Source: https://patents.google.com/patent/KR101154596B1/en
Timestamp: 2019-10-14 12:40:18
Document Index: 654335323

Matched Legal Cases: ['art 124', 'art 124', 'art 124', 'art 124', 'art 124', 'art 124', 'art 124']

KR101154596B1 - Semiconductor light emitting device and fabrication method thereof - Google Patents
KR101154596B1
KR101154596B1 KR1020090044291A KR20090044291A KR101154596B1 KR 101154596 B1 KR101154596 B1 KR 101154596B1 KR 1020090044291 A KR1020090044291 A KR 1020090044291A KR 20090044291 A KR20090044291 A KR 20090044291A KR 101154596 B1 KR101154596 B1 KR 101154596B1
KR1020090044291A
KR20100125532A (en
2009-05-21 Priority to KR1020090044291A priority Critical patent/KR101154596B1/en
2010-12-01 Publication of KR20100125532A publication Critical patent/KR20100125532A/en
2012-06-08 Publication of KR101154596B1 publication Critical patent/KR101154596B1/en
In an embodiment, a semiconductor light emitting device may include a first semiconductor layer having a plurality of rods formed thereon; An air gap portion formed between the rods of the first semiconductor layer; It includes a plurality of compound semiconductor layers formed on the first semiconductor layer.
Semiconductor, light emitting device
The embodiment provides a semiconductor light emitting device having a photonic crystal structure capable of reducing crystal defects of a semiconductor layer and improving light extraction effects, and a method of manufacturing the same.
The embodiment provides a semiconductor light emitting device including a plurality of rods and / or air gaps under a first semiconductor layer and a method of manufacturing the same.
The embodiment provides a semiconductor light emitting device including at least one of a plurality of rods, a mask layer, and an air gap portion between a substrate and a first semiconductor layer, and a method of manufacturing the same.
A semiconductor light emitting device includes a first photonic crystal structure using an air gap portion under a first semiconductor layer, and a second photonic crystal structure using an uneven pattern on an upper surface of a substrate and / or a lower surface of the first semiconductor layer; It provides a manufacturing method.
In an embodiment, a semiconductor light emitting device may include a first semiconductor layer including a plurality of rods formed below; An air gap portion formed between the rods of the first semiconductor layer; It includes a plurality of compound semiconductor layers formed on the first semiconductor layer.
In an embodiment, a semiconductor light emitting device may include forming a mask layer having a plurality of rod holes on a substrate; Forming a group III-V compound semiconductor layer on the mask layer; Exposing a portion of the mask layer; Wet etching the mask layer to form an air gap portion.
The embodiment can improve light extraction efficiency.
The embodiment can reduce defects due to epitaxial growth.
The embodiment can improve light extraction efficiency by using a photonic crystal structure.
Embodiments may use hybrid photonic crystals to reduce crystal defects due to epitaxial growth and to improve light extraction efficiency.
The embodiment can improve the reliability of the semiconductor light emitting device.
The embodiment can minimize damage to the semiconductor crystal structure by the LLO method.
Hereinafter, an embodiment will be described with reference to the accompanying drawings. Hereinafter, in describing the embodiments, the size of each component is an example and is not limited to the size of the drawings.
Referring to FIG. 1, the semiconductor light emitting device 100 may include a substrate 110, a mask layer 120, a first semiconductor layer 130, an active layer 140, and a second conductive semiconductor layer 150.
The substrate 110 may use at least one of sapphire (Al 2 O 3 ), SiC, Si, GaAs, GaN, ZnO, Si, GaP, InP, Ge, Ga 2 0 3 .
The mask layer 120 is formed on the substrate 110. The mask layer 120 may be formed using a growth mask material such as SiO 2 , SiO x , SiN x , SiO x N y , W, or the like. A plurality of rods 132 may be formed in the mask layer 120, and the plurality of rods 132 may be disposed at regular intervals or at irregular intervals, and may be formed of a group III-V group compound semiconductor.
A first semiconductor layer 130 is formed on the mask layer 120, and the first semiconductor layer 130 is formed through the plurality of rods 132. The first semiconductor layer 130 and the rod 132 may be formed of the same semiconductor or different semiconductor materials, and this structure may be changed within the technical scope of the embodiment.
The first semiconductor layer 130 may be formed in a single layer structure or a multilayer structure, in the case of a single layer may be formed of a first conductive semiconductor layer, in the case of a multilayer, an undoped semiconductor layer, a semiconductor layer having a non-conductive property And at least one layer of the first conductive semiconductor layer may be formed, and the first conductive semiconductor layer may be disposed on the upper layer.
