Source: https://patents.google.com/patent/US9339765B2/en
Timestamp: 2018-11-13 19:08:53
Document Index: 528395408

Matched Legal Cases: ['art 236', 'art 236', 'art 237', 'art 237', 'art 232', 'art 232', 'art 233', 'art 233', 'art 236', 'art 236', 'art 236', 'art 237', 'art 237', 'art 237', 'art 232', 'art 232', 'art 232', 'art 233', 'art 233', 'art 233', 'art 236', 'art 236', 'art 237', 'art 237', 'art 232', 'art 232', 'art 233', 'art 233', 'art 236', 'art 236', 'art 237', 'art 237', 'art 232', 'art 232', 'art 233', 'art 233', 'Application No. 101133393', 'Application No. 201280044811', 'Application No. 201280044811']

US9339765B2 - Electrodialysis method and apparatus for passivating scaling species - Google Patents
Electrodialysis method and apparatus for passivating scaling species Download PDF
US9339765B2
US9339765B2 US13234232 US201113234232A US9339765B2 US 9339765 B2 US9339765 B2 US 9339765B2 US 13234232 US13234232 US 13234232 US 201113234232 A US201113234232 A US 201113234232A US 9339765 B2 US9339765 B2 US 9339765B2
scaling species
US13234232
US20130068620A1 (en )
Neil Edwin Moe
In one embodiment, this invention relates to an electrodialysis device comprising an inlet for directing a feed stream into a plurality of first feed paths and a plurality of second feed paths; the feed stream is comprised of a first anionic scaling species and a first cationic scaling species; the first cationic scaling species is transferred from the second feed paths to the first feed paths through a first membrane group, the first anionic scaling species is transferred from the first feed paths to the second feed paths through the first membrane group. In another embodiment, this invention relates to a method for passivating scaling species in an electrodialysis device.
This invention relates to the passivating of scaling species in water.
Water chemistry dominates and limits the design of desalination processes. Most separations are limited by precipitation of slightly soluble compounds such as CaCO3 or CaSO4 rather than by inherent physical characteristics such as osmotic pressure. For example, in desalination of inland brackish water sources, reverse osmosis is typically limited to around 75% water recovery by the presence of small amounts of scaling species such as Ca2+, SO4 2−, and HCO3 −, while osmotic pressure alone would impose a much higher limit of 98% recovery if only Na+ and Cl− were present. The consequences of low water recovery are 1) larger pumps, intakes, outfalls, and pretreatment systems, and 2) larger volumes of reject streams associated with lost water. The first consequence plays out most clearly in thermal desalination of seawater, where most processes run at only 25-35% water recovery and sub-optimum temperature due to scaling species. The second consequence seriously impacts the viability of inland desalination of brackish water.
Accordingly, a need exists for an effective solution to reduce the concentration of scaling species in the desalination process.
In one aspect of the invention an electrodialysis device comprises an inlet for directing a feed stream into a plurality of first feed paths and a plurality of second feed paths; the feed stream is comprised of a first anionic scaling species and a first cationic scaling species; the first cationic scaling species is transferred from the second feed paths to the first feed paths through a first membrane group, the first anionic scaling species is transferred from the first feed paths to the second feed paths through the first membrane group; wherein the concentration of the first anionic scaling species in effluent exiting the first feed paths is less than about 90% of the concentration of the first anionic scaling species in the feed stream at the inlet of the electrodialysis device.
In another aspect, the electrodialysis device further comprises an electrodialysis vessel; a pair of electrodes arranged in the electrodialysis vessel, the pair of electrodes respectively serving as an anode and a cathode; an anode cell unit adjacent the anode, a cathode cell unit adjacent the cathode, and at least one general cell unit arranged between the anode cell unit and the cathode cell unit; the cathode cell unit having a third membrane group comprised of one or more elements, and the general cell unit having a first membrane group comprised of one or more elements, a second membrane group comprised of one or more elements, a first feed path, and a second feed path; the first membrane group comprising an anion exchange membrane and a cation exchange membrane; the first feed path of one of the general cell units is defined by the first membrane group of the general cell unit and the third membrane group of an adjacent cathode cell unit; the first feed path of at least one of the general cell units is defined by the first membrane group of the general cell unit and the second membrane group of an adjacent general cell unit; the second feed path of the one or more general cell units is defined by the first and second membrane groups.
In another aspect of the electrodialysis device, the concentration of the first cationic scaling species in effluent exiting the second feed paths is less than about 90% of the concentration of first cationic scaling species in the feed stream at the inlet of the electrodialysis device.
In another aspect of the electrodialysis, the concentration of the first anionic scaling species in effluent exiting first feed paths is less than about 50% of the concentration of first anionic scaling species in the feed stream at the inlet of the electrodialysis device, wherein the concentration of the first cationic scaling species in effluent exiting the second feed paths is less than about 50% of the concentration of first cationic scaling species in the feed stream at the inlet of the electrodialysis device.
In another aspect of the electrodialysis device, the concentration of the first anionic scaling species in effluent exiting the first feed paths is less than about 20% of the concentration of first anionic scaling species in the feed stream at the inlet of the electrodialysis device, wherein the concentration of the first cationic scaling species in effluent exiting the second feed paths is less than about 20% of the concentration of first cationic scaling species in the feed stream at the inlet of the electrodialysis device.
In another aspect of the electrodialysis device, the first membrane group elements are selected from the group consisting of a monovalent selective anion exchange membrane, a monovalent selective cation exchange membrane, a divalent selective anion exchange membrane, or a divalent selective cation exchange membrane.
In another aspect of the electrodialysis device, the second membrane group is comprised of at least one anion exchange membrane element or at least one cation exchange membrane element.
In another aspect of the electrodialysis device, the third membrane group is comprised of at least one anion exchange membrane element or at least one cation exchange membrane element.
In another aspect of the electrodialysis device, the first cationic scaling species is selected from the group consisting of Mg2+, Ca2+, Sr2+, and Ba2+, and the first anionic scaling species is selected from the group consisting of SO4 2−, HCO3 −, CO3 2−, OH−, F−, PO4 3−, HPO4 2−, and H2PO4 −.
In another aspect of the electrodialysis device, the first feed paths and the second feed paths are in flow communication with a desalination plant intake, the contents of the first feed paths and the second feed paths are processed separately in the desalination plant.
In another aspect, the electrodialysis device further comprises at least two electrodialysis vessels, each vessel comprising a pair of electrodes, the pair of electrodes respectively serving as an anode and a cathode; an anode cell unit adjacent the anode, a cathode cell unit adjacent the cathode, and at least one general cell unit arranged between the anode cell unit and the cathode cell unit; the anode cell unit, the cathode cell unit, and the at least one general cell unit spanning the electrodialysis vessels; the cathode cell unit having a third membrane group comprised of one or more elements, and the general cell unit having a first membrane group comprised of one or more elements, a second membrane group comprised of one or more elements, a first feed path, and a second feed path; the first membrane group comprising an anion exchange membrane and a cation exchange membrane; the first feed path of one of the general cell units is defined by the first membrane group of the general cell unit and the third membrane group of an adjacent cathode cell unit; the first feed path of at least one of the general cell units is defined by the first membrane group of the general cell unit and the second membrane group of an adjacent general cell unit; the second feed path of the one or more general cell units is defined by the first and second membrane groups.
