Source: https://govt.westlaw.com/nycrr/Document/I4eacc3f8cd1711dda432a117e6e0f345?viewType=FullText&originationContext=documenttoc&transitionType=CategoryPageItem&contextData=(sc.Default)
Timestamp: 2019-11-20 17:53:19
Document Index: 431963887

Matched Legal Cases: ['arts 372', 'art 761', 'art 761', 'arts 373', 'arts 373', 'arts 373', 'arts 370']

6 CRR-NY 371.4NY-CRR
6 CRR-NY 371.4
371.4 Lists of hazardous wastes.
(1) A solid waste is a hazardous waste if it is listed in this section, unless it has been excluded from this list under section 370.3(a) and (b) of this Title.
Although the names used for chemicals in this list include common names, trade names and specific isomer names under various chemical naming systems, where any one of these previous names are used, all other equivalent names shall be considered to be listed.
(2) The commissioner will indicate the basis for listing the classes or types of wastes listed in this section by employing one or more of the following hazard codes:
Appendix 22, infra, identifies the constituent which caused the commissioner to list the waste as a toxicity characteristic waste (E) or toxic waste (T) in subdivisions (b) and (c) of this section.
(3) Each hazardous waste listed in this section is assigned an EPA hazardous waste number which precedes the name of the waste. This number must be used in complying with the notification requirements of section 3010 of the Resource Conservation and Recovery Act and certain recordkeeping and reporting requirements under Parts 372, 373 and 376 (see section 370.1[e] of this Title).
(4) The following hazardous wastes listed in subdivisions (b) and (c) of this section are subject to the exclusion limits for acutely hazardous waste established in section 371.1(f) of this Part: EPA hazardous waste numbers F020, F021, F022, F023, F026 and F027.
(1) The following solid wastes are listed hazardous wastes from nonspecific sources unless they are excluded under section 370.3(a) and (c) of this Title and listed in Appendix 24, infra:
F001 The following spent halogenated solvents used in degreasing: tetrachloroethylene, trichloroethylene, methylene chloride, 1,1, 1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, total of 10 percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F002, F004 and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (T)
F002 The following spent halogenated solvents: tetrachloro-ethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro-1,2,2- trifluoroethane, orthodichlorobenzene, trichlorofluoromethane and 1,1,2-trichloroethane; all spent solvent mixtures/blends containing, before use, a total of 10 percent or more (by volume) of one or more of the above halogenated solvents or those listed in F001, F004 or F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (T)
F003 The following spent nonhalogenated solvents: xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, and methanol; all spent solvent mixtures/blends containing, before use, only the above spent nonhalogenated solvents; and all spent solvent mixtures/blends containing, before use, one or more of the above nonhalogenated solvents, and a total of 10 percent or more (by volume) of one or more of those solvents listed in F001, F002, F004 and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (I)*
F004 The following spent nonhalogenated solvents: cresols and cresylic acid, and nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of 10 percent or more (by volume) of one or more of the above nonhalogenated solvents or those solvents listed in F001, F002 and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (T)
F005 The following spent nonhalogenated solvents: toluene, methyl ethyl ketone, carbon disulfide, isobutanol, and pyridine, benzene, 2-ethoxyethanol, and 2-nitropropane; all spent solvent mixtures/blends containing, before use, a total of 10 percent or more (by volume) of one or more of the above nonhalogenated solvents or those solvents listed in F001, F002 or F004; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (I,T)
F006 Wastewater treatment sludges from electroplating operations, except from the following processes: (1) sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or zinc-aluminum plating on carbon steel; (5) cleaning/stripping associated with tin, zinc and aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum. (T)
F012 Quenching wastewater treatment sludges from metal heat treating operations where cyanides are used in the process. (T)
F02I Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of pentachlorophenol, or of intermediates used to produce its derivatives. (H)
F022 Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tetra-, penta-, or hexachlorobenzenes under alkaline conditions. (H)
F023 Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials on equipment previously used for the production or manufacturing use (as a reactant, chemical intermediate, component in a formulating process) of tri- and tetra-chlorophenols. (This listing does not include wastes from equipment used only for the production or use of hexachlorophene from highly purified 2,4,5-trichlorophenol.) (H)
F024 Process wastes, including but not limited to, distillation residues, heavy ends, tars, and reactor clean-out wastes, from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. (This listing does not include wastewaters, wastewater treatment sludges, spent catalysts, and wastes listed in subdivision [b] or [c] of this section.) (T)
F027 Discarded unused formulations containing tri-, tetra-, or pentachlorophenol or discarded unused formulation containing compounds derived from these chlorophenols. (This listing does not include formulations containing hexachlorophene synthesized from prepurified 2,4,5-trichlorophenol as the sole component.) (H)
F028 Residues resulting from the incineration or thermal treatment of soil contaminated with EPA hazardous waste numbers F020, F021, F022, F023, F026 and F027. (T)
F032 Wastewaters (except those that have not come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that currently use or have previously used chlorophenolic formulations (except potentially cross-contaminated wastes that have had the F032 waste code deleted in accordance with subdivision [f] of this section or potentially cross-contaminated wastes that are otherwise currently regulated as hazardous wastes [i.e., F034 or F035], and where the generator does not resume or initiate use of chlorophenolic formulations). This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol. (T)
F035 Wastewaters (except those that have not come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that use inorganic preservatives containing arsenic or chromium. This listing does not include K001 bottom sediment sludge from the treatment of wastewater frorn wood preserving processes that use creosote and/or pentachlorophenol. (T)
F037 Petroleum refinery primary oil/water/solids separation sludge; any sludge generated from the gravitational separation of oil/ water/solids during the storage or treatment of process wastewaters and oily cooling wastewaters from petroleum refineries. Such sludges include, but are not limited to, those generated in: oil/water/solids separators; tanks and impoundments; ditches and other conveyances; sumps; and stormwater units receiving dry weather flow. Sludge generated in stormwater units that do not receive dry weather flow, sludges generated from non-contact once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges generated in aggressive biological treatment units as defined in subparagraph (2)(ii) of this subdivision (including sludges generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units) and K051 wastes are not included in this listing. This listing does include residuals generated from processing or recycling oil-bearing hazardous secondary materials excluded under section 371.1(e)(1)(xii)( a) of this Part, if those residuals are to be disposed of. (T)
F038 Petroleum refinery secondary (emulsified) oil/water/solids separation sludge; any sludge and/or float generated from the physical and/or chemical separation of oil/water/solids in process wastewaters and oily cooling wastewaters from petroleum refineries. Such wastes include, but are not limited to, all sludges and floats generated in: induced air flotation (IAF) units, tanks and impoundments, and all sludges generated in DAF units. Sludges generated in stormwater units that do not receive dry weather flow, sludges generated from non-contact once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges and floats generated in aggressive biological treatment units as defined in subparagraph (2)(ii) of this subdivision (including sludges and floats generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units) and F037, K048, and K051 wastes are not included in this listing. (T)
F039 Leachate (liquids that have percolated through land disposed wastes) resulting from the disposal of more than one restricted waste classified as hazardous under this section. (Leachate resulting from the disposal of one or more of the following EPA hazardous wastes and no other hazardous waste retains its EPA hazardous waste number(s): F020, F021, F022, F026, F027, and/or F028.) (T)
(2) Listing specific definitions:
(i) For the purposes of the F037 and F038 listings, oil/water/solids is defined as oil and/or water and/or solids.
(a) For the purposes of the F037 and F038 listings, aggressive biological treatment units are defined as units which employ one of the following four treatment methods: activated sludge; trickling filter; rotating biological contactor for the continuous accelerated biological oxidation of wastewaters; or high-rate aeration. High-rate aeration is a system of surface impoundments or tanks, in which intense mechanical aeration is used to completely mix the wastes, enhance biological activity, and:
(1) the units employ a minimum of six hp per million gallons of treatment volume; and
(2) either the hydraulic retention time of the unit is no longer than five days; or
(3) the hydraulic retention time is no longer than 30 days and the unit does not generate a sludge that is a hazardous waste by the toxicity characteristic.
