Source: https://patents.google.com/patent/JP4429306B2/en
Timestamp: 2020-01-20 09:32:43
Document Index: 47091792

Matched Legal Cases: ['art 20', 'art 20', 'art 30', 'art 30', 'art 30', 'art 20', 'art 30', 'art 30', 'art 30', 'art 30', 'art 20', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30', 'art 30']

JP4429306B2 - Solar cell and solar cell module - Google Patents
JP4429306B2
JP4429306B2 JP2006347809A JP2006347809A JP4429306B2 JP 4429306 B2 JP4429306 B2 JP 4429306B2 JP 2006347809 A JP2006347809 A JP 2006347809A JP 2006347809 A JP2006347809 A JP 2006347809A JP 4429306 B2 JP4429306 B2 JP 4429306B2
JP2006347809A
JP2008159895A (en
2006-12-25 Application filed by 三洋電機株式会社 filed Critical 三洋電機株式会社
2008-07-10 Publication of JP2008159895A publication Critical patent/JP2008159895A/en
2010-03-10 Publication of JP4429306B2 publication Critical patent/JP4429306B2/en
The present invention is a solar battery cell including a photoelectric conversion unit and finger electrodes stacked on the photoelectric conversion unit, and electrically connected to each other by a wiring tab between the surface protection material and the back surface protection material. The present invention relates to a solar cell module including a plurality of solar cells.
In recent years, development of high-efficiency technologies for improving electric output per unit area has been energetically advanced for solar cell modules.
A conventional solar cell module includes a plurality of solar cells electrically connected to each other by a wiring tab between a front surface protective material and a back surface protective material. The solar battery cell includes a photoelectric conversion unit and a plurality of finger electrodes stacked on the photoelectric conversion unit. FIG. 1 is a top view of the solar battery cell 10.
Generally, the electrical output of the solar cell module 1 is proportional to the light receiving area. That is, if the light receiving area of the solar cell module 1 is increased, a larger electrical output can be obtained.
Therefore, the electrical output of the solar cell module can be increased by reducing the width of the finger electrode 30 stacked on the photoelectric conversion unit 20 and reducing the area that blocks incident light.
Here, since the linear expansion coefficients of the respective materials used for the photoelectric conversion unit 20, the finger electrode 30, and the tab 40 are different, the solar battery cell is changed due to a temperature change when the tab 40 is soldered to the solar battery cell. In the intersecting region α between 10 and the tab 40, stress is generated between the respective materials. Also, stress between such materials is generated by temperature changes in the actual use environment.
Therefore, if the width of the finger electrode 30 is reduced in order to increase the electrical output of the solar cell module, there is a high possibility that the finger electrode 30 is disconnected due to the stress in the intersection region α. FIG. 2 is an enlarged view of portion A in FIG.
In order to avoid disconnection of the finger electrode 30, as shown in FIGS. 2B and 2C, the finger electrode 30 may be widened at the root of the intersecting region α (see, for example, Patent Document 1). .
JP 2003-338631 A
However, as shown in FIGS. 2B and 2C, even if the finger electrode 30 is widened at the base of the intersecting region α, the finger electrode 30 is caused by stress concentrated on a portion where the width of the finger electrode 30 changes. Therefore, the finger electrode 30 cannot be disconnected.
Thus, if the finger electrode 30 is disconnected, the photogenerated carriers in the peripheral region of the finger electrode 30 cannot be collected, and there is a problem that the electric output of the solar cell module is reduced.
Then, this invention is made | formed in view of said problem, and even if the disconnection of a finger electrode generate | occur | produces, providing a photovoltaic cell and a photovoltaic module which can suppress the fall of an electrical output. Objective.
The photovoltaic cell according to the first aspect of the present invention is a photovoltaic cell electrically connected to another photovoltaic cell by a wiring tab, and generates photoelectrically generated carriers upon incidence of light. And a plurality of finger electrodes that are stacked on the photoelectric conversion unit and collect the photogenerated carriers from the photoelectric conversion unit, and the tab is directly connected via a conductive adhesive, The gist of the invention is that the electrode branches into a plurality of branches in the intersection region intersecting the tab, and the branch point of the branch is arranged in the vicinity of the intersection region.
In the solar battery cell according to the first feature of the present invention, one finger electrode is branched into a plurality of branches in a region intersecting with a tab that collects photogenerated carriers from the finger electrode. Moreover, the branch point of each branch part is separated from the intersection region .
Therefore, according to the solar cell according to the first feature of the present invention, even if a part of the branch portion of one finger electrode is disconnected due to the stress generated due to the temperature change in the intersection region, the disconnection is caused. Since the photogenerated carriers can be collected through the branches that are not formed, a decrease in electrical output can be suppressed.