In another aspect, the electrodialysis device of claim 1 further comprises one or more electrodialysis vessels having more than one hydraulic stage, each of the vessels comprising a pair of electrodes, the pair of electrodes respectively serving as an anode and a cathode; the cathode cell unit having a third membrane group comprised of one or more elements, and the general cell unit having a first membrane group comprised of one or more elements, a second membrane group comprised of one or more elements, a first feed path, and a second feed path; the general cell unit, the first and second membrane groups, and the first and second feed paths each have a first and second part; the first membrane group comprising an anion exchange membrane and a cation exchange membrane; the first feed path of the one or more general cell units is at least partially defined by the first membrane group; the second feed path of the one or more general cell units is at least partially defined by the first membrane group and the second membrane group.
In yet another aspect of the invention, a method for passivating scaling species comprises passing a direct current through a pair of electrodes in an electrodialysis device having a first feed path and a second feed path, so as to energize the pair of electrodes respectively as a cathode and an anode; supplying a feed stream comprised of a first anionic scaling species and a first cationic scaling species to the first feed path and the second feed path; the first feed path and the second feed path are separated by a first membrane group; and transferring the first cationic scaling species from the second feed path to the first feed path through the first membrane group.
In another aspect, the method further comprises transferring the first anionic scaling species from the first feed path to the second feed path through the first membrane group; wherein the electrolysis device further comprising one or more electrodialysis vessels, each of the electrodialysis vessels containing the anode and cathode; an anode cell unit is adjacent the anode, a cathode cell unit is adjacent the cathode, and at least one general cell unit is arranged between the anode cell unit and cathode cell unit; the cathode cell unit having a third membrane group comprised of one or more elements, and the general cell units having a first membrane group comprised of one or more elements, a second membrane group comprised of one or more elements, the first feed path, and the second feed path; the first membrane group comprising an anion exchange membrane and a cation exchange membrane; the first feed path of the one or more general cell units is at least partially defined by the first membrane group; the second feed path of the one or more general cell units is at least partially defined by the first and second membrane groups.
In another aspect, the method further comprises removing the effluent from the first and second feed paths; wherein the concentration of the first anionic scaling species in effluent removed from the first feed path is less than about 90% of the concentration of first anionic scaling species in the feed stream entering the first feed path.
In another aspect of the method, the second membrane groups are comprised of at least one anion exchange membrane or at least one cation exchange membrane.
In another aspect of the method, the third membrane groups are comprised of at least one anion exchange membrane or at least one cation exchange membrane.
In another aspect, the method further comprising directing the effluent from the first and second feed paths to a desalination plant, the contents of the first feed path are processed separately from the contents of the second feed path.
In another aspect of the method, the electrodialysis device is further comprised of two or more electrodialysis vessels, each of the electrodialysis vessels having an anode and cathode; the anode cell unit, the cathode cell unit, and the one or more general cell units span the two or more electrodialysis vessels.
In another aspect of the method, the first cationic scaling species is selected from the group consisting of Mg2+, Ca2+, Sr2+, and Ba2+, and the first anionic scaling species is selected from the group consisting of SO4 2−, HCO3 −, CO3 2−, OH−, F−, PO4 3−, HPO4 2−, and H2PO4 −.
FIG. 1 schematically illustrates the electrodialysis device according to a first embodiment of the invention;
FIG. 2 schematically illustrates the electrodialysis device according to a second embodiment of the invention;
FIG. 3 schematically illustrates the electrodialysis device according to a third embodiment of the invention;
FIG. 4 schematically illustrates the electrodialysis device according to a fourth embodiment of the invention;
FIG. 5 schematically illustrates the electrodialysis device according to a fifth embodiment of the invention;
FIG. 6 schematically illustrates the electrodialysis device according to a sixth embodiment of the invention;
FIG. 7a schematically illustrates the electrodialysis device according to a seventh embodiment of the invention; and
FIG. 7b schematically illustrates the electrodialysis device according to an eighth embodiment of the invention.
FIG. 7c schematically illustrates the electrodialysis device according to a ninth embodiment of the invention.
FIG. 7d schematically illustrates the electrodialysis device according to a tenth embodiment of the invention.
FIG. 8 is a block diagram illustrating the use of the electrodialysis device according to an embodiment of the invention.
FIG. 9 is a block diagram illustrating the use of the electrodialysis device according to an embodiment of the invention.
Referring to FIG. 1, a first embodiment of the electrodialysis device 2 for passivating scaling species, such as scaling species selected from the group consisting of CaSO4, CaCO3, Mg(OH)2, CaF2, SrSO4, BaSO4, and Ca3(PO4)2, includes a pair of electrodes respectively acting as an anode 21 and a cathode 22, a cathode cell unit 25 adjacent the cathode 22, an anode cell unit 26 adjacent the anode 21, at least one general cell unit 23 between the anode cell unit 26 and cathode cell unit 25, and a vessel 24 for housing the anode 21, cathode 22, cathode cell unit 25, anode cell unit 26, and the at least one general cell unit 23 therein. The anode 21 and cathode 22 respectively connect to an anode and a cathode of a DC or pulsed power supply. A person having ordinary skill in the art understands that in some embodiments, cathode 22 has an optional cathode guard membrane and anode 21 has an optional anode guard membrane. The optional cathode and anode guard membranes form guard channels adjacent to the anode 21 and cathode 22. In one embodiment, the optional anode and cathode guard membranes are cation exchange membranes.
The vessel 24 includes at least one inlet 240 for inducing feed streams to flow through the electrodialysis device 2, and at least one first feed path outlet 242, at least one second feed path outlet 243, a third feed path outlet 241, and a fourth feed path outlet 244 respectively. The cathode cell unit 25 has a third feed path 235 and a third membrane group 231 comprised of one or more elements. The anode cell unit 26 is comprised of a fourth feed path 238. The general cell unit 23 is comprised of a first feed path 236, a second feed path 237, a first membrane group 232 comprised of one or more elements, and a second membrane group 233 comprised of one or more elements.
In the cathode cell unit 25, the third membrane group 231 is arranged between the cathode 22 and an adjacent general cell unit 23. The third membrane group 231 and cathode 22 define the third feed path 235 having a third feed path outlet 241. In the anode cell unit 26, the fourth feed path 238 having a fourth feed path outlet 244 is defined between an adjacent general cell unit 23 and the anode 21.
In the general cell unit 23, the second membrane group 233 is located on the anode side of general cell unit 23 and a first membrane group 232 is located on the cathode side of the general cell unit 23. The second membrane group 233 and first membrane group 232 define the second feed path 237 having a second feed path outlet 242. The first membrane group 232 and adjacent cell unit on the cathode side of general cell unit 23 define the first feed path 236 having a first feed path outlet 242. Therefore, when progressing from the anode side of the general cell unit 23 to the cathode side of general cell unit 23, the general cell unit 23 is comprised of a second membrane group 233, second feed path 237, first membrane group 232, and first feed path 236. In some embodiments of general cell unit 23, the adjacent cell unit on the cathode side of general cell unit 23 is cathode cell unit 25. In other embodiments, the adjacent cell unit on the cathode side of general cell unit 23 is another general cell unit 23.
In the embodiment shown in FIG. 1, a feed stream is provided to the inlet 240 of the electrodialysis device 2 containing X+, Y−, S+, and T−, X+ and Y− represent non-scaling cations and anions, S+ represents a first cationic scaling species, and T− represents a first anionic scaling species. The elements in the third membrane group 231 are X-selective anion exchange membranes. The elements in the second membrane group 233 are Y-selective anion exchange membranes. The first membrane group 232 is comprised of a T-selective anion exchange membrane element and a S-selective cation exchange membrane element. In FIG. 1, the T-selective anion exchange membrane is placed before the S-selective cation exchange membrane. However, the functionality will not change if the S-selective cation exchange membrane is placed before the T-selective anion exchange membrane. Accordingly, it is contemplated that in some embodiments, the T-selective anion exchange membrane is placed before the S-selective cation exchange membrane in the first membrane group 232.