(b) Generators and treatment, storage and disposal facilities have the burden of proving that their sludges are exempt from listing as F037 and F038 wastes under this definition. Generators and treatment, storage and disposal facilities must maintain, in their operating or other onsite records, documents and data sufficient to prove that:
(1) the unit is an aggressive biological treatment unit as defined in this subparagraph; and
(2) the sludges sought to be exempted from the definitions of F037 and/or F038 were actually generated in the aggressive biological treatment unit.
(a) For the purposes of the F037 listing, sludges are considered to be generated at the moment of deposition in the unit, where deposition is defined as at least a temporary cessation of lateral particle movement.
(b) For the purposes of the F038 listing:
(1) sludges are considered to be generated at the moment of deposition in the unit, where deposition is defined as at least a temporary cessation of lateral particle movement; and
(2) floats are considered to be generated at the moment they are formed in the top of the unit.
(c) Hazardous wastes from specific sources. The following solid wastes are listed hazardous waste from specific sources unless excluded under section 370.3(a) and (c) of this Title and listed in Appendix 24, infra:
K001 Bottom sediment sludge from the treatment of wastewaters from wood preserving processes that use creosote and/or pentachlorophenol. (T)
K002 Wastewater treatment sludge from the production of chrome yellow and orange pigments. (T)
K003 Wastewater treatment sludge from the production of molybdate orange pigments. (T)
K004 Wastewater treatment sludge from the production of zinc yellow pigments. (T)
K005 Wastewater treatment sludge from the production of chrome green pigments. (T)
K006 Wastewater treatment sludge from the production of chrome oxide green pigments (anhydrous and hydrated). (T)
K007 Wastewater treatment sludge from the production of iron blue pigments. (T)
K008 Oven residue from the production of chrome oxide green pigments. (T)
K009 Distillation bottoms from the production of acetaldehyde from ethylene. (T)
K010 Distillation side cuts from the production of acetaldehyde from ethylene. (T)
K011 Bottom stream from the wastewater stripper in the production of acrylonitrile. (R,T)
K013 Bottom stream from the acetonitrile column in the production of acrylonitrile. (R,T)
K014 Bottoms from the acetonitrile purification column in the production of acrylonitrile. (T)
K015 Still bottoms from the distillation of benzyl chloride. (T)
K016 Heavy ends or distillation residues from the production of carbon tetrachloride. (T)
K017 Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin. (T)
K018 Heavy ends from the fractionation column in ethyl chloride production. (T)
K019 Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production. (T)
K020 Heavy ends from the distillation of vinyl chloride monomer production. (T)
K021 Aqueous spent antimony catalyst waste from fluoromethanes production. (T)
K022 Distillation bottom tars from the production of phenol/acetone from cumene. (T)
K023 Distillation light ends from the production of phthalic anhydride from naphthalene. (T)
K024 Distillation bottoms from the production of phthalic anhydride from naphthalene. (T)
K025 Distillation bottoms from the production of nitrobenzene by the nitration of benzene. (T)
K026 Stripping still tails from the production of methyl ethyl pyridines. (T)
K027 Centrifuge and distillation residues from toluene diisocyanate production. (R,T)
K028 Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1-trichloethane. (T)
K029 Waste from the product steam stripper in the production of 1,1,1-trichloroethane. (T)
K030 Column bottoms or heavy ends from the combined production of trichloroethylene and perchloroethylene. (T)
K083 Distillation bottoms from aniline production. (T)
K085 Distillation or fractionation column bottoms from the production of chlorobenzenes. (T)
K093 Distillation light ends from the production of phthalic anhydride from ortho-xylene. (T)
K094 Distillation bottoms from the production of phthalic anhydride from ortho-xylene. (T)
K095 Distillation bottoms from the production of 1,1,1-trichloroethane. (T)
K096 Heavy ends from the heavy ends column from the production of 1,1,1-trichloroethane. (T)
K103 Process residues from aniline extraction from the production of aniline. (T)
K104 Combined wastewater streams generated from nitrobenzene/aniline production. (T)
K105 Separated aqueous stream from the reactor product washing step in the production of chlorobenzene. (T)
K107 Column bottoms from product separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. (C,T)
K108 Condensed column overheads from product separation and condensed reactor vent gases from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. (I,T)
K109 Spent filter cartridges from product purification from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. (T)
K110 Condensed column overheads from intermediate separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. (T)
K111 Product washwaters from the production of dinitrotoluene via nitration of toluene. (C,T)
K112 Reaction by-product water from the drying column in the production of toluenediamine via hydrogenation of dinitrotoluene. (T)
K113 Condensed liquid light ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. (T)
K114 Vicinals from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. (T)
K115 Heavy ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. (T)
K116 Organic condensate from the solvent recovery column in the production of toluene diisocyanate via phosgenation of toluenediamine. (T)
K117 Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene. (T)
K118 Spent adsorbent solids from purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. (T)
K136 Still bottoms from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. (T)
K149 Distillation bottoms from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (This waste does not include still bottoms from the distillation of benzyl chloride.) (T)
K150 Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (T)
K151 Wastewater treatment sludges, excluding neutralization and biological sludges, generated during the treatment of wastewaters from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (T)
K158 Bag house dusts and filter/separation solids form the production of carbamates and arbamoyl oximes. (This listing does not apply to wastes generated from the manufacture of 3-iodo-2-propynyl n-butylcarbamate.) (T)
K159 Organics from the treatment of thiocarbamate wastes. (T)
K161 Purification solids (including filtration, evaporation, and centrifugation solids), bag house dust and floor sweepings from the production of dithiocarbamate acids and their salts. (This listing does not include K125 and K126.) (R,T)
K174 Wastewater treatment sludges from the production of ethylene dicloride or vinyl chloride monomer (including sludges that result from commingled ethylene dichloride or vinyl chloride monomer wastewater and other wastewater), unless the sludges meet the following conditions: (i) they are disposed of in a subtitle C or non-hazardous landfill licensed or permitted by the State or Federal government; (ii) they are not otherwise placed on the land prior to final disposal; and (iii) the generator maintains documentation demonstrating that the waste was either disposed of in an on-site landfill or consigned to a transporter or disposal facility that provided a written commitment to dispose of the waste in an off-site landfill. Respondents in any action brought to enforce the requirements of subtitle C must, upon a showing by the government that the respondent managed wastewater treatment sludges from the production of vinyl chloride monomer or ethylene dichloride, demonstrate that they meet the terms of the exclusion set forth above. In doing so, they must provide appropriate documentation (e.g., contracts between the generator and the landfill owner/operator, invoices documenting delivery of waste to landfill, etc.) that the terms of the exclusion were met. (T)
K175 Wastewater treatment sludges from the production of vinyl chloride monomer using mercuric chloride catalyst in an acetylene-based process. (T)
K071 Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used. (T)
K073 Chlorinated hydrocarbon waste from the steps of the diaphragm cell process using graphite anodes in chlorine production. (T)
K106 Wastewater treatment sludges from the mercury cell process in chlorine production. (T)
K031 By-product salts generated in the production of MSMA and cacodylic acid. (T)
K032 Wastewater treatment sludge from the production of chlordane. (T)
K033 Wastewater and scrub water from the chlorination of cyclopentadiene in the production of chlordane. (T)
K034 Filter solids from the filtration of hexachloro-cyclopentadiene in the production of chlordane. (T)
K035 Wastewater treatment sludges generated in the production of creosote. (T)
K036 Still bottoms from toluene reclamation distillation in the production of disulfoton. (T)
K037 Wastewater treatment sludges from the production of disulfoton. (T)
K038 Wastewater from the washing and stripping of phorate production. (T)
K039 Filter cake from the filtration of diethylphos-phorodithioic acid in the production of phorate. (T)
K040 Wastewater treatment sludge from the production of phorate. (T)
K041 Wastewater treatment sludge from the production of toxaphene. (T)