A second feature of the present invention relates to the first feature of the present invention, and is summarized in that the branch portion is in contact with a branch portion of another finger electrode.
A third feature of the present invention is a solar cell module comprising a plurality of solar cells electrically connected to each other by a wiring tab between a front surface protective material and a back surface protective material, wherein the solar cell The cell is stacked on the photoelectric conversion unit that generates a photogenerated carrier upon incidence of light, and collects the photogenerated carrier from the photoelectric conversion unit, and the tab is interposed via a conductive adhesive. A plurality of finger electrodes that are directly connected to each other, wherein the plurality of finger electrodes are arranged on the photoelectric conversion unit, intersect the tab, and the finger electrode intersects the tab The branching point is branched into a plurality of branch parts, and the branch point of the branch part is arranged in the vicinity of the intersecting region.
In the solar battery cell included in the solar battery module according to the third feature of the present invention, one finger electrode is branched into a plurality of branches in a region intersecting with a tab that collects photogenerated carriers from the finger electrode. . Moreover, the branch point of each branch part is spaced apart from the tab .
Therefore, according to the solar cell module according to the third feature of the present invention, even if a part of the branch portion of one finger electrode is disconnected due to the stress generated due to the temperature change in the intersection region, the disconnection is caused. Since the photogenerated carriers can be collected through the branches that are not formed, a decrease in electrical output can be suppressed.
A fourth feature of the present invention relates to the third feature of the present invention, and is summarized in that the branch portion is in contact with a branch portion of another finger electrode.
ADVANTAGE OF THE INVENTION According to this invention, even if disconnection of a finger electrode generate | occur | produces, the photovoltaic cell and solar cell module which can suppress the fall of an electrical output can be provided.
Next, a first embodiment of the present invention will be described with reference to the drawings. In the following description of the drawings, the same or similar parts are denoted by the same or similar reference numerals. However, it should be noted that the drawings are schematic and ratios of dimensions and the like are different from actual ones. Accordingly, specific dimensions and the like should be determined in consideration of the following description. Moreover, it is a matter of course that portions having different dimensional relationships and ratios are included between the drawings.
<Schematic configuration of solar cell module 1>
FIG. 3 is a cross-sectional view of the solar cell module 1 according to the present embodiment. The cross section of the solar battery cell 10 shown in FIG. 3 is a cross section taken along the line BB ′ (region where the finger electrode 30 and the bus bar electrode 35 intersect) in FIG. In addition, since the upper surface schematic of the photovoltaic cell 10 which concerns on this embodiment is the same as that of FIG. 1, it demonstrates, referring FIG. 1 suitably.
The solar cell module 1 according to this embodiment includes a plurality of solar cells 10, a tab 40, a sealing material 50, a surface protection material 60 and a back surface protection material 70. The solar cell module 1 includes a plurality of solar cells 10 that are electrically connected to each other by a wiring tab 40 between a front surface protective material 60 and a back surface protective material 70.
The solar battery cell 10 includes a photoelectric conversion unit 20, a plurality of finger electrodes 30, and a bus bar electrode 35. The detailed configuration of the solar battery cell 10 will be described in detail later.
The tab 40 is a conductive material such as copper formed into a thin plate shape or a twisted wire shape. One tab 40 has a bus bar electrode 35 provided on the light incident surface of one solar cell 10 and a bus bar electrode 35 provided on the back surface of another solar cell 10 adjacent to the one solar cell 10. And are connected via solder or the like. In the present embodiment, the “conductor” of the present invention includes a bus bar electrode 35 and a tab 40, and the tab 40 is supported by the bus bar electrode 35. As described above, one solar battery cell 10 and another solar battery cell 10 adjacent to the one solar battery cell 10 are electrically connected in series.
The sealing material 50 seals the plurality of solar cells 10 electrically connected in series with each other by the tab 40. As the sealing material 50, a light-transmitting resin such as EVA, EEA, PVB, silicon, urethane, acrylic, or epoxy can be used.
The surface protective material 60 is disposed on the light incident surface of the sealing material 50. As the surface protective material 60, glass having translucency and water shielding property, translucent plastic, or the like can be used.
The back surface protective material 70 is disposed on the back surface of the sealing material 50. As the back surface protective material 70, a resin film such as PET (Polyethylene Terephthalate), a laminated film having a structure in which an Al night is sandwiched between resin films, or the like can be used.
Although the solar cell module 1 is configured as described above, an Al frame (not shown) can be attached around the solar cell module 1 in order to further increase the strength of the module and firmly attach it to the gantry.
