Source: https://www.ecfr.gov/cgi-bin/text-idx?mc=true&node=sp40.14.63.ssss&rgn=div6
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Title 40 → Chapter I → Subchapter C → Part 63 → Subpart SSSS
§63.5120 What emission standards must I meet?
§63.5121 What operating limits must I meet?
§63.5130 When must I comply?
§63.5140 What general requirements must I meet to comply with the standards?
§63.5160 What performance tests must I complete?
§63.5200 What authorities may be delegated to the States?
§§63.5201-63.5209 [Reserved]
Source: 67 FR 39812, June 10, 2002, unless otherwise noted.
(a) Each coil coating affected source must limit organic HAP emissions to the level specified in paragraph (a)(1), (2), or (3) of this section:
(1) No more than 2 percent of the organic HAP applied for each month during each 12-month compliance period (98 percent reduction); or
(2) No more than 0.046 kilogram (kg) of organic HAP per liter of solids applied during each 12-month compliance period; or
(3) If you use an oxidizer to control organic HAP emissions, operate the oxidizer such that an outlet organic HAP concentration of no greater than 20 parts per million by volume (ppmv) on a dry basis is achieved and the efficiency of the capture system is 100 percent.
(b) You must demonstrate compliance with one of these standards by following the applicable procedures in §63.5170.
(a) Except as provided in paragraph (b) of this section, for any coil coating line for which you use an add-on control device, unless you use a solvent recovery system and conduct a liquid-liquid material balance according to §63.5170(e)(1), you must meet the applicable operating limits specified in Table 1 to this subpart. You must establish the operating limits during the performance test according to the requirements in §63.5160(d)(3). You must meet the operating limits at all times after you establish them.
(b) If you use an add-on control device other than those listed in Table 1 to this subpart, or wish to monitor an alternative parameter and comply with a different operating limit, you must apply to the Administrator for approval of alternative monitoring under §63.8(f).
(a) For an existing affected source, the compliance date is 3 years after June 10, 2002.
(b) If you own or operate a new affected source subject to the provisions of this subpart, you must comply immediately upon start-up of the affected source, or by June 10, 2002, whichever is later.
(d) The initial compliance period begins on the applicable compliance date specified in paragraph (a) or (b) of this section and ends on the last day of the 12th month following the compliance date. If the compliance date falls on any day other than the first day of a month, then the initial compliance period extends through that month plus the next 12 months.
(e) For the purpose of demonstrating continuous compliance, a compliance period consists of 12 months. Each month after the end of the initial compliance period described in paragraph (d) of this section is the end of a compliance period consisting of that month and the preceding 11 months.
(b) Table 2 of this subpart provides cross references to subpart A of this part, indicating the applicability of the General Provisions requirements to this subpart.
(a) To demonstrate continuing compliance with the standards, you must monitor and inspect each capture system and each control device required to comply with §63.5120 following the date on which the initial performance test of the capture system and control device is completed. You must install and operate the monitoring equipment as specified in paragraphs (a)(1) through (4) of this section.
Table 1 to §63.5160—Required Performance Testing Summary
1. Limiting HAP or Volatile matter content of coatings Determine the HAP or volatile matter and solids content of coating materials according to the procedures in §63.5160(b) and (c).
2. Using a capture system and add-on control device Conduct a performance test for each capture and control system to determine: (1) the destruction or removal efficiency of each control device according to §63.5160(d), and (2) the capture efficiency of each capture system according to §63.5160(e).
(a) If you use a control device to comply with the requirements of §63.5120, you are not required to conduct a performance test to demonstrate compliance if one or more of the criteria in paragraphs (a)(1) through (3) of this section are met:
(1) The control device is equipped with continuous emission monitors for determining total organic volatile matter concentration, and capture efficiency has been determined in accordance with the requirements of this subpart; and the continuous emission monitors are used to demonstrate continuous compliance in accordance with §63.5150(a)(2); or
(2) You have received a waiver of performance testing under §63.7(h); or
(b) Organic HAP content. You must determine the organic HAP weight fraction of each coating material applied by following one of the procedures in paragraphs (b)(1) through (4) of this section:
(1) Method 311. You may test the material in accordance with Method 311 of appendix A of this part. The Method 311 determination may be performed by the manufacturer of the material and the results provided to you. The organic HAP content must be calculated according to the criteria and procedures in paragraphs (b)(1)(i) through (iii) of this section.