When a direct current from the power supply flows through electrodialysis device 2 while the S+ and T− cationic and anionic scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (T−) is transferred from the first feed path 236 to the second feed path 237 through the first membrane group 232, the first cationic scaling species (S+) is transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, the anionic non-scaling species Y− are transferred from the second feed path 237 to the fourth feed path 238 through the second membrane group 233. Lastly, the cationic non-scaling species X+ are transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231.
It is contemplated that the cationic scaling species can be selected from the group consisting of Mg2+, Ca2+, Sr2+, and Ba2+, and the anionic scaling species can be selected from the group consisting of SO4 2−, HCO3 −, CO3 2−, OH−, F−, PO4 3−, HPO4 2−, and H2PO4 −.
In one embodiment, the concentration of first anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 90% of the concentration of first anionic scaling species in the feed stream 242 at the inlet of electrodialysis device 2. The concentration of first cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 90% of the concentration of first cationic scaling species in the feed stream 240 at the inlet of electrodialysis device 2.
In another embodiment, the concentration of first anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 50% of the concentration of first anionic scaling species in the feed stream at the inlet of electrodialysis device 2. The concentration of first cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 50% of the concentration of first cationic scaling species in the feed stream at the inlet of electrodialysis device 2.
In another embodiment, the concentration of first anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 20% of the concentration of first anionic scaling species in the feed stream at the inlet of electrodialysis device 2. The concentration of first cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 20% of the concentration of first cationic scaling species in the feed stream at the inlet of electrodialysis device 2.
Further, it is contemplated that electrodialysis device 2 may passivate two scaling species within a feed stream, such as is shown below in FIG. 5. Accordingly, in such embodiments, the concentration of second anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 90% of the concentration of second anionic scaling species in the feed stream 242 at the inlet of electrodialysis device 2. The concentration of second cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 90% of the concentration of second cationic scaling species in the feed stream 240 at the inlet of electrodialysis device 2.
In another embodiment in which electrodialysis device 2 passivates two scaling species within a feed stream, the concentration of second anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 50% of the concentration of second anionic scaling species in the feed stream at the inlet of electrodialysis device 2. The concentration of second cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 50% of the concentration of second cationic scaling species in the feed stream at the inlet of electrodialysis device 2.
In another embodiment in which electrodialysis device 2 passivates two scaling species within a feed stream, the concentration of second anionic scaling species in effluent exiting electrodialysis device 2 at the first feed path outlet 242 is less than about 20% of the concentration of second anionic scaling species in the feed stream at the inlet of electrodialysis device 2. The concentration of second cationic scaling species in effluent exiting electrodialysis device 2 at the second feed path outlet 243 is less than about 20% of the concentration of second cationic scaling species in the feed stream at the inlet of electrodialysis device 2.
Further, it is contemplated that in some embodiments, all or a portion of the effluent from the first feed path 236 may be fed back into the first feed paths 236 for additional processing until the concentration of an anionic scaling species of interest in the effluent is below a predetermined level. Additionally, it is contemplated that in some embodiments, all or a portion of the effluent from the second feed path 237 may be fed back into the second feed paths 237 for additional processing until the concentration of a cationic scaling species of interest in the effluent is below a predetermined level.
Additionally, it is contemplated that the effluent from the third and fourth feed paths 235 and 238 are returned to the feed stream 240 of electrodialysis device 2 or sent to a drain.
Since the first anionic scaling species (T−) and first cationic scaling species (S+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlet 242 and second feed path outlet 243, the scaling species are passivated and no longer present a scaling risk. Accordingly, the effluent from the first feed path outlet 242 and second feed path outlet 243 can be provided to a desalination plant where the effluents can be processed separately to high recovery levels.
Referring to FIG. 2, in this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing X+, Y−, S+, and T−. X+ and Y− represent non-scaling species, S+ represents a first cationic scaling species and T− represents a first anionic scaling species. As can be seen, electrodialysis device 2 contains an anode cell unit 26, a cathode cell unit 25, a first general cell unit 23, and a second general cell unit 23′. While two general cell units 23 and 23′ are shown in this embodiment, it is contemplated that other embodiment can contain more than two general cell units.
The elements in the second membrane groups 233 and 233′ are Y-selective anion exchange membranes. The first membrane group 232 and 232′ are comprised of a T-selective anion exchange membrane and an S-selective cation exchange membrane. The third membrane group 231 is comprised of X-selective cation exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the S+ and T− scaling species are flowing through the first feed paths 236 and 236′, and the second feed paths 237 and 237′, the first anionic scaling species (T−) is transferred from the first feed paths 236 and 236′ to the second feed path 237 and 237′ through the first membrane groups 232 and 232′, the first cationic scaling species (S+) is transferred from the second feed paths 237 and 237′ to the first feed path 236 and 236′ through the first membrane groups 232 and 232′. Further, the cationic non-scaling species X+ is transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231. Lastly, the anionic non-scaling species Y− is transferred from the second feed paths 237 and 237′ to the first feed path 236′ and fourth feed path 238.
Since the first anionic scaling species (T−) and first cationic scaling species (S+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlets 242 and 242′ and the second feed path outlets 243 and 243′, the scaling species are no longer a scaling risk. Accordingly, in some embodiments, the effluent from the first feed path outlets 242 and 242′, and second feed path outlet 243 and 243′ can be provided to a desalination plant where the effluents can be processed separately to high recovery.
In other embodiments, the first feed path outlets (e.g. 242 and 242′) can be merged into a combined first feed paths outlet, and the second feed path outlets (e.g. 243 and 243′) can be merged into a combined second feed paths outlet. Accordingly, the effluent from the first and second combined feed paths outlets can be provided to a desalination plant where the effluents can be processed separately to high recovery.
Referring to FIG. 3, in this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, and HCO3 −. In this embodiment, Ca2+ is the first cationic scaling species and HCO3 − is the first anionic scaling species. The elements in the second membrane group 233 are monovalent Cl− selective anion exchange membranes. The elements in the first membrane group 232 are monovalent HCO3 − selective anion exchange and divalent Ca2+ selective cation exchange membranes. The third membrane group 231 is comprised of monovalent Na+ selective anion exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (HCO3 −) is transferred from the first feed path 236 to the second path 237 through the first membrane group 232, and the first cationic scaling species (Ca2+) is transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, anionic non-scaling species Cl− is transferred from the second flow path 237 to the fourth flow path 238 through the second membrane group 233, and the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231.
Since the first anionic scaling species (HCO3 −) and first cationic scaling species (Ca2+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlet 242 and second feed path outlet 243, the scaling species are no longer a scaling risk. Accordingly, the effluent from the first feed path outlet 242 and second feed path outlet 243 can be provided to a desalination plant where the effluents can be processed separately to high recovery.
Referring to FIG. 4, in this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, and SO4 2−. In this embodiment, Ca2+ is the first cationic scaling species and SO4 2− is the first anionic scaling species. The elements comprising the second membrane group 233 are monovalent Cl− selective anion exchange membranes. The elements in the first membrane group 232 are divalent SO4 2− selective anion exchange and divalent Ca2+ selective cation exchange membrane elements.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (SO4 2−) is transferred from the first feed path 236 to the second feed path 237 through the first membrane group 232, the first cationic scaling species (Ca2+) is transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, anionic non-scaling species Cl− is transferred from the second feed path 237 to the fourth feed path 238 through the second membrane group 233, and the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231.
