Source: https://patents.google.com/patent/JP4322096B2/en
Timestamp: 2020-02-20 01:51:57
Document Index: 567847158

Matched Legal Cases: ['art 5', 'art 9', 'art 15', 'art 16', 'art 23', 'art 41', 'art 46']

JP4322096B2 - Resist pattern forming method, magnetic recording medium, and magnetic head manufacturing method - Google Patents
Resist pattern forming method, magnetic recording medium, and magnetic head manufacturing method Download PDF
JP4322096B2
JP4322096B2 JP2003384694A JP2003384694A JP4322096B2 JP 4322096 B2 JP4322096 B2 JP 4322096B2 JP 2003384694 A JP2003384694 A JP 2003384694A JP 2003384694 A JP2003384694 A JP 2003384694A JP 4322096 B2 JP4322096 B2 JP 4322096B2
JP2003384694A
JP2005150335A (en
充 高井
2003-11-14 Application filed by Ｔｄｋ株式会社 filed Critical Ｔｄｋ株式会社
2003-11-14 Priority to JP2003384694A priority Critical patent/JP4322096B2/en
2005-06-09 Publication of JP2005150335A publication Critical patent/JP2005150335A/en
2009-08-26 Publication of JP4322096B2 publication Critical patent/JP4322096B2/en
The present invention relates to a resist pattern forming method using an imprint method, and a magnetic recording medium and a magnetic head manufacturing method using the resist pattern forming method.
For example, an optical lithography method is conventionally known as a method for forming a fine resist pattern on a resist layer on a substrate surface in a process of manufacturing a semiconductor element or a recording medium. As a resist pattern forming method using this photolithographic method, for example, a resist layer formed on a substrate surface (for example, a layer formed by applying a resist material such as a resin that is cured in response to light in a thin film) A method of forming a resist pattern by performing development after irradiating light on the substrate to draw a concavo-convex pattern is performed.
In recent years, electron beam lithography that can form a resist pattern with a nanometer size by irradiating an electron beam instead of light as a technique for dealing with higher density of semiconductor elements and larger capacity of a recording medium. Laws are being developed.
However, this electron beam lithography method has a problem that mass production is difficult because it takes a long time to form a resist pattern. In addition, since the electron beam lithography apparatus is expensive, there is a problem that the price of the product increases due to the introduction cost.
In recent years, as a method for forming a fine resist pattern, a nanometer-sized resist pattern is formed by pressing a nanometer-sized uneven portion formed on a mold against a resist layer on a substrate surface and transferring the uneven shape of the uneven portion. A resist pattern forming method (imprint method) to be formed has been proposed (see, for example, Non-Patent Document 1).
In this resist pattern forming method, as shown in FIG. 12 (a), a concavo-convex shape in which a pattern to be transferred is first reversed as shown in FIG. 12 (b) on the resist layer 12 formed on the surface of the substrate 11. The mold 21 (also referred to as a stamper) 21 and the substrate 11 having (22, 23) on the surface are heated so that the temperature is equal to or higher than the glass transition point of the resist material forming the resist layer 12, and then the mold 21 Is pressed (pressed) with a predetermined pressure. Next, when the mold 21 is pressed against the resist layer 12 and cooled to a temperature not higher than the glass transition point of the resist material and the mold 21 is separated from the resist layer 12, as shown in FIG. The concave / convex pattern (14, 15) is transferred to the layer 12. In general, the resist material that has not been excluded in other parts when pressed by the mold 21 remains in the recesses 14 in the resist pattern formed on the substrate 11 (hereinafter, the resist material remains in the recesses). The layer is referred to as “recessed residual resist layer” and is denoted by reference numeral 3). For this reason, as shown in FIG. 12D, the concave portion residual resist layer 3 is removed by etching, and the substrate surface 16 is exposed in the concave portion 14.
Although there is no direct relationship with such an imprint method, Patent Document 1 and Patent Document 2 listed below disclose isotropic methods using a pattern-exposed photoresist as a semiconductor device manufacturing method using ozone or the like. A technique for performing finer patterning than patterning by pattern exposure by processing by etching is disclosed.
Stefan Y. Stephen Y. Chou, "Imprint of sub 25 nm vias and trenches in polymers", Applied Physics Letters, (USA), November 20, 1995, 67, 21, p.3114-3116 JP 2000-181082 A JP 2002-231608 A
Here, consideration is given to the case where the density of the semiconductor element is increased and the capacity of the recording medium is increased. For example, when manufacturing a discrete track type magnetic recording medium (hereinafter also referred to as “discrete track medium”) that is attracting attention as a next generation magnetic recording medium, in order to increase the density of recorded data, It is necessary to reduce the track pitch of the data recording track formed by the fine pattern of the magnetic layer to some extent. Accordingly, a groove between tracks formed of a magnetic layer (in short, this groove is a non-magnetic portion for reducing the magnetic influence on adjacent data recording tracks during recording / reproduction of recorded data. )) To a certain extent.
