Source: https://patents.google.com/patent/JP4566086B2/en
Timestamp: 2020-08-10 17:32:58+00:00
Document Index: 2609639

Matched Legal Cases: ['art 36', 'art 34', 'art 34', 'art 1', 'art 2', 'art 3', 'art 4', 'art 21', 'art 22', 'art 25', 'art 26', 'art 28', 'art 18', 'art 36']

JP4566086B2 - Manufacturing method of semiconductor device - Google Patents
JP4566086B2
JP4566086B2 JP2005222119A JP2005222119A JP4566086B2 JP 4566086 B2 JP4566086 B2 JP 4566086B2 JP 2005222119 A JP2005222119 A JP 2005222119A JP 2005222119 A JP2005222119 A JP 2005222119A JP 4566086 B2 JP4566086 B2 JP 4566086B2
JP2005222119A
JP2006310725A (en
2005-03-31 Priority to JP2005105507 priority Critical
2005-07-29 Application filed by 富士通セミコンダクター株式会社 filed Critical 富士通セミコンダクター株式会社
2005-07-29 Priority to JP2005222119A priority patent/JP4566086B2/en
2006-11-09 Publication of JP2006310725A publication Critical patent/JP2006310725A/en
2010-10-20 Publication of JP4566086B2 publication Critical patent/JP4566086B2/en
238000004519 manufacturing process Methods 0.000 title claims description 61
239000010408 films Substances 0.000 claims description 503
239000000758 substrates Substances 0.000 claims description 241
238000002955 isolation Methods 0.000 claims description 77
239000002344 surface layers Substances 0.000 claims description 12
229910052710 silicon Inorganic materials 0.000 description 218
XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,PD94bWwgdmVyc2lvbj0nMS4wJyBlbmNvZGluZz0naXNvLTg4NTktMSc/Pgo8c3ZnIHZlcnNpb249JzEuMScgYmFzZVByb2ZpbGU9J2Z1bGwnCiAgICAgICAgICAgICAgeG1sbnM9J2h0dHA6Ly93d3cudzMub3JnLzIwMDAvc3ZnJwogICAgICAgICAgICAgICAgICAgICAgeG1sbnM6cmRraXQ9J2h0dHA6Ly93d3cucmRraXQub3JnL3htbCcKICAgICAgICAgICAgICAgICAgICAgIHhtbG5zOnhsaW5rPSdodHRwOi8vd3d3LnczLm9yZy8xOTk5L3hsaW5rJwogICAgICAgICAgICAgICAgICB4bWw6c3BhY2U9J3ByZXNlcnZlJwp3aWR0aD0nODVweCcgaGVpZ2h0PSc4NXB4JyB2aWV3Qm94PScwIDAgODUgODUnPgo8IS0tIEVORCBPRiBIRUFERVIgLS0+CjxyZWN0IHN0eWxlPSdvcGFjaXR5OjEuMDtmaWxsOiNGRkZGRkY7c3Ryb2tlOm5vbmUnIHdpZHRoPSc4NScgaGVpZ2h0PSc4NScgeD0nMCcgeT0nMCc+IDwvcmVjdD4KPHRleHQgZG9taW5hbnQtYmFzZWxpbmU9ImNlbnRyYWwiIHRleHQtYW5jaG9yPSJzdGFydCIgeD0nMjUuMjQ2OCcgeT0nNDcuNzk1NScgc3R5bGU9J2ZvbnQtc2l6ZTozOHB4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO2ZpbGw6IzNCNDE0MycgPjx0c3Bhbj5TaTwvdHNwYW4+PC90ZXh0Pgo8cGF0aCBkPSdNIDguNzcyNzMsMTguMDQ1NSBMIDguNzY0MTUsMTcuODQ2MiBMIDguNzM4NDYsMTcuNjQ4NCBMIDguNjk1ODcsMTcuNDUzNSBMIDguNjM2NjksMTcuMjYzIEwgOC41NjEzNSwxNy4wNzgzIEwgOC40NzA0MSwxNi45MDA4IEwgOC4zNjQ1NSwxNi43MzE3IEwgOC4yNDQ1NCwxNi41NzI0IEwgOC4xMTEyOSwxNi40MjQgTCA3Ljk2NTc3LDE2LjI4NzYgTCA3LjgwOTA1LDE2LjE2NDIgTCA3LjY0MjMyLDE2LjA1NDcgTCA3LjQ2Njc4LDE1Ljk1OTkgTCA3LjI4Mzc2LDE1Ljg4MDcgTCA3LjA5NDU5LDE1LjgxNzQgTCA2LjkwMDY4LDE1Ljc3MDYgTCA2LjcwMzQ3LDE1Ljc0MDcgTCA2LjUwNDQyLDE1LjcyNzggTCA2LjMwNSwxNS43MzIxIEwgNi4xMDY2OSwxNS43NTM1IEwgNS45MTA5NSwxNS43OTE5IEwgNS43MTkyNCwxNS44NDcgTCA1LjUzMjk3LDE1LjkxODMgTCA1LjM1MzUyLDE2LjAwNTQgTCA1LjE4MjIzLDE2LjEwNzYgTCA1LjAyMDM1LDE2LjIyNDIgTCA0Ljg2OTEsMTYuMzU0MiBMIDQuNzI5NTgsMTYuNDk2OCBMIDQuNjAyODMsMTYuNjUwOCBMIDQuNDg5NzksMTYuODE1MSBMIDQuMzkxMywxNi45ODg2IEwgNC4zMDgwOCwxNy4xNjk5IEwgNC4yNDA3NiwxNy4zNTc2IEwgNC4xODk4MiwxNy41NTA1IEwgNC4xNTU2NiwxNy43NDcgTCA0LjEzODUxLDE3Ljk0NTcgTCA0LjEzODUxLDE4LjE0NTIgTCA0LjE1NTY2LDE4LjM0MzkgTCA0LjE4OTgyLDE4LjU0MDQgTCA0LjI0MDc2LDE4LjczMzMgTCA0LjMwODA4LDE4LjkyMTEgTCA0LjM5MTMsMTkuMTAyMyBMIDQuNDg5NzksMTkuMjc1OCBMIDQuNjAyODMsMTkuNDQwMSBMIDQuNzI5NTgsMTkuNTk0MSBMIDQuODY5MSwxOS43MzY3IEwgNS4wMjAzNSwxOS44NjY3IEwgNS4xODIyMywxOS45ODMzIEwgNS4zNTM1MiwyMC4wODU1IEwgNS41MzI5NywyMC4xNzI2IEwgNS43MTkyNCwyMC4yNDM5IEwgNS45MTA5NSwyMC4yOTkgTCA2LjEwNjY5LDIwLjMzNzQgTCA2LjMwNSwyMC4zNTg4IEwgNi41MDQ0MiwyMC4zNjMxIEwgNi43MDM0NywyMC4zNTAyIEwgNi45MDA2OCwyMC4zMjAzIEwgNy4wOTQ1OSwyMC4yNzM1IEwgNy4yODM3NiwyMC4yMTAzIEwgNy40NjY3OCwyMC4xMzEgTCA3LjY0MjMyLDIwLjAzNjIgTCA3LjgwOTA1LDE5LjkyNjcgTCA3Ljk2NTc3LDE5LjgwMzMgTCA4LjExMTI5LDE5LjY2NjkgTCA4LjI0NDU0LDE5LjUxODUgTCA4LjM2NDU1LDE5LjM1OTIgTCA4LjQ3MDQxLDE5LjE5MDEgTCA4LjU2MTM1LDE5LjAxMjYgTCA4LjYzNjY5LDE4LjgyNzkgTCA4LjY5NTg3LDE4LjYzNzQgTCA4LjczODQ2LDE4LjQ0MjUgTCA4Ljc2NDE1LDE4LjI0NDcgTCA4Ljc3MjczLDE4LjA0NTUgTCA2LjQ1NDU1LDE4LjA0NTUgWicgc3R5bGU9J2ZpbGw6IzAwMDAwMDtmaWxsLXJ1bGU6ZXZlbm9kZDtmaWxsLW9wYWNpdHk9MTtzdHJva2U6IzAwMDAwMDtzdHJva2Utd2lkdGg6MnB4O3N0cm9rZS1saW5lY2FwOmJ1dHQ7c3Ryb2tlLWxpbmVqb2luOm1pdGVyO3N0cm9rZS1vcGFjaXR5OjE7JyAvPgo8cGF0aCBkPSdNIDc5Ljg2MzYsMTguMDQ1NSBMIDc5Ljg1NTEsMTcuODQ2MiBMIDc5LjgyOTQsMTcuNjQ4NCBMIDc5Ljc4NjgsMTcuNDUzNSBMIDc5LjcyNzYsMTcuMjYzIEwgNzkuNjUyMywxNy4wNzgzIEwgNzkuNTYxMywxNi45MDA4IEwgNzkuNDU1NSwxNi43MzE3IEwgNzkuMzM1NSwxNi41NzI0IEwgNzkuMjAyMiwxNi40MjQgTCA3OS4wNTY3LDE2LjI4NzYgTCA3OC45LDE2LjE2NDIgTCA3OC43MzMyLDE2LjA1NDcgTCA3OC41NTc3LDE1Ljk1OTkgTCA3OC4zNzQ3LDE1Ljg4MDcgTCA3OC4xODU1LDE1LjgxNzQgTCA3Ny45OTE2LDE1Ljc3MDYgTCA3Ny43OTQ0LDE1Ljc0MDcgTCA3Ny41OTUzLDE1LjcyNzggTCA3Ny4zOTU5LDE1LjczMjEgTCA3Ny4xOTc2LDE1Ljc1MzUgTCA3Ny4wMDE5LDE1Ljc5MTkgTCA3Ni44MTAxLDE1Ljg0NyBMIDc2LjYyMzksMTUuOTE4MyBMIDc2LjQ0NDQsMTYuMDA1NCBMIDc2LjI3MzEsMTYuMTA3NiBMIDc2LjExMTMsMTYuMjI0MiBMIDc1Ljk2LDE2LjM1NDIgTCA3NS44MjA1LDE2LjQ5NjggTCA3NS42OTM3LDE2LjY1MDggTCA3NS41ODA3LDE2LjgxNTEgTCA3NS40ODIyLDE2Ljk4ODYgTCA3NS4zOTksMTcuMTY5OSBMIDc1LjMzMTcsMTcuMzU3NiBMIDc1LjI4MDcsMTcuNTUwNSBMIDc1LjI0NjYsMTcuNzQ3IEwgNzUuMjI5NCwxNy45NDU3IEwgNzUuMjI5NCwxOC4xNDUyIEwgNzUuMjQ2NiwxOC4zNDM5IEwgNzUuMjgwNywxOC41NDA0IEwgNzUuMzMxNywxOC43MzMzIEwgNzUuMzk5LDE4LjkyMTEgTCA3NS40ODIyLDE5LjEwMjMgTCA3NS41ODA3LDE5LjI3NTggTCA3NS42OTM3LDE5LjQ0MDEgTCA3NS44MjA1LDE5LjU5NDEgTCA3NS45NiwxOS43MzY3IEwgNzYuMTExMywxOS44NjY3IEwgNzYuMjczMSwxOS45ODMzIEwgNzYuNDQ0NCwyMC4wODU1IEwgNzYuNjIzOSwyMC4xNzI2IEwgNzYuODEwMSwyMC4yNDM5IEwgNzcuMDAxOSwyMC4yOTkgTCA3Ny4xOTc2LDIwLjMzNzQgTCA3Ny4zOTU5LDIwLjM1ODggTCA3Ny41OTUzLDIwLjM2MzEgTCA3Ny43OTQ0LDIwLjM1MDIgTCA3Ny45OTE2LDIwLjMyMDMgTCA3OC4xODU1LDIwLjI3MzUgTCA3OC4zNzQ3LDIwLjIxMDMgTCA3OC41NTc3LDIwLjEzMSBMIDc4LjczMzIsMjAuMDM2MiBMIDc4LjksMTkuOTI2NyBMIDc5LjA1NjcsMTkuODAzMyBMIDc5LjIwMjIsMTkuNjY2OSBMIDc5LjMzNTUsMTkuNTE4NSBMIDc5LjQ1NTUsMTkuMzU5MiBMIDc5LjU2MTMsMTkuMTkwMSBMIDc5LjY1MjMsMTkuMDEyNiBMIDc5LjcyNzYsMTguODI3OSBMIDc5Ljc4NjgsMTguNjM3NCBMIDc5LjgyOTQsMTguNDQyNSBMIDc5Ljg1NTEsMTguMjQ0NyBMIDc5Ljg2MzYsMTguMDQ1NSBMIDc3LjU0NTUsMTguMDQ1NSBaJyBzdHlsZT0nZmlsbDojMDAwMDAwO2ZpbGwtcnVsZTpldmVub2RkO2ZpbGwtb3BhY2l0eT0xO3N0cm9rZTojMDAwMDAwO3N0cm9rZS13aWR0aDoycHg7c3Ryb2tlLWxpbmVjYXA6YnV0dDtzdHJva2UtbGluZWpvaW46bWl0ZXI7c3Ryb2tlLW9wYWNpdHk6MTsnIC8+Cjwvc3ZnPgo= [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 217
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 133
HQVNEWCFYHHQES-UHFFFAOYSA-N Silicon nitride Chemical compound data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='300px' height='300px' viewBox='0 0 300 300'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='300' height='300' x='0' y='0'> </rect>
<path class='bond-0' d='M 148.379,175.712 L 151.822,150' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 151.822,150 L 155.265,124.288' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-6' d='M 171.826,209.343 L 198.157,212.869' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-6' d='M 198.157,212.869 L 224.487,216.395' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-7' d='M 116.909,201.989 L 90.5782,198.462' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-7' d='M 90.5782,198.462 L 64.2478,194.936' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 128.065,90.1543 L 101.734,86.6282' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 101.734,86.6282 L 75.404,83.1021' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-8' d='M 190.489,98.514 L 216.819,102.04' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-8' d='M 216.819,102.04 L 243.15,105.566' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-9' d='M 190.489,98.514 L 216.819,102.04' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-9' d='M 216.819,102.04 L 243.15,105.566' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 43.9338,109.378 L 40.4905,135.091' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 40.4905,135.091 L 37.0471,160.803' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-10' d='M 75.404,98.0807 L 149.946,148.725' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-10' d='M 149.946,148.725 L 224.487,199.369' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 64.2478,180.047 L 153.699,149.356' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 153.699,149.356 L 243.15,118.665' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-11' d='M 64.2478,180.047 L 153.699,149.356' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-11' d='M 153.699,149.356 L 243.15,118.665' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 266.597,139.197 L 263.154,164.909' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 263.154,164.909 L 259.71,190.622' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 259.71,190.622 L 263.154,164.909' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 263.154,164.909 L 266.597,139.197' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="middle" x='144.367' y='211.282' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='175.512' y='99.9505' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='60.4272' y='85.0411' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='49.2711' y='196.373' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='258.126' y='114.86' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='239.464' y='226.191' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='258.126' y='114.86' style='font-size:37px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<path d='M 263.12,116.732 L 263.12,101.755 L 278.097,101.755 L 278.097,116.732 L 263.12,116.732' style='fill:none;stroke:#FF0000;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1;' />
</svg>
 data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='85px' height='85px' viewBox='0 0 85 85'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='85' height='85' x='0' y='0'> </rect>
