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Timestamp: 2020-05-29 21:32:10
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CN1143349C - Cathode-ray tube with improved cathode - Google Patents
Cathode-ray tube with improved cathode Download PDF
CN1143349C
CN1143349C CNB00120162XA CN00120162A CN1143349C CN 1143349 C CN1143349 C CN 1143349C CN B00120162X A CNB00120162X A CN B00120162XA CN 00120162 A CN00120162 A CN 00120162A CN 1143349 C CN1143349 C CN 1143349C
CNB00120162XA
CN1277453A (en
小泉幸生
小宫寿文
岩村则夫
1999-06-14 Priority to JP16676499A priority Critical patent/JP2000357464A/en
1999-06-14 Priority to JP166764/1999 priority
2000-06-14 Application filed by 株式会社日立制作所 filed Critical 株式会社日立制作所
2000-12-20 Publication of CN1277453A publication Critical patent/CN1277453A/en
2004-03-24 Publication of CN1143349C publication Critical patent/CN1143349C/en
A cathode ray tube is provided with a phosphor screen and an electron gun including a cathode having an electron-emissive material layer formed on a surface of a cathode base metal. The electron-emissive material layer includes a first layer made of an alkaline earth metal oxide on the surface of the cathode base metal, a second layer on a surface of the first layer which is an alkaline earth metal oxide layer containing at least one rare earth metal oxide in a range of 0.1 to 10 weight percent, the at least one rare earth metal oxide having a particle size distribution in which the number of particles having a maximum diameter over 5 mu m is one or none, the number of particles having a maximum diameter in a range of from 1 mu m to 5 mu m is in a range of from 2 to 30, as measured in an area of 45 mu m x 45 mu m at a center of a top surface of the second layer, the maximum diameter being defined as a perpendicular projection, onto a horizontal direction of tangents to extremities of a profile of each of the particles. The cathode base metal is made chiefly of nickel and containing at least one reducing agent, and a thickness of a portion of the cathode base metal in contact with the electron-emissive material layer is in a range of 0.10 to 0.16 mm.
A kind of cathode ray tube with an improvement negative electrode
The present invention relates to a kind of cathode ray tube, the cromogram image tube or the colour display tube that for example have the negative electrode that contains electron emission material layer, particularly a kind of have improved high electric current operating characteristic and reduce the formation image cathode ray tube of desired warm-up time after heater be opened.
Cathode ray tube, resemble the color cathode ray tube of the monitor that is used for the business automation equipment terminal, for example, generally have one and be connected the vacuum bubbles that the bullet of base plate and eck constitutes with one by base plate, an eck, phosphor screen and an electron gun that is positioned at eck of constituting by the three fluorescence imaging element of an inner surface that covers base plate.
The electron gun that is used for cathode ray tube has three electrode and the many electrodes that are positioned at these three electrode downstreams that are used for producing the electron beam of three horizontal directions, and forms a main lens on the direction that electron beam is walked at interval.Come three electron beams of self-electrode to enter main lens, be accelerated and focus on rightly, bombard on the phosphor screen then.
Phosphor screen is made of point or the form of bar and the three fluorescence pictorial element arranged by preset space length, also comprises a color selection electrode, for example one with phosphor screen and electron gun between the tight adjacent shadow mask of phosphor screen.
In the cathode ray tube of this pattern, each electrode in the electron gun has one and covers the heater that electron emission material layer and on the bottom metal is used for the heated base metal, so that electronics emits from electron emission material layer.
Some electron emission material layers have adopted and have been suitable for big electric current operation and the sandwich construction in order to prevent that electron emission material layer from peeling off from bottom metal, for example double-decker.
In this double-decker, the ground floor on the bottom metal side comprises the alkaline-earth metal oxide powder, and it is by the tricarbonate that contains Ba, Sr and Ca carbonate be transformed ((Ba, Sr, Ca) CO 3), the second layer such as the upper strata, be made of the alkaline-earth metal oxide powder identical with ground floor, and the rare-earth oxide of 1～3 percentage by weight is dispersed in the alkaline earth metallic oxide powder end.Barium silicon compound Ba 2Sc 2O 5, BaSc 2O 4Or Ba 3Sc 4O 9Chemical combination oxide for Ba and Sc is used as rare-earth oxide and is dispersed in the second layer.