K042 Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production 2,4,5-T. (T)
K043 2,6-Dichlorophenol waste from the production of 2,4-D. (T)
K097 Vacuum stripper discharge from the chlordane chlorinator in the production of chlordane. (T)
K098 Untreated process wastewater from the production of toxaphene. (T)
K099 Untreated wastewater from the production of 2,4-D. (T)
K123 Process wastewater (including supernates, filtrates, and washwaters) from the production of ethylenebisdithiocarbamic acid and its salts. (T)
K124 Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid and its salts. (C,T)
K125 Filtration, evaporation, and centrifugation solids from the production of ethylenebisdithiocarbamic acid and its salts. (T)
K126 Baghouse dust and floor sweepings in milling and packaging operations from the production or formulation of ethylenebisdithiocarbamic acid and its salts. (T)
K131 Wastewater from the reactor and spent sulfuric acid from the acid dryer from the production of methyl bromide. (C,T)
K132 Spent absorbent and wastewater separator solids from the production of methyl bromide. (T)
K176 Baghouse filters from the production of antimony oxide, including filters from the production of intermediates (e.g., antimony metal or crude antimony oxide). (E)
K177 Slag from the production of antimony oxide that is speculatively accumulated or disposed, including slag from the production of intermediates (e.g., antimony metal or crude antimony oxide). (T)
K178 Residues from manufacturing and manufacturing-site storage of ferric chloride from acids formed during the production of titanium dioxide using the chloride-ilmenite process. (T)
K044 Wastewater treatment sludges from the manufacturing and processing of explosives. (R)
K045 Spent carbon from the treatment of wastewater containing explosives. (R)
K046 Wastewater treatment sludges from the manufacturing, formulation and loading of lead-based initiating compounds. (T)
K047 Pink/red water from TNT operations. (R)
K048 Dissolved air flotation (DAF) float from the petroleum refining industry. (T)
K049 Slop oil emulsion solids from the petroleum refining industry. (T)
K050 Heat exchanger bundle cleaning sludge from the petroleum refining industry. (T)
K051 API separator sludge from the petroleum refining industry. (T)
K052 Tank bottoms (leaded) from the petroleum refining industry. (T)
K169 Crude oil storage tank sediment from petroleum refining operations. (T)
K170 Clarified slurry oil tank sediment and/or in-line filter/separation solids from petroleum refining operation. (T)
K171 Spent hydrotreating catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media). (I, T)
K172 Spent hydrorefining catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media). (I, T)
K061 Emission control dust/sludge from the primary production of steel in electric furnaces. (T)
K062 Spent pickle liquor generated by steel finishing operations of facilities within the iron and steel industry (SIC codes 331 and 332). (C,T)
K064 Acid plant blowdown slurry/sludge resulting from the thickening of blowdown slurry from primary copper production. (T)
K065 Surface impoundment solids contained in and dredged from surface impoundments at primary lead smelting facilities. (T)
K066 Sludge from treatment of process wastewater and/or acid plant blowdown from primary zinc production. (T)
K088 Spent potliners from primary aluminum reduction. (T)
K090 Emission control dust or sludge from ferrochromium-silicon production. (T)
K091 Emission control dust or sludge from ferrochromium production. (T)
K069 Emission control dust/sludge from secondary lead smelting, except sludge generated from secondary acid scrubber systems. (T)
K100 Waste leaching solution from acid leaching of emission control dust/sludge from secondary lead smelting. (T)
K084 Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds. (T)
K101 Distillation tar residues from the distillation of aniline-based compounds in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds. (T)
K102 Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds. (T)
Ink formation:
K086 Solvent washes and sludges, caustic washes and sludges, or water washes and sludges from cleaning tubs and equipment used in the formulation of ink from pigments, driers, soaps, and stabilizers containing chromium and lead. (T)
K060 Ammonia still lime sludge from coking operations. (T)
K087 Decanter tank tar sludge from coking operations. (T)
K141 Process residues from the recovery of coal tar, including, but not limited to, collecting sump residues from the production of coke from coal or the recovery of coke by-products produced from coal. This listing does not include K087 (decanter tank tar sludges from coking operations). (T)
K142 Tar storage tank residues from the production of coke from coal or from the recovery of coke by-products produced from coal. (T)
K143 Process residues from the recovery of light oil, including, but not limited to, those generated in stills, decanters, and wash oil recovery units from the recovery of coke by-products produced from coal. (T)
K144 Wastewater sump residues from light oil refining, including, but not limited to, intercepting or contamination sump sludges from the recovery of coke by-products produced from coal. (T)
K145 Residues from naphthalene collection and recovery operations from the recovery of coke by-products produced from coal. (T)
K147 Tar storage tank residues from coal tar refining. (T)
K148 Residues from coal tar distillation, including but not limited to, still bottoms. (T)
(d) Discarded commercial chemical products, off-specification species, container residues, and spill residues thereof. The following materials or items are hazardous wastes if and when they are discarded or intended to be discarded as described in section 371.1(c)(2)(i) of this Part, when they are mixed with waste oil or used oil or other material and applied to the land for dust suppression or road treatment, when they are otherwise applied to the land in lieu of their original intended use or when they are contained in products that are applied to the land in lieu of their original intended use, or when, in lieu of their original intended use, they are produced for use as (or as a component of) a fuel, distributed for use as a fuel, or burned as a fuel:
(1) any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in paragraph (5) or (6) of this subdivision;
(2) any off-specification commercial chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in paragraph (5) or (6) of this subdivision;
(3) any residue remaining in a container or inner liner removed from a container that has been used to hold any commercial chemical product or manufacturing chemical intermediate having the generic names listed in paragraph (5) or (6) of this subdivision, or any residue remaining in a container or inner liner removed from a container that has been used to hold any off-specification chemical product or manufacturing chemical intermediate, which if it met specifications, would have the generic name listed in paragraph (5) or (6) of this subdivision, unless the container is empty as defined in section 371.1(h)(2) of this Part.
Unless the residue is being beneficially used or reused, or legitimately recycled or reclaimed, or being accumulated, stored, transported or treated prior to such use, reuse, recycling or reclamation, EPA and the department consider the residue to be intended for discard, and thus, a hazardous waste. An example of a legitimate reuse of the residue would be where the residue remains in the container and the container is used to hold the same commercial chemical product or manufacturing chemical intermediate it previously held. An example of the discard of the residue would be where the drum is sent to a drum reconditioner who reconditions the drum but discards the residues. All waste resulting from the rinsing or cleansing of the container or inner liner, by a nonaqueous solvent, is a hazardous waste. All waste resulting from the aqueous rinsing or cleansing of the container or inner liner is a hazardous waste unless exempt pursuant to section 371.1(d)(1)(ii)(d)(4).
(4) any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into or on any land or water of any commercial chemical product or manufacturing chemical intermediate having the generic name listed in paragraph (5) or (6) of this subdivision, or any residue or contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or water, of any off-specification chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in paragraph (5) or (6) of this subdivision.
The phrase “commercial chemical product or manufacturing chemical intermediate having the generic name listed in. . .” refers to a chemical substance which is manufactured or formulated for commercial or manufacturing use which consists of the commercially pure grade of the chemical, any technical grades of the chemical that are produced or marketed, and all formulations in which the chemical is the sole active ingredient. It does not refer to a material, such as a manufacturing process waste, that contains any of the substances listed in paragraph (5) or (6). Where a manufacturing process waste is deemed to be a hazardous waste because it contains a substance listed in paragraph (5) or (6), such waste will be listed in either subdivision (b) or (c) of this section, or will be identified as a hazardous waste by the characteristics set forth in section 371.3 of this Part.