<path class='bond-0' d='M 41.1332,52.4275 L 42.5297,42' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 42.5297,42 L 43.9261,31.5725' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-6' d='M 45.0054,58.3247 L 55.6074,59.7445' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-6' d='M 55.6074,59.7445 L 66.2094,61.1643' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-7' d='M 35.8458,57.0981 L 25.2438,55.6783' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-7' d='M 25.2438,55.6783 L 14.6419,54.2585' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 38.9946,25.5334 L 28.3926,24.1136' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 28.3926,24.1136 L 17.7906,22.6938' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-8' d='M 50.2728,27.0437 L 60.8748,28.4635' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-8' d='M 60.8748,28.4635 L 71.4768,29.8833' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-9' d='M 50.2728,27.0437 L 60.8748,28.4635' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-9' d='M 60.8748,28.4635 L 71.4768,29.8833' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 12.5032,27.3644 L 11.1068,37.7919' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 11.1068,37.7919 L 9.71036,48.2194' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-10' d='M 17.7906,25.192 L 42,41.6401' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-10' d='M 42,41.6401 L 66.2094,58.0882' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 14.6419,51.5685 L 43.0593,41.8183' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 43.0593,41.8183 L 71.4768,32.068' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-11' d='M 14.6419,51.5685 L 43.0593,41.8183' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-11' d='M 43.0593,41.8183 L 71.4768,32.068' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 75.349,35.7806 L 73.9525,46.2081' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 73.9525,46.2081 L 72.5561,56.6356' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 72.5561,56.6356 L 73.9525,46.2081' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 73.9525,46.2081 L 75.349,35.7806' style='fill:none;fill-rule:evenodd;stroke:#4284F4;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="middle" x='40.4256' y='59.2966' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='49.216' y='27.8737' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='16.7339' y='23.6656' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='13.5851' y='55.0885' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='72.5335' y='32.0818' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='67.2661' y='63.5047' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='72.5335' y='32.0818' style='font-size:10px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#4284F4' ><tspan>N</tspan></text>
<path d='M 73.943,32.6102 L 73.943,28.3831 L 78.1701,28.3831 L 78.1701,32.6102 L 73.943,32.6102' style='fill:none;stroke:#FF0000;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1;' />
</svg>
 N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 49
238000001039 wet etching Methods 0.000 description 13
The present invention relates to a semiconductor device and a manufacturing method thereof, and more particularly to a semiconductor device having a nonvolatile memory and a manufacturing method thereof.
In a semiconductor device having a nonvolatile memory, in addition to flash memory cells, a high voltage transistor for controlling a flash memory and a low voltage transistor for a high performance logic circuit are integrated on the same semiconductor chip. Here, unlike a single-layer gate electrode in a high-voltage transistor or a low-voltage transistor, a flash memory cell has a stack-structure gate electrode in which a floating gate and a control gate are stacked. Therefore, a semiconductor device having a nonvolatile memory has a unique manufacturing process in which a gate electrode having a single layer structure and a gate electrode having a stack structure are formed through the same process.
For example, in the case of manufacturing a semiconductor device having a flash memory cell with a fine stack structure after 90 nm technology, a groove formed at the time of element isolation by an STI (Shallow Trench Isolation) method in a peripheral circuit region and a flash memory cell region. It is necessary to change the depth. That is, in the peripheral circuit region, it is necessary to form a groove by the STI method to some extent in order to ensure insulation between transistors to which a high voltage is applied. On the other hand, in the flash memory cell region, it is necessary to form a shallower trench by the STI method than in the peripheral circuit region in order to avoid inconveniences such as defective filling of the element isolation region.
As a method of forming trenches having different depths in the peripheral circuit region and the flash memory cell region by the STI method, it is conceivable to perform element isolation by the STI method independently in the peripheral circuit region and the flash memory cell region.
However, for example, high overlay accuracy is required for fine device patterns after 90 nm technology. For this reason, if element isolation is performed separately by the STI method in the peripheral circuit region and the flash memory cell region, unrealistic process management is required. If the margin for pattern formation is increased by relaxing the design criteria for peripheral circuits and the like in order to satisfy the requirement for overlay accuracy, it is not possible to meet the demand for miniaturization of device patterns.
In addition, a high overlay accuracy is required for the impurity diffusion layer formed in the semiconductor substrate. Impurities in such an impurity diffusion layer are diffused by heat treatment. For this reason, if the number of times of heat treatment increases as in the case where element isolation by the STI method is performed independently in the peripheral circuit region and the flash memory cell region, the overlay accuracy required for the impurity diffusion layer is satisfied. It becomes difficult. Even in this case, if the design criteria are relaxed to increase the pattern formation margin, it is not possible to meet the demand for miniaturization of the device pattern.
As a technique for forming grooves having different depths in element isolation by the STI method, for example, there is a technique described in Patent Document 1.
JP-A-7-66276 JP 2002-76148 A JP 2003-289114 A
However, the technique described in Patent Document 1 has the following difficulties.
First, dielectrics such as polysilicon are embedded in grooves having different depths formed by the STI method. For this reason, it is difficult to ensure the isolation of the element isolation required for the semiconductor device having the flash memory cell, and the technology described in Patent Document 1 is applied to the element of the semiconductor device having the flash memory cell. Even when applied to separation, it is considered that desired device characteristics cannot be obtained.
In addition, in one method described in Patent Document 1, since many heat treatments are performed when grooves having different depths are formed, diffusion of impurities in the well cannot be avoided. Such diffusion of impurities becomes an impediment to miniaturization of a semiconductor device.
In another method described in Patent Document 1, a polysilicon film pattern is formed under an NSG (Non-doped Silicate Glass) film used as an etching mask, and a step due to the presence or absence of the polysilicon film is masked. Provided. Then, using the steps of the mask film, different depth grooves are formed in the silicon substrate. However, it is considered extremely difficult to form a similar fine pattern above and below the level difference of the mask film.
SUMMARY OF THE INVENTION An object of the present invention is to provide a semiconductor device having a non-volatile semiconductor memory in which trenches having different depths can be formed without complicating the process, and a fine memory cell can be formed with high accuracy, and the semiconductor device It is to provide a manufacturing method.
According to one aspect of the present invention , the step of forming a step on the surface of the semiconductor substrate so that the surface in the first region is lower than the surface in the second region; and the first region and the second region of on the semiconductor substrate in the region, forming a first insulating film having the different semiconductor substrate and the etching characteristics, the first on the first insulating film in the region, the first comprising the floating gate forming a conductive film, wherein the first conductive film and the semiconductor substrate in the second region, the first opening is formed in said first region, said second region Forming a mask having a second opening formed thereon, etching the first conductive film exposed in the first opening, the first insulating film, and the semiconductor substrate, and Exposed in the second opening The semiconductor substrate is etched to form a first groove in the semiconductor substrate in the first region, and a second groove deeper than the first groove in the semiconductor substrate in the second region. Forming a first element isolation region that defines a first element region in the first groove, and a second element that defines a second element region in the second groove. A semiconductor device comprising: a step of forming an element isolation region; and a step of forming a control gate on the floating gate via a second insulating film and forming a gate electrode of a transistor on the second element region A manufacturing method is provided.
According to the present invention, the first conductive film serving as the floating gate is formed on the semiconductor substrate in the first region via the first insulating film having different etching characteristics from the semiconductor substrate. A mask having a first opening formed in the first region and a second opening formed in the second region is formed on the semiconductor substrate in the upper region and the second region. The first conductive film, the first insulating film, and the semiconductor substrate exposed in the opening are etched, and the semiconductor substrate exposed in the second opening is etched. The first element isolation region for defining the first element isolation region is formed relatively shallowly, and the second element isolation region for defining the second element region in the semiconductor substrate in the second region The second groove formed is relatively It is possible to Ku formation.
Further, according to the present invention, the step is formed on the surface of the semiconductor substrate so that the surface in the first region is lower than the surface in the second region, so that the first conductive film constituting the floating gate is formed. The height of the upper surface and the height of the upper surface of the semiconductor substrate in the second region can be made substantially equal. Therefore, the semiconductor substrate and the first conductive film in the second region can be patterned with high accuracy, and thus a semiconductor device having fine memory cells can be provided.
