Source: https://patents.google.com/patent/CN107045235A/en
Timestamp: 2019-12-08 07:59:49
Document Index: 332036745

Matched Legal Cases: ['Application No. 201180010369', 'arty 1014', 'arty 1014', 'arty 1014', 'arty 114', 'arty 114', 'arty 114', 'arty 114', 'arty 114', 'arty 114', 'arty 114', 'art 2213', 'art 2225', 'art 2227', 'art 2225', 'art 2225', 'art 2227', 'art 2273', 'art 2273', 'art 2273', 'art 2273', 'art 2277', 'art, 2214', 'art, 2227', 'art, 2231', 'art, 2279']

CN107045235A - Liquid crystal display device - Google Patents
CN107045235A
CN107045235A CN201610889237.9A CN201610889237A CN107045235A CN 107045235 A CN107045235 A CN 107045235A CN 201610889237 A CN201610889237 A CN 201610889237A CN 107045235 A CN107045235 A CN 107045235A
CN201610889237.9A
今藤敏和
2010-02-26 Priority to JP2010042584 priority Critical
2010-02-26 Priority to JP2010-042584 priority
2011-02-02 Application filed by 株式会社半导体能源研究所 filed Critical 株式会社半导体能源研究所
2011-02-02 Priority to CN201180010369.5A priority patent/CN102754022B/en
2017-08-15 Publication of CN107045235A publication Critical patent/CN107045235A/en
Entitled " liquid crystal display device " of the invention.An object of the present invention is to reduce the parasitic capacitance for the signal wire that liquid crystal display device includes.Using the transistor including oxide semiconductor layer, as being arranged on each pixel（100）In transistor（105）.Note, the oxide semiconductor layer is to become electron donor by thoroughly removing（Donor）Impurity（Hydrogen or water etc.）Obtain the oxide semiconductor layer of high purity.Thus, it is possible to reduce transistor（105）Leakage current during in cut-off state（OFF-state current）Amount.It therefore, it can remain applied to the voltage of liquid crystal cell and be not provided with capacitor in each pixel.In addition, being connected up with this subsidiary capacitor that can remove the pixel portion for extending to liquid crystal display device.Thus, it is possible to remove signal wire（103）The parasitic capacitance in the region of crossings on different level each other is connected up with capacitor.
The parent application day of this divisional application is 2 days 2 months, Application No. 201180010369.5, denomination of invention in 2011 For " liquid crystal display device ".The present invention relates to a kind of liquid crystal display device.
Popularized with the active array type LCD for being arranged as rectangular multiple pixels.In general, The pixel includes：Its grid is electrically connected to scan line and its source electrode is electrically connected to the transistor of signal wire with the side in drain electrode； It is public that the opposing party and its opposing party's terminal that one square end is electrically connected in the source electrode and drain electrode of the transistor are electrically connected to supply The wiring of common-battery position（Hereinafter also referred to capacitor is connected up）Capacitor；And one square end（Pixel electrode）It is electrically connected to this The square end of the opposing party and capacitor in the source electrode and drain electrode of transistor and its opposing party's terminal（Opposite electrode）Electrical connection To the liquid crystal cell for the wiring for supplying opposed current potential.
Figure 13 A to Figure 13 C show the configuration example of above-mentioned pixel.Figure 13 A are the top views of pixel.Note, Figure 13 A to figure 13C is the part for omitting liquid crystal cell（Liquid crystal layer, opposite electrode etc.）Figure（So-called active array substrate is shown）.Figure Pixel 1000 shown in 13A is arranged on by being arranged as scan line 1001 parallel or substantially parallel and scan line 1002 and row It is classified as in the region that orthogonal or generally normal to scan line 1001 and 1002 signal wire 1003 and signal wire 1004 are surrounded.Separately Outside, pixel 1000 includes transistor 1005, capacitor 1006 and pixel electrode layer 1007.Note, one as capacitor 1006 The conductive layer of square electrode layer（Capacitor wiring 1008）To be arranged as parallel or substantially parallel to scan line 1001 and 1002, and it is horizontal The mode for crossing multiple pixels is set.
Figure 13 B are the sectional views taken along the line A-B in Figure 13 A.Transistor 1005 includes：It is arranged on substrate 1010 Grid layer 1011；It is arranged on the gate insulator 1012 on grid layer 1011；It is arranged on the semiconductor on gate insulator 1012 Layer 1013；It is arranged on the side 1014a in the source layer and drain electrode layer on one end of semiconductor layer 1013；And be arranged on and partly lead The opposing party 1014b in source layer and drain electrode layer on the other end of body layer 1013.Capacitor 1006 includes：Capacitor is connected up 1008 part；It is arranged on the insulating barrier in capacitor wiring 1008（Gate insulator 1012）；Set on which insulating layer Source layer and drain electrode layer in the opposing party 1014b.Also, the opposing party 1014b in source layer and drain electrode layer is being arranged on crystalline substance In the contact hole 1016 formed in insulating barrier 1015 on body pipe 1005 and capacitor 1006, pixel electrode layer is electrically connected to 1007。
Figure 13 C are the sectional views taken along the line C-D in Figure 13 A.Signal wire 1003 is distinguished across gate insulator 1012 It is three-dimensional with scan line 1001, capacitor wiring 1008 and scan line 1002 in region 1017a, region 1017b and region 1017c Intersect.Therefore, signal wire 1003 is in region 1017a, 1017b and 1017c, and its upper surface has convex shape.Note, show Right signal wire 1004 also has and the identical upper surface shape of signal wire 1003.
Note, in the liquid crystal display device including pixel 1000 shown in Figure 13 A to Figure 13 C, scan line 1001,1002 And capacitor wiring 1008 is formed using identical conducting film, and the gate insulator 1012 in transistor 1005 is also served as Dielectric in capacitor 1006.That is, it is possible to say that the liquid crystal display device is the liquid crystal display for reducing manufacturing process's step Device.
In the pixel 1000 shown in Figure 13 A to Figure 13 C, there is transistor 1005 control to determine to be applied to liquid crystal cell Voltage（It is applied to the current potential of pixel electrode layer 1007）Data-signal input function, capacitor 1006 have keep apply To the voltage of liquid crystal cell（It is applied to the current potential of pixel electrode layer 1007）Function.
For example, when forming the dielectric of capacitor 1006 by thickness for 0.1 μm of silicon oxide film, its capacitance is The area of 0.4pF capacitor 1006 is about 1160 μm2.Here, when the size of pixel is 126 μm of 42 μ m（4 inches of VGA Pixel）When, it is about 22% for the ratio shared by the area capacitor 1006 of pixel, causes aperture opening ratio to reduce.Note, In above-mentioned dot structure, capacitor 1006 can also be removed.Because liquid crystal cell has storage capacitance in itself, even if not having Meaning ground sets capacitor 1006 to keep a certain amount of electric charge.But, the relative dielectric constant of liquid crystal is left for 3 when minimum Box gap right and that there are 3 to 4 μm（cell gap）.So static capacity is to use to be by 0.1 μm of silicon oxide film of thickness 1/50 or so of the static capacity of the device of dielectric capacitor 1006, it requires 58000 μm2The liquid crystal cell of left and right Area.Because the size is equivalent to the pixel that size is 420 μm of 140 μ m, resolution ratio is reduced to 60ppi or so, only when Liquid crystal display device, which has, can keep electric charge during below 60ppi resolution ratio.In other words, when with more than 60ppi resolution ratio When forming pixel, it is desirable to capacitor 1006.
In liquid crystal display device, by controlling the current potential of scan line 1001 transistor 1005 is turned into conducting state, and The current potential of signal wire 1003 is used as to the data-signal control to pixel 1000.Thus, it is possible to which desired voltage is applied to Included liquid crystal cell in pixel 1000.In addition, during the voltage is kept into certain by capacitor 1006 so that Ke Yi In each pixel desired display is carried out in certain period.The liquid crystal display device carries out this operation successively to each pixel, Thus image is formed in pixel portion（Still image）.Also, the liquid crystal display device makes the image change successively（For example, one Seconds 60 times（Frame rate is 60Hz））, to show dynamic image.
As described above, the dynamic image is formed by multiple still images.That is, it is strict for the dynamic image be not to connect Continuous image.Therefore, when the dynamic image that display is quickly moved, it is easy to after image is produced in display.Especially, in liquid crystal In showing device, from data-signal be input to each pixel in be input to the data-signal of next time in each pixel, each pixel remains aobvious Show.Thus, being readily apparent from of after image.In patent document 1, the technology for reducing after image is disclosed（Commonly referred to as " double frame rate is driven It is dynamic "）.Specifically, in patent document 1, following technology is disclosed：By forming interpolation between two images continuously displayed Image, and the image is inserted between two images continuously displayed so that reduce after image.
【With reference to】
【Patent document 1】Japanese patent application discloses H04-302289 publications.
It can be said that above-mentioned technology is to increase the technology for the data-signal number that time per unit is input to each pixel.Therefore, it is The technology is applied to liquid crystal display device, it is necessary to supply data-signal to the signal wire of each pixel with high speed operation.But, It is possible to produce parasitic capacitance between the signal wire of pixel portion and another wiring for extending to pixel portion extending to, and the parasitism Electric capacity hinders the high speed operation of signal wire.
Thus, the first purpose of an embodiment of the invention is to reduce signal wire included in liquid crystal display device Parasitic capacitance.
, should as the transistor being arranged in each pixel in the liquid crystal display device of an embodiment of the invention With the transistor including oxide semiconductor layer.Note, the oxide semiconductor layer is by thoroughly removing as electron donor （Donor）Impurity（Hydrogen or water etc.）Obtain the oxide semiconductor layer of high purity.Come from the carrier pole of hydrogen or oxygen defect etc. It is few（It is bordering on 0）, obtaining the oxide semiconductor layer of high purity has extremely low carrier, and carrier density is less than 1 ×1012/cm3Or less than 1 × 1011/cm3.That is, by the carrier for coming from hydrogen or oxygen defect etc. in oxide semiconductor layer Density is reduced to is bordering on 0 as far as possible.Because in oxide semiconductor layer, coming from the quantity pole of the carrier of hydrogen or oxygen defect etc. It is small, so when transistor is in cut-off state, the leakage current of transistor can be reduced（OFF-state current）.
