Source: https://patents.google.com/patent/WO1999057198A1/en
Timestamp: 2018-03-19 22:49:43
Document Index: 636538660

Matched Legal Cases: ['art 815', 'art 815', 'art 815', 'art 815', 'art 815', 'art 815']

WO1999057198A1 - Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content - Google Patents
Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content
WO1999057198A1
WO1999057198A1 PCT/US1999/007727 US9907727W WO1999057198A1 WO 1999057198 A1 WO1999057198 A1 WO 1999057198A1 US 9907727 W US9907727 W US 9907727W WO 1999057198 A1 WO1999057198 A1 WO 1999057198A1
PCT/US1999/007727
Den Helder Lambertus Johannes Van
A thermoplastic resin composition that contains an aromatic polycarbonate resin, a rubber modified graft copolymer comprising a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase, a phosphorus containing flame retardant compound, and a fluoropolymer, in an amount effective to improve the flame retardant performance of the composition, provided that the fluorine content of the composition does not exceed 0.1 percent by weight fluorine.
The invention relates to flame retardant resin compositions that are based on blends of polycarbonate resin and rubber modified graft copolymers and that have a low halogen content. BRIEF DESCRIPTION OF THE RELATED ART
Flame retardant compositions containing an aromatic polycarbonate resin a graft copolymer, a fluoropolymer and a phosphorus containing flame retardant compound are known and have been found to exhibit good flame retardency and good heat resistance, see for example, coassigned U.S. Patent Number 5,204,394. The compositions in the '394 patent contain, for example, from 0.2 to 0.5 parts by weight (pbw) per 100 parts by weight polytetrafluoroethylene per 100 pbw of the composition. In some applications, the amount of fluorine that may be contained in a composition is limited by government regulations, such as, for example, DIN/ VDE 0472, Part 815, Test B, which limits allowable fluorine content to less than or equal to 0.1 percent by weight fluorine. A thermoplastic resin composition that exhibits the high performance and good flame retardant properties of the compositions disclosed in the '394 patent and that exhibit a low fluorine content are desired. SUMMARY OF THE INVENTION
The thermoplastic resin composition of the present invention comprises: (a) an aromatic polycarbonate resin, (b) a rubber modified graft copolymer comprising a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase, (c) a phosphorus containing flame retardant compound, and
(d) a fluoropolymer, in an amount effective improve the flame retardant performance of the composition, provided that the fluorine content of the composition does not exceed 0.1 percent by weight fluorine. The composition of the present invention meets the low fluorine content requirements of DIN/ VDE 0472 Part 815, Test B yet unexpectedly provides high performance and good flame retardant properties. DETAILED DESCRIPTION OF THE INVENTION
In a preferred embodiment, the thermoplastic resin composition of the present invention is comprises, based on 100 pbw of the composition, from 60 to 95 pbw, more preferably from 75 to 95 pbw, even more preferably from 80 to 90 pbw, of the polycarbonate resin, from 1 to 15 pbw, more preferably from 4 to 10 pbw, even more preferably from 5 to 7 pbw, of the rubber modified graft copolymer, from 3 to 15 pbw, more preferably from 5 to 12 pbw, even more preferably from 8 to 10 pbw, of the phosphorus containing flame retardant compound, and wherein the amount of fluoropolymer is effective to provide a fluorine content of from 0.038 to 0.1 pbw, more preferably from 0.05 to 0.1 pbw, even more preferably from 0.08 to 0.1 pbw, fluorine. Aromatic Polycarbonate Resin
Aromatic polycarbonate resins suitable for use as the polycarbonate resin component of the thermoplastic resin composition of the present invention are known compounds whose preparation and properties have been described, see, generally, U.S. Patent Nos. 3,169,121, 4,487,896 and 5,411,999, the respective disclosures of which-are each incorporated herein by reference.
HO— A — OH (I)
wherein A is a divalent aromatic radical, with a carbonate precursor and contains structural units according to the formula (II):
II - (O - A -O -O - (π) wherein A is defined as above.
As used herein, the term "divalent aromatic radical "includes those divalent radicals containing a single aromatic ring such as phenylene, those divalent radicals containing a condensed aromatic ring system such as, for example, naphthlene, those divalent radicals containing two or more aromatic rings joined by a non-aromatic linkage, such as for example, an alkylene, alkylidene or sulf onyl group, any of which may be substituted at one or more sites on the aromatic ring with, for example, a halo group or (Cι-Cό)alkyl group. In a preferred embodiment, A is a divalent aromatic radical according to the formula (XXI):
-O- c-o-
CH' (III).