According to the present invention, the flatness of the substrate surface on which the conductive film for forming the control gate in the first region and the gate electrode in the second region is formed by the step formed on the surface of the semiconductor substrate. The conductive film can be formed flat. Therefore, a fine control gate can be formed with high accuracy in the first region, and a fine gate electrode can be formed with high accuracy in the second region.
Further, according to the present invention, when the first conductive film constituting the floating gate is patterned, the first trench in which the first element isolation region in the first region is formed is formed in a self-aligned manner. Therefore, the first groove can be formed without requiring high-precision pattern superposition. Therefore, according to the present invention, it is possible to easily cope with the miniaturization of the memory cell.
Furthermore, according to the present invention, since the side wall portion formed of the second conductive film is formed on the side wall portion of the floating gate, the capacitance between the floating gate and the control gate can be increased. . For this reason, according to the present invention, it is possible to sufficiently secure the capacitance between the floating gate and the control gate even when the memory cell is further miniaturized. For this reason, according to the present invention, a desired coupling ratio can be obtained even when the memory cell is miniaturized, and a memory cell with good electrical characteristics can be obtained.
The semiconductor device and the manufacturing method thereof according to the first embodiment of the present invention will be described with reference to FIGS. FIG. 1 is a schematic view showing the structure of the semiconductor device according to the present embodiment, FIGS. 2 to 41 are process diagrams showing the method of manufacturing the semiconductor device according to the present embodiment, and FIGS. 42 to 48 are steps formed on the surface of the silicon substrate. It is process sectional drawing explaining the inconvenience when not carrying out.
First, the structure of the semiconductor device according to the present embodiment will be explained with reference to FIG. 1A is a plan view showing the structure of the semiconductor device according to the present embodiment, and FIG. 1B is a cross-sectional view taken along the lines AA ′ and BB ′ in FIG.
The semiconductor device according to the present embodiment has a flash memory cell region 10 in which flash memory cells 46 are formed, and a peripheral circuit region 12 in which peripheral circuits are formed. The peripheral circuit region 12 has an NMOS transistor region 12n where the NMOS transistor 62 is formed and a PMOS transistor region 12p where the PMOS transistor 66 is formed.
On the surface of the silicon substrate 14, a step is formed between the flash memory cell region 10 and the peripheral circuit region 12. That is, the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12. The height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 is substantially equal to the height of the upper surface of a doped amorphous silicon film 34 described later formed in the flash memory cell region 10.
As will be described later, the step 16 on the surface of the silicon substrate 14 near the boundary between the flash memory cell region 10 and the peripheral circuit region 12 is used to form a tunnel oxide film and a floating gate of the flash memory cell 46, respectively. The resulting silicon oxide film 30 and doped amorphous silicon film 34 remain.
A trench 18 for element isolation is formed in the silicon substrate 14 in the flash memory cell region 10. The trench 18 is formed by etching the silicon substrate 14 when the doped amorphous silicon film 34 for forming the floating gate 32 is patterned. That is, the trench 18 is formed in a self-aligned manner when the doped amorphous silicon film 34 for forming the floating gate 32 is patterned. In the trench 18, an element isolation region 20 a made of a silicon oxide film is formed. A trench 22 for element isolation deeper than the trench 18 is formed in the silicon substrate 14 in the vicinity of the boundary between the flash memory cell region 10 and the peripheral circuit region 12. In the trench 22, an element isolation region 20b made of a silicon oxide film is formed.
A trench 24 for element isolation is formed in the silicon substrate 14 in the peripheral circuit region 12. The depth of the groove 24 is deeper than the depth of the groove 18 in the flash memory region 10 and is equal to the depth of the groove 22 in the vicinity of the boundary between the flash memory cell region 10 and the peripheral circuit region 12. In the trench 24, an element isolation region 20c made of a silicon oxide film is formed.
An n-type deep well 26 is formed in the silicon substrate 14 in the flash memory cell region 10. A p-type well 28 shallower than the n-type deep well 26 is formed in the n-type deep well 26.
A floating gate 32 is formed via a tunnel oxide film 30 on the silicon substrate 14 in the element region defined by the element isolation region 20 a formed in the groove 18 in the flash memory cell region 10. The floating gate 32 includes a main portion 34 made of a doped amorphous silicon film formed on the tunnel oxide film 30 and a side wall made of a doped amorphous silicon film formed on the side wall portion of the main portion 34 on the element isolation region 20a side. Part 36. A plurality of floating gates 32 are arranged and formed on the silicon substrate 14 between the element isolation regions 20 a embedded in the trenches 18.
A gate electrode (control gate) 40 made of a polysilicon film is formed on the floating gate 32 through an ONO film 38 having a silicon oxide film / silicon nitride film / silicon oxide film structure. The control gate 40 is formed in a stripe shape extending over the plurality of floating gates 32 across the element isolation region 20 a formed in the trench 18.
Source / drain regions 42 having an LDD structure are formed in the silicon substrate 14 on both sides of the control gate 40.
A sidewall insulating film 44 is formed on the sidewall portion of the control gate 40 and the sidewall portion of the floating gate 32.
Thus, a flash memory cell 46 having a stacked gate structure having the floating gate 32, the control gate 40, and the source / drain region 42 is formed in the flash memory region 10.
An n-type deep well 48 is formed in the silicon substrate 14 in a region where a predetermined NMOS transistor is formed in the NMOS transistor region 12n of the peripheral circuit region 12. A p-type well 50 shallower than the n-type deep well 48 is formed in the silicon substrate 14 in the NMOS transistor region 12n including the region where the n-type deep well 48 is formed.
An n-type well 52 that is shallower than the n-type deep well 48 is formed in the silicon substrate 14 in the PMOS transistor region 12 p of the peripheral circuit region 12.
In the NMOS transistor region 12 n, a gate electrode 56 is formed on the silicon substrate 14 in the element region defined by the element isolation region 20 c formed in the trench 24 via a gate insulating film 54. Source / drain regions 58 having an LDD structure are formed in the silicon substrate 14 on both sides of the gate electrode 56. A sidewall insulating film 60 is formed on the side wall portion of the gate electrode 56. Thus, the NMOS transistor 62 having the gate electrode 56 and the source / drain region 58 is formed in the NMOS transistor region 12n.
In the PMOS transistor region 12 p, a gate electrode 56 is formed on the silicon substrate 14 in the element region defined by the element isolation region 20 c formed in the trench 24 via a gate insulating film 54. A source / drain region 64 having an LDD structure is formed in the silicon substrate 14 on both sides of the gate electrode 56. A sidewall insulating film 60 is formed on the side wall portion of the gate electrode 56. Thus, the PMOS transistor 66 having the gate electrode 56 and the source / drain region 64 is formed in the PMOS transistor region 12p.
A silicide film 68 is formed on the control gate 40 and the source / drain region 42 in the flash memory cell region 10. A silicide film 68 is formed on the gate electrode 56 and the source / drain regions 58 and 64 in the peripheral circuit region 12.
In the flash memory cell region 10, the region on the peripheral circuit region 12 side where the flash memory cell 46 is not formed and the region on the flash memory cell region 10 side where no transistor is formed in the peripheral circuit region 12 are on the silicon substrate 14. An ONO film 38 is formed on the element isolation regions 20 b and 20 c and on the doped amorphous silicon film 34 in the step portion 16.
On the silicon substrate 14 in which the flash memory cell 46 is formed in the flash memory cell region 10 and the NMOS transistor 62 and the PMOS transistor 66 are formed in the peripheral circuit region 12, an interlayer insulating film 70 is formed.
In the flash memory cell region 10, a contact hole 72 reaching the silicide film 68 on the control gate 40 and a contact hole 74 reaching the silicide film 68 on the source / drain region 42 are formed in the interlayer insulating film 70. . An electrode plug 76 that is electrically connected to the control gate 40 is embedded in the contact hole 72. An electrode plug 78 that is electrically connected to the source / drain region 42 is embedded in the contact hole 74.
In peripheral circuit region 12, contact hole 80 reaching silicide film 68 on gate electrode 56 and contact holes 82 and 84 reaching silicide film 68 on source / drain regions 58 and 64 are formed in interlayer insulating film 70. Has been. An electrode plug 86 that is electrically connected to the gate electrode 56 is embedded in the contact hole 80. In the contact holes 82 and 84, electrode plugs 88 and 90 electrically connected to the source / drain regions 58 and 64 are embedded.
In the semiconductor device according to the present embodiment, a step is formed on the surface of the silicon substrate 14 such that the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12. A trench 18 for shallow device isolation is formed in the silicon substrate 14 in the flash memory cell region 10, and a trench 24 for device isolation deeper than the trench 18 is formed in the silicon substrate 14 in the peripheral circuit region 12. There is one of the main features.
According to the present embodiment, the step is formed on the surface of the silicon substrate 14 so that the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12. The height of the upper surface of the doped amorphous silicon film 34 constituting the floating gate 32 and the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 can be made substantially equal. Since the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 and the height of the upper surface of the doped amorphous silicon film 34 constituting the floating gate 32 can be made substantially equal, as described later, When exposing the photoresist film 104 (see FIG. 13) for patterning the silicon substrate 14 and the doped amorphous silicon film 34 in the flash memory cell region 10, it is possible to perform extremely high-precision exposure. For this reason, according to the present embodiment, the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 constituting the floating gate 32 can be patterned with high precision. A semiconductor device having the same can be provided.
Moreover, according to the present embodiment, since the tunnel oxide film 30 having a low etching rate exists under the doped amorphous silicon film 34, the etching rate in the flash memory cell region 10 is slowed as will be described later. Can do. For this reason, the groove 24 in the peripheral circuit region 12 can be formed relatively deep, while the groove 18 in the flash memory region 10 can be formed relatively shallow.
In addition, the semiconductor device according to the present embodiment has one of the main features that the groove 18 is also formed when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned, as will be described later. In other words, the semiconductor device according to the present embodiment has one of the main features that the trench 18 is formed in a self-aligning manner when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned.
According to the present embodiment, since the groove 18 is also formed when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned, the groove 18 can be formed without requiring high-precision pattern superposition. it can. Therefore, according to the present embodiment, it is possible to easily cope with the miniaturization of the memory cell.
Furthermore, the semiconductor device according to the present embodiment includes the main portion 34 in which the trench 18 is formed in a self-aligned manner when the floating gate 32 is formed, and the side wall portion 36 formed in the side wall portion of the main portion 34. This is one of the main characteristics.
The side wall portion 36 of the floating gate 32 makes it possible to increase the capacitance between the floating gate 32 and the control gate 40 as compared with the case where the floating gate 32 is composed of only the main portion 34. For this reason, according to the present embodiment, it is possible to ensure a sufficient capacitance between the floating gate 32 and the control gate 40 even when the memory cell is further miniaturized. For this reason, according to the present embodiment, a desired coupling ratio can be obtained even when the memory cell is miniaturized, and a memory cell with good electrical characteristics can be obtained.
Next, the method for fabricating the semiconductor device according to the present embodiment will be explained with reference to FIGS. (A) in FIGS. 2 to 41 is a plan view, (b) in FIGS. 2 to 37 is a cross-sectional view taken along the line AA ′ in FIGS. 2 to 37, and FIGS. 41B is a cross-sectional view taken along lines AA ′ and BB ′ of FIG. 38A to FIG. 41A, respectively.
First, a silicon oxide film 92 of, eg, a 10 nm-thickness is grown as a sacrificial oxide film on the silicon substrate 14 by, eg, thermal oxidation (see FIG. 2).
Next, a photoresist film 94 that covers the peripheral circuit region 12 and exposes the flash memory cell region 10 is formed on the silicon oxide film 92 by photolithography (see FIG. 3).