At this time, using the resist pattern 60 formed by the resist pattern forming method as described above as a mask, the metal mask layer 61 and the magnetic layer 62 are etched to form the groove (nonmagnetic portion) 63 as shown in FIG. In the case of forming, as shown by a broken line in FIG. 13, the groove width to be etched tends to be narrower as it is away from the resist pattern 60 (lower side in FIG. 13). For this reason, when the width W7 of the convex portion of the resist pattern 60 is excessively widened without changing the formation pitch of the data recording track 65, it is difficult to form the groove 63 having a depth reaching the substrate 64. There is a fear.
Therefore, in order to form a resist pattern with a narrow convex shape width (w7 in FIG. 13), the concave portion 23 ′ has a narrow width (the convex portion 22 ′ has a wide width) as shown in FIG. It is necessary to press the resist layer 12 formed on the surface of the substrate 11 using the mold 21 ′ to transfer the uneven shape.
However, as shown in FIG. 14B, forming a resist pattern with a narrow convex portion by pressing with a mold 21 ′ having a narrow concave portion 23 ′ as shown in FIG. It is more difficult than forming a resist pattern with a wide convex portion by pressing with a wide mold 23 ″. That is, in the mold 21 ′ with a narrow concave portion 23 ′ shown in FIG. Since the contact area is large, a high load is required for pressing, and the formed resist pattern is easily peeled when the pressed mold 21 ′ is released from the resist layer 12. As shown in FIGS. 14 (a) and 14 (b), this becomes prominent in the case of a mold having a line-and-space pattern in which concave and convex portions are periodically arranged.
The present invention has been made to solve the above-mentioned problems, and a first object of the present invention is to provide a resist pattern that can easily form a resist pattern having a narrow convex portion with no problems such as peeling during production. It is to provide a forming method. In addition, the second and third objects of the present invention are to provide a method for manufacturing a magnetic recording medium and a method for manufacturing a magnetic head that can easily form a magnetic recording medium corresponding to high density and large capacity. There is to do.
In order to achieve the first object, the resist pattern forming method of the present invention transfers a pattern of a mold having a concavo-convex shape to a resist layer formed on a substrate by an imprint method, and then transfers the transferred resist pattern. By etching the convex pattern side surface, a resist pattern having a convex shape narrower than the width of the concave portion of the corresponding mold is formed, and the etching of the convex pattern side surface of the resist pattern is transferred The residual resist layer is formed together with the removal of the residual resist layer remaining in the concave portion of the resist pattern, so that the width of the convex shape of the resist pattern becomes a desired width almost simultaneously with the completion of the removal of the residual resist layer. The thickness is changed .
According to this invention, by etching the convex pattern side surface of the transferred resist pattern, it is possible to form a resist pattern having a convex shape with a width narrower than the width of the concave portion of the corresponding mold. A convex narrow mold (that is, a wide concave mold) that can be easily transferred by a printing method can be used. The use of such a mold has the advantage of reducing the area in contact with the resist layer and not requiring a high load during pressing, and can significantly reduce pattern peeling that tends to occur when the mold is released from the resist layer. . Furthermore, according to the present invention, when the recess residual resist layer is completely removed, the etching processing end point is when the thickness of the recess residual resist layer becomes zero or when it slightly exceeds the zero time. Therefore, damage to the lower structure of the resist layer can be prevented.
According to this invention, even when the width of the concave portion of the mold is made constant, the thickness of the above-described concave portion residual resist layer is changed, and etching is performed so as to completely remove the concave portion residual resist layer. Resist patterns having different convex widths (convex widths) can be formed.
In the resist pattern forming method of the present invention, in the resist pattern forming method, etching of the convex pattern side surface of the resist pattern is performed together with removal of the residual resist layer remaining in the concave portion of the transferred resist pattern, The thickness of the residual resist layer is sufficient to suppress the occurrence of defects due to peeling of the resist layer when the mold is released from the resist layer after the pattern of the mold is transferred to the resist layer. It is characterized by a thickness.
According to the present invention, the side surface of the convex pattern is etched together with the removal of the concave residual resist layer. The thickness of the concave residual resist layer is transferred to the resist layer after transferring the mold pattern to the resist layer. When the mold is removed from the resist layer, the thickness is sufficient to suppress the occurrence of defects due to the peeling of the resist layer. Therefore, pattern peeling that is likely to occur when the mold is removed from the resist layer can be prevented, and there are few defects. A resist pattern can be formed.
In the resist pattern forming method of the present invention, in the resist pattern forming method, the etching is preferably plasma etching.
According to the present invention, by applying plasma etching, the etching rate for the resist layer is moderately faster in the thickness direction than in the width direction, and the convex shape of the resist pattern while removing the residual resist layer well. Etching can be performed to narrow the width of the film.
A method of manufacturing a magnetic recording medium of the present invention that achieves the second object described above is characterized by using the above-described resist pattern forming method of the present invention.
According to the present invention, since the fine pattern formation in the magnetic recording medium manufacturing process is performed by applying the above-described resist pattern forming method, the resist acting as an etching mask having a small number of defects and a narrow convex shape is formed. Patterns are formed with good yield. As a result, since fine etching can be performed using such a resist pattern as an etching mask, a high-density, large-capacity and high-performance magnetic recording medium can be manufactured easily and with high yield.
The method of manufacturing the magnetic head of the present invention that achieves the third object is characterized by using the resist pattern forming method of the present invention described above.
