selected taking into account the materials of the module case and the hollow fiber membrane and a communication pipe and a raw-water distributive supply portion described below. A 5 thermosetting polymer material, for example, an epoxy resin, a urethane resin, or silicone, may be used as the adhesive. As an adhesive fixation method, a well known method such as a centrifugal adhesion method may be used. The adhesive may further contain a fibrous 10 substance such as glass fiber or carbon fiber or a fine powder such as carbon black, alumina, or silica because these substances may enhance the hardening and shrinkage and the strength of the adhesive. The hollow fiber membrane module 20 includes 15 a permeated water communication portion connecting the opposite outer end surfaces of the adhesive fixing portions 26 and 27 together so that a liquid can be passed through the outer end surfaces. The permeated water communication portion is a pipe having a larger 20 equivalent diameter and offering a smaller channel resistance, than the above-described hollow fiber membrane 24. Even if the hollow fiber membrane has a large length of, for example, about 2 m, such a permeated water communication portion allows permeated 25 water having permeated a portion of the membrane which is relatively close to a raw water supply port to be sampled with a small pressure drop. This significantly improves membrane utilization factor. The equivalent 21 diameter may be calculated from the immersion side length of the inner circumference of the channel through which raw water or compressed air flows, based on hydrodynamics. However, just to make certain, the 5 calculation method is described below. [0027] The equivalent diameter in the specification is defined as De. Then, the equivalent diameter is determined by multiplying the inner sectional area S of 10 the permeated water communication section by 4 and then dividing the product by the inner circumferential side length (the length over which a fluid contacts the inner cross section) L, as shown in: De = 4 x S/L. 15 [0028] The permeated water communication portion may be based on a method of placing a straight line in the module, a method of forming the module case itself into an irregular shaped double pipe, or the like. An 20 example of the former method is shown in Fig. 1. In this example, a communication pipe 25 is contained in the bundle of the hollow fiber membranes 24 parallel to the hollow fiber membranes 24. The communication pipe has a larger equivalent diameter than each of the 25 hollow fiber membranes 24 and allows permeated water to flow from the bottom to top of the module. At least one such communication pipe may be used. The number of communication pipes may be appropriately determined 22 within a scope that allows the membrane utilization efficiency of the hollow fiber membrane module to be increased. In this case, the communication pipe 25 is adhesively fixed in the module case both on the sides 5 of the upper adhesive fixing portion 26 and the lower adhesive fixing portion 27. Like the hollow fiber membrane 24, the communication pipe 25 is open so as to allow a liquid to pass to the interior of the module. Thus, permeated water or the like can pass easily 10 through the communication pipe 25 from the top to bottom or bottom to top of the module. [0029] Preferably, such a communication pipe is made by extruding a polymer material. Examples of available 15 polymer materials include polyolefins such as polyethylene, polypropylene, and polybutene, polyvinyl chloride, polyester, polysulphone, polyethersulphone, polyphenylene ether, an ABS resin, and an AS resin. If a straight pipe is used as the communication pipe, the 20 pipe may have any sectional shape such as a circle, an ellipse, a semicircle, or a spindle but needs to have a larger equivalent diameter and offer a smaller channel resistance, than the hollow fiber membrane. [0030] 25 Furthermore, by way of example, in the method of forming the module case itself into an irregular shaped double pipe, the module case may be formed into an irregular-shaped double pipe made up of a first 23 portion with a relatively large inner sectional area and a second portion with a relatively small inner sectional area. Then, a bundle of hollow fiber membranes may be housed in the first portion, and a 5 permeated water communication portion may be provided in the second portion. In the example, the irregular shaped double pipe is generally shaped like a cylinder the internal volume of which is divided into two by a plate parallel to the length direction such that the 10 opposite ends of a circular arc that is a part of a circle in a cross section of the cylinder which is perpendicular to the length direction are connected together by a straight line so that the cross section is divided into a semicircular cross section (see Fig. 15 21) and another cross section. In this case, the semicircular sectional portion serves as a communication portion. The remaining portion is used to house the hollow fiber membranes. Such a hollow fiber membrane module can be produced by a method of 20 joining an irregular-shaped double pipe extruded through an irregular-shaped double nozzle to a head portion with a double structure corresponding to the divided internal space. Alternatively, an opening may be formed in a part of the circumference of the side 25 surface of the upper part of an extruded irregular shaped double pipe. Then, a joint with a nozzle may be installed over the side opening in the irregular-shaped double pipe. In this case, a method described in 24 Japanese Patent No. 3713343 may be adopted. If the irregular-shaped double pipe is used as a permeated water communication portion, the same material as that of the module case may be used. The permeated water 5 communication portion may have a sectional shape different from the above-described one, such as a circle, an ellipse, a semicircle, or a spindle. The permeated water communication portion may be installed at one location or at two or more locations. Figs. 21 10 to 25 show examples of irregular-shaped double pipes having the above-described and other shapes, respectively. [00311 One of the adhesive fixing portions of the 15 hollow fiber membrane module internally has a raw-water distributive supply portion that enables raw water to be fed into the module case. The raw-water distributive supply portion allows raw water supplied through the raw water supply port to be distributively 20 and evenly fed to the hollow fiber membranes parallel thereto without causing an excessive pressure drop. The raw-water distributive supply portion provides the function of separating raw water from permeated water (which permeates the hollow fiber membranes from the 25 lower portion thereof and flows from a permeated water circulation space provided outside the lower end surface of the module, through the communication pipe to a permeated water sampling port) in a liquid-tight 25 manner and feeding the raw water to the periphery of the hollow fiber membranes in the hollow fiber membrane module. Furthermore, the raw-water distributive supply portion is used for a mixed flow of raw water and compressed air and the supply only of compressed air. Moreover, the raw-water distributive supply portion is used to discharge and drain water resulting from physical washing such as back washing or aeration. In this case, such a particular structure as described above allows raw water to be supplied with a reduced pressure drop and enables a hollow fiber membrane module to be manufactured in relatively simple manufacture steps. [00321 The particular structure of the raw-water distributive supply portion will be described with reference to Fig. 1 (Fig. 3). The raw-water distributive supply portion is made up of a supply source pipe portion 34 through which raw water or the like is supplied, a raw-water supply branching portion 33 evenly distributing the supplied raw water or the like, in the direction of the cross section of the hollow fiber membrane module, and a raw-water introduction hole 32 through which the distributed raw water or the like is introduced into the outside of the hollow fiber membranes in the module. [0033] First, the supply source pipe portion 34 is 26 one cylindrical void drilled substantially parallel to the length direction of the module case from the substantial center of an outer end surface 29 of the adhesive fixing portion 27, located on the side on 5 which the raw-water distributive supply portion is provided. The terms "substantial center" and "substantially parallel" as used herein need not be geometrically strictly central or parallel but may be central or parallel within a scope that enables a 10 desired function to be fulfilled. This also applies to other terms with the word "substantial" or "substantially". A first cap nozzle described below is coupled to the supply source pipe portion in a liquid tight manner using seal means such as an 0 ring seal. 15 [00343 In a certain method, a plurality of supply source pipe portions are provided in the outer circumferential portion of the module so as to allow raw water to be fed toward the center of the cross 20 section of the module. In this case, as is apparent from Experiment Example 7 described below, if fluids with different viscosities need to be supplied, such as a liquid that is raw water, compressed air used for aeration washing, and a multiphase flow of raw water 25 and compressed air, it is difficult to allow all of the fluids to be evenly fed with a possible pressure drop limited within a narrow range. However, provision of the single supply source pipe portion 34 enables raw 27 water or the like to be fed into the module with a relatively small pressure drop. The position of the supply source pipe portion 34 on the outer end surface 29 need not necessarily be the center but may be close 5 to the outer circumference. However, to allow raw water to be proportionately and evenly distributed in the module, the supply source pipe portion 34 is preferably located as close to the center as possible. Locating the supply source pipe portion 34 in the 10 center facilitates the coupling of the first cap described below to the outer end surface 29 of the module. [0035] Now, the raw-water supply branching portion 15 33, following the supply source pipe portion 34, will be described. The raw-water supply branching portion 33 is a void shaped like a plate which is substantially parallel to the length direction of the module and which has a surface 30 with an acute forward angle 20 formed as the raw-water supply branching portion 33 advances from the supply source pipe portion 34 along the length direction of the module. Such a void enables raw water to be evenly distributed in the direction of the cross section of the module. The 25 "forward angle" as used herein refers to one of the angles which, when a certain advancing direction branches at a branching point, are formed around the branching point by the advancing direction and the 28 branching direction, the angle being formed between the branching direction and a reference line extending forward from the branching point in the advancing direction, as shown in Fig. 2(1). In Fig. 1, the raw 5 water supply branching portion 33 is shown as a part of the raw-water distributive supply portion with a funnel-shaped cross section. [00361 The raw-water supply branching portion 10 preferably has the above-described surface with the acute angle. This is because the surface allows the length of the void to decrease in the length direction of the module with increasing distance from the supply source pipe (center) with respect to the outer 15 circumference of the module, enabling raw water or the like to be evenly fed from the center axis toward the outer circumference of the module. As a result, the sum of the sectional areas of the plurality of raw water supply branching portions in the length direction 20 of the module increases along the forward flow direction of raw water. Alternatively, the thickness of the plate-like void may be varied from the center to outer circumference of the module. Although also depending on the permeating capability of the hollow 25 fiber membrane or the hollow fiber membrane module, the acute angle in the raw-water supply branching portion may be appropriately selected taking into account, for example, the diameter and shape of a raw water 29 introduction hole described below. [0037] Now, how the cross section of the raw-water supply branching portion is enlarged will be described 5 with reference to Fig. 26. Fig. 26(3) shows the sectional area Si of a cross section taken along line J-J' in Fig. 26(2). Fig. 26(4) shows the sectional area S2 of a cross section taken along line K-K' in Fig. 26(2). As seen in Fig. 26, the sectional area 10 increases from S2 to Sl as the raw-water supply branching portion advances in the forward flow direction from the cross section K-K', close to the raw water supply side, toward the cross section J-J'. [0038] 15 Preferably, a plurality of the raw-water supply branching portions 33 are radially provided around the supply source pipe portion 34, serving as a substantial center axis. Specifically, 3 to 9 raw water supply branching portions 33 are preferably 20 provided in terms of the balance between, for example, the distributive evenness of raw water and air and the easiness of module production and the number of hollow fiber membranes that can be filled into the module. More preferably, 4 to 6 raw-water supply branching 25 portions are provided. The plurality of raw-water supply branching portions may be branched at equal angles. However, the raw-water supply branching portions may be branched at slightly different angles.