Next, ion implantation is performed using the photoresist film 94 as a mask to form an n-type deep well 26 in the silicon substrate 14 in the flash memory cell region 10 (see FIG. 4).
Next, ion implantation is performed using the photoresist film 94 as a mask to form a p-type well 28 in the n-type deep well 26 (see FIG. 5).
Next, the silicon oxide film 92 is etched by wet etching, for example, using the photoresist film 94 as a mask, and the silicon oxide film 92 in the flash memory cell region 10 is removed (see FIG. 6).
Next, the photoresist film 94 is removed by, for example, ashing.
Next, for example, by chemical dry etching, the surface layer portion of the silicon substrate 14 is etched using the silicon oxide film 92 as a mask, so that the surface of the silicon substrate 14 in the flash memory cell region 10 is more than the surface of the silicon substrate 14 in the peripheral circuit region 12 Lower (see FIG. 7). At this time, the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 is substantially equal to the height of the upper surface of a doped amorphous silicon film 34 described later formed in the flash memory cell region 10. A step is formed on the surface. Specifically, the step between the surface of the silicon substrate 14 in the flash memory cell region 10 and the surface of the silicon substrate 14 in the peripheral circuit region 12 is formed to be 70 nm, for example.
The reason why the silicon substrate 14 is etched using only the silicon oxide film 92 as a mask after removing the photoresist film 94 is that the surface of the silicon substrate 14 is contaminated by organic substances contained in the photoresist film 94. It is for preventing.
After a step is thus formed between the surface of the silicon substrate 14 in the flash memory cell region 10 and the surface of the silicon substrate 14 in the peripheral circuit region 12, the silicon oxide film 92 is removed by wet etching, for example (see FIG. 8).
Next, a silicon oxide film having a thickness of, for example, 5 to 200 nm is grown as a sacrificial oxide film on the silicon substrate 14 by, eg, thermal oxidation. Thereby, the damage on the surface of the silicon substrate 14 is recovered. Subsequently, the silicon oxide film is removed by wet etching, for example.
Next, a silicon oxide film 30 of, eg, a 10 nm-thickness is grown on the silicon substrate 14 by, eg, thermal oxidation. As will be described later, the silicon oxide film 30 is used as a tunnel oxide film of the flash memory cell 46.
Next, a doped amorphous silicon film 34 of, eg, a 70 nm-thickness is deposited on the silicon oxide film 30 by, eg, CVD (Chemical Vapor Deposition) method (see FIG. 9). The doped amorphous silicon film 34 is used as a main part of the floating gate 32 of the flash memory cell 46, as will be described later.
The thickness of the doped amorphous silicon film 34 is set so that the height of the upper surface of the doped amorphous silicon film 34 in the flash memory cell region 10 is substantially equal to the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12. It is desirable to set. By making the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 substantially equal to the height of the upper surface of the doped amorphous silicon film 34 in the flash memory cell 10, This is because extremely high-precision exposure can be performed when the photoresist film 104 (see FIG. 13) for patterning the doped amorphous silicon film 34 in the flash memory cell region 10 is exposed. As a result, the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 constituting the floating gate 32 can be patterned with high accuracy. As a result, a semiconductor device having fine memory cells is provided. Is possible.
Next, a photoresist film 96 is formed on the doped amorphous silicon film 34 by photolithography so as to cover a region where the flash memory cell 46 is to be formed in the flash memory cell region 10 and expose other regions (see FIG. 10). .
Next, using the photoresist film 96 as a mask, the doped amorphous silicon film 34 is etched by dry etching, for example, and the doped amorphous silicon film 34 other than the region where the flash memory cell 46 is to be formed is removed (see FIG. 11). The doped amorphous silicon film 34 remains on the step portion 16 on the surface of the silicon substrate 14.
Next, the silicon oxide film 30 is etched using the photoresist film 96 as a mask.
Next, the photoresist film 96 is removed by, for example, ashing.
Next, for example, thermal oxidation corresponding to 10 nm is performed, and a silicon oxide film 98 is grown as a sacrificial oxide film on the silicon substrate 14 and the doped amorphous silicon film 34.
Next, a silicon nitride film 100 of, eg, a 100 nm-thickness is deposited on the silicon oxide film 98 by, eg, CVD (see FIG. 12).
Next, a photoresist film 104 having openings 102a, 102b, and 102c exposing the regions where the trenches 18, 22, and 24 for element isolation are to be formed is formed on the silicon nitride film 100 by photolithography (FIG. 13). reference). As described above, since the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 and the height of the upper surface of the doped amorphous silicon film 34 in the flash memory cell 10 are set to be approximately equal, the photoresist film is formed by photolithography. When exposing 104, it is possible to perform extremely high-precision exposure. As a result, the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 constituting the floating gate 32 can be patterned with high accuracy. As a result, a semiconductor device having fine memory cells is provided. Is possible.
Next, using the photoresist film 104 as a mask, the silicon nitride film 100 is etched by dry etching, for example, and the openings 106a exposing the regions where the trenches 18, 22, and 24 for element isolation are to be formed are exposed in the silicon nitride film 100. 106b and 106c are formed (see FIG. 14).
Next, the photoresist film 104 is removed by, for example, ashing (see FIG. 14).
Next, using the silicon nitride film 100 as a mask, the silicon oxide film 98, the doped amorphous silicon film 34, the silicon oxide film 30, and the silicon substrate 14 exposed in the opening 106a are etched by dry etching, for example, and the opening The silicon oxide film 98 and the silicon substrate 14 exposed at 106b and 106c are etched (see FIGS. 15, 16, and 17). Thus, trenches 18 and 22 for element isolation are formed in the flash memory cell region 10 and a trench 24 for element isolation is formed in the peripheral circuit region 12 (see FIG. 17). At this time, the etching condition is such that the selection ratio of the silicon layer (doped amorphous silicon film 34, silicon substrate 14) to the silicon oxide film is, for example, 10. Note that the selection ratio of the silicon layer to the silicon oxide film during etching is not limited to 10, and can be changed as appropriate according to the depth of the grooves 18, 22, 24 to be formed.
Here, after the silicon oxide film 98 is removed by etching, only the silicon layer (silicon substrate 14) is etched in the openings 106b and 106c exposing the regions where the grooves 22 and 24 are to be formed. On the other hand, the silicon oxide film 30 exists under the doped amorphous silicon film 34 in the opening 106a exposing the region where the trench 18 is to be formed. Due to the silicon oxide film 30 having etching characteristics different from those of the silicon layer, the progress of etching in the opening 106a is slower than the progress of etching in the openings 106b and 106c. Thereby, the groove 18 is formed shallower than the grooves 22 and 24.
Specifically, first, the doped amorphous silicon film 34 is etched in the opening 106a, whereas in the openings 106b and 106c, the thickness of the etched doped amorphous silicon film 34 is the same. The silicon substrate 14 is etched by this depth, and grooves 22 and 24 are formed in the silicon substrate 14 (see FIG. 15). For example, the doped amorphous silicon film 34 having a film thickness of 60 nm is etched in the opening 106a, whereas the silicon substrate 14 is etched by a depth of 60 nm in the openings 106b and 106c. 14, grooves 22 and 24 having a depth of 60 nm are formed.
FIG. 15 shows a state in which etching has progressed until the silicon oxide film 30 is exposed in the opening 106a.
Thereafter, when the etching is further advanced, the silicon oxide film 30 is etched at a relatively slow speed in the opening 106a, whereas the silicon substrate 14 is relatively fast in the openings 106b and 106c. Etched at a rate (see FIG. 16). For example, when an etching condition in which the selection ratio of the silicon layer to the silicon oxide film is 10 is used, the silicon oxide film 30 having a thickness of 10 nm is etched in the opening 106a, whereas the openings 106b and 106c In FIG. 5, the silicon substrate 14 is further etched by the depth of 100 nm, and the depth of the grooves 22 and 24 is 160 nm in total.
FIG. 16 shows a state in which etching has progressed until the silicon substrate 14 is exposed in the opening 106a.
Thereafter, when the etching further proceeds, the etching further proceeds at substantially the same speed in the opening 106a and the openings 106b and 106c (see FIG. 17). For example, when the silicon substrate 14 is etched by a depth of 140 nm in the opening 106a, the silicon substrate 14 is further etched by a depth of 140 nm in the openings 106b and 106c. The total depth of 22 and 24 is 300 nm. Thus, a groove 18 having a depth of 140 nm is formed in the silicon substrate 14 in the opening 106a, whereas a groove 22 having a depth of 300 nm deeper than the groove 18 is formed in the silicon substrate 14 in the openings 106b and 106c. 24 is formed.
While the trenches 18, 22, and 24 for element isolation are formed as described above, in the flash memory cell region 10, the doped amorphous silicon film 34 and the silicon oxide film 30 constituting the floating gate 32 are patterned. . That is, the semiconductor device manufacturing method according to the present embodiment forms the trenches 18 in a self-aligning manner when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned. As described above, since the groove 18 is also formed when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned, the groove 18 can be formed without requiring superposition of highly accurate patterns. Therefore, according to the present embodiment, it is possible to easily cope with the miniaturization of the memory cell.
Next, thermal oxidation or the like is performed to form a silicon oxide film (not shown) for a liner on the inner surfaces of the grooves 18, 22, 24, and then, for example, a film thickness of 500 to 900 nm is formed on the entire surface by, for example, high density plasma CVD. A silicon oxide film 20 is deposited (see FIG. 18).
Next, the silicon oxide film 20 is polished by, for example, CMP (Chemical Mechanical Polishing) until the surface of the silicon nitride film 100 is exposed, and the silicon oxide film 20 on the silicon nitride film 100 is removed. Thus, the silicon oxide film 20 is embedded in the grooves 18, 22, 24 formed in the silicon substrate 14.
Thus, element isolation regions 20a, 20b, and 20c made of silicon oxide films embedded in the trenches 18, 22, and 24 having different depths are formed by the STI method (see FIG. 19).
In the case where no step is formed on the surface of the silicon substrate 14 as in the present embodiment, the following inconvenience may occur. Hereinafter, a case where no step is formed on the surface of the silicon substrate 14 will be described with reference to FIGS.
First, on the silicon substrate 14 on which the n-type deep well 26 and the p-type well 28 are formed in the same manner as described above, a silicon oxide having a film thickness of, for example, 9.5 nm is formed by, for example, thermal oxidation without forming a step on the surface. An oxide film 30 is grown.
Next, a doped amorphous silicon film 34 of, eg, a 70 nm-thickness is deposited on the silicon oxide film 30 by, eg, CVD (see FIG. 42A).
Next, a photoresist film 96 is formed on the doped amorphous silicon film 34 by photolithography so as to cover the area where the flash memory cell 46 is to be formed in the flash memory cell area 10 and expose the other areas (FIG. 42B). )reference).
Next, using the photoresist film 96 as a mask, the doped amorphous silicon film 34 is etched by dry etching, for example, and the doped amorphous silicon film 34 other than the flash memory cell region 10 is removed (see FIG. 43A).
Next, a silicon nitride film 100 of, eg, a 100 nm-thickness is deposited on the silicon oxide film 98 by, eg, CVD (see FIG. 43B).
Next, a photoresist film 104 having openings 102a and 102c exposing the regions where the trenches 18 and 24 for element isolation are to be formed is formed on the silicon nitride film 100 by photolithography (see FIG. 44A). ).
Next, using the photoresist film 104 as a mask, the silicon nitride film 100 is etched by dry etching, for example, and openings 106a and 106c exposing the regions where the trenches 18 and 24 for element isolation are to be formed are exposed in the silicon nitride film 100. you formed.
Next, the photoresist film 104 is removed by, for example, ashing (see FIG. 44B).