(5) Acute hazardous waste. The commercial chemical products, manufacturing chemical intermediates or off-specification commercial chemical products or manufacturing chemical intermediates referred to in paragraphs (1) through (4) of this subdivision, are identified as acute hazardous wastes (H) and are subject to the small quantity exclusion defined in section 371.1(f)(5) of this Part.
For the convenience of the regulated community the primary hazardous properties of the materials have been indicated by the letters T [Toxicity], and R [Reactivity]. Absence of a letter indicates that the compound only is listed for acute toxicity.
P099 506-61-6 Argentate (1-), bis (cyano-C)-, potassium
P010 7778-39-4 Arsenic acid H3AsO4
P011 1303-28-2 Arsenic oxide As2O5
P042 51-43-4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino) ethyl]-, (R)-
P046 122-09-8 Benzeneethanamine, alpha, alpha-dimethyl-
P127 1563-66-2 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate
P188 57-64-7 Benzoic acid, 2-hydroxy-, compd. w/(3aS-cis)-1,2,3a, 8,8a- hexahydro-1,3a,8-trimethylpyrrolo[2,3-b]indol-5-yl methycarbamate ester (1:1)
P001 181-81-2 2H-1-Benzopyran-2-one, 4-hydroxy-3- (3-oxo-1-phenylbutyl)-1, & salts, when present at concentrations greater than 0.3 percent
P045 39196-18-4 2-Butanone, 3,3-dimethyl- 1-(methylthio)-, O-[(methylamino) carbonyl] oxime
P189 55285-14-8 Carbamic acid, [(dibutylamino)-thio]methyl-, 2, 3-dihydro-2,2-dimethyl-7-benzofuranyl ester
P191 644-64-4 Carbamic acid, dimethyl-, 1-[(dimethyl- amino)carbonyl]-5-methyl-1H-pyrazol-3-yl ester
P192 119-38-0 Carbamic acid, dimethyl-, 3-methyl-1(1-methylethyl)-1H-pyrazol-5yl ester
P202 64-00-6 m-Comenyl methylcarbamate
P034 131-89-5 2-Cyclohexyl-4, 6-dinitrophenol
P004 309-00-2 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10- hexa- chloro-1,4,4a,5,8,8a,- hexahydro-, (1alpha, 4alpha, 4abeta, 5alpha, 8alpha, 8abeta) -
P060 465-73-6 1,4,5,8- Dimethanonaphthalene, 1,2,3,4,10, 10-hexa-chloro- 1,4,4a,5,8,8a- hexahydro-, (1alpha, 4alpha, 4abeta, 5beta, 8beta, 8abeta) -
P037 60-57-1 2,7:3,6-Dimethanonaphth[2,3-b]oxirene 3,4,5,6,9,9- hexachloro- 1a,2,2a,3,6,6a,7,7a-octahydro-, (1-a-alpha, 2beta, 2aalpha, 3beta, 6beta, 6aalpha, 7beta, 7aalpha) -
P051 172-20-8 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha, 2beta, 2abeta, 3alpha, 6alpha, 6abeta, 7beta, 7aalpha)-, & metabolites
P185 26419-73-8 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-,0-[(methylamino)-carbonyl]oxime
P194 23135-22-0 Ethanimidothioc acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester
P066 16752-77-5 Ethanimidothioic acid, N-[[(methylamino) carbonyl]oxy]-, methyl ester
P065 628-86-4 Fulminic acid, mercury (2+) salt (R,T)
P196 15339-3603 Manganese, bis(dimethylcarbamodithioato-S,S')-
P198 233422-53-9 Methanimidamide, N, N-dimethyl-N'-[3-[[(methylamino)-carbonyl]oxy]phenyl]-, monohydrochloride
P197 17702-57-7 Methanimidamide, N, N-dimethyl-N'-[2-methyl-4[(methylamino)carbonyl]oxy]phenyl]-
P050 115-29-7 6,9-Methano-2,4, 3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
P059 76-44-8 4, 7-Methano-lH-indene, 1,4,5,6,7,8,8-heptachloro- 3a,4,7,7a-tetrahydro-
P128 315-18-4 Mexacarbate
P075 154-11-5 Nicotine, & salts
P088 145-73-3 7-Oxabicyclo[2.2.l]heptane-2, 3-dicarboxylic acid
P034 131-89-5 Phenol, 2-cyclohexyl-4, 6-dinitro-
P128 315-18-4 Phenol, 4-(dimethylamino)-3,5-dimethyl-,methylcarbamate (ester)
P199 2032-65-7 Phenol,(3,5-dimethyl-4-(methylthio)-, methylcarbamate
P202 64-00-6 Phenol,3-(1-methylethyl)-,methyl carbamate
P201 2631-37-0 Phenol, 3-methyl-5-(1-methylethyl)-,methyl carbamate
P020 88-85-7 Phenol, 2-(1-methylpropyl)-4, 6-dinitro-
P039 298-04-4 Phosphorodithioic acid O,O-diethyl S-[2-(ethylthio)ethyl] ester
P094 298-02-2 Phosphorodithioic acid, O,O-diethyl S-[(ethylthio) methyl] ester
P044 60-51-5 Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino) -2-oxoethyl] ester
P097 52-85-7 Phosphorothioic acid, O-[4-[(dimethylamino) sulfonyl] phenyl] O,O-dimethyl ester
P188 57-64-7 Physostigimine salicylate
P070 116-06-3 Propanal, 2-methyl-2- (methylthio)-, O- [(methylamino)carbonyl]oxime
P203 1646-88-4 Propanal, 2-methyl-2-(methyl-sulfonyl)-, 0-[(methylamino)carbonyl] oxime
P075 154-11-5 Pyridine, 3-(1-methyl- 2-pyrrolidinyl)-, (S)-, & salts
P204 57-47-6 Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexahydro-1,3a, 8-trimethyl-, methylcarbamate (ester), (3aS-cis)-
P114 12039-52-0 Selenious acid, dithallium(1 +) salt
P115 7446-18-6 Sulfuric acid, dithallium(1 +) salt
P109 3689-24-5 Tetraethyldithio pyrophosphate
P113 1314-32-5 Thallium oxide Tl2O3
P049 541-53-7 Thioimidodicarbonic diamide [(H2N)C(S)] 2NH
P001 181-81-2 Warfarin, & salts, when present at concentrations greater than 0.3 percent
P205 137-30-4 Zinc, bis(dimethylcarbamodithioato-S,S')-
P122 1314-84-7 Zinc phosphide Zn3P2, when present at concentrations greater than 10 percent (R,T)
