Source: https://patents.google.com/patent/CN103262342B/en
Timestamp: 2019-12-14 16:38:02
Document Index: 686306574

Matched Legal Cases: ['art 444', 'art 454', 'art 924', 'arts 922', 'arts 942', 'art 944', 'arts 964', 'art 962', 'art 1014', 'art 1012']

CN103262342B - Transparency micro-patterning RFID antenna and the goods of assembling transparency micro-patterning RFID antenna - Google Patents
Transparency micro-patterning RFID antenna and the goods of assembling transparency micro-patterning RFID antenna Download PDF
CN103262342B
CN103262342B CN201180060557.9A CN201180060557A CN103262342B CN 103262342 B CN103262342 B CN 103262342B CN 201180060557 A CN201180060557 A CN 201180060557A CN 103262342 B CN103262342 B CN 103262342B
CN201180060557.9A
CN103262342A (en
M·H·弗雷
祖丽君
W·C·埃格伯特
S·R·巴纳吉
R·A·塞纳提
2010-12-16 Priority to US42376910P priority Critical
2010-12-16 Priority to US61/423,769 priority
2011-11-17 Application filed by 3M创新有限公司 filed Critical 3M创新有限公司
2011-11-17 Priority to PCT/US2011/061188 priority patent/WO2012082300A1/en
2013-08-21 Publication of CN103262342A publication Critical patent/CN103262342A/en
2016-08-10 Publication of CN103262342B publication Critical patent/CN103262342B/en
The present invention relates to the antenna be applicable to RFID device, described antenna includes dielectric base and arranges the first micro-pattern of electric conductivity on the substrate or in described substrate, and the described first micro-pattern of electric conductivity limits adjacent apertured conductor.The described first micro-pattern of electric conductivity forms the antenna of frequency at least responding 915MHz, and includes having and be positioned at 0.5 micron of interconnection traces to the track width of 20 micrometer ranges.Additionally, the described first micro-pattern of electric conductivity is characterised by the aperture area ratio of at least 80% or 90%.RFID device includes this type of antenna and is configured to utilize described antenna to launch and receive the integrated circuit of signal.The card of such as financial transaction card or tag card etc includes this type of antenna carried by card layer.
Transparency micro-patterning RFID antenna and assembling transparency micro-patterning RFID antenna Goods
Present invention relates generally to RF identification (RFID) device, for application-specific, relate in such device Antenna.The invention still further relates to goods, the system and method being correlated with.
RF identification (RFID) technology has been widely used in multiple industry, including traffic, ship, manufacture, waste management, Postal tracking, aviation luggage identification and highway toll management.RFID label tag and label can be used for follow the tracks of from supplier to client also And even with the shipment of client's supply chain.
Typical rfid system include multiple RFID label tag or label, at least one have for RFID label tag or label The RFID reader of antenna of communication or detecting system and control the calculating device of RFID reader.RFID label tag can include Or may not include adhesive phase.RFID tag usually has the RFID of the adhesive phase for RFID label tag is attached to article Label.RFID reader includes to provide energy or the emitter of information to label or label and receiving from label or label Identification information and the receptor of out of Memory.Calculating device can be read and/or write and process and be obtained by RFID reader Information.
In general, be specifically from the information of RFID tag for concrete application, but often provide right The identification of labeled article.Exemplary article includes manufacture, pig, books, file, animal or substantially any Other shaped article.The extra information of goods can also be provided.Label or label can be for such as referring to during preparation processes Show color of paint or other useful information of automobile chassis in manufacture process.
The emitter of RFID reader is by its antenna output RF signal to produce electromagnetic field, and described electromagnetic field can make mark Label or label return the RF signal of information of carrying.Emitter uses amplifier to drive its sky with the output signal by modulation Line.
Conventional RFID tags or label can be " active " label or the label including internal electric source, or for be read by RFID " passive " label of field excitation produced by device antenna or label.Once after excitation, label and label just use predetermined scheme to enter Row communication, thus allows RFID reader to receive from one or more labels or the information of label.Calculate device by receiving From the information of RFID reader and perform certain action the most more new database and be used as information management system.Additionally, meter Calculate device to can be used as, by emitter, data are programmed into the mechanism in label or label.
Known there is multiple preparation RFID label tag and the method for circuit, including following these: United States Patent (USP) 6,805,940 (Koskenmaki et al.)；United States Patent (USP) 6,816,125 (Kuhns et al.)；United States Patent (USP) 6,399,258 (O ' Brien et al.)； Patent application publication US 2003/0151028 (Lawrence et al.)；Patent application publication US 2004/0175515 (Lawrence et al.)；Patent application publication US 2002/0018880 (Young)；PCT Publication WO 03/038748 (Leerkamp et al.)；With PCT Publication WO 00/42678 (Vega et al.).
Electric conductor in micro-patterning conductive material form is known.These construct in, can by metal level or other Suitably conductive material layer is arranged in electrical insulating substrate.Metal level is micropatterning to be formed the two dimension of electric conductivity linear character Grid.Exemplary micro-patterning conductor is described in one or more in following patent documentation: PCT Publication WO 2009/108765 (Frey et al.), WO 2009/108771 (Zu et al.), WO 2009/154812 (Frey et al.) and WO 2010/099132 (Moran et al.).
Although can by utilization have the pattern of relatively big " aperture area ratio " this type of patterned conductor is made have low Visibility or high transparent, but this type of conductor is unknown for the fitness of some application-specific.Specifically, this type of conductor Fitness for the antenna in applying as RFID is the unknown and uncertain.We have studied some high transparents Micro-patterning conductor, is especially concerned with having for example, at least 90% or at least 95% or be positioned in the range of 95-98% The micro-patterning conductor of aperture area ratio, and its fitness being used as the antenna during some RFID applies is assessed. This is completed by following manner: prepares and uses multiple high transparent micro-patterning conductor to fill as the multiple RFID of antenna Put, and utilize RFID reader to test gained device.
The result of these researchs shows, this type of high transparent micro-patterning conductor (the otherwise referred to as micro-pattern of electric conductivity) can It is prepared to can be used in some RFID device, but is not useable in other RFID device.RFID device can have different size, Shape and design, this depend on (inter alia) they be designed to the electromagnetic frequency that is operated.Some RFID device It is designed in the low frequency (LF) being positioned at electromagnetic spectrum partly (that is, the electromagnetic spectrum part in the range of 30KHz to 300KHz) In operation at frequencies.Other RFID device is designed at the high frequency (HF) being positioned at electromagnetic spectrum that partly (that is, 3MHz is extremely Electromagnetic spectrum part in the range of 30MHz) in operation at frequencies.Other RFID device is designed to be positioned at electromagnetic spectrum Ultra-high frequency (UHF) partly (that is, the electromagnetic spectrum part in the range of 300MHz to 3GHz) in operation at frequencies.In U.S. State, the 902-928MHz in 13.56MHz and the UHF region that the characteristic frequency being preserved for RFID device includes in HF region.Generation Other countries and regions in boundary retain other characteristic frequency and apply for RFID.902-928MHz frequency position for the U.S. In applying in the range of in the wider UHF frequency band of 868MHz to 956MHz for RFID.Other country's employing is used for this of RFID Different frequency in wider UHF frequency band.Such as, some European countries retain 868MHz for RFID application.In Japan, retain 956MHz applies for RFID.
Have been found that display has the high transparent micro-patterning gold of the aperture area ratio of at least 90% or at least 95% Belong to conductor and can be prepared to be applicable to the RFID antenna worked the UHF part of electromagnetic spectrum, as, it is adaptable under 915MHz Or the RFID antenna worked in the range of 860MHz to 960MHz.
Therefore present patent application in particular discloses the antenna being applicable to RFID device.Described antenna can include dielectric base with And be arranged in substrate or the intrabasement first micro-pattern of electric conductivity, the described first micro-pattern of electric conductivity limits adjacent grid and leads Body.The first micro-pattern of electric conductivity can form the antenna at least responding 915MHz frequency, and it is micro-to 20 to include having 0.5 micron The interconnection traces of the track width in the range of meter.Additionally, the feature of the first micro-pattern of electric conductivity may be in having at least 80% or At least 90% aperture area ratio.
In some cases, aperture area ratio can be at least 95% or be positioned in the range of 95 to 98%.In some feelings Under condition, the first micro-pattern of electric conductivity can be made up of the opaque material comprising metal.In some cases, metal selected from silver, gold, Palladium, platinum, aluminum, copper, nickel, stannum, alloy and combinations thereof.In some cases, the first micro-pattern of electric conductivity can have and is less than 2 microns or less than 1 micron or thickness in 30 nanometers to 1 micrometer range.In some cases, track width can be located at 1 To 10 microns or 1 to 5 micron or 1.5 to 4 microns.In some cases, track width be smaller than 5 microns, little In 2 microns or less than 1 micron.In some cases, the feature of the first micro-pattern of electric conductivity may be in having 0.1 to 200 Europe Effective thin layer resistance in nurse/square range or in the range of 1 to 50 ohm-sq.In some cases, dielectric base can be Transparent.In some cases, antenna can have the visible transmission value more than 50%, more than 70% or more than 90%.
We also disclosed following RFID device, described RFID device includes any of above sky being combined with integrated circuit Line, described integrated circuit is configured to use antenna launch and receive signal.In some cases, antenna can be customized to carry Communication can be carried out with this device for RFID reader (being operated under 1 watts radiative power with 902-928MHz frequency-hopping mode) Ultimate range.Ultimate range can such as be positioned at 1 centimetre to 2 meters or 1.5 centimetres to 1 meter or 2 to 50 centimetres or 2.5 to 30 lis In the range of meter.
