Source: https://patents.google.com/patent/US20070172234A1/en
Timestamp: 2019-01-22 20:08:13
Document Index: 75840085

Matched Legal Cases: ['art 91', 'art 91', 'art 91', 'art 91', 'art 91', 'art 91', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 719', 'art 567', 'art 567', 'art 567', 'art 92', 'art 92', 'art 92', 'art 92', 'art 92', 'art 92', 'art 92', 'art 92', 'art 92', 'art 91', 'art 91', 'art 91', 'art 92', 'art 91', 'art 92', 'art 91', 'art 92']

US20070172234A1 - Apparatus for and method of processing substrate - Google Patents
US20070172234A1
US20070172234A1 US11626593 US62659307A US2007172234A1 US 20070172234 A1 US20070172234 A1 US 20070172234A1 US 11626593 US11626593 US 11626593 US 62659307 A US62659307 A US 62659307A US 2007172234 A1 US2007172234 A1 US 2007172234A1
US11626593
A stage cleaning substrate for use in the operation of cleaning a substrate stage within an exposure unit compatible with immersion exposure and a dummy substrate for use during the adjustment of an exposure position of a pattern image are held in a cleaning substrate housing part and a dummy substrate housing part, respectively, provided in a substrate processing apparatus. For the operation of cleaning the substrate stage or an alignment operation within the exposure unit, the stage cleaning substrate or the dummy substrate is transported from the substrate processing apparatus to the exposure unit. The process of cleaning the stage cleaning substrate or the dummy substrate is performed in a cleaning processing unit of the substrate processing apparatus immediately before or immediately after the operation of cleaning the substrate stage or the alignment operation.
The present invention relates to a substrate processing apparatus for performing a resist coating process and a development process on a substrate such as a semiconductor substrate, a glass substrate for a liquid crystal display device, a glass substrate for a photomask, a substrate for an optical disk and the like, the substrate processing apparatus being disposed adjacent to an exposure apparatus for performing an exposure process on the substrate. The present invention also relates to a substrate processing method which uses the substrate processing apparatus.
As is well known, semiconductor and liquid crystal display products and the like are fabricated by performing a series of processes including cleaning, resist coating, exposure, development, etching, interlayer insulation film formation, heat treatment, dicing and the like on the above-mentioned substrate. Of these various processes, the exposure process is the process of transferring a pattern of a reticle (a mask for printing) to a resist-coated substrate, and serves as a key part of what is called a photolithography process. Because the pattern is extremely fine, what is called step-and-repeat exposure, rather than single exposure of the entire wafer, is typically performed in such a manner that the wafer is exposed repeatedly in batches of several chips.
With the rapid increase in the density of semiconductor devices and the like in recent years, there has been a strong demand to make the mask pattern finer. Thus, light sources for an exposure apparatus for performing the exposure process which become dominant are deep-UV light sources such as a KrF excimer laser light source and an ArF excimer laser light source which emit light with relatively short wavelengths in place of conventional UV lamps. However, even the ArF excimer laser light source is insufficient to meet the requirement for much finer patterns of late. To solve such a problem, it is conceivable to employ a light source which emits light with a shorter wavelength, e.g. an F2 laser light source, for the exposure apparatus. An immersion exposure processing method as disclosed in International Publication No. WO 99/49504 in the form of a pamphlet is proposed as an exposure technique which is capable of providing the much finer patterns while reducing burdens in cost.
The immersion exposure processing method is the technique of performing “immersion exposure,” with the space between a projection optical system and a substrate filled with a liquid having a refractive index n (e.g., deionized water with n=1.44) greater than that of the atmosphere (n=1), to increase numerical aperture, thereby improving resolution. This immersion exposure processing method provides an equivalent wavelength of 134 nm when a conventional ArF excimer laser light source (which emits light with a wavelength of 193 nm) is diverted directly, to achieve the finer pattern of the resist mask while suppressing growing burdens in cost.
It is important for such an immersion exposure processing method as well as for a conventional dry exposure process to precisely align a pattern image of the mask and an exposure area on the substrate with each other. Thus, an alignment process for calibrating the position of a substrate stage and a reticle position to adjust the exposure position of the pattern image is performed also in an exposure apparatus compatible with the immersion exposure processing method. In the exposure apparatus compatible with the immersion exposure process, however, there is apprehension that liquid (liquid for immersion) enters the inside of the substrate stage during the alignment process to cause a trouble. To solve this problem, Japanese Patent Application Laid-Open No. 2005-268747 discloses a technique such that a dummy substrate is placed on the substrate stage for the execution of the alignment process. This prevents the liquid from entering the ins ide of the stage because the dummy substrate closes a recessed portion of the stage, as in the conventional exposure process.
In the alignment process disclosed in Japanese Patent Application Laid-Open No. 2005-268747, the liquid is prevented from entering the inside of the stage, but there is a likelihood that the liquid comes in contact with the dummy substrate itself to remain in the form of droplets on the substrate after the alignment process. Such droplets may adsorb extraneous matter such as particles to result in apprehension that only the extraneous matter adheres as contaminants to the dummy substrate after the liquid dries. The execution of the alignment process using the dummy substrate contaminated in this manner creates a problem that the substrate stage and its surroundings are contaminated.
In the immersion exposure process for a normal substrate (a substrate formed with a resist film for semiconductor device fabrication), there are cases where part of the immersion liquid comes in contact with the substrate stage, in particular, when the substrate near its peripheral edge portion is exposed in a pattern. At this time, the particles deposited on the substrate surface are flushed away with the immersion liquid, carried to the substrate stage, and remain thereon, to result in the problem of contaminating the substrate stage.
The present invention is intended for a substrate processing apparatus for performing a resist coating process and a development process on a substrate, the substrate processing apparatus being disposed adjacent to an exposure apparatus for performing an exposure process on a substrate.
According to the present invention, the substrate processing apparatus comprises: a housing part for housing an exposure apparatus adjustment substrate for use in an adjustment operation within the exposure apparatus; a cleaning part for cleaning the exposure apparatus adjustment substrate; and a transport element for transferring and receiving the exposure apparatus adjustment substrate to and from the exposure apparatus and for transporting the exposure apparatus adjustment substrate between the housing part and the cleaning part.
This allows the adjustment operation within the exposure apparatus by the use of the clean exposure apparatus adjustment substrate cleaned in the substrate processing apparatus, thereby to reduce the contamination of mechanisms within the exposure apparatus.
Preferably, the substrate processing apparatus further comprises a cleaning controller for controlling the transport element and the cleaning part to clean the exposure apparatus adjustment substrate immediately before or immediately after the adjustment operation within the exposure apparatus.
This reduces the contamination of the mechanisms within the exposure apparatus with higher reliability.
Preferably, the substrate processing apparatus further comprises a cleaning controller for controlling the transport element and the cleaning part to periodically clean the exposure apparatus adjustment substrate.
This reduces the contamination of the mechanisms within the exposure apparatus with stability.
The present invention is also intended for a method of processing a substrate, the method including transporting a substrate subjected to a resist coating process in a substrate processing apparatus to an exposure apparatus to expose the substrate in a pattern in the exposure apparatus, and then transporting the substrate back to the substrate processing apparatus to perform a development process on the substrate in the substrate processing apparatus.
It is therefore an object of the present invention to provide a substrate processing technique capable of reducing contamination of mechanisms within an exposure apparatus.
FIG. 2 is a front view of a liquid processing part in the substrate processing apparatus;
FIG. 3 is a front view of a thermal processing part in the substrate processing apparatus;
FIG. 7 is a schematic sectional view showing an example of the structure of a two-fluid nozzle;
FIG. 10 is a schematic block diagram showing a control mechanism for the substrate processing apparatus and an exposure unit;
FIG. 11 is a flow chart showing an example of a procedure for substrate stage cleaning;
FIG. 12 is a flow chart showing another example of the procedure for substrate stage cleaning;
FIG. 13 is a flow chart showing an example of a procedure for an alignment process in the exposure unit; and
FIG. 14 shows an immersion exposure process performed on a substrate in the exposure unit.
FIG. 1 is a plan view of a substrate processing apparatus SP according to the present invention. FIG. 2 is a front view of a liquid processing part in the substrate processing apparatus SP. FIG. 3 is a front view of a thermal processing part in the substrate processing apparatus SP. FIG. 4 is a view showing a construction around substrate rest parts. An XYZ rectangular coordinate system in which an XY plane is defined as the horizontal plane and a Z axis is defined to extend in the vertical direction is additionally shown in FIG. 1 and the subsequent figures for purposes of clarifying the directional relationship therebetween.
The substrate processing apparatus SP is an apparatus (what is called a coater-and-developer) for forming an anti-reflective film and a photoresist film on substrates such as semiconductor wafers by coating and for performing a development process on substrates subjected to a pattern exposure process. The substrates to be processed by the substrate processing apparatus SP according to the present invention are not limited to semiconductor wafers, but may include glass substrates for a liquid crystal display device, and the like.