Thus, it is possible to remain applied to the voltage of liquid crystal cell, and capacitor is not provided with each pixel.Furthermore it is possible to Remove the capacitor wiring for the pixel portion for extending to liquid crystal display device.Therefore, in the liquid crystal of an embodiment of the invention In display device, the parasitic capacitance produced in the region of crossings on different level each other is connected up in the absence of signal wire and capacitor.On the contrary, In conventional liquid crystal display device, in signal wire and scan line, the region of crossings on different level and signal wire and capacitor connect up that each other Parasitic capacitance is produced in the region of this crossings on different level.That is, it is possible to reduce the parasitic capacitance of signal wire.
Specifically, an embodiment of the invention is a kind of liquid crystal display device.The liquid crystal display device includes：Row It is classified as the first scan line and the second scan line parallel or substantially parallel；It is arranged as orthogonal or generally normal to described first The first signal wire and secondary signal line of scan line and second scan line；And its grid is electrically connected to first scanning A side in line and its source electrode and drain electrode is electrically connected to first signal wire and the opposing party's electrical connection in its source electrode and drain electrode Include the transistor of oxide semiconductor layer to pixel electrode layer.The pixel electrode layer is arranged on to be scanned by described first In the region that line, second scan line, first signal wire and the secondary signal line are surrounded.First signal wire and The secondary signal line is swept across the insulating barrier being arranged in first scan line and second scan line with described first Retouch line and the second scan line crossings on different level.The upper surface of first signal wire is in first signal wire and described first In the first area of scan line crossings on different level and first signal wire and the second scan line crossings on different level second area In, with convex shape, and in region between the first area and the second area, with flat shape or substantially Flat shape.That is, the whole upper surface of first signal wire is whole between the first area and second area In region, exist at grade or substantially on same plane.
In the liquid crystal display device of an embodiment of the invention, as the transistor being arranged in each pixel, make With the transistor including oxide semiconductor layer.Thus, it is possible to remove the capacitor being arranged in each pixel.Specifically, i.e., Make the liquid crystal display device that there is more than 60ppi resolution ratio, the voltage of liquid crystal cell can also be remained applied to and in each picture Capacitor is not provided with element.Thus, it is possible to improve the aperture opening ratio of each pixel.Liquid crystal display device is extended to furthermore it is possible to remove Pixel portion capacitor wiring.In other words, the liquid crystal display device is the liquid crystal display dress of the parasitic capacitance reduction of signal wire Put.Therefore, in the liquid crystal display device of an embodiment of the invention, with the signal wire in conventional liquid crystal display device Driving frequency compare, the driving frequency of signal wire can be increased.That is, the liquid crystal display of an embodiment of the invention Device is preferably used as the liquid crystal display device for carrying out double frame rate or the speed higher than double frame rate drives.
According to the first aspect of the invention there is provided a kind of display device, including:First scan line and the second scan line；Institute State the first insulating barrier on the first scan line and second scan line；Oxide semiconductor on first insulating barrier Layer；Signal wire on the oxide semiconductor layer；And the second insulating barrier on the signal wire, wherein the signal Line is respectively in the first crosspoint and the second crosspoint and first scan line and the second scan line crossings on different level, wherein institute State signal wire includes the first convex surface and the second convex surface in first crosspoint and second crosspoint respectively, wherein the letter It is substantially whole flat in number region of the line between first convex surface and second convex surface, wherein the oxide half Conductor layer is located at first crosspoint, and wherein described signal wire entirely connects in this region with first insulating barrier Touch.
Include according to the second aspect of the invention there is provided a kind of display device:First scan line and the second scan line；It is described The first insulating barrier on first scan line and second scan line；The first signal wire on first insulating barrier and Binary signal line；What first scan line, second scan line, first signal wire and the secondary signal line were surrounded Transistor, wherein the transistor include grid, first insulating barrier on the grid and first insulating barrier it On oxide semiconductor layer；The second insulating barrier on first signal wire and the secondary signal line；And described Pixel electrode on two insulating barriers, wherein first signal wire is respectively in the first crosspoint and the second crosspoint and described the Scan line and the second scan line crossings on different level, wherein first signal wire is respectively in first crosspoint and described Second crosspoint includes the first convex surface and the second convex surface, wherein first signal wire is on first convex surface and described second convex It is substantially whole flat in region between face, wherein the oxide semiconductor layer is located at first crosspoint, wherein First signal wire is entirely contacted in this region with first insulating barrier, and wherein described pixel electrode passes through position Contact hole in second insulating barrier is electrically connected to the transistor.
Figure 1A to Fig. 1 C is the top view and sectional view of an example of the structure for the pixel for showing liquid crystal display device；
Fig. 2 is the figure for the characteristic for showing transistor；
Fig. 3 is the evaluating characteristics circuit diagram of transistor；
Fig. 4 is the evaluating characteristics timing diagram of transistor；
Fig. 5 is the figure for the characteristic for showing transistor；
Fig. 6 is the figure for the characteristic for showing transistor；
Fig. 7 is the figure for the characteristic for showing transistor；
Fig. 8 A to Fig. 8 C are the sectional views of an example of the structure for the pixel for showing liquid crystal display device；
Fig. 9 A to Fig. 9 C are the sectional views of an example of the structure for the pixel for showing liquid crystal display device；
Figure 10 A and Figure 10 B are the sectional views of an example of the structure for the pixel for showing liquid crystal display device；
Figure 11 A to Figure 11 D are the sectional views of an example of the manufacturing process for showing transistor；
Figure 12 A to Figure 12 F are the figures for an example for showing electronic equipment；
Figure 13 A to Figure 13 C are the top view and sectional view of an example of the structure for the pixel for showing liquid crystal display device.
Embodiments of the present invention are described in detail next, with reference to accompanying drawing.Note, the present invention is not limited to following Illustrate, and person of an ordinary skill in the technical field should be readily understood that a fact is exactly not depart from the present invention Objective and its scope in the case of can carry out various change and modifications.Therefore, the present invention is not construed as It is limited to the following description.
（The configuration example of pixel）
First, knots of the reference picture 1A to Fig. 1 C to pixel included in the liquid crystal display device of an embodiment of the invention Structure example is illustrated.Specifically, reference picture 1A to Fig. 1 C is to by being provided with side's substrate of pixel electrode and setting It is equipped with the liquid crystal display device of the structure of the opposing party's substrate clamping liquid crystal material of opposite electrode（Vertical electric field is applied to liquid crystal The liquid crystal display device of material）The configuration example of pixel illustrate.
Figure 1A is the top view of pixel.Note, Figure 1A is the part for omitting liquid crystal cell（Liquid crystal layer, opposite electrode etc.） Figure（So-called active array substrate is shown）.Pixel 100 shown in Figure 1A is arranged on by being arranged as parallel to each other or substantially putting down Capable scan line 101 and scan line 102 and it is arranged as orthogonal or signal wire 103 generally normal to scan line 101 and 102 and letter In the region that number line 104 is surrounded.In addition, in pixel 100, being provided with transistor 105 and pixel electrode layer 107.In other words, scheme Pixel 100 shown in 1A has the structure that the relevant component of capacitor 1006 is omitted from the pixel 1000 shown in Figure 13 A.
Figure 1B is the sectional view that the line E-F shown in Figure 1A takes.Transistor 105 includes：Grid on a substrate 110 are set Pole layer 111；It is arranged on the gate insulator 112 on grid layer 111；It is arranged on the oxide semiconductor on gate insulator 112 Layer 113；It is arranged on the side 114a in the source layer and drain electrode layer on one end of oxide semiconductor layer 113；And be arranged on The opposing party 114b in source layer and drain electrode layer on the other end of oxide semiconductor layer 113.Note, in Figure 1A and Figure 1B institutes In the transistor 105 shown, the ledge by the use of scan line 101 as grid, and by the use of signal wire 103 ledge as A side in source electrode and drain electrode.Therefore, in the transistor 105 shown in Figure 1A and Figure 1B, grid can be expressed as scan line 101 A part, and the side in source electrode and drain electrode is expressed as a part for signal wire 103.The opposing party in source layer and drain electrode layer In the contact hole 116 that 114b is formed in the insulating barrier 115 being arranged on transistor 105, pixel electrode layer 107 is electrically connected to.
Fig. 1 C are the sectional views that the line G-H shown in Figure 1A takes.Signal wire 103 is across insulating barrier（Gate insulator 112）Respectively in region 117a and region 117c with scan line 101, and the crossings on different level of scan line 102.Therefore, signal wire 103 In region 117a, 117c, its upper surface has convex shape.Furthermore, signal wire 103 is between region 117a and region 117c Region 117b in, its upper surface has flat shape or substantially flat shape.That is, the upper surface of signal wire 103 is in area In whole region 117b between domain 117a and 117c, exist at grade or substantially on same plane.This be due to It is not provided with liquid crystal display device including pixel 100 caused by capacitor wiring.Note, it is clear that signal wire 104 also has With the identical upper surface shape of signal wire 103.
As described above, the transistor 105 shown in Figure 1A to Fig. 1 C is used as semiconductor layer including oxide semiconductor layer 113. As the oxide semiconductor for oxide semiconductor layer 113, it can use：The In-Sn-Ga-Zn- of quaternary metallic oxide O base oxide semiconductors；In-Ga-Zn-O base oxides semiconductor, the In-Sn-Zn-O base oxides half of ternary metal oxide Conductor, In-Al-Zn-O base oxides semiconductor, Sn-Ga-Zn-O base oxides semiconductor, Al-Ga-Zn-O base oxides are partly led Body, Sn-Al-Zn-O base oxide semiconductors；In-Zn-O base oxides semiconductor, the Sn-Zn-O base oxygen of binary metal oxide Compound semiconductor, Al-Zn-O base oxides semiconductor, Zn-Mg-O base oxides semiconductor, Sn-Mg-O base oxides semiconductor, In-Mg-O base oxide semiconductors；Or In-O base oxides semiconductor, the Sn-O base oxides of unit metal oxide are partly led Body, Zn-O base oxide semiconductors.In addition, above-mentioned oxide semiconductor can also include SiO2.Here, such as In-Ga-Zn-O Base oxide semiconductor refers at least include In, Ga and Zn oxide, and its ratio of components is had no particular limits.In addition, In-Ga-Zn-O base oxides semiconductor can also include the element beyond In, Ga and Zn.