____ 1CAS number given for parent compound only.
(6) The commercial chemical products, manufacturing chemical intermediates, or off- specification commercial chemical products referred to in paragraphs (1) through (4) of this subdivision, are identified as toxic waste (T) unless otherwise designated and are subject to the small quantity generator exclusion defined in section 371.1(f)(1) and (7) of this Part. (Note: For the convenience of the regulated community, the primary hazardous properties of these materials have been indicated by the letters T [Toxicity], R [Reactivity], I [Ignitability] and C [Corrosivity]. Absence of a letter indicates that the compound is only listed for toxicity. These wastes and their corresponding EPA hazardous waste numbers are:
U144 301-04-2 Acetic acid, lead(2+) salt
U214 563-68-8 Acetic acid, thallium(1+) salt
U010 50-07-7 Azirino [2′,3′: 3,4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino- 8-[[(aminocarbonyl) oxy] methyl] -1,1a,2,8a,8b-hexahydro- 8a- methoxy-5-methyl-, [1aS- (1aalpha, 8beta, 8aalpha,8balpha)]-
U278 22781-23-3 Bemdocarb
U157 56-49-5 Benz [j] aceanthrylene, 1,2-dihydro-3-methyl-
U192 23950-58-5 Benzamide, 3, 5-dichloro-N- (1,1-dimethyl-2-propynyl) -
U014 492-80-8 Benzenamine, 4,4′ -carbonimidoylbis[N,N-dimethyl-
U093 60-11-7 Benzenamine, N,N-dimethyl-4- (phenylazo)-
U158 101-14-4 Benzenamine, 4,4′ -methylenebis [2-chloro-
U038 510-15-6 Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha- hydroxy-, ethyl ester
U030 101-55-3 Benzene, 1-bromo-4-phenoxy
U035 305-03-3 Benzenebutanoic acid, 4-[bis (2- chloroethyl) amino] -
U060 72-54-8 Benzene, 1,1′-(2,2-dichloroethylidene) bis[4-chloro-
U223 26471-62-5 Benzene, 1, 3-diisocyanatomethyl- (R, T)
U239 1330-20-7 Benzene, dimethyl-(I)
U061 50-29-3 Benzene, 1,1′-(2,2,2-trichloroethylidene) bis[4-chloro-
U247 72-43-5 Benzene, 1,1,-(2,2,2-trichloroethylidene) bis[4- methoxy-
U202 81-07-2 1,2-Benzisothiazol- 3(2H)-one, 1,1-dioxide, & salts
U203 94-59-7 1, 3-Benzodioxole, 5-(2-propenyl)-
U141 120-58-1 1, 3-Benzodioxole, 5-(1-propenyl)-
U364 22961-82-6 1,3-Benzodioxol-4-ol, 2-2-dimethyl-
U248 181-81-2 2H-1-Benzopyran-2-one, 4-hydroxy-3- (3-oxo-1- phenyl- butyl)-, & salts, when present at concentrations of 0.3 percent or less
U021 92-87-5 [1,1′-Biphenyl] -4,4′-diamine
U128 87-68-3 1, 3-Butadiene, 1,1,2,3,4,4-hexachloro-
U143 303-34-4 2-Butenoic acid, 2-methyl-,7-[[2,3-dihydroxy-2-(1-methoxyethyl) - 3-methyl-1-oxobutoxy] methyl] - 2,3,5,7a-tetrahydro-1H- pyrrolizin-1-yl ester, [1S- [1alpha(Z), 7(2S*,3R*),7aalpha]]-
U372 10605-21-7 Carbamic acid, 1H-benzimidazol-2-yl,methyl ester
U271 17804-35-2 Carbamic acid, [1-[(butylamino)carbonyl]-1H- benzimidazol-2-yl]-,methyl ester
U280 101-27-9 Carbamic acid, (3-chlorophenyl)-,4-chloro-2-butynyl ester
U114 111-54-6 Carbamodithioic acid, 1,2-ethanediylbis-, salts & esters
U062 2303-16-4 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3- dichloro-2-propenyl) ester
U389 2303-17-5 Carbamothioic acid, bis(1-methylethyl-,, S(2,3,3-trichloro-2-propenyl) ester
U387 52888-80-9 Carbamothioic acid, dipropyl-, S- (phenylmethyl) ester
U215 6533-73-9 Carbonic acid, dithallium(1+) salt
U032 13765-19-0 Chromic acid H2CrO4, calcium salt
U197 106-51-4 2, 5-Cyclohexadiene- 1,4-dione
U129 58-89-9 Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1alpha, 2alpha, 3beta, 4alpha, 5alpha, 6beta) -
U130 77-47-4 1, 3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
U066 96-12-8 1,2-Dibromo- 3-chloropropane
U085 1464-53-5 1,2:3,4-Diepoxybutane (I, T)
U394 30558-43-1 Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-,methyl ester
U410 59669-26-0 Ethanimidothioic acid, N,N'-[thiobis[(methylimino)carbonyloxy]]bis-,dimethyl ester
U155 91-80-5 1,2-Ethanediamine, N,N-dimethyl-N′ -2-pyridinyl- N′- (2-thienylmethyl) -
U024 111-91-1 Ethane, 1,1′ - [methylenebis(oxy)]bis[2-chloro-
U208 630-20-6 Ethane, 1,1,1,2- tetrachloro-
U209 79-34-5 Ethane, 1,1,2,2- tetrachloro-
U173 1116-54-7 Ethanol, 2,2′- (nitrosoimino)bis-
U395 5952-26-1 Ethanol, 2,2'-oxybis-, dicarbamate
U206 18883-66-4 Glucopyranose, 2-deoxy-2- (3-methyl-3- nitrosoureido) -, D-
U206 18883-66-4 D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)- carbonyl]amino] -
U163 70-25-7 Guanidine, N-methyl- N′-nitro-N-nitroso-
U137 193-39-5 Indeno [1,2, 3-cd] pyrene
U190 85-44-9 1, 3-Isobenzofurandione
U036 57-74-9 4, 7-Methano-lH-indene, 1,2,4,5,6,7,8,8-octachloro- 2,3,3a,4,7,7a-hexahydro-
U142 143-50-0 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5, 5,5a,5b,6-decachlorooctahydro-
U158 101-14-4 4,4′-Methylenebis (2-chloroaniline)
U164 56-04-2 Mitomycin C
U059 20830-81-3 5,12-Naphthacenedione, 8-acetyl-10- [(3-amino-2,3,6-trideoxy) -alpha-L-lyxo-hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8, 11-trihydroxy-1-methoxy-, (8S-cis)-
U236 72-57-1 2,7-Naphthalenedisulfonic acid, 3,3′-[(3,3′-dimethyl[l,l′-biphenyl]-4,4′-diyl) bis(azo)bis [5-amino-4-hydroxy]-, tetrasodium salt
U217 10102-45-1 Nitric acid, thallium(1 +) salt
U173 116-54-7 N-Nitrosodiethanolamine
U058 50-18-0 2H-1,3,2-Oxazaphosphorin- 2-amine, N,N-bis (2-chloroethyl) tetrahydro-, 2-oxide
U161 108-10-1 Pentanol, 4-methyl- (I)
U089 56-53-1 Phenol, 4,4′- (1,2-diethyl-1,2-ethenediyl)bis-, (E) -
U132 70-30-4 Phenol, 2,2′-methylenebis [3,4,6-trichloro-
See F027 58-90-2 Phenol, 2,3,4,6 -tetrachloro-
U150 148-82-3 L-Phenylalanine, 4-[bis(2-chloroethyl) amino]-
U145 7446-27-7 Phosphoric acid, lead(2+) salt (2:3)
U087 3288-58-2 Phosphorodithioic acid, O,O-diethyl S-methylester
U066 96-12-8 Propane, 1,2-dibromo- 3-chloro-
See F027 93-72-1 Propanoic acid, 2- (2,4,5-trichlorophenoxy)-
U243 1888-71-7 1-Propene, 1,1,2,3,3,3 -hexachloro-
U237 66-75-1 2,4-(1H, 3H)-Pyrimidinedione, 5-[bis(2-chloroethyl)amino]-
U202 181-07-2 Saccharin, & salts
U207 95-94-3 1,2,4,5- Tetrachlorobenzene
U208 630-20-6 1,1,1,2- Tetrachloroethane
U209 79-34-5 1,1,2,2- Tetrachloroethane
See F027 58-90-2 2,3,4,6- Tetrachlorophenol
U215 6533-73-9 Thallium (I) carbonate
U217 10102-45-1 Thallium (I) nitrate
U244 137-26-8 Thioperoxydicarbonic diamide [(H2N)C(S)]2S2, tetramethyl-
U228 79-01-6 Trlchloroethylene
U248 181-81-2 Warfarin, & salts, when present at concentrations of 0.3 percent or less
U200 50-55-5 Yohimban-16- carboxylic acid, 11,17-dimethoxy-18-[(3,4, 5-trimethoxybenzoyl)oxy]-, methyl ester, (3beta, 16beta, 17alpha, 18beta, 20alpha)-
U249 1314-84-7 Zinc phosphide Zn3P2, when present at concentrations of 10 percent or less
(e) Wastes containing polychlorinated biphenyls (PCBs).