The substrate processing apparatus SP according to the first preferred embodiment includes an indexer block 1, a BARC (Bottom Anti-Reflective Coating) block 2, a resist coating block 3, a development processing block 4, and an interface block 5. In the substrate processing apparatus SP, the five processing blocks 1 to 5 are arranged in side-by-side relation. An exposure unit (or stepper) EXP for performing an exposure process on a resist-coated substrate is provided and connected to the interface block 5. That is, the substrate processing apparatus SP is disposed adjacent to the exposure unit EXP. The substrate processing apparatus SP according to the first preferred embodiment and the exposure unit EXP are connected via LAN lines to a host computer 100.
The indexer block 1 is a processing block for receiving unprocessed substrates from the outside of the substrate processing apparatus SP to transfer the unprocessed substrates outwardly to the BARC block 2 and the resist coating block 3, and for transporting processed substrates received from the development processing block 4 to the outside of the substrate processing apparatus SP. The indexer block 1 includes a table 11 for placing thereon a plurality of (in this preferred embodiment, four) cassettes (or carriers) C in juxtaposition, and a substrate transfer mechanism 12 for taking an unprocessed substrate W out of each of the cassettes C and for storing a processed substrate W into each of the cassettes C. The substrate transfer mechanism 12 includes a movable base 12 a movable horizontally (in the Y direction) along a path TP, and a holding arm 12 b mounted on the movable base 12 a and for holding a substrate W in a horizontal position. The holding arm 12 b is capable of moving upwardly and downwardly (in the Z direction) over the movable base 12 a, pivoting within a horizontal plane and moving back and forth in the direction of the pivot radius. Thus, the substrate transfer mechanism 12 can cause the holding arm 12 b to gain access to each of the cassettes C, thereby taking an unprocessed substrate W out of each cassette C and storing a processed substrate W into each cassette C. The cassettes C may be of the following types: an SMIF (standard mechanical interface) pod, and an OC (open cassette) which exposes stored substrates W to the atmosphere, in addition to a FOUP (front opening unified pod) which stores substrates W in an enclosed or sealed space.
A dummy substrate housing part 91 for housing a dummy substrate DW is provided over a portion of the path TP along which the substrate transfer mechanism 12 is movable. The dummy substrate housing part 91 has a multi-tier cabinet structure capable of storing a plurality of dummy substrates DW. The dummy substrate DW is used in the immersion-compatible exposure unit EXP to prevent deionized water from entering the inside of a substrate stage during an alignment process for adjusting the exposure position of a pattern image, such as calibrating a stage position and the like. The dummy substrate DW is approximately identical in shape and size with a normal substrate W (for semiconductor device fabrication). The material of the dummy substrate DW may be the same as that of the normal substrate W (for example, silicon), but is required only to prevent contaminants from dissolving out in a liquid during an immersion exposure process. The dummy substrate DW may have a surface made water-repellent. An example of the technique of making the surface of the dummy substrate DW water-repellent is a coating process using a water-repellent material such as a fluorine compound, a silicon compound, acrylic resin, polyethylene and the like. Alternatively, the dummy substrate DW itself may be made of the above-mentioned water-repellent materials. When the alignment process is not performed, e.g. when the normal exposure process is performed, the dummy substrate DW is unnecessary and therefore is held in the dummy substrate housing part 91 of the indexer block 1. The substrate transfer mechanism 12 transports the dummy substrate DW into and out of the dummy substrate housing part 91. Specifically, the movable base 12 a moves along the path TP, and the holding arm 12 b moves upwardly and downwardly and moves back and forth, whereby the substrate transfer mechanism 12 transports the dummy substrate DW into and out of the dummy substrate housing part 91.
The upper substrate rest part PASS1 is used for the transport of a substrate W from the indexer block 1 to the BARC block 2. The substrate rest part PASS1 includes three support pins. The substrate transfer mechanism 12 of the indexer block 1 places an unprocessed substrate W taken out of one of the cassettes C onto the three support pins of the substrate rest part PASS1. The substrate transfer mechanism 12 also places the dummy substrate DW taken out of the dummy substrate housing part 91 onto the substrate rest part PASS1. A transport robot TR1 of the BARC block 2 to be described later receives the substrate W or the dummy substrate DW placed on the substrate rest part PASS1. The lower substrate rest part PASS2, on the other h and, is used for the transport of a substrate W from the BARC block 2 to the indexer block 1. The substrate rest part PASS2 also includes three support pins. The transport robot TR1 of the BARC block 2 places a processed substrate W onto the three support pins of the substrate rest part PASS2. The substrate transfer mechanism 12 receives the substrate W placed on the substrate rest part PASS2 and stores the substrate W into one of the cassettes C. Pairs of substrate rest parts PASS3 to PASS10 to be described later are similar in construction to the pair of substrate rest parts PASS1 and PASS2.
In the BARC block 2, the bottom coating processor BRC and the pair of thermal processing towers 21 are arranged on opposite sides of the transport robot TR1. Specifically, the bottom coating processor BRC is on the front side of the substrate processing apparatus SP, and the pair of thermal processing towers 21 are on the rear side thereof. Additionally, a thermal barrier not shown is provided on the front side of the pair of thermal processing towers 21. Thus, the thermal effect of the pair of thermal processing towers 21 upon the bottom coating processor BRC is avoided by spacing the bottom coating processor BRC apart from the pair of thermal processing towers 21 and by providing the thermal barrier.
Thus, stacking the coating processing units BRC1 to BRC3 and the thermal processing units (the hot plates HP1 to HP6, the cool plates CP1 to CP3, and the adhesion promotion processing parts AHL1 to AHL3 in the BARC block 2) in tiers provides smaller space occupied by the substrate processing apparatus SP to reduce the footprint thereof. The side-by-side arrangement of the pair of thermal processing towers 21 is advantageous in facilitating the maintenance of the thermal processing units and in eliminating the need for extension of ducting and power supply equipment necessary for the thermal processing units to a much higher position.
In the resist coating block 3, the resist coating processor SC and the pair of thermal processing towers 31 are arranged on opposite sides of the transport robot TR2. Specifically, the resist coating processor SC is on the front side of the substrate processing apparatus SP, and the pair of thermal processing towers 31 are on the rear side thereof. Additionally, a thermal barrier not shown is provided on the front side of the pair of thermal processing towers 31. Thus, the thermal effect of the pair of thermal processing towers 31 upon the resist coating processor SC is avoided by spacing the resist coating processor SC apart from the pair of thermal processing towers 31 and by providing the thermal barrier.
The local transport mechanism 34 is provided on the opposite side of the above-mentioned hot plate and the temporary substrate rest part from the transport robot TR2, that is, on the rear side of the substrate processing apparatus SP. The temporary substrate rest part has both an open side facing the transport robot TR2 and an open side facing the local transport mechanism 34. The hot plate, on the other hand, has only an open side facing the local transport mechanism 34, and a closed side facing the transport robot TR2. Thus, both of the transport robot TR2 and the local transport mechanism 34 can gain access to the temporary substrate rest part, but only the local transport mechanism 34 can gain access to the hot plate. The heating parts PHP1 to PHP6 are generally similar in construction (FIGS. 8A and 8B) to heating parts PHP7 to PHP12 in the development processing block 4 to be described later.
The cleaning processor SOAK includes a single cleaning processing unit SOAK1. As shown in FIG. 2, the cleaning processing unit SOAK1 is disposed under the development processing unit SD1. The cleaning processing unit SOAK1 is substantially similar in construction to a cleaning processing unit SU to be described later. The cleaning processing unit SOAK1 is capable of performing a cleaning process for supplying a cleaning liquid (e.g., deionized water) to a rotating substrate W, a surface preparation process for supplying a surface preparation liquid (e.g., hydrofluoric acid) thereto, and a drying process for spraying an inert gas (e.g., nitrogen gas) thereonto.
FIGS. 8A and 8B schematically show the construction of the heating part PHP7 with the temporary substrate rest part. FIG. 8A is a side sectional view of the heating part PHP7, and FIG. 8B is a plan view of the heating part PHP7. Although the heating part PHP7 is shown in FIGS. 8A and 8B, the heating parts PHP8 to PHP12 are precisely identical in construction with the heating part PHP7. The heating part PHP7 includes a heating plate 710 for performing a heating process on a substrate W placed thereon, a temporary substrate rest part 719 for placing a substrate W in an upper or lower position (in this preferred embodiment, an upper position) spaced apart from the heating plate 710, and a local transport mechanism 720 specific to a thermal processing part for transporting a subs t rate W between the heating plate 710 and the temporary substrate rest part 719. The heating plate 710 is provided with a plurality of movable support pins 721 extendable out of and retractable into the plate surface. A vertically movable top cover 722 for covering a substrate W during the heating process is provided over the heating plate 710. The temporary substrate rest part 719 is provided with a plurality of fixed support pins 723 for supporting a substrate W.