In addition, for oxide semiconductor layer 113, can use with Formula I nMO3（ZnO）m（m>0）The film of expression. Here, M represents one or more metallic elements in Ga, Al, Mn and Co.For example, M can be Ga, Ga and Al, Ga and Mn, Ga and Co etc..
In order to suppress electrical characteristics change, above-mentioned oxide semiconductor removed by intention property the hydrogen as variable, Moisture, hydroxyl or hydride（Also referred to as hydrogen compound）Deng impurity come to obtain high purity with electrical I types（It is intrinsic）In the presence of.
It is therefore preferable that oxide semiconductor includes hydrogen as few as possible.In addition, obtaining the oxide semiconductor of high purity Layer has the considerably less carrier for coming from hydrogen or oxygen defect etc.（It is bordering on zero）, carrier density is less than 1 × 1012/cm3Or be less than 1×1011/cm3.That is so that the carrier density for coming from hydrogen or oxygen defect etc. in oxide semiconductor layer, which is tried one's best, to be bordering on 0.Because in oxide semiconductor layer, the carrier for coming from hydrogen or oxygen defect etc. is few, so transistor is in cut-off state When, leakage current（OFF-state current）Amount be small.It is preferred that the amount of OFF-state current is small as far as possible.Including above-mentioned Oxide semiconductor is used as in the transistor of semiconductor layer, per micron channel width（w）Current value be 100zA/ μm （zeptoampere）Hereinafter, below less than 10zA/ μm, or 1zA/ μm.Also, due to no pn-junction and deterioration of hot-carrier, Therefore the electrical characteristics of transistor do not become negatively affected.
The oxide of high purity will be obtained by the hydrogen thoroughly removed included in oxide semiconductor layer as described above Semiconductor is used in the channel formation region of transistor, it is possible thereby to obtain indivisible cut-off current.That is, in transistor During in nonconducting state, oxide semiconductor layer can be regarded as insulator and carry out circuit design.On the other hand, in crystal When managing in the conduction state, it can expect that the high oxide of the electric current deliverability of the semiconductor layer than being formed by non-crystalline silicon is partly led The electric current deliverability of body layer.
As substrate 110, the glass substrate of barium borosilicate glass or alumina-borosilicate glass etc. can be used.
In transistor 105, the dielectric film as basilar memebrane can also be arranged between substrate 110 and grid layer 111. Basilar memebrane has the function of preventing that impurity element from spreading from substrate 110, and can use by silicon nitride film, silicon oxide film, nitrogen One or more films in silicon oxide film and oxygen silicon nitride membrane are formed with laminated construction or single layer structure.
As grid layer 111, it can use：Selected from aluminium（Al）, copper（Cu）, titanium（Ti）, tantalum（Ta）, tungsten（W）, molybdenum（Mo）、 Chromium（Cr）, neodymium（Nd）, scandium（Sc）In element；Include the alloy of these any elements；Or include the nitrogen of these any elements Compound.Alternatively, it is also possible to use the laminated construction of these materials.
As gate insulator 112, it can use such as lower insulator：By using plasma CVD method or sputtering method etc. Come the silicon oxide layer formed, silicon nitride layer, silicon oxynitride layer, silicon oxynitride layer, alumina layer, aln layer, oxynitriding aluminium lamination, Nitrogen oxidation aluminium lamination or hafnium oxide layer etc..Alternately, the laminated construction of these insulators can also be used.For example, by wait from Daughter CVD, it is more than 50nm and below 200nm silicon nitride layer that can form thickness（SiNy（Y ＞ 0））It is used as first grid Insulating barrier, it is possible to the silicon oxide layer that thickness is more than 5nm and below 300nm is laminated on first grid insulating barrier（SiOx（x ＞ 0））It is used as second grid insulating barrier.
, can as the material of the opposing party 114b in a side 114a, source layer and the drain electrode layer in source layer and drain electrode layer To use：Selected from aluminium（Al）, chromium（Cr）, copper（Cu）, tantalum（Ta）, titanium（Ti）, molybdenum（Mo）, tungsten（W）In element；Comprising it is any this The alloy of a little elements；Or include the nitride of these any elements.The laminated construction of these materials can also be used.As standby Choosing, can also be used in aluminium（Al）, copper（Cu）Deng metal level downside and/or upside stacking titanium（Ti）, molybdenum（Mo）, tungsten（W） Deng high melting point metal layer structure.Alternatively, it is also possible to by using added with preventing in aluminium（Al）Hillock or crystalline substance are produced in film The element of palpus（Si, Nd, Sc etc.）Aluminium alloy, to improve heat resistance.
Note, in above-mentioned liquid crystal display device, the side 114a in source layer and drain electrode layer is one of signal wire 103 Point.Therefore, from the viewpoint of the high-speed driving of signal wire 103, source layer and drain electrode layer preferably use low resistance conductive material To be formed so that suppress the delay of signal.For example, it is preferable to use copper（Cu）Or using copper as the low of the alloy of main structural elements etc. Resistance conductive material is formed.Alternately, source layer and drain electrode layer, which can have, includes copper（Cu）Or using copper as primary structure The laminated construction of the layer of the alloy of element.
Note, in above-mentioned liquid crystal display device, capacitor is not provided with pixel 100.Therefore, from pixel 100 From the viewpoint of the holding of data-signal, metal nitride is preferably used as source layer and drain electrode layer, to be suppressed to oxide The flowing of the carrier of semiconductor layer.For example, it is preferable to use the nitride of titanium nitride, tungsten nitride etc..Alternately, it can also adopt Following laminated construction is used, that is, the layer for being contacted with oxide semiconductor layer is formed using the nitride of titanium nitride or tungsten nitride etc., And form other conductive layers on its upper strata.It is for instance possible to use tungsten nitride and copper（Cu）Deng laminated construction.
Alternately, as source layer and drain electrode layer 114a and 114b（Including the use of with these layer of 114a and 114b The wiring layer that identical layer is formed）Conducting film, conducting metal oxide can also be used to be formed.It is used as conductive metal oxide Thing, can use indium oxide（In2O3）, tin oxide（SnO2）, zinc oxide（ZnO）, indium oxide tin oxide（In2O3-SnO2, abbreviation For ITO）, indium oxide zinc oxide（In2O3-ZnO）Or wherein include any one of metal oxide of silica.
As insulating barrier 115, inorganic insulating membrane such as silicon oxide film, oxygen silicon nitride membrane, aluminum oxide can be typically used Film or oxynitriding aluminium film etc..
As insulating barrier 115, inorganic insulating membrane such as silicon nitride film, aluminium nitride film, silicon oxynitride film, nitrogen oxygen can be used Change aluminium film etc..
Planarization insulating film can be formed on insulating barrier 115, to reduce the concave-convex surface due to transistor 105. As planarization insulating film, the organic material of polyimides, acrylic resin, benzocyclobutane alkenyl resin etc. can be used.Remove Outside above-mentioned organic material, it is also possible to use advanced low-k materials（Low-k materials）Deng.Note, can also be many by being laminated The individual dielectric film formed by these materials forms planarization insulating film.
（The OFF-state current of transistor 105）
Then, the measurement to the OFF-state current of the transistor of the oxide semiconductor layer including obtaining high purity is obtained Result illustrate.
First, it is contemplated that the OFF-state current of the transistor including the oxide semiconductor layer for obtaining high purity is minimum Situation, prepare the sufficiently large i.e. 1m transistors of its channel width W, then measure OFF-state current.Fig. 2 shows channel width W obtains result by the measurement of the OFF-state current of 1m transistor.In fig. 2, transverse axis shows grid voltage VG, and indulge Axle shows leakage current ID.As drain voltage VDFor+1V or+10V and when grid voltage VG is in the range of -5V to -20V, hair The OFF-state current of existing transistor is 1 × 10 as detection limit-12Below A.It moreover has been found that the cut-off state of transistor Current density（Per unit channel width（1μm））For 1aA/ μm（1×10-18A/μm）Below.
Then, the survey to more accurately including obtaining the cut-off current of the transistor of the oxide semiconductor layer of high purity The obtained result of amount is illustrated.As described above, finding to include obtaining the transistor of the oxide semiconductor layer of high purity OFF-state current when as measuring apparatus detection limit 1 × 10-12Below A.Therefore, manufacturing characteristics evaluation will be used The result that the measurement of element and more accurately OFF-state current is obtained（The detection limit of measuring apparatus in above-mentioned measurement with Under value）Illustrate.
First, 3 pairs of evaluating characteristics for being used to use in current measuring method of reference picture are illustrated with element.
In the evaluating characteristics element shown in Fig. 3, three measuring systems 800 are connected in parallel.Measuring system 800 includes： Capacitor 802；Transistor 804；Transistor 805；Transistor 806；And transistor 808.It is used as transistor 804, transistor 808, use the transistor of the oxide semiconductor layer including obtaining high purity.
In measuring system 800, square end, the crystalline substance of a side, capacitor 802 in the source electrode and drain electrode of transistor 804 A side in the source electrode and drain electrode of body pipe 805 is connected to power supply（Apply V2 power supply）.In addition, source electrode and the leakage of transistor 804 The side's in the opposing party, the source electrode and drain electrode of transistor 808, the opposing party's terminal of capacitor 802, transistor 805 in extremely Grid is electrically connected to each other.In addition, in the opposing party, the source electrode and drain electrode of transistor 806 in the source electrode and drain electrode of transistor 808 One side, the grid of transistor 806 are electrically connected to power supply（Supply V1 power supply）.It is another in the source electrode and drain electrode of transistor 805 The opposing party in the source electrode and drain electrode of side and transistor 806 is electrically connected to lead-out terminal.
Note, the conducting state of controlling transistor 804 and the current potential of cut-off state are supplied to the grid of transistor 804 Vext_b2.The conducting state of controlling transistor 808 and the current potential V of cut-off state are supplied to the grid of transistor 808ext_b1.In addition, From lead-out terminal output current potential Vout。
Then, by being illustrated using above-mentioned evaluating characteristics with the current measuring method of element.
First, by apply potential difference to measure OFF-state current initial stage during overview illustrate. During initial stage, the grid input to transistor 808 makes transistor 808 turn into the current potential V of conducting stateext_b1, and to being electrically connected The node for the opposing party being connected in the source electrode and drain electrode of transistor 804（That is, it is electrically connected to source electrode and the leakage of transistor 808 The node of the opposing party's terminal of a side, capacitor 802 in extremely and the grid of transistor 805）, i.e. node A application current potentials V1. This, current potential V1 is, for example, high potential.Transistor 804 is set to be in cut-off state.