<Configuration of Solar Cell 10>
The solar battery cell 10 includes a photoelectric conversion unit 20, finger electrodes 30, and bus bar electrodes 35.
The photoelectric conversion unit 20 generates a photogenerated carrier by light incident from a light incident surface on which the surface protective material 60 is disposed. The photogenerated carrier refers to holes and electrons generated when incident light is absorbed by the photoelectric conversion unit 20. The photoelectric conversion unit 20 has a semiconductor junction such as a pn junction or a pin junction. The photoelectric conversion unit 20 includes a semiconductor material such as a crystalline semiconductor material such as single crystal Si or polycrystalline Si, a thin film semiconductor material such as an amorphous Si alloy or CuInSe, or a compound semiconductor material such as GaAs or InP, or a dye. An organic material such as a sensitizing type can be used.
The finger electrode 30 is an electrode that collects photogenerated carriers from the photoelectric conversion unit 20. As shown in FIG. 3, the finger electrode 30 according to the present embodiment has a line shape with a predetermined interval over almost the entire area of the light incident surface of the photoelectric conversion unit 20 and the back surface of the photoelectric conversion unit 20 (the surface opposite to the light incident surface). Formed.
In addition, the electrode laminated | stacked on the back surface of the photoelectric conversion part 20 may be formed so that the whole back surface of the photoelectric conversion part 20 may be covered. The present invention does not limit the shape of the electrode provided on the back surface of the photoelectric conversion unit 20. In the present embodiment, as an example, the solar battery cell 10 including a plurality of finger electrodes 30 on the back surface of the photoelectric conversion unit 20 will be described.
The bus bar electrode 35 is an electrode that collects photogenerated carriers from the plurality of finger electrodes 30. As shown in FIG. 3, the bus bar electrode 35 according to the present embodiment is formed in a line shape with a predetermined interval so as to intersect the finger electrode 30. The number of bus bar electrodes 35 is set to an appropriate number in consideration of the size and resistance of the solar battery cell 10. The solar battery cell 10 according to this embodiment includes two bus bar electrodes 35.
Therefore, in this embodiment, the plurality of finger electrodes 30 and the bus bar electrodes 35 are formed in a comb shape on the light incident surface and the back surface of the photoelectric conversion unit 20. The intersecting region α where the finger electrode 30 and the bus bar electrode 35 intersect will be described in detail later because it is a feature of the present invention.
Here, it is desirable that the finger electrode 30 and the bus bar electrode 35 according to the present embodiment be formed of a conductive paste that is cured in a temperature range in which thermal damage to the semiconductor layer in the photoelectric conversion unit 20 is small. When the photoelectric conversion unit 20 includes an amorphous semiconductor layer, a resin-type conductive paste using a resin material as a binder and conductive particles such as silver particles as a filler is used as such a conductive paste. Can do.
The binder is a resin material whose main purpose is to adhere. The binder is required to have excellent moisture resistance and heat resistance in order to maintain reliability. As such a binder, one kind selected from an epoxy resin, an acrylic resin, a polyimide resin, a phenol resin, a urethane resin, a silicon resin, or a mixture of these resins, a copolymer, or the like can be used.
The main purpose of the filler is to obtain electrical conductivity. As the filler, at least one metal particle selected from aluminum, nickel, tin, gold and the like, or an alloy thereof can be used. In addition, the filler may be one in which at least one inorganic oxide selected from alumina, silica, titanium oxide, glass and the like is subjected to metal coding, epoxy resin, acrylic resin, polyimide resin, phenol resin, urethane. A metal coating may be applied to at least one selected from a resin, a silicon resin, or the like, or a copolymer or mixture of these resins.
Next, the configuration of an example of the solar battery cell 10 according to the present embodiment will be described focusing on the configuration of the photoelectric conversion unit 20. 4 is a cross-sectional view taken along the line CC ′ of FIG.
As shown in FIG. 4, the photoelectric conversion unit 20 includes ITO films 20a and 20g, a p-type amorphous silicon layer 20b, i-type amorphous silicon layers 20c and 20e, an n-type single crystal silicon substrate 20d, an n-type non-crystal. A crystalline silicon layer 20f is provided.
A p-type amorphous silicon layer 20b is formed on the light incident surface of the n-type single crystal silicon substrate 20d via an i-type amorphous silicon layer 20c. An ITO film 20a is formed on the light incident surface of the p-type amorphous silicon layer 20b. On the other hand, an n-type amorphous silicon layer 20f is formed on the back surface of the n-type single crystal silicon substrate 20d via an i-type amorphous silicon layer 20e. An ITO film 20g is formed on the back side of the n-type amorphous silicon layer 20f.