The local transport mechanism 720 further includes a cooling element for cooling a substrate W in the course of the transport of the substrate W from the heating plate 710 to the temporary substrate rest part 719. As illustrated in FIG. 8B, the cooling element is constructed so that a cooling water passage 724 b through which a cooling water flows is provided inside the holding plate 724. The cooling element may be constructed so that, for example, a Peltier device or the like is provided inside the holding plate 724.
The above-mentioned local transport mechanism 720 is provided at the rear of (i.e., on the (+Y) side relative to) the heating plate 710 and the temporary substrate rest part 719 in the substrate processing apparatus SP. A transport robot TR4 of the interface block 5 is disposed on the (+X) side relative to the heating plate 710 and the temporary subs t rate rest part 719, and the transport robot TR3 of the development processing block 4 is disposed on the (−Y) side relative to the heating plate 710 and the temporary substrate rest part 719. In an upper portion of an enclosure 727 covering the heating plate 710 and the temporary substrate rest part 719, i.e., a portion of the enclosure 727 which covers the temporary substrate rest part 719, an opening 719 a is provided on the (+X) side for allowing the transport robot TR4 to enter the temporary substrate rest part 719, and an opening 719 b is provided on the (+Y) side for allowing the local transport mechanism 720 to enter the temporary substrate rest part 719. In a lower portion of the enclosure 727, i.e., a portion of the enclosure 727 which covers the heating plate 710, no openings are provided on the (+X) and (−Y) sides (i.e., the surfaces of the enclosure 727 opposed to the transport robot TR3 and the transport robot TR4), and an opening 719 c is provided on the (+Y) side for allowing the local transport mechanism 720 to enter the heating plate 710.
The transport robot TR4 transfers and receives the substrate W to and from only the temporary substrate rest part 719, but does not directly transfer and receive the substrate W to and from the heating plate 710. This avoids the temperature rise of the transport robot TR4. Additionally, the opening 719 c through which the substrate W is placed onto and removed from the heating plate 710 is formed only on the side of the local transport mechanism 720. This prevents the heat atmosphere leaking out through the opening 719 c from raising the temperatures of the transport robot TR3 and the transport robot TR4 and also from affecting the development processor SD and the cleaning processor SOAK.
Next, the interface block 5 for connection to the exposure unit EXP will be described. The interface block 5 is a block provided adjacent to the development processing block 4. The interface block 5 receives a substrate W with the resist film formed thereon by the resist coating process from the resist coating block 3 to transfer the substrate W to the exposure unit EXP. Also, the interface block 5 receives an exposed substrate W from the exposure unit EXP to transfer the exposed substrate W to the development processing block 4. The interface block 5 in this preferred embodiment includes a transport mechanism 55 for transferring and receiving a substrate W to and from the exposure unit EXP, an edge exposure unit EEW1 for exposing the periphery of a substrate W formed with the resist film, the cleaning processing unit SU for cleaning the dummy substrate DW and a stage cleaning substrate CW, and the transport robot TR4 for transferring and receiving a substrate W to and from the heating parts PHP7 to PHP12 and cool plate CP14 provided in the development processing block 4 and the edge exposure unit EEW1. The transport robot TR4 provided adjacent to the edge exposure unit EEW1, the cleaning processing unit SU, and the thermal processing tower 42 of the development processing block 4 is similar in construction to the above-mentioned transport robots TR1 to TR3. Both the transport mechanism 55 and the transport robot TR4 are capable of transferring and receiving a substrate W to and from the cleaning processing unit SU.
As shown in FIG. 2, the edge exposure unit EEW1 includes a spin chuck 56 for rotating a substrate W in a substantially horizontal plane while holding the substrate W in a substantially horizontal position under suction, a light irradiator 57 for exposing the periphery of the substrate W held on the spin chuck 56 to light, and the like.
FIG. 6 is a view for illustrating the construction of the cleaning processing unit SU. The cleaning processing unit SU includes a spin chuck 421 for rotating a substrate W about a vertical rotation axis passing through the center of the substrate W while holding the substrate W in a horizontal position.
The cleaning processing nozzle 450 according to the first preferred embodiment is a two-fluid nozzle which mixes droplets into a gas to eject the mixture. A tip of a cleaning supply pipe 463 is connected in communication with the cleaning processing nozzle 450. The cleaning supply pipe 463 is connected in communication with a cleaning liquid supply source R1 and a surface preparation liquid supply source R2 through a valve Va and a valve Vb, respectively. Controlling the opening and closing of the valves Va and Vb allows the selection of a processing liquid to be supplied to the cleaning supply pipe 463 and the adjustment of the amount of supply thereof. Specifically, the cleaning liquid (in this preferred embodiment, deionized water) is supplied to the cleaning supply pipe 463 by opening the valve Va, and the surface preparation liquid (in this preferred embodiment, hydrofluoric acid) is supplied to the cleaning supply pipe 463 by opening the valve Vb. The cleaning liquid supplied from the cleaning liquid supply source R1 or the surface preparation liquid supplied from the surface preparation liquid supply source R2 is fed through the cleaning supply pipe 463 to the cleaning processing nozzle 450.
A tip of a gas supply pipe 474 is also connected in communication with the cleaning processing nozzle 450. The gas supply pipe 474 is connected at its proximal end in communication with an inert gas supply source R3 (e.g., factory utilities). A valve Vd is inserted at some point along the length of the gas supply pipe 474. The inert gas (in this preferred embodiment, nitrogen gas) at a predetermined pressure is fed to the cleaning processing nozzle 450 by opening the valve Vd.
FIG. 7 is a schematic sectional view showing an example of the structure of the cleaning processing nozzle 450 that is a two-fluid nozzle. The cleaning processing nozzle 450 is what is called an internal mix two-fluid nozzle which mixes nitrogen gas supplied from the inert gas supply source R3 and deionized water supplied from the cleaning liquid supply source R1 together within the nozzle to form and eject droplets of deionized water in the form of a mist toward the substrate W. As shown in FIG. 7, the cleaning processing nozzle 450 has a double-tube structure such that a gas inlet tube 566 through which the nitrogen gas is supplied is inserted in a cleaning liquid inlet tube 565 through which the deionized water is supplied. A mixing part 567 for mixing the nitrogen gas and the deionized water together is provided downstream from the end of the gas inlet tube 566 inside the cleaning liquid inlet tube 565.
Pressurized nitrogen gas and deionized water are mixed in the mixing part 567 to form a fluid mixture including droplets of deionized water in the form of a mist. The formed fluid mixture is accelerated by an acceleration tube 568 downstream from the mixing part 567, and is ejected from an outlet port 569. The cleaning processing nozzle 450 may be what is called an external mix two-fluid nozzle which mixes nitrogen gas and deionized water together by causing a collision therebetween in an open space outside the nozzle to form and eject droplets of deionized water in the form of a mist toward the substrate W. When hydrofluoric acid is fed to the cleaning processing nozzle 450, the cleaning processing nozzle 450 forms a fluid mixture including droplets of hydrofluoric acid in the form of a mist in the gas to eject the fluid mixture toward the substrate W.
Referring again to FIG. 6, a second pivoting motor 470 is provided on a different side of the spin chuck 421 than the above-mentioned side. A second pivoting shaft 471 is connected to the second pivoting motor 470. A second arm 472 is coupled to the second pivoting shaft 471 so as to extend in a horizontal direction, and a drying processing nozzle 451 is provided on a distal end of the second arm 472. The second pivoting motor 470 drives the second pivoting shaft 471 to rotate, thereby pivoting the second arm 472, whereby the drying processing nozzle 451 moves to over the substrate W held by the spin chuck 421.
A tip of a drying supply pipe 473 is connected in communication with the drying processing nozzle 451. The drying supply pipe 473 is connected in communication with the inert gas supply source R3 through a valve Vc. Controlling the opening and closing of the valve Vc allows the adjustment of the amount of nitrogen gas to be supplied to the drying supply pipe 473.
The nitrogen gas supplied from the inert gas supply source R3 is fed through the drying supply pipe 473 to the drying processing nozzle 451. Thus, the nitrogen gas is sprayed from the drying processing nozzle 451 onto the surface of the substrate W.
When supplying the cleaning liquid or the surface preparation liquid to the surface of the substrate W, the cleaning processing nozzle 450 is positioned over the substrate W held by the spin chuck 421 whereas the drying processing nozzle 451 is retracted to a predetermined position. When supplying the inert gas to the surface of the substrate W, on the other hand, the drying processing nozzle 451 is positioned over the substrate W held by the spin chuck 421 whereas the cleaning processing nozzle 450 is retracted to a predetermined position, as shown in FIG. 6.
The substrate W held by the spin chuck 421 is surrounded by a processing cup 423. A cylindrical partition wall 433 is provided inside the processing cup 423. A drainage space 431 for draining the processing liquid (the cleaning liquid or the surface preparation liquid) used for the processing of the substrate W is formed inside the partition wall 433 so as to surround the spin chuck 421. A collected liquid space 432 for collecting the processing liquid used for the processing of the substrate W is formed between the outer wall of the processing cup 423 and the partition wall 433 so as to surround the drainage space 431.