The first semiconductor layer 130 may include at least one of a Group III-V compound semiconductor material, for example, GaN, InN, AlN, InGaN, AlGaN, InAlGaN, AlInN, AlGaAs, GaP, GaAs, GaAsP, AlGaInP. . The plurality of rods 132 may be formed of an undoped semiconductor or a first conductive semiconductor doped with a conductive dopant and may have a thickness of 20 μm or less.
Each of the rods 132 may have a columnar shape, for example, a circular columnar or a polygonal columnar shape or a trapezoidal shape, and may have a predetermined shape (eg, a mesh) at regular intervals or at irregular intervals over the entire area of the mask layer 120. Form).
At least an upper layer of the first semiconductor layer 130 may function as a first electrode contact layer in the case of the first conductive semiconductor layer, and may include GaN, InN, AlN, InGaN, AlGaN, InAlGaN, AlInN, AlGaAs, GaP, It may be formed of at least one of GaAs, GaAsP, AlGaInP. The first conductive semiconductor layer is implemented as a group III-V compound semiconductor doped with a first conductive dopant, and when the first conductive semiconductor layer is an N-type semiconductor layer, the first conductive dopant is N. Type dopants include Si, Ge, Sn, Se, Te.
The first semiconductor layer 130 may be formed through a plurality of rods 132 disposed between the mask layers 120, thereby reducing defects due to epitaxial growth and improving light extraction effects.
An active layer 140 is formed on the first semiconductor layer 130. The active layer 140 may be formed of a single quantum well or a multiple quantum well (MQW) structure, and may be formed of InGaN / GaN or AlGaN / GaN.
A first conductive clad layer (not shown) may be formed between the first semiconductor layer 130 and the active layer 140. The first conductive clad layer may be formed of an AlGaN-based semiconductor.
The second conductive semiconductor layer 150 is formed on the active layer 140. The second conductive semiconductor layer 150 is a semiconductor semiconductor doped with a second conductive dopant, for example, a compound semiconductor such as GaN, InN, AlN, InGaN, AlGaN, InAlGaN, AlInN, AlGaAs, GaP, GaAs, GaAsP, AlGaInP, or the like. It can be made of either. When the second conductive semiconductor layer 150 is a P-type semiconductor layer, the second conductive dopant may be a P-type dopant, and may include Mg, Zn, Ca, Sr, and Ba.
At least one of a transparent electrode layer (not shown), a reflective electrode layer, and a second electrode may be formed on the second conductive semiconductor layer 150. The transparent electrode layer may be formed by selecting from materials of ITO, ZnO, IrOx, RuOx, NiO.
The first conductive semiconductor layer may be a P-type semiconductor layer, and the second conductive semiconductor layer 150 may be an N-type semiconductor layer. An N-type semiconductor layer or a P-type semiconductor layer may be formed on the second conductive semiconductor layer 150. Accordingly, the light emitting structure may be implemented as any one of an N-P junction structure, a P-N junction structure, an N-P-N junction structure, and a P-N-P junction structure.
2 to 5 illustrate a process of fabricating a semiconductor light emitting device according to the first embodiment.
2 and 3, a mask layer 120A is formed on the substrate 110. The substrate 110 may use at least one of sapphire (Al 2 O 3 ), SiC, Si, GaAs, GaN, ZnO, Si, GaP, InP, Ge. Here, after forming a buffer layer (not shown) on the substrate 110, the mask layer 120A may be formed on the buffer layer (not shown).
The mask layer 120 may be formed of a material such as Si0 2 , SiO x , SiN x , SiO x N y , W, or the like to a predetermined thickness T1, for example, 20 μm or less. The additive mask layer 120 is deposited by a plasma enhanced chemical vapor deposition (PECVD) or a sputtering method.
After the mask pattern is disposed on the mask layer 120, the mask pattern 120 is patterned by an etching method such as photolithography to form a plurality of rod holes 122.
3 and 4, the rod hole 122 may be formed in a columnar shape, for example, a circular columnar shape or a polygonal columnar shape, but is not limited thereto. The mask layer 120 may be etched in the rod hole 122 to expose the upper surface of the substrate or the upper surface of the buffer layer. The etching method may use a dry etching method, but is not limited thereto.
The rod hole 122 may be formed in a mesh shape at regular intervals and arranged in a row / column direction, and this shape may be changed by the mask pattern.