According to the present invention, since the fine pattern is formed in the magnetic head manufacturing process by applying the above-described resist pattern forming method, the resist pattern that functions as an etching mask having a small number of defects and a narrow convex shape is formed. Is formed with good yield. As a result, since fine etching can be performed using such a resist pattern as an etching mask, a high-density and high-performance magnetic head can be manufactured easily and with high yield.
As described above, according to the resist pattern forming method of the present invention, a resist pattern with a narrow convex shape width (convex portion width) can be easily formed with less defects such as pattern peeling by imprinting. Good and improves yield. In the present invention, since a mold having a wide concave portion (that is, a mold having a narrow convex portion width) can be used, the load during pressing can be reduced, and the pattern can be easily transferred. In addition, according to the present invention, when removing the residual resist layer by etching with oxygen plasma or the like, the side surface of the resist pattern is also etched to form a convex resist pattern with a narrow width. Accordingly, the thickness of the concave portion resist layer can be increased, so that it is possible to remarkably reduce pattern peeling that is likely to occur when the mold is separated from the resist layer, and to further reduce fine pattern defects.
Furthermore, according to the method for manufacturing a magnetic recording medium and the method for manufacturing a magnetic head of the present invention, the mask pattern for performing fine etching in the manufacturing process of the magnetic recording medium or the magnetic head has a convex shape with few defects. Therefore, a high-density and high-performance magnetic recording medium or magnetic head can be manufactured easily and with a high yield.
Hereinafter, the best mode of a resist pattern forming method, a magnetic recording medium, and a magnetic head manufacturing method of the present invention will be described in detail with reference to the drawings.
(Method for forming resist pattern)
FIG. 1 is a schematic cross-sectional view illustrating each step in an example of a resist pattern forming method according to the present invention.
As shown in FIGS. 1A to 1D, the resist pattern 2 forming method of the present invention transfers a pattern of a mold 21 having a concavo-convex shape to a resist layer 12 formed on a substrate 11 by an imprint method. After that, the convex pattern side surface of the transferred resist pattern 1 is etched to etch the convex shape 15 having a width w4 narrower than the width w6 of the concave portion 23 of the corresponding mold 21 (hereinafter sometimes referred to as the convex portion 15). .)) Is formed.
That is, in the method for forming the resist pattern 2 of the present invention, pressing is relatively easy and there is little risk of resist peeling when the mold is removed, and the width w6 of the recesses 23 is wide (the ratio of the recesses 23 between the pitches P is high). High) mold 21 is used. Then, the resist 21 formed on the surface of the substrate 11 is pressed by the mold 21 to transfer and form the resist pattern 1 having a wide width w2 of the convex portion 5 (a ratio of the convex portion 5 between the pitches P is high). At this time, the recessed portion residual resist layer 3 is left. Thereafter, when the concave portion residual resist layer 3 is removed by etching, the side surface of the resist pattern 1 having a wide width w2 of the convex portion 5 is also etched, whereby a resist pattern 2 having a narrow width w4 of the convex portion 15 is formed. The
As described above, in the present invention, the mold 21 having the narrow width w5 of the convex portion 22 (that is, the mold 21 having the wide width w6 of the concave portion 23) that can be easily transferred by the imprint method can be used. Is advantageous in that it reduces the area in contact with the resist layer 12 and does not require a high load during pressing, and remarkably reduces pattern peeling that tends to occur when the mold 21 is detached from the resist layer 12. There is an effect that can be done.
In order to leave the recessed portion residual resist layer 3 thick, for example, the thickness t4 of the resist layer 12 applied on the substrate 11 is increased, or the mold 21 is pressed with a low load. it can.
The thickness t1 of the recessed portion residual resist layer 3 depends on the pattern shape to be formed, the type of resist material used, the plasma type used for etching, etc. In a preferred embodiment, the width w4 of the convex shape 15 is controlled by changing the etching processing time by changing the thickness t1 of the concave residual resist layer 3, for example. That is, even when the mold 21 having a constant width w6 of the concave portion 23 is used, by changing the thickness t1 of the concave portion residual resist layer 3 and performing etching so as to remove the concave portion residual resist layer 3, Various resist patterns 2 having different widths w4 (convex widths) of the convex shape 15 can be formed.
In this case, considering the etching rate in the thickness direction (height direction) and width direction (in-plane direction) of the resist layer in particular, the width w2 of the convex portion 5 of the resist pattern 1 after being transferred by the mold 21. The thickness t1 of the recessed portion residual resist layer 3 is determined depending on how much is increased.
Thus, in the present invention, the etching of the pattern side surface of the convex portion 5 of the resist pattern 1 after the transfer is performed together with the removal of the concave portion residual resist layer 3 remaining in the concave portion 4 of the transferred resist pattern 1, Almost at the same time as the removal of the concave portion residual resist layer 3 is completed, the thickness t1 of the concave portion residual resist layer 3 and the concave portion 23 of the mold 21 are set so that the width w4 of the convex shape 15 of the resist pattern 2 becomes a desired width. At least one of the widths w6 is changed.