The splash guard 424 is driven to move upwardly and downwardly in a vertical direction by a guard driving mechanism (not shown) including a ball screw mechanism and the like. The guard driving mechanism moves the splash guard 424 upwardly and downwardly between a collection position in which the collected liquid guide portion 442 surrounds the edge portion of the substrate W held by the spin chuck 421 and a drainage position in which the drainage guide groove 441 surrounds the edge portion of the substrate W held by the spin chuck 421. When the splash guard 424 is in the collection position (the position shown in FIG. 6), the processing liquid splashed from the edge portion of the substrate W is guided by the collected liquid guide portion 442 into the collected liquid space 432, and is then collected through the collection pipe 435. When the splash guard 424 is in the drainage position, on the other hand, the processing liquid splashed from the edge portion of the substrate W is guided by the drainage guide groove 441 into the drainage space 431, and is then drained through the drainage pipe 434. In this manner, the drainage and collection of the processing liquid can be selectively carried out. When hydrofluoric acid is used as the surface preparation liquid, strict atmosphere control is required so as to prevent the atmosphere from leaking out within the apparatus. The cleaning processing unit SOAK1 in the development processing block 4 is similar in construction to the cleaning processing unit SU except that the cleaning processing nozzle 450 is a straight nozzle for directly ejecting the processing liquid without mixing the processing liquid and a gas together.
With reference to FIGS. 2 and 9, description will be further continued. FIG. 9 is a side view of the interface block 5 as seen from the (+X) side. A return buffer RBF for the return of substrates W is provided under the cleaning processing unit SU, and the pair of vertically arranged substrate rest parts PASS9 and PASS10 are provided under the return buffer RBF. The return buffer RBF is provided to temporarily store a substrate W subjected to a post-exposure bake process in the heating parts PHP7 to PHP12 of the development processing block 4 if the development processing block 4 is unable to perform the development process on the substrate W because of some sort of malfunction and the like. The return buffer RBF includes a cabinet capable of storing a plurality of substrates W in tiers. The upper substrate rest part PASS9 is used for the transfer of a substrate W from the transport robot TR4 to the transport mechanism 55. The lower substrate rest part PASS10 is used for the transfer of a substrate W from the transport mechanism 55 to the transport robot TR4. The transport robot TR4 gains access to the return buffer RBF.
As shown in FIG. 9, the transport mechanism 55 includes a movable base 55 a in threaded engagement with a threaded shaft 522. The threaded shaft 522 is rotatably supported by a pair of support bases 523 so that the rotation axis thereof extends along the Y axis. The threaded shaft 522 has one end coupled to a motor Ml. The motor Ml drives the threaded shaft 522 to rotate, thereby moving the movable base 55 a horizontally along the Y axis.
A hand support base 55 b is mounted on the movable base 55 a. The hand support base 55 b is movable upwardly and downwardly in a vertical direction (along the Z axis) and is pivotable about a vertical axis by a lifting mechanism and a pivot mechanism incorporated in the movable base 55 a. A pair of holding arms 59 a and 59 b for holding a substrate W is mounted on the hand support base 55 b so as to be arranged vertically. The pair of holding arms 59 a and 59 b are movable back and forth in the direction of the pivot radius of the hand support base 55 b independently of each other by a sliding drive mechanism incorporated in the movable base 55 a. With such an arrangement, the transport mechanism 55 transfers and receives a substrate W to and from the exposure unit EXP, transfers and receives a substrate W to and from the substrate rest parts PASS9 and PASS10, and stores and takes a substrate W into and out of a send buffer SBF for the sending of substrates W. The send buffer SBF is provided to temporarily store a substrate W prior to the exposure process if the exposure unit EXP is unable to accept the substrate W, and includes a cabinet capable of storing a plurality of substrates W in tiers.
In the interface block 5, a cleaning substrate housing part 92 for housing the stage cleaning substrate CW is provided under the send buffer SBF. The cleaning substrate housing part 92 has a multi-tier cabinet structure capable of storing a plurality of stage cleaning substrates CW. The stage cleaning substrate CW is used in the immersion-compatible exposure unit EXP to clean the substrate stage. The stage cleaning substrate CW is approximately identical in shape and size with the normal substrate W (for semiconductor device fabrication). The material of the stage cleaning substrate CW may be the same as that of the normal substrate W (for example, silicon), but is required only to prevent contaminants from dissolving out in the immersion liquid. Like the dummy substrate DW, the stage cleaning substrate CW may have a surface made water-repellent. When the process of cleaning the substrate stage is not performed, e.g. when the normal exposure process is performed, the stage cleaning substrate CW is unnecessary and therefore is held in the cleaning substrate housing part 92. The transport mechanism 55 transports the stage cleaning substrate CW into and out of the cleaning substrate housing part 92.
As shown in FIGS. 2 and 9, the cleaning processing unit SOAK1 has an opening 58 on the (+X) side. Thus, the transport mechanism 55 can transfer and receive a substrate W to and from the cleaning processing unit SOAK1 through the opening 58.
A downflow of clean air is always supplied into the indexer block 1, the BARC block 2, the resist coating block 3, the development processing block 4, and the interface block 5 described above to thereby avoid the adverse effects of raised particles and gas flows upon the processes in the blocks 1 to 5. Additionally, a slightly positive pressure relative to the external environment of the substrate processing apparatus SP is maintained in each of the blocks 1 to 5 to prevent the entry of particles and contaminants from the external environment into the blocks 1 to 5.
The indexer block 1, the BARC block 2, the resist coating block 3, the development processing block 4 and the interface block 5 as described above are units into which the substrate processing apparatus SP of this preferred embodiment is divided in mechanical terms. The blocks 1 to 5 are assembled to individual block frames, respectively, which are in turn connected together to construct the substrate processing apparatus SP.
The substrate processing apparatus SP in this preferred embodiment includes six cells: an indexer cell, a BARC cell, a resist coating cell, a development processing cell, a post-exposure bake cell, and an interface cell. The indexer cell includes the table 11 and the substrate transfer mechanism 12, and is consequently similar in construction to the indexer block 1 which is one of the units based on the mechanical division. The BARC cell includes the bottom coating processor BRC, the pair of thermal processing towers 21 and the transport robot TR1. The BARC cell is also consequently similar in construction to the BARC block 2 which is one of the units based on the mechanical division. The resist coating cell includes the resist coating processor SC, the pair of thermal processing towers 31, and the transport robot TR2. The resist coating cell is also consequently similar in construction to the resist coating block 3 which is one of the units based on the mechanical division.
The post-exposure bake cell includes the thermal processing tower 42 positioned in the development processing block 4, the edge exposure unit EEW1 positioned in the interface block 5, and the transport robot TR4 positioned in the interface block 5. That is, the post-exposure bake cell extends over the development processing block 4 and the interface block 5 which are units based on the mechanical division. In this manner, constituting one cell including the heating parts PHP7 to PHP12 for performing the post-exposure bake process and the transport robot TR4 allows the rapid transport of exposed substrates W into the heating parts PHP7 to PHP12 for the execution of the thermal process. Such an arrangement is preferred for the use of a chemically amplified resist which is required to be subjected to a heating process as soon as possible after the exposure of a substrate W in a pattern.
The interface cell includes the transport mechanism 55 for transferring and receiving a substrate W to and from the exposure unit EXP, the cleaning processor SOAK, and the cleaning processing unit SU. The interface cell has a construction different from that of the interface block 5 which is one of the units based on the mechanical division in that the interface cell includes the cleaning processor SOAK positioned in the development processing block 4 and does not include the transport robot TR4 and the edge exposure unit EEW1. The substrate rest parts PASS9 and PASS10 under the cleaning processing unit SU are provided for the transfer of a substrate W between the transport robot TR4 of the post-exposure bake cell and the transport mechanism 55 of the interface cell.
The exposure unit EXP performs the exposure process on a substrate W resist-coated in the substrate processing apparatus SP. The exposure unit EXP according to this preferred embodiment is an immersion exposure apparatus compatible with an “immersion exposure processing method” which substantially shortens the wavelength of exposure light to improve resolution and to substantially widen the depth of focus. The exposure unit EXP performs the exposure process, with the space between a projection optical system and the substrate W filled with a liquid having a high refractive index (e.g., deionized water having a refractive index n=1.44).
Next, a control mechanism for the substrate processing apparatus SP according to this preferred embodiment will be described. FIG. 10 is a schematic block diagram of a control mechanism for the substrate processing apparatus SP and the exposure unit EXP. As shown in FIG. 10, the substrate processing apparatus SP and the exposure unit EXP are connected to each other through the host computer 100 and a LAN line 101. The substrate processing apparatus SP has a three-level control hierarchy composed of a main controller MC, cell controllers CC, and unit controllers. The main controller MC, the cell controllers CC and the unit controllers are similar in hardware construction to typical computers. Specifically, each of the controllers includes a CPU for performing various computation processes, a ROM or read-only memory for storing a basic program therein, a RAM or readable/writable memory for storing various pieces of information therein, a magnetic disk for storing control applications and data therein, and the like.