Next, using the silicon nitride film 100 as a mask, the silicon oxide film 98, the doped amorphous silicon film 34, the silicon oxide film 30, and the silicon substrate 14 exposed in the opening 106a are etched by dry etching, for example, and the opening The silicon oxide film 98 and the silicon substrate 14 exposed in 106c are etched (see FIGS. 45A, 45B, and 46). As a result, a trench 18 for element isolation is formed in the flash memory cell region 10, and a trench 24 for element isolation is formed in the peripheral circuit region 12 (see FIG. 46).
Here, after the silicon oxide film 98 is removed by etching, only the silicon layer (silicon substrate 14) is etched in the opening 106c exposing the region where the groove 24 is to be formed. On the other hand, the silicon oxide film 30 exists under the doped amorphous silicon film 34 in the opening 106a exposing the region where the trench 18 is to be formed. Due to the silicon oxide film 30 having etching characteristics different from those of the silicon layer, the progress of etching in the opening 106a is slower than the progress of etching in the opening 106c. Thereby, the groove 18 is formed shallower than the groove 24.
Specifically, first, the doped amorphous silicon film 34 is etched in the opening 106a, whereas the depth equal to the thickness of the etched doped amorphous silicon film 34 in the opening 106c. The silicon substrate 14 is etched by that amount, and a groove 24 is formed in the silicon substrate 14 (see FIG. 45A). For example, the doped amorphous silicon film 34 having a thickness of 60 nm is etched in the opening 106a, whereas the silicon substrate 14 is etched by a depth of 60 nm in the opening 106c. A groove 24 having a depth of 60 nm is formed.
FIG. 45A shows a state where etching has progressed until the silicon oxide film 30 is exposed in the opening 106a.
Thereafter, when the etching is further advanced, the silicon oxide film 30 is etched at a relatively slow speed in the opening 106a, whereas the silicon substrate 14 is etched at a relatively high speed in the opening 106c. Etching is performed (see FIG. 45B). For example, when an etching condition in which the selection ratio of the silicon layer to the silicon oxide film is 10 is used, the silicon oxide film 30 having a film thickness of 9.5 nm is etched in the opening 106a, whereas in the opening 106c. In FIG. 5, the silicon substrate 14 is further etched by the depth of 95 nm, and the depth of the groove 24 is 155 nm in total.
FIG. 45B shows a state in which etching has progressed until the silicon substrate 14 is exposed in the opening 106a.
Thereafter, when the etching further proceeds, the etching further proceeds at substantially the same speed in the opening 106a and the opening 106c (see FIG. 46). For example, when the silicon substrate 14 is etched by a depth of 125 nm in the opening 106a, the silicon substrate 14 is further etched by a depth of 125 nm in the opening 106c, and the groove 24 The depth is 280 nm in total. Thus, a groove 18 having a depth of 125 nm is formed in the silicon substrate 14 in the opening 106a, whereas a groove 24 having a depth of 280 nm deeper than the groove 18 is formed in the silicon substrate 14 in the opening 106c. The
While the trenches 18 and 24 for element isolation are formed as described above, the doped amorphous silicon film 34 and the silicon oxide film 30 constituting the floating gate 32 are patterned in the flash memory cell region 10. That is, when patterning the doped amorphous silicon film 34 constituting the floating gate 32, the groove 18 is formed in a self-aligning manner.
Next, thermal oxidation or the like is performed to form a silicon oxide film (not shown) for the liner on the inner surfaces of the grooves 18 and 24, and then, for example, silicon having a film thickness of 500 to 900 nm is formed on the entire surface by, for example, high-density plasma CVD. An oxide film 20 is deposited (see FIG. 47).
Next, the silicon oxide film 20 is polished by CMP, for example, until the surface of the silicon nitride film 100 is exposed, and the silicon oxide film 20 on the silicon nitride film 100 is removed. Thus, the silicon oxide film 20 is embedded in the grooves 18 and 24 formed in the silicon substrate 14.
Thus, element isolation regions 20a and 20c made of silicon oxide films embedded in the trenches 18 and 24 having different depths are formed by the STI method (see FIG. 48).
However, if no step is formed on the surface of the silicon substrate 14, when the silicon oxide film 20 is polished until the silicon nitride film 100 in the peripheral circuit region 12 is exposed, the silicon nitride film 100 is formed in the flash memory cell region 10. All may be removed. In such a case, the silicon oxide film 98 on the floating gate (doped amorphous silicon film 34) and even the doped amorphous silicon film 34 are damaged by polishing by the CMP method. Thus, when the silicon nitride film 100 is removed in the flash memory cell region 10 and the silicon oxide film 98 and further the doped amorphous silicon film 34 are exposed, the subsequent processes cannot be performed.
In contrast to the case where no step is formed on the surface of the silicon substrate 14 that causes such inconvenience, in the present embodiment, the surface of the silicon substrate 14 in the flash memory cell region 10 is the surface of the silicon substrate 14 in the peripheral circuit region 12. A step is formed on the surface of the silicon substrate 14 so as to be lower. Therefore, it is possible to avoid the removal of the silicon nitride film 100 on the doped amorphous silicon film 34 during the polishing by the CMP method for forming the element isolation regions 20a, 20b, and 20c. In order to surely avoid the removal of the silicon nitride film 100 on the doped amorphous silicon film 34, the height of the surface of the silicon substrate 14 in the peripheral circuit region 12 is formed in the flash memory cell region 10. A step is formed on the surface of the silicon substrate 14 so as to be approximately equal to or higher than the height of the upper surface of the doped amorphous silicon film 34.
Therefore, in the semiconductor device manufacturing method according to the present embodiment, the silicon oxide film 98 and the doped amorphous silicon film 34 on the doped amorphous silicon film 34 are damaged by polishing by the CMP method, or the element isolation regions 20a, 20b, There is no inconvenience that the process after forming 20c becomes impossible.
By forming steps on the surface of the silicon substrate 14 and forming the element isolation regions 20a, 20b, and 20c without the above-described disadvantages, the peripheral portions in the peripheral circuit region 12 and the flash memory cell region 10 are formed by photolithography. A photoresist film 108 is formed which covers the boundary region on the circuit region 12 side and exposes the region where the flash memory cell 46 is to be formed in the flash memory cell region 10.
Next, using the photoresist film 108 as a mask, the upper portion of the element isolation region 20a in the flash memory cell formation scheduled region is etched away by, for example, a thickness of 140 nm by dry etching, for example (see FIG. 20). At this time, the upper portion of the element isolation region 20 a is etched so that the upper surface of the element isolation region 20 a is slightly higher than the upper surface of the tunnel oxide film 30 or the same position as the upper surface of the tunnel oxide film 30.
Next, a doped amorphous silicon film 36 of, eg, a 120 nm-thickness is deposited on the entire surface by, eg, CVD (see FIG. 21). Thus, the doped amorphous silicon film 36 is embedded in the opening on the element isolation region 20a between the main portions 34 of the adjacent floating gates 32.
Next, the doped amorphous silicon film 36 is etched back to leave the doped amorphous silicon film 36 only on the element isolation region 20a, and the doped amorphous silicon film 36 in other regions is removed. At this time, the doped amorphous silicon film 36 is formed so that the upper surface of the doped amorphous silicon film 36 on the element isolation region 20 a is at the same position as the upper surface of the silicon oxide film 98 on the main part 34 of the floating gate 32. Etch back.
Next, a silicon oxide film 110 of, eg, a 10 nm-thickness is grown on the surface of the doped amorphous silicon film 36 by, eg, thermal oxidation (see FIG. 22).
Next, a silicon nitride film 112 of, eg, a 5 nm-thickness is deposited as a spacer film on the entire surface by, eg, CVD (see FIG. 23).
Next, the silicon nitride film 112 is etched back, leaving the silicon nitride film 112 only on the side walls of the silicon nitride film 100 on the main part 34 of the floating gate 32, and removing the silicon nitride film 112 in other regions.
Next, using the silicon nitride film 112 as a mask, the doped amorphous silicon film 36 is etched by dry etching, for example, so that the doped amorphous silicon film 36 remains on the side wall portion of the main portion 34 of the floating gate 32 (see FIG. 24). ).
Thus, the side wall portion 36 of the floating gate 32 made of the doped amorphous silicon film is formed in a self-aligned manner on the side wall portion of the main portion 34 of the floating gate 32. The side wall portion 36 can further reduce the interval between the adjacent floating gates 32 as compared with the case where the floating gate 32 is constituted by only the main portion 34. As a result, the capacitance between the floating gate 32 and the control gate 40 can be increased. For this reason, according to the present embodiment, it is possible to ensure a sufficient capacitance between the floating gate 32 and the control gate 40 even when the memory cell is further miniaturized. For this reason, according to the present embodiment, a desired coupling ratio can be obtained even when the memory cell is miniaturized, and a memory cell with good electrical characteristics can be obtained.
Next, a silicon oxide film 114 of, eg, a 100 nm-thickness is deposited on the entire surface by, eg, CVD using TEOS as a source gas (see FIG. 25).
Next, the silicon oxide film 114 is etched back using, for example, wet etching. Thereby, the silicon oxide film 114 is buried between the floating gates 32, and the silicon oxide film 114 in other regions is removed. At this time, the element isolation regions 20b and 20c made of the silicon oxide film are also etched back (see FIG. 26). The element isolation region 20c is etched back until the step between the upper surface of the element isolation region 20c and the upper surface of the element region defined by the element isolation region 20c is sufficiently small to form an element in the peripheral circuit region 12. Specifically, the silicon oxide film 114 is etched back until the upper surface of the silicon oxide film 114 buried between the floating gates 32 is located, for example, 70 nm below the upper surface of the silicon nitride film 100. As a result, the element isolation regions 20 b and 20 c are also etched back, and the upper surfaces of the element isolation regions 20 b and 20 c are also lowered by, for example, 70 nm from the upper surface of the silicon nitride film 100.
Next, the silicon nitride films 100 and 112 are removed by wet etching using, for example, phosphoric acid (see FIG. 27). At this time, the periphery of the doped amorphous silicon films 34 and 36 constituting the floating gate 32 is covered with the silicon oxide films 98, 110 and 114. For this reason, the doped amorphous silicon films 34 and 36 are protected from etching. Note that the remaining film (not shown) of the unnecessary doped amorphous silicon film that is not used as the floating gate 32 is removed by this wet etching.
Next, a photoresist film 116 that covers the peripheral circuit region 12 and exposes the flash memory cell region 10 is formed by photolithography.
Next, using the photoresist film 116 as a mask, the silicon oxide film 114 on the element isolation region 20a and the silicon oxide films 98 and 110 on the floating gate 32 (doped amorphous silicon films 34 and 36) are removed by wet etching, for example. (See FIG. 28). At this time, the upper portion of the element isolation region 20b in the boundary region on the peripheral circuit region 12 side of the flash memory cell region 10 is also etched. As a result, the upper surface of the element isolation region 20b is lowered to a position equivalent to the upper surface of the element isolation region 20a.
Next, the photoresist film 116 is removed by, for example, ashing.
Next, a silicon oxide film having a thickness of, for example, 6 nm and a silicon nitride film having a thickness of, for example, 10 nm are sequentially deposited on the entire surface by, e.g., CVD. Grow the film. Thus, an ONO film 38 having a silicon oxide film / silicon nitride film / silicon oxide film structure is formed on the entire surface (see FIG. 29).
Next, by photolithography, the NMOS transistor region 12n in which the predetermined NMOS transistor 62 is formed in the NMOS transistor region 12n in the peripheral circuit region 12 is exposed, and a photoresist film 118 covering the other region is formed.
Next, ion implantation is performed using the photoresist film 118 as a mask, and an n-type deep well 48 is formed in the silicon substrate 14 in the NMOS transistor region 12n where the predetermined NMOS transistor 62 is formed in the NMOS transistor region 12n in the peripheral circuit region 12. (See FIG. 30).