We also disclosed following rfid system, described rfid system includes having the above-mentioned sky combined with integrated circuit The device of line and be operated in 0.2 watt with the frequency between 860MHz and 960MHz and read to the RFID under 5 watts radiative power Going out device, wherein antenna is customized to so that RFID reader can be positioned at 1 centimetre to 2 with the ultimate range of described device communication Rice or 1.5 centimetres to 1 meter or 2 centimetres to 50 centimetres or 2.5 centimetres to 30 centimetres in the range of.In some cases, maximum Distance is less than 30 centimetres, less than 10 centimetres or less than 5 centimetres.
The invention also discloses following card, described card includes card layer, card the layer antenna carried and is configured to use Antenna is launched and receives the integrated circuit of signal.Antenna can include the micro-pattern of electric conductivity limiting adjacent apertured conductor, described The micro-pattern of electric conductivity forms the antenna at least responding 915MHz frequency.The micro-pattern of electric conductivity may also include to have and is positioned at 0.5 to 20 The interconnection traces of the track width in micrometer range, and the feature of the micro-pattern of electric conductivity may be in having at least 80% or at least The aperture area ratio of 90%.In some cases, card layer can be printing opacity for visible wavelength.In certain situation Under, aperture area ratio can be located in the range of 95% to 98%.In some cases, the first micro-pattern of electric conductivity can be by including The opaque material of following metal is constituted, described metal selected from silver, gold, palladium, platinum, aluminum, copper, nickel, stannum, alloy and they Combination.In some cases, the first micro-pattern of electric conductivity can have less than 2 microns or is less than 1 micron or is positioned at 30 nanometers to 1 Thickness in micrometer range.In some cases, track width can be located at 0.5 to 20 micron or 1 to 10 micron or 1 to 5 micro- Rice or 1.5 to 4 microns in the range of.In some cases, track width is smaller than 5 microns, less than 2 microns or less than 1 micro- Rice.
The present invention also discusses correlation technique, system and goods.
These and other aspects of present patent application will be apparent to from detailed description below.But, any In the case of should be not to be the restriction to claimed theme by foregoing invention content understanding, this theme only by appended right want Ask book to limit, and can modify in course of the review.
Fig. 1 is the schematic isometric views of the rfid system including RFID device and RFID reader；
Fig. 2 is the schematic diagram of the part illustrating electromagnetic spectrum, and described part includes the high frequency (HF) of wave spectrum, very high frequency(VHF) And hyperfrequency (UHF) part (VHF).
Fig. 3 is the front schematic view of slot antenna or the top view carrying out at uhf frequencies testing；
Fig. 4 a, 4b and 4c are the front schematic view of different RFID antenna, the top view being designed under HF frequency use Figure or plane graph；
Fig. 4 d and 4e be designed to use at uhf frequencies the front schematic view of different RFID antenna, top view, Or plane graph；
Fig. 5 is the schematic isometric views of the high transparent conductive region of the goods of such as antenna etc；
Fig. 6 a is front schematic view or the top view of the high transparent conductive region with the square or micro-pattern of rectangle；
Fig. 6 b is to have the micro-pattern of identical nominal with Fig. 6 a, but uses the high transparent nonconductive regions of " discontinuity cell " The front schematic view in territory or top view；
Fig. 7 a is front schematic view or the top view of the high transparent conductive region with the micro-pattern of hexagon；
Fig. 7 b is to have the micro-pattern of identical nominal with Fig. 7 a, but uses the high transparent nonconductive regions of " discontinuity cell " The front schematic view in territory or top view；
Fig. 7 c be the goods with high transparent conductive region and high transparent non-conducting areas front schematic view or Top view, these regions are respectively provided with the micro-pattern of identical nominal；
Fig. 8 is the microphotograph of the high transparent conductive region with the micro-pattern of pseudorandom grid；
Fig. 9 is front schematic view or the top view of the conductive region combining detectable image；
Fig. 9 a, 9b and 9c are schematically amplification front view or top view, these different accompanying drawings in the region 914 in Fig. 9 Show that some are for the different technologies forming detectable image；With
Figure 10 is card or the schematic exploded isometric view of similar articles that assembling has the RFID device of UHF antenna.
In the drawings, similar reference number refers to like.
This document describes that (inter alia) has been found that the high transparent conduction of the antenna that can be used as some RFID device Structure and assemble the goods of this type of antenna, such as tag card and transactional cards.Therefore, card or other goods can assemble in RFID The high transparent micro-patterning conductor of antenna form, described RFID antenna has the visibility of reduction and enough electromagnetic propertys Combine to receive or launch the information of radiofrequency signal form.Suitably conductor includes metal, polymer, metal-oxide and answers Compound, as further discussed below.Especially preferred conductor is metal.Exemplary micro-patterning conductor is characterised by some Character or characteristic, the aperture area ratio of the most micro-pattern, the thickness of conductive trace and the transverse width of conductive trace.Micro-figure The aperture area ratio preferably more than 80,90 or 95% of case or be positioned in the range of 95 to 98%.The thickness of conductive trace It is preferably located in 20 nanometers in the range of 10 microns or less than 2 microns or less than 1 micron or be positioned at 30 nanometers to 1 micron In the range of.The transverse width of conductive trace be preferably located in 0.1 to 20 micron or 0.5 to 20 micron or 0.5 to 10 micron, Or in the range of 1 to 5 micron or 1.5 to 4 microns or less than 20,10,6,5,4,3,2 or 1 microns.
In FIG, exemplary rfid system 110 includes RFID reader 112 and RFID device 114, and described RFID fills Putting 114 can be maybe to include active or passive RFID tags or label.The electromagnetic signal of characteristic frequency launched by reader 112 122b, described characteristic frequency is customized to be received by RFID device 114.Reader 112 also receives and detects by 114, device Electromagnetic signal 122a penetrated, wherein signal 122a is generally and signal 122b has same or similar frequency.Signal 122a can enter Row modulation to include about device 114 or the information of following goods, described goods on it attachment arrangement 114 or its be embedded in this dress Put.
RFID device 114 includes electrical insulating substrate 116 and is formed at the antenna 118 in substrate or in substrate.Antenna 118 It is characterised by that high transparent conductive region, described high transparent conductive region are appropriately shaped for receiving and launching appropriate frequency The electromagnetic radiation of rate.Conductive region is different from non-conducting areas 116a, 116b of substrate 116.High transparent conductive region micro- Patterning person's character is discussed further below.
Substrate 116 can include any suitable electrolyte or other non-conducting material.Substrate 116 can be substantially by monolayer material Material forms, or it can include extra play and have more complicated structure.Substrate 116 can be as needed for rigidity or flexible 's.Although it addition, substrate 116 is basic printing opacity in the exemplary embodiment, as transparent or translucent, but in other feelings Under condition, substrate can only have low light transmission level, or it can be the most opaque.The example of suitable substrates includes polymerization Thing film, such as polyethylene terephthalate (PET) or PEN (PEN).Other suitable substrate bag Include multi-layer optical film and related film, reflector, polariser, light filter and goods, e.g., as disclosed in United States Patent (USP) 5,882, 774 (Jonza et al.) or 7, any one in those substrates in 271,951 (Weber et al.), above-mentioned two patent all with Way of reference is expressly incorporated herein.Wherein RFID device 114 be transparent or printing opacity transactional cards or tag card (wherein in card structure also Including infrared barrier film or light filter) part in the case of, antenna can be set directly on infrared barrier film.A reality Executing in example, infrared barrier film can be the multi-layer optical film that maybe can include being made up of alternating polymer layers, described alternating polymer layers Refractive index and thickness be customized to for vertical incidence visible ray provide high-transmission rate (as 400 nanometers to 700 nanometers Light have at least 70% average transmittance), but substantially intercept near infrared light (as its for 800 nanometers to 1000 nanometers Vertical incidence light have no more than 8% or the average transmittance of no more than 5%).Can be come by method as known in the art It is laminated together goods needed for forming card or forming other with other material by having the substrate 116 being suitable for antenna 118.
The geometry of antenna 118 and characteristic depend on the required operating frequency of RFID device 114.Such as, at 902- The RFID device worked under 928MHz or 2.45GHz will generally include dipole antenna (such as linear dipole antennas or folding Dipole antenna or single turn loop aerial).By contrast, the RFID device worked under 13.56MHz (or similar frequency) will be logical Frequently with spiral type or multiturn coil antenna.But, these general introductions should not be construed as restrictive, and other Antenna Design pair It is known for those skilled in the art.Under any circumstance, antenna 118 intercepts by query source or reader 112 spoke Radio-frequency (RF) energy 122b penetrated.Power and order (or out of Memory) can be sent to device 114 by this signal energy.Antenna 118 can Allow RFID device to absorb enough energy with to integrated circuit 120 energy supply, and the response detected thus is provided.Therefore, sky Characteristic Ying Yuqi of line is inserted system therein and is matched.For the RFID device at the conspicuous operated within range of high MHz to GHz Speech, important characteristic is antenna length.Generally, the effective length of dipole antenna is selected as being close to inquire about the half of signal Wavelength or many times of half-wavelengths.For for the RFID device that works low to middle MHz region (such as, 13.56MHz), due to half Wavelength antennas is unpractical because of size limitation, then some important characteristics are the coil turn of antenna induction coefficient and antenna Number.For both antenna types, it is required to good electrical conductivity.Additionally, in order to obtain between antenna and integrated circuit Obtaining ceiling capacity transmission, the input impedance of integrated circuit should mate the impedance of antenna.Additional information about antenna is this area Those of ordinary skill known to, such as, from list of references such as K.Finkenzeller, " RFID Handbook.Radio- Frequency Identification Fundamentals and Applications, " (1999 John Wiley & Sons Ltd, Chichester, West Sussex, England) know.