The single main controller MC at the first level is provided for the entire substrate processing apparatus SP, and is principally responsible for the management of the entire substrate processing apparatus SP, the management of a main panel MP, and the management of the cell controllers CC. The main panel MP functions as a display for the main controller MC. Various commands and parameters may be entered into the main controller MC from a keyboard KB. The main panel MP may be in the form of a touch panel so that a user performs an input process into the main controller MC from the main panel MP.
The exposure unit EXP, on the other hand, is provided with a controller EC which is a separate controller independent of the above-mentioned control mechanism of the substrate processing apparatus SP. In other words, the exposure unit EXP does not operate under the control of the main controller MC of the substrate processing apparatus SP, but controls its own operation alone. The controller EC for the exposure unit EXP is similar in hardware construction to a typical computer. The controller EC controls the exposure process in the exposure unit EXP, and also controls the operation of transferring and receiving a substrate to and from the substrate processing apparatus SP
The host computer 100 ranks as a higher level control mechanism than the three-level control hierarchy provided in the substrate processing apparatus SP and than the controller EC for the exposure unit EXP. The host computer 100 includes a CPU for performing various computation processes, a ROM or read-only memory for storing a basic program therein, a RAM or readable/writable memory for storing various pieces of information therein, a magnetic disk for storing control applications and data therein, and the like. The host computer 100 is similar in construction to a typical computer. Typically, a plurality of substrate processing apparatuses SP and a plurality of exposure units EXP according to this preferred embodiment are connected to the host computer 100. The host computer 100 provides a recipe containing descriptions about a processing procedure and processing conditions to each of the substrate processing apparatuses SP and the exposure units EXP connected thereto. The recipe provided from the host computer 100 is stored in a storage part (e.g., a memory) of the main controller MC of each of the substrate processing apparatuses SP and the controller EC of each of the exposure units EXP.
Next, the operation of the substrate processing apparatus SP of this preferred embodiment will be described. First, brief description will be given on a procedure for the circulating transport of a normal substrate W in the substrate processing apparatus SP. The processing procedure to be described below is executed by the main controller MC giving instructions to the lower-level controllers to control mechanical parts in accordance with the descriptions of the recipe received from the host computer 100.
First, unprocessed substrates W stored in a cassette C are transported from the outs ide of the substrate processing apparatus SP into the indexer block 1 by an AGV (automatic guided vehicle) and the like. Subsequently, the unprocessed substrates W are transferred outwardly from the indexer block 1. Specifically, the substrate transfer mechanism 12 in the indexer cell (or the indexer block 1) takes an unprocessed substrate W out of a predetermined cassette C, and places the unprocessed substrate W onto the upper substrate rest part PASS1. After the unprocessed substrate W is placed on the substrate rest part PASS1, the transport robot TR1 of the BARC cell uses one of the holding arms 6 a and 6 b to receive the unprocessed substrate W. The transport robot TR1 transports the received unprocessed substrate W to one of the coating processing units BRC1 to BRC3. In the coating processing units BRC1 to BRC3, the substrate W is spin-coated with the coating solution for the anti-reflective film.
After the substrate W with the resist film formed thereon by the resist coating process is placed on the substrate rest part PASS5, the transport robot TR3 of the development processing cell receives the substrate W, and places the substrate W onto the substrate rest part PASS7 without any processing of the substrate W. Then, the transport robot TR4 of the post-exposure bake cell receives the substrate W placed on the substrate rest part PASS7, and transports the substrate W into the edge exposure unit EEW1. In the edge exposure unit EEW1, a peripheral edge portion of the substrate W is exposed to light (edge exposure process). The transport robot TR4 places the substrate W subjected to the edge exposure process onto the substrate rest part PASS9. The transport mechanism 55 of the interface cell receives the substrate W placed on the substrate rest part PASS9, and transports the substrate W into the exposure unit EXP. In this step, the transport mechanism 55 uses the holding arm 59 a to transport the substrate W from the substrate rest part PASS9 into the exposure unit EXP. The resist-coated substrate W transported into the exposure unit EXP is subjected to the pattern exposure process.
Because the chemically amplified resist is used in this preferred embodiment, an acid is formed by a photochemical reaction in the exposed portion of the resist film formed on the substrate W. In the exposure unit EXP, the substrate W is subjected to the immersion exposure process. This achieves a high resolution with virtually no change of the conventional light source and exposure process. The substrate W subjected to the edge exposure process may be transported to the cool plate CP14 for the cooling process by the transport robot TR4 before being transported into the exposure unit EXP.
The transport mechanism 55 takes the exposed substrate W subjected to the pattern exposure process out of the exposure unit EXP, to thereby return the substrate W from the exposure unit EXP to the interface cell again. Thereafter, the transport mechanism 55 transports the exposed substrate W into the cleaning processing unit SOAK1. In this step, the transport mechanism 55 uses the holding arm 59 b to transport the substrate W from the exposure unit EXP to the cleaning processing unit SOAK1. There are cases where a liquid adheres to the substrate W subjected to the immersion exposure process. However, the holding arm 59 a is used for the transport of the unexposed substrate W and the holding arm 59 b is exclusively used for the transport of the exposed substrate W. This avoids the adhesion of the liquid to at least the holding arm 59 a, to prevent the transfer of the liquid to the unexposed substrate W.
The cleaning process of supplying deionized water to the rotating substrate W, and the subsequent drying process of spraying nitrogen gas onto the substrate rotating at a high speed are performed in the cleaning processing unit SOAK1. The transport mechanism 55 takes the substrate W subjected to the cleaning and drying processes out of the cleaning processing unit SOAK1, and places the substrate W onto the substrate rest part PASS10. In this step, the transport mechanism 55 uses the holding arm 59 a to transport the substrate W from the cleaning processing unit SOAK1 to the substrate rest part PASS10. After the exposed substrate W is placed on the substrate rest part PASS10, the transport robot TR4 of the post-exposure bake cell receives the substrate W, and transports the substrate W to one of the heating parts PHP7 to PHP12. The processing operation in the heating parts PHP7 to PHP12 is as described above. In the heating parts PHP7 to PHP12, the heating process (or the post-exposure bake process) is performed which causes a reaction such as crosslinking, polymerization and the like of the resist resin to proceed by using a product formed by the photochemical reaction during the exposure process as an acid catalyst, thereby locally changing the solubility of only an exposed portion of the resist resin in the developing solution. The local transport mechanism 720 having the cooling mechanism transports the substrate W subjected to the post-exposure bake process to thereby cool down the substrate W, whereby the above-mentioned chemical reaction stops. Subsequently, the transport robot TR4 takes the substrate W from the one of the heating parts PHP7 to PHP12, and places the substrate W onto the substrate rest part PASS8.
Thereafter, the transport robot TR3 places the substrate W onto the substrate rest part PASS6. The transport robot TR2 of the resist coating cell places the substrate W from the substrate rest part PASS6 onto the substrate rest part PASS4 without any processing of the substrate W. Next, the transport robot TR1 of the BARC cell places the substrate W from the substrate rest part PASS4 onto the substrate rest part PASS2 without any processing of the substrate W, whereby the substrate W is stored in the indexer block 1. Then, the substrate transfer mechanism 12 of the indexer cell stores the processed substrate W held on the substrate rest part PASS2 into a predetermined cassette C. Thereafter, the cassette C in which a predetermined number of processed substrates W are stored is transported to the outside of the substrate processing apparatus SP. Thus, a series of photolithography processes are completed.
As discussed above, the exposure unit EXP according to this preferred embodiment performs the immersion exposure process. FIG. 14 shows the immersion exposure process performed on the substrate W in the exposure unit EXP. A substrate stage 150 for holding the substrate W thereon is positioned under a projection optical system 160. An illumination optical system and a mask both not shown are provided over the projection optical system 160. The projection optical system 160 and the mask are slidable in a horizontal plane. While a liquid supply nozzle 170 supplies an immersion liquid (in this preferred embodiment, deionized water) EL onto the substrate W, a liquid collecting nozzle 180 collects the immersion liquid EL. This forms a flow of immersion liquid EL between the projection optical system 160 and the substrate W held on the substrate stage 150, and always fills the gap therebetween with the immersion liquid EL with stability. In such conditions, exposure light is emitted so that a pattern image of the mask is projected through the projection optical system 160 onto the substrate W to expose the substrate W. In this process, the gap between the projection optical system 160 and the substrate W is filled with the immersion liquid EL having a high refractive index (deionized water having a refractive index n=1.44). This substantially shortens the wavelength of the exposure light to improve resolution and to substantially widen the depth of focus.