Next, both regions of the NMOS transistor region 12n in which the n-type deep well 48 is formed and the NMOS transistor region 12n in which the n-type deep well 48 is not formed in the peripheral circuit region 12 are exposed by photolithography, and other regions are exposed. A covering photoresist film 120 is formed.
Next, ion implantation is performed using the photoresist film 120 as a mask to form a p-type well 50 in the silicon substrate 14 in the NMOS transistor region 12n of the peripheral circuit region 12 (see FIG. 31).
Next, the photoresist film 120 is removed by, for example, ashing.
Next, a photoresist film 122 that exposes the PMOS transistor region 12p in the peripheral circuit region 12 and covers other regions is formed by photolithography.
Next, ion implantation is performed using the photoresist film 122 as a mask to form an n-type well 52 in the silicon substrate 14 in the PMOS transistor region 12p of the peripheral circuit region 12 (see FIG. 32).
Next, the photoresist film 122 is removed by, for example, ashing.
Next, a photoresist film 124 that exposes the NMOS transistor region 12n and the PMOS transistor region 12p in the peripheral circuit region 12 and covers the other regions is formed by photolithography.
Next, the ONO film 38 is etched by dry etching, for example, using the photoresist film 124 as a mask, and the ONO film 38 in the NMOS transistor region 12n and the PMOS transistor region 12p in the peripheral circuit region 12 is removed (see FIG. 33).
Next, on the silicon substrate 14 in the NMOS transistor region 12n and the PMOS transistor region 12p in the peripheral circuit region 12, a gate insulating film 54 made of, for example, a silicon oxide film having a thickness of 1 to 20 nm is formed by, eg, thermal oxidation.
Next, a polysilicon film 126 of, eg, a 120 nm-thickness is deposited on the entire surface by, eg, CVD (see FIG. 34).
Next, the polysilicon film 126 in the flash memory cell region 10 is patterned by photolithography and dry etching, and the polysilicon film 126 in the peripheral circuit region 12 is patterned. Thus, the gate electrode (control gate) 40 made of the polysilicon film 126 is formed in the flash memory cell region 10, and the gate electrode 56 made of the polysilicon film 126 is formed in the peripheral circuit region 12. Further, in the flash memory cell region 10, the ONO film 38 and the floating gate 32 under the control gate 40 are patterned by photolithography and dry etching (see FIG. 35).
Here, due to the level difference formed on the surface of the silicon substrate 14, the level difference due to the tunnel oxide film 30 and the floating gate 32 is relaxed on the substrate surface on which the polysilicon film 126 is formed, and flatness is ensured. Therefore, the polysilicon film 126 can be formed flat. For this reason, when exposing a photoresist film (not shown) for patterning the polysilicon film 126, extremely high-precision exposure can be performed. Therefore, the fine control gate 40 and the fine gate electrode 56 can be formed with high accuracy.
Next, a photoresist film (not shown) that exposes the flash memory cell region 10 and covers other regions is formed by photolithography. Next, ion implantation is performed using this photoresist film as a mask to form an LDD region 42 a of the source / drain region 42 of the flash memory cell 46. After forming the LDD region 42a, the photoresist film used as a mask is removed by, for example, ashing.
Next, a photoresist film (not shown) that exposes the NMOS transistor region 12n and covers other regions is formed by photolithography. Next, ion implantation is performed using the photoresist film as a mask to form an LDD region 58 a of the source / drain region 58 of the NMOS transistor 62. After forming the LDD region 58a, the photoresist film used as a mask is removed by, for example, ashing.
Next, a photoresist film (not shown) that exposes the PMOS transistor region 12p and covers other regions is formed by photolithography. Next, ion implantation is performed using this photoresist film as a mask to form an LDD region 64 a of the source / drain region 64 of the PMOS transistor 66. After forming the LDD region 64a, the photoresist film used as a mask is removed by, for example, ashing.
Thus, the LDD region 42a of the source / drain region 42 of the flash memory cell 46, the LDD region 58a of the source / drain region 58 of the NMOS transistor 62, and the LDD region 64a of the source / drain region 64 of the PMOS transistor 66 are formed (FIG. 36).
Next, a silicon oxide film or a silicon nitride film having a thickness of, for example, 1 to 100 nm is formed on the entire surface by, eg, CVD. Next, this silicon oxide film or silicon nitride film is etched back to form a sidewall insulating film 44 from the silicon oxide film or silicon nitride film on the side walls of the gate electrode (control gate) 40 and the floating gate 32, and the gate electrode 56. A side wall insulating film 60 made of a silicon oxide film or a silicon nitride film is formed on the side wall portion (see FIG. 37).
Next, a photoresist film (not shown) that exposes the flash memory cell region 10 and covers other regions is formed by photolithography. Next, ion implantation is performed using the photoresist film as a mask to form the source / drain regions 42 of the flash memory cell 46. After the source / drain regions 42 are formed, the photoresist film used as a mask is removed by, for example, ashing.
Next, a photoresist film (not shown) that exposes the NMOS transistor region 12n and covers other regions is formed by photolithography. Next, ion implantation is performed using this photoresist film as a mask to form source / drain regions 58 of the NMOS transistor 62. After the source / drain regions 58 are formed, the photoresist film used as a mask is removed by, for example, ashing.
Next, a photoresist film (not shown) that exposes the PMOS transistor region 12p and covers other regions is formed by photolithography. Next, ion implantation is performed using this photoresist film as a mask to form the source / drain regions 64 of the PMOS transistor 66. After forming the source / drain regions 64, the photoresist film used as a mask is removed by, for example, ashing.
Thus, the source / drain region 42 of the flash memory cell 46, the source / drain region 58 of the NMOS transistor 62, and the source / drain region 64 of the PMOS transistor 66 are formed (see FIG. 38).
Then, the silicide is selectively silicided on the control gate 40, the gate electrode 56, and the source / drain regions 42, 58, 64 by a well-known salicide process, and then on the control gate 40, the gate electrode 56, and the source / drain. A silicide film 68 is formed on the regions 42, 58 and 64 (see FIG. 39).
In this manner, the flash memory cell 46, the NMOS transistor 62, and the PMOS transistor 66 are formed on the silicon substrate 14.
Next, a silicon oxide film is formed on the silicon substrate 14 on which the flash memory cells 46 and the like are formed by, for example, a CVD method, and the surface of the silicon oxide film is planarized by, for example, a CMP method. Thus, an interlayer insulating film 70 made of, for example, a silicon oxide film having a thickness of 250 to 500 nm is formed (see FIG. 40).
Then, after forming a contact hole 72,74,80,82,84 in the interlayer insulating film 7 0, electrode plug buried in the contact hole 72,74,80,82,84 76,78,86,88,90 (See FIG. 41).
Thus, the semiconductor device according to the present embodiment shown in FIG. 1 is manufactured.
Thus, according to the present embodiment, a step is formed on the surface of the silicon substrate 14 so that the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12. Therefore, the height of the upper surface of the doped amorphous silicon film 34 constituting the floating gate 32 and the height of the upper surface of the silicon substrate 14 in the peripheral circuit region 12 can be made substantially equal. Therefore, when exposing the photoresist film 104 for patterning the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 in the flash memory cell region 10, it is possible to perform extremely high-precision exposure. Become. For this reason, according to the present embodiment, the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 constituting the floating gate 32 can be patterned with high precision. A semiconductor device having the same can be provided.
In addition, according to the present embodiment, since the tunnel oxide film 30 having a low etching rate exists under the doped amorphous silicon film 34, the etching rate in the flash memory cell region 10 can be reduced. For this reason, the groove 24 in the peripheral circuit region 12 can be formed relatively deep, while the groove 18 in the flash memory region 10 can be formed relatively shallow.
Further, according to the present embodiment, the level difference formed on the surface of the silicon substrate 14 ensures the flatness of the substrate surface on which the polysilicon film 126 for forming the control gate 40 and the gate electrode 56 is formed. The polysilicon film 126 can be formed flat. For this reason, when exposing the photoresist film for patterning the polysilicon film 126, it is possible to perform exposure with extremely high accuracy. Therefore, the fine control gate 40 and the fine gate electrode 56 can be formed with high accuracy.
In addition, according to the present embodiment, when patterning the doped amorphous silicon film 34 constituting the floating gate 32, the groove 18 is formed in a self-aligned manner, so that the groove is not required to overlap with a highly accurate pattern. 18 can be formed. Therefore, according to the present embodiment, it is possible to easily cope with the miniaturization of the memory cell.
Further, according to the present embodiment, the floating gate 32 is constituted by the main portion 34 in which the groove 18 is formed in a self-alignment manner when formed, and the side wall portion 36 formed in the side wall portion of the main portion 34. Therefore, it is possible to increase the capacitance between the floating gate 32 and the control gate 40 as compared with the case where the floating gate 32 is composed only of the main portion 34. For this reason, according to the present embodiment, it is possible to ensure a sufficient capacitance between the floating gate 32 and the control gate 40 even when the memory cell is further miniaturized. For this reason, according to the present embodiment, a desired coupling ratio can be obtained even when the memory cell is miniaturized, and a memory cell with good electrical characteristics can be obtained.
Next, a method for manufacturing a semiconductor device according to a modification of the present embodiment will be described with reference to FIGS. 49 to 51 are process cross-sectional views illustrating a method for manufacturing a semiconductor device according to this modification.
In the method of manufacturing a semiconductor device according to the present modification, a surface layer portion of the silicon substrate 14 in the flash memory cell region 10 is selectively oxidized to form a silicon oxide film, and the silicon oxide film is removed to remove the flash memory cell. A feature is that a step is formed on the surface of the silicon substrate 14 so that the surface of the silicon substrate 14 in the region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12.
The steps up to forming the n-type deep well 26 and the p-type well 28 in the silicon substrate 14 in the flash memory cell region 10 are the same as those described above with reference to FIGS.
Next, after removing the photoresist film 94 for forming the n-type deep well 26 and the p-type well 28 by, for example, ashing, the silicon nitride film 128 having a thickness of, eg, 110 nm is formed on the silicon oxide film 92 by, eg, CVD. Is deposited (see FIG. 49A).
Next, a photoresist film 130 that exposes the flash memory cell region 10 and covers the peripheral circuit region 12 is formed by photolithography.
Next, the silicon nitride film 128 is etched by wet etching, for example, using the photoresist film 130 as a mask, and the silicon nitride film 128 in the flash memory cell region 10 is removed (see FIG. 49B).
Next, the photoresist film 130 is removed by, for example, ashing.
Then, for example, by thermal oxidation, a silicon nitride film 1 28 by oxidizing the surface layer portion of the silicon substrate 14 as a mask, the surface of the silicon substrate 14 in the flash memory cell region 10, for example, growing a film thickness 160nm of silicon oxide film 132 (See FIG. 50A).
Next, the silicon nitride film 128 is etched by, for example, wet etching, and the silicon nitride film 128 in the peripheral circuit region 12 is removed (see FIG. 50B).
Next, the silicon oxide film 92 and the silicon oxide film 132 are etched by, for example, wet etching, and the silicon oxide film 92 in the peripheral circuit region 12 and the silicon oxide film 132 in the flash memory cell region 10 are removed (see 51 (a)). By removing the silicon oxide film 132 in the flash memory cell region 10, the surface of the silicon substrate 14 in the flash memory cell region 10 is made lower than the surface of the silicon substrate 14 in the peripheral circuit region 12. A step is formed.
Next, a silicon oxide film 30 of, eg, a 10 nm-thickness is grown on the entire surface by, eg, thermal oxidation. This silicon oxide film 30 is used as a tunnel oxide film of the flash memory cell 46.