Since the first anionic scaling species (SO4 2−) and first cationic scaling species (Ca2+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlet 242 and second feed path outlet 243, the scaling species are no longer a scaling risk. Accordingly, the effluent from the first feed path outlet 242 and second feed path outlet 243 can be provided to a desalination plant where the effluents can be processed separately to high recovery.
Referring to FIG. 5, in this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, HCO3 −, and SO4 2−. In this embodiment, Ca2+ is the first cationic scaling species and SO4 2− is the first anionic scaling species. Further, Ca2+ is the second cationic scaling species and HCO3 − is the second anionic scaling species. The elements in second membrane group 233 are monovalent Cl− selective anion exchange membranes. The elements in the first membrane group 232 are monovalent HCO3 − selective anion exchange, divalent SO4 2− selective anion exchange, and divalent Ca2+ selective cation exchange membranes. The elements in the third membrane group 231 are monovalent Na+ selective cation exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (SO4 2−) and second anionic scaling species (HCO3 −) are transferred from the first feed path 236 to the second feed path 237 through the first membrane group 232, the first and second cationic scaling species (Ca2+) are transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, anionic non-scaling species Cl− is transferred from the second feed path 237 to the fourth feed path 238 through the second membrane group 233. Also, the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path through the third membrane group 231.
Since the first anionic scaling species (SO4 2−) and second anionic scaling species (HCO3 −), and the first and second cationic scaling species (Ca2+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlet 242 and second feed path outlet 243, the scaling species are no longer a scaling risk. Accordingly, the effluent from the first feed path outlet 242 and second feed path outlet 243 can be provided to a desalination plant where the effluents can be processed separately to high recovery.
Accordingly, it is contemplated that in other embodiments, the cationic scaling species can be selected from the group consisting of Mg2+, Ca2+, Sr2+, and Ba2+, and the anionic scaling species can be selected from the group consisting of SO4 2−, HCO3 −, CO3 2−, OH−, F−, PO4 3−, HPO4 2−, and H2PO4 −.
Referring to FIG. 6, it is contemplated that some embodiments of electrodialysis device 2 may have multiple electrodialysis vessels, or electrical stages, 24 a, 24 b, and 24 c connected in series. In such embodiments, the one or more general cell units 23, anode cell unit 26, cathode cell unit 25, the elements of the first, second, and third membrane groups 232, 231, and 233, and the first, second, third, and fourth feed paths 236, 237, 235, and 238 are divided between electrical stages 24 a, 24 b, and 24 c. Each electrical stage 24 a, 24 b, and 24 c has an anode 21 a, 21 b, and 21 c, and a cathode 22 a, 22 b, and 22 c.
In this embodiment, three electrical stages are shown, but it is contemplated that a person having ordinary skill in the art can choose to use a different number of electrical stages, such as two or more. Further, in this embodiment, each electrical stage is shown as having only one membrane element of each membrane group. However, a person having ordinary skill in the art can choose to use a different number of membrane elements in each electrical stage.
Referring to FIGS. 7a-d , it is contemplated that some embodiments of electrodialysis device 2 may have multiple hydraulic stages. Accordingly, in such embodiments, the one or more general cell units 23 span multiple hydraulic stages. Therefore, the elements of the first and second membrane groups 232 and 233, and the first and second feed paths 236 and 237 also span multiple hydraulic stages.
In the embodiment shown in FIG. 7a , general cell unit 23 is divided into a first stage hydraulic stage 23 a and a second hydraulic stage 23 b; the first feed path 236 is divided up into a first part 236 a and a second part 236 b; the second feed path 237 is divided up into a first part 237 a and a second part 237 b; the first membrane group 232 is divided up into a first part 232 a and a second part 232 b; and the second membrane group 233 is divided up into a first part 233 a and a second part 233 b. The first hydraulic stage of the general cell unit 23 a contains the first part of the first feed path 236 a, the first part of the second feed path 237 a, the first part of the first membrane group 232 a, and the first part of the second membrane group 233 a. The second hydraulic stage of the general cell unit 23 b contains the second part of the first feed path 236 b, the second part of the second feed path 237 b, the second part of the first membrane group 232 b, and the second part of the second membrane group 233 b.
The first part of first feed path 236 a is defined by the third membrane group 231 of the cathode unit cell 25 and the first part of the first membrane group 232 a, and the second part of the first feed path 236 b is defined by the first part of the second membrane group 233 a and the second part of the first membrane group 232 b. The first part of the second feed path 237 a is defined by the first part of the first membrane group 232 a and the first part of the second membrane group 233 a, and the second part of the second feed path 237 b is defined by the second part of the first membrane group 232 b and the second part of the second membrane group 233 b.
Accordingly, in the general cell unit, the first feed path 236 is at least partially defined by the first membrane group 232, second membrane group 232, and the third membrane group 231 of the cathode cell unit 25. Further, the second feed path 237 is at least partially defined by the first membrane group 232 and second membrane group 233.
In the cathode cell unit 25, the third feed path 235 is defined by the third membrane group 213 and the cathode 22. In the anode cell unit 26, the fourth feed path 238 is defined by the at least part of the second membrane group 233 and the anode 21.
In this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, and HCO3 −. In this embodiment, Ca2+ is the first cationic scaling species and HCO3 − is the first anionic scaling species. The elements in the second membrane group 233 are monovalent Cl− selective anion exchange membranes. The elements in the first membrane group 232 are monovalent HCO3 − selective anion exchange and divalent Ca2+ selective cation exchange membranes. The third membrane group 231 is comprised of monovalent Na+ selective anion exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (HCO3 −) is transferred from the first feed path 236 to the second path 237 through the first membrane group 232, and the first cationic scaling species (Ca2+) is transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, anionic non-scaling species Cl− is transferred from the second flow path 237 to the fourth flow path 238 through the second membrane group 233, anionic non-scaling species Cl− is transferred from the second flow path 237 to the first flow path 233 through the second membrane group 233, and the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231.
In the embodiment shown in FIG. 7b , general cell unit 23 is divided into a first stage hydraulic stage 23 a, a second hydraulic stage 23 b, and a third hydraulic stage 23 c. The first hydraulic stage of the general cell unit 23 a is located between the cathode cell unit 25 and second hydraulic stage of the general cell unit 23 b. The third hydraulic stage of the general cell unit 23 c is located between the anode cell unit 26 and the second hydraulic stage of the general cell unit 23 b.
The first feed path 236 is divided up into a first part 236 a, a second part 236 b, and a third part 236 c; the second feed path 237 is divided up into a first part 237 a, a second part 237 b, and a third part 237 c; the first membrane group 232 is divided up into a first part 232 a, a second part 232 b, and a third part 232 c; and the second membrane group 233 is divided up into a first part 233 a, a second part 233 b, and a third part 233 c.
The first hydraulic stage of the general cell unit 23 a contains the first part of the first feed path 236 a, the first part of the second feed path 237 a, the first part of the first membrane group 232 a, and the first part of the second membrane group 233 a. The second hydraulic stage of the general cell unit 23 b contains the second part of the first feed path 236 b, the second part of the second feed path 237 b, the second part of the first membrane group 232 b, and the second part of the second membrane group 233 b. The third hydraulic stage of the general cell unit 23 c contains the third part of the first feed path 236 c, the third part of the second feed path 237 c, the third part of the first membrane group 232 c, and the third part of the second membrane group 233 c.