The finger electrode 30 and the bus bar electrode 35 are formed on the light incident surface of the ITO film 20a and the back surface of the ITO film 20g.
The solar cell module 1 having the solar cell 10 having such a configuration is referred to as a HIT solar cell module.
As shown in FIG. 3, the solar battery cell 10 having the above configuration is electrically connected in series with other solar battery cells 10 by a wiring tab 40.
<Shape of Finger Electrode 30 in Crossing Area α>
The shape of the finger electrode 30 in the intersection area | region (alpha) where the finger electrode 30 and the bus-bar electrode 35 cross | intersect is demonstrated using FIG. In the following description, FIG. 1 will be referred to as appropriate.
In the solar cell 10 according to the present embodiment, as shown in FIGS. 1 and 5, the plurality of finger electrodes 30 and the bus bar electrodes 35 are formed in a comb shape on the light incident surface and the back surface of the photoelectric conversion unit 20. ing.
FIG. 5 is an enlarged view of a portion A in FIG. As shown in FIG. 5, the one finger electrode 30 according to the present embodiment branches into two branch portions 30 a in an intersecting region α intersecting with the bus bar electrode 35. Each branch 30 a is in contact with the bus bar electrode 35 that supports the tab 40. Further, the branch point 30 b of the two branch portions 30 a is separated from the bus bar electrode 35.
The finger electrode 30 may be branched into three or more branch portions 30a in the intersection region α.
<Method for Manufacturing Solar Cell Module 1>
A method for manufacturing the solar cell module 1 according to this embodiment will be described. In the following description, please refer to FIG. 3 and FIG. 4 as appropriate.
The n-type single crystal silicon substrate 20d is anisotropically etched with an alkaline aqueous solution to form fine irregularities on the surface. Further, the surface of the n-type single crystal silicon substrate 20d is washed to remove impurities.
Next, an i-type amorphous silicon layer 20c and a p-type amorphous material are formed on the light incident surface of the n-type single crystal silicon substrate 20d by using a vapor phase growth method such as an RF plasma CVD method or a Cat-CVD method. Silicon layers 20b are sequentially stacked. Similarly, an i-type amorphous silicon layer 20e and an n-type amorphous silicon layer 20f are sequentially stacked on the back surface of the n-type single crystal silicon substrate 20d.
Next, an ITO film 20a is formed on the light incident surface of the p-type amorphous silicon layer 20b by using a magnetron sputtering method. Similarly, an ITO film 20g is formed on the back surface of the n-type amorphous silicon layer 20f.
Next, using a printing method such as a screen printing method or an offset printing method, an epoxy thermosetting silver paste is arranged in a predetermined pattern on the light incident surface of the ITO film 20a. Similarly, an epoxy thermosetting silver paste is arranged in a predetermined pattern on the back surface of the ITO film 20g. The silver paste is heated under predetermined conditions to volatilize the solvent, and then further heated to be fully dried. Thereby, the finger electrode 30 and the bus bar electrode 35 are integrally laminated on the photoelectric conversion unit 20.
Here, the predetermined pattern in which the finger electrode 30 and the bus bar electrode 35 are arranged means a comb shape in the present embodiment. That is, the plurality of finger electrodes 30 arranged in parallel lines at a predetermined interval intersect with two bus bar electrodes 35 arranged in parallel lines at a predetermined interval. Furthermore, one finger electrode 30 is branched into a plurality of branch portions 30 a in a region intersecting with the bus bar electrode 35.
Thus, the solar battery cell 10 is manufactured.
Next, the solder is melted by heating while pressing the tab 40 on the bus bar electrode 35, and an alloy layer of the bus bar electrode 35 and the tab 40 is formed. Thereby, one solar cell 10 and another solar cell 10 adjacent to the one solar cell 10 are electrically connected in series.
Next, a plurality of solar cells 10, EVA (sealing material 50) sheets and back surface protection material 70 connected to each other by an EVA (sealing material 50) sheet and tab 40 on a glass substrate (surface protection material 60). Are sequentially laminated to form a laminate. The glass substrate, the EVA sheet, and the back surface protective material 70 have substantially the same outer dimensions. The back surface protective material 70 has a three-layer structure of PET / aluminum / PET.
Next, the laminate is temporarily bonded by thermocompression bonding in a vacuum atmosphere and then completely cured by heating under a predetermined condition.
Thus, the solar cell module 1 is manufactured.
Note that a terminal box, an Al frame, or the like can be attached to the solar cell module 1.