Then, the grid input to transistor 808 makes transistor 808 turn into the current potential V of cut-off stateext_b1, make transistor 808 turn into cut-off state.After transistor 808 is turned into cut-off state, current potential V1 is set to low.Still it is in transistor 804 Cut-off state.Current potential V2 is and current potential V1 identical current potentials.Therefore, completed during initial stage.In the state of being completed during in the early stage, Potential difference occurs between a side in the source electrode and drain electrode of node A and transistor 804, also, in node A and transistor 808 Source electrode and drain electrode in the opposing party between occur potential difference.So electric charge seldom flows through transistor 804 and transistor 808.Just It is to say, OFF-state current flowing.
Then, the overview during the measurement of OFF-state current is illustrated.During measuring, by transistor 804 Source electrode and drain electrode in a side current potential（V2）And the current potential of the opposing party in the source electrode and drain electrode of transistor 808（V1）It is set to It is low and fixed.On the other hand, in during measuring, not stationary nodes A current potential（Node A is in quick condition）.Thus, in crystalline substance Flow through electric charge in body pipe 804, transistor 808, also, process over time and be held in the change of the quantity of electric charge in node A.And And, as the quantity of electric charge being held in node A changes, node A potential change.That is, the output current potential V of lead-out terminalout Also change.
The relation between each current potential in during Fig. 4 shows initial stage using potential difference and during measurement hereafter it is detailed Situation（Timing diagram）.
During in the early stage, first, by current potential Vext_b2It is set as transistor 804 is turned into the current potential of conducting state（High electricity Position）.Thus, node A current potential is low potential as V2（VSS）.Note, by low potential（VSS）Node A is applied to be not required Want.Then, by current potential Vext_b2It is set as transistor 804 is turned into the current potential of cut-off state（Low potential）, thus make transistor 804 turn into cut-off state.Then, by current potential Vext_b1It is set as transistor 808 is turned into the current potential of conducting state（High potential）. Thus, node A current potential is high potential as V1（VDD）.Then, by current potential Vext_b1It is set as transistor 808 is turned into cut-off The current potential of state.Thus, completed during bringing node A into quick condition, and initial stage.
During measurement thereafter, current potential V1 and current potential V2 are each set as that electric charge flows there through node A or from node A Flow out the current potential of electric charge.Here, current potential V1 and current potential V2 are low potentials（VSS）.Note, due in measurement output current potential VoutWhen Have to make output circuit work in sequence, so V1 is temporarily set into high potential sometimes（VDD）.V1 is set as high potential （VDD）During be short so that not interfering with measurement.
When produce potential difference as described above and when during starting measurement, process over time and be held in node A The quantity of electric charge changes, and it causes node A potential change.This means the potential change of the grid of transistor 805, thus with when Between process and the output current potential V of lead-out terminaloutCurrent potential also change.
The method for illustrating to calculate OFF-state current based on the output current potential Vout obtained below.
Node A current potential V is first obtained before cut-off current is calculatedAWith output current potential VoutRelation.Thus, it is possible to make With output current potential VoutObtain node A current potential VA.According to above-mentioned relation, node A current potential VAIt is used as output current potential VoutFunction And can be expressed with following formula.
In addition, node A charge QAUsing node A current potential VA, be connected to node A electric capacity CA, constant（const）And use Following formula expression.Here, being connected to node A electric capacity CAIt is the electric capacity of capacitor 802 and the sum of other electric capacity.
Because node A electric current IAIt is the electric charge for flowing to node A（Or the electric charge flowed out from node A）Time diffusion, so Node A electric current IAExpressed with following formula.
In this way, according to the electric capacity C for being connected to node AAWith the output current potential V of lead-out terminalout, node A electric current can be obtained IA。
According to the above method, the leakage electricity flowed between the source electrode of the transistor of possible measurement in the off state and drain electrode Stream（OFF-state current）.
Here, the use of channel length L being the oxide semiconductor for obtaining high purity that 10 μm and channel width W are 50 μm Layer forms transistor 804 and 808.In addition, in the measuring system 800 being arranged in parallel, respectively by the capacitance of capacitor 802 It is set as 100fF, 1pF, 3pF.
Note, in above-mentioned measurement, VDDIt is 5V and VSSIt is 0V.It is V by current potential V1 basic settings in during measuringSS, And only during 100 milliseconds in every 10 seconds to 300 seconds in current potential V1 is set as VDD.In addition, the electricity for flowing through element The Δ t flowed in I calculating is about 30000 seconds.
Fig. 5 shows the elapsed time Time according to above-mentioned current measurement（Time）With output current potential VoutRelation.According to figure 5, process over time and potential change.
Fig. 6 shows to calculate in room temperature based on above-mentioned current measurement（25℃）OFF-state current.Note, Fig. 6 is Relation between transistor 804 or the source-drain voltages V and OFF-state current I of transistor 808 is shown.According to Fig. 6, Source-drain voltages are about 40zA/ μm for OFF-state current under conditions of 4V.In addition, being 3.1V in source-drain voltages Under conditions of, OFF-state current is less than 10zA/ μm.Note, 1zA represents 10-21A。
Fig. 7 shows the OFF-state current in 85 DEG C of temperature environment calculated based on above-mentioned current measurement.Fig. 7 shows Go out between the transistor 804 in 85 DEG C of temperature environment or the source-drain voltages V and OFF-state current I of transistor 808 Relation.According to Fig. 7, OFF-state current is less than 100zA/ μm under conditions of source-drain voltages are 3.1V.
According to the above results, confirm：In the transistor of the oxide semiconductor layer including obtaining high purity, end shape State electric current can be sufficiently small.
（Include the liquid crystal display device of pixel 100）
In liquid crystal display device disclosed in this specification, as the transistor being arranged in each pixel, using including oxidation The transistor 105 of thing semiconductor layer.Because the OFF-state current for the transistor 105 that should include oxide semiconductor layer is small, institute In the liquid crystal display device, the voltage of liquid crystal cell can be remained applied to and capacitor is not provided with each pixel.By This, can improve the aperture opening ratio in each pixel.Furthermore it is possible to remove the capacitor cloth for the pixel portion for extending to liquid crystal display device Line.Therefore, in liquid crystal display device disclosed in this specification, the parasitic capacitance not connected up due to capacitor.Specifically For, connected up without signal wire and capacitor across parasitic capacitances such as the electric capacity provided in the region of insulating barrier crossings on different level.Knot Really, in liquid crystal display device disclosed in this specification, the driving frequency of signal wire can be improved.That is, this specification Disclosed liquid crystal display device is preferably used as carrying out the speed driving of double frame rate driving or higher than double frame rate Liquid crystal display device.
When carrying out the speed driving of double frame rate driving or higher than double frame rate, the data-signal in each pixel Rewrite frequencies increase.That is, shortened during the voltage for the liquid crystal cell being applied in each pixel.It therefore, it can into one Step reduces the variation for the voltage for being applied to liquid crystal cell（The deterioration of display in each pixel（Change））.In addition, working as this specification Disclosed liquid crystal display device by field-sequential method system to drive when can also obtain similar effect.That is, to this theory It is preferred that liquid crystal display device disclosed in bright book, which is carried out by field-sequential method driving,.
Especially, liquid crystal display device disclosed in this specification is used as large-scale liquid crystal display device（For example, the English of size 40 More than very little）Effect when using is very big.With the size increase of liquid crystal display device, due to the data-signal of routing resistance etc. Delay etc. easily occurs.In contrast, in liquid crystal display device disclosed in this specification, reduce what is produced in signal wire Parasitic capacitance so that delay of data-signal etc. can be reduced.In addition, when small-sized liquid crystal display device and large-scale liquid crystal display are filled When pixel count in putting is identical, included each pixel becomes large-sized in large-scale liquid crystal display device.This means liquid crystal cell The capacitance of part in itself becomes big.Therefore, in addition to being used in each pixel and including the transistor 105 of oxide semiconductor layer, The variation that the capacitance of liquid crystal cell in itself becomes the voltage big, liquid crystal cell is applied to reduction has been contributed.
In addition, liquid crystal display device disclosed in this specification is used as fine definition（Pixel count is big）Liquid crystal display device （For example, overall height definition（FHD）, more than 2K4K definition）Effect when using is very big.With the high definition of liquid crystal display device Clearization（The increase of pixel count）The subsidiary cloth line number increase being arranged in pixel portion so that the parasitic capacitance produced in signal wire Easily increase.In contrast, can because being not provided with capacitor wiring in liquid crystal display device disclosed in this specification To reduce the increase of parasitic capacitance.In addition, ought be in the liquid crystal display device and the few liquid crystal display device of pixel count more than pixel count In, the liquid crystal display device it is equal sized when, the wiring density increase in the pixel portion of the former device.This means each pixel Aperture opening ratio reduction.In contrast, in liquid crystal display device disclosed in this specification, electric capacity is not provided with each pixel Device, it is possible to suppress the reduction of aperture opening ratio.
In addition, in conventional liquid crystal display device, the main basis of retention performance of the data-signal of each pixel is arranged on The characteristic of the transistor set in each pixel（The value of OFF-state current）Determine.But by by including obtaining high purity The transistor 105 of oxide semiconductor layer is used as the transistor being arranged in each pixel, mainly according to the characteristic of liquid crystal cell（ The electric current flowed in liquid crystal cell）Determine.In other words, in liquid crystal display device disclosed in this specification, liquid crystal cell is passed through The influence of leakage of the influence than the electric charge by transistor 105 of the leakage of the electric charge of part is big.Therefore, wrapped as in liquid crystal cell The liquid crystal material included, preferably uses the high material of its intrinsic resistance rate.Specifically, in liquid crystal display disclosed in this specification In device, the intrinsic resistance rate of liquid crystal material is 1 × 1012More than Ω cm, preferably more than 1 × 1013Ω cm, more preferably For higher than 1 × 1014Ω·cm.Because the possibility that impurity is mixed into from alignment films or encapsulant, work as and use the liquid crystal material Expect to be formed during liquid crystal cell, the resistivity of liquid crystal cell is preferably 1 × 1011More than Ω cm, more preferably higher than 1 × 1012 Ω·cm.Note, the value of the intrinsic resistance in this specification is defined in 20 DEG C of values measured.