Here, the state in which the etching of the pattern side surface of the convex portion 5 is performed together with the removal of the concave portion residual resist layer 3 means that (i) the etching of the pattern side surface of the convex portion 5 and the etching removal of the concave portion residual resist layer 3 are performed simultaneously. And (ii) a state in which the pattern side surface of the convex portion 5 is etched even after the etching removal of the concave portion residual resist layer 3 is finished first. Also, “substantially simultaneously” means that (a) when the etching removal of the recessed portion residual resist layer 3 is completely completed, when the thickness t1 of the recessed portion residual resist layer 3 becomes zero and when it becomes zero. (B) In the case where the etching removal of the recessed portion residual resist layer 3 is not completely completed and is removed without any problem in the next etching step, the thickness of the recessed portion remaining resist layer 3 is included. This includes the point in time when a sufficiently thin thickness is left until t1 does not become zero.
From the viewpoint of preventing the peeling of the resist layer, which is likely to occur when the mold 21 after the transfer is separated from the resist layer, the thickness t1 of the recess remaining resist layer 3 is suppressed from generating defects due to the peeling of the resist layer. It is desirable that the thickness be sufficient to achieve this.
The thickness t1 of the recessed portion residual resist layer 3 is determined in particular by the adherence between the substrate 11 and the resist layer 12, the thickness t4 of the resist layer 12 to be formed, and the like. Although not particularly limited, for example, if the thickness t1 of the recessed portion residual resist layer 3 is set to 20 nm or more, more preferably 50 nm or more, a defect due to the peeling of the resist layer occurs when the mold is detached. The fear is reduced.
As an etching means used for etching the pattern side surface of the convex portion 5 of the resist pattern 1, plasma etching such as oxygen plasma and argon plasma is preferable. In the plasma etching such as oxygen plasma, the etching rate with respect to the resist layer is generally moderately faster in the thickness direction than in the width direction, and the recess residual resist layer 3 left in the recess 4 of the resist pattern 1 is well removed. However, the width w2 of the convex portion 5 of the resist pattern 1 (the width w4 of the convex portion 15) can be reduced. In particular, it is desirable to use plasma etching in which the etching rate ratio between the width direction and the thickness direction of the resist layer is 0.4 to 1.0 in the [width direction / thickness direction].
In the present invention, in addition to the etching of the resist pattern 1 using plasma such as oxygen plasma described above, it is also possible to etch the resist pattern using ozone or the like. Since the etching rate of the resist pattern 1 by ozone is approximately the same in the width direction and the thickness direction, the convex portion 5 of the resist pattern 1 is removed for a time corresponding to the time for etching and removing the thickness t1 of the concave portion residual resist layer 3. Etching from the width direction can reduce the width w2 (width w4 in the convex portion 15). In the present invention, a plurality of etchings can be combined as necessary.
As an end point of the etching process, it is more preferable that the end point is when the thickness t1 of the residual resist layer 3 becomes zero or slightly exceeds zero from the viewpoint of preventing damage to the lower structure of the resist layer. desirable. In addition, after the thickness t1 of the recessed portion residual resist layer 3 becomes zero, the pattern side surface may be continuously etched.
Next, the process of forming a resist pattern according to the resist pattern forming method according to the present invention will be described with reference to the drawings.
A coating apparatus 41 shown in FIG. 2 forms a resist layer 12 (see FIG. 3) by coating a resist material on the surface side of the disk-shaped substrate 11 ′ (see FIG. 3) according to the resist pattern forming method according to the present invention. It is a device to do. The coating device 41 includes a motor 42, a turntable 43, a discharge mechanism 44, and a control unit 45.
The motor 42 rotates the turntable 43 in accordance with a control signal from the control unit 45. The turntable 43 is configured so that the disk-shaped substrate 11 ′ can be placed thereon, and is rotated by the motor 42. In accordance with a control signal from the control unit 45, the discharge mechanism 44 has a resist material (as an example) on the inner peripheral part (slightly outer side than the hole formed in the central part) of the disk-shaped substrate 11 ′ placed on the turntable 43. Polystyrene copolymer) is discharged. The controller 45 controls the rotation of the motor 42 and the discharge of the resist material by the discharge mechanism 44 so that the thickness t4 (see FIG. 3) of the resist layer 12 becomes a predetermined thickness.
Here, the above-described disk-shaped substrate 11 ′ is, for example, a substrate for a discrete track type recording medium (hereinafter also referred to as “discrete track medium”). For example, the base substrate 11 is a disc made of a glass material. It is formed in a shape. In this case, a large number of concentric data recording tracks (hereinafter also referred to as “discrete tracks”) separated from each other at a predetermined arrangement pitch (for example, 150 nm) are formed on the surface of the disk-shaped substrate 11 ′ in the completed state. It is formed. As shown in FIG. 3, the disk-shaped substrate 11 ′ has a magnetic layer 10 and a metal mask layer 9 preliminarily formed on a substrate 11 serving as a base. The laminated substrate is referred to as “disk-shaped substrate 11 ′” or simply “substrate 11 ′”. In this case, in order to enable perpendicular recording, the magnetic layer 10 is actually provided with a backing layer (soft magnetic layer) and a recording magnetic layer (both not shown) on the disk-shaped substrate 11 ′ side. The layers are stacked in order.