(CaO) operating temperature with the electron emission material layer that is dispersed in rare earth metal formation wherein is generally 1000K for BaO, SrO by these alkaline earth oxides.
A reducing agent that is contained in the electrode underlying metal is diffused into the surface of electrode underlying metal under this temperature, reduced alkaline earth oxide BaO, underlying metal is thick more, it is long more that reducing agent continues to be diffused into time of underlying metal, cause the prolongation of electrode life, these have detailed description in Hei 5-12983 Japan patent applicant announce (being published on January 22nd, 1993).
Usually the electrode underlying metal known to is to be main component by nickeliferous, and mixes a spot of reduction elements such as silicon (Si) or magnesium (Mg).
The performance of underlying metal is relevant from the mechanism of electrode emission with electronics, and the mechanism of electronics emission is had different selections.
It is generally acknowledged that the reducing agent in the underlying metal has reduced ba oxide to produce free barium, these free barium are diffused in the electron emission material layer, form a donor level, emitting electrons then in alkaline earth oxide.
Usually, emission lifetime is decided by the consumption of the reducing agent in the electrode underlying metal and the evaporation of electronic emission material BaO.As for the consumption of electrode underlying metal, the electrode underlying metal is thick more, and it is long more that reducing agent continues to be diffused into time on electrode underlying metal surface, causes long electrode life.
Because top reason, thickness are that 0.19 millimeter negative electrode underlying metal is universal, be to be distributed in the detailed description of the cathode type before the cathode type in the electron emission layer below to having rare earth metal.
The evaporation of electronic emission material BaO is by the decision of the temperature of electron emission material layer, but the consumption of the reducing agent in the negative electrode underlying metal is owing to be distributed in the influence of electron emission layer interior barium sweep time and reduce.
The high concentration of the free barium in the electron emission material layer has been suppressed the minimizing of ba oxide by the reducing agent in the underlying metal, thereby has reduced the consumption of reducing agent.
In the above in Shuo Ming the former technology, by adopting double-deck electron emission material layer and the rare-earth oxide that in electron emission material layer, distributes, taken into full account the emission lifetime characteristic, but do not consider on cathode ray tube to form image desired warm-up time, such as the colour display screen pipe behind image display device, such as the monitor of opening.To form as image below and mention warm-up time warm-up time.
It is that electron emission material layer meets the requirements of the needed time of temperature that image forms warm-up time, by the heating efficiency decision of heater cathod system.
Especially, when the colour display screen pipe is used for information equipment such as the monitor of PC (PC), a kind of trend is arranged, when information equipment does not use, heater cut out automatically in the stand-by period, was in the purpose of saving electric power, then, image forms warm-up time, can throw into question when information equipment reused after the stand-by period.
On the experience, behind power supply opening, wish that screen intensity reaches 50% and requires the needed time restriction of brightness at 8 seconds or still less (or needed time of Weak-luminescence of becoming of phosphor screen must be limited in 3 or 4 seconds), if the time surpasses 8 seconds, the operator feels inconvenience sometimes.
It is also very important with the protection environmental point of view from saving the energy to save electric power, therefore opens the back at heating power supply and requires the minimizing image to form warm-up time according to the stand-by period.
The invention solves top problem, an object of the present invention is to provide a cathode ray tube, it can keep fundamental characteristics, and for example high current practice and long hair are penetrated the life-span and reduced image and form warm-up time.