In the solar battery cell 10 included in the solar battery module 1 according to the present embodiment, one finger electrode 30 has a plurality of branch portions 30a in the intersection region α with the bus bar electrode 35 that collects photogenerated carriers from the finger electrode 30. It is branched to. Each branch 30 a is in contact with the bus bar electrode 35. Further, the branch point 30 b of each branch part 30 a is separated from the bus bar electrode 35.
Therefore, even if a part of the branch part 30a in one finger electrode 30 is disconnected due to the stress caused by the temperature change in the intersecting region α, the photogenerated carriers are collected through the branch part 30a that is not disconnected. Can do. Thereby, the fall of the electrical output of the solar cell module 1 can be suppressed.
Moreover, when selecting the material of the photoelectric conversion part 20 and the tab 40, it can select from many materials irrespective of the difference in a linear expansion coefficient.
Next, a second embodiment of the present invention will be described with reference to FIG. The basic configuration and the manufacturing method are the same as those in the first embodiment, and therefore different parts from the first embodiment will be described.
The solar battery cell 10 according to the present embodiment does not include the bus bar 35.
<Configuration of solar cell module 1>
A schematic top view of the solar battery cell 10 according to this embodiment is the same as FIG. 1, and an enlarged view of a portion A in FIG. 1 is the same as FIG. However, the bus bar electrode 35 supporting the tab 40 in the first embodiment does not exist. Therefore, in the present embodiment, the “conductor” of the present invention includes only the tab 40.
The tab 40 is directly connected to the light incident surface of the photoelectric conversion unit 20 in the solar battery cell 10 and the back surface of the photoelectric conversion unit 20 in the other solar battery cell 10 via a conductive adhesive such as solder or conductive resin. It is connected.
The plurality of finger electrodes 30 intersect with the tabs 40 arranged on the photoelectric conversion unit 20. That is, as shown in FIG. 1, the plurality of finger electrodes 30 and the tabs 40 intersect with each other in a comb shape on the photoelectric conversion unit 20. The tab 40 collects photogenerated carriers directly from the plurality of finger electrodes 30.
About another structure, it is the same as that of 1st Embodiment.
<Configuration of Finger Electrode 30 in Crossing Area α>
The shape of the finger electrode 30 in the intersection area | region (alpha) where the finger electrode 30 and the tab 40 cross | intersect is demonstrated using FIG.
One finger electrode 30 according to the present embodiment branches into two branch portions 30a in the intersection region α. Each branch portion 30 a is electrically connected to the tab 40.
FIG. 6 is an enlarged view of a portion A in FIG. As shown in FIGS. 6A to 6C, the branch part 30a of one finger electrode 30 may be separated from the other branch part 30a or may be in contact with each other. In particular, as shown in FIG. 6C, the branch part 30 a of one finger electrode 30 may intersect the branch part 30 a of another finger electrode 30. The finger electrode 30 may be branched into three or more branch portions 30a in the intersection region α.
In any of FIGS. 6A to 6C, the branch point 30b of each branch 30a is separated from the intersection region α.
In 1st Embodiment, the finger electrode 30 and the bus-bar electrode 35 were printed on the photoelectric conversion part 20 in the comb shape using the printing method. On the other hand, in this embodiment, the bus bar electrode 35 is not printed.
The finger electrodes 30 (silver paste) according to this embodiment are arranged in a predetermined pattern shown in FIG. However, as long as one finger electrode 30 branches into a plurality of branch portions 30a in the intersecting region α and the branch portion 30a is electrically connected to the tab 40, there is no shape limitation on the branch portion 30a. Absent.
After the finger electrode 30 is printed, the conductive adhesive is melted or softened by heating while pressing the tab 40 through the conductive adhesive on the photoelectric conversion unit 20, and the photoelectric conversion unit 20 and the tab 40 are bonded. Adhere.
In the solar cell module 1 including the solar battery cell 10 according to the present embodiment, one finger electrode 30 branches into a plurality of branch portions 30a in an intersecting region α with the tab 40 that collects photogenerated carriers from the finger electrode 30. is doing. Each branch 30 a is electrically connected to the tab 40. Further, the branch point 30b of each branch part 30a is separated from the intersection region α.
Therefore, in the intersection region α, even if a part of the branch part 30a in one finger electrode 30 is disconnected due to the stress caused by the temperature change, the photogenerated carriers are collected through the branch part 30a that is not disconnected. Therefore, a decrease in the electric output of the solar cell module 1 can be suppressed.
Furthermore, since the solar cell module 1 including the solar battery cell 10 according to the present embodiment does not include the bus bar electrode 35, the amount of the conductive paste used can be reduced. That is, the manufacturing cost can be greatly reduced.