Referring to FIG. 5, a first semiconductor layer 130 is disposed on the mask layer 120, an active layer 140 is disposed on the first semiconductor layer 130, and a second conductive semiconductor layer 150 is disposed on the active layer 140. It may be formed in the order of.
A plurality of rods 132 are formed in the rod hole 122 of FIG. 3 under the first semiconductor layer 130. The plurality of rods 132 may be formed in the same shape as the rod hole shape.
The plurality of rods 132 may be disposed in the mask layer 120 and may be formed of the same or different semiconductors as the first semiconductor layer 130. For example, the plurality of rods 132 may be formed of an undoped semiconductor made of a group III-V compound semiconductor or a semiconductor doped with a conductive dopant.
The first semiconductor layer 130 may have an upper region except for the plurality of rods 132 having a single layer structure or a multilayer structure. The single layer structure may be formed of a first conductive semiconductor layer, and the multilayer structure may include a structure in which an undoped semiconductor layer is formed in a lower layer and a first conductive semiconductor layer is formed in an upper layer.
The Group III-V compound semiconductor includes, for example, a semiconductor such as GaN, InN, AlN, InGaN, AlGaN, InAlGaN, AlInN, AlGaAs, GaP, GaAs, GaAsP, AlGaInP, and the like. The first conductive dopant may be doped into the Group III-V compound semiconductor. When the first conductive semiconductor layer is an N-type semiconductor layer, the first conductive dopant is an N-type dopant and includes Si, Ge, Sn, Se, and Te.
The growth equipment of the Group III-V group nitride semiconductors includes electron beam evaporators, physical vapor deposition (PVD), chemical vapor deposition (CVD), plasma laser deposition (PLD), and dual-type thermal evaporator sputtering. ), Metal organic chemical vapor deposition (MOCVD), and the like, but is not limited thereto.
After the first semiconductor layer 130 is grown from the plurality of rods 132, the first semiconductor layer 130 is grown to further promote horizontal growth on the mask layer 120 and is sealed on the mask layer 120. The first semiconductor layer 130 may be grown to have an upper surface flat.
When the first semiconductor layer 130 and the plurality of rods 132 are GaN, they may be formed by CVD (or MOCVD). For example, a group gas such as trimethylgallium (TMGa) or triethylgallium (TEGa) is used for the source gas for Ga, and ammonia (NH 3 ), monomethylhydrazine (MMHy) or Group 5 gases such as dimethylhydrazine (DMHy) can be used.
The first semiconductor layer 130 may be grown by controlling growth conditions such as a growth temperature, a ratio of a Group 5 gas to a Group 3 gas, and a growth pressure. In this case, the first semiconductor layer 130 is grown from the rod hole (122 in FIG. 3) at the initial stage of growth (vertical growth promoting condition), and is grown on the mask layer 120 as the growth time passes. Suture (horizontal growth promoting condition). When the first semiconductor layer 130 is grown, a first conductive dopant may be added.
The vertical growth promoting condition increases the pressure, lowers the growth temperature, and the Ga flow rate allows vertical growth using a number of conditions selectively. In addition, the horizontal growth promoting conditions may be grown by controlling the vertical growth conditions in the opposite direction, such as gradually increasing the growth temperature of the vertical growth promoting conditions. These growth conditions can be adjusted within the technical scope of the embodiment.
After the first semiconductor layer 130 is grown through the plurality of rods 132 in the mask layer 120, the first semiconductor layer 130 is grown through horizontal growth promoting conditions, thereby causing defects in the first semiconductor layer 130. Can be minimized. That is, defects due to lattice mismatch with the substrate 110 can be reduced.
An active layer 140 is formed on the first semiconductor layer 130, and a second conductive semiconductor layer 150 is formed on the active layer 140. The active layer 140 may be formed of a single quantum well structure or a multi quantum well structure, and may include a material that emits colored light such as light of blue wavelength, light of red wavelength, and light of green wavelength. A conductive clad layer may be formed on or under the active layer 140, and the conductive clad layer may be formed of an AlGaN-based semiconductor.
The second conductive semiconductor layer 150 is a semiconductor semiconductor doped with a second conductive dopant, for example, a compound semiconductor such as GaN, InN, AlN, InGaN, AlGaN, InAlGaN, AlInN, AlGaAs, GaP, GaAs, GaAsP, AlGaInP, or the like. It can be made of either. When the second conductive semiconductor layer 150 is a P-type semiconductor layer, the second conductive dopant may be a P-type dopant, and at least one of Mg, Zn, Ca, Sr, and Ba may be added.