30 For example, a part of the raw-water supply branching portions to which the permeated water communication portion is attached may be branched at a larger angle. The hollow fiber membranes are arranged between the 5 raw-water supply branching portions (see Fig. 2(2)). Furthermore, if a straight pipe is used in the module case as a communication pipe, the communication pipes are also arranged between the raw-water supply branching portions. A method for producing the raw 10 water supply branching portion 33 will be described below. [0039] The raw-water introduction hole 32 is drilled continuously from the raw-water supply branching 15 portion 33 to an inner end surface 31 of the adhesive fixing portion 27. Raw water is fed to the interior 23 of the module through the raw-water introduction hole 32. The raw-water introduction hole 32 may be drilled all over the inner end surface 31 of the raw-water 20 supply branching portion 33. However, the raw-water introduction hole 32 is desirably formed as a set of a plurality of holes in order to facilitate the production of the raw-water supply branching portion and to allow raw water to be evenly distributed. If 25 the raw-water introduction hole 32 is formed as a plurality of holes, the sum of the equivalent diameters of the plurality of raw-water introduction holes is smaller than the sum of the equivalent diameters of the 31 plurality of raw-water supply branching portions in the direction of the length of the module. Here, a method for calculating the equivalent diameter of the raw water supply branching portion will be described with 5 reference to Fig. 26(3). The equivalent diameter De(a) of the raw-water supply branching portion 33 is determined by multiplying the sectional area Si by 4 and dividing the product by the inner circumferential side length Li (thick line portion), as shown in: 10 De(a) = 4 x Si/Li. [0040] Furthermore, it is assumed that (m) raw-water introduction holes dl, d2, d3, ... dm with different cross sections and different immersion side lengths are 15 drilled in each of the (n) raw-water supply branching portions corresponding to the respective branching directions. When the opening sectional areas and immersion side lengths of the raw-water introduction holes are defined as s1, s2, s3, ... sm and al, a2, 20 a3, ... , am, the sum De(b) of the equivalent diameters of the holes is determined by: De = n x 4 x {(sl/al)+(s2/a2)+(s3/a3)+...+(sm/am)}. A specific description will be given with reference to Fig. 26(1). If three types of holes dl, 25 d2, and d3 are drilled at the respective positions in each of the four raw-water supply branching portions corresponding to the respective branching directions, when the opening sectional areas and immersion side 32 lengths of the raw-water introduction holes dl, d2, and d3 are defined as sl, s2, and s3 and al, a2, and a3, the sum De(b) of the equivalent diameters of a total of 12 holes is determined by: 5 De(b) = 4 x 4 x {(sl/al)+(s2/a2)+(s3/a3)}. [0041] Each of the holes may be shaped like a circle, an ellipse, a semicircle, a rectangle, or the like but is preferably circular in order to facilitate 10 the formation of the holes. Although depending on the amount of water supplied and the number of holes, the pore diameter of the raw-water introduction hole is preferably 5 to 12 mm. Moreover, the pore diameter is preferably such that in a cross section of the module 15 perpendicular to the length direction thereof, the equivalent diameter of the raw-water introduction hole increases consistently with the distance from the center of the module with respect to the outer circumference thereof. This preferably allows raw 20 water or the like to be more evenly introduced into the module. In this case, with the distribution of raw water kept even, the above-described acute angle can be set closer to 90 degrees. This enables a reduction in the required length of the adhesive fixing potion 27 in 25 the length direction of the module. Here, the equivalent diameter of the raw-water introduction hole can be increased consistently with the distance from the center of the module with respect to the outer 33 circumference thereof as follows. The introduction holes may be arranged such that the pore diameter itself increases sequentially with decreasing distance to the outside of the module. Alternatively, the 5 portion between the center and the outer circumference may be divided into two or three areas, a plurality of holes with different inner sectional areas may be drilled in each of the resulting areas, and the sum of the equivalent diameters or sectional areas in each of 10 the areas is increased from the center toward the outer circumference. Alternatively, the raw-fluid branching portion may be divided into a central side and an outer side at the position of a half diameter in the outward direction from the center so that the sum of the 15 equivalent diameters of the raw-fluid introduction holes formed in the outer side is larger than that of the equivalent diameters of the raw-fluid introduction holes formed in the central side. [00421 20 Furthermore, the intervals between the holes may be equal or different depending on the position of the hole. However, if the outer circumference-side holes have a larger pore diameter, the intervals are preferably equal in order to facilitate the formation 25 of the holes. On the contrary, the pore diameter may be set constant with the interval decreasing consistently with the distance to the outer circumference. Furthermore, the raw-water introduction 34 holes may be arranged on the inner end surface 31 in a line or staggeredly with respect to the respective raw water supply branching portions. Alternatively, the raw-water introduction holes may be arranged in two or 5 more rows. Furthermore, the introduction holes may be open perpendicularly or obliquely to the inner end surface of the raw-water supply branching portion. [0043] Fig. 2(2) shows a diagram of a cross section 10 A-A' of the hollow fiber membrane module in Fig. 1 as viewed from above (in the direction of the arrow in the Fig. 1). Four raw-water supply branching portions are arranged in the cylindrical module case 21 in cross form such that the angle between the adjacent raw-water 15 supply branching portions is set to 90 degrees. A plurality of the raw water introduction holes 32 are arranged on the module inner end surface 31 of each raw-water supply branching portion in a line. Furthermore, the equivalent diameter of the raw-water 20 introduction hole increases consistently with the distance from the center of the module cross section toward the outer circumference thereof. [0044] Additionally, large numbers of the hollow 25 fiber membranes 24 and the communication pipes 25 are arranged between the four raw-water supply branching portions. That is, the raw-water introduction holes are drilled in the clearance between the hollow fiber 35 membranes. If the communication pipes are also arranged between the raw-water supply branching portions, the raw-water introduction holes are also drilled in the clearance between the communication 5 pipes. Thus, in the module cross section, the raw water introduction holes 32, through which raw water is fed, are arranged appropriately separately from the hollow fiber membranes 24 and the communication pipes 25. The cross section in Fig. 1 is as viewed from a 10 cross section B-B' in Fig. 2(2). [0045] The hollow fiber membrane module constructed as described above allows raw water or compressed air to be evenly fed with a small pressure drop. This is 15 because the size of a space extending to the raw-water introduction hole is maximized to allow raw water to be fed without an increase in supply loss and the pore diameter of the raw-water introduction hole is reduced to a predetermined value to impose a small pressure 20 drop to allow raw water to be evenly fed into the module. Furthermore, preferably, the supply flow of raw water or compressed air from the raw-water introduction hole into the module is substantially parallel to the length direction of the hollow fiber 25 membrane. This allows a reduction in the load of a water flow or the like on the hollow fiber membrane. The "substantially parallel" as used herein refers to the distributive feeding of raw water or compressed air 36 to the hollow fiber membranes at an angle of less than 45 degrees. [00461 The hollow fiber membrane module is formed 5 into a hollow fiber membrane module assembly by attaching a predetermined cap to the outside of the end surface of each of the opposite ends of the module in a liquid-tight manner. The outer end surface of the side of the hollow fiber membrane module on which the raw 10 water distributive supply portion is provided forms a cup shape with the raw-water supply port. A first cup with a permeated water holding space is mounted inside the cup shape. In Fig. 1, a cap 50 positioned at the lower end of the hollow fiber membrane module 20 15 corresponds to the first cap. The cap 50 is mainly composed of a cup 41 having a curved surface which covers the lower end surface 29 of the hollow fiber membrane module and which is tapered downward. An 0 ring 25 and a groove therefor are formed in a 20 circumferential end surface of the cup 41 which contacts the lower end surface 29. Thus, the cap 50 is coupled to the hollow fiber membrane module in a liquid-tight manner. [0047] 25 Furthermore, a raw-water supply port 43 is open at the bottom of the center of the cup 41. A nozzle 42 extending continuously from the raw-water supply port 43 projects into the inner space of the cup 37 41. The nozzle 42 is coupled to the supply source pipe portion 34 of the hollow fiber membrane module in a liquid-tight manner. The inner space of the cup 41 surrounded by the cup 41, the nozzle 42, and the lower 5 end surface 29 serves as a permeated water holding chamber 44. Mounting of such a cap allows raw water to be fed into the module with a reduced pressure drop, and further enables the utilization efficiency of the hollow fiber membrane to be kept high. 10 [0048] A specific example of the first cap is shown in Fig. 5. Fig. 5(1) is a top view. Fig. 5(2) is a front view. Fig. 5(3) is a sectional view taken along line G-G'. Fig. 5(4) is a bottom view. The cap in 15 Fig. 5 includes a disc 41 shaped like a shallow cup or deep dish with a central recess (hereinafter simply referred to as a cup-shaped disc), a thick ring portion 45 provided all along the outer circumference of the disc 41, and a groove 46 formed in the circumferential 20 end side of the ring portion so as to hold an 0 ring fixing the cap to the outer end surface of the module in a light-tight manner. Furthermore, a relatively short pipe 48 is provided in the center of the disc 41 and has a flange 40 around the outer circumference of 25 the end thereof. The pipe 48 is provided on the protruding surface side of the disc 41 so as to form the raw-water supply port 43. On the recessed surface side corresponding to the inside of the disc 41, the 38 nozzle 42 projects, and the raw-water supply port 43 extends continuously to the tip of the nozzle in a liquid-tight manner. When the hollow fiber membrane module assembly is constructed, the space in the 5 recessed surface of the disc 41 forms a permeated water holding chamber between the recessed surface and the outer end surface of the hollow fiber membrane module. [0049] Furthermore, Fig. 6 shows an example of a 10 first cap with different shape. In this cap, a pipe 48' forming a raw-water supply port is longer than that in the example in Fig. 5. Moreover, instead of the flange, an antislip groove is formed in the outer circumference of the vicinity of a lower end 40' of the 15 pipe. The first cap needs to provide two functions. First, the first cap needs to allow raw water to be fed to the supply source pipe portion of the hollow fiber membrane module through the raw water supply port via the nozzle in a liquid-tight manner. Second, the first 20 cap needs to allow the permeated water holding chamber to be formed between the cap and the lower end surface of the hollow fiber membrane module in a liquid-tight manner. Provided that the two functions are fulfilled, the first cap is not limited to the shapes in Figs. 5 25 and 6. [0050] An example of a second cap corresponds to a cap 10 coupled to the upper end surface of the hollow 39 fiber membrane module 20 via an 0 ring 15 as shown in Fig. 1. The cap 10 has a permeated water sampling port 13 provided in the center thereof and having a flange 11 at the outer circumferential end thereof. The 5 permeated water sampling port 13 is continuous with an intra-cap space 14. [0051] The above-described 0 rings may be used to couple the outer circumferential end of the first or 10 second cap and the outer end surface of the hollow fiber membrane module together in a liquid-tight manner and to couple the nozzle of the first cap and the supply source pipe portion of the hollow fiber membrane module together in a liquid-tight manner. However, it 15 is possible to use a sealing scheme based on a packing or adhesion based on application of an adhesive. In the example in Fig. 1, a metal cap tightening jig 52 is used to removably fix the second cap to the lower end surface 29 of the hollow fiber membrane module. 