The first part of the first feed path 236 a is defined by the third membrane group 231 of the cathode unit cell 25 and the first part of the first membrane group 232 a, the second part of the first feed path 236 b is defined by the first part of the second membrane group 233 a and the second part of the first membrane group 232 b, and the third part of the first feed path 236 c is defined by the second part of the second membrane group 233 b and the third part of the first membrane group 232 c. The first part of the second feed path 237 a is defined by the first part of the first membrane group 232 a and the first part of the second membrane group 233 a, the second part of the second feed path 237 b is defined by the second part of the first membrane group 232 b and the second part of the second membrane group 233 b, the third part of the second feed path 237 c is defined by the third part of the first membrane group 232 c and the third part of the second membrane group 233 c.
In this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, HCO3 −, and SO4 2−. In this embodiment, Ca2+ is the first cationic scaling species and SO4 2− is the first anionic scaling species. Further, Ca2+ is the second cationic scaling species and HCO3 − is the second anionic scaling species. The elements in second membrane group 233 are monovalent Cl− selective anion exchange membranes. The elements in the first membrane group 232 are monovalent HCO3 − selective anion exchange, divalent SO4 2− selective anion exchange, and divalent Ca2+ selective cation exchange membranes. The elements in the third membrane group 231 are monovalent Na+ selective cation exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed path 236 and the second feed path 237, the first anionic scaling species (SO4 2−) and second anionic scaling species (HCO3 −) are transferred from the first feed path 236 to the second feed path 237 through the first membrane group 232, the first and second cationic scaling species (Ca2+) are transferred from the second feed path 237 to the first feed path 236 through the first membrane group 232. Further, anionic non-scaling species Cl− is transferred from the second feed path 237 to the second and fourth feed paths 237 and 238 through the second membrane group 233. Also, the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path through the third membrane group 231.
Further, as is shown in FIGS. 7c and 7d , it is contemplated that some embodiments can have two or more general cell units 23. In the embodiments shown in FIGS. 7c and 7d , in the first general cell unit 23 is divided into a first hydraulic stage 23 a and a second hydraulic stage 23 b. In the first general cell unit 23, first feed path 236 is divided up into a first part 236 a and a second part 236 b; the second feed path 237 is divided up into a first part 237 a and a second part 237 b; the first membrane group 232 is divided up into a first part 232 a and a second part 232 b; and the second membrane group 233 is divided up into a first part 233 a and a second part 233 b.
The first hydraulic stage of the first general cell unit 23 a contains the first part of the first feed path 236 a, the first part of the second feed path 237 a, the first part of the first membrane group 232 a, and the first part of the second membrane group 233 a. The second hydraulic stage of the first general cell unit 23 b contains the second part of the first feed path 236 b, the second part of the second feed path 237 b, the second part of the first membrane group 232 b, and the second part of the second membrane group 233 b.
The second general cell unit 23′ is divided into a first hydraulic stage 23 a′ and a second hydraulic stage 23 b′. In the second general cell unit 23′, first feed path 236′ is divided up into a first part 236 a′ and a second part 236 b′; the second feed path 237′ is divided up into a first part 237 a′ and a second part 237 b′; the first membrane group 232′ is divided up into a first part 232 a′ and a second part 232 b′; and the second membrane group 233′ is divided up into a first part 233 a′ and a second part 233 b′.
The first hydraulic stage of the second general cell unit 23 a′ contains the first part of the first feed path 236 a′, the first part of the second feed path 237 a′, the first part of the first membrane group 232 a′, and the first part of the second membrane group 233 a′. The second hydraulic stage of the second general cell unit 23 b′ contains the second part of the first feed path 236 b′, the second part of the second feed path 237 b′, the second part of the first membrane group 232 b′, and the second part of the second membrane group 233 b′.
In the first general cell unit 23, the first part of first feed path 236 a is defined by the third membrane group 231 of the cathode unit cell 25 and the first part of the first membrane group 232 a situated in the first hydraulic stage of the first general cell unit 23 a, and the second part of the first feed path 236 b is defined by the second part of the first membrane group 232 b situated in the second hydraulic stage of the first general cell unit 23 b and the first part of the second membrane group 233 a′ situated in the first stage of the second general cell unit 23 b. The first part of the second feed path 237 a is defined by the first part of the first membrane group 232 a situated in the first hydraulic stage of the of the first general cell unit 23 a and the first part of the second membrane group 233 a situated in the first hydraulic stage of the first general cell unit 23 a, and the second part of the second feed path 237 b is defined by the second part of the first membrane group 232 b situated in the second hydraulic stage of the first general cell unit 23 b and the second part of the second membrane group 233 b situated in the second hydraulic stage of the first general cell unit 23 b.
Accordingly, in the first general cell unit 23, the first feed path 236 is at least partially defined by one or more elements of the first membrane group 232 of the first general cell unit 23, the second membrane group 233′ of the second general cell unit 23′, and the third membrane group 231 of the cathode cell unit 25. Further, the second feed path 237 is at least partially defined by one or more elements of the first membrane group 232 and second membrane group 233 of the first general cell unit 23.
In this embodiment, only the first and second general cell units 23 and 23′ are present. However, it is contemplated that in embodiments having a larger number of general cell units (e.g. seven), the first feed path of the first general cell unit would be at least partially defined by one or more elements of the first membrane group of the first general cell unit, the second membrane group of the highest order general cell unit (e.g. seventh), and the third membrane group of the cathode cell unit.
Turning to the second general cell unit 23′, the first part of first feed path 236 a′ is defined by the first part of the second membrane group 233 a situated in the first hydraulic stage of the first general cell unit 23 a and the first part of the first membrane group 232 a′ situated in the first hydraulic stage of the second general cell unit 23 a′. The second part of the first feed path 236 b′ is defined by the second part of the second membrane group 233 b situated in the second hydraulic stage of the first general cell unit 23 b and the second part of the first membrane group 232 b′ situated in the second hydraulic stage of the second general cell unit 23 b′. The first part of the second feed path 237 a′ is defined by the first part of the first membrane group 232 a′ situated in the first hydraulic stage of the second general cell unit 23 a′ and the first part of the second membrane group 233 a′ situated in the first hydraulic stage of the second general cell unit 23 a′. The second part of the second feed path 237 b′ is defined by the second part of the first membrane group 232 b′ situated in the second hydraulic stage of the second general cell unit 23 b′ and the second part of the second membrane group 233 b′ situated in the second hydraulic stage of the second general cell unit 23 b′.
Accordingly, in the second general cell unit 23′, the first feed path 236′ is at least partially defined by one or more elements of the first membrane group 232′ of the second general cell unit 23′ and the second membrane group 233 of the first general cell unit 23. Further, the second feed path 237′ is at least partially defined by one or more elements of the first membrane group 232′ and second membrane group 233′ of the second general cell unit 23′.
In the cathode cell unit 25, the third feed path 235 is defined by the third membrane group 231 and the cathode 22. In the anode cell unit 26, the fourth feed path 238 is defined by the second membrane group 233′ of the second general cell unit 23′ and the anode 21. In embodiments having more than two general cell units, the fourth feed path 238 is defined by at least part of the second membrane group of the highest order general cell unit and the anode 21.
In this embodiment, a feed stream is provided to the inlet 240 of electrodialysis device 2 containing Na+, Cl−, Ca2+, and HCO3 −. In this embodiment, Ca2+ is the first cationic scaling species and HCO3 − is the first anionic scaling species. The elements in the second membrane groups 233 and 233′ are monovalent Cl− selective anion exchange membranes. The elements in the first membrane groups 232 and 232′ are of monovalent HCO3 − selective anion exchange and divalent Ca2+ selective cation exchange membranes. The third membrane group 231 is comprised of monovalent Na+ selective anion exchange membranes.