The second conductive semiconductor layer 150 may be selectively formed from a transparent electrode layer (not shown), a reflective electrode layer (not shown), and a first electrode (not shown). The transparent electrode layer may be formed by selecting from materials of ITO, ZnO, IrOx, RuOx, NiO. The reflective electrode layer may optionally include Al, Ag, Pd, Rh, Pt, Ir, and the like.
In the semiconductor light emitting device 100, when the first semiconductor layer 130 includes a P-type semiconductor layer, the second conductive semiconductor layer 150 may be implemented as an N-type semiconductor layer. In addition, an N-type semiconductor layer or a P-type semiconductor layer may be formed on the second conductive semiconductor layer 150. Accordingly, the light emitting structure may be implemented as any one of an N-P junction structure, a P-N junction structure, an N-P-N junction structure, and a P-N-P junction structure.
The semiconductor light emitting device 100 grows a plurality of compound semiconductor layers 130, 140, and 150 through a plurality of rods 132 in the mask layer 120, thereby reducing defects due to epitaxial growth and improving light extraction effects. Can be.
6 to 11 show a second embodiment. In the description of the second embodiment, the same parts as in the first embodiment are referred to the first embodiment, and redundant description thereof will be omitted.
6 is a semiconductor light emitting device according to the second embodiment, and FIG. 7 is a cross-sectional view taken along the line A-A of FIG.
6 and 7, the semiconductor light emitting device 101 may include a substrate 110, an air gap 124, a first semiconductor layer 130 including a plurality of rods 132, an active layer 140, and The second conductive semiconductor layer 150 is included.
A buffer layer (not shown) may be formed on the substrate 110, but is not limited thereto. The plurality of rods 132 may be disposed on the substrate 110 or the buffer layer.
An air gap part 124 is formed between the plurality of rods 132. The air gap part 124 may be formed in a part or the entire area of the region in which the plurality of rods 132 are disposed. The air gap portion 124 may be formed in at least an outer circumferential region between the first semiconductor layer 130 and the substrate 110.
As shown in FIG. 7, the air gap part 124 may be formed in all regions except for the plurality of rods 132, in which case the entire mask layer of FIG. 4 is removed. When the air gap portion 124 is formed around the upper outer circumference of the substrate 110, the outer circumference of the mask layer of FIG. 4 is removed.
Since the first semiconductor layer 130 is formed through the plurality of rods 132 in the mask layer 120 (FIG. 1), crystal defects may be improved.
In addition, the refractive index of the first semiconductor layer 130 is 2.12 ~ 2.44, the refractive index of the air gap portion 124 is 1. Due to the difference in refractive index, the critical angle of the light traveling through the first semiconductor layer 130 and the air gap part 124 may be changed, so that light extraction may be improved.
When a mask layer (120 of FIG. 1) such as SiO 2 is present under the first semiconductor layer 130, the refractive index of SiO 2 is 1.544 to 1.553. Light incident by the medium difference between the first semiconductor layer 130 having the rod 132, the air gap portion 124, and the mask layer 120 (FIG. 1) may be reflected or a critical angle of the light may be changed, The total internal reflection rate can be reduced and the light extraction efficiency can be improved.
8 to 11 are views illustrating a manufacturing process of the second embodiment.
Referring to FIG. 8, a mask layer 120 on the substrate 110, a first semiconductor layer 130 having a plurality of rods 132, and an active layer 140 and a second conductive layer on the first semiconductor layer 130. The type semiconductor layer 150 is sequentially formed. This process will be referred to the first embodiment.
As the first semiconductor layer 124 is grown through the plurality of rods 122 in the mask layer 120, crystal defects may be improved.
Referring to FIG. 9, at least one hole 161 is formed along the chip 1 CHIP boundary region through mesa etching. The hole 161 is formed from the second conductive semiconductor layer 150 to the mask layer 120 along the periphery of the chip boundary, and may be formed in a strip shape or a plurality of holes. It is not limited.
By injecting a wet etching solution through the holes 161, a part or the entirety of the mask layer 120 may be removed. The wet etching solution may be etched using HF or / and NH 4 F, and the like, but is not limited thereto.
The mask layer 120 may be removed by exposing a chip boundary region through mesa etching, forming a separate hole after growth of a specific semiconductor layer, or removing after manufacturing a final device. May be changed within the technical scope of the embodiment.
When the mask layer 120 is removed, as shown in FIGS. 10 and 11, the mask layer region is formed of an air gap portion 124. The air gap portion 124 is a pupil region, and is formed between the plurality of rods 132. FIG. 11 is a cross-sectional view of the A-A side of FIG. 10.