A transfer device 46 shown in FIG. 4 is a device that forms a resist pattern on the resist layer 12 formed on the surface side of the disk-shaped substrate 11 ′ in accordance with the resist pattern forming method according to the present invention. The transfer device 46 includes a heating stage 47, a press mechanism 48, a control unit 49, and the mold 21.
The heating stage 47 is configured such that the disk-shaped substrate 11 ′ on which the resist layer 12 is formed can be placed, and heats the resist layer 12 and the disk-shaped substrate 11 ′ in accordance with a control signal from the control unit 49. The press mechanism 48 is configured so that the mold 21 can be fixed, and pushes down (presses) the mold 21 toward the heating stage 47 in accordance with a control signal from the control unit 49. In this case, the press mechanism 48 has a heating function for heating the fixed mold 21. The control unit 49 controls heating by the heating stage 47 and heating and pressing by the press mechanism 48.
The mold 21 is formed in a disc shape as a whole, and as shown in FIG. 5, an uneven portion for forming a resist pattern on the resist layer 12 is formed on the surface thereof. In this case, in order to prevent the resist material from adhering to the mold 21 when the mold 21 is detached from the resist layer 12 in the step of forming the resist pattern, the unevenness portion of the mold 21 is subjected to, for example, a fluorine coating process. It has been subjected. For example, an electron beam lithography apparatus and a reactive ion etching apparatus are used to form the uneven portions in the mold 21. In order to facilitate understanding of the invention, the mold 21 shown in FIG.
Using the apparatuses 41 and 46 shown in FIGS. 2 and 4, a resist pattern is formed according to the resist pattern forming method of the present invention.
First, the disk-shaped substrate 11 ′ is placed on the turntable 43 and the coating apparatus 41 starts processing. In response to this, the control unit 45 outputs a control signal to the motor 42 and the discharge mechanism 44. At this time, the motor 42 rotates the turntable 43 on which the disk-shaped substrate 11 'is placed according to the control signal, for example, at a low speed of 5 rotations, and the discharge mechanism 44 responds to the control signal with a predetermined amount of resist material (for example, polystyrene copolymer). Is discharged to the inner periphery of the disk-shaped substrate 11 ′. Next, the control unit 45 outputs a control signal for rotating the turntable 43 at a high speed for a predetermined time to the motor 42. In response to this, the motor 42 rotates the turntable 43 at a high speed. At this time, the disk-shaped substrate 11 ′ rotates at a high speed according to the rotation of the turntable 43, and the discharged resist material is stretched with a uniform thickness in the outer peripheral direction of the disk-shaped substrate 11 ′ by centrifugal force. . As a result, the resist layer 12 is formed on the surface of the disk-shaped substrate 11 ′ with a desired thickness t 4, for example, 100 nm.
Next, in the step of forming a resist pattern on the resist layer 12 using the transfer device 46, first, the disk-shaped substrate 11 ′ having the resist layer 12, the metal mask layer 9 and the magnetic layer 10 is placed on the heating stage 47. Then, the transfer device 46 starts processing. In response to this, the control unit 49 outputs a control signal instructing heating to the heating stage 47 and the press mechanism 48. At this time, the heating stage 47 heats the resist layer 12 and the disk-shaped substrate 11 ′ according to the control signal, and the press mechanism 48 heats the fixed mold 21 according to the control signal. In this case, when the temperature of the resist layer 12 exceeds the glass transition point of the resist material (in this case, 105 ° C. which is the glass transition point of the polystyrene copolymer), the resist layer 12 is softened and deformed. Become. Next, the control unit 49 monitors the output signal of a temperature sensor (not shown), for example, so that the temperature of the resist layer 12, the disk-shaped substrate 11 ′, and the mold 21 is, for example, 170 ° C. above the glass transition point of the resist material. When it is confirmed that the pressure has reached, a control signal instructing pressing is output to the pressing mechanism 48. In response to this, the press mechanism 48 presses the mold 21 with a pressure of 2.1 MPa (21.2 kgf / cm 2 ), for example.
At this time, as shown in FIG. 6, the convex portion 22 of the mold 21 is pressed against the resist layer 12, and the resist material forming the resist layer 12 is deformed and enters the concave portion 23 of the mold 21. Subsequently, the control unit 49 outputs a control signal instructing the press mechanism 48 to stop pressing, and outputs a control signal instructing the heating stage 47 and the press mechanism 48 to stop heating. In response to this, the heating stage 47 stops heating, and the press mechanism 48 stops pressing and heating. Next, the resist layer 12, the disk-shaped substrate 11 ', and the mold 21 are left until the temperature drops to room temperature. In this case, a method of forcibly lowering the temperature by providing a cooling mechanism can also be adopted.
Next, the mold 21 is released from the resist layer 12. As a result, the uneven shape of the mold 21 is transferred to the resist layer 12 as shown in FIG. In this case, by pushing the mold 21 to the position where the tip surface of the convex portion 22 does not become so deep in the resist layer 12, the resist pattern 1 is formed on the bottom surface of the concave portion 4 and the disk-shaped substrate 11 ′ as shown in FIG. The distance from the surface 16 is sufficiently long (for example, 52 nm), and the concave portion residual resist layer 3 is left. Alternatively, as described above, by forming the resist layer 12 with a large thickness t4, the resist layer 12 can be formed in a state where the recessed portion residual resist layer 3 (thickness t1) remains.