Have been found that can the conductor micropattern of designing antenna to realize following efficiency, described efficiency can be customized wittingly For the efficiency less than similar metal opaque, thick (e.g., 18 microns of thick copper) antenna.Specific, the antenna efficiency of reduced levels Can be used for such as customizing antenna will be provided for making RFID device with the given query source that parameter work is set or reader it Between carry out the distance of communication.Such as, according to our discovery, including the transparent or hidden sky of the conductor micropattern in grid configuration Line design can be customized to produce ultimate range so that reader still is able to and RFID device successfully communication.Such as, this is Big distance can be located between 1 centimetre and 2 meters between 1.5 centimetres and 1 meter or between 2 and 50 centimetres or 2.5 and 30 centimetres it Between.Alternatively, this ultimate range is smaller than 30 centimetres, less than 10 centimetres or less than 5 centimetres.Can be at UHF The RFID device worked in region is to realize these maximum communication distance scopes.The ultimate range with restriction scope is kept to have Reduce sharply thief or hacker read or inquiry comprises sensitive information RFID device (e.g., RFID device be financial transaction card or A part for tag card) probability.From reader launch energy and the energy received by RFID device between relation by Friis formula gives, and this is discussed further below.Maximum communication can be realized for specific required RFID working range Distance range, such as, for the RFID query source operated for the U.S. or reader: 902-928MHz, frequency-hopping mode and 1 watt Special ERP.
Integrated circuit (IC) 120 is connected to antenna 118 so that IC can be with RFID reader 112 communication.IC120 can provide The main identification function of RFID device 114.Therefore, IC can include software and circuit, with permanently stored tag identification information With other information needed, explain and process the order from inquiry hardware acceptance, response requestor is to the request of information and assists The conflict that hardware solves to respond inquiry due to multiple labels simultaneously and causes.IC optionally can more be newly stored in its memorizer Interior information (reading/write), rather than only read information (read-only).The integrated circuit 120 being applicable to RFID device 114 includes From the Texas Instruments (e.g., their TAG-IT product line) of Dallas, Texas (Dallas, Texas), The NXP Semiconductors of Eindhoven, Holland (Eindhoven, Netherlands) (e.g., they I-CODE, MIFARE or HITAG product line) and the ST Microelectronics of Geneva, Switzerland (Geneva, Switzerland) Those etc..
Fig. 1 show with RFID reader 112 in be directed at form orientation RFID device 114.That is, it is perpendicular to substrate 116 and the axis of central point through antenna 118 also intersect with RFID reader 112.Fig. 1 also show D spaced apart Device 114 and reader 112.One quality factor of assessment or the performance of evaluating given RFID device be reader 112 still Can be with RFID device 114 success and ultimate range D of reliably communication.This ultimate range is referred to herein as Dmax.Greatly At distance D of Dmax, reader 112 can not be with RFID device 114 successfully communication.According to Friis formula, Dmax is appreciated that For following distance, outside described distance, received power P r is not enough to connect the silicon wafer in RFID device.
Fig. 2 describes the relevant portion of the electromagnetic spectrum represented by frequency f of electromagnetic radiation.Upper lineal scale shows 0 To more than the frequency in the range of 3GHz；Lower linear scale shows 0 to the frequency more than 300MHz on enlargement scale.Scale is total Show high frequency (HF) scope (it extends to 30MHz from 3MHz) altogether, (it extends to very high frequency(VHF) (VHF) scope from 30MHz 300MHz) and hyperfrequency (UHF) scope (it extends to 3GHz from 300MHz).Also show relevant with the rfid system of the U.S. The characteristic frequency of 13.56MHz, 915MHz and 2.45GHz.915MHz frequency is positioned at the 902-928MHz frequency band for the U.S. Center and be positioned at the wider UHF frequency band in the range of 868MHz to 956MHz mentioned above.
Before being more fully described high transparent micro-patterning conductor, forward some antennas processed and test to and set Meter.
In fig. 3 it is shown that slot antenna device 310.Device 310 includes the dielectric base 312 that nominal is square.Will conduction Layer is arranged in substrate 312 or in substrate, in order to cover unless all regions outside the 312a of conductive slot region, described conduction Layer is consequently formed slot antenna 314.In the exemplary embodiment, conductive layer includes high transparent micro-patterning conductor, its design Discussed further below.The size of device 310 can be properly selected with at given concern frequency ranges of operation.? In one example, the external boundary of substrate 312 or antenna 314 forms the square of about 15cm × 15cm, and gap area 312a There is the size of 5cm × 0.5cm.These sizes should not be construed as restrictive.
Coaxial cable 316 or other suitable cable can pass through contact in the center of gap area 312a or immediate vicinity Pad 318a, 318b are connected to the desired part of antenna 314.Engagement pad can for example, or include adhering to via electroconductive binder etc. The copper strips contact pin of conductive layer.Cable 316 includes that adapter 320 to be beneficially connected to test equipment, described test by antenna 314 Equipment can detect or measure the signal received by antenna 314 and can be sent to antenna 314 by driving signal so that it launches electricity Magnetic radiation.In alternative embodiment, cable 316 can be saved, and IC or other suitable RFID circuit can be installed In gap area 312a of the center or immediate vicinity that are positioned at antenna 314.
Preparation and test Antenna Design shown in Fig. 3.Design details and the test result of antenna are provided in examples below In part.
Fig. 4 a-e shows other Antenna Design.The antenna of Fig. 4 a-c has and is suitable at HF frequency (such as 13.65MHz) The winding escalator of lower use or helical design；The antenna of Fig. 4 d and 4e have be suitable under UHF frequency (such as 915MHz) use Dipole or folded dipole design.
In fig .4, antenna assembly 410 includes the substrate 412 with non-conducting areas 412a, 412b and is shaped to spiral shell Rotation shape is to provide the conductive region of antenna 414.Non-conducting areas 412a, 412b are in shape each other by spiral type nonconductive regions Territory (unmarked) connects together.At antenna 414 opposed ends, formation may optionally be entity and (carries out i.e., the most in a grid formation Micro-patterning) engagement pad 414a, 414b.If it is required, suitable IC can be installed to device 410, in order to pass through engagement pad 414a, 414b are connected to antenna 414.
In fig. 4b, antenna assembly 420 includes the substrate 422 with non-conducting areas 422a, 422b and is shaped to spiral shell Rotation shape is to provide the conductive region of antenna 424.Non-conducting areas 422a, 422b are in shape each other by spiral type nonconductive regions Territory (unmarked) connects together.In antenna 424 opposite two ends, formation may optionally be entity and (carries out i.e., the most in a grid formation Micro-patterning) engagement pad 424a, 424b.Extra engagement pad is arranged in substrate or in substrate, may optionally be to provide Complementary engagement pad 425a of entity (carrying out micro-patterning i.e., the most in a grid formation), 425b.If it is required, available wire jumper Deng engagement pad 424b being connected to engagement pad 425a, and suitable IC can be installed to device 420 will pass through engagement pad 424a, 425b are connected to antenna 424.
In Fig. 4 c, antenna assembly 430 includes the substrate 432 with non-conducting areas 432a, 432b and is shaped to spiral shell Rotation shape is to provide the conductive region of antenna 434.Non-conducting areas 432a, 432b are in shape each other by spiral type nonconductive regions Territory (unmarked) connects together.In antenna 434 opposite two ends, formation may optionally be entity and (carries out i.e., the most in a grid formation Micro-patterning) engagement pad 434a, 434b.Another conductive mesh region 435 is arranged in substrate or in substrate, to carry For complementary engagement pad 435a, 435b.If it is required, engagement pad 434a is connected to engagement pad 435a by available wire jumpers etc., and And suitable IC can be installed to device 430 will pass through engagement pad 434b, 435b be connected to antenna 434.
In figure 4d, antenna assembly 440 includes the substrate 442 with non-conducting areas 442a and is shaped to fold occasionally The most sub-shape is to provide the conductive region of antenna 444.Can will may optionally be entity (carrying out micro-patterning i.e., the most in a grid formation) Antenna part 444a, 444b be used as engagement pad.If it is required, suitable IC can be installed to device 440 will pass through contact Pad 444a, 444b are connected to antenna 444.
In figure 4e, antenna assembly 450 includes the substrate 452 with non-conducting areas 452a and is shaped to fold occasionally The most sub-shape is to provide the conductive region of antenna 454.Can will may optionally be entity (carrying out micro-patterning i.e., the most in a grid formation) Antenna part 454a, 454b be used as engagement pad.If it is required, suitable IC can be installed to device 450 will pass through contact Pad 454a, 454b are connected to antenna 454.