When a direct current from the power supply flows through electrodialysis device 2 while the scaling species are flowing through the first feed paths 236 and 236′ and the second feed paths 237 and 237′, the first anionic scaling species (HCO3 −) is transferred from the first feed paths 236 and 236′ to the second paths 237 and 237′ through the first membrane groups 232 and 232′, and the first cationic scaling species (Ca2+) is transferred from the second feed paths 237 and 237′ to the first feed paths 236 and 236′ through the first membrane groups 232 and 232′. Further, anionic non-scaling species (Cl−) is transferred from the second flow path 237 and 237′ to the fourth flow paths 238 and 238′ through the second membrane group 233, anionic non-scaling species Cl− is transferred from the second flow paths 237 and 237′ to the first flow paths 236 and 236′ through the second membrane groups 233 and 233′, and the cationic non-scaling species Na+ is transferred from the first feed path 236 to the third feed path 235 through the third membrane group 231.
Since the first anionic scaling species (HCO3 −) and first cationic scaling species (Ca2+) are located in separate feed path streams when they exit the electrodialysis device 2 in the form of effluent from the first feed path outlets 242 and 242′ and the second feed path outlets 243 and 243′, the scaling species are no longer a scaling risk. Accordingly, the effluent from the first feed path outlets 242 and 242′ and the second feed path outlets 243 and 243′ can be provided to a desalination plant where the effluents can be processed separately to high recovery.
Additionally, it is contemplated that in some embodiments of electrolysis device having multiple first and second feed path outlets, the multiple first feed path outlets (e.g. 242, 242′) can be merged into a combined first feed path outlet 342 and the multiple second feed path outlets e.g. (243, 243′) can be merged into a combined second feed path outlet 343. In other embodiments of electrolysis device having multiple first and second feed path outlets (e.g. 242, 242′, 243, 243′), the outlets are kept separated.
Accordingly, in embodiments containing two or more general cell units 23, it is understood that the second part of the first feed path 236 b of the first general cell unit 23 would be at least partially defined by one or more elements of the second membrane group of the highest order general cell unit.
As can be seen, in FIG. 7c , in the first general cell unit 23, the entirety of the effluent from the first section of the first feed path 236 a flows into the second section of the first feed path 236 b, and the entirety of the effluent from the first section of the second feed path 237 a flows into the second section of the second feed path 237 b. Further, in the second general cell unit 23′, the entirety of the effluent from the first section of the first feed path 236 a′ flows into the second section of the first feed path 236 b′, and the entirety of the effluent from the first section of the second feed path 237 a′ flows into the second section of the second feed path 237 b′.
However, in the embodiment shown in FIG. 7d , the effluent from the first part of the first flow paths of the first and second general units 236 a and 236 a′ is directed into the first flow paths conduit 246 where the effluents are combined and delivered to the second flow paths of the first and second general units 236 b and 236 b′. Further, the effluent from the first part of the first flow paths of the first and second general units 237 a and 237 a′ is directed into the first flow paths conduit 247 where the effluents are combined and delivered to the second flow paths of the first and second general units 237 b and 237 b′. Further, in this embodiment shown in FIGS. 7a-d , the first and second part of each membrane group is shown as having only one membrane element of each membrane group. However, a person having ordinary skill in the art can choose to use a different number of membrane elements in the first and second parts of each membrane group.
Referring to FIGS. 8 and 9, it is contemplated that in some embodiments, electrodialysis device 2 may receive a feed stream through inlet 240 of water from a variety of salt or brackish sources. The feed stream can be comprised of two or more scaling species. The feed stream is directed into first and second feed paths. The electrodialysis device 2 passivates the two or more scaling species by moving the cationic scaling species from the second feed paths to the first feed paths, and moving the anionic scaling species from the first feed paths to the second feed paths. Effluent from the first feed paths is delivered to a desalination plant intake from one or more of the first feed path outlets 242 and effluent from the second feed paths is delivered to the desalination plant intake through one or more of the second feed path outlets 243. It is contemplated that in some embodiments having multiple first and second feed path outlets 242 and 243, the multiple first feed path outlets (e.g. 242, 242′) can be merged into a combined first feed path outlet 342 and the multiple second feed path outlets e.g. (243, 243′) can be merged into a combined second feed path outlet 343. The contents of the first feed paths do not mix with the contents of the second feed paths once they exit electrodialysis device 2. The contents of the first and second feed paths are processed separately in the desalination plant to a high recovery.
Additionally, it is contemplated that this invention is further comprised of a method for passivating a scaling species through the use of the electrodialysis apparatus described above. In one embodiment, the method is comprised of passing a direct current through a pair of electrodes in the electrodialysis device, so as to energize the pair of electrodes respectively as a cathode and an anode, and supplying a feed stream to the one or more inlets of the electrodialysis device. The one or more inlets direct the feed stream to a first feed path and a second feed path. The first feed path and the second feed path are separated by a first membrane group. The feed stream is comprised of at least a first anionic scaling species, a first cationic scaling species, a first anionic non-scaling species, and a first cationic non-scaling species. In some embodiments, the feed stream is comprised of additional scaling and/or non-scaling species.
While travelling down the first and second feed paths, the first cationic scaling species is transferred from the second feed path, through the first membrane group, and into the first feed path. Further, the first anionic scaling species is transferred from the first feed path, through the first membrane group, and into the second feed path.
In some embodiments in which the feed stream contains more than one anionic and cationic scaling species, while travelling down the first and second feed paths, the additional cationic scaling species are transferred from the second feed path, through the first membrane group, and into the first feed path. Further, additional anionic scaling species are transferred from the first feed path, through the first membrane group, and into the second feed path.
The method is further comprised of removing the effluent from the first feed path through a first feed path outlet and removing the effluent from the second feed path through a second feed path outlet. In one embodiment, the first and second feed path outlets direct the effluent to the inlet of a desalination unit where the effluent from the first feed path is processed separately from the effluent from the second feed path.
In one embodiment of the method, the scaling species are selected from the group consisting of CaSO4, CaCO3, Mg(OH)2, CaF2, SrSO4, BaSO4, and Ca3(PO4)2.
In one embodiment, the concentration of the first anionic scaling species in effluent removed from the first feed path is less than about 90% of the concentration of the first anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the first cationic scaling species in effluent removed from the second feed path is less than about 90% of the concentration of first cationic scaling species in the feed stream entering the second feed path.
In another embodiment, the concentration of the first anionic scaling species in effluent removed from the first feed path is less than about 50% of the concentration of the first anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the first cationic scaling species in effluent removed from the second feed path is less than about 50% of the concentration of first cationic scaling species in the feed stream entering the second feed path.
In an additional embodiment, the concentration of the first anionic scaling species in effluent removed from the first feed path is less than about 20% of the concentration of the first anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the first cationic scaling species in effluent removed from the second feed path is less than about 20% of the concentration of first cationic scaling species in the feed stream entering the second feed path.
In one embodiment, the concentration of the first anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 90% of the concentration of the first anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the first cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 90% of the concentration of first cationic scaling species in the feed stream entering the electrodialysis device.
In another embodiment, the concentration of the first anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 50% of the concentration of the first anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the first cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 50% of the concentration of first cationic scaling species in the feed stream entering the electrodialysis device.
In an additional embodiment, the concentration of the first anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 20% of the concentration of the first anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the first cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 20% of the concentration of first cationic scaling species in the feed stream entering the electrodialysis device.
In one embodiment, the concentration of the second anionic scaling species in effluent removed from the first feed path is less than about 90% of the concentration of the second anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the second cationic scaling species in effluent removed from the second feed path is less than about 90% of the concentration of second cationic scaling species in the feed stream entering the second feed path.