20 Furthermore, a similar jig 51 is used to fix the first cap to the upper end surface of the module. [0052] The caps may be made of metal such as stainless steel or aluminum alloy or a polymer 25 material. If the caps are made of metal, for example, stainless steel, the caps may be produced by machining but are desirably made by casting, particularly, a precision casting method such as lost wax or MIM 40 because this allows part accuracy to be improved. Furthermore, if the caps are made of a polymer material, the caps are desirably produced by an injection molding method in order to ensure part 5 accuracy. Examples of available polymer materials include polyolefins such as polyethylene, polypropylene, and polyethersulphone, polyvinyl chloride, polyester, polysulphone, polyethersulphone, polyphenylene, an ABS resin, and an AS resin. 10 [0053] The caps are used not only for the supply of raw water and the sampling of permeated water or the formation of the permeated water holding chamber but also for the supply of compressed air or raw water 15 mixed with compressed air, physical washing such as back washing or aeration, and drainage as is the case with the above-described raw-water distributive supply portion. The raw-water supply port in the first cap and the permeated water sampling port in the second cap 20 preferably include a joint that can be connected to a line to a membrane separation apparatus, for example, the flange in Fig. 5 or the groove formed near the lower end 40' as shown in Fig. 6. [0054] 25 Now, a liquid flow during normal filtration using the hollow fiber membrane module assembly in Fig. 1 will be described with reference to Fig. 7. First, raw water is fed from the raw-water supply port 43 in 41 the first cap 50 through the nozzle 42, the supply source pipe portion 34, the raw-water supply branching portion 33, and the raw-water introduction holes 32 to a space 23 surrounding the hollow fiber membranes 24 in 5 the module. The supplied raw water permeates the hollow fiber membrane 24 from the outer surface to inner surface thereof. The resulting permeated water moves through the upper and lower openings of the hollow portion of the hollow fiber membrane 24 to the 10 upper and lower intra-cap spaces 14 and 44, respectively. Then, the permeated water sampled from a relatively high portion of the hollow fiber membrane is sampled directly through the permeated water sampling port 13 via the second cap 10. However, the permeated 15 water having moved into the cap 50 through the lower opening is held in the permeated water holding chamber 44. The permeated water then moves to the internal space of the upper cap 10 via the communication pipe 25 through the lower opening thereof. The permeated water 20 is then sampled from the internal space. Furthermore, concentrated water resulting from removal of the permeated water from the raw water and air mixed in the raw water are discharged through the discharge port 22 on the side surface of the top of the module. 25 [0055] As described above, the permeated water is sampled from the opposite sides of the hollow fiber membrane 24. This levels off a pressure drop resulting 42 from the flow of the permeated water on the inner surface side of the hollow fiber membrane. Thus, the lower half of the hollow fiber membrane in the hollow fiber membrane module contributes more to filtration. 5 As a result, the treated flow rate per membrane area is leveled off with respect to the position of the membrane in the module. This eliminates the need to increase filtration pressure more than required, enabling a reduction in the liquid transfer pressure of 10 a raw water transfer pump used for pressurization. Therefore, power consumption per predetermined permeated water sample amount is reduced. [0056] Similarly, a liquid flow during back washing 15 using the hollow fiber membrane module assembly in Fig. 1 will be described with reference to Fig. 8. Part of the sampled permeated water is supplied through the permeated water sampling port 13 in the cap 10. Then, part of the supplied water is fed directly through the 20 upper opening of the hollow portion of the hollow fiber membrane 24 as back washing water. However, the remaining part is fed through the communication pipe 25 into the lower permeated water holding chamber 44 and then from the permeated water holding chamber 44 into 25 the hollow fiber membrane 24 through the lower opening thereof as back washing water. This levels off the pressure distribution in the hollow portion of the hollow fiber membrane, enhancing the back washing 43 effect in the lower part of the hollow fiber membrane. Washing effluent during the back washing may be discharged through the concentrated water discharge port 22 in the side surface of the upper portion or 5 only through the raw-water supply port 43 with the circulatory supply of permeated water to the lower part of the hollow fiber membrane via the communication pipe maintained as shown in Fig. 9. The washing effluent may be discharged through both the concentrated water 10 discharge port 22 and the raw-water supply port 43. [0057] During flushing, raw water is fed from the lower raw-water supply port 43 to the intra-module space 23 via the raw-water distributive supply portion. 15 Most of the raw water is discharged through the concentrated water discharge nozzle 22 to eject suspended substances from the module by a water flow at a high flow velocity. The suspended substances are deposited on the outer surface of the hollow fiber 20 membrane 24 and in the gap between the hollow fiber membranes. In aeration flushing, raw water mixed with compressive gas such as compressed air is introduced into the intra-module space 23 through the lower raw water supply port 43. With aeration performed to shake 25 the hollow fiber membrane 24, the raw water is discharged through the concentrated water discharge nozzle 22 together with suspended solutions. [0058] 44 Fig. 10 shows a liquid flow during aeration back washing using the hollow fiber membrane module assembly in Fig. 1. Permeated water is fed through the upper permeated water supply port 13 and subject to 5 back washing. Concurrently, compressed air is fed through the lower raw-water supply port 43. The water used for the back washing and the compressed air are discharged through the concentrated water discharge nozzle 22. At this time, the permeated water used for 10 the back washing exerts pressure on the inner surface side of the hollow fiber membrane 24. However, the hollow fiber membrane 24 is pressurized, via the communication pipe 25, through the openings in both the upper and lower end surfaces of the hollow fiber 15 membrane 24. Thus, the pressure exerted on the inner surface acts uniformly in both the upper and lower portions of the membrane. This enhances the effect of the aeration back washing. [0059] 20 Now, the formation of a permeated water communication portion using a module case that is an irregular-shaped double pipe will be described with reference to Fig. 11. In Fig. 1, at least one straight pipe is used as the communication pipe 25. However, in 25 the hollow fiber membrane module in Fig. 11, a module case that is an irregular-shaped double pipe is used in place of the straight pipe used as the communication pipe in Fig. 1. A part of the irregular-shaped portion 45 which has a reduced opening sectional area is used as a permeated water communication portion (hereinafter simply referred to as an irregular-shaped communication portion). The remaining part of the structure of the 5 hollow fiber membrane module in Fig. 11 is almost the same as that in Fig. 1. [0060] The "irregular-shaped double pipe" as used herein refers to a pipe having a cross section at right 10 angles to the length direction thereof which cross section is not shaped like such a circle as in the module case in Fig. 1 but is pre-divided into two portions using a structure in which the interior of the pipe is partitioned by a wall or in which at least two 15 pipes externally contact each other. The irregular shaped double pipe may have a plurality of irregular shaped communication portions. However, a single irregular-shaped communication portion can sufficiently provide the appropriate functions and is thus 20 preferable in view of the moldability of the pipe during extrusion. The hollow fiber membrane and the irregular-shaped communication portion are open in both the upper and lower adhesive fixing portions. Thus, permeated water can be passed downward or upward. 25 [0061] The raw-water distributive supply portion is adhesively fixed in the lower adhesive fixing portion in such a way as to be almost buried therein. Then 46 raw-water supply source pipe portion of the raw-water distributive supply portion is joined to the lower first cap in a liquid-tight manner. The liquid-tight junction may be based on a sealing method using a seal 5 part such as an 0 ring or adhesion based on application of an adhesive as in the case of Fig. 1. Fig. 11 shows an example using a liquid-tight seal based on an 0 ring. The upper and lower caps are fixed to the hollow fiber membrane module using clamps. 10 [0062] Now, a liquid flow during normal filtration using the hollow fiber membrane module assembly with the irregular-shaped double pipe will be described with reference to Fig. 11. Raw water is fed into the module 15 through the lower first cap. The supplied raw water permeates the hollow fiber membrane from the outer surface to inner surface thereof. The resulting permeated water moves through the upper and lower openings of the hollow portion of the hollow fiber 20 membrane to the upper and lower intra-cap spaces, respectively. Then, the permeated water sampled from the top of the hollow fiber membrane is obtained via the second cap. However, the permeated water having moved to the lower intra-cap space (permeated water 25 holding chamber) moves from the lower opening to upper opening of the irregular-shaped communication portion. The permeated water is then sampled from the upper cap. The water flow during back washing, aeration flushing, 47 or aeration back washing is similar to that shown in Fig. 1 except for functions of the permeated water communication portion, and will thus not described below. [0063] In the example of the structure of the hollow fiber membrane module in Fig. 11, the concentrated water holding chamber including the concentrated water nozzle from the side surface of which concentrated water is discharged is sealed, via an 0 ring, to the side surface of the outer pipe of the irregular-shaped double pipe. Specifically, a method described in Japanese Patent No. 3713343 can be used. However, when the module case is produced, the components may be sealably pre-fixed together in a liquid-tight manner by means of soldering or adhesion. Alternatively, the pipes may be joined together such that the communication portion includes the concentrated water holding portion. [0064] Now, a method of manufacturing a hollow fiber membrane module will be described focusing on a method of forming a raw-water distributive supply portion. The remaining part of the manufacture method is similar to that for conventional hollow fiber membrane modules. First, such a hollow element as shown in Fig. 3 is prepared. Fig. 3(1) is a top view of the hollow element. Fig. 3(2) is a sectional view of the hollow 48 element taken along line C-C' in Fig, 3(1), Fig. 3(3) is a front view of the hollow element. Fig. 3(4) is a sectional view of the hollow element taken along line D-D' in Fig. 3(3). Fig. 3(5) is a bottom view of the hollow element. The hollow element includes a pipe portion 35 serving as a supply source pipe portion, four hollow plates 37 and 38 arranged radially around the pipe portion 35, corresponding to a center axis, and at right angles to one another so as to form a cross (the hollow plates 37 and 38 serve as a raw-water supply branching portion), and a plurality of holes 32 formed in a line along the top surface of each of the hollow plates (the holes serve as raw-water introduction