In the exemplary embodiment, conductive region disclosed in this invention is the low visibility by grid configuration or high saturating Bright property micro-patterning conductive material provides.In these construct, metal level or other suitable conductive material layer are arranged In electrical insulating substrate or in electrical insulating substrate.Metal level is carried out micro-patterning and includes that the two dimension of interconnection traces adjoins to be formed Grid.In this regard, " include the adjacent grid of interconnection traces " and refer to being formed and limit the network of open cells or grid Conductive trace patterns, wherein network or grid electrical connection are electrically connected (there is not interruption) between cells.Exemplary Grid or micro-pattern geometries are described in other places herein.In some cases, for the optical-quality homogeneous of holding means Spending and/or make antenna relatively be difficult to detect, grid or micro-pattern can extend in conductive region (wherein grid is adjacent) equably With on non-conducting areas, but provide the selectivity of lattice to be interrupted (produce " discontinuity cell ") in non-conducting areas so that These regions are nonconducting, as discussed further below.Selectivity is interrupted generation and is not electrically connected to each other, but fills When " empty " element or one group of metallic section of the floating element (its main purpose is to maintain optical uniformity) of electricity.In some cases, Can be from one, completely left out " empty " element some or all non-conducting areas.
Fig. 5 schematically shows representational micro-patterning conductive material.Herein, the part (example of goods 501 or goods Part such as antenna assembly) there is the high transparent conduction region provided by the micro-patterning conductor 540 being arranged in substrate 530 Territory.Conductor 540 usually carries out patterning, design or perhaps molding with limit tiny lattice conductive film (as Thin metal film).Can limit according to the uniformity of (1) width of conductive trace, (2) density and (3) density of constituting lattice Determine lattice.Definable replaces the contrary or complementary parameters of the referred to as aperture area ratio of density.On paid close attention to conductive region Aperture area ratio only 1 deduct the area ratio (as a percentage) occupied by conductive trace.(occupied by conductive trace Area ratio be alternatively referred to as dead area ratio).For calculating the purpose of this aperture area ratio, unless additionally referred to Bright, interest region should correspond to the current-carrying part of goods rather than include the part of only " empty " element.Additionally, the technology of this area Personnel will appreciate that, it is necessary to properly selects interest region relative to the ratio of micro-pattern, in order to obtains open area ratio Rate or the suitable measurement result of other characteristic or result of calculation.It is desirable that this result of calculation or measurement result should with will be for The result that the region of infinite field calculates is identical, and the region of described infinite field has a micro-pattern identical with interest region, but its In micro-pattern repeat to extend in other words conj.or perhaps on whole infinite region.
Lattice can be any required form, and e.g., rule is with that repeat or irregular and unduplicated.Just rule weight For multiple pattern, grid can have the elementary cell (minimum repeat patterns) in following geometric figure form, such as triangle, side Shape, rectangle, rhombus, trapezoidal, hexagon, heptagon etc..In other cases, grid can by have difformity (include with Machine or pseudorandom shape) unit composition, as shown in Fig. 8 the most hereafter.Random conductive pattern is available from by being separated The method generating random cells structure.
The goods 501 of Fig. 5 are shown as having that well-regulated repeatability is square or the micro-pattern of rhombus.Do not exist in substrate 530 and lead The space of body 540 constitutes aperture area 532.Conductor 540 has thickness 570, and carries out the mark patterning have in the x-direction Line width 552 and track width in the y-direction 562.Trace has spacing 550 in the x-direction and spacing 560 in the y-direction.? In the most isotropic or symmetrical embodiment, width 552,562 can be substantially the same, and spacing 550,560 It is alternatively substantially the same.Can be not in other isotropic or symmetrical embodiments, direction along not coplanar Track width can be different, and the trace spacing in direction is alternatively different along not coplanar.
Micro-patterning conductor can be formed by any appropriate method that can produce required geometry.These method bags Include photo-patterning method (such as photoetching process), (e.g., laser curing, laser ablation and laser irradiation add aobvious laser patterning process Shadow) and printing process (such as intaglio printing, flexographic printing and micro-contact printing).The forming method of micro-patterning conductor can be wrapped Include etching or plating step, such as electroless plating step that optional and any of the above described patterning step combines.For forming this The especially useful method of the micro-patterning conductor of bright disclosed RFID antenna relates to the combination of micro-contact printing and etching, as Described in United States Patent (USP) 5,512,131 (Kumar et al.) and PCT Publication WO 2009/154812 (Frey et al.).Micro-contact print The combination of brush and etching can be used for being formed the antenna pattern meeting condition shown herein as, then by suitable electronic device (example As, one or more integrated circuits) it is attached to high transparent antenna.
Suitably conductive material includes: metal, such as silver, gold, palladium, platinum, aluminum, copper, nickel, stannum, their alloy and it Combination；And complex, the polymer ink such as filled containing metallic.Especially preferred conductor is metal.
As already mentioned above, exemplary micro-patterning conductor show have more than 80,90 or 95% or be positioned at 95 Aperture area ratio in the range of 98%.Exemplary micro-patterning conductor also shows to have and is positioned at 20 nanometers to 10 microns In the range of or less than 2 microns or less than 1 micron or be positioned at 30 nanometers to the conductive trace thickness in the range of 1 micron.Preferably Ground, the transverse width of conductive trace be positioned at 0.1 to 20 micron or 0.5 to 20 micron or 0.5 to 10 micron or 1 to 5 micron, Or in the range of 1.5 to 4 microns or less than 20,10,6,5,4,3,2 or 1 microns.Preferably, the trace of micro-pattern and mark Distance between centers of tracks is less than 300 microns.
The major optical characteristic of micro-patterning conductor is the aperture area ratio of the micro-pattern having been discussed above.Other is notable Optical characteristics include micro-patterning goods current-carrying part visible transmission than and mist degree and conductive trace visible Degree.In the exemplary embodiment, the haze value of the conductive region of goods disclosed in this invention is less than 10%, 5% or 2%.Can Such as use the Haze-Gard Plus of the BYK-Gardner deriving from Columbia, MD (Columbia, Maryland) The mist degree to article made to order or its current-carrying part measured by apparatus.The most in the exemplary embodiment, including dielectric base and conduction The conductive region (such as antenna) of the goods disclosed in this invention of the micro-pattern of property has in the conductive region of micro-pattern and is more than 50%, 60%, 70%, 80% or 90% or be positioned at the visible transmission value in the range of 80% to 90%.
The sheet resistance of the current-carrying part that main electrical property is goods of micro-patterning conductor.In the exemplary embodiment, Along any given side, the sheet resistance in direction is positioned in the range of 0.1 to 200 ohm-sq, is positioned at 1 to 100 ohm-sq In the range of or less than 50,20,10,5,1 or even 0.1 ohm-sq.
Turning now to Fig. 6 a, the high transparent that can be observed to have the micro-pattern of square or rectangle formed by trace 612 is led The front schematic view of electricity region 610a or top view.The pattern of Fig. 6 a is similar to the pattern of Fig. 5, but trace 612 is laterally wide Degree (with the ratiometer of opposite trace spacing) is less than the transverse width shown in Fig. 5.The pitch mark of the trace of Fig. 6 a is along one The 620a of axis in individual face and the 630a of axis along normal surface.These spacing can be same or different, and this depends on leading The desirable characteristics of electricity region 610a.Equally, trace transverse width of axis along normal surface can be same or different (for For forming the different traces of pattern), this depends on the required character of conductive region 610a.
Fig. 6 b is front schematic view or the top view of high transparent non-conducting areas 610b.Region 610b has and Fig. 6 a The micro-pattern of identical nominal, except for the difference that includes that selectivity is interrupted 611 so that region 610b is nonconducting.Form Fig. 6 b's The trace of pattern can be same or like with the trace of pattern forming Fig. 6 a, such as, they can by with phase in the embodiment of Fig. 6 a Same or similar metal or other thin layer of conductive material are constituted, and except for the difference that selectivity is interrupted 611 prevention electric currents along Fig. 6 b's The flowing of the micro-pattern of discontinuity cell.It is interrupted and is preferably relatively short, e.g., less than 30,20,10 or even 2 microns.
By interruption is prepared as being shorter than pattern-pitch and a small amount of by having in each elementary cell of pattern It is interrupted (such as less than 10), can will include that the non-conducting areas 610b being interrupted micro-pattern is prepared as the general viewers for goods With there is for user the outward appearance identical or almost identical with conductive region 610a.This outward appearance similarity is advantageously used for hidden Covering RFID antenna, described RFID antenna is to utilize conductive region (such as conductive region 610a) and non-conducting areas (the most non-to lead Electricity region 610b) formed.Therefore, in the case of the non-conductive section of goods does not have the trace of any conductive material, i.e. Conductive region 610a is made to have the aperture area ratio of 90% or 95% so that the existence of trace 612 is by the system in these positions The transmission of visible light of product reduces the most only 5% or 10%, and observer can still be able to the geometric layout according to antenna and this Layout notices antenna relative to the 5 of adjacent part or the transmission of visible light difference of 10% of goods.On the other hand, pass through The non-conductive section of the goods of the neighbouring current-carrying part constituting antenna provides and is interrupted trace patterns (pattern of such as Fig. 6 b), The close coupling of transmission of visible light of adjacent part can be made, and the transmission of visible light difference between adjacent part can be made (contrast) significantly reduces, and such antenna is that pole is not notable and the most unconspicuous for user or general viewers.
Fig. 7 a is front schematic view or the top view of another high transparent conductive region 710a.Region 710a uses and leads The trace 712 of electric material, the trace of described conductive material is arranged to form the micro-pattern of hexagon, and the micro-figure of non-square Case.The paired relative edge (trace) of hexagonal elementary cell limits axis in three faces, can limit trace spacing, Qi Zhong simultaneously In Fig. 7 a, a trace spacing is marked as 720a.For the equilateral hexagon of rule, whole along the spacing of three axis Can be identical, if but use the elongated or hexagon of distortion, then along not coplanar, the spacing of axis can be different.