（The version of the structure of pixel）
Liquid crystal display device with said structure is an embodiment of the invention, and present invention additionally comprises in some points and tool There is the different liquid crystal display device of the liquid crystal display device of said structure.
Although, in above-mentioned liquid crystal display device, between signal wire 103 and scan line 101 and signal wire 103 and scanning Gate insulator 112 is only set between line 102（Reference picture 1C）, but can also signal wire 103 and gate insulator 112 it Between set oxide semiconductor layer 201（Reference picture 8A）.That is, forming the oxide semiconductor that transistor 105 includes The process of layer 113（Photo-mask process and etching work procedure）In, can also be in the region for forming signal wire 103 below not to oxide Semiconductor layer remains it in the case of being etched.Therefore, by being set between signal wire 103 and gate insulator 112 Oxide semiconductor layer 201, can further be reduced between signal wire 103 and scan line 101 and signal wire 103 and scan line Parasitic capacitance between 102.
Alternatively, it is also possible to optionally set oxide semiconductor layer between signal wire 103 and gate insulator 112. For example, can be respectively in the region 117a and signal wire 103 and scan line of the crossings on different level each other of signal wire 103 and scan line 101 102 each other in the region 117c of crossings on different level, optionally sets oxide semiconductor layer 202a and oxide semiconductor layer 202b（Reference picture 8B）.Alternatively, it is also possible to using in addition to region 117a, 117c, be selected also in a region 117b part Oxide semiconductor layer 202a, 202b structure are set to selecting property（Reference picture 8C）.Note, in the case, due to signal wire There is platform in oxide semiconductor layer between 103 and gate insulator 112, the upper surface of the signal wire 103 in the 117b of region Rank, but in this manual, the upper surface shape can be regarded as substantially flat shape.In other words, it is being clipped in scan line 101st, in the whole region between the step that scan line 102 and oxide semiconductor layer 202a, 202b a part are caused, signal Line 103 and gate insulator 112 are in direct contact with one another, also, in this region, the whole upper surface of signal wire 103 is all same Exist in one plane or substantially on same plane.
In above-mentioned liquid crystal display device, as the transistor being arranged in each pixel, using as with bottom grating structure Transistor a kind of channel etch type transistor 105（Reference picture 1B）, but the crystalline substance with other structures can also be used Body pipe.It is, for example, possible to use being used as a kind of channel stop transistor npn npn 210 of the transistor with bottom grating structure（Reference picture 9A）, or it is used as a kind of bottom contact transistor npn npn 220 of the transistor with bottom grating structure（Reference picture 9B）.
Specifically, the channel stop transistor npn npn 210 shown in Fig. 9 A includes：Grid layer on a substrate 110 is set 111；It is arranged on the gate insulator 112 on grid layer 111；It is arranged on the oxide semiconductor layer on gate insulator 112 113；It is arranged on the insulating barrier 211 as channel protective layer on the central portion of oxide semiconductor layer 113；It is arranged on oxide The side 114a in source layer and drain electrode layer on one end of semiconductor layer 113 and one end of insulating barrier 211；And it is arranged on oxygen The opposing party 114b in source layer and drain electrode layer on the other end of compound semiconductor layer 113 and the other end of insulating barrier 211.Note Meaning, insulating barrier 211 can use inorganic insulating membrane silicon oxide film, oxygen silicon nitride membrane, pellumina or oxynitriding aluminium film etc. To be formed.
Bottom contact transistor npn npn 220 shown in Fig. 9 B includes：Grid layer 111 on a substrate 110 is set；It is arranged on grid Gate insulator 112 on layer 111；It is arranged on a side 114a and source in the source layer and drain electrode layer on gate insulator 112 The opposing party 114b in pole layer and drain electrode layer；And be arranged on one end of the side 114a in source layer and drain electrode layer, source electrode Oxide semiconductor layer 113 on one end of the opposing party 114b in layer and drain electrode layer and on gate insulator 112.
Also, can be in signal wire 103 when the transistor being arranged in each pixel is channel stop transistor npn npn 210 Insulating barrier 212 is set between gate insulator 112（Reference picture 9C）.Note, insulating barrier 212 be use with transistor 210 The included identical material of insulating barrier 211 as channel protective layer is come the insulating barrier that is formed.Alternatively, it is also possible to exhausted in grid Oxide semiconductor layer is set between edge layer 112 and insulating barrier 212（It is not shown）.Note, the oxide semiconductor layer is to use The oxide semiconductor layer formed with the identical material of oxide semiconductor layer 113 included in transistor 210.Also, Only the oxide semiconductor layer and the insulating barrier can also be optionally set in scan line 101 and scan line 102（Do not scheme Show）.
Alternately, top gate-type transistors 230 can also be used（Reference picture 10A）It is used as transistor 105.Specifically, Top gate-type transistors 230 shown in Figure 10 A include：Base insulating layer 231 on a substrate 110 is set；It is arranged on substrate insulation Oxide semiconductor layer 113 on layer 231；It is arranged on the gate insulator 112 on oxide semiconductor layer 113；It is arranged on grid Grid layer 111 on pole insulating barrier 112；In the insulating barrier 232 being arranged on oxide semiconductor layer 113 and grid layer 111 The side 114a in the source layer and drain electrode layer of oxide semiconductor layer 113 is contacted with the contact hole 233a of formation；And Oxidation is contacted with the contact hole 233b formed in the insulating barrier 232 being arranged on oxide semiconductor layer 113 and grid layer 111 The opposing party 114b in the source layer and drain electrode layer of thing semiconductor layer 113.The opposing party 114b in source layer and drain electrode layer is being set Put in the contact hole 235 formed in the insulating barrier 234 on transistor 230 and be electrically connected to pixel electrode layer 107.In this situation Under, signal wire 103 is in region 117a and 117c, across insulating barrier 232 and scan line 101,102 crossings on different level（Reference picture 10B）.Note, base insulating layer 231 could be formed with using silicon nitride film, silicon oxide film, silicon oxynitride film and oxygen silicon nitride membrane In one or more films laminated construction or single layer structure.Insulating barrier 232 could be formed with using silicon oxide film, silicon nitride Film, oxygen silicon nitride membrane, silicon oxynitride film, pellumina, aluminium nitride film, oxynitriding aluminium film, nitrogen oxidation aluminium film and hafnium oxide film etc. Inorganic insulator in one or more films laminated construction or single layer structure.Note, insulating barrier 234 can be used and insulated The similar inorganic insulator film of inorganic insulator of layer 232 uses polyimides, allyl resin, benzocyclobutane alkenyl resin etc. Organic material formed.
, can also be in each pixel although in above-mentioned liquid crystal display device, a transistor is set in each pixel It is middle that more than two transistors are set.For example, for vertical orientation（Vertical Alignment；VA）The liquid crystal display of mode The problem of relevant visual angle of device, in the case that two transistors are arranged in each pixel, it can use and partly be led including oxide The transistor of body layer is used as the two transistors.Here, the liquid crystal display device is considered as including passing through crystal in each pixel The liquid crystal display device of two flux leakage paths of pipe.Therefore, in conventional liquid crystal display device, by setting two in each pixel Individual capacitor, increases the area of capacitor to remain applied to the voltage of liquid crystal cell.In other words, sacrifice aperture opening ratio and keep applying It is added to the voltage of liquid crystal cell.In contrast, in liquid crystal display device disclosed in this specification, substantially reduce by including The electric charge of the transistor of oxide semiconductor layer is sewed so that can remove capacitor in itself.That is, in this specification institute In disclosed liquid crystal display device, multiple transistors are set to maintain high aperture in each pixel.
（The specific example of the manufacture method of transistor）
Below, as an example of the transistor being arranged in each pixel of liquid crystal display device disclosed in this specification, Manufacture works of the reference picture 11A to Figure 11 D to a kind of channel etch type transistor 410 as the transistor with bottom grating structure Sequence is illustrated.Although being shown in which single gate transistor, it can also be formed as needed with multiple channel formation regions Multiple-gate transistor.
Below, reference picture 11A to Figure 11 D, is illustrated to the process that transistor 410 is manufactured on substrate 400.
First, conducting film is formed on the substrate 400 with insulating surface, and carries out thereon the first photo-mask process, So that forming grid layer 411.Note, the Etching mask used in the process can also be formed by ink-jet method.When making Formed with ink-jet method during Etching mask because without using photomask, it is possible to reduce manufacturing cost.
Although there is no special limitation to the substrate that can be used as the substrate 400 with insulating surface, at least have to With the heat resistance that can bear heating degree below.It is, for example, possible to use barium borosilicate glass, aluminoborosilicate The glass substrate of glass etc..When using glass substrate and followed by heating temperature it is higher when, preferably use should Height is more than 730 DEG C of glass substrate.
The insulating barrier of basalis can also be set between substrate 400 and grid layer 411.Basalis, which has, prevents miscellaneous The function that prime element spreads from substrate 400, it is possible to be formed with using silicon nitride film, silicon oxide film, silicon oxynitride film and oxygen nitrogen The laminated construction or single layer structure of one or more films in SiClx film.
Grid layer 411 can be formed into the metal using molybdenum, titanium, chromium, tantalum, tungsten, aluminium, copper, neodymium or scandium etc. or comprising appointing What these metal material as the alloy of key component single layer structure or laminated construction.
For example, being used as the double-decker of grid layer 411, preferably following structure：The structure of molybdenum layer is laminated on aluminium lamination； The double-decker of molybdenum layer is laminated in layers of copper；The structure of Azide titanium layer or tantalum nitride layer on layers of copper upper strata；Or stacking nitridation The structure of titanium layer and molybdenum layer.As three-decker, preferably tungsten layer or tungsten nitride layer, the alloy-layer or aluminium of aluminium and silicon and titanium The lamination of alloy-layer and titanium nitride layer or titanium layer.
Then, gate insulator 402 is formed on grid layer 411.