holes). Furthermore, a rib 39 is provided at the lower end of each of the hollow plates 37 and 38 for alignment (centering) in the module. Moreover, a bottom surface 30 of an internal void in the hollow plate is tapered at an acute angle 0 to the center axis. Although not shown in the drawings, a cross section taken along line E-E' is rectangular, A cross section closer to the tip (outer circumference side) of the rib 39 has a shorter vertical length. The lower end of the pipe portion 35 is sealed by a surface 36 so as to prevent an adhesive from entering the interior of the pipe portion 35 during adhesive fixation. An example of another hollow element is shown in Fig. 4. In this hollow element, the number of holes 32' (serving as raw-water introduction holes) formed in the top surface 49 is larger than that in the example in Fig. 3, The hole closest to the center of the hollow element in this example is closer to the center than that in the example in Fig. 3. [0065] A material for the hollow elements may be metal such as stainless steel or aluminum alloy but is preferably a polymer material in terms of the productivity and costs of the holding members. Specific examples of available materials include polyolefins such as polyethylene, polypropylene, and polybutene, polyvinyl chloride, polyester, polysulphone, polyethersulphone, polyphenylene, an AS resin, and an ABS resin. When made of a polymer material, the hollow element is preferably a molding article produced by injection molding so as to increase the dimensional accuracy of the equivalent diameter of the raw-water introduction hole as well as the sealing accuracy of the 0 ring. In this case, the surface portion of the hollow element which is bonded with an adhesive is preferably textured in order to increase the adhesive strength with the adhesive. [0066] Using any of the hollow elements, the raw water distributive supply portion is formed as follows. A bundle of a large number of the hollow fiber membranes is inserted into the module case, and the communication pipe is inserted into the module case as 50 required. Moreover, the hollow element is inserted into the module case from the lower end side thereof so that the directions of the module case and the hollow element match. In this condition, an adhesive is filled into the module case through the opposite ends thereof and solidified. At this time, the amount of adhesive provided through the end side from which the hollow element has been inserted is adjustably reduced so as not to block the holes 32 in the hollow element. Once the adhesive is solidified, each of the opposite ends is cut at an appropriate position so as to form a surface at right angles to the length direction of the module. Thus, the hollow portions of each of the hollow fiber membranes, the communication pipe, and the pipe portion 35 are opened to form a supply source pipe portion of a raw-water distributive supply portion. A hollow fiber membrane module is thus obtained. [0067] According to the present manufacture method, the top plane 31 of the hollow element corresponds to the inner end surface 31 of the adhesive fixing portion 27 of the hollow fiber membrane module. The height of the top plane 31 is different from that of an inner end surface 28 formed by the solidified adhesive. [00681 On the other hand, in a second method described below, the height of the top plane 31 of the hollow element may be set the same as that of the inner 51 end surface 28 of the adhesive. In this method, the top plane 31 is flush with the inner end surface 28 of the adhesive. This advantageously eliminates a possible dead space. The manufacture method allowing the top plane 31 and the inner end surface 28 to be set at the same height will be described below with reference to Fig. 12. [0069] The inner end surface 28 of the adhesive and the inner end surface 31 may be set at the same height, for example, as follows. First, a liquid such as water, hot water, or an organic solvent is prepared which does not affect the member making up the hollow fiber membrane module assembly. A material that can be easily dissolved into or easily absorbed and dispersed in the liquid is used to mold plug parts 60 temporarily blocking the raw-water introduction holes. Then, as shown in Fig. 12(2), the molded plug parts 60 are inserted into the raw-water introduction holes in the hollow element shown in Fig. 12(1) and which are similar to those described above, to temporarily block the holes. At this time, the plug parts are inserted such that the height of the plug parts projecting from the top surface of the hollow element is larger than that of a surface corresponding to the adhesive fixing portion. [0070] The hollow element in this condition is 52 housed at a predetermined position in the module case 21 together with the hollow fiber membranes as well as the communication pipe as required. The adhesive 27 is filled and solidified for adhesive fixation so that the whole hollow element is buried in the adhesive 27 but not the top of each of the plug parts 60, as shown in Fig. 12(3). Once the adhesive on the inner end surface is solidified, the end of the module case is cut along a cutting line to open the bottom of the hollow element as well as the hollow fiber membranes and the communication pipe. Here, description will be given below of an example of a method of preventing the top of each of the plug parts 60 from being buried under the inner end surface of the adhesive fixing portion. [0071] A module case having a lower header to which a discharge port 22 similar to that of an upper header is attached is used to arrange the plug parts 60 inside the discharge port 22. Then, centrifugal adhesion is performed to adhesively fix the hollow portion with an unwanted part of a liquid thermosetting resin removed through the discharge port 22. Thus, the hollow fiber membrane module can be produced so as not to bury the plug parts 60. [0072] Then, as shown in Fig. 12(4), a lower cap 50 is mounted in the hollow fiber membrane module. Furthermore, the upper cap is similarly mounted to form 53 a hollow fiber membrane module assembly. Then, as shown in Fig. 12(5), the liquid 43 such as water, hot water, or an organic solvent which has been prepared as described above is fed into the module through the raw water supply port in the lower cap. The plug parts blocking the raw-water introduction holes are dissolved into or absorbed and dispersed in the liquid and thus disappear. The present method prevents the formation of a step between the inner end surface of the adhesive and the inner end surface of the adhesive fixing portion. Thus, a proper hollow fiber membrane module or an assembly thereof are obtained which have no dead space. [0073] The following are examples of materials that are dissolved into or absorbed and dispersed in the liquid such as water, hot water, or an organic solvent without exerting an adverse effect such as dissolution on the hollow fiber membranes and other components of the hollow fiber membrane module assembly: polysaccharides and celluloses such as starch, cellulose acetate, and ethylcellulose, and a mixture thereof, and carbonates, hydrogen carbonates, phosphates, and acetates of sodium and potassium. To form the hollow element using polysaccharide or cellulose, the material is desirably mixed with carboxycellulose or the like which serves as a binder. When carbonate or the like is used, it is desirable to 54 thermally dissolve and pour salt into a cast or to pack the material into a wet condition and then dry and solidify the material. [0074] Moreover, not only any of the above-described materials may be used to form the plug parts but also the following is possible. Only a pipe portion of the hollow element which corresponds to the raw-water supply source pipe portion is formed of metal or a polymer material. The raw-water supply branching portion is formed using a dissolvable material. Then, the raw-water supply source pipe portion and the raw water supply branching portion are assembled together to form a raw-water distributive supply portion. Alternatively, the whole hollow element forming the raw-water distributive supply portion may be formed using any of the above-described materials. Alternatively, the plug parts may be pre-inserted into the hollow element. Any of these methods provides a suitable hollow fiber membrane module with a reduced pressure drop. The raw fluid used in the present invention is preferably water. Preferably, the product of the turbidity and TOC (Total Organic Carbon) of the raw water is 100,000 degrees x mg/liter or less. The raw water preferably has a turbidity of 100 degrees or less and a TOC of 100 mg/liter or less. Examples 55 [0075] Now, the present invention will be described with reference to experiment examples, examples, and comparative examples. Comparison of performance with 5 conventional hollow fiber membrane module assemblies was performed using a multi-sequence evaluation apparatus having independent raw-water supply pumps and independent back washing supply pumps and a common raw water tank and a permeated water tank (also used as a 10 back washing tank). The evaluation apparatus uses an inverter to control the raw-water supply pumps for the multiple sequences and allows power consumption to be monitored. Furthermore, river surface stream water was used as raw water except for Example 4 and Comparative 15 Example 3 (In Example 4 and Comparative Example 3, evaluation was performed based on a closed line using a model liquid). The turbidity and TOC of the raw water were measured by the following method. 20 Turbidity: UV-160A, 50-mm cell manufactured by Shimadzu Corporation was used as a measurement apparatus to measure the turbidity in conformity with JIS K0101 9.2. (For a turbidity of 50 degrees or more, the raw water was diluted with water). 25 TOC: TOC-5000A manufactured by Shimadzu Corporation was used as a measurement apparatus to measure TOC in conformity with JIS K0101 20.1. [00761 56 [Experiment Example 1] First, experiments were carried out on the appropriate bore diameters of the raw-water introduction holes and the positions and number of the 5 holes. As shown in Fig. 13(1), a pipe 72 made of polyvinyl chloride was prepared which had six circular holes 73 of 5 mm formed in a side surface thereof in a line at intervals of 10 mm and having a nominal diameter of 20 mm (outer diameter: 26 mm; approximate 10 inner diameter: 20 mm) in conformity with JIS K6742. An end cap 71 was attached to one end of the pipe 72, and a tee 74 was attached to the other end thereof. Thus, a test part was prepared. A pressure gauge was attached to a right-angle branch of the tee, and a 15 joint was attached to another branch so as to allow water or compressed air to be supplied (this construction is hereinafter collectively referred to as a supply pipe). The supply pipe was used to supply 27 [L/min] of water under atmospheric pressure. Then, 20 water was uniformly discharged from the holes. At this time, to allow 27 [L/min] of water to be supplied, a water supply pressure of 19 [KPa] measured by the pressure gauge was required. Then, the same supply pipe was used to supply 1.2 [Nm 3 /Hr] of compressed air 25 of pressure 200 [KPa] at a water depth of about 30 cm. Then, air was uniformly discharged from all the holes. [0077] [Experiment Example 2] 57 A polyvinyl chloride pipe of nominal diameter 20 mm as shown in Fig. 13(2) was prepared which was similar to that in Experiment Example 1 except that the pipe had circular holes of diameter 5.5 mm, 6.0 mm, 6.5 5 mm, and 7.0 mm, respectively, formed in a side surface thereof at intervals of 15 mm. The pipe was used to supply 27 [L/min] of water under atmospheric pressure. Then, water was uniformly discharged from the holes. At this time, to allow 27 [L/min] of water to be 10 supplied, a water supply pressure of 17 [KPa] measured by the pressure gauge was required. Then, the same supply pipe was used to supply 1.2 [Nm 3 /Hr] of compressed air of pressure 200 [KPa] at a water depth of about 30 cm. Then, air was uniformly discharged 15 from all the holes. [0078] [Experiment Example 3] Such a supply pipe as shown in Fig. 13(3) was prepared which had the same circular hole diameter and 20 opening interval as those in Experiment Example 1 but had a nominal pipe diameter of 13 mm (outer diameter: 18 mm; approximate inner diameter: 13 mm). Water and compressed air were supplied as in the case of Experiment Example 1. Then, water was uniformly 25 supplied, and the required supply pressure was 25 [KPa]. However, for the air supply, air sometimes failed to be discharged from the hole located farthest from the tee.