(i) Count only those organic HAP that are measured to be present at greater than or equal to 0.1 weight percent for Occupational Safety and Health Administration (OSHA)-defined carcinogens as specified in 29 CFR 1910.1200(d)(4) and greater than or equal to 1.0 weight percent for other organic HAP compounds.
(ii) Express the weight fraction of each organic HAP you count according to paragraph (b)(1)(i) of this section as a value truncated to four places after the decimal point (for example, 0.3791).
(iii) Calculate the total weight fraction of organic HAP in the tested material by summing the counted individual organic HAP weight fractions and truncating the result to three places after the decimal point (for example, 0.763).
(2) Method 24. For coatings, you may determine the total volatile matter content as weight fraction of nonaqueous volatile matter and use it as a substitute for organic HAP, using Method 24 of 40 CFR part 60, appendix A. The Method 24 determination may be performed by the manufacturer of the coating and the results provided to you.
(3) Alternative method. You may use an alternative test method for determining the organic HAP weight fraction once the Administrator has approved it. You must follow the procedure in §63.7(f) to submit an alternative test method for approval.
(4) Formulation data. You may use formulation data provided that the information represents each organic HAP present at a level equal to or greater than 0.1 percent for OSHA-defined carcinogens as specified in 29 CFR 1910.1200(d)(4) and equal to or greater than 1.0 percent for other organic HAP compounds in any raw material used, weighted by the mass fraction of each raw material used in the material. Formulation data may be provided to you by the manufacturer of the coating material. In the event of any inconsistency between test data obtained with the test methods specified in paragraphs (b)(1) through (3) of this section and formulation data, the test data will govern.
(c) Solids content. You must determine the solids content of each coating material applied. You may determine the volume solids content using ASTM D2697-86 (Reapproved 1998) or ASTM D6093-97 (incorporated by reference, see §63.14), or an EPA approved alternative method. The ASTM D2697-86 (Reapproved 1998) or ASTM D6093-97 determination may be performed by the manufacturer of the material and the results provided to you. Alternatively, you may rely on formulation data provided by material providers to determine the volume solids.
(d) Control device destruction or removal efficiency. If you are using an add-on control device, such as an oxidizer, to comply with the standard in §63.5120, you must conduct a performance test to establish the destruction or removal efficiency of the control device or the outlet HAP concentration achieved by the oxidizer, according to the methods and procedures in paragraphs (d)(1) and (2) of this section. During the performance test, you must establish the operating limits required by §63.5121 according to paragraph (d)(3) of this section.
(1) An initial performance test to establish the destruction or removal efficiency of the control device must be conducted such that control device inlet and outlet testing is conducted simultaneously. To establish the outlet organic HAP concentration achieved by the oxidizer, only oxidizer outlet testing must be conducted. The data must be reduced in accordance with the test methods and procedures in paragraphs (d)(1)(i) through (ix).
(iii) Method 3, 3A, or 3B of 40 CFR part 60, appendix A, used for gas analysis to determine dry molecular weight. You may also use as an alternative to Method 3B, the manual method for measuring the oxygen, carbon dioxide, and carbon monoxide content of exhaust gas, ANSI/ASME PTC 19.10-1981, “Flue and Exhaust Gas Analyses” (incorporated by reference, see §63.14).
(vi) Method 25 or 25A of 40 CFR part 60, appendix A, is used to determine total gaseous non-methane organic matter concentration. Use the same test method for both the inlet and outlet measurements, which must be conducted simultaneously. You must submit notification of the intended test method to the Administrator for approval along with notification of the performance test required under §63.7 (b). You must use Method 25A if any of the conditions described in paragraphs (d)(1)(vi)(A) through (D) of this section apply to the control device.
(B) The control device is an oxidizer, but an exhaust gas volatile organic matter concentration of 50 ppmv or less is required to comply with the standards in §63.5120; or
(C) The control device is an oxidizer, but the volatile organic matter concentration at the inlet to the control system and the required level of control are such that they result in exhaust gas volatile organic matter concentrations of 50 ppmv or less; or
(D) The control device is an oxidizer, but because of the high efficiency of the control device, the anticipated volatile organic matter concentration at the control device exhaust is 50 ppmv or less, regardless of inlet concentration.