Next, the disk-shaped substrate 11 ′ having the resist layer 12 to which the concave and convex shape of the mold 21 is transferred is transferred to a plasma etching apparatus (not shown), and the entire surface of the resist layer 12 is irradiated with oxygen plasma to perform plasma etching. The pattern side surface of the convex portion 5 is etched together with the removal of the concave portion residual resist layer 3 in the concave portion 4.
By such etching, as shown in FIG. 8, a desired resist pattern in which the width w3 of the concave portion 14 is sufficiently wide (that is, the convex portion 15 has a width w4 narrower than the width w6 of the concave portion 23 of the corresponding mold 21). 2 is formed.
Next, a process of manufacturing a discrete track medium by forming a discrete track made of a magnetic layer on the surface of a disk-shaped substrate using a resist layer on which a resist pattern is formed as a mask will be described with reference to FIG. . Since the reactive ion etching process is a known technique, a detailed description thereof is omitted.
First, a reactive ion etching process is performed on the metal mask layer 9 using the resist pattern 2 formed in the mode of FIG. 8 as a mask. As a result, as shown in FIG. 9A, the metal mask layer 9 exposed from the resist pattern 2 (see FIG. 8) is removed, and a metal mask pattern 91 is produced. At this time, a very small part of the surface layer of the magnetic layer 10 at the portion where the metal mask layer 9 is removed is also removed. At this time, most of the convex resist layer 12 disappears, but a part remains on the metal mask layer 9.
Next, a reactive etching process is performed on the magnetic layer 10 using the manufactured metal mask pattern 91 as a mask. As a result, as shown in FIG. 9B, the magnetic layer 10 in a portion exposed from the metal mask pattern 91 is removed. At this time, all of the resist layer 12 disappears.
Next, the remaining metal mask layer 9 is removed by performing a reactive ion etching process using a metal mask etching gas. Thereby, as shown in FIG. 9C, a discrete track 92 is formed.
Next, a surface finishing process (not shown) is performed. In this surface finishing treatment, first, for example, silicon oxide is filled in the gaps between the separated magnetic layers 10,..., 10, and then the surface is flattened using a CMP apparatus (chemical mechanical polish). Next, a protective film is formed on the flattened surface by, for example, DLC (Diamond Like Carbon), and finally a lubricant is applied (none of which is shown). Thereby, a discrete track type magnetic recording medium is completed.
As described above, the example in which the resist pattern forming method of the present invention is applied to the manufacture of a discrete track type magnetic recording medium has been shown. However, the present invention is not limited to this, and the divided recording elements are arranged in the circumferential direction of the track (sectors). Manufacturing of magnetic disks arranged in parallel at fine intervals, magnetic disks arranged in parallel in both radial and circumferential directions of the track, and magnetic disks in which the divided recording elements form a spiral shape. The present invention is naturally applicable.
The present invention is also applicable to the manufacture of magneto-optical disks such as MO, and other discrete type magnetic recording media other than disk shapes such as magnetic tape.
Further, the resist pattern forming method of the present invention can be applied to the above-described magnetic recording medium manufacturing method, as well as a magnetic head manufacturing method and other various semiconductor device manufacturing methods.
(Method of manufacturing magnetic head)
Next, a method for manufacturing the magnetic head of the present invention will be described.
As the thin film magnetic head, a composite thin film magnetic head having a structure in which a recording head having an inductive magnetic conversion element for writing and a reproducing head having a magnetoresistive (MR) element for reading is widely used. Are known. MR elements include an AMR (Anisotropic Magneto Resistive) element using an anisotropic magnetoresistive effect and a GMR (Giant Magneto Resistive) element using a giant magnetoresistive effect. A reproducing head using an AMR element is an AMR. A reproducing head using a GMR element is called a GMR head. The GMR element exhibits a greater resistance change when the same external magnetic field is applied than the AMR element. For this reason, the GMR head can increase the reproduction output by about 3 to 5 times compared with the AMR head. As the performance of the reproducing head is improved, the performance of the recording head is also required to be improved. Of the performance of the recording head, in order to increase the recording density, it is necessary to increase the track density in the magnetic recording medium. For this purpose, a narrow track structure in which the width of the air bearing surface of the lower magnetic pole (bottom pole) and the upper magnetic pole (top pole) formed above and below the write gap is narrowed to the submicron order. It is necessary to realize a recording head, and semiconductor processing technology is used for that purpose.
FIG. 10 shows a sectional configuration diagram of a composite thin film magnetic head which is an example of a thin film magnetic head. 10A shows a cross section perpendicular to the track surface, and FIG. 10B shows a cross section parallel to the track surface of the magnetic pole portion. The magnetic head 100 includes a magnetoresistive read head unit (hereinafter referred to as a read head unit) 100A for reproduction and an inductive recording head unit (hereinafter referred to as a recording head unit) 100B for recording.