58 [0079] [Experiment Example 4] Such a supply pipe as shown in Fig. 13(4) was prepared which had the same circular hole diameter and 5 opening interval as those in Experiment Example 2 but had a nominal pipe diameter of 13 mm. Water and compressed air were supplied as in the case of Experiment Example 1. Then, water was uniformly supplied, and the required supply pressure was 23 10 [KPa]. However, for the air supply, air sometimes failed to be discharged from the hole located farthest from the tee. [00801 [Experiment Example 5] 15 A hollow element (which was made of polyvinyl chloride) was produced which was similar to that shown in Fig. 3 except that the bottom surface 36 was open. A tee was attached to the pipe portion 35. Moreover, a pressure gauge was attached to the tee, and a joint was 20 attached to the tee so as to allow water or compressed air to be supplied. In the hollow element, the pipe portion 35 was a straight pipe of inner diameter 26 mm. Furthermore, four hollow plates were combined together in cross form. Circular holes 32 of diameter 5.5 mm, 25 6.0 mm, 6.5 mm, and 7.0 mm were formed in the top surface 31 of each of the hollow plates so as to lie in this order from the center of the hollow element at intervals of 15 mm. Furthermore, the hollow portion 59 inside the hollow plates appeared rectangular in a sectional view taken along line E-E'. The equivalent diameter and opening sectional area of the hollow portion were about 20 mm and 610 mm 2 in a rectangular 5 cross section closest to the center axis and about 13 mm and 200 mm 2 at a terminal farthest from the center axis. [00811 The hollow element was used to supply 5 10 [m 3 /Hr] of water under atmospheric pressure. Then, water was uniformly discharged from all the holes. At this time, to allow 5.0 [m 3 /Hrl of water to be supplied, a water supply pressure of 4 [KPa] measured by the pressure gauge was required. Then, the same hollow 15 element was used to supply 7 [Nm 2 /Hr] of compressed air of pressure 200 [KPa] at a water depth of about 50 cm. Then, air was uniformly discharged from all the holes. Additionally, even when the flow rate of compressed air was reduced to 5 [Nm 3 /Hr] or 3 [Nm 3 /Hr], air was 20 similarly uniformly discharged. [0082] [Experiment Example 6] A hollow element (which was made of polyvinyl chloride) was produced which was similar to that shown 25 in Fig. 4 except that the bottom surface of the pipe portion was open. A tee was attached to the pipe portion. A pressure gauge was attached to the tee. A joint was also attached to the tee so as to allow water 60 or compressed air to be supplied. The pipe portion of the hollow element was a straight pipe of inner diameter 26 mm. Furthermore, the hollow plates were shaped like a cross. Six circular holes 32 of diameter 5 5 mm were formed in a top surface 31' of each of the hollow plates at intervals of 10 mm. Furthermore, as in the case of the member shown in Fig. 3, the hollow portion inside the hollow plates was a void having a rectangular cross section in the direction E-E'. The 10 equivalent diameter and opening sectional area of the hollow portion were about 22 mm and 600 mm 2 on the central side and about 13 mm and 200 mm 2 at the outer circumferential terminal. [00831 15 The raw-water distributive supply portion was used to supply 4.8 [m 3 /Hr] of water under atmospheric pressure. Then, water was uniformly discharged from all the holes. At this time, to allow 4.8 [m 3 /Hr] of water to be supplied, a water supply pressure of 3 20 [KPa] measured by the pressure gauge was required. Then, the same raw-water distributive supply portion was used to supply 5 [Nm 2 /Hrl of compressed air of pressure 200 [KPa] at a water depth of about 50 cm. Then, air was uniformly discharged from all the holes. 25 Additionally, even when the flow rate of compressed air was reduced to 3 [Nm 3 /Hr], air was similarly uniformly discharged. [0084] 61 [Experiment Example 71 Such an element 80 as shown in Fig. 14 was prepared which had an air introduction structure similar to that shown in Fig. 5 of JP-U-63-111901. In 5 Experiment Example 7, the air introduction structure in JP-U-63-111901 was used as raw water and an air introduction element. The element 80 had four raw water introduction plates 82 and 83 combined together at right angles to one another, raw-water introduction 10 passages 84 and 86 that are pipe-like voids drilled in the raw-water introduction plates so as to extend at right angles to one another, and an outer ring 81 forming a slit through which raw water is passed from a pipe portion 87 to the raw-water introduction passage. 15 A tee was attached to the pipe portion 87. A pressure gauge was attached to the tee. A joint was also attached to the tee so as to allow water or compressed air to be supplied. In the element 80, the outer ring 81 had an inner diameter of 149 mm, and the slit had a 20 width of 3 mm. Furthermore, the raw-water introduction passage had a diameter of 8 mm. [0085] A holding chamber for holding permeated water and otherwise provided under an adhesive fixing portion 25 85 was unnecessary in Experiment Example 7 and was thus omitted. [0086] The element was used to supply 3.3 [m 3 /Hr] of 62 water under atmospheric pressure. Then, water was uniformly discharged from the four introduction holes. At this time, 7.2 [KPa] of supply pressure was determined to be required to supply 3.3 [m 3 /Hr] of 5 water. To allow about 5 [m 3 /Hr] of water to be discharged as in the case of Experiment Examples 5 and 6, an excessive supply pressure of about 150 to 165 [KPa] was expected to be required. Thus, further water supply experiments were suspended. When the supply 10 pressure was set to 4 [KPa] as in the case of Experiment Examples 5 and 6, the supply flow rate was 0.8 [m 3 /Hr]. No water was discharged from one of the four holes. Furthermore, the same element was used to supply 5 [Nm 2 /Hr] of compressed air of pressure 200 15 [KPa] at a water depth of about 50 cm. Then, air was uniformly discharged from all the holes. Additionally, even when the flow rate of compressed air was reduced to 3 [Nm 3 /Hr], air was similarly uniformly discharged. [00871 20 [Experiment Example 8] Such an element 130 as shown in Fig. 20 was prepared which had an air introduction structure similar to that shown in Figs. 2 and 3 of JP-U-03 119424. In Experiment Example 8, the air introduction 25 structure in JP-U-03-119424 was used as raw water and an air introduction element. The element 130 had six holes each of diameter 10.5 mm drilled, at intervals of 120 degrees, along a circumference in an adhesive 63 fixing portion 133 which is located at the position of a diameter of 96 mm from the center. A second cap was fastened to the lower end surface of the element 130 via an 0 ring using a cap fastening jig 132. A tee 5 with a flange was attached to a flange portion 134 at the second cap end. Moreover, a pressure gauge was attached to the tee. A joint was also attached to the tee so as to allow water or compressed air to be supplied. Here, the water or compressed air was fed 10 from the flange portion 134 into the second cap via the raw-water supply port and then flow into the module via the raw-water introduction passage 131. [0088] A holding chamber holding permeated water and 15 otherwise provided in an adhesive fixing portion 133 was unnecessary in Experiment Example 8 and was thus omitted. [0089] The element was used to supply 4.8 [m 3 /Hrl of 20 water under atmospheric pressure. Then, water was uniformly discharged from the six introduction holes. At this time, the pressure required for the supply was low, 5 [kPa], as in the case of Experiment Examples 5 and 6. Then, the element 130 was used to supply 7 25 [Nm 3 /Hr] of compressed air of pressure 200 [KPa] at a water depth of about 50 cm. Then, air was uniformly discharged from all the holes, but sometimes failed to be discharged from some of the holes. Additionally, 64 when the flow rate of compressed air was reduced to 5 [Nm /Hr], air failed to be discharged from a significantly large number of holes. When the flow rate of compressed air was reduced to 3 [Nr 3 /Hr], no air was discharged from some of the holes. [0090] [Example 1] Six thousand hollow fiber precision membranes as described in Example 3 of W002/070115 were prepared. The openings at the opposite ends of each of the membranes were sealed to form a bundle. Furthermore, two polyvinyl chloride pipes were prepared which had an outer diameter of 22 mm, an approximate inner diameter of 16 mm, and the same length as that of each of the hollow fiber membranes. The pipes were used as communication pipes. The hollow fiber membrane bundle and the two pipes were housed at a time in a module case made up of a cylindrical pipe with an outer diameter of 165 mm and an approximate inner diameter of 153 mm. The module case was made of an ABS resin. Then, the hollow element shown in Fig. 3 and which was the same as that used in Experiment Example 5 was inserted into the vicinity of one end of the module case, with the other end remaining intact. An adhesion jig for centrifugal casting was attached to each of the opposite ends. [0091] Then, centrifugal casting was performed to 65 adhesively fix together the hollow fiber membranes, the hollow element, and the module case on one side and the hollow fiber membranes, the pipe, and the module case on the other side by means of filling of a two component urethane resin. At this time, the amount of resin filled was adjusted so as not to block the holes in the top surface of the hollow element with the resin. After the resin was sufficiently cured, the opposite adhesion jigs were removed, and the opposite ends were cut at appropriate positions. This exposed, on one side, the end surface in which the hollow portions of the hollow fiber membranes, the communication pipe, and the supply source pipe portion of the raw-water distributive supply portion were open, and on the other side, the end surface in which the hollow portions of the hollow fiber membranes and the communication pipe were open. Thus, a hollow fiber membrane module was obtained. A first cap similar to that shown in Fig. 5 was attached to the former end surface via an 0 ring. Moreover, a metal cap fastening jig was installed on and fastened to the former end surface like a nut. Thus, the module end surface and the cap were sealed in a liquid-tight manner. Furthermore, a second cap similar to that shown in Fig. 1 was attached to the latter end surface via an O ring. A metal cap fastening jig was fastened to the latter end surface like a nut for liquid-tight sealing. Thus, a hollow fiber membrane module assembly was obtained.
66 [00921 In the hollow fiber membrane module assembly, the filling rate at which the hollow fiber membranes were filled into the module case (the ratio of the 5 outer diameter-based sectional area of the hollow fiber membranes to the intra-pipe sectional area excluding the outer diameter-based sectional area of the communication pipe) was 40%, outer surface-based membrane area was 46 M 2 , and effective membrane length 10 was 2 m. The water permeation performance of the hollow fiber membrane module was measured using, as raw water, ion-exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are 15 shown in Table 1. [0093] Then, the hollow fiber membrane module assembly was mounted in an evaluation apparatus. The hollow fiber membrane module assembly was then 20 evaluated for filtration stability using, as raw water, river surface stream water having a turbidity of 0.4 to 3.1 degrees, an average turbidity of 1.2 degrees, a TOC of 0.32 to 1.65 mg/L, and an average TOC of a 0.55 mg/L. First, filtration was performed at a set water 25 sample amount of 2.2 m/day {the set water sample amount (m/day) was determined by dividing filtration flow rate (m 3 /day) by extra-membrane surface area (m 2 ) } for 29 minutes. Then, aeration back washing was performed for 67 60 seconds. The back washing flow rate was the same as the set filtrate sample rate, 2.2 m/day (extra-membrane surface area-based value). The amount of air from the raw-water distributive supply portion at the bottom of 5 the module was 5 Nm 3 /Hr. This cycle was continued. Then, a low inter-membrane differential pressure of about 40 KPa was achieved for 10 days or longer, indicating a stable operation result. Since stable filtration was possible for 10 days or longer, the 10 cycle was continued with the set water sample amount and the back washing flow rate increased to 2.7 m/day. Then, in spite of an increase in inter-membrane differential pressure from 50 to 60 KPa, a stable operation was possible for further 10 days or longer. 