Also, the exposure process includes exposing the substrate W repeatedly in batches of several chips into which the pattern formed on the mask is divided while moving the mask and the substrate stage 150 in opposite directions in synchronization with each other (step-and-repeat exposure). When the substrate W near its peripheral edge portion is exposed in a pattern by using the step-and-repeat exposure process, the substrate stage 150 is moved a considerable distance so that the immersion liquid EL comes over the edge of the substrate W into contact with the substrate stage 150 in some cases. If a small number of particles are deposited on the substrate W, the particles are sometimes flushed away with the immersion liquid EL to adhere to the substrate stage 150. Thus, a portion of the substrate stage 150 lying near the peripheral edge portion of the substrate W placed thereon is especially susceptible to contamination.
This preferred embodiment avoids such a problem by cleaning the substrate stage 150 in a manner to be described below. FIG. 11 is a flow chart showing an example of a procedure for substrate stage cleaning. This procedure is performed by the main controller MC giving instructions to the lower-level controllers to control the mechanical parts such as the transport mechanism 55 and the cleaning processing unit SU.
First, the stage cleaning substrate CW is transported from the substrate processing apparatus SP to the exposure unit EXP (in Step S11). Specifically, the transport mechanism 55 takes the stage cleaning substrate CW out of the cleaning substrate housing part 92 of the interface block 5 to transport the stage cleaning substrate CW to the exposure unit EXP. In the exposure unit EXP, the stage cleaning substrate CW received from the substrate processing apparatus SP is placed on the substrate stage 150, and the substrate stage 150 is moved to under the projection optical system 160. Then, while the liquid supply nozzle 170 supplies deionized water, the liquid collecting nozzle 180 collects the deionized water, whereby a flow of deionized water is formed between the projection optical system 160 and the stage cleaning substrate CW. This creates a situation similar to that shown in FIG. 14.
While a flow of deionized water is maintained between the projection optical system 160 and the stage cleaning substrate CW, the substrate stage 150 is slid so that a portion of the upper surface of the substrate stage 150 near the peripheral edge portion of the stage cleaning substrate CW is washed with the flow of deionized water. In this manner, the stage cleaning process in the exposure unit EXP proceeds (in Step S12).
After the completion of the cleaning process throughout the peripheral edge portion of the stage cleaning substrate CW, the stage cleaning substrate CW subjected to the cleaning process is transported from the exposure unit EXP back to the substrate processing apparatus SP (in Step S13). Specifically, the stage cleaning substrate CW is taken from the substrate stage 150 in the exposure unit EXP and transported toward the interface block 5 in the substrate processing apparatus SP. Because the stage cleaning substrate CW subjected to the cleaning process has adsorbed the contaminants coming from the substrate stage 150, it is necessary to remove the contaminants from the stage cleaning substrate CW to clean the stage cleaning substrate CW. To this end, the transport mechanism 55 receives the stage cleaning substrate CW and transports the stage cleaning substrate CW directly to the cleaning processing unit SU in the substrate processing apparatus SP. Then, the cleaning process is performed on the stage cleaning substrate CW in the cleaning processing unit SU (in Step S14).
When the stage cleaning substrate CW is transported into the cleaning processing unit SU, the splash guard 424 is moved downwardly, and the transport mechanism 55 places the stage cleaning substrate CW onto the spin chuck 421. The stage cleaning substrate CW placed on the spin chuck 421 is held in a horizontal position under suction by the spin chuck 421.
Next, the splash guard 424 moves to the above-mentioned drainage position, and the cleaning processing nozzle 450 moves to over the center of the stage cleaning substrate CW. Thereafter, the rotary shaft 425 starts rotating. As the rotary shaft 425 rotates, the stage cleaning substrate CW held by the spin chuck 421 is rotated. Thereafter, the valve Va and the valve Vb are opened to eject a fluid mixture including droplets of deionized water in the form of a mist formed by mixing nitrogen gas and deionized water together from the cleaning processing nozzle 450 onto the upper surface of the stage cleaning substrate CW. At the same time, the cleaning processing nozzle 450 is reciprocated (or scans) between a position lying directly over the center of rotation of the stage cleaning substrate CW and a position lying over a peripheral edge portion thereof. Thus, the process of cleaning the stage cleaning substrate CW proceeds to flush away water or moisture and contaminants which have been deposited on the stage cleaning substrate CW. The liquid splashed from the rotating stage cleaning substrate CW by centrifugal force is guided by the drainage guide groove 441 into the drainage space 431, and is drained through the drainage pipe 434.
After a lapse of a predetermined time period, the ejection of the fluid mixture from the cleaning processing nozzle 450 is stopped. The cleaning processing nozzle 450 is retracted to a predetermined position, and the drying processing nozzle 451 moves to over the center of the stage cleaning substrate CW. Thereafter, the valve Vc is opened to apply nitrogen gas from the drying processing nozzle 451 to near the center of the upper surface of the stage cleaning substrate CW. At the same time, the drying processing nozzle 451 is reciprocated (or scans) between a position lying directly over the center of rotation of the stage cleaning substrate CW and a position lying over a peripheral edge portion thereof. The speed of rotation of the rotary shaft 425 is increased. Thus, a great centrifugal force is exerted on a film of water remaining on the stage cleaning substrate CW, and the nitrogen gas is sprayed onto the entire surface of the stage cleaning substrate CW. This removes the water or moisture on the stage cleaning substrate CW to dry the stage cleaning substrate CW with reliability.
Thereafter, the supply of the nitrogen gas is stopped. The drying processing nozzle 451 is retracted to a predetermined position, and the rotation of the rotary shaft 425 is stopped. The splash guard 424 is moved downwardly, and the transport mechanism 55 transports the stage cleaning substrate CW out of the cleaning processing unit SU. This completes the operation of the cleaning process of the stage cleaning substrate CW in the cleaning processing unit SU. The position of the splash guard 424 during the cleaning and drying processes is preferably appropriately changed depending on the need for the collection and drainage of the processing liquid.
The transport mechanism 55 transports the stage cleaning substrate CW subjected to the cleaning and drying processes in the cleaning processing unit SU back to the cleaning substrate housing part 92, and houses the stage cleaning substrate CW into its original position (in Step S15). Thus, the operation of cleaning the substrate stage 150 is completed.
In this way, the stage cleaning substrate CW is always held in the substrate processing apparatus SP, and the clean stage cleaning substrate CW subjected to the cleaning process and received from the substrate processing apparatus SP is used for the operation of cleaning the substrate stage 150 in the exposure unit EXP. This reduces the contamination of the substrate stage 150.
In the first preferred embodiment, the process of cleaning the stage cleaning substrate CW in the cleaning processing unit SU is performed immediately after the operation of cleaning the substrate stage 150 in the exposure unit EXP, that is, immediately after the stage cleaning substrate CW is contaminated. If the contaminated stage cleaning substrate CW is left uncleaned after the operation of cleaning the substrate stage 150, the immersion liquid dries and the contaminants adhere to the stage cleaning substrate CW stubbornly. This makes it difficult to remove the contaminants from the stage cleaning substrate CW in some cases. However, the process of cleaning the stage cleaning substrate CW immediately after the operation of cleaning the substrate stage 150 as in the first preferred embodiment removes the contamination from the stage cleaning substrate CW easily with reliability.
Next, a second preferred embodiment according to the present invention will be described. The second preferred embodiment is similar to the first preferred embodiment in construction of the substrate processing apparatus SP and the exposure unit EXP and in procedure for the processing of the normal substrate W. The second preferred embodiment differs from the first preferred embodiment in procedure for the operation of cleaning the substrate stage 150. FIG. 12 is a flow chart showing another example of the procedure for substrate stage cleaning.
In the procedure shown in FIG. 12, the transport mechanism 55 takes the stage cleaning substrate CW out of the cleaning substrate housing part 92 to transport the stage cleaning substrate CW directly to the cleaning processing unit SU. First, the cleaning process is performed on the stage cleaning substrate CW in the cleaning processing unit SU (in Step S21). The details of the processes of cleaning and drying the stage cleaning substrate CW in the cleaning processing unit SU in the second preferred embodiment are similar to those in the first preferred embodiment.
The transport mechanism 55 transports the stage cleaning substrate CW subjected to the cleaning and drying processes out of the cleaning processing unit SU directly to the exposure unit EXP (in Step S22). Then, the operation of cleaning the substrate stage 150 by using the stage cleaning substrate CW is performed in a manner similar to that in the first preferred embodiment (in Step S23).
After the completion of the process of cleaning the substrate stage 150, the stage cleaning substrate CW subjected to the cleaning process is transported from the exposure unit EXP to the substrate processing apparatus SP (in Step S24). In the second preferred embodiment, the transport mechanism 55 which receives the stage cleaning substrate CW transports the stage cleaning substrate CW directly to the cleaning substrate housing part 92, and houses the stage cleaning substrate CW into its original position (in Step S25).