The read head unit 100A is obtained by forming a pattern of a magnetoresistive layer 105 on a substrate 101 through a base layer 102, a lower shield layer 103, and a shield gap layer 104 in this order. A lead terminal layer 105 a made of a material that does not diffuse into the MR layer is also formed on the shield gap layer 104, and the lead terminal layer 105 a is electrically bonded to the MR layer 105. A shield gap layer 106 is laminated on the MR layer 105 and the lead terminal layer 105a.
In the recording head portion 100B, an upper magnetic pole (upper pole) 109a is formed on the read head 100A via a lower magnetic pole 107 that also serves as an upper shield layer for the MR layer 105 and a gap layer. A first thin film coil 111 and a second thin film coil 112 are stacked on the gap layer 108. The thin film coils 111 and 112 are covered with insulating layers 113 and 114, and an upper magnetic pole layer 109 including an upper magnetic pole 109a is formed on the insulating layers 110, 113, and 114. The top pole layer 109 is covered with an overcoat layer 115. In the recording head portion 100B, the lower magnetic pole (lower pole) 107a facing the upper magnetic pole 109a has a trim structure in which the surface portion of the upper shield layer 107 is partially processed into a projecting shape.
In this magnetic head 100, information is read from a magnetic disk (not shown) by using the magnetoresistive effect of the MR layer 105 in the read head unit 100A, and the upper magnetic pole 109a and the lower magnetic pole are formed in the recording head unit 100B. Information is written to the magnetic disk by using a change in magnetic flux with the magnetic pole 107a.
A method of manufacturing such a composite thin film magnetic head, in particular, a magnetic pole (pole) of a recording head portion by the resist pattern forming method according to the present invention will be described with reference to FIG.
First, as shown in FIG. 11A, an insulating layer 52 made of, for example, alumina (Al 2 O 3 ) is formed on, for example, an AlTiC (Al 2 O 3 .TiC) substrate 51 by, for example, a sputtering method (hereinafter referred to as a sputtering method). To a thickness of about 3 to 5 μm. Subsequently, although not shown, after forming a lower shield layer, a recording gap layer, an MR element, a GMR element, and the like, a magnetic layer, for example, an upper shield / lower magnetic pole (hereinafter referred to as a lower magnetic pole) 53 made of permalloy, for example, It is formed with a thickness of about 3 to 4 μm by sputtering. Subsequently, a recording gap layer 54 made of an insulating film such as an alumina film is formed by, for example, a sputtering method, and an upper magnetic pole layer 55 is formed on the recording gap layer 54 by, for example, a sputtering method. As the material of the upper magnetic pole layer 55, for example, a high saturation magnetic flux density (Hi-Bs) material such as FeN (iron nitride) or FeZrN (zirconia iron nitride) is used in addition to permalloy (NiFe).
Subsequently, an inorganic insulating film 56 made of alumina, for example, of the same material as that of the recording gap layer is formed on the upper magnetic pole layer 55 by, for example, sputtering. This inorganic insulating film 56 becomes an etching mask material for the upper magnetic pole layer 55 (showing the same action as the “metal mask 9” in the embodiment of the magnetic recording medium manufacturing method described above). Subsequently, a resist layer 57 is formed on the inorganic insulating film 56. This resist layer 57 serves as an etching mask material for the inorganic insulating film 56.
Next, as shown in FIG. 11B, a resist pattern 57a wider than a desired pattern width (for example, the same width as the magnetic pole) is transferred to the resist layer by a mold (also called a stamper). That is, since a mold having a wide concave portion is used, it is possible to easily separate from the press and the resist layer in a mode in which defects due to occurrence of peeling of the resist layer are reduced.
Subsequently, the recessed portion residual resist layer 57b in the recessed portion of the resist layer is removed by etching, for example, with oxygen plasma, and the side surface of the resist pattern 57a is etched, for example, as shown in FIG. A resist mask 57c having a width and etching the inorganic insulating film 56 is formed.
Next, as shown in FIG. 11D, the inorganic insulating film 56 is selected by reactive ion etching using CF 4 (carbon tetrafluoride), Cl 2 (chlorine) or the like using the resist mask 57c as a mask. Then, an inorganic insulating mask 56a for etching the upper magnetic pole layer 55 is formed. The inorganic insulating mask 56a may be formed from silicon dioxide (SiO 2 ) or the like.
Next, in FIG. 11D, the upper magnetic pole layer 55 is selectively removed by ion milling of Ar (argon), for example, using this inorganic insulating mask 56a. The resist mask 57c may be removed during ion milling of the upper magnetic pole layer 55, but it may be used as a mask material for ion milling together with the inorganic insulating mask 56a. After selectively removing the recording gap film 54 by reactive ion etching, the surface of the lower magnetic pole 53 is etched again by, for example, Ar ion milling, and trimming as shown in FIG. A structure is formed.
Next, the present invention will be described more specifically based on examples.
FIG. 1 is a diagram schematically showing steps in one embodiment of the resist pattern forming method of the present invention.