For reaching top purpose, according to a kind of cathode ray tube that constitutes by vacuum bubbles of the present invention, comprise: an operation board part, one eck part and one is used to be connected the tapering part of said operation board part and eck part, one is formed on the phosphor screen of said operation board part inner surface, one is positioned at the electron gun of said eck part, with comprise that one has the negative electrode of the electron emission material layer that is formed on negative electrode underlying metal surface, said electron emission material layer comprises: a ground floor on said negative electrode underlying metal surface that is made of alkaline earth oxide, with a second layer that contains the alkaline-earth metal oxide layer of at least a rare-earth oxide, it is characterized in that, the said second layer contains one of following at least various materials: (i) composite oxides of scandium oxide and barium and scandium, (ii) Ba 2Sc 2O 5, (iii) Ba 3Sc 4O 9, (iv) BaSc 2O 4, (v) Ba 6Sc 6O 15, (vi) Sc 2O 3, (vii) Ba 3Y 4O 9, (viii) BaY 2O 4, (ix) Ba 3Ce 4O 9, (x) Sr 2Sc 4O 8(xi) CaSc 4O 9Its content is in the scope of 0.1 to 10 percentage by weight, said at least a rare-earth oxide have particle size distribution wherein the maximum gauge quantity that surpasses 5 microns particle be one or zero, having maximum gauge is in 2 to 30 scope at 1 micron amounts of particles in 5 micrometer ranges, this is at one 45 microns * 45 microns the area inner measuring at the center of the top surface of the said second layer, said maximum gauge is defined as the distance of tangent line of end of the profile of the said particle of in the horizontal direction each of perpendicular projection, and the said second layer is formed on the surface of said ground floor; Said negative electrode underlying metal is mainly by nickel with contain a kind of reducing agent at least and constitute, and the thickness of the negative electrode underlying metal that contacts with said electron emission material layer is in 0.10 to 0.16 millimeter scope.
In the accompanying drawings, same parts of reference number sign Chi in all figure wherein.Wherein,
Fig. 1 is the integrally-built cross sectional representation of explanation according to the mask color cathode ray tube in one embodiment of the present of invention;
Fig. 2 is the floor map of the exemplary architecture of the explanation electron gun as color cathode ray tube of the present invention;
Fig. 3 is the amplifier section cross sectional representation of a pith of the electron gun of Fig. 2;
Fig. 4 is the amplifier section cross sectional representation of the pith of Fig. 3;
Fig. 5 is that explanation has the figure of the granular size of rare-earth oxide as the operating characteristic of the cathode ray tube of a parameter;
Fig. 6 illustrates that underlying metal and life-span and image form the figure that concerns between the characteristic warm-up time;
Fig. 7 is the sketch of the miniature photo of electronics in one 45 microns * 45 microns zone at center of top surface of the embodiment of the second layer of the present invention, is used for determining maximum dimension D max;
Fig. 8 is the table that the particle size distribution in one 45 microns * 45 microns zone at center of top surface of the example of the explanation second layer of the present invention was compared with former technology negative electrode.
Embodiments of the invention describe in detail with reference to the accompanying drawings.
Reference number 11 refers to the operation board part, the 12nd, eck part, the 13rd, tapering part, the 14th, phosphor screen, the 15th, wherein have the shadow mask of many electron beam holes, the 16th, shadow mask frame, the 17th, magnetic screen, the 18th, shadow mask hitch, the 19th, be used to launch the electron gun of three electron beams, one center electron beam Bc and two side electron beam Bs, DY one are used for the deflecting coil of level and vertical deflection electron beam, and MA one is used to adjust the outer magnetic machine of colour purity etc. and so on.
In Fig. 1, vacuum bubbles comprises operation board part 11, tapering part 13 and eck part 12, phosphor screen 14 is formed on the inner surface of operation board part 11, the shadow mask frame 16 of the magnetic screen 17 that has shadow mask 15 and be fixed to the upper is suspended in the operation board part 11 by shadow mask hitch 18, operation board part 11 is melted the glass glaze by heat and is sealed on the tapering part 13 by glazing, electron gun 19 is installed in the eck part 12 that is connecting tapering part 13, and vacuum bubbles is sealed behind the air of finding time in it then.
Three electron beam Bc, the electron gun 19 that Bs is positioned in the eck part 12 is launched, they by in the transitional region of deflecting coil DY between eck part 12 and tapering part 13 by along level and vertical direction deflection, by being transmitted as the electron beam hole in the shadow mask 15 of colour selection electrode, with the fluoroscopic image element of the formation phosphor screen 14 that bombards the color that their wish, and form an image.