Gate insulator 402 can be formed into using the silicon oxide layer by plasma CVD method or sputtering method etc., Silicon nitride layer, silicon oxynitride layer, the individual layer or laminated construction of silicon oxynitride layer and alumina layer.For example, using silane（SiH4）、 Oxygen and nitrogen simultaneously form silicon oxynitride layer using plasma CVD method, are used as deposition gases.In addition it is possible to use hafnium oxide (HfOx) or tantalum oxide (TaOx) etc. high-g value be used as gate insulator 402.The thickness of gate insulator 402 is formed as More than 100nm and below 500nm, when using for example laminated construction is to form gate insulator 402 when, stacking thickness be 50nm with Upper and below 200nm first grid insulating barrier and thickness is more than 5nm and below 300nm second grid insulating barrier.
Here, by plasma CVD method formation silicon oxynitride layer, it is used as gate insulator 402.
As gate insulator 402, high-density plasma device formation silicon oxynitride layer can be used.Here high density Plasma device refers to can be achieved 1 × 1011/cm3The device of plasma density above.For example, applying 3kW to 6kW Microwave power produce plasma so that forming insulating barrier.
In the reaction chamber, as unstrpped gas（source gas）Introduce silane（SiH4）, nitrous oxide（N2O）And it is dilute There is gas.Then high-density plasma is produced under 10Pa to 30Pa pressure, and there is insulation meter in glass substrate etc. Insulating barrier is formed on the substrate in face.Then, silane is stopped（SiH4）Supply, it is possible to do not make insulating layer exposing in air Under the conditions of introduce nitrous oxide（N2O）Corona treatment is carried out to surface of insulating layer with rare gas.Pass through above-mentioned operation The insulating barrier of process formation can also have been contributed the high reliability of transistor even if its thickness of thin.
When forming gate insulator 402, the silane in reative cell is incorporated into（SiH4）And nitrous oxide（N2O）Stream Ratio is measured 1：10 to 1：In the range of 200.As the rare gas being incorporated into reative cell, helium, argon, krypton, xenon etc. can be used. Especially, cheap argon is preferably used.
Because the insulating barrier formed using high-density plasma device can have uniform thickness so with superior Step coverage.In addition, using high-density plasma device, accurate control can be carried out to the thickness of thin dielectric membrane.
The insulating barrier formed by above-mentioned operation process using conventional parallel plate-type plasma CVD equipment with being formed Insulating barrier make a world of difference.When being compared using identical etchant to etching speed, formed by above-mentioned operation process Insulating barrier etching speed of the etching speed than the dielectric film using conventional parallel plate-type plasma CVD equipment formation Slow more than 10% or more than 20%, it can be said that the insulating barrier formed using high-density plasma device is fine and close film.
Become the oxide semiconductor of I types or substantial I types in process below（By the oxide of high purity half Conductor）To interface energy level（interface state）, interface charge it is very sensitive；So the interface between gate insulator It is particularly significant.Therefore, be contacted with is needed with high-quality by the gate insulator of the oxide semiconductor of high purity.Thus, Due to that can form densification and the dielectric film of high-quality of high pressure, it is advantageous to sample to utilize microwave（2.45GHz）It is highly dense Spend plasma CVD equipment., can be with by making to be contacted with the gate insulator of high-quality by the oxide semiconductor of high purity Reduction interface energy level density simultaneously can obtain good interfacial characteristics.It is important that：Except good as the film quality of gate insulator Beyond good, gate insulator also has the lower interface energy level density between oxide semiconductor and good interface.
Then, the oxide semiconductor film that thickness is more than 2nm and below 200nm is formed on gate insulator 402 430.Note, it is preferred that before by sputtering method formation oxide semiconductor film 430, by introducing argon gas and producing The reverse sputtering of plasma, to be removably attached the flour on the surface of gate insulator 402（Also referred to as particulate or dust）.Instead Sputtering refers to not apply voltage to target side and use RF power supplys to apply substrate side in argon atmospher voltage so that in lining The method that bottom is formed about plasma to carry out surface modification.Note, blanket of nitrogen, helium-atmosphere, oxygen atmosphere etc. can also be used Instead of argon atmospher.
As oxide semiconductor film 430, In-Ga-Zn-O base oxides semiconductor film, In-Sn-O base oxides are used Semiconductor film, In-Sn-Zn-O base oxides semiconductor film, In-Al-Zn-O base oxides semiconductor film, Sn-Ga-Zn-O base oxygen Compound semiconductor film, Al-Ga-Zn-O base oxides semiconductor film, Sn-Al-Zn-O base oxides semiconductor film, In-Zn-O bases Oxide semiconductor film, Sn-Zn-O base oxides semiconductor film, Al-Zn-O base oxides semiconductor film, In-O base oxides half Electrically conductive film, Sn-O base oxides semiconductor film, Zn-O base oxide semiconductor films.Here, In-Ga-Zn-O Base Metal oxygen is utilized Compound target forms oxide semiconductor film 430 by sputtering method.Sectional view in this stage is shown in Figure 11 A.As Alternatively, can be in rare gas（Typically argon）In atmosphere, in oxygen atmosphere or rare gas（Typically argon）And oxygen is mixed Close in atmosphere by sputtering method formation oxide semiconductor film 430.In addition, when using sputtering method, can also use and include More than 2wt% and below 10wt% SiO2Target deposited, and make in oxide semiconductor film 430 comprising hindering crystallization SiOx（x>0）So that it is used to suppress crystallization during the heating of dehydrationization or dehydrogenation in process that can be below.
Here, using the metal oxide target comprising In, Ga and Zn（In2O3:Ga2O3:ZnO=1:1:1 [mol], and In:Ga:Zn=1:1:0.5[atom]）Carry out film deposition.Sedimentary condition sets as follows：The distance between substrate and target are 100mm；Pressure is 0.2Pa；Direct current（DC）Power is 0.5kW；And atmosphere is the mixed atmosphere of argon and oxygen（Argon:Oxygen= 30sccm:20sccm, and oxygen flow ratio are 40%）.Note, pulse direct current（DC）Power supply is preferably as can reduce The flour produced during deposition, and film thickness can be uniform.It is more than 2nm that In-Ga-Zn-O basement membranes are formed as into thickness Below 200nm.Here, as oxide semiconductor film, sputtering method shape is passed through using In-Ga-Zn-O metal oxides target Into the In-Ga-Zn-O basement membranes that thickness is 20nm.As the metal oxide target comprising In, Ga and Zn, can also use has In:Ga:Zn=1:1:The metal oxide target of 1 [atom] ratio of components or with In:Ga:Zn=1:1:2 [atom] composition The target of ratio.
The example of sputtering method includes, RF sputtering methods, DC sputtering methods using high frequency electric source as shielding power supply and with arteries and veins The pulse DC sputtering methods that the mode of punching is biased.RF sputtering methods are used primarily in form dielectric film in the case of, and DC sputtering method masters To be used in the case of forming metal film.
The multi-source sputter equipment of the different target of multiple materials can be also set.Utilize multi-source sputter equipment, Ke Yi Stacking forms the film of different materials in same reative cell, or can be in same reative cell by while discharging and forming a variety of materials The film of material.
In addition, also having provided with magnetite system and for the sputter equipment of magnetron sputtering system in reative cell, and it is used for The sputter equipment of ECR sputtering methods, wherein applying the plasma produced in the case of microwave rather than glow discharge.
In addition, as the deposition process by sputtering method, there are as below methods：Make target material and sputtering gas during depositing Body produces the reactive sputtering for chemically reacting and being formed their compound film；And electricity is also applied to substrate during depositing The bias sputtering method of pressure.
Then, oxide semiconductor film 430 is processed as island oxide semiconductor layer in the second photo-mask process.Note The Etching mask used in meaning, the process can be formed by ink-jet method.When by ink-jet method formation Etching mask when without Light requirement mask, therefore manufacturing cost can be reduced.
Then, dehydrationization or dehydrogenation are carried out to oxide semiconductor layer.First for carrying out dehydrationization or dehydrogenation The temperature of heating is more than 400 DEG C and less than 750 DEG C, preferably 400 DEG C of strain points less than substrate.Here, Place the substrate into the electric furnace as one of heat treatment apparatus, 1 is carried out to oxide semiconductor layer with 450 DEG C in blanket of nitrogen The heating of hour, and then in order to prevent water, hydrogen to be mixed into oxide semiconductor layer again, be not exposed to greatly Cooled down in the case of gas；It is derived from oxide semiconductor layer 431（Reference picture 11B）.
Note, heat treatment apparatus is not limited to electric furnace and can included by the heating member from resistance heating element etc. The device that the heat transfer of part or heat radiation are heated to the object that is processed.It is, for example, possible to use gas rapid thermal annealing（Gas Rapid Thermal Anneal：GRTA）Device, lamp rapid thermal annealing（Lamp Rapid Thermal Anneal：LRTA）Dress The rapid thermal annealing put etc.（Rapid Thermal Anneal：RTA）Device.LRTA devices are by Halogen lamp LED, Metal halogen lamp, xenon The light of the lamp transmitting of arc lamp, carbon arc lamp, high-pressure mercury lamp or high-pressure sodium lamp etc.（Electromagnetic wave）Radiate to heat processed object Device.GRTA devices are the devices heated using high-temperature gas.As gas, using such as argon etc. rare gas or As nitrogen even if heated also not with the aitiogenic inert gas of processed object.
For example, heating as first, GRTA can be carried out, high temperature is heated to wherein substrate is moved to（I.e. 650 DEG C To 700 DEG C）Inert gas in, carry out a few minutes heating, then substrate is removed from the inert gas for being heated to high temperature. The high-temperature heating treatment of short-term can be realized by using GRTA.
Note, in first heats, preferably nitrogen or rare gas（Such as helium, neon or argon）Atmosphere in do not include Water, hydrogen etc..It is preferred that the nitrogen or rare gas that are introduced into heat treatment apparatus（Such as helium, neon or argon）Purity be set as 6N （99.9999%）More than, more preferably it is set as 7N（99.99999%）More than（That is, impurity concentration is below 1ppm, is preferably Below 0.1ppm）.
Oxide can be carried out to the oxide semiconductor film 430 before being processed into island oxide semiconductor layer partly to lead The first of body layer is heated.In this case, after the first heating is carried out, substrate is taken out from heater, and Then the second photo-mask process is carried out.
Dehydration, the heating of dehydrogenation are carried out to oxide semiconductor layer, can how descend sequential to carry out with office：Shape Into after oxide semiconductor layer；Formed on oxide semiconductor layer after source electrode layer and drain electrode layer；And in source electricity Formed on pole layer and drain electrode layer after protection dielectric film.