First, as shown in FIG. 1A, a mold 21 having a recess 23 with a width w6 of 126 nm, a depth H1 of 230 nm, and a pitch P of 200 nm is fabricated by electron beam lithography and reactive ion etching. Next, as shown in FIG. 1B, a resist layer 12 is formed on the surface of the substrate 11 with a thickness t4 of 100 nm. The substrate 11 having the mold 21 and the resist layer 12 formed on the surface is mounted on a press device, heated to 170 ° C., and then pressed at a pressure of 2.1 MPa (21.2 kgf / cm 2 ). When the mold 21 and the substrate 11 are cooled to 35 ° C. in the pressed state and then the mold 21 is detached from the substrate 11, a resist pattern 1 as shown in FIG. 1C is transferred. Here, the thickness t2 of the convex portion 5 of the resist pattern 1 was 107 nm, and the thickness t1 of the concave residual resist layer 3 was 52 nm. Next, the resist pattern 1 is etched by oxygen plasma. The etching rate of the resist pattern 1 by oxygen plasma was about 15 nm / min in the width direction and about 20 nm / min in the thickness direction. When the removal of the recessed portion residual resist layer 3 is finished, as shown in FIG. 1 (d), the width w4 of the convex portion 15 of the obtained resist pattern 2 becomes 80 nm, and the convex portion is removed from the mold 21 having the wide width w6 of the concave portion 23. A narrow resist pattern 2 having a width w4 of 15 could be formed.
It is a schematic cross section explaining each process in one example of a resist pattern formation method concerning the present invention. It is a block diagram which shows the structure of the coating device used in one Embodiment of the resist pattern formation method of this invention. It is a schematic cross section which shows the structure of the disk-shaped board | substrate with which the magnetic layer, the metal mask layer, and the resist layer were formed. It is a block diagram which shows the structure of the transfer apparatus used in one Embodiment of the resist pattern formation method of this invention. It is a schematic cross section which shows the structure of the mold in a transfer apparatus. It is a schematic cross section which shows the state which pressed the mold to the resist layer. It is a schematic cross section which shows the structure of the resist layer to which the pattern of the mold was transcribe | transferred. It is a schematic cross section which shows the structure of the resist layer in the state which performed the etching process with respect to the resist layer. It is process drawing which shows an example of the manufacturing method of the magnetic recording medium of this invention. 1 is a schematic cross-sectional configuration diagram of a composite thin film magnetic head which is an example of a thin film magnetic head. FIG. It is process drawing which shows an example which manufactures a magnetic head by applying the formation method of the resist pattern of this invention. It is each process figure of the resist pattern formation method by the imprint method. It is a schematic cross section for demonstrating the manufacturing method about a discrete track medium. It is a schematic cross section which shows the shape of the mold used for the resist pattern formation by the imprint method.
DESCRIPTION OF SYMBOLS 1, 2 Resist pattern 3 Concave residual resist layer 4 Concave part 5 Convex part 9 Metal mask layer 10 Magnetic layer 11, 11 'Substrate 12 Resist layer 14 Concave part 15 Convex part 16 Substrate surface 21, 21', 21 "Mold 22, 22 ' , 22 "Mold convex part 23, 23 ', 23" Mold concave part 41 Coating device 42 Motor 43 Turntable 44 Discharge mechanism 45 Control part 46 Transfer device 47 Heating stage 48 Press mechanism 49 Control part P Pitch H1 depth t1, t2, t3, t4 thickness w1, w2, w3, w4, w5, w6, w7 width
After transferring the pattern of the mold having the concavo-convex shape to the resist layer formed on the substrate by the imprint method, the convex pattern side surface of the transferred resist pattern is etched to obtain the width of the concave portion of the corresponding mold. Forming a resist pattern having a convex shape with a narrow width,
Etching of the convex pattern side surface of the resist pattern is performed together with removal of the residual resist layer remaining in the concave portion of the transferred resist pattern,
A resist pattern forming method, wherein the thickness of the residual resist layer is changed so that the width of the convex shape of the resist pattern becomes a desired width substantially at the same time as the removal of the residual resist layer is completed.
The thickness of the residual resist layer is sufficient to suppress the occurrence of defects due to peeling of the resist layer when the mold is released from the resist layer after the pattern of the mold is transferred to the resist layer. The resist pattern forming method according to claim 1, wherein the thickness is a thickness.
The resist pattern forming method according to claim 1 or 2, wherein the etch is a plasma etch.
Method of manufacturing a magnetic recording medium characterized by using a resist pattern forming method according to any one of claims 1-3.
Method of manufacturing a magnetic head characterized by using a resist pattern forming method according to any one of claims 1-3.
JP2003384694A 2003-11-14 2003-11-14 Resist pattern forming method, magnetic recording medium, and magnetic head manufacturing method Expired - Fee Related JP4322096B2 (en)
JP2003384694A JP4322096B2 (en) 2003-11-14 2003-11-14 Resist pattern forming method, magnetic recording medium, and magnetic head manufacturing method
US10/982,824 US7214624B2 (en) 2003-11-14 2004-11-08 Resist pattern forming method, magnetic recording medium manufacturing method and magnetic head manufacturing method
JP2005150335A JP2005150335A (en) 2005-06-09
JP4322096B2 true JP4322096B2 (en) 2009-08-26
ID=34616105
JP2003384694A Expired - Fee Related JP4322096B2 (en) 2003-11-14 2003-11-14 Resist pattern forming method, magnetic recording medium, and magnetic head manufacturing method
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