Fig. 2 is the floor map of a configuration example of the explanation electron gun as color cathode ray tube of the present invention.Reference number 20 expression cathode constructions, its example will be got in touch Fig. 3 and 4 more detailed descriptions subsequently.Reference number 21 expression first electrodes (control electrode), 22 is second electrode (accelerating electrodes), and 23,24 and 25 is respectively the 3rd, the 4th and the 5th electrode (focusing electrode), and 26 is the 6th electrode (anodes), the 27th, multiform glass (only wherein a kind of being drawn), the 28th, base pin.
Cathode construction 20, the first to the 6th electrodes 21 to 26 are coaxial being fixed on a pair of having on the slotting multiform glass 27 within it of supporting slice.
Suitably quickened and focus on by first electrode 21, second electrode 22, third electrode 23, the 4th electrode 24, the 5th electrode 25 and the 6th electrode 26 from cathode construction 20 electrons emitted bundles, throw towards phosphor screen from the 6th electrode 26.28 conducts of base pin are used to apply required voltage or picture signal forms the connector lug of the electrode of electron gun 19 to each.
Fig. 3 is the amplifier section cross sectional representation of a pith of the electron gun of Fig. 2.Cathode construction 20 be inclusive with one it low side be fixed to heater 31 in the heater supporting 32.Reference number 33 expression one negative electrode eyelet cathode construction 20 at its low end bearing, thereby fixes it by a pearl shape supporting 34 that is used to support cathode construction 20 on the position that requires in electron gun.
Fig. 4 is the amplifier section cross sectional representation of the pith of Fig. 3.Reference number 40 expression one negative electrode, it comprises that a cup-shaped underlying metal 41 and is formed on the electron emission material layer 42 on the top 41a of underlying metal 41.Reference number 43 expressions one cathode sheath.One end of cathode sheath 43 is fixed to the sidewall of the underlying metal 41 of negative electrode 40, and the other end of cathode sheath 43 is fixed to carrying cylinder 44.Negative electrode 40, cathode sheath 43 and carrying cylinder 44 form cathode construction 20.
Underlying metal 41 is made of nickeliferous material as main component, and the reducing metal of containing low concentration is such as silicon (Si) or magnesium (Mg).In this embodiment, the thickness t 1 of the top section of the cup-shaped underlying metal 41 that covers with electron emission material layer is 0.14 millimeter.
The height h of the sidewall 41b of cup-shaped underlying metal 41 and thickness t 2 are respectively 0.5 millimeter and 0.05 millimeter, and the proportion of underlying metal 21 and specific heat are respectively 8.9 and 0.148cal/ ℃/g, and the quality of cup-shaped underlying metal 41 is 3.4mg.
Preferably t2 and the ratio of t1 are in 1/5 to 3/5 scope, and the consumption of the reducing agent in the underlying metal can postpone by the thickness that increases t1.
It is 0.018 millimeter that the minimizing that the wall thickness of cathode sheath 43 forms warm-up time with the view picture is made into thin, and the diameter of cathode sheath 43 is chosen as 1.57 millimeters.Underlying metal 41 and carrying cylinder 44 are fixed on the cathode sheath 43 by using common laser welding technology.
The desired value of the output of reducing agent diffusion and barium guarantees as the reducing metal by one or both among use Si and the Mg.
Electron emission material layer 42 is forms of double-layer structure, comprises with common injection soverlay technique being formed on the ground floor 421 and the second layer 422 on the underlying metal 41.Ground floor 421 on the underlying metal side is made of alkaline earth oxide, and the second layer 422 is made of the rare-earth oxide of an alkaline earth oxide and an about percentage by weight, and for example composite oxides are such as Ba 2Sc 2O 5Be dispersed in the alkaline earth oxide.
In the electron emission material layer 42 in this embodiment, the ground floor 421 that is made of alkaline earth oxide is from containing the tricarbonate of Ba, Sr and Ca carbide, ((Ba, Sr, Ca) CO 3) wait and so on and to convert, the second layer 422 is alkaline-earth metal oxide layers, wherein is scattered with rare-earth oxide, contains the tricarbonate of Ba, Sr and Ca carbide, ((Ba, Sr, Ca) CO by conversion 3) wait and so on, obtain, be mixed with barium scandium thing (Ba 2Sc 2O 5) material that waits and so on.