(vii) Each performance test must consist of three separate runs, except as provided by §63.7(e)(3); each run must be conducted for at least 1 hour under the conditions that exist when the affected source is operating under normal operating conditions. For the purpose of determining volatile organic matter concentrations and mass flow rates, the average of the results of all runs will apply. If you are demonstrating initial compliance with the outlet organic HAP concentration limit in §63.5120(a)(3), only the average outlet volatile organic matter concentration must be determined.
(viii) If you are determining the control device destruction or removal efficiency, for each run, determine the volatile organic matter mass flow rates using Equation 1 of this section:
Mf = total organic volatile matter mass flow rate, kg/per hour (h).
Qsd = volumetric flow rate of gases entering or exiting the control device, as determined by Method 2, 2A, 2C, 2D, 2F, or 2G, dry standard cubic meters (dscm)/h.
(ix) For each run, determine the control device destruction or removal efficiency, DRE, using Equation 2 of this section:
(x) The control device destruction or removal efficiency is determined as the average of the efficiencies determined in the three test runs and calculated in Equation 2 of this section.
(2) You must record such process information as may be necessary to determine the conditions in existence at the time of the performance test. Operations during periods of start-up, shutdown, and malfunction will not constitute representative conditions for the purpose of a performance test.
(3) Operating limits. If you are using a capture system and add-on control device other than a solvent recovery system for which you conduct a liquid-liquid material balance to comply with the requirements in §63.5120, you must establish the applicable operating limits required by §63.5121. These operating limits apply to each capture system and to each add-on emission control device that is not monitored by CEMS, and you must establish the operating limits during the performance test required by paragraph (d) of this section according to the requirements in paragraphs (d)(3)(i) through (iii) of this section.
(i) Thermal oxidizer. If your add-on control device is a thermal oxidizer, establish the operating limits according to paragraphs (d)(3)(i)(A) and (B) of this section.
(ii) Catalytic oxidizer. If your add-on control device is a catalytic oxidizer, establish the operating limits according to either paragraphs (d)(3)(ii)(A) and (B) or paragraphs (d)(3)(ii)(C) and (D) of this section.
(C) As an alternative to monitoring the temperature difference across the catalyst bed, you may monitor the temperature at the inlet to the catalyst bed and implement a site-specific inspection and maintenance plan for your catalytic oxidizer as specified in paragraph (d)(3)(ii)(D) of this section. During the performance test, you must monitor and record the temperature just before the catalyst bed at least once every 15 minutes during each of the three test runs. Use the data collected during the performance test to calculate and record the average temperature just before the catalyst bed during the performance test. This is the minimum operating limit for your catalytic oxidizer.
(D) You must develop and implement an inspection and maintenance plan for your catalytic oxidizer(s) for which you elect to monitor according to paragraph (d)(3)(ii)(C) of this section. The plan must address, at a minimum, the elements specified in paragraphs (d)(3)(ii)(D)(1 (3) of this section.
(1) Annual sampling and analysis of the catalyst activity (i.e., conversion efficiency) following the manufacturer's or catalyst supplier's recommended procedures.
(2) Monthly inspection of the oxidizer system including the burner assembly and fuel supply lines for problems and,
(3) Annual internal and monthly external visual inspection of the catalyst bed to check for channeling, abrasion, and settling. If problems are found, you must take corrective action consistent with the manufacturer's recommendations and conduct a new performance test to determine destruction efficiency according to §63.5160.
(iii) Other types of control devices. If you use a control device other than an oxidizer or a solvent recovery system for which you choose to comply by means of a monthly liquid-liquid material balance, or wish to monitor an alternative parameter and comply with a different operating limit, you must apply to the Administrator for approval of alternative monitoring under §63.8(f).
(e) Capture efficiency. If you are required to determine capture efficiency to meet the requirements of §63.5170(e)(2), (f)(1) through (2), (h)(2) through (4), or (i)(2) through (3), you must determine capture efficiency using the procedures in paragraph (e)(1), (2), or (3) of this section, as applicable.
(1) For an enclosure that meets the criteria for a PTE, you may assume it achieves 100 percent capture efficiency. You must confirm that your capture system is a PTE by demonstrating that it meets the requirements of section 6 of EPA Method 204 of 40 CFR part 51, appendix M (or an EPA approved alternative method), and that all exhaust gases from the enclosure are delivered to a control device.