Here, the air gap portion 124 may be etched in at least the chip circumferential region (G1 of FIG. 11) by the etching of the mask layer 120 around the chip boundary, or extended inwardly through the chip circumferential region. It may be formed in the form.
The refractive index of the first semiconductor layer 130 is 2.12 to 2.44, and the refractive index of the air gap portion 124 is 1. Due to the difference in refractive index, the first semiconductor layer 130 and the air gap portion 124 may change the critical angle of the light L3 that travels, and thus the light extraction effect may be improved. The air gap part 124 may improve light extraction by providing a two-dimensional photonic crystal structure under the first semiconductor layer 130.
When the first part of the mask layer (120 in FIG. 8), such as SiO 2 are below the semiconductor layer 130, the refractive index of SiO 2 is a 1.544 ~ 1.553. Accordingly, by reflecting the light by the refractive index difference of the medium such as the rod 132, the air gap 124, the mask layer (120 of FIG. 8), or by changing the critical angle of the light, to reduce the total internal reflection ratio of the light It can improve the extraction efficiency.
12 is a side cross-sectional view of a semiconductor light emitting device according to a third embodiment, and FIG. 13 is a cross-sectional view taken along the line B-B of FIG. 12. In the description of the third embodiment, the same parts as those of the first and second embodiments are referred to the first and second embodiments, and redundant description thereof will be omitted.
12 and 13, the semiconductor light emitting device 102 includes a plurality of rods 132A and air gap portions 124A arranged in a zigzag on the substrate 110. The air gap portion 124A is formed in a two-dimensional photonic crystal structure between the first semiconductor layer 130 and the substrate 110, so that some light L4 emitted from the active layer 140 is passed through the air gap portion 124A. The light L5 traveling to the air gap portion 124A is changed or reflected by the critical angle, thereby improving the light extraction effect as a whole.
14 is a side cross-sectional view of a semiconductor light emitting device according to the fourth embodiment. In the description of the fourth embodiment, the same parts as in the embodiment (s) will be referred to, and duplicate description thereof will be omitted.
Referring to FIG. 14, the semiconductor light emitting device 103 includes a plurality of rods 132B and an air gap portion 124B on the substrate 110. The air gap portion 124B may be formed in a two-dimensional photonic crystal structure between the first semiconductor layer 130 and the substrate 110. In this case, the plurality of rods 132B may be formed in a shape having a larger upper diameter than a lower diameter, for example, a rhombic shape, a cone, or a polygonal pyramid shape. The shape of the plurality of rods 132B may vary by rod holes (see FIG. 3), but is not limited thereto.
The air gap portion 124B disposed between the plurality of rods 132B may be formed to be inclined at a bonding surface with the plurality of rods 132B, and may improve light extraction efficiency.
In the semiconductor light emitting device 103, some light L6 emitted from the active layer 140 proceeds to the air gap part 124B, and the critical angle of the light L7 passing through the air gap part 124B is changed. Can be reflected or reflected to improve the overall light extraction effect.
15 is a side cross-sectional view of a semiconductor light emitting device according to a fifth embodiment. In the description of the fifth embodiment, the same parts as in the embodiment (s) will be referred to, and descriptions thereof will not be repeated.
Referring to FIG. 15, the semiconductor light emitting device 103 includes a first semiconductor layer 130A having a plurality of rods 133 and first uneven patterns 134 and 135 on the substrate 110. An air gap 125 is formed between the rod 133 disposed in the space between the first semiconductor layer 130A and the first substrate 110.
First uneven patterns 134 and 135 are formed on a lower surface of the first semiconductor layer 130A, and the first uneven patterns 134 and 135 partially or partially mask the mask layer 120 of FIG. 9 through the second embodiment. After etching the whole, the bottom surface of the first semiconductor layer 130A may be etched through the air gap space where the mask layer is etched. Since the N-polarity crystal plane is disposed on the bottom surface of the first semiconductor layer 130A, the roughness-shaped first uneven patterns 134 and 135 may be formed by wet etching. In this case, the rod 133 of the first semiconductor layer 130A may be formed thicker than the thickness of the mask layer 120 of FIG. 9 by etching the bottom surface of the first semiconductor layer 130A.
Here, the thickness T2 that is not etched in the first semiconductor layer 130A may be etched to an extent that does not affect the operating characteristics of the first semiconductor layer 130A, but is not limited thereto.