Fig. 5 is explanation electronics emission lifetime and the rare-earth oxide that is dispersed in the second layer 422, for example barium scandium thing (Ba 2Sc 2O 5), the figure of correlation of granular size, use 6A/cm based on one 2The accelerated test of negative electrode load, contain the cathode ray tube of a negative electrode of making according to the explanation of narration subsequently by use.
In Fig. 5, the electronics emission lifetime of the second layer 422 with barium scandium thing particle size distribution of present embodiment is used in the curve A representative, wherein having the number of particles of maximum gauge above 5 microns is one or does not have, scope with maximum gauge number of particles between 1 micron to 5 microns is 2 to 30, be at one 45 microns * 45 microns the area measure at the center of the top surface of the second layer 422, curve B is represented the electronics emission lifetime of the conventional cathode of the second layer that adopts the barium scandium thing with particle size distribution, the quantity that wherein has the particle of maximum gauge above 5 microns is 3 at least, having maximum gauge is 10 in the quantity of 1 micron particle in 5 micrometer ranges at least, is at one 45 microns * 45 microns the area measure at the center of the top surface of the second layer 422.
The method of measurement of the maximum gauge of rare-earth oxide particle then, is described.
By should the zone with electron bombard, use scanning electron microscopy class wavelength dispersion X-ray spectroscope, Hitachi, the SEM-WDX650 (trade name) that Ltd makes obtains the image of the rare-earth oxide particle on one 45 microns * 45 microns the zone at the center of the top surface of the second layer 422.The maximum dimension D max of rare-earth oxide particle measures on the enlarged image of particle.Fig. 7 is the electron micrograph in one 45 microns * 45 microns zone at the center of the top surface at the second layer 422 of the present invention, the maximum dimension D max of each rare-earth oxide particle 50 is defined as the tangent line (Feret of upright projection particle profile end as shown in Figure 7 in the horizontal direction, see Perry Chemical Engineering handbook, sixth version, p.8-6, mcgraw-hill, inc, New York).Fig. 8 is that the particle size distribution in one 45 microns * 45 microns zone at center of top surface of tabulating the example of the second layer 422 of the present invention is compared with former technology negative electrode.
As ise apparent from FIG. 5, curve B shows, the negative electrode of the particle size distribution of technology barium scandium thing before traditional employing, and the reduction rate of maximum anode current increases with the increase of operating time, therefore its operating characteristic worsens rapidly, and is difficult to prolong the life-span of negative electrode.
On the other hand, curve A shows that in the embodiment of employing according to the particle size distribution of barium scandium thing of the present invention, its operating characteristic is compared deterioration with traditional negative electrode less, like this, makes prolongation cathode life become possibility.
By comprising the different test of the foregoing description, the present invention finds, if the average diameter of the rare-earth oxide particle in the second layer distributes above 1.0 microns, its operating characteristic worsens rapidly, be difficult to prolong cathode life, on the other hand, if the average diameter of the rare-earth oxide particle of average diameter in the second layer distributes less than 0.2 micron, the rare-earth oxide particle has a kind of aggregation tendency, because the average diameter of rare-earth oxide particle less than in the second layer as the average diameter of the alkaline earth oxide particle of main component, this gathering is undesirable for the manufacturing of electron emission material layer.
Fig. 8 is by revising the result of aforesaid test, for the top surface of the second layer by observing electron emission material layer is realized possible production control.
To illustrate below alkaline earth oxide ground floor 421 a kind of manufacture method and be distributed with the manufacture method of the second layer 422 of the alkaline-earth metal oxide layer of rare-earth oxide.
At first, first hang to be to prepare for the manufacturing of the ground floor 421 made with alkaline earth oxide.
At first, contain the tricarbonate of Ba, Sr and Ca carbonate, ((Ba, Sr, Ca) CO 3) be by adding sodium carbonate (Na 2CO 3) to a ba nitrate (BaNO who contains by 54 percentage by weights 3), the strontium nitrate (SrNO of 39 percentage by weights 3) and the calcium nitrate (CaNO of 7 percentage by weights 3) mixed solvent of the dissolved matter that constitutes comes precipitated.The carbonate particle that contains Ba, Sr and Ca carbonate that obtains, ((Ba, Sr, Ca) CO 3) be the needle-shaped crystals of about 15 microns average diameters.