The aperture area ratio discussed in this paper other places, conductive traces thickness, conductive traces transverse width, between conductive traces Away from, transmission of visible light, mist degree and the exemplary value of sheet resistance and scope be equally applicable to the conductive region of Fig. 7 a 710a。
Fig. 7 b is front schematic view or the top view of high transparent non-conducting areas 710b.Region 710b has and Fig. 7 a The micro-pattern of identical nominal, except for the difference that includes that selectivity is interrupted 711 so that region 710b is nonconducting.Form Fig. 7 b's The trace of pattern can be same or like with the trace of pattern forming Fig. 7 a, such as, they can by with phase in the embodiment of Fig. 7 a With or similar metal or other thin layer of conductive material constitute, except for the difference that selectivity is interrupted 711 prevention electric currents along between Fig. 7 b The flowing of disconnected micro-pattern.It is interrupted the most relatively short, e.g., less than 30,20,10 or even 2 microns, and each six The most a small amount of interruption (such as less than 10) is included, so that the visual appearance of region 710b can be made in the shape elementary cell of limit Identical or almost identical with the visual appearance of conductive region 710a.When region 710a, 710b take on RF device adjacent (e.g., Complementary) region time, this visual appearance similarity is advantageously used for hidden RF antenna.
Fig. 7 c for include high transparent conductive region 710a (e.g., as dipole antenna or a part for other antenna) and The front schematic view of the goods 710c (such as, RFID antenna device) of adjacent high transparent non-conducting areas 710b or top view Figure.Region 710a, 710b have the identical micro-pattern of nominal hexagon formed by the trace 712 of conductive material, but in region 710b provides and is interrupted 711 so that this region becomes non-conductive.Border between 710a and 710b of region can represent herein The electric conductivity of any one (combined any one in the antenna assembly as described in Fig. 3 or 4a-e) in described antenna assembly Border between part and non-conductive section.
Fig. 8 has the microphotograph of the high transparent conductive region 810 of the micro-pattern of pseudorandom grid.At random, pseudorandom and Irregular pattern (and pattern of irregular repetition) can be used for the micro-patterning in RFID antenna device disclosed in this invention Conductor.Adhere to combine with another parts including visible lines, unit or further feature in other words conj.or perhaps in RFID antenna In the case of, irregular pattern etc. can be used to alleviate unwanted wave pattern.
In some cases it may be beneficial to one or more labellings or other image to be attached to high transparent conduction In region, wherein said labelling can be highly-visible or it will be evident that or the most described labelling for user Can be the most visible.In some cases, labelling can be hidden, i.e. is difficult to be seen by human eye or see Observe, but can detect that under following specific condition, such as amplify under the conditions of, under specific shot wavelength and/or specific Under illumination angle and/or visual angle.In some cases, it is marked at utilization and passes principally through the illumination of antenna (such as relative to observer For from back surface incident to antenna on) can be to be difficult to see or the most visible when observing, and utilize mainly from The antenna side essentially identical with observer incides the illumination on antenna (such as, to become to be less than relative to the direction of observation of observer The angle of 90 degree incides on antenna) can be visible when observing or be significantly more easy to see；In this type of embodiment, including The material of conductive pattern is the most reflexive.In fig .9, under the background of conductive region 910, it is schematically shown that can be Hidden or the exemplary indicia 912 of highly-visible.Labelling can present brand mark or safety sign or other shape as required The form of shape.Labelling can be attached in mesh design self, and/or extra micro-pattern characteristics can be added to conduction In the master pattern of trace (micro-patterning conductor) thus provide unique visual signature for antenna stack or conductive region.Extra The shape of micro-pattern characteristics or pattern can have minimum for the function aspects of antenna pattern or not have an impact, such as, for The sheet resistance of conductive region has minimum or does not have impact.
The example of extra micro-pattern characteristics includes reflection or the lattice array of diffraction light and linear array, and wherein said array limits The shape of calibration note.Other example of extra micro-pattern characteristics includes the kind of thread elements with following orientation, and described orientation is different Orientation in the kind of thread elements of the functional antenna part constituting conductive pattern.In the certain situation relating to extra micro-pattern characteristics Under, conductive element can be the most reflexive.Fig. 9 a to 9c provides and can be used for providing labelling (labelling of such as Fig. 9) Some examples of extra micro-pattern characteristics.Discussing to compare and being easy to, each of which in Fig. 9 a to 9c is shown as table Region 914 in diagram 9, described region 914 includes that a part for labelling 912 and also include represents original or unchanged The background parts of micro-patterning conductive region.
In fig. 9 a, the trace 920 of the conductive material being arranged to hexagonal shaped pattern provides high transparent conductive region.Separately Outer extra micro-pattern characteristics 926 (in the case, for the pattern of isolated point) is arranged in substrate or in substrate, to distinguish Mark part 924 and the background parts 922 of conductive region.Dotted line indicatrix 912a, 912b be plotted as flag activation part and Border between background parts, described indicatrix forms a part of " M " in the labelling shown in Fig. 9.Micro-pattern characteristics 926 can It is made up of the identical conduction film of trace 920 or material forming micro-patterning conductor, or they can be made from a different material, As, other suitable conductor any or other suitable material (including non-conductive or insulant).Micro-pattern characteristics 926 can be Sufficiently small, with diffraction light in mark part.In the exemplary embodiment, feature 926 can be the pros of 3 × 3 micron-scales Shape, described square is arranged to hexagonal array, wherein has between adjacent square between the center to center of 10.2 microns Away from.
In figure 9b, the trace 940 of the conductive material being arranged to hexagonal shaped pattern provides high transparent conductive region.Additionally Extra micro-patterning feature 946 (in the case, for the line segment pattern arranged near trace 940) is arranged in substrate or In substrate, with the background parts 942 of separator part 944 with conductive region.Dotted line indicatrix 912a, 912b are plotted as showing Going out the border between mark part and background parts, described indicatrix forms a part of " M " in the labelling shown in Fig. 9.Micro- Pattern characteristics 946 can be made up of the identical conduction film of trace 940 or material that form micro-patterning conductor, or they can be by not Make with material, e.g., other suitable conductor any or other suitable material (including non-conductive or insulant).
In Fig. 9 c, the trace 960 of the conductive material being arranged to hexagonal shaped pattern provides high transparent conductive region.Additionally Extra micro-patterning feature 966a, 966b (in the case, for the independent sets of line segments of different orientation) are arranged in substrate Or in substrate, with the background parts 964 of separator part 962 with conductive region.Dotted line indicatrix 912a, 912b are plotted as Border between flag activation part and background parts, described indicatrix forms a part of " M " in the labelling shown in Fig. 9. In micro-pattern characteristics 966a, 966b one group or two groups can by formed micro-patterning conductor trace 960 identical conduction film or Material is made, or one group or two groups can be made from a different material, e.g., and other suitable conductor any or other suitable material (including non-conductive or insulant).
Figure 10 is that the schematic isometry of card or similar articles 1010 that assembling has the RFID device of UHF antenna 1020 decomposes View.These goods include being laminated to or perhaps adhere to the second layer or the ground floor of part 1014 or part 1012.Ground floor Element or the feature being applicable to the desired use of goods be can include, e.g., photographic information, the information of word and numeral, impressing included Feature and security features.In the illustrated embodiment, goods 1010 represent the driver's license of people, but in other cases, it can be Maybe can include another kind of goods, such as financial transaction card (including the credit card and debit card), tag card, Payment Card etc..Second Layer 1014 includes dielectric base or film, and wherein at dielectric base or film, on it or in it, high transparent conductive region 1016 is formed In non-conducting areas 1018, described conductive region is configured to form antenna 1020.Conductive region 1016 is provided with in this paper other places Any one in described high transparent micro-patterning conductor.For the enhancing during providing card preparation and during use Reliability and durability, micro-patterning conductor is preferably used conductive metal material, rather than metal conductive oxide material (example Such as indium tin oxide (ITO)).Goods 1010 are further adapted for including small-sized RFID integrated circuit (not shown), the integrated electricity of described RFID Road is connected to antenna 1020 to carry out communication with RFID reader.
Card can include known to mark and art of transaction cards and can give safety, communication or graphic feature or merit Other structure, parts or the material of energy.In the exemplary embodiment, non-conducting areas 1018 include being interrupted micro-pattern (see as Fig. 6 b, 7b, 7c) to reduce the contrast between region 1016,1018, and thus reduce the visibility of antenna 1020 (especially In the case of whole card is designed to printing opacity).More known printing opacity cards include near infrared filter device, described near infrared filter device High transmission visible ray, but absorb, reflect or perhaps intercept the light on near-infrared wavelength frequency band, so that card can intercept The existence blocked with detection from the light of the infrared LED in ATM (ATM) or similar light source.In this case, As the most mentioned above, antenna can be set directly on infrared barrier film.Infrared barrier film can be maybe can to include by alternately The multi-layer optical film that polymeric layer is constituted, refractive index and the thickness of described alternating polymer layers are customized to for vertical incidence Visible ray provides high-transmission rate, but substantially intercepts near infrared light.Applicable antenna can will be had by methods known in the art The layer 1014 of 1020 and other material carry out lamination goods needed for forming card or forming other.