15 Thereafter, the evaluation was suspended and then resumed with the set water sample amount and the back washing flow rate maintained at 2.7 m/day. Then, a stable operation was possible for further 10 days or longer with the inter-membrane differential pressure 20 maintained at 50 to 60 KPa. The results are shown in Fig. 15. [00941 [Example 2] Six thousand hollow fiber precision membranes 25 as described in Example 3 of W002/070115 were prepared and bundled. The openings at the opposite ends of each of the membranes were sealed. Then, an irregular shaped double pipe made of polyvinyl chloride was 68 prepared. The irregular-shaped double pipe was shaped like a cylinder having an outer diameter of 165 mm and an approximate inner diameter of 153 mm. The irregular-shaped double pipe contained a permeated water communication portion having a spindle-shaped opening with a cross section at right angles to the length direction which cross section has a major diameter of 56 mm and a minor diameter of 11 mm. A 6.5S ferule joint was provided on the outer circumference of each of the opposite ends of the double pipe. The hollow fiber membrane bundle was housed in the double pipe at a time. One hundred and twenty holes of diameter 6 mm were open in the side surface of a head portion at one end of the irregular shaped double pipe. The holes connect the exterior of the side surface to the space in which the hollow fiber membranes were housed. Furthermore, the same hollow element as that used in Experiment Example 6 was inserted into the other end. An adhesion jig for centrifugal casting was attached to each of the opposite ends. [0095] Then, centrifugal casting was performed to adhesively fix together the hollow fiber membranes and the module case on one side and the hollow fiber membranes, the module case, and the hollow element on the other side by means of filling and solidification of a two-component urethane resin. After the resin was 69 sufficiently cured, the opposite adhesion jigs were removed, and the opposite ends were cut at appropriate positions. This exposed, on one side, the end surface in which the hollow portions of the hollow fiber 5 membranes, the permeated water communication portion, and the supply source pipe portion were open, and on the other side, the end surface in which the hollow portions of the hollow fiber membranes and the permeated water communication portion were open. Thus, 10 a hollow fiber membrane module was obtained. The first cap shown in Fig. 6 was attached and clamped to one end of the hollow fiber membrane module via an 0 ring. Thus, the module end surface and the cap were sealed in a liquid-tight manner. Furthermore, a cap similar to 15 the cap 10 shown in Fig. 1 was attached and similarly clamped to the other end surface via an 0 ring. Besides this, the concentrated water holding chamber 12 shown in Fig. 11 and including the concentrated water discharge nozzle was fixed to the hollow fiber membrane 20 module via an 0 ring. Thus, a hollow fiber membrane module assembly was obtained. In the hollow fiber membrane module assembly, the filling rate of the hollow fiber membranes (the ratio of the outer diameter-based sectional area of the 25 hollow fiber membranes to the intra-pipe sectional area excluding the outer diameter-based sectional area of the communication pipe) was 40%, the outer surface based membrane area was 46 M 2 , and the effective 70 membrane length was 2 m. The permeated water communication portion, shaped like a spindle, had an inner sectional area of about 400 mm 2 . The water permeation performance of the hollow fiber membrane 5 module was measured using, as raw water, ion-exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are shown in Table 1. [00961 10 [Example 3] Fifty-eight hundred hollow fiber precision membranes as described in Example 1 of W007/043553 were prepared. The openings at the opposite ends of each of the membranes were sealed to form a bundle. A hollow 15 fiber membrane module was produced which had the same structure as that in Example 1 except for the type of the hollow fiber ultrafiltration membrane, the inner/outer diameter of the membrane, and the number of hollow fiber membranes filled. The first and second 20 caps were attached to the respective ends of the hollow fiber membrane module to form a hollow fiber membrane module assembly. [0097] In the hollow fiber membrane module assembly, 25 the filling rate at which the hollow fiber membranes were filled into the module case was 40%, the outer surface-based membrane area was 46 M 2 , and the effective membrane length was 2 m. The water permeation 71 performance of the hollow fiber membrane module was measured using, as raw water, ion-exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The 5 results are shown in Table 1. [0098] Then, the hollow fiber membrane module assembly was mounted in an evaluation apparatus. The hollow fiber membrane module assembly was then 10 evaluated for filtration stability using, as raw water, river surface stream water having a turbidity of 0.5 to 9.7 degrees, an average turbidity of 1.5 degrees, a TOC of 0.35 to 1.83 mg/L, and an average TOC of a 0.58 mg/L. First, filtration was performed at a set water 15 sample amount of 2.7 m/day {the set water sample amount (m/day) was determined by dividing the filtration flow rate (m 3 /day) by the extra-membrane surface area (m 2 ) for 29 minutes. Then, aeration back washing was performed for 60 seconds. The back washing flow rate 20 was the same as the set filtrate sample rate, 2.7 m/day (extra-membrane surface area-based value). The amount of air from the raw-water distributive supply portion at the bottom of the module was 5 Nm 3 /Hr. This cycle was continued. Then, a low inter-membrane differential 25 pressure of about 50 KPa was achieved for 20 days, indicating a stable operation result. Since stable filtration was possible for 20 days, the cycle was continued with the set water sample amount and the back 72 washing flow rate increased to 3.3 m/day. Then, in spite of an increase in inter-membrane differential pressure from 60 to 70 KPa, a stable operation was possible for further 20 days or longer. The results are shown in Fig. 18. [0099] [Example 4] Seventeen hundred hollow fiber precision membranes as described in Example 2 of W007/043553 were prepared. The openings at the opposite ends of each of the membranes were sealed to form a bundle. Furthermore, one polyvinyl chloride pipe was prepared which had an outer diameter of 18 mm, an approximate inner diameter of 13 mm, and the same length as that of each of the hollow fiber membranes. The opposite ends of the pipe were sealed. The pipe was used as a communication pipe. The hollow fiber membrane bundle and the pipe were housed at a time in a module case made up of a cylindrical pipe with an outer diameter of 89 mm and an approximate inner diameter of 83 mm. The module case was made of polyvinyl chloride. Then, the hollow element shown in Fig. 3 and which was the same as that used in Experiment Example 5 was inserted into the vicinity of one end of the module case (the size of the module case was different from that in Examples 1 and 3), with the other end remaining intact. An adhesion jig for centrifugal casting was attached to each of the opposite ends.
73 [0100] Then, centrifugal casting was performed to adhesively fix together the hollow fiber membranes, the pipe, the hollow element, and the module case on one side and the hollow fiber membranes, the pipe, and the module case on the other side by means of filling of a two-component urethane resin. At this time, a mixture of equal amounts (volume ratio) of commercially available paper clay and ethylcellulose was molded into cylindrical pieces, which were then inserted into the introduction holes. The cylindrical pieces were thus adhesively fixed. [0101] After the resin was sufficiently cured, the opposite adhesion jigs were removed, and the opposite ends were cut at appropriate positions. This exposed, on one side, the end surface in which the hollow portions of the hollow fiber membranes, the communication pipe, and the supply source pipe portion of the raw-water distributive supply portion were open, and on the other side, the end surface in which the hollow portions of the hollow fiber membranes and the communication pipe were open. Thus, a hollow fiber membrane module was obtained. A first cap similar to that shown in Fig. 5 was attached to the former end surface via an 0 ring. Moreover, a metal cap fastening jig was installed on and fastened to the former end surface like a nut. Thus, the module end surface and 74 the cap were sealed in a liquid-tight manner. Furthermore, a second cap similar to the cap 10 shown in Fig. 1 was attached to the latter end surface via an o ring. A metal cap fastening jig was similarly used 5 and fastened to the latter end surface like a nut for liquid-tight sealing. A 50-mass% ethanol water solution was filled into the resulting hollow fiber membrane module assembly through the concentrated water discharge nozzle. The hollow fiber membrane module 10 assembly was then left overnight to dissolve the ethylcellulose components of the molding articles made of the mixture of paper clay and ethylcellulose and blocking the introduction holes. After the hollow fiber membrane module assembly was left overnight, back 15 washing was performed using ion-exchanged water from the first cap side under a pressure of 100 KPa. Thus, remaining paper clay components were dispersed and discharged to ensure a raw-water supply path leading from the raw-water supply source pipe to the 20 introduction holes via the supply branching portion. [0102] In the hollow fiber membrane module assembly, the filling rate at which the hollow fiber membranes are filled in the module case (the ratio of the outer 25 diameter-based sectional area of the hollow fiber membranes to the intra-pipe sectional area excluding the outer diameter-based sectional area of the communication pipe) was 40%, the outer surface-based 75 membrane area was 13 m 2 , and the effective membrane length was 2 m. The water permeation performance of the hollow fiber membrane module was measured using, as raw water, ion-exchanged water allowed to permeate an 5 ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are shown in Table 1. [0103] Then, the hollow fiber membrane module 10 assembly was mounted in a laboratory evaluation apparatus (a closed evaluation apparatus that returns water overflowing a filtration tank and discharged water resulting from physical washing such as back washing, to a raw-water tank). A model liquid (a mixed 15 solution of a humic acid and bentonite {for preparation, humic acid concentration: 100 mg/liter in term of TOC, bentonite concentration: 100 degrees in terms turbidity}) was used as raw water. Since turbidity components and TOC components are captured in 20 the hollow fiber membrane bundle to reduce the turbidity of the raw water and the TOC concentration, the turbidity in the raw-water tank and the TOC were periodically measured. When each of the turbidity and the TOC became lower than 70% of the initial value 25 thereof, a humic acid component and/or bentonite was added to the raw water for evaluation. A set water sample amount of raw water was filtered at 2.8 m/day for nine minutes. Then, aeration back washing was 76 performed for 60 seconds. The back washing flow rate was the same as the set water sample amount, 2.8 m/day. The flow rate of air from the raw-water distributive supply portion at the bottom of the module was 1.5 Nin 3 /Hr. This cycle was continued. Then, a stable operation was achieved with an inter-membrane differential pressure of 40 to 60 KPa. The results are shown in Fig. 19. [0104] [Comparative Example 1] The method described in Example 1 was similarly carried out from the beginning through the adhesive fixing process except for the following. The number of hollow fiber precision filtration membranes filled was 6,300. For one side of the hollow fiber microfiltration membranes, sealing of the hollow portions of the membranes was avoided so that when the opposite ends of membranes were cut at the appropriate positions after solidification, the hollow portions were not open in the resulting cut surface. Instead of the hollow element, 24 hollow objects made of polyethylene and having an outer diameter of 11 mm as shown in Fig. 16 were arranged and adhesively fixed in the hollow fiber membrane bundle. No communication portion was provided. For the other side, the hollow portions of the hollow fiber membranes were sealed, and an adhesion jig was attached to the corresponding end. [0105] 77 Then, centrifugal casting was performed to adhesively fix together the hollow fiber membranes, the module case, and the hollow objects at one end of the module and the hollow fiber membranes and the module 5 case at the other end by means of filling and solidification of a two-component urethane resin. At this time, the amount of resin filled was adjusted so as not to bury the vicinity of the tip of each of the hollow objects in the resin. After the resin was 10 sufficiently cured, the opposite adhesion jigs were removed, and the opposite ends were cut at appropriate positions to expose the opening surfaces. Moreover, the 24 hollow objects were removed from the one end. Thus, one end had the end surface in which the hollow 15 portions of the hollow fiber membranes and the 24 raw water or air introduction ports for raw-water supply were open. The other end had the end surface in which the hollow portions of the hollow fiber membranes were open. Thus, a comparative module was obtained. A cap 20 similar to the second cap 10 shown in Fig. 1 was attached, via an 0 ring, to and fastened to each of the opposite ends of comparative module like a nut. Thus, a comparative module assembly was obtained. [01061 25 In the comparative module assembly, permeated water was sampled only from one side of the hollow fiber membranes. The filling rate of the hollow fiber membranes was 40%. The water permeation performance of 78 the comparative module assembly was measured using, as raw water, ion-exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are 5 shown in Table 1. [0107] The resulting comparative module assembly was mounted in the same evaluation apparatus as that in Example 1 and concurrently subjected to filtration 10 stability tests. First, filtration was performed at a set water sample amount of 2.2 m/day {the set water sample amount (m/day) was determined by dividing the filtration flow rate (m 3 /day) by the extra-membrane surface area (M 2 )} for 29 minutes. Then, aeration back 15 washing was performed for 60 seconds. The back washing flow rate was the same as the set filtrate sample rate, 2.2 m/day (extra-membrane surface area-based value). The amount of air from the raw-water and air introduction port at the bottom of the module was 5 20 Nm /Hr. This cycle was continued. Then, a stable operation was possible for 10 days or longer, but the required inter-membrane differential pressure was about 80 KPa, which is double the inter-membrane differential pressure in Example 1. In spite of the relatively high 25 inter-membrane differential pressure of about 80 KPa, the stable operation result was obtained. Thus, the cycle was continued again with the set water sample amount and the back washing flow rate increased to 2.7 79 m/day. Then, a stable operation was possible for 10 days or longer, but the required inter-membrane differential pressure was 80 to 100 KPa, which is 1.6 times as high as the inter-membrane differential 5 pressure in Example 1. [0108] The evaluation was suspended and then resumed with the set water sample amount and the back washing flow rate remaining at 2.7 m/day. A stable operation 10 was still possible for 10 days or longer. However, as in the case before the suspension, the inter-membrane differential pressure was 70 to 90 KPa, which is about 1.6 times as high as the inter-membrane differential pressure in Example 1. The results are shown in Fig. 15 15. [01091 Furthermore, when the set water sample amount was 2.2 m/D and power consumption in Comparative Example 1 was defined as 100, the power consumption in 20 Example 1 was 59. Additionally, when the set water sample amount was 2.7 m/D and the power consumption in Comparative Example 1 was defined as 100, the power consumption in Example 1 was 71. This means that in Example 1, at each set water sample amount, almost the 25 same amount of permeated water was successfully sampled with required power consumption accounting for 59 or 71% of that in the conventional art. [0110] 80 [Comparative Example 2] One polyvinyl chloride pipe was prepared