A hybrid photonic crystal structure including first uneven patterns 134 and 135, a plurality of rods 133, and an air gap portion 125 is disposed below the first semiconductor layer 130A, thereby reducing defects due to epitaxial growth, It can improve the extraction effect.
16 is a side cross-sectional view of a semiconductor light emitting device according to a sixth embodiment. In describing the sixth embodiment, the same parts as those of the embodiment (s) will be referred to the embodiment, and description thereof will be omitted.
Referring to FIG. 16, in the semiconductor light emitting device 104, second uneven patterns 112 and 113 are formed on an upper surface of the substrate 110A, and first uneven patterns 134 and 135 on the bottom surface of the first semiconductor layer 130A. The air gap 125 and the plurality of rods 133 are formed.
The second uneven patterns 112 and 113 formed on the upper surface of the substrate 110A may be formed in a roughness shape by a wet etching method and / or a dry etching method before the mask layer of FIG. 2 is grown.
The shape of the second uneven patterns 112 and 113 may be formed in a mesh shape or a stripe shape such as a polygonal shape or a lens shape such as a triangle, but is not limited thereto.
First uneven patterns 134 and 135 are formed on a bottom surface of the first semiconductor layer 130A, and a plurality of rods 133 and air gap portions 125 are disposed between the first semiconductor layer 130A and the substrate 110A. Is placed.
The first concave-convex patterns 134 and 135 may remove the mask layer (120 of FIG. 9) through the second embodiment, and then etch the bottom surface of the first semiconductor layer 130A on which the mask layer is etched. Since the N-polarity crystal plane is disposed on the bottom surface of the first semiconductor layer 130A, the first semiconductor layer 130A may be etched into the roughness-shaped first uneven patterns 134 and 135 by wet etching.
The mask layer may be removed even in a wafer state, which is a step before separation from the chip, and is not limited thereto.
Under the first semiconductor layer 130A, a hybrid photonic crystal structure including a first uneven pattern 134 and 135, a plurality of rods 133, an air gap portion 125, and a second uneven pattern 112 and 113 may be disposed. It is possible to reduce defects due to epitaxial growth and to change or reflect the critical angle of the light traveling in the downward direction of the first semiconductor layer 130A, thereby improving the light extraction effect.
Here, the first uneven patterns 134 and 135 on the bottom surface of the first semiconductor layer 130A may not be formed.
17 is a side cross-sectional view of a semiconductor light emitting device according to a seventh embodiment. In describing the seventh embodiment, the same parts as the embodiment (s) are referred to the embodiment, and redundant description thereof will be omitted.
Referring to FIG. 17, the semiconductor light emitting device 105 may include at least one layer including compound semiconductors (eg, ZnO, GaN, etc.) of Groups 2, 3, 4, 5, and 6 on the substrate 110. The second semiconductor layer 115 may be formed. The second semiconductor layer 115 may be formed under the plurality of rods 132 and the mask layer 120 of the first semiconductor layer 130. The second semiconductor layer 115 may be formed in a pattern shape or a layer shape, but is not limited thereto.
18 is a side cross-sectional view illustrating a horizontal semiconductor light emitting device using FIG. 6.
Referring to FIG. 18, the semiconductor light emitting device 101A forms a second electrode 163 on the second conductive semiconductor layer 150, and forms a first electrode 161 on the first semiconductor layer 130. Done. The first semiconductor layer 130 or the upper layer may be a first conductive semiconductor layer, and the plurality of rods 132 may be an undoped semiconductor layer or a first conductive semiconductor layer.
In addition, the light emitting device of the first to sixth embodiments may be implemented as a horizontal semiconductor light emitting device. In addition, a reflective electrode layer or a transparent electrode layer may be formed on the second conductive semiconductor layer 150 after or before the second electrode 163 is formed, but is not limited thereto.
19 is a side cross-sectional view illustrating a vertical semiconductor light emitting device using FIG. 6.
Referring to FIG. 19, the semiconductor light emitting device 101B forms an electrode layer 155 on the second conductive semiconductor layer 150 and a conductive support member 156 on the electrode layer 155. The electrode layer 155 may optionally include Al, Ag, Pd, Rh, Pt, Ir, and the like, and the conductive support member 156 may be copper (Cu-copper), gold (Au-gold), or nickel (Ni-). nickel), molybdenum (Mo), copper-tungsten (Cu-W), carrier wafers (eg, Si, Ge, GaAs, ZnO, SiC, etc.) may be optionally included.