In some cases, the device in RFID label tag form includes integrated circuit and antenna, and wherein antenna includes metal The micro-pattern of conductive mesh, the described micro-pattern of metallic conductivity grid has the gold being positioned at about 30 nanometers to about 1 micrometer range Belong to thickness, be positioned at 0.5 micron of track width to 10 micrometer ranges, the aperture area ratio of at least 90% and be positioned at 1 Europe Nurse/square to the effective thin layer resistance in the range of 200 ohm-sq.Additionally, as included above-mentioned at card described elsewhere herein Label, described card is optionally transparent.It addition, rfid system can include above-mentioned label and with 860MHz and 960MHz between One or more frequencies be operated in 0.2 watt to the reader under 5 watts radiative power, wherein said antenna is customized to make Obtain RFID reader to be positioned in the range of 1 centimetre to 2 meters with the ultimate range of device communication.
In some cases, the device in RFID label tag form includes integrated circuit and antenna, and wherein antenna includes metal The micro-pattern of conductive mesh, the described micro-pattern of metallic conductivity grid has the gold being positioned at about 30 nanometers to about 1 micrometer range Belong to thickness, be positioned at the track width of 1 to 5 micrometer range, the aperture area ratio of at least 95% and be positioned at 1 to 100 ohm/ Effective thin layer resistance in square range.Additionally, as included that above-mentioned label, described card are optionally at card described elsewhere herein Transparent.It addition, rfid system can include above-mentioned label and with the one or more frequency works between 860MHz and 960MHz Making reader under 0.2 watt to 5 watts radiative power, wherein said antenna is customized to so that RFID reader can be with The ultimate range of device communication is positioned in the range of 1 centimetre to 2 meters.
In some cases, the device in RFID label tag form includes integrated circuit and antenna, and wherein antenna includes metal The micro-pattern of conductive mesh, the described micro-pattern of metallic conductivity grid has the gold being positioned at about 30 nanometers to about 1 micrometer range Belong to thickness, be positioned at the track width of 1 to 5 micrometer range, be positioned at the aperture area ratio in the range of 95% to 98% and be positioned at Effective thin layer resistance in the range of 1 to 100 ohm-sq.Additionally, as above-mentioned label can be included at card described elsewhere herein, Described card is optionally transparent.It addition, rfid system can include above-mentioned label and with between 860MHz and 960MHz Or multiple frequency be operated in 0.2 watt to the reader under 5 watts radiative power, wherein said antenna is customized to so that RFID Reader can be positioned in the range of 1 centimetre to 2 meters with the ultimate range of device communication.
Utilize high transparent micro-patterning conductor discussed herein to prepare some RFID antenna devices, and test.
For example 1, utilize high transparent micro-patterning conductor to prepare the transparent slit sky of type shown in Fig. 3 Line.The external boundary of conductive region is 15cm × 15cm.Conductive region (is i.e. in the non-conductive gap area at the center of antenna Inner boundary 312a) is 5cm × 0.5cm.Patterned conductor by be deposited on transparent poly-(ethylene glycol terephthalate) (PET, Product code ST504,125 microns of thickness, it is available from Wilmington, DE (Wilmington, Delaware) E.I.DuPont de Nemours and Company) on silver metal thin film make, and according to PCT Publication WO 2009/ Micro-contact printing method described in 154812 (Frey et al.) patterns.Design (that is, the grid geometric form of micro-pattern Shape) use randomly shaped unit, the microphotograph (shooting in transmission) of the design of described micro-pattern is shown in Figure 8.Averagely Unit size (lateral dimension or spacing) is about 200 microns.The track width of all traces is about 1.5 microns.The thickness of silver metal Degree is about 100 nanometers.The aperture area ratio of conductive region is about 98.5%.The sheet resistance of conductive region is tested to be about 30 Ohm-sq is to 40 ohm-sq.Utilize conductive adhesive that two copper strips contact pin are adhered to leading of the every side of center slot Electricity region, as shown in Figure 3.Obtain coaxial cable and at one end carry out cutting to expose signal and earth conductor, and using These conductors are attached to copper contact pin by solder.
As benchmark (comparative example 1), the copper sheet using gum (not carrying out micro-patterning) continuously is similarly sized to prepare Opaque antenna structure.Cutting copper sheet is to form the square of 15cm × 15cm size.From foursquare heartcut go out 5cm × The gap of 0.5cm size is to produce the antenna pattern shown in Fig. 3.This gum copper sheet is installed to the foamed core web of 15cm × 15cm On.Foaming core provides rigidity backing for copper sheet, but does not hinder its electromagnetic property.Obtain coaxial cable and by its according to example Mode that the antenna of 1 is identical and being attached on the copper conductor of gap opposite side by its signal and earth conductor.
Evaluation example 1 and the antenna of comparative example 1 is come by analyzing Charge Transport Properties.Optimal by coming with reference to Friis formula Ground explaination Principle of surveying:
P r = ( | F | 2 4 &pi; r 2 ) e t D t P t [ 1 - | &Gamma; t | 2 ] [ 1 - | &Gamma; r | 2 ] p [ &lambda; 2 4 &pi; e r D r ]
Dt, Dr=antenna direction
er, et=antenna efficiency (depends on material)
F=E reality/E free space
Γt, Γr=antenna reflection coefficient
P=polarization mismatch is lost
Pt=transmit power
Pr=receive power
Distance between r=antenna
There is multiple factor determining to receive power.But, during measuring at this, due to example 1 and the sky of comparative example 1 Line is configured to have identical overall geometry, it is therefore assumed that all variablees in addition to the efficiency depending on material parameter All can keep constant.
Antenna (example 1 or comparative example 1) in test is connected to the port 1 of network analhyzer, and by standard 2.45GHz paster antenna is connected to the port 2 of analyzer.The distance between antenna and paster antenna in test remains constant 32cm.The transmission value measuring antenna of gained is as follows: the antenna of example 1 ,-31.5dB；The antenna of comparative example 1 ,-28.8dB； Only cable (disconnecting from the antenna of example 1) ,-50dB.Bigger shows higher transporting on the occasion of (less negative value).We are also Being not optimised antenna impedance, therefore, absolute number is important not as the difference of the measured value between example 1 and the antenna of comparative example 1.Under performance Drop about 3dB and show under 2.45GHz, the effect of the opaque copper sheet that efficiency is comparative example 1 of the transparent micro-patterning conductor of example 1 About half of rate.The measurement performing only cable serves as bad antenna with confirmation copper contact pin and cable, thus proves the antenna of example 1 Record transporting non-cable/copper contact pin owing to micro-patterning conductor.
Utilize high transparent micro-patterning conductor to prepare RFID antenna.Use multiple Antenna Design, including being suitable to Under 13.56MHz use antenna and be suitable under 915MHz use antenna.Additionally use different micro-patterning conductors, institute State difference and include track width, trace spacing, trace thickness and the difference of aperture area ratio.For each RFID antenna Speech, utilizes digital multimeter (Fluke 73III Multimeter derives from the Fluke Corporation of the U.S.) to measure sky The DC resistance of line, and subsequently RFID integrated circuit is connected to antenna.Then the RFID reader utilizing routine is evaluated such as This RFID device prepared, to determine RFID device is directly abutted against when RFID reader is arranged whether signal be can be observed. If it is observed that signal, it is incrementally increased the distance between RFID reader and RFID device the most subsequently until no longer observing letter Number, record this distance using as value Dmax discussed above in association with Fig. 1.
Antenna preparation method
Preparing each antenna by patterned polymer film suprabasil Ag films deposit, this process was based on 2009 Entitled " the Methods of Wet Etching a Self-assembled Monolayer that June 25 submitted to Patterned Substrate and Metal Patterned Articles " (wet etching self-assembled monolayer patterning base The end and the method for metal pattern goods) U.S. Patent Application Serial No.61/220407 (attorney Method described in 65462US002).Described method includes poly-(p-phthalic acid thick for the veneer to 125 microns of silver Glycol ester) (ST504 is available from Wilmington, DE (Wilmington, Delaware) to (PET) polymer film substrate E.I.DuPont de Nemours and Company) on.Use different methods for depositing the silver layer of different-thickness.Right For coming from the antenna of silver layer of 30,300,500,700 or 1000 nano thickness, first evaporation has the average of 0.5 nanometer The adhesion promoting layer of the titanium of thickness, subsequently by electron beam evaporation plating by deposition of silver to PET base.Receive for coming from 60 or 100 For the antenna of the silver layer of meter Hou Du, by sputtering by deposition of silver to PET base.By micro-contact printing by octadecyl The pattern deposition of mercaptan self-assembled monolayer is on silver surface, and the most never printing zone is etched selectively to silver layer, and these are two years old Individual process is based on entitled " the Methods of Wet Etching a Self-assembled submitted on June 25th, 2009 Monolayer Patterned Substrate and Metal Patterned Articles " (wet etching self assembly list Pattern layers substrate and the method for metal pattern goods) U.S. Patent Application Serial No.61/220407 (attorney docket Number 65462US002) described in method.
RFID label tag assemble method
For each RFID label tag, IC wafer is adhered to the antenna prepared as described above.For hereafter For each UHF label (that is, example 6 to 45) listed, wafer is for deriving from Jennings technology (San Jose, CA) The NXP G2XM UHF RFID wafer of NXP Semiconductors.This G2XM wafer is installed in polymeric substrates Metal lead wire frame, described polymeric substrates meets the JEDEC MO-283-B nominal contour (reference net for RFID belt carrier Location http://www.jedec.org/committees/jc-65).The big end pad of MO-283-B belt carrier is designed to even Receive the corresponding pad on antenna.In automated circuit assembly operation, MO-283-B belt carrier is designed to continuous roll form Use.For the sample for this research preparation, from bigger supply volume, cut out each carrier, the most each Carrier all includes the single G2XM wafer of the metal lead wire frame being attached on polymer support.