Next, a third embodiment of the present invention will be described with reference to FIGS. The basic configuration and the manufacturing method are the same as those in the first embodiment, and therefore different parts from the first embodiment will be described.
In the present embodiment, the finger electrodes 30 are arranged in lines and lattices, and the bus bar electrodes 35 are arranged in nodes.
FIG. 7 is a schematic top view of the solar battery cell 10 according to the present embodiment.
As shown in FIG. 7, the finger electrodes 30 according to the present embodiment are formed in a line shape and a lattice shape at predetermined intervals over almost the entire light incident surface and back surface of the photoelectric conversion unit 20.
The bus bar electrode 35 is formed in a region where the tab 40 is disposed. The bus bar electrode 35 is formed on the intersection of the finger electrode 30 formed in a line shape and the finger electrode 30 formed in a lattice shape. That is, the bus bar electrodes 35 are scattered in a node shape along the direction in which the solar cells 10 are electrically connected in series.
The tabs 40 are arranged on the bus bar electrodes 35 scattered in a node shape. Therefore, the tab 40 is supported by the bus bar electrode 35 at the intersection of the finger electrode 30 and the bus bar electrode 35. In the present embodiment, the “conductor” of the present invention includes the tab 40 and the bus bar electrode 35. A portion of the tab 40 that is not supported by the bus bar electrode 35 is directly disposed on the photoelectric conversion unit 20.
The shape of the finger electrode 30 in the intersection region α between the finger electrode 30 and the bus bar electrode 35 will be described with reference to FIG.
FIG. 8 is an enlarged view of a portion A in FIG. In FIG. 8A, one finger electrode 30 is branched into two branch portions 30a in the intersection region α. Each branch 30 a is in contact with the bus bar electrode 35. The bus bar electrode 35 supports the tab 40. Further, the branch point 30 b of each branch part 30 a is separated from the bus bar electrode 35.
In FIG. 8B, one finger electrode 30 is branched into three branch portions 30a in the intersection region α. Of the three branch portions 30 a, one branch portion 30 a is in contact with the bus bar electrode 35, and the second branch portion 30 a is in contact with the branch portions 30 a of the two adjacent finger electrodes 30. The second branch 30a is preferably formed so as to draw a concentric circle with the bus bar electrode 35. The two branch portions 30a that are not in direct contact with the bus bar electrode 35 can be formed in a polygonal shape close to a circular shape in addition to a circular shape.
The manufacturing method of the solar cell module 1 according to the present embodiment is different from the first embodiment in the pattern in which the finger electrodes 30 and the bus bar electrodes 35 are printed.
The finger electrodes 30 are printed in a line shape and a lattice shape. The bus bar electrode 35 is printed in a node shape at the intersection of the finger electrodes.
Further, as shown in FIG. 8A, the finger electrode 30 is printed so as to be branched into a plurality of branch portions 30a in an intersecting region α intersecting with the bus bar electrode 35. The branch portion 30 a is printed so as to be in contact with the bus bar electrode 35. Here, as shown in FIG. 8B, the branch part 30 a may be in contact with the branch part 30 a of another finger electrode 30 in the vicinity of the bus bar electrode 35.
After the finger electrode 30 and the bus bar electrode 35 are printed, the conductive adhesive is melted or softened by heating along the bus bar electrode 35 while pressing the tab 40 through the conductive adhesive, and the bus bar electrode 35 and The photoelectric conversion unit 20 and the tab 40 are bonded.
In the solar cell module 1 including the solar battery cell 10 according to the present embodiment, the finger electrode 30 is branched into a plurality of branch portions 30 a in the intersecting region α with the bus bar electrode 35. Each branch 30 a is in contact with the bus bar electrode 35. Further, the branch point 30 b of each branch part 30 a is separated from the bus bar electrode 35. Further, it is preferable that the branch part 30 a is in contact with the branch part 30 a of another finger electrode 30 in the vicinity of the bus bar electrode 35.
According to such a solar cell module 1, even if a part of the branch part 30a in one finger electrode 30 is disconnected due to the stress caused by the temperature change in the intersection region α, the branch part 30a that is not disconnected is removed. Thus, since the photogenerated carriers can be collected, a decrease in the electrical output of the solar cell module 1 can be suppressed.
Furthermore, when the branch part 30a is in contact with the branch part 30a of the other finger electrode 30, even if the branch part 30a in contact with the bus bar electrode 35 is disconnected, the photogenerated carriers are collected by the other finger electrode 30. be able to. That is, a decrease in the electric output of the solar cell module 1 can be suppressed more fully.
For example, there is no restriction | limiting in the shape of the branch part 30a which concerns on the said embodiment, A curved shape, a rectangle, etc. may be sufficient.