After removing the substrate (110 of FIG. 6) under the first semiconductor layer 130, the first electrode 161 is formed under the first semiconductor layer 130. The removal method of the substrate (110 in FIG. 6) may be removed by a laser lift off (LLO) method. The substrate removal order may be performed in the mask layer (120 in FIG. 8) after the formation of the conductive support member 156. It may be removed before or after the wet etch on. Here, the wet etching of the mask layer may be performed after the formation of the second conductive semiconductor layer 150 or / and after forming the conductive support member 156 and then forming a hole in the substrate.
Here, when the substrate is removed, the substrate (110 in FIG. 6) is separated from the rod of the first semiconductor layer 130, so that the gas between the rods is discharged to the outside through the air, and thus, the coefficient of thermal expansion is different. By minimizing the area where crack defects propagate into the semiconductor layer can improve device yield and reliability. That is, the rod 132 of the first semiconductor layer 130 can reduce the damage of the semiconductor layer crystal structure by the LLO method.
The mask layer 120 (refer to FIG. 8) may remove the substrate (110 of FIG. 8) and then remove some or all of the mask layer through wet etching. In this case, the mask layer removal method may selectively use a first removal process using FIG. 9 and a second removal process after removing the substrate.
When the substrate is removed, when the rod size of the first semiconductor layer 130 is a relatively narrow diameter, the wet etching rate of the lower rod of the first semiconductor layer 130 may proceed relatively quickly, and a stable LLO may be performed. It can provide a way.
A process of polishing the lower surface of the first nitride semiconductor layer 125 from which the substrate 110 is removed by Inductively Coupled Plasma / Reactive Ion Etching (ICP / RIE) may be performed. I do not. In this case, part of the rod 132 may be removed.
The first electrode 161 may be formed before or after chip separation, but is not limited thereto. The surface under the first semiconductor layer 130 may be removed from the rod, and a conductive semiconductor having a simple flat layer or an uneven pattern may be formed. These features can be changed within the technical scope of the embodiment.
The semiconductor light emitting device 101B is separated by a chip unit by using an expanding and breaking process after the mesa etching. The embodiment has described a semiconductor light emitting device, for example, an LED, as an example, but can be applied to other semiconductor devices that can be formed on the substrate, and the technical features are not limited to the above embodiments.
The first electrode 161 may directly contact the plurality of rods 132 and the first semiconductor layer 130. In this case, the plurality of rods 132 may be an undoped semiconductor layer or a first conductive semiconductor layer, and the first semiconductor layer 130 may be implemented as a first conductive semiconductor layer. Since the plurality of rods 132 operate under roughness under the first semiconductor layer 130, the rods 132 may improve the light extraction effect.
The semiconductor light emitting device may be implemented as a vertical semiconductor light emitting device with respect to the light emitting device according to the first to seventh embodiments.
2 to 5 are views illustrating a manufacturing process of the semiconductor light emitting device of FIG. 1.
8 to 11 illustrate a process of manufacturing the semiconductor light emitting device of FIG. 6.
12 is a side cross-sectional view illustrating a semiconductor light emitting device according to a third embodiment.
FIG. 13 is a sectional view taken along the line B-B in FIG.
14 is a side sectional view showing a semiconductor light emitting device according to the fourth embodiment.
15 is a side cross-sectional view illustrating a semiconductor light emitting device according to a fifth embodiment.
16 is a side sectional view showing a semiconductor light emitting device according to the sixth embodiment.
17 is a side cross-sectional view illustrating a semiconductor light emitting device according to a seventh embodiment.
A first semiconductor layer having a plurality of rods formed below;
An uneven pattern on a bottom surface of the first semiconductor layer;
An air gap portion formed between the rods of the first semiconductor layer; And
It includes a plurality of compound semiconductor layer formed on the first semiconductor layer,
And a lower surface of the first semiconductor layer corresponds to a region of the air gap portion.
A first semiconductor layer disposed on the substrate and having a plurality of rods thereunder;
An uneven pattern on at least one of a lower surface of the first semiconductor layer and an upper surface of the substrate;
An air gap portion between the first semiconductor layer and the substrate; And
The semiconductor light emitting device of claim 1, further comprising at least one second semiconductor layer including a group 2 to 6 compound semiconductor under the rod of the first semiconductor layer.
The semiconductor light emitting device of claim 1, further comprising at least one of a substrate and a first electrode disposed under the rod of the first semiconductor layer.
The semiconductor light emitting device of claim 1, wherein the first semiconductor layer comprises at least one of an undoped semiconductor layer and a first conductive semiconductor layer.