Suitable dihydric phenols include, for example, one or more of 2, 2-bis- (4-hydroxyphenyl) propane ("bisphenol A"), 2,2-bis(3,5-dimethyl-4- hydroxyphenyl)propane, bis(4-hydroxyphenyl) methane, 4,4-bis(4- hydroxyphenyl)heptane, 3,5,3',5'-tetrachloro-4,4'-dihydroxyphenyl)propane, 2,6-dihydroxy naphthalene, hydroquinone, 2,4'-dihydroxyphenyl sulfone. In a highly preferred embodiment, the dihydric phenol is bisphenol A. The carbonate precursor is one or more of a carbonyl halide, a carbonate ester or a haloformate. Suitable carbonyl halides include, for example, carbonyl bromide and carbonyl chloride. Suitable carbonate esters include, such as for example, diphenyl carbonate, dichlorophenyl carbonate, dinaphthyl carbonate, phenyl tolyl carbonate and ditolyl carbonate. Suitable haloformates include, for example, bishaloformates of a dihydric phenols, such as, for example, hydroquinone, or glycols, such as, for example, ethylene glycol, neopentyl glycol. In a highly preferred embodiment, the carbonate precursor is carbonyl chloride.
Suitable aromatic polycarbonate resins include linear aromatic polycarbonate resins and branched aromatic polycarbonate resins. Suitable linear aromatic polycarbonates resins include, e.g., bisphenol A polycarbonate resin. Suitable branched polycarbonates are known and are made by reacting a polyfunctional aromatic compound with a dihydric phenol and a carbonate precursor to form a branched polymer, see generally, U. S. Patent Nos. 3,544,514, 3,635,895 and 4,001,184, the respective disclosures of which are incorporated herein by reference. The polyfunctional compounds are generally aromatic and contain at least three functional groups which are carboxyl, carboxylic anhydrides, phenols, haloformates or mixtures thereof, such as, for example, l,l,l-tri(4-hydroxyphenyl)ethane, 1,3,5,-trihydroxy- benzene, trimellitic anhydride, trimellitic acid, trimellityl trichloride, 4- chloroformyl phthalic anhydride, pyromellitic acid, pyromellitic dianhydride, mellitic acid, mellitic anhydride, trimesic acid, benzophenonetetracarboxylic acid, benzophenone-tetracar boxy lie dianhydride. The preferred polyfunctional aromatic compounds are l,l,l-tri(4-hydroxyphenyl)ethane, trimellitic anhydride or trimellitic acid or their haloformate derivatives. In a preferred embodiment, the polycarbonate resin component of the present invention is a linear polycarbonate resin derived from bisphenol A and phosgene.
In a preferred embodiment, the weight average molecular weight of the polycarbonate resin is from about 10,000 to about 200,000 grams per mole ("g/mol"), as determined by gel permeation chromatography relative to polystyrene. Such resins typically exhibit an intrinsic viscosity of about 0.3 to about 1.5 deciliters per gram in methylene chloride at 25°C.
Polycarbonate resins are made by known methods, such as, for example, interfacial polymerization, transesterif ication, solution polymerization or melt polymerization.
Copolyester-carbonate resins are also suitable for use as the aromatic polycarbonate resin component of the present invention. Copolyester- carbonate resins suitable for use as the aromatic polycarbonate resin component of the thermoplastic resin composition of the present invention are known compounds whose preparation and properties have been described, see, generally, U.S. Patent Nos. 3,169,121, 4,430,484 and 4,487,896, the respective disclosures of which are each incorporated herein by reference. Copolyester-carbonate resins comprise linear or randomly branched polymers that contain recurring carbonate groups, carboxylate groups and aromatic carbocyclic groups in the polymer chain, in which at least some of the carbonate groups are bonded directly to the ring carbon atoms of the aromatic carbocyclic groups.