Moreover, the photovoltaic cell 10 which concerns on the said embodiment may have a pair of positive and negative electrodes on the back surface.
Moreover, the solar cell module 1 which concerns on the said embodiment does not need that all the finger electrodes 30 are branched to the branch part 30a. Even in this case, the finger electrode 30 having the plurality of branch portions 30a has the effect of the present invention.
Moreover, the solar cell module 1 according to the above embodiment may be a solar cell module using a crystalline solar cell or the like in which a junction is formed by a thermal diffusion method.
In the solar cell module 1 according to the above embodiment, the case where the finger electrode 30 and the conductor (the bus bar electrode 35 or the tab 40) intersect in a comb shape has been described. You may cross diagonally.
As a solar cell module according to an example of the present invention, the solar cell module 1 according to the first embodiment was manufactured as follows.
A 100 μm thick, 125 mm square n-type single crystal silicon substrate 20d was anisotropically etched with an alkaline aqueous solution to form fine irregularities on the surface. Further, the surface of the n-type single crystal silicon substrate 20d was washed to remove impurities.
Next, an RF plasma CVD method is used to sequentially form a 5 nm thick i-type amorphous silicon layer 20 c and a 5 nm thick p-type amorphous silicon layer 20 b on the light incident surface of the n-type single crystal silicon substrate 20 d. Laminated. Similarly, an i-type amorphous silicon layer 20e having a thickness of 5 nm and an n-type amorphous silicon layer 20f having a thickness of 5 nm were sequentially stacked on the back surface of the n-type single crystal silicon substrate 20d. Here, various conditions of the RF plasma CVD method were a frequency of about 13.56 MHz, a formation temperature of about 200 ° C., a reaction pressure of about 30 Pa, and an RF power of about 50 W.
Next, an ITO film 20a having a thickness of 100 nm was formed on the light incident surface of the p-type amorphous silicon layer 20b by using a magnetron sputtering method. Similarly, an ITO film 20g having a thickness of 100 nm was formed on the back surface of the n-type amorphous silicon layer 20f. Here, various conditions of the magnetron sputtering method were a formation temperature of about 200 ° C., an Ar gas flow rate of about 200 sccm, an O 2 gas flow rate of about 50 sccm, a power of about 3 kW, and a magnetic field strength of about 500 Gauss.
Next, using an offset printing method, an epoxy thermosetting silver paste was arranged in a predetermined pattern on the light incident surface and the back surface of the ITO film 20a. The silver paste was heated at 150 ° C. for 5 minutes to volatilize the solvent, and further heated at 200 ° C. for 1 hour to be fully dried. As a result, 60 finger electrodes 30 with a width of 50 μm and a pitch of 2 mm and two bus bar electrodes 35 with a width of 2 mm were laminated on the photoelectric conversion unit 20 once. In particular, the finger electrode 30 according to the present embodiment branches into two branch portions 30a in a region (intersection region α) 5 mm away from the bus bar electrode 35.
The solar battery cell 10 was manufactured by the above.
Next, one end of the solder-coated tab 40 having a width of 1.5 mm and a thickness of 200 μm was heated to 230 ° C. while being pressed onto the bus bar electrode 35 of one solar battery cell 10. Furthermore, the other end of the tab 40 was heated and connected while being pressed onto the bus bar electrode 35 of another solar battery cell 10. This was repeated to electrically connect a plurality of solar cells 10 in series.
Next, an EVA sheet, a plurality of solar cells 10, an EVA sheet, and a back surface protective material having a three-layer structure of PET / aluminum / PET were sequentially laminated on the glass substrate to form a laminate. The glass substrate, the EVA sheet, and the back surface protective material have substantially the same outer dimensions.
Next, the laminate was heat-pressed at 150 ° C. for 10 minutes in a vacuum atmosphere, and then completely cured by heating at 150 ° C. for 1 hour.
Thus, the solar cell module 1 according to the first embodiment was manufactured.
<Conventional example 1>
As Conventional Example 1, the solar cell module 1 shown in FIGS. 1 and 2A was manufactured. The finger electrode 30 according to Conventional Example 1 is not branched in the intersecting region α with the bus bar electrode 35. That is, the finger electrode 30 according to the conventional example does not include the branch portion 30a.
Other processes are the same as in the above embodiment.
<Conventional example 2>
As Conventional Example 2, the solar cell module 1 shown in FIGS. 1 and 2B was manufactured. The finger electrode 30 according to Conventional Example 2 is not branched in the intersecting region α with the bus bar electrode 35. That is, the finger electrode 30 according to the conventional example does not include the branch portion 30a.