The semiconductor light emitting device of claim 1 or 2, further comprising a mask layer in a partial region between the rods of the first semiconductor layer.
The semiconductor light emitting device of claim 6, wherein the air gap portion is formed at an outer periphery under the first semiconductor layer.
The semiconductor light emitting device of claim 1, wherein a shape of the rod includes a columnar shape or a horn shape, and the plurality of rods are arranged at regular or irregular intervals.
The semiconductor light emitting device of claim 2, wherein the uneven pattern includes a first uneven pattern on a lower surface of the first semiconductor layer and a second uneven pattern on an upper surface of the substrate.
The semiconductor light emitting device of claim 1, wherein the plurality of compound semiconductor layers comprises an active layer and a second conductive semiconductor layer formed on the active layer.
The semiconductor light emitting device of claim 10, further comprising at least one of a second electrode, a reflective electrode layer, a transparent electrode layer, and an N-type semiconductor layer formed on the second conductive semiconductor layer.
The semiconductor light emitting device of claim 2, wherein the air gap portion is disposed between the rods of the first semiconductor layer, and the uneven pattern is disposed to correspond to a region of the air gap portion.
Forming a mask layer having a plurality of rod holes on the substrate;
Forming a plurality of compound semiconductor layers on the mask layer;
Exposing a portion of the mask layer; And
Wet etching the mask layer to form an air gap portion,
And at least one of an upper surface of the substrate and a lower surface of the plurality of compound semiconductor layers.
The method of claim 13, wherein the rod hole comprises at least one of a pillar shape, a horn shape, and a horn shape.
The semiconductor device of claim 13, wherein the plurality of compound semiconductor layers comprises: a first semiconductor layer having a plurality of rods formed through the rod holes on the mask layer; And a light emitting structure formed on the first semiconductor layer.
The method of claim 15, wherein the first semiconductor layer comprises an undoped semiconductor or a semiconductor doped with a first conductive dopant.
The method of claim 13, wherein the air gap portion is formed by etching an outer region or an entire region of the mask layer.
The method of claim 13, wherein the concave-convex pattern is formed on a lower surface of the compound semiconductor layer and is disposed to correspond to an area of the air gap portion.
The method of claim 13, wherein the uneven pattern includes a first uneven pattern formed on a lower surface of the compound semiconductor layer and a second uneven pattern formed on an upper surface of the substrate.
The method of claim 13, further comprising forming a buffer layer including a group III-V compound semiconductor between the substrate and the mask layer.
The method of claim 15, further comprising: forming an electrode layer on the light emitting structure; Removing the substrate under the plurality of rods; And forming a first electrode on the plurality of rods.
KR1020090044291A 2009-05-21 2009-05-21 Semiconductor light emitting device and fabrication method thereof KR101154596B1 (en)
KR1020090044291A KR101154596B1 (en) 2009-05-21 2009-05-21 Semiconductor light emitting device and fabrication method thereof
EP10163214.9A EP2254167B1 (en) 2009-05-21 2010-05-19 Light emitting device
US12/783,741 US8384106B2 (en) 2009-05-21 2010-05-20 Light emitting device and light emitting device package having the same
CN 201010184458 CN101894894B (en) 2009-05-21 2010-05-21 Light emitting device and light emitting device package having the same
KR20100125532A KR20100125532A (en) 2010-12-01
KR101154596B1 true KR101154596B1 (en) 2012-06-08
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KR101136064B1 (en) * 2010-06-14 2012-04-18 전북대학교산학협력단 Nitride Semiconductor Light emitting device and fabrication method thereof
CN102709410B (en) * 2012-06-04 2014-08-27 中国科学院半导体研究所 Method for manufacturing nanometer column LED (Light Emitting Diode)
CN102683522B (en) * 2012-06-04 2014-11-19 中国科学院半导体研究所 Manufacture method of light-emitting diode with air bridge structure
CN102709411B (en) * 2012-06-04 2014-08-20 中国科学院半导体研究所 Vertically-structured LED manufacturing method based on wet lift-off
JP2007088165A (en) 2005-09-21 2007-04-05 Hamamatsu Photonics Kk Compound semiconductor substrate, manufacturing method thereof, and compound semiconductor device
KR101316120B1 (en) 2006-12-28 2013-10-11 서울바이오시스 주식회사 Fabrication method of light emitting device having scattering center using anodic aluminum oxide and light emitting device thereby
KR20080093557A (en) 2007-04-17 2008-10-22 엘지이노텍 주식회사 Nitride light emitting device
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