Next, a doped amorphous silicon film 34 of, eg, a 70 nm-thickness is deposited on the silicon oxide film 30 by, eg, CVD (see FIG. 51B). The doped amorphous silicon film 34 is used as a main part of the floating gate 32 of the flash memory cell 46.
The process after the doped amorphous silicon film 34 is formed is the same as the above-described case shown in FIGS.
As in the present modification, the surface layer portion of the silicon substrate 14 in the flash memory cell region 10 is selectively oxidized to form a silicon oxide film 132, and the silicon oxide film 132 is removed, whereby the flash memory cell region 10 A step may be formed on the surface of the silicon substrate 14 such that the surface of the silicon substrate 14 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12.
A semiconductor device and a manufacturing method thereof according to the second embodiment of the present invention will be described with reference to FIGS. FIG. 52 is a schematic view showing the structure of the semiconductor device according to the present embodiment, and FIGS. 53 to 59 are process sectional views showing the method for manufacturing the semiconductor device according to the present embodiment. The same components as those of the semiconductor device and the manufacturing method thereof according to the first embodiment are denoted by the same reference numerals, and description thereof is omitted or simplified.
First, the structure of the semiconductor device according to the present embodiment will be explained with reference to FIG. FIG. 52A is a plan view showing the structure of the semiconductor device according to the present embodiment, and FIG. 52B is a cross-sectional view taken along the lines AA ′ and BB ′ of FIG.
The basic configuration of the semiconductor device according to the present embodiment is substantially the same as that of the semiconductor device according to the first embodiment. The semiconductor device according to the present embodiment has a silicon layer 134 epitaxially grown on the surface of the silicon substrate 14 in the peripheral circuit region 12, and the silicon substrate 14 in the flash memory cell region 10 is equal to the thickness of the silicon layer 134. The main feature is that the surface of the silicon layer 134 is lower than the surface of the silicon layer 134 in the peripheral circuit region 12. In other words, the main feature is that the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12 by the thickness of the silicon layer 134.
As shown in FIG. 52B, an epitaxially grown silicon layer 134 is formed on the surface of the silicon substrate 14 in the peripheral circuit region 12. Due to this silicon layer 134, a step is formed between the flash memory cell region 10 and the peripheral circuit region 12 on the surface of the silicon substrate 14. That is, the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon layer 134 in the peripheral circuit region 12 by the thickness of the silicon layer 134. In other words, the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12 by the thickness of the silicon layer 134. The height of the surface of the silicon layer 134 in the peripheral circuit region 12 is substantially equal to the height of the upper surface of the doped amorphous silicon film 34 formed in the flash memory cell region 10.
In the flash memory cell region 10, as in the semiconductor device according to the first embodiment, the flash memory cell 46 is formed on the silicon substrate 14 on which the element isolation region 20a formed in the groove 18 is formed.
In the peripheral circuit region 12, the NMOS transistor 62 and the PMOS transistor 66 are formed on the silicon substrate 14 on which the silicon layer 134 is formed, as in the semiconductor device according to the first embodiment.
Like the semiconductor device according to the present embodiment, the silicon layer 134 epitaxially grown on the surface of the silicon substrate 14 in the peripheral circuit region 12 causes the surface of the silicon substrate 14 in the flash memory cell region 10 to be the surface of the silicon substrate 14 in the peripheral circuit region 12. A step may be formed on the surface of the silicon substrate 14 so as to be lower.
First, a silicon oxide film 136 of, eg, a 80 nm-thickness is deposited on the silicon substrate 14 on which the n-type deep well 26 and the p-type well 28 are formed by, eg, CVD (see FIG. 53A).
Next, a photoresist film 138 that exposes the peripheral circuit region 12 and covers the flash memory cell region 10 is formed by photolithography (see FIG. 53B).
Next, the silicon oxide film 136 is etched by wet etching, for example, using the photoresist film 138 as a mask, and the silicon oxide film 136 in the peripheral circuit region 12 is removed.
Next, the photoresist film 138 is removed by, for example, ashing (see FIG. 54A).
Next, a predetermined surface treatment is performed on the silicon substrate 14 to clean the surface of the silicon substrate 14.
Next, a silicon layer 134 of, eg, a 70 nm-thickness is selectively epitaxially grown on the surface of the silicon substrate 14 in the peripheral circuit region 12 by, eg, CVD, using the silicon oxide film 136 as a mask (see FIG. 54B).
Next, the silicon oxide film 136 is etched by wet etching, for example, and the silicon oxide film 136 in the flash memory cell region 10 is removed (see FIG. 55A).
Next, a silicon oxide film 30 of, eg, a 10 nm-thickness is grown on the silicon substrate 14 on which the silicon layer 134 is epitaxially grown on the surface in the peripheral circuit region 12 by, eg, thermal oxidation (see FIG. 55B). This silicon oxide film 30 is used as a tunnel oxide film of the flash memory cell 46.
Next, a doped amorphous silicon film 34 of, eg, a 70 nm-thickness is deposited on the silicon oxide film 30 by, eg, CVD (see FIG. 56A). The doped amorphous silicon film 34 is used as a main part of the floating gate 32 of the flash memory cell 46.
Next, a photoresist film 96 that covers the flash memory cell region 10 and exposes the peripheral circuit region 12 is formed on the doped amorphous silicon film 34 by photolithography.
Next, using the photoresist film 96 as a mask, the doped amorphous silicon film 34 is etched by dry etching, for example, and the doped amorphous silicon film 34 other than the flash memory cell region 10 is removed (see FIG. 56B).
Next, for example, thermal oxidation corresponding to 10 nm is performed, and a silicon oxide film 98 is grown as a sacrificial oxide film on the silicon layer 134 and the doped amorphous silicon film 34.
Next, a silicon nitride film 100 of, eg, a 100 nm-thickness is deposited on the silicon oxide film 98 by, eg, CVD (see FIG. 57A).
Next, a photoresist film 104 having openings 102a, 102b, and 102c exposing the regions where the trenches 18, 22, and 24 for element isolation are to be formed is formed on the silicon nitride film 100 by photolithography (FIG. 57). (See (b)). Since the height of the upper surface of the silicon substrate 14 on which the silicon layer 134 is formed in the peripheral circuit region 12 and the height of the upper surface of the doped amorphous silicon film 34 in the flash memory cell 10 are set to be substantially equal, When exposing the resist film 104, it is possible to perform exposure with extremely high accuracy. As a result, the silicon substrate 14 in the peripheral circuit region 12 and the doped amorphous silicon film 34 constituting the floating gate 32 can be patterned with high accuracy. As a result, a semiconductor device having fine memory cells is provided. Is possible.
Next, using the photoresist film 104 as a mask, the silicon nitride film 100 is etched by dry etching, for example, and the openings 106a exposing the regions where the trenches 18, 22, and 24 for element isolation are to be formed are exposed in the silicon nitride film 100. 106b and 106c are formed (see FIG. 58A).
Next, using the photoresist film 104 and the silicon nitride film 100 as a mask, the silicon oxide film 98, the doped amorphous silicon film 34, the silicon oxide film 30, and the silicon substrate 14 exposed in the openings 106a and 106b, for example, by dry etching. Are etched, and the silicon oxide film 98 exposed in the opening 106c and the silicon substrate 14 on which the silicon layer 134 is epitaxially grown are respectively etched (see FIGS. 58B, 59A, and 59B). . Thus, trenches 18 and 22 for element isolation are formed in the flash memory cell region 10, and a trench 24 for element isolation is formed in the peripheral circuit region 12 (see FIG. 59B). At this time, the etching condition is such that the selection ratio of the silicon layer (the doped amorphous silicon film 34, the silicon substrate 14, and the silicon layer 134) to the silicon oxide film is 10, for example.
Here, after the silicon oxide film 98 is removed by etching, only the silicon layer (the silicon substrate 14 on which the silicon layer 134 is epitaxially grown) is etched in the opening 106c exposing the region where the trench 24 is to be formed. On the other hand, the silicon oxide film 30 exists under the doped amorphous silicon film 34 in the openings 106a and 106b exposing the regions where the grooves 18 and 22 are to be formed. Due to the silicon oxide film 30 having etching characteristics different from those of the silicon layer, the progress of etching in the openings 106a and 106b is slower than the progress of etching in the opening 106c. As a result, the grooves 18 and 22 are formed shallower than the groove 24.
Specifically, first, the doped amorphous silicon film 34 is etched in the openings 106a and 106b, whereas in the opening 106c, the film thickness is equal to the thickness of the etched doped amorphous silicon film 34. The silicon layer 134 on the surface of the silicon substrate 14 is etched by an amount corresponding to this depth, and a groove 24 is formed in the silicon layer 134 (see FIG. 58B). For example, the doped amorphous silicon film 34 having a film thickness of 60 nm is etched in the openings 106a and 106b, whereas the silicon layer 134 is etched by a depth of 60 nm in the opening 106c. A groove 24 having a depth of 60 nm is formed in 134.
FIG. 58B shows a state in which etching has progressed until the silicon oxide film 30 is exposed in the opening 106a.
Thereafter, when the etching is further advanced, the silicon oxide film 30 is etched at a relatively low rate in the openings 106a and 106b, whereas in the opening 106c, the silicon substrate on which the silicon layer 134 is epitaxially grown is etched. 14 is etched at a relatively fast rate (see FIG. 59 (a)). For example, when an etching condition in which the selection ratio of the silicon layer to the silicon oxide film is 10 is used, the silicon oxide film 30 having a film thickness of 10 nm is etched in the openings 106a and 106b, whereas in the opening 106c. In FIG. 5, the silicon substrate 14 on which the silicon layer 134 is epitaxially grown is further etched by the depth of 100 nm, and the depth of the groove 24 is 160 nm in total.
FIG. 59A shows a state where etching has progressed until the silicon substrate 14 is exposed in the opening 106a.
Thereafter, when the etching further proceeds, the etching further proceeds at substantially the same speed in the openings 106a and 106b and in the opening 106c (see FIG. 59B). For example, the silicon substrate 14 is etched by a depth of 140 nm in the openings 106a and 106b, whereas the silicon layer 134 is epitaxially grown by a depth of 140 nm in the opening 106c. The substrate 14 is further etched, and the depth of the groove 24 is 300 nm in total. Thus, the groove 18 having a depth of 140 nm is formed in the silicon substrate 14 in the openings 106a and 106b, whereas the depth deeper than the groove 18 is formed in the silicon substrate 14 in which the silicon layer 134 is epitaxially grown in the opening 106c. A groove 24 having a thickness of 300 nm is formed.
While the trenches 18, 22, and 24 for element isolation are formed as described above, in the flash memory cell region 10, the doped amorphous silicon film 34 and the silicon oxide film 30 constituting the floating gate 32 are patterned. . That is, in the semiconductor device manufacturing method according to the present embodiment, the groove is formed in a self-aligned manner when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned, as in the semiconductor device manufacturing method according to the first embodiment. 18 is formed. As described above, since the groove 18 is also formed when the doped amorphous silicon film 34 constituting the floating gate 32 is patterned, the groove 18 can be formed without requiring superposition of highly accurate patterns. Therefore, according to the present embodiment, it is possible to easily cope with the miniaturization of the memory cell.
Next, the photoresist film 104 is removed by, for example, ashing.
The subsequent steps are the same as those of the semiconductor device manufacturing method according to the first embodiment shown in FIGS.
For example, in the above embodiment, the surface layer portion of the silicon substrate 14 is removed by etching the silicon substrate 14 by chemical dry etching or removing the silicon oxide film 132 formed by oxidizing the surface layer portion of the silicon substrate 14. However, the method of removing the surface layer portion of the silicon substrate 14 for forming a step on the surface is not limited to these. For example, the silicon substrate 14 may be etched by wet etching to form a step on the surface of the silicon substrate 14.