When forming opening portion in gate insulator 402, the process for forming opening portion can also be to oxide semiconductor Film 430 carried out before or after dehydrationization or dehydrogenation processing.
Note, the etching of oxide semiconductor film 430 is not limited to wet etching, it would however also be possible to employ dry ecthing.
As the etching gas for dry etching, the gas including chlorine is preferably used（Chlorine-based gas, such as chlorine（Cl2）、 Boron chloride（BCl3）, silicon tetrachloride（SiCl4）, carbon tetrachloride（CCl4）Deng）.
Alternately, the gas comprising fluorine can also be used（Fluorine base gas, such as carbon tetrafluoride（CF4）, sulfur hexafluoride （SF6), Nitrogen trifluoride（NF3）, fluoroform（CHF3）Deng）, hydrogen bromide（HBr）, oxygen（O2）Or with the addition of helium（He）Or argon（Ar） Deng rare gas these any gases.
As dry ecthing method, parallel plate-type reactive ion etching can be used（Reactive Ion Etching：RIE） Method or inductively coupled plasma（Inductively Coupled Plasma：ICP）Etching method.Wished in order to which film is etched to The shape of prestige, suitably adjusts etching condition（It is applied to the amount of the electrical power of line ring-shaped electrode, is applied to the electrode of substrate side Amount, the electrode temperature of substrate side of electrical power etc.）.
As the etching solution for wet etching, it can use solution of phosphoric acid, acetic acid and nitric acid mixing etc..In addition, ITO07N can also be used（Japanese Northeast chemical company manufacture）.
The etching solution removed by cleaning after wet etching and the material being etched.Can also be to including being etched Material and the waste liquid of etching solution are purified, the reusable material.Collect and partly led in oxide in waste liquid after from the etching The material of the indium that body layer includes etc. simultaneously carries out the used time again to it, and resource can be efficiently used and cost is reduced.
Etching condition is suitably adjusted according to material（Etching solution, etching period, temperature etc.）So that can be by material etches Into desired shape.
Then, metal conductive film is formed on gate insulator 402 and oxide semiconductor layer 431.Sputtering method can be passed through Or vacuum vapour deposition formation metal conductive film.As the material of metal conductive film, it can enumerate selected from aluminium（Al）, chromium（Cr）, copper （Cu）, tantalum（Ta）, titanium（Ti）, molybdenum（Mo）, tungsten（W）In element, comprising these any elements as the alloy of composition or comprising Alloy of these any element combinations etc..Alternately, it can also use selected from manganese（Mn）, magnesium（Mg）, zirconium（Zr）, beryllium（Be）、 Yttrium（Y）In one or more materials.In addition, metal conductive film can have single layer structure or more than two layers of laminated construction. For example, following structure can be enumerated：The single layer structure of aluminium film including silicon, copper film or including list of the copper as the film of main component Rotating fields, the double-decker for being laminated in aluminium film titanium film, nitridation tantalum film or nitridation copper film upper strata fold copper film double-decker, Aluminium film is laminated on titanium film and the three-decker of another titanium film is laminated in aluminium film.Alternately, it can also use：Include aluminium（Al） With selected from titanium（Ti）, tantalum（Ta）, tungsten（W）, molybdenum（Mo）, chromium（Cr）, neodymium（Nd）And scandium（Sc）One or more of the film of element, Alloy film or nitride film.
When being heated after forming metal conductive film, preferably metal conductive film, which has, is sufficient to resist the heating The high-fire resistance of processing.
Etching mask is formed on metal conductive film by the 3rd photo-mask process, and carries out selective etching so that Form source layer 415a and drain electrode layer 415b.Then Etching mask is removed（Reference picture 11C）.Alternately, make in the process Etching mask can be formed by ink-jet method.By ink-jet method formation Etching mask without photomask；Therefore can be with Reduce manufacturing cost.
Note, suitably adjust material and etching condition so that oxide semiconductor layer 431 is not by the erosion of metal conductive film Carve and remove.
Here, titanium film is used as metal conductive film, In-Ga-Zn-O base oxides is used for oxide semiconductor layer 431, And use hydrogen peroxide ammoniacal liquor（The mixed liquor of ammonia, water and aquae hydrogenii dioxidi）.
Note, in the 3rd photo-mask process, oxide semiconductor layer 431 is partially etched sometimes, is consequently formed with groove Portion（Recess）Oxide semiconductor layer.
In order to reduce the photomask number and photo-mask process number that are used in photo-mask process, can also use is turned into by the light passed through The masstone mask of the exposed mask of a variety of intensity（multi-tone mask）It is etched process.Due to being covered using masstone The Etching mask of mould formation has multi-thickness, and further changes shape by be ashed, therefore can be in multiple erosions Process is carved using to provide different pattern.Thus, it is possible to be at least corresponded to by a masstone mask formation two or more The Etching mask of different pattern.Thus, it is possible to reduce exposed mask number and corresponding photo-mask process number can also be reduced, thus The simplification of process can be realized.
Then, carry out using nitrous oxide（N2O）, nitrogen（N2）Or argon（Ar）Deng the corona treatment of gas.By this Corona treatment removal is attached to absorption water on the exposed surface of oxide semiconductor layer etc..Oxygen and argon can also be used Mixed gas carries out corona treatment.
After corona treatment is carried out, formed in the case where not making oxide semiconductor layer be exposed to air and oxidation Oxide insulating layer 416 that is that a part for thing semiconductor layer is contacted and turning into protection dielectric film.
The method that the impurity of water, hydrogen etc. will not be made to be mixed into oxide insulating layer 416 of sputtering method etc. can be suitably used Form the oxide insulating layer 416 that thickness is at least 1nm.When including hydrogen in oxide insulating layer 416, hydrogen is caused to enter oxidation So as to cause the back of the body raceway groove of oxide semiconductor layer 431 that there is low resistance in thing semiconductor layer（As N-type）And therefore may shape Into parasitic channel.It is therefore important that using the deposition process without using hydrogen, can to make oxide insulating layer 416 include warp The few hydrogen of energy.
Here, the silicon oxide film that the thickness as oxide insulating layer 416 is 200nm is deposited by sputtering method.During deposition Underlayer temperature can be more than room temperature and less than 300 DEG C, be herein 100 DEG C.Can be in rare gas（Typically argon）Gas In atmosphere, in oxygen atmosphere or rare gas（Typically argon）In the atmosphere of oxygen, progress forms silicon oxide film by sputtering method.Make For target, silica target or silicon target can be used.For example, by sputtering method silicon target can be used in the atmosphere of oxygen and nitrogen Material forms silicon oxide film.
Then, second is carried out in inert gas atmosphere or in carrier of oxygen atmosphere to heat（Preferably more than 200 DEG C And less than 400 DEG C, such as more than 250 DEG C and less than 350 DEG C）.For example, in blanket of nitrogen with 250 DEG C carry out 1 hour second plus Heat treatment.Heat by second, a part for oxide semiconductor layer（Channel formation region）With with oxide insulating layer 416 The state of contact is heated.Thus, a part for oxide semiconductor layer（Channel formation region）It is supplied oxygen.In addition, passing through The heating, can transmit hydrogen into oxide insulating layer 416 from oxide semiconductor layer.
By above-mentioned operation, oxide semiconductor layer is carried out to be used for the heating of dehydrationization or dehydrogenation, then Optionally make a part for oxide semiconductor layer（Channel formation region）In oxygen excess state.Thus, with the weight of grid layer 411 Folded channel formation region 413 becomes I types, and formed in a self-aligned manner the source region 414a overlapping with source layer 415a and with drain electrode Drain region 414b overlapping layer 415b.Pass through above-mentioned operation formation transistor 410.
In such as grid bias-heat stress test（BT is tested）In those conditions it is some under the conditions of（For example, in 85 DEG C, 2 ×106V/cm and time are 12 hours）If there is impurity in oxide semiconductor（Hydrogen etc.）, then impurity and oxide half Key between the main component of conductor is by highfield（B：Bias）And high temperature（T：Temperature）Cut-out so that the dangling bonds of generation causes Threshold voltage（Vth）Drift.On the other hand, by through may remove more impurity in oxide semiconductor, especially hydrogen or Water etc., and using the high densification of above-specified high density plasma CVD equipment formation resistance to pressure and the dielectric film of high-quality and absolutely The good interface characteristic of edge mould and oxide semiconductor, as described above, it is possible thereby to obtaining under harsh external environment condition Also the transistor stablized.
And more than 1 hour and less than 30 hours attached can also be carried out in an atmosphere with more than 100 DEG C and less than 200 DEG C Plus heat.Here, with the heating of 150 DEG C of progress 10 hours.The heating can be carried out in fixed heating-up temperature.Make , can be with the following change of repeated multiple times progress heating-up temperature to be alternative：Heating-up temperature is raised to more than 100 DEG C and 200 DEG C from room temperature Then following temperature drops to room temperature.In addition, the heating can also be before oxide insulating layer 416 be formed under reduced pressure Carry out.By being heated under reduced pressure, the heat time can be shortened.
By forming drain region 414b in the part of the oxide semiconductor layer overlapping with drain electrode layer 415b, crystalline substance can be improved The reliability of body pipe.Specifically, by forming drain region 414b, can obtain electric conductivity can pass through drain region from drain electrode layer 415b The structure that 414b changes to channel formation region 413.
In addition, when the thickness of oxide semiconductor layer is below 15nm, source region or drain region in oxide semiconductor layer Formed on whole thickness direction.When the thickness of oxide semiconductor layer is more than 30nm and below 50nm, oxide is partly led A part for body layer, i.e., the region contacted with source layer or drain electrode layer and its neighbouring source region or leakage are formed by low resistance Area, can make the region close to gate insulator of oxide semiconductor layer turns into I types.
Protection insulating barrier can also be formed on oxide insulating layer 416.For example, passing through RF sputtering methods formation silicon nitride Film.Because RF sputtering methods have high production, so it is preferably used as protecting the deposition process of insulating barrier.It is used as protection insulation Layer, using not including moisture, hydrogen ion or OH-Deng impurity and stop these impurity from outside intrusion inorganic insulating membrane；Example Such as use silicon nitride film, aluminium nitride film, silicon oxynitride film, oxynitriding aluminium film.Here, as protection insulating barrier, nitridation is used Silicon fiml formation protection insulating barrier 403（Reference picture 11D）.