(1) All solid wastes containing 50 parts per million (ppm) by weight (on a dry weight basis for other than liquid wastes) or greater of polychlorinated biphenyls (PCBs) are listed hazardous wastes, excluding small capacitors as defined in paragraph (3) of this subdivision and PCB articles drained in accordance with subparagraphs (2)(ii) and (iii) of this subdivision. PCB articles that contain less than 50 ppm PCBs are not regulated as hazardous waste. Oils in or from electrical equipment whose PCB concentration is unknown, except circuit breakers, reclosers and cable, must be assumed to contain between 50 and 500 ppm PCB and are listed hazardous waste. PCB and PCBs mean any chemical substance that is limited to the biphenyl molecule that has been chlorinated to varying degrees. Any chemical waste, combination of waste, or environmental media that contains less than 50 ppm PCBs are listed hazardous waste only as specifically provided in paragraph (2) of this subdivision. Wastes that may contain PCBs include dielectric fluids, contaminated solvents, waste oil, heat transfer fluids, hydraulic fluids, dredge spoils, and material contaminated as a result of spills. The hazardous code for these PCB wastes shall be toxic waste (T). Environmental media means naturally occurring, non-living substances, including soil, sediment, rock, groundwater, surface water, surface runoff, air, and only such animal and vegetable matters as may be incidentally contained therein (e.g., soil and water bacteria, underground roots, skeletal remains, etc.). These wastes shall have hazardous waste numbers assigned as follows:
B001 PCB oil (concentrated) from transformers, capacitors, etc.
B002 Petroleum oil or other liquid containing 50 ppm or greater of PCBs, but less than 500 ppm PCBs. This includes oil from electrical equipment whose PCB concentration is unknown, except for circuit breakers, reclosers, and cable.
B003 Petroleum oil or other liquid containing 500 ppm or greater of PCBs.
B004 PCB articles containing 50 ppm or greater of PCBs, but less than 500 ppm PCBs, excluding small capacitors. This includes oil-filled electrical equipment whose PCB concentration is unknown, except for circuit breakers, reclosers and cable.
B005 PCB articles, other than transformers, that contain 500 ppm or greater of PCBs, excluding small capacitors.
B006 PCB transformers. PCB transformers means any transformer that contains 500 ppm PCB or greater.
B007 Other PCB wastes, including contaminated soil, solids, sludges, clothing, rags and dredge material.
Note: PCBs are also regulated by 40 CFR part 761. A person must comply with both this Part and 40 CFR part 761 (see section 370.1[e] ot this Title).
(2) Drained PCB articles.
(i) Except as provided in subparagraphs (ii) and (iii) of this paragraph, drained PCB articles containing at least 50 ppm PCBs are regulated as hazardous waste.
(ii) PCB articles, except capacitors, that contain between 50 and 500 ppm PCB, are no longer regulated as PCB listed hazardous waste provided that all free-flowing liquid has been drained from the article. The drained liquid is a listed hazardous waste, as is any solvent used for flushing.
(a) Hydraulic machines containing less than 1,000 ppm PCB are no longer regulated as PCB listed hazardous waste, provided that all free-flowing liquid has been drained from the hydraulic machine. The drained liquid is a liquid hazardous waste, as is any solvent used for flushing.
(b) Hydraulic machines containing 1,000 ppm PCB are no longer regulated as PCB listed hazardous waste, provided that all free-flowing liquid has been drained from the hydraulic machine, and the drained hydraulic machine is flushed with a solvent in which PCBs are readily soluble. The solvent to be used for flushing must contain less than 50 ppm PCB. The drained liquid and the solvent used for flushing are listed hazardous wastes.
(i) PCB article means any manufactured article, other than a PCB container, that contains PCBs and whose surface(s) has been in direct contact with PCBs. PCB article includes capacitors, transformers, electric motors, circuit breakers, reclosers, voltage regulators, switches (including sectionalizers and motor starters), electromagnets, cable, hydraulic machines, pumps, pipes, and any other manufactured item which is formed to a specific shape or design during manufacture, has end use function(s) dependent in whole or in part upon its shape or design during end use, and has either no change of chemical composition during its end use or only those changes of composition which have no commercial purpose separate from that of the PCB article.
(ii) Small capacitor means a capacitor which contains less than 1.36 kg (3 lb.) of dielectric fluid. The following assumptions may be used if the actual weight of the dielectric fluid is unknown. A capacitor whose total volume is less than 1,639 cubic centimeters (100 cubic inches) may be considered to contain less than 1.36 kg (3 lb.) of dielectric fluid and a capacitor whose total volume is more than 3,278 cubic centimeters (200 cubic inches) must be considered to contain more than 1.36 kg (3 lb.) of dielectric fluid. A capacitor whose volume is between 1,639 and 3,278 cubic centimeters may be considered to contain less than 1.36 (3 lb.) of dielectric fluid if the total weight of the capacitor is less than 4.08 kg (9 lb.).
(4) Testing procedures. The procedures in 40 CFR 761.60(g) (see section 370.1[e] of this Title) will be used to determine the concentration of PCBs, unless a petition for equivalent testing or analytical methods is submitted and approved per section 370.3 of this Title.
(f) Deletion of certain hazardous waste codes following equipment cleaning and replacement.
(1) Wastes from wood preserving processes at plants that do not resume or initiate use of chlorophenolic preservatives will not meet the listing definition of F032 once the generator has met all of the requirements of paragraphs (2) and (3) of this subdivision. These wastes may, however, continue to meet another hazardous waste listing description or may exhibit one or more of the hazardous waste characteristics.
(2) Generators must either clean or replace all process equipment that may have come into contact with chlorophenolic formulations or constituents thereof, including, but not limited to, treatment cylinders, sumps, tanks, piping systems, drip pads, fork lifts, and trams, in a manner that minimizes or eliminates the escape of hazardous waste or constituents, leachate, contaminated drippage, or hazardous waste decomposition products to the ground water, surface water, or atmosphere.
(i) Generators shall do one of the following:
(a) prepare and follow an equipment replacement plan and clean equipment in accordance with this subdivision;
(b) prepare and follow an equipment replacement plan and replace equipment in accordance with this subdivision; or
(c) document cleaning and replacement in accordance with this subdivision, carried out after termination of use of chlorophenolic preservations.
(ii) Cleaning requirements.
(a) Prepare and sign a written equipment cleaning plan that describes:
(1) the equipment to be cleaned;
(2) how the equipment will be cleaned;
(3) the solvent to be used in cleaning;
(4) how solvent rinses will be tested; and
(5) how cleaning residues will be disposed.
(b) Equipment must be cleaned as follows:
(1) remove all visible residues from process equipment; and
(2) rinse process equipment with an appropriate solvent until dioxins and dibenzofurans are not detected in the final solvent rinse.
(c) Analytical requirements.
(1) Rinses must be tested in accordance with SW-846, Method 8290.
(2) not detected means at or below the lower method calibration limit (MCL) in SW-846, Method 8290, Table 1.
(d) The generator must manage all residues from the cleaning process as F032 waste.
(iii) Replacement requirements.
(a) Prepare and sign a written equipment replacement plan that describes:
(1) the equipment to be replaced;
(2) how the equipment will be replaced; and
(3) how the equipment will be disposed.
(b) The generator must manage the discarded equipment as F032 waste.
(iv) Documentation requirements.
(a) Document that previous equipment cleaning and/or replacement was performed in accordance with this subdivision and occurred after cessation of use of chlorophenolic preservatives.