In the above embodiment, the case where the step is formed on the silicon substrate 14 so that the surface of the silicon substrate 14 in the flash memory cell region 10 is lower than the surface of the silicon substrate 14 in the peripheral circuit region 12 has been described as an example. Depending on the size of the device pattern, the process margin, etc., such a step may not be formed on the surface of the silicon substrate 14.
Further, in the above embodiment, the case where the floating gate 32 is configured by the main portion 34 and the side wall portion 36 has been described as an example. However, the floating gate 32 is configured only by the main portion 34 without forming the side wall portion 36. May be.
A semiconductor substrate having a step formed on the surface so that the surface of the first region is lower than the surface of the second region;
A first element isolation region formed in a first groove formed in the semiconductor substrate in the first region;
A second element isolation region formed on the semiconductor substrate in the second region and formed in a second groove deeper than the first groove;
A floating gate formed on the first element region defined by the first element isolation region via a first insulating film, and a control formed on the floating gate via a second insulating film A memory cell having a gate;
And a transistor formed on the second element region defined by the second element isolation region.
The surface layer part of the said semiconductor substrate in the said 1st area | region is removed. The semiconductor device characterized by the above-mentioned.
A step is formed on the surface of the semiconductor substrate by the semiconductor layer formed in the second region.
A height of the upper surface of the floating gate is substantially equal to a height of the upper surface of the semiconductor substrate in the second region.
The floating gate has a main part formed on the semiconductor substrate through the first insulating film, and a side wall part formed on a side wall part of the main part.
Forming a first conductive film serving as a floating gate on a semiconductor substrate in a first region via a first insulating film having etching characteristics different from those of the semiconductor substrate;
A first opening is formed in the first region and a second opening is formed in the second region on the first conductive film and on the semiconductor substrate in the second region. Forming a mask,
Etching the first conductive film, the first insulating film, and the semiconductor substrate exposed in the first opening, and etching the semiconductor substrate exposed in the second opening, Forming a first groove in the semiconductor substrate in the first region, and forming a second groove deeper than the first groove in the semiconductor substrate in the second region;
A first element isolation region that defines a first element region is formed in the first groove, and a second element isolation region that defines a second element region is formed in the second groove. Process,
Forming a control gate on the floating gate through a second insulating film, and forming a gate electrode of a transistor on the second element region.
In the method for manufacturing a semiconductor device according to attachment 6,
Before the step of forming the first conductive film, the method further includes the step of forming a step on the surface of the semiconductor substrate such that the surface in the first region is lower than the surface in the second region. A method of manufacturing a semiconductor device.
In the method for manufacturing a semiconductor device according to attachment 7,
In the step of forming a step on the surface of the semiconductor substrate, the step is formed on the surface of the semiconductor substrate by selectively etching a surface layer portion of the semiconductor substrate in the first region. Device manufacturing method.
In the step of forming a step on the surface of the semiconductor substrate, a surface layer portion of the semiconductor substrate in the first region is selectively oxidized to form an oxide film, and the oxide film is removed to remove the oxide film. A method of manufacturing a semiconductor device, comprising forming a step on a surface.
In the step of forming a step on the surface of the semiconductor substrate, a step is formed on the surface of the semiconductor substrate by selectively growing a semiconductor layer on the surface of the semiconductor substrate in the second region. A method for manufacturing a semiconductor device.
In the method for manufacturing a semiconductor device according to any one of appendices 7 to 10,
In the step of forming the first conductive film, the height of the upper surface of the semiconductor substrate in the second region is substantially equal to the height of the upper surface of the first conductive film in the first region. Forming the first conductive film. A method of manufacturing a semiconductor device, comprising: forming a first conductive film;
In the method for manufacturing a semiconductor device according to any one of appendices 6 to 11,
After the step of forming the first element isolation region and the second element isolation region, and before the step of forming the control gate, a side wall portion made of a second conductive film is formed on the side wall portion of the floating gate. A method for manufacturing a semiconductor device, further comprising the step of forming the semiconductor device.
In the method for manufacturing a semiconductor device according to attachment 12,
In the step of forming the side wall portion, the second conductive film is embedded between the plurality of adjacent floating gates, and the second conductive film is etched to form the second conductive film on the side wall portion of the floating gate. A method of manufacturing a semiconductor device, wherein a conductive film is selectively left.
1 is a schematic diagram showing a structure of a semiconductor device according to a first embodiment of the present invention. FIG. 6 is a process diagram (part 1) illustrating the method for fabricating the semiconductor device according to the first embodiment of the invention; FIG. 6 is a process diagram (part 2) illustrating the method for producing the semiconductor device according to the first embodiment of the invention; FIG. 6 is a process diagram (part 3) illustrating the method for producing the semiconductor device according to the first embodiment of the invention; FIG. 4D is a process diagram (part 4) illustrating the method for fabricating the semiconductor device according to the first embodiment of the present invention; It is process drawing (the 5) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 6) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 7) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 8) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 9) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 10) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 11) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 12) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 13) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 14) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 15) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 16) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 17) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 18) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 19) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 20) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. FIG. 29 is a process diagram (part 21) illustrating the method for manufacturing the semiconductor device according to the first embodiment of the present invention; FIG. 22 is a process diagram (part 22) illustrating the method for producing the semiconductor device according to the first embodiment of the invention; It is process drawing (the 23) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 24) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. FIG. 26 is a process diagram (part 25) illustrating the method for producing the semiconductor device according to the first embodiment of the invention; FIG. 26 is a process diagram (part 26) illustrating the method for manufacturing the semiconductor device according to the first embodiment of the present invention; It is process drawing (the 27) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. FIG. 28 is a process diagram (part 28) illustrating the method for producing the semiconductor device according to the first embodiment of the present invention; It is process drawing (the 29) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 30) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 31) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 32) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 33) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 34) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 35) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 36) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 37) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 38) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 39) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process drawing (the 40) which shows the manufacturing method of the semiconductor device by 1st Embodiment of this invention. It is process sectional drawing (the 1) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 2) explaining the inconvenience when a level | step difference is not formed in the surface of a silicon substrate. It is process sectional drawing (the 3) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 4) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 5) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 6) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 7) explaining the inconvenience when not forming a level | step difference in the surface of a silicon substrate. It is process sectional drawing (the 1) which shows the manufacturing method of the semiconductor device by the modification of 1st Embodiment of this invention. It is process sectional drawing (the 2) which shows the manufacturing method of the semiconductor device by the modification of 1st Embodiment of this invention. It is process sectional drawing (the 3) which shows the manufacturing method of the semiconductor device by the modification of 1st Embodiment of this invention. It is the schematic which shows the structure of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 1) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 2) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 3) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 4) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 5) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 6) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention. It is process sectional drawing (the 7) which shows the manufacturing method of the semiconductor device by 2nd Embodiment of this invention.
DESCRIPTION OF SYMBOLS 10 ... Flash memory cell area | region 12 ... Peripheral circuit area | region 12n ... NMOS transistor area | region 12p ... PMOS transistor area | region 14 ... Silicon substrate 16 ... Step part 18 ... Groove 20a, 20b, 20c ... Element isolation region 22 ... Groove 24 ... Groove 26 ... n Type deep well 28 ... p type well 30 ... tunnel oxide film 32 ... floating gate 34 ... main part 36 of floating gate ... side wall 38 of floating gate ... ONO film 40 ... control gate 42 ... source / drain region 42a ... LDD region 44 ... sidewall insulating film 46 ... flash memory cell 48 ... n-type deep well 50 ... p-type well 52 ... n-type well 54 ... gate insulating film 56 ... gate electrode 58 ... source / drain region 58a ... LDD region 60 ... sidewall insulation Membrane 62 ... NMOS transistor Transistor 64 ... Source / drain region 64a ... LDD region 66 ... PMOS transistor 68 ... Silicide film 70 ... Interlayer insulating films 72, 74 ... Contact holes 76, 78 ... Electrode plugs 80, 82, 84 ... Contact holes 86, 88, 90 ... Electrode plug 92 ... Silicon oxide film 94 ... Photoresist film 96 ... Photoresist film 98 ... Silicon oxide film 100 ... Silicon nitride films 102a, 102b, 102c ... Opening 104 ... Photoresist films 106a, 106b, 106c ... Opening 108 ... Photoresist film 110 ... Silicon oxide film 112 ... Silicon nitride film 114 ... Silicon oxide film 116 ... Photoresist film 118 ... Photoresist film 120 ... Photoresist film 122 ... Photoresist film 124 ... Photoresist film 126 ... Polysilicon film 128 Silicon nitride film 130 ... photoresist film 132 ... silicon oxide film 134 ... silicon layer 136 ... silicon oxide film 138 ... photoresist film
Forming a step on the surface of the semiconductor substrate such that the surface in the first region is lower than the surface in the second region;
And forming the the first region and the semiconductor substrate in the second region, the first insulating film having the different semiconductor substrate and the etching characteristics,
Forming a first conductive film to be a floating gate on the first insulating film in the first region ;
On the semiconductor substrate in the on the first conductive film and the second region, the first opening is formed in said first region, forming a second opening in the second region Forming a patterned mask;
In the manufacturing method of the semiconductor device of any one of Claims 1 thru / or 4 ,
JP2005222119A 2005-03-31 2005-07-29 Manufacturing method of semiconductor device Active JP4566086B2 (en)
JP2005222119A JP4566086B2 (en) 2005-03-31 2005-07-29 Manufacturing method of semiconductor device
TW94136493A TWI264122B (en) 2005-03-31 2005-10-19 Semiconductor device and method for fabricating the same
US11/253,739 US20060220097A1 (en) 2005-03-31 2005-10-20 Semiconductor device and method for fabricating the same
US12/318,580 US7816206B2 (en) 2005-03-31 2008-12-31 Semiconductor device and method for fabricating the same
JP2006310725A JP2006310725A (en) 2006-11-09
JP4566086B2 true JP4566086B2 (en) 2010-10-20
JP2005222119A Active JP4566086B2 (en) 2005-03-31 2005-07-29 Manufacturing method of semiconductor device
TW (1) TWI264122B (en)
TWI271824B (en) * 2005-06-15 2007-01-21 Powerchip Semiconductor Corp Method of fabricating non-volatile memory
JP2000323564A (en) * 1999-05-10 2000-11-24 Nec Corp Manufacture of semiconductor device
JP2002026152A (en) * 2000-07-07 2002-01-25 Mitsubishi Electric Corp Semiconductor device and its manufacturing method
JP2002158281A (en) * 2000-11-21 2002-05-31 Sharp Corp Semiconductor device and manufacturing method thereof
JP3075211B2 (en) 1996-07-30 2000-08-14 日本電気株式会社 Semiconductor device and manufacturing method thereof
JP4004721B2 (en) 2000-08-30 2007-11-07 株式会社東芝 Nonvolatile semiconductor memory device and manufacturing method thereof
2005-07-29 JP JP2005222119A patent/JP4566086B2/en active Active
2005-10-19 TW TW94136493A patent/TWI264122B/en active
2005-10-20 US US11/253,739 patent/US20060220097A1/en not_active Abandoned
2008-12-31 US US12/318,580 patent/US7816206B2/en active Active
US20060220097A1 (en) 2006-10-05
US20090176359A1 (en) 2009-07-09
JP2006310725A (en) 2006-11-09
US7816206B2 (en) 2010-10-19
TW200635049A (en) 2006-10-01
TWI264122B (en) 2006-10-11
US8034684B2 (en) 2011-10-11 Semiconductor device with improved overlay margin and method of manufacturing the same
KR100589477B1 (en) 2006-06-14 Semiconductor device group and method for fabricating the same, and semiconductor device and method for fabricating the same
KR100481856B1 (en) 2005-04-11 Semiconductor Device Having electrically erasable programmable read-only memory(EEPROM) And Mask-ROM And Method Of Fabricating The Same
Ref document number: 4566086