For these samples, the metal gasket of MO-283-B carrier utilizes anisotropy conductiving glue (ACP) binding agent electricity The corresponding attachment pad being connected to and be physically connected on antenna structure.ACP is Loctite3447 Snap Cure anisotropy Electroconductive binder glue, it derives from the Henkel Loctite, Research of Dublin, Ireland (Dublin, Ireland) Development ， &Engineering, Tallaght Business Park.ACP binding agent includes Thermocurable one pack system ring Epoxy resins carrier, described Thermocurable one-component epoxy resin carrier has and is distributed in whole epoxy resin volume The nickel spheroid of 0.005mm diameter.The density of nickel spheroid is of a sufficiently low, so that when epoxy resin cure, can be by compression The vertical dimension (" Z axis ") of film realizes connecting.The surface density of particle is of a sufficiently low, so that at the ACP binding agent of compression The most lateral (x-y) electric conductivity is there is not in Ceng.
In order to MO-283-B carrier is bonded to UHF antenna, use following method.
The attachment pad that ACP binding agent is coated on antenna by (adhesion step 1).The total amount of the glue needed for this process is attachment The thickness of about face size (3mm × 3mm) × about 0.025mm of pad or 0.225mm3(0.225×10-3Milliliter).Implementing During, it is difficult to manually distribute smaller size smaller；The ACP binding agent of excess is often expressed to pad edge during bonding Around.
MO-283-B carrier is arranged on incured adhesives by (adhesion step 2), the biggest metallic attachment pad alignment sky Line attachment pad.MO-283-B carrier is temporarily remained alignment by the surface tension of incured adhesives.
(adhesion step 3) at MO-283-B carrier alignment antenna attachment pad and is adhered by uncured epoxy resin In the case of, will process in label move to the M ü artificial cementing machine of hlbauer TTS300 (derive from Germany Luo Ding (Roding, Germany) M ü hlbauer AG High Tech International) adhesion station.
(adhesion step 4) TTS300 is designed to flip-chip die attachment method, wherein by little (* (2 squares of millis of ＜ Rice) silicon wafer is bonded to circuit.Due to the attachment pad on MO-283-B belt carrier and antenna relatively big (about 3 square millimeters) and It is spaced wider, therefore one end of carrier is bonded to the antenna attachment pad of its correspondence every time.This needs each carrier is repeated two This bonding process secondary, every time for an end.Carrier is bonded to by twice operation the Another reason of antenna be in order to Avoid being applied on the silicon wafer of carrier central authorities any pressure and heat.Silicon wafer is easily affected by physical damage, and by heat The stress that electrode is forced can make it rupture or lose efficacy.It addition, silicon wafer will tend to keep thermoelectricity the most separate, it is therefore prevented from They pressure is applied to the attachment pad of belt carrier end.
(adhesion step 5) artificial cementing machine of TTS300 is designed to the program control value applying pressure and heat to electrically connect and solid Change ACP binding agent.Two thermodes (one above, one below) promptly connection gasket and ACP binding agent.Thermode applies Pressure, to engage nickel particles, thus forms electrical connection between two metal surfaces.The heat of bonded areas is flowed into from thermode Cured epoxy resin substrate and in position seal this connection.
(adhesion step 6) discharges thermode and removes finished product sample from artificial cementing machine.
Specified for projection silicon wafer being bonded to the viscous of RFID antenna by binding agent manufacturer (Henkel Loctite) Knot condition is 100 grams of (0.98 newton) power/projections square or the circle of 0.080mm (size of lug be usually), at tack line Position is at a temperature of 170 DEG C to 190 DEG C, in 3 to 5 seconds and applies pressure and heat first.According to metal connection pads and substrate In heat dissipation, thermode will typically require offer 190 DEG C to 210 DEG C with the tack line temperature reaching to specify within the time limit specified Degree.
Attachment pad for MO-283-B assembly is of about the square of 3mm, therefore upper close to 8 Newton force of thermode It is operated under limit state.Under these conditions, the power of per unit area be enough to will be carried by the electroconductive particle of ACP binding agent The attachment pad of body band is electrically connected to the attachment pad of antenna.
For each HF label (that is, example 2 to 5) being listed herein below, RFID IC wafer is polymer lead frame NXP I-Code SLI on the metal of frame.Lead frame is similar to the material in JEDEC MO-283-B and structure.HF crystal grain Lead frame is different in terms of form factor.In this case, form of metal is of about 15mm length.Wafer is in center It is connected to the wide trace of about 1mm.Trace is in its end terminates at the square pad of 3mm, and wherein actual effect looks class It is similar to Os Canitis.
In addition to the metal on polymer support has different form factors, the HF wafer on lead frame The adhesive method of the G2XMUHF wafer that adhesive method is similar on MO-283-B carrier.
RFID label tag evaluation methodology
According to reading the distance of RFID label tag and utilize specified requirements to evaluate RFID label tag.
For HF label (example 2 to 5), utilize Texas Instruments TRF7960EVM reader (Texas The Texas Instruments of state Dallas (Dallas, TX)；Derive from Minnesota State stannum husband livre Fu Ersi (Thief River Falls, MN) TRF7960EVM) check RFID function, described Texas Instruments TRF7960EVM reads Go out device and the embedded reader antenna provided with module is provided.
TRF7960EVM is connected to the USB terminal of laboratory computer.USB terminal provides power to module, and The program utilizing TRF7960EVM to provide carries out communication with it.TRF7960EVM has when reader detection RFID label tag response The onboard light-emitting diode display illuminated.Under this nominal operating mode, TRF7960EVM being sent out with 200 milliwatts at 13.56 mhz Penetrate RF power to be operated in RFIDISM band.
In order to test the label prepared according to this specification, by the USB port of TRF7960EVM loading test room computer In.Utilize Known good RFID label tag to test reader operation, work with checking " label response " LED indicator, And verify the approximation read range for 50mm square HF Antenna Design.The read range of the label in test is can be by Reader detects the ultimate range of the RFID response from label, i.e. parameter Dmax discussed above.This distance is from label Center record to the center of reader antenna, wherein the putting down towards amount (being perpendicular to the vector of antenna plane) of reader antenna Row in label antenna towards amount and with label antenna towards amount coaxial.All the measurement of HF label read range is to utilize The label above TRF7960EVM antenna being positioned in free space is carried out.TRF7960EVM is arranged in non-conductive mineral In composite lab platform.
Confirmed just after function at TRF7960EVM, test prepare according to this specification sample (example 2 to 5).As shown in the result of table 1 below, wherein the entry " NR " in Dmax row refers to even be directly abutted against reader in RFID device During layout, RFID reader is still " without response ", and HF grid Antenna Design does not demonstrates appoints TRF7960EVM RFID reader What response.
In order to test UHF label (example 6 to 45), use SAMSys MP93202.8 " EPC " reader and Cushcraft (the SAMSys Techologies of Toronto, Ontario (Toronto, Ontario) (is now the portion of Sirit to 9028PC antenna Point)；The Cushcraft Corporation in Manchester, the state of New Hampshire (Manchester, NH)).MP 9320 reader It is set to the nominal output RF power of 1 watt.MP 9320 is positioned at its antenna range and responds its RFID signal detecting Audible sound is produced during RFID label tag.MP 9320 reader is being specified the 902-928MHz for UHF rfid system by U.S. FCC UHF frequency band is operated with frequency-hopping mode.
There are the some UHF frequency band specified for rfid system operation, it should be noted that be 868MHz in European Union member countries And it is 956MHz in Japan.Multiple countries in the world use other UHF frequency band some.As same frequency, each area under one's jurisdiction The operating power limit allowed has the biggest difference.For these examples, use working band and U.S. of peak power State's specification measures label response.
According to being similar to the mode of HF label to test UHF label (example 6 to 45).Label is alignment, so that mark Label antenna is parallel and coaxial with reader antenna towards amount.If seen when label is directly abutted against when RFID reader is arranged Observe signal, the most subsequently label is moved away from the direction of reader antenna along the center alignment of reader antenna.Read Go out scope (that is, Dmax) to be confirmed as reader and remain to detect being positioned in reader antenna and label antenna of RFID label tag Ultimate range between the heart.The measurement process of Dmax be absorber lined chamber (that is, be specially designed to be used at low RF noise and low RF anti- The room that sensitive RF measures is carried out under conditions of penetrating) middle execution.
The test job three different antennae designs in the range of HF.The related geometry of these three design is shown in figure In 4a, 4b and 4c.The integral level being dimensioned to there is about 51.3mm of the design (example 2) of Fig. 4 a and vertical size. Being dimensioned to of the design (example 3) of Fig. 4 b is respectively provided with the integral level (major axis) of about 76.27mm and 22.65mm and perpendicular Directly (short axle) size.Being dimensioned to of the design (example 4 and 5) of Fig. 4 c is respectively provided with the whole of about 25.57mm and 6.73mm Body level (major axis, only ring geometry；That is, do not include padding 434a) and vertical (short axle) size.In each case, accordingly Micro-patterning conductor (discussed further below) design conductive region (e.g., the region 414 of Fig. 4 a, 414a and It is continual in 414b), but (e.g., region 412a, 412b and the spiral type of Fig. 4 a are non-conductive in the non-conducting areas of design Region) in for be interrupted.