(2) You may determine capture efficiency, CE, according to the protocols for testing with temporary total enclosures that are specified in Method 204A through F of 40 CFR part 51, appendix M. You may exclude never-controlled work stations from such capture efficiency determinations.
(1) Approval of alternatives to the emission limitations in §63.5120;
(2) Approval of major alternatives to test methods under §63.7(e)(2)(ii) and (f) and as defined in §63.5160;
(3) Approval of major alternatives to monitoring under §63.8(f) and as defined in §63.5150; and
(4) Approval of major alternatives to recordkeeping and reporting under §63.10(f) and as defined in §§63.5180 and 63.5190.
§63.1(a)(1)-(4) Yes
§63.1(a)(6)-(8) Yes
§63.1(a)(10)-(14) Yes
§63.1(b)(1) No Subpart SSSS specifies applicability.
§63.1(b)(2)-(3) Yes
§63.1(c)(1) Yes
§63.1(c)(2) Yes
§63.1(c)(4) Yes
§63.1(e) Yes
§63.2 Yes Additional definitions in subpart SSSS.
§63.3(a)-(c) Yes
§63.4(a)(1)-(3) Yes
§63.4(a)(5) Yes
§63.4(b)-(c) Yes
§63.5(a)(1)-(2) Yes
§63.5(b)(3)-(6) Yes
§63.5(d) Yes Only total HAP emissions in terms of tons per year are required for §63.5(d)(1)(ii)(H).
§63.5(e) Yes
§63.5(f) Yes
§63.6(a) Yes
§63.6(b)(1)-(5) Yes
§63.6(b)(7) Yes
§63.6(c)(1)-(2) Yes
§63.6(c)(5) Yes
§63.6(e) Yes Provisions in §63.6(e)(3) pertaining to startups, shutdowns, malfunctions, and CEMS only apply if an add-on control system is used.
§63.6(f) Yes
§63.6(h) No Subpart SSSS does not require continuous opacity monitoring systems (COMS).
§63.6(i)(1)-(14) Yes
§63.7 Yes With the exception of §63.7(a)(2)(vii) and (viii), which are reserved.
§63.8(a)(1)-(2) Yes
§63.8(a)(4) Yes
§63.8(b) Yes
§63.8(c)(1)-(3) Yes Provisions only apply if an add-on control system is used.
§63.8(c)(4) No
§63.8(c)(5) No Subpart SSSS does not require COMS.
§63.8(c)(6) Yes Provisions only apply if CEMS are used.
§63.8(c)(7)-(8) Yes
§63.8(d)-(e) Yes Provisions only apply if CEMS are used.
§63.8(f)(1)-(5) Yes
§63.8(f)(6) No Section 63.8(f)(6) provisions are not applicable because subpart SSSS does not require CEMS.
§63.8(g)(1)-(4) Yes
§63.8(g)(5) No
§63.9(a) Yes
§63.9(b)(1) Yes
§63.9(b)(2) Yes With the exception that §63.5180(b)(1) provides 2 years after the proposal date for submittal of the initial notification.
§63.9(b)(3)-(5) Yes
§63.9(c)-(e) Yes
§63.9(f) No Subpart SSSS does not require opacity and visible emissions observations.
§63.9(g) No Provisions for COMS are not applicable.
§63.9(h)(1)-(3) Yes
§63.9(h)(5)-(6) Yes
§63.9(i) Yes
§63.9(j) Yes
§63.10(b)(1)-(3) Yes Provisions pertaining to startups, shutdowns, malfunctions, and maintenance of air pollution control equipment and to CEMS do not apply unless an add-on control system is used. Also, paragraphs (b)(2)(vi), (x), (xi), and (xiii) do not apply.
§63.10(c)(1) No
§63.10(c)(5)-(8) No
§63.10(c)(10)-(15) No
§63.10(d)(1)-(2) Yes
§63.10(d)(3) No Subpart SSSS does not require opacity and visible emissions observations.
§63.10(d)(4)-(5) Yes
§63.10(e) No
§63.10(f) Yes
§63.11 Yes
§63.12 Yes
§63.13 Yes
§63.14 Yes Subpart SSSS includes provisions for alternative ASTM and ASME test methods that are incorporated by reference.
§63.15 Yes