In the second preferred, the process of cleaning the stage cleaning substrate CW in the cleaning processing unit SU is performed immediately before the operation of cleaning the substrate stage 150, whereas in the first preferred embodiment the process of cleaning the stage cleaning substrate CW is performed immediately after the operation of cleaning the substrate stage 150 in the exposure unit EXP. There is apprehension that particles and the like adhere to the stage cleaning substrate CW while the stage cleaning substrate CW is held in the cleaning substrate housing part 92. However, when the process of cleaning the stage cleaning substrate CW is performed immediately before the operation of cleaning the substrate stage 150 as in the second preferred embodiment, the operation of cleaning the substrate stage 150 is performed by using the clean stage cleaning substrate CW obtained immediately after the cleaning. This removes the contamination from the substrate stage 150 with higher reliability.
Next, a third preferred embodiment according to the present invention will be described. The third preferred embodiment is similar to the first preferred embodiment in construction of the substrate processing apparatus SP and the exposure unit EXP and in procedure for the processing of the normal substrate W. The third preferred embodiment differs from the first preferred embodiment in performing the alignment process using the dummy substrate DW in the exposure unit EXP. FIG. 13 is a flow chart showing an example of a procedure for the alignment process in the exposure unit EXP.
First, the dummy substrate DW is transported from the substrate processing apparatus SP to the exposure unit EXP (in Step S31). Specifically, the substrate transfer mechanism 12 takes the dummy substrate DW out of the dummy substrate housing part 91 in the indexer block 1. The dummy substrate DW is transferred through the transport robots TR1, TR2, TR3 and TR4 in order to the transport mechanism 55 in the interface block 5. The transport mechanism 55 finally transports the dummy substrate DW into the exposure unit EXP. During the above-mentioned transfer, the substrate rest parts PASS1, PASS3, PASS5, PASS7 and PASS9 are used. In the exposure unit EXP, the dummy substrate DW received from the substrate processing apparatus SP is placed on the substrate stage 150, and the substrate stage 150 is moved to under the projection optical system 160.
The exposure unit EXP performs the immersion exposure process, and uses the dummy substrate DW to prevent deionized water from entering the inside of the substrate stage 150 during the alignment process for adjusting the exposure position of the pattern image. Specifically, the dummy substrate DW is fitted in a recessed stage portion of the substrate stage 150 for the execution of the alignment process (in Step S32). This prevents the liquid from entering the inside of the substrate stage 150.
After the completion of the alignment process, the dummy substrate DW used for the alignment process is transported from the exposure unit EXP back to the substrate processing apparatus SP (in Step S33). Specifically, the dummy substrate DW is taken from the substrate stage 150 within the exposure unit EXP, and is transported toward the interface block 5 in the substrate processing apparatus SP. The use of the dummy substrate DW for the alignment process prevents the liquid from entering the inside of the substrate stage 150, but creates a likelihood that the liquid adheres to the dummy substrate DW to remain in the form of droplets on the dummy substrate DW. When left unremoved, such droplets dry to become a source of contamination. The substrate processing apparatus SP avoids this problem in such a manner that the transport mechanism 55 receives the dummy substrate DW to transport the dummy substrate DW directly to the cleaning processing unit SU. Then, the process of cleaning the dummy substrate DW is performed in the cleaning processing unit SU (in Step S34). The details of the processes of cleaning and drying the dummy substrate DW in the cleaning processing unit SU in the third preferred embodiment are similar to those of the processes of cleaning and drying the stage cleaning substrate CW in the first preferred embodiment.
The transport mechanism 55 takes the dummy substrate DW subjected to the cleaning and drying processes in the cleaning processing unit SU out of the cleaning processing unit SU. The dummy substrate DW is transferred through the transport robots TR4, TR3, TR2 and TR1 in order to the substrate transfer mechanism 12 in the indexer block 1. The substrate transfer mechanism 12 finally transports the dummy substrate DW back to the dummy substrate housing part 91, and houses the dummy substrate DW into its original position (in Step S35). During the transfer of the dummy substrate DW being returned, the substrate rest parts PASS10, PASS8, PASS6, PASS4 and PASS2 are used.
In this way, the dummy substrate DW is always held in the substrate processing apparatus SP, and the clean dummy substrate DW subjected to the cleaning process and received from the substrate processing apparatus SP is used for the alignment operation such as the stage position calibration and the like in the exposure unit EXP. This reduces the contamination of the substrate stage 150. That is, such exposure unit adjustment substrates (the stage cleaning substrate CW and the dummy substrate DW) for use during the adjustment operations (the operation of cleaning the substrate stage 150 and the alignment operation) are held in the substrate processing apparatus SP including the cleaning processing unit SU, and a clean exposure unit adjustment substrate is used for a predetermined adjustment operation in the exposure unit EXP. This reduces the contamination of the substrate stage 150.
In the third preferred embodiment, the process of cleaning the dummy substrate DW in the cleaning processing unit SU is performed immediately after the alignment operation in the exposure unit EXP, that is, immediately after the immersion liquid adheres to the dummy substrate DW to contaminate the dummy substrate DW. If the contaminated dummy substrate DW is left uncleaned after the alignment operation, the immersion liquid dries and the contaminants adhere to the dummy substrate DW stubbornly. This makes it difficult to remove the contaminants from the dummy substrate DW. However, the process of cleaning the dummy substrate DW immediately after the alignment operation as in the third preferred embodiment removes the contamination from the dummy substrate DW easily with reliability.
When the dummy substrate DW is water-repellent, there are cases where the water repellency of the dummy substrate DW is impaired due to contamination. However, the removal of the contaminants by the above-mentioned cleaning process restores the water repellency of the substrate surface. As a result, the dummy substrate DW holds the immersion liquid with reliability also during the alignment process. This also significantly reduces the costs, as compared with the process of replacing dummy substrates DW made less water-repellent one by one.
While the preferred embodiments according to the present invention are described hereinabove, various changes and modifications in addition to those described above may be made therein without departing from the spirit of the invention. For example, although the process of cleaning the dummy substrate DW is performed in the cleaning processing unit SU immediately after the alignment operation in the exposure unit EXP in the above-mentioned third preferred embodiment, the process of cleaning the dummy substrate DW may be performed in the cleaning processing unit SU immediately before the alignment operation. This allows the use of the clean dummy substrate DW obtained immediately after the cleaning for the alignment operation, to prevent the contamination of the substrate stage 150.
The present invention is not limited to the execution of the process of cleaning the stage cleaning substrate CW either immediately before or immediately after the operation of cleaning the substrate stage 150 in the exposure unit EXP as in the first and second preferred embodiments. The process of cleaning the stage cleaning substrate CW may be performed both immediately before and immediately after the operation of cleaning the substrate stage 15. Similarly, the process of cleaning the dummy substrate DW may be performed both immediately before and immediately after the alignment operation in the exposure unit EXP. This reduces the contamination of the substrate stage 150 with higher reliability.
The substrate processing apparatus SP may be scheduled to perform the cleaning process on the stage cleaning substrate CW and/or the dummy substrate DW (or the exposure unit adjustment substrate) periodically at predetermined time intervals. Specifically, a module for the periodic cleaning of the exposure unit adjustment substrate at preset time intervals is included in application software to be executed by the main controller MC of the substrate processing apparatus SP, and the main controller MC which executes the application software causes the transport mechanism 55 and the cleaning processing unit SU to periodically perform the cleaning process on the exposure unit adjustment substrate. The periodic cleaning of the exposure unit adjustment substrate keeps the surface condition of the exposure unit adjustment substrate always the same with stability to consequently reduce the contamination of the mechanisms in the exposure unit EXP with stability.
The time to periodically perform the cleaning process on the exposure unit adjustment substrate may be, for example, the time of regular maintenance of the substrate processing apparatus SP. The execution of the cleaning process on the exposure unit adjustment substrate as one of the maintenance processes at the time of regular maintenance eliminates the apprehension of interference with the process of normal substrates W, to thereby facilitate the control of the cleaning and transport. However, the execution of the cleaning process on the exposure unit adjustment substrate immediately before the adjustment operation (the operation of cleaning the substrate stage 150 and the alignment operation) within the exposure unit EXP allows the execution the adjustment operation using the cleaner exposure unit adjustment substrate obtained immediately after the cleaning. The execution of the cleaning process on the exposure unit adjustment substrate immediately after the adjustment operation ensures the removal of the contamination before the adhering liquid dries. The time intervals at which the exposure unit adjustment substrate is cleaned periodically may be inputted from the main panel MP and the keyboard KB to the main controller MC. Alternatively, the host computer 100 may give an instruction to the main controller MC to cause the execution of the periodic cleaning.