(i) the name and address of the facility;
(ii) formulations previously used and the date on which their use ceased in each process at the plant;
(iii) formulations currently used in each process at the plant;
(iv) the equipment cleaning or replacement plan;
(v) the name and address of any persons who conducted the cleaning and replacement;
(vi) the dates on which cleaning and replacement were accomplished;
(vii) the dates of sampling and testing;
(viii) a description of the sample handling and preparation techniques, including techniques used for extraction, containerization, preservation, and chain-of-custody of the samples;
(ix) a description of the tests performed, the date the tests were performed, and the results of the tests;
(x) the name and model numbers of the instrument(s) used in performing the tests;
(xi) QA/QC documentation; and
(xii) the following statement signed by the generator or an authorized representative:
“I certify under penalty of law that all process equipment required to be cleaned or replaced under subdivision (f) of this section was cleaned or replaced as represented in the equipment cleaning and replacement plan and accompanying documentation. I am aware that there are significant penalties for providing false information, including the possibility of fine or imprisonment.”
(i) Comparable/syngas fuel exclusion.
Wastes that meet the following comparable/syngas fuel requirements are not solid wastes:
(1) Comparable fuel specifications.
(i) Physical specifications.
(ii) Constituent specifications. For compounds listed in table 1 of this subdivision the specification levels and, where non-detect is the specification, minimum required detection limits are: (see table 1 of this subdivision).
(2) Synthesis gas fuel specification. Synthesis gas fuel (i.e., syngas fuel) that is generated from hazardous waste must:
(v) contain less than 1 ppmv of each hazardous constituent in the target list of Appendix 23, infra constituents.
Detection and Detection Limit Values for Comparable Fuel Specification
Table 1 to 40 CFR section 261.38, as of July 1, 2002, is incorporated by reference as if fully set forth herein (see section 370.1[e] of this Title).
(3) Implementation. Waste that meets the comparable or syngas fuel specifications provided by paragraph (1) or (2) of this subdivision (these constituent levels must be received by the comparable fuel when generated, or as a result of treatment or blending, as provided in clause [iii][c] or subparagraph [iv] of this paragraph) is excluded from the definition of solid waste provided that the following requirements are met:
(i) Notices. For purposes of this section, the person claiming and qualifying for the exclusion is called the comparable/syngas fuel generator and the person burning the comparable/syngas fuel is called the comparable/syngas burner. The person who generates the comparable fuel or syngas fuel must claim and certify to the exclusion.
(a) State RCRA and CAA directors in other authorized states or USEPA regional RCRA and CAA directors in unauthorized states. (This is the commissioner, in New York State.)
(1) The generator must submit a one-time notice to the regional or State RCRA and CAA directors in whose jurisdiction the exclusion is being claimed and where the comparable/syngas fuel will be burned, certifying compliance with the conditions of the exclusion and providing documentation as required by subclause (3) of this clause.
(2) If the generator is a company that generates comparable/syngas fuel at more than one facility, the generator shall specify at which sites the comparable/syngas fuel will be generated.
(3) A comparable/syngas fuel generator's notification to the directors must contain the following items:
(i) the name, address, and RCRA ID number of the person/facility claiming the exclusion;
(ii) the applicable EPA hazardous waste codes for the hazardous waste;
(iii) name and address of the units, meeting the requirements of subparagraph (ii) of this paragraph, that will burn the comparable/syngas fuel; and
(iv) the following statement is signed and submitted by the person claiming the exclusion or his authorized representative:
“Under penalty of criminal and civil prosecution for making or submitting false statements, representations, or omissions, I certify that the requirements of 6 NYCRR 371.4(i) have been met for all waste identified in this notification. Copies of the records and information required at 6 NYCRR 371.4(i)(3)(x) are available at the comparable/syngas fuel generator's facility. Based on my inquiry of the individuals immediately responsible for obtaining the information, the information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.”
(b) Public notice. Prior to burning an excluded comparable/syngas fuel, the burner must publish in a major newspaper of general circulation local to the site where the fuel will be burned, a notice entitled “Notification of Burning a Comparable/Syngas Fuel Excluded Under the Resource Conservation and Recovery Act” containing the following information:
(1) name, address, and facility ID number of the generating facility;
(2) name and address of the unit(s) that will burn the comparable/syngas fuel;
(3) a brief, general description of the manufacturing, treatment, or other process generating the comparable/syngas fuel;
(4) an estimate of the average and maximum monthly and annual quantity of the waste claimed to be excluded; and
(5) name and mailing address of the regional or State directors to whom the claim was submitted.
(ii) Burning. The comparable/syngas fuel exclusion for fuels meeting the requirements of paragraph (1) or (2) of this subdivision and subparagraph (i) of this paragraph applies only if the fuel is burned in the following units that also shall be subject to Federal/State/local air emission requirements, including all applicable CAA MACT requirements:
(a) industrial furnaces as defined in section 370.2 of this Title;
(b) boilers, as defined in section 370.2 of this Title, that are further defined as follows:
(1) industrial boilers located on the site of a facility engaged in a manufacturing process where substances are transformed into new products, including the component parts of products, by mechanical or chemical processes; or
(2) utility boilers used to produce electric power, steam, heated or cooled air, or other gases or fluids for sale;
(c) hazardous waste incinerators subject to regulation under section 373-2.15 or 373-3.15 of this Title or applicable CAA MACT standards.
(iii) Blending to meet the viscosity specification. A hazardous waste blended to meet the viscosity specification shall:
(a) as generated and prior to any blending, manipulation, or processing meet the constituent and heating value specifications of clause (1)(i)(a) and subparagraph (1)(ii) of this subdivision;
(b) be blended at a facility that is subject to the applicable requirements of Subparts 373-2 and 373-3, or section 372.2(a)(8) of this Title; and
(c) not violate the dilution prohibition of subparagraph (vi) of this paragraph.
(iv) Treatment to meet the comparable fuel exclusion specifications.
(a) A hazardous waste may be treated to meet the exclusion specifications of subparagraphs (1)(i) and (ii) of this subdivision provided the treatment:
(1) destroys or removes the constituent listed in the specification or raises the heating value by removing or destroying hazardous constituents or materials;
(2) is performed at a facility that is subject to the applicable requirements of Subparts 373-2 and 373-3, or section 372.2(a)(8) of this Title; and
(3) does not violate the dilution prohibition of subparagraph (vi) of this paragraph.
(b) Residuals resulting from the treatment of a hazardous waste listed in this section to generate a comparable fuel remain a hazardous waste.
(v) Generation of a syngas fuel.
(a) A syngas fuel can be generated from the processing of hazardous wastes to meet the exclusion specifications of paragraph (2) of this subdivision provided the processing:
(1) destroys or removes the constituent listed in the specification or raises the heating value by removing or destroying constituents or materials;
(2) is performed at a facility that is subject to the applicable requirements of Subparts 373-2 and 373-3, or section 372.2(a)(8) of this Title or is an exempt recycling unit pursuant to section 371.1(g)(3) of this Part; and
(b) Residuals resulting from the treatment of a hazardous waste listed in this section to generate a syngas fuel remain a hazardous waste.
(vi) Dilution prohibition for comparable and syngas fuels. No generator, transporter, handler, or owner or operator of a treatment, storage, or disposal facility shall in any way dilute a hazardous waste to meet the exclusion specifications of clause (1)(i)(a), subparagraph (1)(ii) or paragraph (2) of this subdivision.
(vii) Waste analysis plans. The generator of a comparable/syngas fuel shall develop and follow a written waste analysis plan which describes the procedures for sampling and analysis of the hazardous waste to be excluded. The waste analysis plan shall be developed in accordance with the applicable sections of the “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods” (SW-846), as incorporated by reference in section 370.1(e) of this Title. The plan shall be followed and retained at the facility excluding the waste.