Nitrocellulose sprays paint and acetate butyl is added to top deposit (powder) then, and mixes them to obtain first suspension by rolling.
Then, prepare second suspension, be scattered with the second layer 422 of the alkaline earth oxide of rare-earth oxide with formation.
At first, contain the tricarbonate of Ba, Sr and Ca carbonate, ((Ba, Sr, Ca) CO 3) be by adding sodium carbonate (Na 2CO 3) to a ba nitrate (BaNO who contains by 57 percentage by weights 3), the strontium nitrate (SrNO of 42 percentage by weights 3) and the calcium nitrate (CaNO of 1 percentage by weight 3) mixed solvent of the dissolved matter that constitutes comes precipitated.
The carbonate particle that contains Ba, Sr and Ca carbonate that obtains, ((Ba, Sr, Ca) CO 3) be the needle-shaped crystals of about 15 microns average diameters.
Then, the barium scandium thing (Ba of 0.5 of 1 percentage by weight micron average diameter 2Sc 2O 5) the powder air penetration method of the band subsieve-size of making by Fisher Co. (trade name), for example, mix with top sediment (powder), nitrocellulose sprays paint and acetate butyl is added to this mixture then, and is admixed together to obtain second suspension with rolling.
First suspension is directed onto mainly the top 41a of the cup-shaped underlying metal 41 that is made of nickel (Ni) then, be approximately 17 microns first spray-up that is intended for use ground floor 421 to form thickness, second suspension is directed onto first spray-up then, is about 60 microns second spray-up that is intended for use the second layer 422 to form thickness.
Barium scandium thing (Ba 2Sc 2O 5) make by common deposited, and be polyhedron.
Then, in the pump step of making cathode ray tube, first and second spray-ups are by heater 31 heating, so that decompose the carbonate that contains Ba, Sr and Ca carbonate, enter barium, strontium and calcium ((Ba, Sr, Ca) O) at spray-up, form ground floor 421 that constitutes by alkaline earth oxide and the second layer 422 that is distributed with the alkaline-earth metal oxide layer of rare-earth oxide.
After this, when making cathode ray tube, be excited by in 900 to 1100 ℃ of scopes, heating, carry out a burin-in process step then, form the negative electrode of wishing like this by first and second layer 421,422 electron emission material layer that constitutes 42.
Negative electrode with electron emission material layer 42 of top structure is being distributed with rare-earth oxide such as barium scandium thing (Ba 2Sc 2O 5) the second layer 422 of alkaline-earth metal oxide layer in, free barium closing function by rare-earth oxide, free barium (Ba) remains on high concentration in electron emission material layer 42, therefore the high concentration state of donor is extended, the generation of restriction Joule heat is to provide the negative electrode that shows remarkable high current density operation characteristic with electron emission material layer 42.And, can obtain long emission lifetime, because the evaporation of barium is pressed, thereby the free barium of high concentration is held.
Particularly, this effect is roughly proportional with the total surface area that is dispersed in the rare-earth oxide particle in the electron emission layer 42, when showing that average diameter when the rare-earth oxide particle is in 0.2 micron to 1.0 microns scope, like this, make the minimizing of the thickness of negative electrode underlying metal become possibility.
In this embodiment, the composite oxides of barium (Ba) and scandium (Sc), just, barium scandium thing (Ba 2Sc 2O 5) be used as rare-earth oxide, be dispersed in and have in the alkaline earth oxide material layer 422 that is distributed with rare-earth oxide, but that the present invention is not restricted to is this, other rare-earth oxide can be used for the present invention.
For example, the composite oxides of other barium (Ba) and scandium (Sc), Ba 3Sc 4O 9, BaSc 2O 4, Ba 6Sc 6O 15Scandium oxide (Sc 2O 3); The composite oxides of barium (Ba) and iridium (Y), Ba 3Y 4O 9, BaY 2O 4The composite oxides of barium (Ba) and cerium (Ce), Ba 3Ce 4O 9Sr 2Sc 4O 8And CaSc 4O 9Also can be separately or unite with one or more of other oxide and to be used as the rare-earth oxide that is dispersed in the alkaline earth oxide material layer, the identical advantage that provides with the composite oxides that obtain by above-mentioned barium (Ba) and scandium (Sc).