In the above-mentioned preferred embodiments, the adjustment operation using the exposure unit adjustment substrate may be started by sending an exposure unit adjustment substrate request signal from the controller EC of the exposure unit EXP to the main controller MC of the substrate processing apparatus SP or by sending an adjustment operation start request signal in the opposite direction from the main controller MC to the controller EC. Alternatively, the adjustment operation using the exposure unit adjustment substrate may be started by sending an adjustment operation start signal from the host computer 100 ranking as the higher level controller to the main controller MC and to the controller EC.
The cleaning processing unit SU for cleaning the exposure unit adjustment substrate is disposed in the interface block 5 in the above-mentioned preferred embodiments, but may be disposed in a different position. For example, the position of the cleaning processing unit SOAK1 in the development processing block 4 and the position of the cleaning processing unit SU in the interface block 5 may be interchanged with each other. Further, a single cleaning processing unit may be adapted to perform both the process of cleaning the normal exposed substrate W and the process of cleaning the exposure unit adjustment substrate. The substrate W coated with a chemically amplified resist, immediately after the exposure, is highly susceptible to an alkaline atmosphere. Thus, it is preferable to provide a cleaning processing unit designed specifically for the exposure unit adjustment substrate when a process using the surface preparation liquid is performed in the cleaning processing unit.
In the above-mentioned preferred embodiments, the dummy substrate housing part 91 is provided in the indexer block 1 whereas the cleaning substrate housing part 92 is provided in the interface block 5. The present invention, however, is not limited to such an arrangement. The positions in which the dummy substrate housing part 91 and the cleaning substrate housing part 92 are placed may be any position within the substrate processing apparatus SP. For example, both the dummy substrate housing part 91 and the cleaning substrate housing part 92 may be provided in the indexer block 1. Additionally, both the stage cleaning substrate CW and the dummy substrate DW may be housed in a single multi-tier substrate housing part.
Although the two-fluid nozzle is used as the cleaning processing nozzle 450 in the above-mentioned preferred embodiments, a straight nozzle for directly ejecting the cleaning liquid such as deionized water or the surface preparation liquid such as hydrofluoric acid which is fed thereto may be used in place of the two-fluid nozzle. The cleaning processing nozzle 450 used herein may be an ultrasonic cleaning nozzle for ejecting the cleaning liquid or surface preparation liquid subjected to ultrasound, and a high-pressure cleaning nozzle for ejecting the cleaning liquid or the like at high pressure, as well as that described above. A cleaning brush for performing a cleaning process in contact with or in proximity to the substrate may be provided in place of or in addition to the cleaning processing nozzle 450. The straight nozzle, the ultrasonic cleaning nozzle, the high-pressure cleaning nozzle and the cleaning brush used herein may be those known in the art. When the cleaning brush is provided, it is preferable to provide a front surface cleaning unit for cleaning the front surface of the substrate and a back surface cleaning unit for cleaning the back surface of the substrate individually, and to provide a flipping unit for flipping the substrate being transported to these units upside down.
The surface preparation may be done by supplying the surface preparation liquid (a chemical solution) to the exposure unit adjustment substrate in place of performing the cleaning process on the exposure unit adjustment substrate in the cleaning processing unit SU or after performing the cleaning process. For example, hydrofluoric acid is supplied as the surface preparation liquid in the cleaning processing unit SU. When the exposure unit adjustment substrate is a silicon wafer as well as the normal substrate W, a silicon oxide film (a native oxide film) is formed on the surface of the exposure unit adjustment substrate to make the surface hydrophilic. The supply of hydrofluoric acid serving as the surface preparation liquid to the surface of the exposure unit adjustment substrate removes the silicon oxide film to expose a silicon body, thereby making the surface of the exposure unit adjustment substrate water-repellent. That is, the supply of the surface preparation liquid imparts (or restores) the water repellency to the surface of the exposure unit adjustment substrate. Specifically, while the exposure unit adjustment substrate held by the spin chuck 421 is rotated, the valve Vb and the valve Vd are opened to feed hydrofluoric acid from the surface preparation liquid supply source R2 and nitrogen gas from the inert gas supply source R3, respectively, through the cleaning processing nozzle 450, thereby ejecting a fluid mixture including droplets of hydrofluoric acid in the form of a mist formed by mixing nitrogen gas and hydrofluoric acid together from the cleaning processing nozzle 450 onto the upper surface of the exposure unit adjustment substrate. The surface preparation liquid supplied to the exposure unit adjustment substrate is not limited to hydrofluoric acid. Depending on the materials of the exposure unit adjustment substrate, such a material as a fluorine compound, acrylic resin and the like, for example, may be supplied to the exposure unit adjustment substrate to perform a coating process for making the surface of the exposure unit adjustment substrate water-repellent in the cleaning processing unit SU.
Although the exposure unit EXP is compatible with the immersion exposure in the above-mentioned preferred embodiments, the exposure unit EXP may be of the type which does not use the immersion liquid during the exposure process. When the exposure unit EXP is of such dry exposure type, the cleaning of the substrate stage by using the clean stage cleaning substrate CW cleaned in the substrate processing apparatus SP reduces the contamination of the mechanisms within the exposure unit EXP.
The construction of the substrate processing apparatus SP according to the present invention is not limited to the configuration shown in FIGS. 1 to 4. However, various modifications may be made to the construction of the substrate processing apparatus SP if a transport robot circulatingly transports a substrate W to a plurality of processing parts whereby predetermined processes are performed on the substrate W. For example, a cover film coating block for forming a cover film on the resist film may be provided between the resist coating block 3 and the development processing block 4 to prevent the resist from dissolving during the exposure. A cover film coating processor for forming a cover film on the resist film may be provided in part of the resist coating block 3.
1. A substrate processing apparatus for performing a resist coating process and a development process on a substrate, said substrate processing apparatus being disposed adjacent to an exposure apparatus for performing an exposure process on a substrate, said substrate processing apparatus comprising:
a housing part for housing an exposure apparatus adjustment substrate for use in an adjustment operation within said exposure apparatus;
a cleaning part for cleaning said exposure apparatus adjustment substrate; and
a transport element for transferring and receiving said exposure apparatus adjustment substrate to and from said exposure apparatus and for transporting said exposure apparatus adjustment substrate between said housing part and said cleaning part.
a cleaning controller for controlling said transport element and said cleaning part to clean said exposure apparatus adjustment substrate immediately before or immediately after the adjustment operation within said exposure apparatus.
a cleaning controller for controlling said transport element and said cleaning part to periodically clean said exposure apparatus adjustment substrate.
an indexer part for transporting an unprocessed substrate into said substrate processing apparatus and for transporting a processed substrate out of said substrate processing apparatus,
wherein said housing part is provided in said indexer part.
said cleaning part includes a chemical solution supply part for supplying hydrofluoric acid to said exposure apparatus adjustment substrate.
said exposure apparatus adjustment substrate is an exposure apparatus cleaning substrate used for cleaning the inside of said exposure apparatus.
said exposure apparatus adjustment substrate is a dummy substrate for use when said exposure apparatus performs an alignment process for adjusting an exposure position.
8. A method of processing a substrate, said method including transporting a substrate subjected to a resist coating process in a substrate processing apparatus to an exposure apparatus to expose said substrate in a pattern in said exposure apparatus, and then transporting said substrate back to said substrate processing apparatus to perform a development process on said substrate in said substrate processing apparatus, said method comprising the steps of:
a) transferring an exposure apparatus adjustment substrate from said substrate processing apparatus to said exposure apparatus, said exposure apparatus adjustment substrate being for use in an adjustment operation within said exposure apparatus;
b) performing the adjustment operation using said exposure apparatus adjustment substrate in said exposure apparatus;
c) transferring said exposure apparatus adjustment substrate subjected to said adjustment operation from said exposure apparatus to said substrate processing apparatus; and
d) cleaning said exposure apparatus adjustment substrate in said substrate processing apparatus.
said step d) is performed immediately before said step a) or immediately after said step c).
said step d) is performed periodically.
said step d) includes the step of supplying hydrofluoric acid to said exposure apparatus adjustment substrate to perform surface preparation.
US11626593 2006-01-26 2007-01-24 Apparatus for and method of processing substrate Abandoned US20070172234A1 (en)
JP2006-017580 2006-01-26
JP2006017580A JP4704221B2 (en) 2006-01-26 2006-01-26 The substrate processing apparatus and a substrate processing method
US20070172234A1 true true US20070172234A1 (en) 2007-07-26
ID=38285682
US11626593 Abandoned US20070172234A1 (en) 2006-01-26 2007-01-24 Apparatus for and method of processing substrate
US (1) US20070172234A1 (en)
JP (1) JP4704221B2 (en)
JP2005268412A (en) * 2004-03-17 2005-09-29 Nikon Corp Aligner, manufacturing method thereof, and exposure method
JP2007201148A (en) 2007-08-09 application
JP4704221B2 (en) 2011-06-15 grant
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SHIGEMORI, KAZUHITO;KANEYAMA, KOJI;KANAOKA, MASASHI;AND OTHERS;REEL/FRAME:018808/0733;SIGNING DATES FROM 20061130 TO 20061213