which had an outer diameter of 32 mm, an approximate inner diameter of 25 mm, and a length of 2 m. The pipe 5 included a large number of circular holes drilled therein and having a diameter of 2 mm, and one side of the pipe was sealed. The pipe was used as a raw-water supply pipe. Furthermore, as in the case of Example 1, two polyvinyl chloride pipes were prepared which had an 10 outer diameter of 22 mm, an approximate inner diameter of 16 mm, and the same length as that of each hollow fiber membrane and both sides of which were sealed. The two pipes were used as communication pipes. The three pipes and fifty-six hundred hollow fiber 15 microfiltration membranes as described in Example 2 of WO07/043553, which were used in Example 3 were prepared, and the opposite ends of each of the membranes were sealed to form a bundle. The hollow fiber microfiltration membranes and the above-described 20 three pipes were assembled together to produce a hollow fiber membrane module as in the case of Examples 1 and 3. At this time, the pipe having an outer diameter of 32 mm and used as a raw-water supply pipe was located in the center of the module case. A first cap was 25 attached, via an 0 ring, to the end source in which the raw-water supply pipe of the hollow fiber membrane module was open. A second cap was attached, via an 0 ring, to the end source in which the raw-water supply 81 pipe of the hollow fiber membrane module was sealed. Each of the first and second caps was tightened using a metal fastening jig. Thus, a hollow fiber membrane module assembly in the present comparative example was 5 obtained. [0111] The comparative module assembly allowed permeated water to be sampled through the opposite ends of the hollow fiber membranes. However, raw water is 10 fed from the raw-water supply pipe through a countless number of holes open all along the longitudinal direction of each of the hollow fiber membranes, from the center to outer circumference of the bundle in a direction perpendicular to the hollow fiber membranes 15 and the hollow fiber membrane bundle. The filling rate of the hollow fiber membranes was 41%. As in the case of Example 3, the water permeation performance of the comparative module assembly was measured using, as raw water, ion 20 exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are shown in Table 1. [0112] Then, the comparative module assembly was 25 mounted in the same evaluation apparatus as that in Example 3 and concurrently subjected to filtration stability tests. First, filtration was performed at a set water sample amount of 2.7 m/day {the set water 82 sample amount (m/day) was determined by dividing the filtration flow rate (m 3 /day) by the extra-membrane surface area (m 2 ) } for 29 minutes. Then, aeration back washing was performed for 60 seconds. The back washing 5 flow rate was the same as the set filtrate sample rate, 2.7 m/day (extra-membrane surface area-based value). The amount of air from the raw-water and air introduction port at the bottom of the module was 5 Nm 3 /Hr. This cycle was continued. Then, the inter 10 membrane differential pressure was stable at 55 KPa during the first through fifth days of the evaluation but then started to increase. On the 20th day of the evaluation, the inter-membrane differential pressure increased up to 110 KPa. Thus, in Example 3, an 15 evaluation with a set water sample amount of 3.3 m/day was suspended. The comparative hollow fiber membrane module was disassembled and checked for accumulation of turbid components in the hollow fiber membrane bundle. Then, there were not many turbid components in the 20 outer circumferential portion of the hollow fiber membrane bundle. In contrast, many turbid components are closely deposited near the center of the bundle, corresponding to the raw-water supply side. [0113] 25 [Comparative Example 3] The method described in Example 4 was similarly carried out from the beginning through the adhesive fixing process except for the following. The 83 number of hollow fiber precision filtration membranes filled was 1,800. For one side of the hollow fiber microfiltration membranes, sealing of the hollow portions of the membranes was avoided so that when the opposite ends of membranes were cut at the appropriate positions after solidification, the hollow portions were not open in the resulting cut surface. Instead of the hollow element, 5 hollow objects made of polyethylene and having an outer diameter of 11 mm as shown in Fig. 16 were arranged and adhesively fixed in the hollow fiber membrane bundle. No communication portion was installed. For the other side, the hollow portions of the hollow fiber membranes were sealed, and an adhesion jig was attached to the corresponding end. [0114] Then, centrifugal casting was performed to adhesively fix together the hollow fiber membranes, the module case, and the hollow objects at one end of the module and the hollow fiber membranes and the module case at the other end by means of filling and solidification of a two-component urethane resin. At this time, the amount of resin filled was adjusted so as not to bury the vicinity of the tip of each of the hollow objects in the resin. After the resin was sufficiently cured, the opposite adhesion jigs were removed, and the opposite ends were cut at appropriate positions to expose the opening surfaces. Moreover, the 5 hollow objects were removed from the one end.
84 Thus, one end had the end surface in which the hollow portions of the hollow fiber membranes and the 5 raw water or air introduction ports for raw-water supply were open. The other end had the end surface in which 5 the hollow portions of the hollow fiber membranes were open. Thus, a comparative module was obtained. A cap similar to the second cap 10 shown in Fig. 1 was attached and fastened to each of the opposite ends of comparative module like a nut as in the case of Example 10 4. Thus, a comparative module assembly was obtained. [0115] In the comparative module assembly, permeated water was sampled only from one side of the hollow fiber membranes. The filling rate of the hollow fiber 15 membranes was 41%. The water permeation performance of the comparative module assembly was measured using, as raw water, ion-exchanged water allowed to permeate an ultrafiltration membrane module with a nominal molecular cutoff of 6,000 daltons. The results are 20 shown in Table 1. [0116] Then, the comparative module assembly was mounted in a laboratory evaluation apparatus concurrently with the hollow fiber membrane module 25 assembly in Example 4. A filtration stability evaluation operation was then performed. Then, a stable operation was possible with an inter-membrane differential pressure of 60 to 100 KPa. This indicates 85 the inter-membrane differential pressure during the filtration operation was 1.5 times higher than that in Example 4.
86 -H 41 a) LC) C) 0 W ( -P) CD _ C ______ (0- 1 04 (0 0 w a) 0 w) ( 004 (U ( (N~ U0) C) 04~ x LO) U) ~ U 5- 4 4- )( 13 4 (N -4 1L U1) 0 4 C r- 4-)1 U)1 ) 0 a) U):s Z4 rH ,-4 1 2 L4 44- 87 INDUSTRIAL APPLICABILITY [0118] The hollow fiber membrane module and the assembly thereof according to the present invention can be used in various fields but are particularly preferably used in the fields of water treatment such as clarification of river water, lake water, river-bed water, or the like. BRIEF DESCRIPTION OF THE DRAWINGS [0119) Fig. 1 is a schematic sectional view showing an example of the sectional structure of a hollow fiber membrane module assembly; Fig. 2(1) is a diagram illustrating a forward angle, and Fig. 2(2) is a sectional view of the hollow fiber membrane module taken along line A-A' in Fig. 2(1); Fig. 3(1) is a top view schematically showing an example of a hollow element, Fig. 3(2) is a sectional view schematically showing the example of the hollow element and taken along line C-C' in Fig. 3(1), Fig. 3(3) is a front view schematically showing the example of the hollow element, Fig. 3(4) is a sectional view schematically showing the example of the hollow element and taken along line D-D' in Fig. 3(3), and Fig. 3(5) is a bottom view schematically showing the example of the hollow element; 88 Fig. 4(1) is a top view schematically showing another example of the hollow element, Fig. 4(2) is a front view schematically showing the example of the hollow element, Fig. 4(3) is a sectional view schematically showing the example of the hollow element and taken along line F-F' in Fig. 4(1), and Fig. 4(4) is a bottom view schematically showing the example of the hollow element; Fig. 5(1) is a top view schematically showing an example of a first cap, Fig. 5(2) is a front view schematically showing the example of the first cap, Fig. 5(3) is a sectional view schematically showing the example of the first cap and taken along line G-G' in Fig. 5(1), and Fig. 5(4) is a bottom view schematically showing the example of the first cap; Fig. 6(1) is a top view schematically showing another example of a first cap, Fig. 6(2) is a front view schematically showing the example of the first cap, Fig. 6(3) is a sectional view schematically showing the example of the first cap and taken along line H-H' in Fig. 6(1), and Fig. 6(4) is a bottom view schematically showing the example of the first cap; Fig. 7 is a schematic diagram showing a liquid flow during normal filtration using the hollow fiber membrane module assembly; Fig. 8 is a schematic diagram showing a liquid flow during back washing using the hollow fiber membrane module assembly; 89 Fig. 9 is a schematic diagram showing a liquid flow in the case where raw water is discharged through a raw-water supply port 43 during back washing; Fig. 10 is a schematic diagram showing a 5 liquid flow during aeration back washing using the hollow fiber membrane module assembly; Fig. 11 is a schematic diagram showing a liquid flow during normal filtration in which an irregular-shaped double pipe is used as a module case; 10 Fig. 12 is a series of diagrams illustrating a manufacture method allowing the heights of a bonded end surface and an inner end surface to be set equal; Fig. 13 is schematic diagrams of test parts used in Experiment Examples 1 to 4; 15 Fig. 14 is a schematic diagram of an element 80 used in Experiment Example 7; Fig. 15 is a graph showing the results of filtration stability tests in Example 1 and Comparative Example 1; 20 Fig. 16 is a schematic diagram of a hollow object used in Comparative Example 1; Fig. 17 is a schematic sectional view showing the structure of a conventional, comparative module assembly; 25 Fig. 18 is a graph showing the results of filtration stability tests in Example 3 and Comparative Example 2; Fig. 19 is a graph showing the results of 90 filtration stability tests in Experiment Example 4 and Comparative Example 3; Fig. 20 is a schematic diagram of an element 130 used in Experiment Example 8; 5 Fig. 21 is a sectional view showing an example of an irregular-shaped double pipe; Fig. 22 is a sectional view showing an example of the irregular-shaped double pipe; Fig. 23 is a sectional view showing an 10 example of the irregular-shaped double pipe; Fig. 24 is a sectional view showing an example of the irregular-shaped double pipe; Fig. 25 is a sectional view showing an example of the irregular-shaped double pipe; and 15 Fig. 26 is a schematic diagram illustrating how the inner sectional area of a raw-water supply branching portion is increased as well as raw-water introduction holes, wherein Fig. 26(1) is a top view, Fig. 26(2) is a front view, Fig. 26(3) is a sectional 20 view taken along line J-J', and Fig. 26(4) is a sectional view taken along line K-K'. DESCRIPTION OF REFERENCE NUMERALS [0120] 1 Hollow fiber membrane module assembly 25 10 Second cap 11 Flange 12 Cup 91 13 Permeated water sampling port 14 Intra-cap space 15 0 ring 20 Hollow fiber membrane module 5 21 Module case 22 Concentrated water or air discharge port 23 Intra-module space 24 Hollow fiber membrane 25 Communication pipe 10 26 (Upper) adhesive fixing portion 27 (Lower) adhesive fixing portion 28 Bonded end surface 29 Outer end surface 30 Tapered surface 15 31, 31' Inner end surface or top surface of hollow plate 32, 32' Raw-water introduction hole 33 Raw-water supply branching portion 34 Space serving as supply source pipe portion 20 35 Pipe portion 36 Bottom surface 37, 38 Hollow plates 39 Centering rib 40 Flange 25 40' Lower end 41 Cup 42 Projecting portion joined to supply source pipe portion 92 43 Raw-water supply port 44 Permeated water holding chamber 45 Ring portion 46 0 ring groove 5 48, 48' Pipe 50 First cap 51, 52 Cap fastening jig 60 Plug part 70 Test part 10 71 End cap 72 Pipe 73 Circular hole 74 Tee 80 Element 15 81 Outer ring-like space 82, 83 Raw-water introduction plates 84, 86 Raw-water introduction passages 85 Adhesive fixing portion 87 Pipe portion 20 88 Raw-water supply port 90 Hollow object 100 Comparative module assembly 101, 103 Second caps 102 Comparative module 25 104 Module case 105 Hollow fiber membrane 106, 107 Adhesive fixing portions 108 Raw-water introduction hole 93 110 Raw-water supply port 111 Concentrated water or air discharge port 112 Permeated water sampling port 120, 121 Cap fastening jigs 5 130 Element 131 Raw-water introduction passage 132 Cap fastening jig 133 Adhesive fixing portion 134 Flange portion 10 135 Raw-water supply port 141 First portion in which hollow fiber membranes are placed 142 Second portion serving as permeated water communication portion
1. A hollow fiber membrane module including a cylindrical module case, a bundle of a large number of hollow fiber membranes housed in the module case, adhesive fixing portions fixing respective opposite ends of the bundle in the module case so as to allow a raw fluid to pass through the hollow fiber membranes, a permeated fluid communication portion connecting opposite outer end surfaces of the adhesive fixing portions together via a pipe with a larger equivalent diameter than each of the hollow fiber membranes, and a raw-fluid distributive supply portion located at one of the adhesive fixing portion to enable the raw fluid to be fed into the module case, wherein the raw-fluid distributive supply portion includes one supply source pipe portion drilled from a center of the outer end surface of the one of the adhesive fixing portions in a length direction of the module case and a raw-fluid supply branching portion evenly distributing the supplied raw fluid in a direction of a cross section of the hollow fiber membrane module, and has a plurality of raw-fluid introduction holes drilled in a gap between the hollow fiber membranes so as to enable the raw fluid to be fed along a longitudinal direction of the hollow fiber membranes.