The test job two different antennae designs in the range of UHF.The related geometry of the two design is shown in figure In 4d and 4e.The design (example 6 to 25) of Fig. 4 d be dimensioned to be respectively provided with the overall water of about 8.02mm and 94.66mm Flat (short axle) and vertically (major axis) size.The size (example 26 to 45) of Fig. 4 e be designed to be respectively provided with about 4.02mm and Integral level (the short axle, only conductive mesh region of 128.88mm；That is, do not include padding 454a and 454b) and vertical (short axle) chi Very little.In each case, corresponding micro-patterning conductor (discussed further below) is at conductive region (e.g., Fig. 4 d of design Region 444,444a, 444b) in be continual, but design non-conducting areas (e.g., the region 442a of Fig. 4 d) in be It is interrupted.
Micro-patterning conductor
Process above-mentioned silver metal layer to form the trace of the square-shaped repeating patterns being arranged to rule.For example 2,3 and For the antenna of 6 to 45, spacing (that is, the nominal chi of the side edge length of square elementary cell of trace axis along vertical plane Very little) it is 200 microns.For the antenna (Fig. 4 c) of example 4, trace spacing of axis along two normal surfaces is 50 microns. For the antenna (the most as illustrated in fig. 4 c) of example 5, trace spacing of axis along two normal surfaces is 50 microns.Such as following table Shown in 1, some embodiments are used to the track width of 2 microns, and other embodiments are used to the trace width of 5 microns Degree, thus produces the aperture area ratio being listed in table.Each antenna is intended in the region of conduction, i.e. corresponding being formed In the part of antenna, square-shaped repeating patterns is continual (see for example Fig. 6 a).For wherein the trace of 2 microns being arranged For the above-mentioned silver apertured conductor pattern of the square net (the aperture area ratio of 98%) becoming to have 200 micron pitch, The effective thin layer resistance of the target metal thickness of 30nm, 60nm, l00nm, 300nm, 500nm and 700nm lays respectively at 80 through measuring To 150,10 to 13,10 to 13,5 to 6,3 to 6 and 3 to 5 ohm-sq.For wherein the trace of 5 microns being set For the above-mentioned silver apertured conductor pattern of the square net (the aperture area ratio of 95%) being set to have 200 micron pitch, The effective thin layer resistance of the target metal thickness of 30nm, 60nm, 100nm, 300nm, 500nm and 700nm lays respectively at 40 through measuring To 60,5 to 7,5 to 7,2.5 to 5,1.5 to 2.5 and 1 to 2 ohm-sq.In being intended to nonconducting part, Use the interruption of rule so that trace is the most nonconducting (participating in such as Fig. 6 b).Such as, for example 2,3 and 6-45 Antenna for, each unit square arranges eight interruptions, as shown in Figure 6 b, a length of 6 microns of each interruption.Use each Planting silver metal thickness, described thickness is also shown in Table 1 below.
Example Antenna Design Track width (micron) Aperture area (%) Metal thickness (nm) Dmax(cm) Resistance (Ω) 21 Fig. 4 d 5 95 100 34 96 22 Fig. 4 d 5 95 100 43 89 23 Fig. 4 d 5 95 300 70 49 24 Fig. 4 d 5 95 500 91 35 25 Fig. 4 d 5 95 1000 190 38 26 Fig. 4 e 2 98 30 NR 3.58k、4.87k 27 Fig. 4 e 2 98 60 22 339 28 Fig. 4 e 2 98 60 17 402 29 Fig. 4 e 2 98 60 27 419 30 Fig. 4 e 2 98 100 14 431 31 Fig. 4 e 2 98 100 8 435 32 Fig. 4 e 2 98 100 19 396 33 Fig. 4 e 2 98 300 27 229 34 Fig. 4 e 2 98 500 41 166 35 Fig. 4 e 2 98 500 37 205 36 Fig. 4 e 5 95 30 NR 2k、1.5k 37 Fig. 4 e 5 95 60 29 197 38 Fig. 4 e 5 95 60 38 250 39 Fig. 4 e 5 95 60 25 205 40 Fig. 4 e 5 95 100 38 191 41 Fig. 4 e 5 95 100 42 192 42 Fig. 4 e 5 95 100 27 175 43 Fig. 4 e 5 95 300 74 90 44 Fig. 4 e 5 95 500 107 63 45 Fig. 4 e 5 95 700 190 42
Can be it is readily apparent that all do not see in any RFID device of the HF operation at frequencies of 13.56MHz by scrutinizing table Observe response.On the other hand, find that the multiple RFID device being designed at the UHF operation at frequencies of 915MHz can be successfully Work.The function of these devices below indicates associated materials and design other frequency in UHF frequency band (is prolonged from 860MHz Extend 960MHz) under the fitness that works.
Except as otherwise noted, it is used for the most in the specification and claims representing all of quantity, characteristics metrics etc. Numerical value is all to be understood that as being modified by term " about ".Therefore, unless the contrary indication, otherwise present specification and claims In the numerical parameter listed be approximation, these approximations can utilize present patent application according to those skilled in the art Desirable characteristics that teachings goes for and change.Each numerical parameter is not intended as the application of doctrine of equivalents is limited in power In the range of profit claim, at least should be according to the number of the significant digit recorded with by applying usual rounding-off method Explain each numerical parameter.Although the numerical range listed in the approximate range of the present invention and parameter are approximations, but the most any For numerical value is all listed in instantiation described herein, its record is accurate as much as possible and reasonable.But, any numerical value is permissible Comprise and limit relevant error to test or measurement.
Under the premise without departing from the spirit and scope of the present invention, various amendments and change to the present invention are for this area Interior technical staff will be apparent to, and should be appreciated that and the invention is not restricted to exemplary embodiment listed herein.Example As, except as otherwise noted, otherwise reader is it should be assumed that the feature of a disclosed embodiment also apply be applicable to disclosed institute There are other embodiments.It is also understood that herein cited all United States Patent (USP)s, patent application publication case and other patents and non-specially Profit document is all incorporated by reference in the case of not inconsistent with above disclosure.
1. a RFID device, including:
Antenna, described antenna includes:
Dielectric base；With
Arranging the first micro-pattern of electric conductivity on the substrate or in described substrate, the described first micro-pattern of electric conductivity limits neighbour The apertured conductor connect；
The wherein said first micro-pattern of electric conductivity forms the antenna of the frequency at least responding 915MHz；
The wherein said first micro-pattern of electric conductivity includes that interconnection traces, described interconnection traces have and is positioned at 0.5 micron to 20 microns In the range of track width；
The wherein said first micro-pattern of electric conductivity has the thickness less than 2 microns；And
The wherein said first micro-pattern of electric conductivity is characterized by the aperture area ratio of at least 80%；And
It is configured to utilize described antenna to launch and receive the integrated circuit of signal；
Wherein said antenna is customized to produce the RFID being operated under 1 watts radiative power with 902-928MHz frequency-hopping mode and reads Going out device can be with the ultimate range of described device communication.
Device the most according to claim 1, wherein said track width is positioned in the range of 1 to 10 micron.
Device the most according to claim 1, the wherein said first micro-pattern of electric conductivity be characterised by 0.1 to 200 ohm/ Effective thin layer resistance in square range.
Device the most according to claim 1, wherein said antenna is customized to produce with 902-928MHz frequency-hopping mode work The RFID reader made under 1 watts radiative power can be positioned at 1 with the ultimate range of described device communication, described ultimate range Centimetre in the range of 2 meters.
5. a rfid system, including the device according to claim 1 combined with the first RFID reader, described One RFID reader with the one or more frequencies between 860MHz and 960MHz under the radiant power of 0.2 watt to 5 watt Work, wherein said first RFID reader can be positioned at the scope of 1 centimetre to 2 meters with the ultimate range of described device communication In.
6. a card, including:
Card layer；
Antenna by the carrying of described card layer；And
Wherein said antenna includes the micro-pattern of electric conductivity limiting adjacent apertured conductor, and the micro-pattern of described electric conductivity is formed at least The antenna of frequency of response 915MHz, the micro-pattern of described electric conductivity includes having and is positioned at 0.5 micron of mark to 20 micrometer ranges The interconnection traces of line width, the micro-pattern of wherein said electric conductivity has the thickness less than 2 microns；And the micro-pattern of described electric conductivity It is characterised by the aperture area ratio of at least 80%；Wherein said antenna is customized to produce with 902-928MHz frequency-hopping mode Being operated in the RFID reader under 1 watts radiative power can be with the ultimate range of described card communication.
Card the most according to claim 6, the micro-pattern of wherein said electric conductivity is by the opaque material structure including following metal Becoming, described metal is selected from silver, gold, palladium, platinum, aluminum, copper, nickel, stannum, alloy and combinations thereof.
8., according to the card described in claim 6 or claim 7, the micro-pattern of wherein said electric conductivity has and is positioned at 30 nanometers to 1 Thickness in micrometer range.
CN201180060557.9A 2010-12-16 2011-11-17 Transparency micro-patterning RFID antenna and the goods of assembling transparency micro-patterning RFID antenna CN103262342B (en)
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CN103262342A CN103262342A (en) 2013-08-21
CN103262342B true CN103262342B (en) 2016-08-10
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CN201180060557.9A CN103262342B (en) 2010-12-16 2011-11-17 Transparency micro-patterning RFID antenna and the goods of assembling transparency micro-patterning RFID antenna
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JP (2) JP2014501465A (en)
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2011-11-17 CN CN201180060557.9A patent/CN103262342B/en not_active IP Right Cessation
2011-11-17 US US13/880,180 patent/US8998099B2/en not_active Expired - Fee Related
2011-11-17 JP JP2013544498A patent/JP2014501465A/en active Pending
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