（The various electronic installations of liquid crystal display device are installed）
Below, reference picture 12A to 12F enters to the example of the electronic installation for being provided with liquid crystal display device disclosed in this specification Row explanation.
Figure 12 A show laptop PC, and it includes main body 2201, framework 2202, display portion 2203 and keyboard 2204 etc..
Figure 12 B show personal digital assistant（PDA）, it includes being provided with display part 2213, external interface 2215 and operation The main body 2211 of the grade of button 2214.Including screen touch pen（stylus）2212, it is used as appurtenances.
Figure 12 C are shown as the E-book reader 2220 of an example of Electronic Paper.E-book reader 2220 includes Two frameworks, framework 2221 and framework 2223.Framework 2221 and framework 2223 are formed as one by axle portion 2237, and can be with The axle portion 2237 is that axle is opened and closed E-book reader 2220.By this structure, E-book reader 2220 may be used as papery Books.
Framework 2221 includes display part 2225, and framework 2223 includes display part 2227.Display part 2225 and aobvious Show that portion 2227 can be with an image or different images.In the structure that picture different from each other is shown in display part, such as the right Display part（Display part 2225 in Figure 12 C）It can show text, and the display part on the left side（Display part 2227 in Figure 12 C）Can With display image.
In addition, in fig. 12 c, framework 2221 is provided with operating portion etc..For example, framework 2221 is provided with power switch 2231, behaviour Make key 2233 and loudspeaker 2235 etc..Can be with page turning using operated key 2233.Note, can also framework setting display part Face on keyboard, positioner etc. are set.Alternatively, it is also possible to set external connection terminal on the back side or side of framework （Earphone terminal, USB terminals or the terminal that can be connected with the various cables of AC adapters and USB cable etc. etc.）, recording medium insert Enter portion etc..In addition, E-book reader 2220 can have the function of electronic dictionary.
E-book reader 2220 can be configured to wirelessly receive and send messages., can be from electronics by radio communication Book reader server is bought and downloads desired book data etc..
Note, Electronic Paper can apply to the device of all spectra of display information.For example, except E-book reader it Display that Electronic Paper can also be used for outside in the various cards such as advertisement, credit card in the vehicles such as poster, electric car etc..
Figure 12 D show mobile phone.The mobile phone includes two frameworks, framework 2240 and framework 2241.Framework 2241 Provided with display panel 2242, loudspeaker 2243, microphone 2244, positioner 2246, device for filming image with lens 2247 with And external connection terminals 2248 etc..Framework 2240 be provided with the mobile phone is charged solar battery cell 2249, outside Portion's memory bank 2250 etc..Framework 2241 includes antenna.
Display panel 2242 has touch panel function, is revealed using shown in phantom as image in Figure 12 D Multiple operated keys 2245.Note, the mobile phone includes being used for the boost in voltage for exporting solar battery cell 2249 to respectively The booster circuit of voltage required for circuit.In addition, than the above described structure, mobile phone can also include contactless ic core Piece, small-sized tape deck etc..
Suitably change the display direction of display panel 2242 according to application mode.In addition, same with display panel 2242 Device for filming image lens 2247 are simultaneously provided with, therefore may be used as visual telephone.Loudspeaker 2243 and microphone 2244 It can be used for video phone call, recording, play sound etc. and audio call.Furthermore, in expansion shape as indicated in fig. 12d The framework 2240 and framework 2241 of state can be slided so that a framework is overlapped with another framework, so that mobile phone is adapted to In carrying.
External connection terminals 2248 can be connected with the various cables such as AC adapters or USB cable, and it is allowed for The charging and data communication of mobile phone.In addition, by the way that recording medium is inserted into external memory slot 2250, can preserve And mobile a greater amount of data.In addition, in addition to the functions discussed above, infrared communication function, television receiving function can also be set Deng.
Figure 12 E show digital camera.The digital camera includes main body 2261, display part（A）2267th, view finder 2263, behaviour Make switch 2264, display part（B）2265 and battery 2266 etc..
Figure 12 F show television equipment, and television equipment 2270 includes display part 2273, and display part 2273 is included in framework In 2271.Display part 2273 can be with display image.Here, the support frame 2271 of support 2275.
Television equipment 2270 can be operated by the Operation switch or single remote control 2280 of framework 2271.Pass through remote control The control channel of operated key 2279 and volume of device 2280 so that the image shown on display part 2273 can be controlled.In addition, remote control Device 2280 can have display part 2277 of the display from the information of the remote control 2280 output.
Note, television equipment 2270 is preferably provided with receiver or modem etc..By receiver, it can receive general Television broadcasting.In addition, when television equipment is connected to wired or wireless communication network via modem, can perform unidirectional （From sender to recipient）Or it is two-way（Between the sender and receiver or between recipient）Data communication.
The application is based on the Japanese patent application 2010-042584 submitted to Japan Office for 2010, herein by drawing With including its entire content.
100：Pixel, 101：Scan line, 102：Scan line, 103：Signal wire, 104：Signal wire, 105：Transistor, 107：Pixel Electrode layer, 110：Substrate, 111：Grid layer, 112：Gate insulator, 113：Oxide semiconductor layer, 114a：Source layer and leakage A side in the layer of pole, 114b：The opposing party in source layer and drain electrode layer, 115：Insulating barrier, 116：Contact hole, 117a：Region, 117b：Region, 117c：Region, 201：Oxide semiconductor layer, 202a：Oxide semiconductor layer, 202b：Oxide semiconductor Layer, 210：Transistor, 211：Insulating barrier, 212：Insulating barrier, 220：Transistor, 230：Transistor, 231：Base insulating layer, 232： Insulating barrier, 233a：Contact hole, 233b：Contact hole, 234：Insulating barrier, 235：Contact hole, 400：Substrate, 402：Gate insulator, 403：Protect insulating barrier, 410：Transistor, 411：Grid layer, 413：Channel formation region, 414a：Source region, 414b：Drain region, 415a： Source layer, 415b：Drain electrode layer, 416：Oxide insulating layer, 430：Oxide semiconductor film, 431：Oxide semiconductor layer, 800：Measuring system, 802：Capacitor, 804：Transistor, 805：Transistor, 806：Transistor, 808：Transistor, 1000：Picture Element, 1001：Scan line, 1002：Scan line, 1003：Signal wire, 1004：Signal wire, 1005：Transistor, 1006：Capacitor, 1007：Pixel electrode layer, 1008：Capacitor is connected up, and 1010：Substrate, 1011：Grid layer, 1012：Gate insulator, 1013：Half Conductor layer, 1014a：A side in source layer and drain electrode layer, 1014b：The opposing party in source layer and drain electrode layer, 1015：Insulation Layer, 1016：Contact hole, 1017a：Region, 1017b：Region, 1017c：Region, 2201：Main body, 2202：Framework, 2203：Display Portion, 2204：Keyboard, 2211：Main body, 2212：Screen touch pen, 2213：Display part, 2214：Operation button, 2215：External interface, 2220：E-book reader, 2221：Framework, 2223：Framework, 2225：Display part, 2227：Display part, 2231：Power supply, 2233： Operated key, 2235：Loudspeaker, 2237：Axle portion, 2240：Framework, 2241：Framework, 2242：Display panel, 2243：Loudspeaker, 2244：Microphone, 2245：Operated key, 2246：Positioner, 2247：Device for filming image lens, 2248：External connection terminal Son, 2249：Solar battery cell, 2250：External memory slot, 2261：Main body, 2263：View finder, 2264：Operation is opened Close, 2265：Display part (B), 2266：Battery, 2267：Display part (A), 2270：Television equipment, 2271：Framework, 2273：Display Portion, 2275：Support, 2277：Display part, 2279：Operated key, and 2280：Remote control.
1. a kind of display device, including:
First scan line and the second scan line；
The first insulating barrier on first scan line and second scan line；
Oxide semiconductor layer on first insulating barrier；
Signal wire on the oxide semiconductor layer；And
The second insulating barrier on the signal wire,
Wherein described signal wire is respectively in the first crosspoint and the second crosspoint and first scan line and second scanning DNA mitochondrial DNA intersects,
Wherein described signal wire includes the first convex surface and the second convex surface in first crosspoint and second crosspoint respectively,
Wherein described signal wire be in the region between first convex surface and second convex surface it is substantially whole flat,
Wherein described oxide semiconductor layer is located at first crosspoint, and
Wherein described signal wire is entirely contacted in this region with first insulating barrier.
2. display device as claimed in claim 1, wherein the signal wire includes:
First titanium-containing layer；
Aluminous layer on first titanium-containing layer；And
The second titanium-containing layer on the aluminous layer.
3. a kind of display device includes:
The first signal wire and secondary signal line on first insulating barrier；
The crystal that first scan line, second scan line, first signal wire and the secondary signal line are surrounded Pipe, wherein the transistor is included on grid, first insulating barrier on the grid and first insulating barrier Oxide semiconductor layer；
The second insulating barrier on first signal wire and the secondary signal line；And
Pixel electrode on second insulating barrier,
Wherein described first signal wire is respectively in the first crosspoint and the second crosspoint and first scan line and described second Scan line crossings on different level,
Wherein described first signal wire includes the first convex surface and second in first crosspoint and second crosspoint respectively Convex surface,
Wherein described first signal wire is substantially whole flat in the region between first convex surface and second convex surface ,
Wherein described oxide semiconductor layer is located at first crosspoint,
Wherein described first signal wire is entirely contacted in this region with first insulating barrier, and
Wherein described pixel electrode is electrically connected to the transistor by the contact hole in second insulating barrier.
4. display device as claimed in claim 3, wherein first signal wire and the secondary signal line respectively include:
5. the display device as described in claim 1 or 3, wherein first insulating barrier has laminated construction, it includes nitridation Silicon oxide film on silicon fiml and the silicon nitride film.
6. the 3rd insulating barrier on the display device as described in claim 1 or 3, in addition to second insulating barrier.
7. display device as claimed in claim 6, wherein the 3rd insulating barrier includes organic material.
8. the display device as described in claim 1 or 3, wherein second insulating barrier is inorganic insulating membrane.
9. the display device as described in claim 1 or 3, wherein first scan line and second scan line respectively include:
Containing tantalum layer；And
It is described containing on tantalum layer contain tungsten layer.
CN201610889237.9A 2010-02-26 2011-02-02 Liquid crystal display device CN107045235A (en)
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