In the above embodiments, for example, the rare-earth oxide of 1 percentage by weight, the composite oxides of barium (Ba) and scandium (Sc), barium scandium thing (Ba 2Sc 2O 5), be dispersed in the second layer 422, wherein be scattered with the alkaline-earth metal oxide layer of rare-earth oxide, but the concentration of the rare-earth oxide that scatters can be selected at 0.1 percentage by weight arbitrarily in the scope of 10 percentage by weights.
If be dispersed in the concentration of the rare-earth oxide in the second layer 422, for example, the barium scandium thing (Ba of the composite oxides of barium and scandium 2Sc 2O 5), be less than 0.1 percentage by weight, can not be improved fully, thereby can not be reduced the thickness of underlying metal 41.
On the other hand, surpass 10 percentage by weights if be dispersed in the concentration of the rare-earth oxide in the second layer 422, the rare-earth oxide particle has a kind of trend of gathering, because the granular size of rare-earth oxide likens to the granular size of the alkaline earth oxide of the second layer 422 main components is little, this gathering is undesirable to the manufacturing of electron emission material layer.Therefore the concentration that preferably is dispersed in the rare-earth oxide in the second layer 422 at 0.5 percentage by weight in the scope of 3 percentage by weights.
Substitute rare-earth oxide, a kind of or oxide together, for example MgSiO of magnesium and silicon 3, can be dispersed in 0.1 total percentage by weight in the scope of 10 percentage by weights, in the second layer 422 to obtain the advantage similar to above-mentioned advantage.
The thickness t 1 of the part of the top 41a of target underlying metal 41 of the present invention, electron emission material layer 42 is capped thereon, and the thickness t 2 of the sidewall of cup-shaped underlying metal 41 has been done different tests with the height h of cup-shaped underlying metal 41.
Fig. 6 is that the thickness and the image of explanation cathode life and negative electrode underlying metal forms the figure that concerns between the thickness of warm-up time and negative electrode underlying metal, obtain by the speed (producing the amount of free barium) of calculating, then it is used one and have in the double-deck negative electrode of barium (Ba) and scandium (Sc) distribution composite oxides wherein based on the reduction reaction of the diffusivity in nickel.
In Fig. 6, curve S and L representative image respectively form warm-up time and life expectancy.Usually, the life-span of cathode ray tube generally has 18000 hours or more.As ise apparent from FIG. 6, for guaranteeing 18000 hours or more life time that thickness t 1 must be chosen as 0.1 millimeter or more, for limited images forms warm-up time to 8 second, thickness t 1 must be limited to 0.16 millimeter.
If the thickness of underlying metal is selected less than 0.1 millimeter, only improve electron emission material layer 42, can not guarantee the emission lifetime of requirement above-mentioned.On the other hand, if the thickness of underlying metal is selected greater than 0.16 millimeter, image forms and is increased warm-up time, for example, when negative electrode was installed in the employed cathode ray tube of monitor of personal computer terminal, the image that produces user expectation formed the problem that is difficult to obtain warm-up time.Therefore thickness t 1 can provide more useful effect in 0.12 millimeter to 0.14 millimeter scope.
Explained one embodiment of the present of invention, but the present invention is not restricted to top embodiment, can makes variation and modification, and not deviate from the spirit and scope of the present invention that in accessory claim, define.
As explained above, the invention provides a kind of cathode ray tube with remarkable high current practice characteristic, high brightness and well focussed characteristic, when it is incorporated in the large scale display monitor, by being the electron emission material layer employing sandwich construction of negative electrode, the amount of having stipulated average particulate diameter and rare-earth oxide is such as the oxide in the sandwich construction upper strata of being dispersed in of barium scandium thing or other, and stipulated the negative electrode underlying metal material and with the thickness of the contacted underlying metal part of electron emission material layer.Even monitor apparatus is configured, so that the power supply of the heater of cathode ray tube is closed automatically, for do not use the time to economize the purpose of electric power when monitor apparatus, can provide the image of enough weak points to form warm-up time according to cathode ray tube of the present invention, after being closed, the electric power of heater do not have inconvenience to cause in practice, because after electric power is closed, can reach the desired short time of the electron emission amount of desired value.