2. The hollow fiber membrane module according to Claim 1, wherein a plurality of the raw-fluid supply branching portions following the supply source pipe 95 portion are drilled therein, each having an acute forward angle advancing from the supply source pipe portion along the length direction.
3. The hollow fiber membrane module according to Claim 2, wherein the raw-fluid distributive supply portion includes raw-fluid introduction holes drilled so as to follow the raw-fluid supply branching portions and extend to an inner end surface of the adhesive fixing portion, and a sectional area of the plurality of raw-fluid supply branching portions increases along a forward flow direction of the raw water.
4. The hollow fiber membrane module according to Claim 2 or 3, wherein the raw-fluid supply branching portions are plate-like voids substantially parallel to the length direction, and a plurality of the raw-fluid supply branching portions are radially arranged in the raw-fluid distributive supply portion around the supply source pipe portion serving as a substantial center axis.
5. The hollow fiber membrane module according to any one of Claims 2 to 4, wherein the plurality of raw fluid supply branching portions are 3 to 9 raw-fluid supply branching portions branching from the supply source pipe portion.
6. The hollow fiber membrane module according to any one of Claims 2 to 5, wherein a plurality of the raw-fluid introduction holes are formed in each of the raw-fluid supply branching portions, and a sum of 96 equivalent diameters of the plurality of raw-fluid introduction holes is smaller than a maximum equivalent diameter of the plurality of raw-fluid supply branching portions.
7. The hollow fiber membrane module according to any one of Claims 2 to 6, wherein when each of the raw fluid supply branching portions is divided into a central side and an outer side at a position of a half radius outward from the center of the raw-fluid supply branching portion, the sum of the equivalent diameters of the raw-fluid introduction holes formed in the outer-side division is larger than that of the raw fluid introduction holes formed in the central-side division.
8. The hollow fiber membrane module according to any one of Claims 2 to 7, wherein the plurality of raw fluid introduction holes are drilled at equal intervals.
9. The hollow fiber membrane module according to any one of Claims 2 to 8, wherein the equivalent diameter of the raw-fluid introduction hole increases with decreasing distance to an outer circumference of the module case.
10. The hollow fiber membrane module according to any one of Claims 1 to 9, wherein the permeated fluid communication portion is at least one communication pipe contained in the hollow fiber membrane bundle.
11. The hollow fiber membrane module according to 97 Claim 10, wherein a number of the communication pipes is one to four.
12. The hollow fiber membrane module according to Claim 1, wherein the module case is an irregular-shaped double pipe including a first portion having a relatively large inner sectional area and a second portion having a relatively small inner sectional area, and the hollow fiber membrane bundle is housed in the first portion, whereas the permeated fluid communication portion is provided in the second portion.
13. The hollow fiber membrane module according to any one of Claims 1 to 12, wherein the inner end surface of each of the adhesive fixing portions is substantially flush with an inner end surface of an adhesive used to form the adhesive fixing portion.
14. A process for manufacturing the hollow fiber membrane module according to Claim 13, including molding at least a part of a raw-fluid distributive supply portion using a material which is easily dissolved into, or easily absorbed and dispersed in water, hot water, or an organic solvent not affecting a member including a hollow fiber membrane module, placing an inner end surface of the molded raw-fluid distributive supply portion inside the adhesive fixing portion, then adhesively fixing the raw-fluid distributive supply portion, a hollow fiber membrane, a permeated fluid communication portion, and a module 98 case together, and then allowing at least a part of the raw-fluid distributive supply portion to be dissolved into or absorbed and dispersed in any of the water, the hot water, and the organic solvent to form the raw fluid distributive supply portion.
15. A hollow fiber membrane module assembly including a first cup (i) shaped like a cup including a raw-fluid supply port and (ii) having a permeated fluid holding space inside the cup shape, the first cup being fixed to an outside of an outer end surface of an adhesive fixing portion at a circumferential end side of the cup shape in a liquid-tight manner, the adhesive fixing portion including the raw-fluid distributive supply portion of the hollow fiber membrane module according to any of Claims 1 to 13, and a second cup (a) shaped like a cup including a permeated fluid sampling pcrt and (b) having a permeated fluid holding space inside the cup shape, the second cup being fixed to an outside of an outer end surface of another adhesive fixing portion at a circumferential end side of the cup shape in a liquid-tight manner, iii) the first cup including a nozzle extending continuously from the raw-fluid supply port in a liquid-tight manner and projecting into the permeated fluid holding space, and iv) th nozzle being coupled to the supply source pipe portion in a liquid-tight manner.
16. A method of purifying suspended water wherein a raw fluid is water and a product of a turbidity of 99 the water and TOC (Total organic Carbon) is 10,000 degrees x mg/liter or less and wherein water with a turbidity of 100 degrees or less and a TOC of 100 mg/liter or less and the hollow fiber membrane module according to Claim 1 is used to obtain filtrate.
17. A hollow element for forming a raw-fluid distributive supply portion including a supply source pipe portion for supplying raw water, compressed air, or a mixed flow of raw water and compressed air; a plurality of raw-fluid supply branching portion for evenly distributing the supplied raw water, the supplied compressed air or the supplied mixed flow of raw water and compressed air; and a raw-fluid introduction hole for introducing the distributed raw water, the distributed compressed air or the distributed mixed flow of raw water and compressed air.
18. The hollow element according to claim 17, wherein a sectional area of the plurality of raw-fluid supply branching portions increases along a forward flow direction of the raw water, the compressed air, or the mixed flow of raw water and compressed air.
19. The hollow element according to claim 17 or 18, wherein the raw-fluid supply branching portions are plate-like voids substantially parallel to the length direction, and the plurality of the raw-fluid supply branching portions are radially arranged in the raw fluid distributive supply portion around the supply source pipe portion serving as a substantial center 100 axis.
20. The hollow element according to any one of claims 17 to 19, wherein the plurality of raw-fluid supply branching portions are 3 to 9 raw-fluid supply branching portions branching from the supply source pipe portion.
21. The hollow element according to any one of claims 17 to 20, wherein a plurality of the raw-fluid introduction holes are formed in each of the raw-fluid supply branching portions, and a sum of equivalent diameters of the plurality of raw-fluid introduction holes is smaller than a maximum equivalent diameter of the plurality of raw-fluid supply branching portions.
22. The hollow element according to any one of claims 17 to 21, wherein when each of the raw-fluid supply branching portions is divided into a central side and an outer side at a position of a half radius outward from the center of the raw-fluid supply branching portion, the sum of the equivalent diameters of the raw-fluid introduction holes formed in the outer-side division is larger than that of the raw fluid introduction holes formed in the central-side division.
23. The hollow element according to any one of claims 17 to 22, wherein the plurality of raw-fluid introduction holes are drilled at equal intervals.
24. A hollow fiber membrane module including the hollow element according to any one of claims 17 to 23. 101
25. A hollow fiber membrane module substantially as herein before described with reference to the accompanying drawings.
26. A hollow element for forming a raw-fluid distributive supply portion substantially as herein before described with reference to the accompanying drawings, ASAHI KASEI CHEMICALS CORPORATION WATERMARK PATENT & TRADE MARK ATTORNEYS P32538AUD0
AU2008254000A 2007-05-22 2008-05-21 Hollow fiber membrane module, process for manufacturing the same, hollow fiber membrane module assembly and method of purifying suspended water with use thereof Ceased AU2008254000B9 (en)
JP2007134951 2007-05-22
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PCT/JP2008/059366 WO2008143292A1 (en) 2007-05-22 2008-05-21 Hollow fiber membrane module, process for manufacturing the same, hollow fiber membrane module assembly and method of purifying suspended water with use thereof
AU2008254000A1 AU2008254000A1 (en) 2008-11-27
AU2008254000B2 AU2008254000B2 (en) 2010-11-25
AU2008254000B9 true AU2008254000B9 (en) 2011-05-12
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AU2008254000A Ceased AU2008254000B9 (en) 2007-05-22 2008-05-21 Hollow fiber membrane module, process for manufacturing the same, hollow fiber membrane module assembly and method of purifying suspended water with use thereof
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2008-05-21 AU AU2008254000A patent/AU2008254000B9/en not_active Ceased
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