In another embodiment, the concentration of the second anionic scaling species in effluent removed from the first feed path is less than about 50% of the concentration of the second anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the second cationic scaling species in effluent removed from the second feed path is less than about 50% of the concentration of second cationic scaling species in the feed stream entering the second feed path.
In an additional embodiment, the concentration of the second anionic scaling species in effluent removed from the first feed path is less than about 20% of the concentration of the second anionic scaling species in the feed stream entering the first feed path. Further, wherein the concentration of the second cationic scaling species in effluent removed from the second feed path is less than about 20% of the concentration of second cationic scaling species in the feed stream entering the second feed path.
In one embodiment, the concentration of the second anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 90% of the concentration of the second anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the second cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 90% of the concentration of second cationic scaling species in the feed stream entering the electrodialysis device.
In another embodiment, the concentration of the second anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 50% of the concentration of the second anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the second cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 50% of the concentration of second cationic scaling species in the feed stream entering the electrodialysis device.
In an additional embodiment, the concentration of the second anionic scaling species in effluent exiting the electrodialysis device through the first feed path outlet is less than about 20% of the concentration of the second anionic scaling species in the feed stream entering the electrodialysis device. Further, wherein the concentration of the second cationic scaling species in effluent exiting the electrodialysis device through the second feed path outlet is less than about 20% of the concentration of second cationic scaling species in the feed stream entering the electrodialysis device.
1. A method of reducing scale imparting ion content of a desalination unit (DSU) feed stream comprising:
a) passing a direct current through a pair of electrodes in an electrolysis device (ED) so as to energize said pair of electrodes as a cathode and an anode respectively;
b) feeding an aqueous stream to said ED, said aqueous stream having an anionic scale imparting species (ASIS), an anionic non-scale imparting species (ANSIS), a cationic scale imparting species (CSIS), and a cationic non scale imparting species (CNSIS) therein, said ASIS being present in a first ASIS concentration and said CSIS being present in a first CSIS concentration;
c) contacting said aqueous stream in said ED along a first feed path and along a second feed path separated by a first membrane group, said second feed path also being in fluid communication with a second membrane, and said first feed path also being in fluid communication with a third membrane group, said first membrane group permitting transfer of ASIS from the first feed path to the second feed path and permitting transfer of CSIS from the second feed path to the first feed path, said second membrane permitting passage of ANSIS therethrough and out of said second feed path, said third membrane permitting passage of CNSIS therethrough and out of said first feed path, whereby after passage of said aqueous stream through said first feed path a first effluent is provided and after passage of said aqueous stream through said second feed path a second effluent is provided, wherein said first effluent has a reduced ASIS concentration compared to said first ASIS concentration and said second effluent has a reduced CSIS concentration compared to said first CSIS concentration; and
d) feeding either or both of said first and second effluents to said DSU as said DSU feed stream, with the proviso that when both said first and second effluents are fed to said DSU, they are fed separately and are not mixed.
2. The method of claim 1, wherein said CSIS is selected from the group consisting of Mg2+, Ca2+, Sr2+, and Ba2+, and said ASIS is selected from the group consisting of SO4 2−, HCO3 −, CO3 2−, OH−, F−, PO4 3−, HPO4 2−, and H2PO4 −.
3. The method of claim 2 wherein said CSIS is Ca2+ and wherein said ASIS is HCO3 −.
4. The method of claim 2 wherein said CSIS is Ca2+ and wherein said ASIS is SO4 2−.
5. The method of claim 2 wherein said CSIS is Ca2+ and wherein said ASIS comprises SO4 2− and HCO3 −.
6. The method as recited in claim 3 wherein said anionic selective exchange membrane is a monovalent HCO3 − selective membrane.
7. The method as recited in claim 3 wherein said cation selective exchange membrane is divalent Ca2+ selective membrane.
8. The method as recited in claim 4 wherein said anionic selective exchange membrane is a monovalent HCO3 − selective membrane.
9. The method as recited in claim 4 wherein said cationic selective exchange membrane is divalent Ca2+ selective membrane.
10. The method of claim 5 wherein said cation selective exchange membrane is divalent Ca2+ selective membrane.
11. The method as recited in claim 5 wherein said anion selective exchange membrane comprises a first membrane component defined by a monovalent HCO3 − membrane and a second membrane component defined by a divalent SO4 2− membrane.
12. The method as recited in claim 1 wherein said first effluent comprises a reduced ASIS concentration of less than about 90% of said first ASIS concentration and said second effluent comprises a reduced CSIS concentration of less than about 90% of said first CSIS concentration.
13. The method as recited in claim 1 wherein said first effluent comprises a reduced ASIS concentration of less than about 50% of said first ASIS concentration and said second effluent comprises a reduced CSIS concentration of less than about 50% of said first CSIS concentration.
14. The method as recited in claim 1 wherein said first effluent comprises a reduced ASIS concentration of less than about 20% of said first ASIS concentration and said second effluent comprises a reduced CSIS concentration of less than about 20% of said CSIS concentration.
US13234232 2011-09-16 2011-09-16 Electrodialysis method and apparatus for passivating scaling species Active 2034-11-27 US9339765B2 (en)
US13234232 US9339765B2 (en) 2011-09-16 2011-09-16 Electrodialysis method and apparatus for passivating scaling species
JP2014530680A JP6386379B2 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scale yielding species
AU2012309080A AU2012309080C1 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
KR20147006749A KR101892787B1 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
PCT/US2012/052591 WO2013039677A1 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
SG11201400600TA SG11201400600TA (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
CN 201280044811 CN103781534B (en) 2012-08-28 Electrodialysis apparatus and method for scaling passivating species
CA 2847427 CA2847427A1 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
EP20120756059 EP2755745A1 (en) 2011-09-16 2012-08-28 Electrodialysis method and apparatus for passivating scaling species
TW101133393A TWI557079B (en) 2011-09-16 2012-09-12 Electrodialysis method and apparatus for passivating scaling species
US15092112 US9707517B2 (en) 2011-09-16 2016-04-06 Electrodialysis method and apparatus for passivating scaling species
JP2017128163A JP2017164748A (en) 2011-09-16 2017-06-30 Electrodialysis method and apparatus for passivating scaling species
US15092112 Division US9707517B2 (en) 2011-09-16 2016-04-06 Electrodialysis method and apparatus for passivating scaling species