1, a kind of cathode ray tube that constitutes by vacuum bubbles, comprise: an operation board part, one eck part and one is used to be connected the tapering part of said operation board part and eck part, one is formed on the phosphor screen of said operation board part inner surface, one is positioned at the electron gun of said eck part, with comprise that one has the negative electrode of the electron emission material layer that is formed on negative electrode underlying metal surface, said electron emission material layer comprises:
One by alkaline earth oxide constitute the ground floor on said negative electrode underlying metal surface and
One contains the second layer of the alkaline-earth metal oxide layer of at least a rare-earth oxide,
The said second layer contains one of following at least various materials: (i) composite oxides of scandium oxide and barium and scandium, (ii) Ba 2Sc 2O 5, (iii) Ba 3Sc 4O 9, (iv) BaSc 2O 4, (v) Ba 6Sc 6O 15, (vi) Sc 2O 3, (vii) Ba 3Y 4O 9, (viii) BaY 2O 4, (ix) Ba 3Ce 4O 9, (x) Sr 2Sc 4O 8(xi) CaSc 4O 9, its content in the scope of 0.1 to 10 percentage by weight,
Said at least a rare-earth oxide have particle size distribution wherein the maximum gauge quantity that surpasses 5 microns particle be one or zero, having maximum gauge is in 2 to 30 scope at 1 micron amounts of particles in 5 micrometer ranges, this is at one 45 microns * 45 microns the area inner measuring at the center of the top surface of the said second layer
Said maximum gauge is defined as the distance of tangent line of end of the profile of the said particle of in the horizontal direction each of perpendicular projection,
The said second layer is formed on the surface of said ground floor;
Said negative electrode underlying metal is mainly by nickel with contain a kind of reducing agent at least and constitute,
The thickness of the negative electrode underlying metal that contacts with said electron emission material layer is in 0.10 to 0.16 millimeter scope.
2, according to the described cathode ray tube of claim 1, it is characterized in that, said negative electrode underlying metal is cup-shaped, and the thickness of the sidewall of said cup is in 1/5 to 3/5 scope of the thickness at the top of the said negative electrode underlying metal that contacts with electron emission material layer.
According to the described cathode ray tube of claim 1, it is characterized in that 3, said at least a reducing agent is a kind of of magnesium and silicon.
CNB00120162XA 1999-06-14 2000-06-14 Cathode-ray tube with improved cathode CN1143349C (en)
JP16676499A JP2000357464A (en) 1999-06-14 1999-06-14 Cathode-ray tube
JP166764/1999 1999-06-14
CN1277453A CN1277453A (en) 2000-12-20
CN1143349C true CN1143349C (en) 2004-03-24
ID=15837281
CNB00120162XA CN1143349C (en) 1999-06-14 2000-06-14 Cathode-ray tube with improved cathode
US (1) US6504293B1 (en)
EP (1) EP1061543A3 (en)
JP (1) JP2000357464A (en)
CN (1) CN1143349C (en)
TW (1) TW563159B (en)
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1999-06-14 JP JP16676499A patent/JP2000357464A/en active Pending
2000-06-09 US US09/589,804 patent/US6504293B1/en not_active Expired - Fee Related
2000-06-09 EP EP00111884A patent/EP1061543A3/en not_active Withdrawn
2000-06-13 TW TW89111521A patent/TW563159B/en active
2000-06-14 CN CNB00120162XA patent/CN1143349C/en not_active IP Right Cessation
US6504293B1 (en) 2003-01-07
EP1061543A2 (en) 2000-12-20
KR20010015015A (en) 2001-02-26
CN1277453A (en) 2000-12-20
JP2000357464A (en) 2000-12-26
TW563159B (en) 2003-11-21
EP1061543A3 (en) 2003-08-13
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2000-12-20 PB01 Publication
2009-08-19 CF01 Termination of patent right due to non-payment of annual fee