(a) At a minimum, the plan must specify:
(1) the parameters for which each hazardous waste will be analyzed and the rationale for the selection of those parameters;
(3) the sampling method which will be used to obtain a representative sample of the waste to be analyzed;
(4) the frequency with which the initial analysis of the waste will be reviewed or repeated to ensure that the analysis is accurate and up to date; and
(5) if process knowledge is used in the waste determination, any information prepared by the generator in making such determination.
(b) The waste analysis plan shall also contain records of the following:
(1) the dates and times waste samples were obtained, and the dates the samples were analyzed;
(2) the names and qualifications of the person(s) who obtained the samples;
(3) a description of the temporal and spatial locations of the samples;
(4) the name and address of the laboratory facility at which analyses of the samples were performed;
(5) a description of the analytical methods used, including any clean-up and sample preparation methods;
(6) all quantitation limits achieved and all other quality control results for the analysis (including method blanks, duplicate analyses, matrix spikes, etc.), laboratory quality assurance data, and description of any deviations from analytical methods written in the plan or from any other activity written in the plan which occurred;
(7) all laboratory results demonstrating that the exclusion specifications have been met for the waste; and
(8) all laboratory documentation that support the analytical results, unless a contract between the claimant and the laboratory provides for the documentation to be maintained by the laboratory for the period specified in subparagraph (xi) of this paragraph and also provides for the availability of the documentation to the claimant upon request.
(c) Syngas fuel generators shall submit for approval, prior to performing sampling, analysis, or any management of a syngas fuel as an excluded waste, a waste analysis plan containing the elements of clause (a) of this subparagraph to the appropriate regulatory authority. The approval of waste analysis plans must be stated in writing and received by the facility prior to sampling and analysis to demonstrate the exclusion of a syngas. The approval of the waste analysis plan may contain such provisions and conditions as the regulatory authority deems appropriate.
(viii) Comparable fuel sampling and analysis.
(a) General. For each waste for which an exclusion is claimed, the generator of the hazardous waste must test for all the constituents on Appendix 23, infra except those that the generator determines, based on testing or knowledge, should not be present in the waste. The generator is required to document the basis of each determination that a constituent should not be present. The generator may not determine that any of the following categories of constituents should not be present:
(1) a constituent that triggered the toxicity characteristic for the waste constituents that were the basis of the listing of the waste stream, or constituents for which there is a treatment standard for the waste code in section 376.4(a) of this Title;
(2) a constituent detected in previous analysis of the waste;
(3) constituents introduced into the process that generates the waste; or
(4) constituents that are byproducts or side reactions to the process that generates the waste.
Any claim under this subparagraph must be valid and accurate for all hazardous constituents; a determination not to test for a hazardous constituent will not shield a generator from liability should that constituent later be found in the waste above the exclusion specifications.
(b) For each waste for which the exclusion is claimed where the generator of the comparable/syngas fuel is not the original generator of the hazardous waste, the generator of the comparable/syngas fuel may not use process knowledge pursuant to clause (a) of this paragraph and must test to determine that all of the constituent specifications of subparagraph (1)(ii) and paragraph (2) of this subdivision have been met.
(c) The comparable/syngas fuel generator may use any reliable analytical method to demonstrate that no constituent of concern is present at concentrations above the specification levels. It is the responsibility of the generator to ensure that the sampling and analysis are unbiased, precise, and representative of the waste. For the waste to be eligible for exclusion, a generator must demonstrate that:
(1) each constituent of concern is not present in the waste above the specification level at the 95 percent upper confidence limit around the mean; and
(2) the analysis could have detected the presence of the constituent at or below the specification level at the 95 percent upper confidence limit around the mean.
(d) Nothing in this subparagraph preempts, overrides or otherwise negates the provision in section 372.2(a)(2) of this Title, which requires any person who generates a solid waste to determine if that waste is a hazardous waste.
(e) In an enforcement action, the burden of proof to establish conformance with the exclusion specification shall be on the generator claiming the exclusion.
(f) The generator must conduct sampling and analysis in accordance with their waste analysis plan developed under subparagraph (vii) of this paragraph.
(g) Syngas fuel and comparable fuel that has not been blended in order to meet the kinematic viscosity specifications shall be analyzed as generated.
(h) If a comparable fuel is blended in order to meet the kinematic viscosity specifications, the generator shall:
(1) analyze the fuel as generated to ensure that it meets the constituent and heating value specifications; and
(2) after blending, analyze the fuel again to ensure that the blended fuel continues to meet all comparable/syngas fuel specifications.
(i) Excluded comparable/syngas fuel must be re-tested, at a minimum, annually and must be retested after a process change that could change the chemical or physical properties of the waste.
(ix) Speculative accumulation. Any persons handling a comparable/syngas fuel are subject to the speculative accumulation test under section 371.1(c)(4)(iv) of this Part.
(x) Records. The generator must maintain records of the following information on-site:
(a) all information required to be submitted to the implementing authority as part of the notification of the claim:
(1) the owner/operator name, address, and RCRA facility ID number of the person claiming the exclusion;
(2) the applicable EPA hazardous waste codes for each hazardous waste excluded as a fuel; and
(3) the certification signed by the person claiming the exclusion or his authorized representative;
(b) a brief description of the process that generated the hazardous waste and process that generated the excluded fuel, if not the same;
(c) an estimate of the average and maximum monthly and annual quantities of each waste claimed to be excluded;
(d) documentation for any claim that a constituent is not present in the hazardous waste as required under clause (viii)(a) of this paragraph;
(e) the results of all analyses and all detection limits achieved as required under subparagraph (viii) of this paragraph;
(f) if the excluded waste was generated through treatment or blending, documentation as required under subparagraph (iii) or (iv) of this paragraph;
(g) if the waste is to be shipped off-site, a certification from the burner as required under subparagraph (xii) of this paragraph;
(h) a waste analysis plan and the results of the sampling and analysis that includes the following:
(7) all laboratory analytical results demonstrating that the exclusion specifications have been met for the waste; and
(8) all laboratory documentation that support the analytical results, unless a contract between the claimant and the laboratory provides for the documentation to be maintained by the laboratory for the period specified in subparagraph (xi) of this paragraph and also provides for the availability of the documentation to the claimant upon request;
(i) if the generator ships comparable/syngas fuel off-site for burning, the generator must retain for each shipment the following information on-site:
(1) the name and address of the facility receiving the comparable/syngas fuel for burning;
(2) the quantity of comparable/syngas fuel shipped and delivered;
(3) the date of shipment or delivery;
(4) a cross-reference to the record of comparable/syngas fuel analysis or other information used to make the determination that the comparable/syngas fuel meets the specifications as required under subparagraph (viii) of this paragraph; and
(5) a one-time certification by the burner as required under subparagraph (xii) of this paragraph.
(xi) Records retention. Records must be maintained for the period of three years. A generator must maintain a current waste analysis plan during that three-year period.
(xii) Burner certification. Prior to submitting a notification to the State and regional directors, a comparable/syngas fuel generator who intends to ship their fuel off-site for burning must obtain a one-time written, signed statement from the burner:
(a) certifying that the comparable/syngas fuel will only be burned in an industrial furnace or boiler, utility boiler, or hazardous waste incinerator, as required under paragraph (c)(2) of this section;
(b) identifying the name and address of the units that will burn the comparable/syngas fuel; and
(c) certifying that the state in which the burner is located is authorized to exclude wastes as comparable/syngas fuel under the provisions of this section.
(xiii) Ineligible waste codes. Wastes that are listed because of presence of dioxins or furans, as set out in Appendix 22, infra are not eligible for this exclusion, and any fuel produced from or otherwise containing these wastes remains a hazardous waste subject to full Parts 370, 371, 372, 373, 374 and 376 of this Title, hazardous waste management requirements.