As shown in FIG. 2B, the finger electrode 30 according to the conventional example 1 has triangular portions formed on both sides of the intersecting region α with the bus bar electrode 35 as the center. The triangular portion is an isosceles triangle having a base of 0.2 mm and a height of 5 mm with the side in contact with the bus bar electrode 35 as the base.
A temperature cycle test (JIS C8917) was performed on each solar cell module 1 according to the example, the conventional example 1 and the conventional example 2, and the output reduction rate of the solar cell module 1 before and after the test was compared.
In the temperature cycle test, in accordance with JIS standards, 200 cycles were carried out continuously with one cycle consisting of changing the temperature from high temperature (90 ° C.) to low temperature (−40 ° C.) or from low temperature to high temperature. The output of the solar cell module was measured under light irradiation of AM 1.5 and 100 mW / cm 2 . The output reduction rate was calculated from the equation (1−output after test / output before test) × 100 (%).
Comparing the output decrease rate of each solar cell module 1, the output decrease rate of the solar cell module 1 according to the example is suppressed 0.8% lower than the conventional example 1, and 0.4% lower than the conventional example 2. It was suppressed.
Thus, according to the solar cell module 1 according to the example, even if a part of the branch portion 30a in the one finger electrode 30 is disconnected due to the stress generated due to the temperature change in the intersecting region α, the disconnection occurs. Since the photogenerated carriers can be collected through the branch part 30a that has not been provided, it is possible to suppress a decrease in electrical output. That is, according to the solar cell module 1 which concerns on a present Example, it confirmed that the reliability of the solar cell module could be improved.
<About electrical output>
The electric output of the solar cell module 1 according to the example was larger than the electric outputs of Conventional Example 1 and Conventional Example 2.
This is because, on the light incident surface of the solar cell module 1, the light shielding area (see FIG. 5) by the finger electrode 30 of the embodiment is smaller than the light shielding area of the conventional example 2 (see (b)), and the tab. This is because the characteristic deterioration due to the disconnection of the finger electrode 30 caused by the temperature change at the time of connection 40 can be reduced in the solar cell module of the example. That is, according to the solar cell module 1 which concerns on an Example, it has confirmed that a bigger electrical output could be obtained.
1 is a schematic top view of a conventional solar battery cell 10. FIG. It is an upper surface enlarged view of the conventional photovoltaic cell 10. It is sectional drawing of the solar cell module which concerns on 1st Embodiment. It is sectional drawing of the photovoltaic cell concerning 1st Embodiment. It is an upper surface enlarged view of the photovoltaic cell concerning a 1st embodiment. It is an upper surface enlarged view of the photovoltaic cell concerning a 2nd embodiment. It is an upper surface schematic diagram of the photovoltaic cell concerning a 3rd embodiment. It is an upper surface enlarged view of the photovoltaic cell concerning a 3rd embodiment.
DESCRIPTION OF SYMBOLS 1 ... Solar cell module 10 ... Solar cell 20 ... Photoelectric conversion part 30 ... Finger electrode 30a ... Branch part 30b ... Branch point 35 ... Bus-bar electrode 40 ... Tab 50 ... Sealing material 60 ... Surface protection material 70 ... Back surface protection material
A solar cell electrically connected to another solar cell by a wiring tab,
A photoelectric conversion unit that generates photogenerated carriers upon incidence of light; and
A plurality of finger electrodes stacked on the photoelectric conversion unit, collecting the photogenerated carriers from the photoelectric conversion unit, and the tabs being directly connected via a conductive adhesive;
The finger electrode is branched into a plurality of branches in an intersecting region intersecting the tab,
The solar battery cell, wherein a branch point of the branch portion is disposed in the vicinity of the intersecting region.
The solar cell according to claim 1, wherein the branch portion is in contact with a branch portion of another finger electrode.
A solar cell module comprising a plurality of solar cells electrically connected to each other by a wiring tab between the front surface protective material and the back surface protective material,
A plurality of finger electrodes stacked on the photoelectric conversion unit, collecting the photogenerated carriers from the photoelectric conversion unit, and having the tabs directly connected via a conductive adhesive,
The plurality of finger electrodes are arranged on the photoelectric conversion unit and intersect the tab.
The solar cell module, wherein a branch point of the branch portion is disposed in the vicinity of the intersection region.
The solar cell module according to claim 3, wherein the branch portion is in contact with a branch portion of another finger electrode.
JP2006347809A 2006-12-25 2006-12-25 Solar cell and solar cell module Active JP4429306B2 (en)
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JP2006347809A Active JP4429306B2 (en) 2006-12-25 2006-12-25 Solar cell and solar cell module
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