US20130068620A1 true US20130068620A1 (en) 2013-03-21
US9339765B2 true US9339765B2 (en) 2016-05-17
ID=46800371
US13234232 Active 2034-11-27 US9339765B2 (en) 2011-09-16 2011-09-16 Electrodialysis method and apparatus for passivating scaling species
US15092112 Active US9707517B2 (en) 2011-09-16 2016-04-06 Electrodialysis method and apparatus for passivating scaling species
US (2) US9339765B2 (en)
EP (1) EP2755745A1 (en)
JP (2) JP6386379B2 (en)
KR (1) KR101892787B1 (en)
CA (1) CA2847427A1 (en)
WO (1) WO2013039677A1 (en)
CN106795015A (en) 2015-04-07 2017-05-31 苏特沃克技术有限公司 Process and apparatus for multivalent ion desalination
US3933610A (en) 1974-03-30 1976-01-20 Asahi Kasei Kogyo Kabushiki Kaisha Desalination process by improved multistage electrodialysis
US4802966A (en) 1986-04-17 1989-02-07 Kureha Kagaku Kogyo Kabushiki Kaisha Method for treating liquid used for absorbing gaseous sulfur dioxide in the process for desulfurization of combustion exhaust gas
JPH1085755A (en) 1996-09-10 1998-04-07 Hitachi Plant Eng & Constr Co Ltd Desalting method by electrodialyser
US6461491B1 (en) 2000-06-07 2002-10-08 The University Of Chicago Method and apparatus for electrodialysis processing
JP2003190959A (en) 2001-12-28 2003-07-08 Ebara Corp Electric demineralizer
WO2003067082A1 (en) 2002-02-04 2003-08-14 Wader, Llc Disposal of waste fluids
US20040079704A1 (en) 2000-12-12 2004-04-29 Arvid Garde Method and apparatus for isolation of ionic species from a liquid
JP2006021106A (en) 2004-07-07 2006-01-26 Saline Water Conversion Corp Method and apparatus for desalting novel perfect total nf thermal seawater
TW200706233A
WO2007134226A1 (en) 2006-05-12 2007-11-22 Energy Recovery, Inc. Hybrid ro/pro system
WO2008060435A2 (en) 2006-11-09 2008-05-22 Yale University Osmotic heat engine
US7514001B2 (en) 2003-04-14 2009-04-07 Ge Infrastructure, Water & Process Technologies High recovery reverse osmosis process and apparatus
US20090159448A1 (en) 2007-12-25 2009-06-25 General Electric Company Electrolysis device, method, and washer using such a device
US7563370B2 (en) 2000-08-04 2009-07-21 Statkraft Development As Semi-permeable membrane for use in osmosis and method and plant for providing elevated pressure by osmosis to create power
WO2009152148A1 (en) 2008-06-11 2009-12-17 The Regents Of The University Of California Method and system for high recovery water desalting
CN101818180A (en) 2010-04-22 2010-09-01 石家庄开发区德赛化工有限公司 Method for producing vitamin C by elec-trodialysis with bipolar membrane
US20110131994A1 (en) 2009-12-04 2011-06-09 General Electric Company Economical and Sustainable Disposal of Zero Liquid Discharge Salt Byproduct
JP4721323B2 (en) 2004-12-06 2011-07-13 オルガノ株式会社 Method for manufacturing electrodeionization solution producing apparatus and deionized solution
WO2008048656A3 (en) 2006-10-18 2009-04-16 James E Bolton Electroregeneration apparatus and water treatment method
JP5574287B2 (en) * 2009-05-14 2014-08-20 国立大学法人東北大学 Electrodialysis apparatus
Achilli et al., "Power generation with pressure retarded osmosis: An experimental and theoretical investigation", Journal of Membrane Science, vol. 343, (2009), pp. 42-52.
California Coastal Commission, Seawater Desalination and the California Coastal Act, Mar. 2004.
Doyle, Reuters, Salt could shake up world energy supply, Mar. 18, 2008.
Intellectual Property Office Recommendations Letter received Dec. 11, 2015 in Taiwan Patent Application No. 101133393 filed Sep. 16, 2011.
International Search Report and Written Opinion mailed Nov. 2, 2012 for PCT/US2012/052591 filed Aug. 28, 2012.
Leonardo Energy.Org-Reverse Electrodialysis-http://www.leonardo-energy.org/23-reverse-electrodialysis, Jun. 1, 2009.
M.E. Guendouzi et al., "Water activities, osmotic and activity coefficients in aqueous chloride solutions at T = 298.15 K by the hygrometric method", J. Chem. Thermodynamics, 33 (2001) pp. 1059-1072.
Membrane Technology Group-Power Generation by Reverse Electrodialysis-http://mtg.tnw.utwente.nl/teaching/assign/blue, Jun. 1, 2009.
Mickley, "Survey of high-recovery and zero liquid discharge technologies for water utilities", WateReuse Foundation Report (2008) pp. 15-29.
Mickley, "Treatment of Concentrate", Desalination and Water Purification Research and Development Program Report No. 155, (2009).
Olsson et al, "Salinity Gradient Power: Utilizing Vapor Pressure Differences", Science, vol. 206, (Oct. 26, 1979), pp. 452-454.
Post et al., "Salinity-gradient power: evaluation of pressure-retarded osmosis and reverse electrodialysis", Journal of Membrane Science, vol. 288, (2007), pp. 218-230.
R.C. Weast, ed., CRC Handbook of Chemistry and Physics, 69th Edition (1988-1989), CRC Press, Inc., Boca Raton, Florida, pp. D-253-254.
Sanitation Districts of Los Angeles County-Joint Water Pollution Control Plant-http://www.lacsd.org/about/wastewater-facilities/jwpcp/default.asp, Oct. 14, 2010.
Skilhagen et al., "Osmotic power-power production based on the osmotic pressure difference between waters with varying salt gradients", Desalination, vol. 220, (2008), pp. 476-482.
Statkraft-Informational Material-Osmotic Power-A Huge Renewable Energy Source (2006).
Statkraft-PowerPoint Presentation from Apr. 2007-Osmotic Power-A New Renewable Energy Source.
Thorsen et al., "The potential for power production from salinity gradients by pressure retarded osmosis", Journal of Membrane Science, vol. 335, (2009), pp. 103-110.
Unofficial English translation of Chinese Office Action issued in connection with corresponding CN Application No. 201280044811.0 on Feb. 5, 2015.
Unofficial English translation of Office Action issued in connection with corresponding CN Application No. 201280044811.0 on Feb. 5, 2015.
Watson et al., "Desalination and Water Purification Research and Development Program Report No. 72", Desalting Handbook for Planners 3rd Edition, Jul. 2003.
Wikipedia-article regarding Reverse Electrodialysis-http://en.wikipedia.org/wiki/Reverse-electrodialysis (2009).
Wikipedia-article regarding Reverse Osmosis-http://en.wikipedia.org/wiki/Reverse-Osmosis (2009).
JP2014530091A (en) 2014-11-17 application
CN103781534A (en) 2014-05-07 application
CA2847427A1 (en) 2013-03-21 application
US20130068620A1 (en) 2013-03-21 application
EP2755745A1 (en) 2014-07-23 application
JP6386379B2 (en) 2018-09-05 grant
KR20140074896A (en) 2014-06-18 application
KR101892787B1 (en) 2018-08-28 grant
US9707517B2 (en) 2017-07-18 grant
JP2017164748A (en) 2017-09-21 application
US20160214061A1 (en) 2016-07-28 application
WO2013039677A1 (en) 2013-03-21 application
Malaeb et al. 2011 Reverse osmosis technology for water treatment: state of the art review
Al-Zoubi et al. 2007 Rejection and modelling of sulphate and potassium salts by nanofiltration membranes: neural network and Spiegler–Kedem model
Strathmann 1992 Design and cost estimates
WO2004013048A2 (en) 2004-02-12 Production of purified water and high value chemicals from salt water
Macedonio et al. 2008 Pressure-driven membrane operations and membrane distillation technology integration for water purification
Madaeni et al. 2006 Application of taguchi method in the optimization of wastewater treatment using spiral-wound reverse osmosis element
JP2009047012A (en) 2009-03-05 Osmotic pressure power generation system
JP2008161797A (en) 2008-07-17 Operation method of freshwater production apparatus, and freshwater production apparatus
US20110036774A1 (en) 2011-02-17 Spiral Wound Membrane Module for Forward Osmotic Use
Macedonio et al. 2011 Wind-aided intensified evaporation (WAIV) and membrane crystallizer (MCr) integrated brackish water desalination process: advantages and drawbacks
JP2008307487A (en) 2008-12-25 Desalting device
EP0709130A1 (en) 1996-05-01 Apparatus and method for multistage reverse osmosis separation
Hung et al. 2009 Prediction of boron transport through seawater reverse osmosis membranes using solution–diffusion model
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MOE, NEIL EDWIN;REEL/FRAME:027452/0405