In a preferred embodiment, the copolyester-carbonate resin component of the present invention is derived from a carbonate precursor, at least one dihydric phenol and at least one dicarboxylic acid or dicarboxylic acid equivalent. In a preferred embodiment, the dicarboxylic acid is one according to the formula (IV): -6-
° ii ° i i
HO — C — A 1 — C — OH ,
wherein A' is alkylene, alkylidene, cycloaliphatic or aromatic and is preferably a non-substituted phenylene radical or a substituted phenylene radical that is substituted at one or more sites on the aromatic ring , wherein each of such substituent groups is independently (Q-Cβ) alkyl, and the copolyester carbonate resin comprises first structural units according to formula (II) above and second structural units according to formula (V):
- (O- C -A' -Q - {V) wherein A' is defined as above. Suitable carbonate precursors and dihydric phenols are those disclosed above.
Suitable dicarboxylic acids, include, for example, phthalic acid, isophthalic acid, terephthalic acid, dimethyl terephthalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dimethyl malonic acid, 1,12-dodecanoic acid, s-l,4-cyclohexane dicarboxylic acid, £πms-l,4-cyclohexane dicarboxylic acid, 4,4'- bisbenzoic acid, naphthalene-2,6-dicarboxylic acid. Suitable dicarboxylic acid equivalents include, for example, anhydride, ester or halide derivatives of the above disclosed dicarboxylic acids, such as, for example, phthalic anhydride, dimethyl terephthalate, succinyl chloride.
In a preferred embodiment, the ratio of ester bonds to carbonate bonds present in the copolyester carbonate resin is from 0.25 to 0.9 ester bonds per carbonate bond. -7-
Copolyester-carbonate resins are made by known methods, such as, for example, interfacial polymerization, transesterification, solution polymerization or melt polymerization. Rubber Modified Thermoplastic Resin
Rubber modified thermoplastic resins suitable as the rubber modified thermoplastic resin of the present invention comprise a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, . wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase.
Suitable materials for use as the elastomeric phase are polymers those having a glass transition temperature (Tg) of less than or equal to 25°C, more preferably less than or equal to 0 °C, and even more preferably less than or equal to -30°C. As referred to herein, the Tg of a polymer is the Tg value of polymer as measured by differential scanning calorimetry (heating rate 20° C/ minute, with the Tg value being determined at the inflection point). In a preferred embodiment, the elastomer phase comprises a polymer having repeating units derived from one or more monoethylenically unsaturated monomers selected from conjugated diene monomers, non- conjugated diene monomers or (Qι-Gι 2) alkyl (meth)acrylate monomers Suitable conjugated diene monomers include, e.g., 1,3-butadiene, isoprene, 1,3-heptadiene, methyl-l,3-pentadiene, 2,3-dimethylbutadiene, 2- ethyl-l,3-pentadiene, 1,3-hexadiene, 2, 4, hexadiene, dichlorobutadiene, bromobutadiene and dibromobutadiene as well as mixtures of conjugated -8-
diene monomers. In a preferred embodiment, the conjugated diene monomer is 1,3-butadiene.
Suitable non-conjugated diene monomers include, e.g., ethylidene norbornene, dicyclopentadiene, hexadiene or phenyl norbornene. As used herein, the term "(G[-Ci2)alkyl" means a straight or branched alkyl substituent group having from 1 to 12 carbon atoms per group and includes, e.g., methyl, ethyl, n-butyl, sec-butyl, t-butyl, n-propyl, iso-propyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl and dodecyl, and the terminology "(meth)acrylate monomers" refers collectively to acrylate monomers and methacrylate monomers. Suitable (Cι-Q 2)alkyl
(meth)acrylate monomers include ( [-Ci2)alkyl acrylate monomers, e.g., ethyl acrylate, butyl acrylate, iso-pentyl acrylate, n-hexyl acrylate, 2-ethyl hexyl acrylate, and their (Cι-Ci2)alkyl methacrylate analogs such as, e.g., methyl methacrylate, ethyl methacrylate, propyl methacrylate, iso-propyl methacrylate, butyl methacrylate, hexyl methacrylate, decyl methacrylate.
The elastomeric phase may, optionally, include up to about 25 percent by weight ("wt%") of one or more monomers selected from (C2-Cs)olefin monomers, vinyl aromatic monomers and monoethylenically unsarurated nitrile monomers. As used herein, the term "(C.2-C8)olefin monomers" means a compound having from 2 to 8 carbon atoms per molecule and having a single site of ethylenic unsaturation per molecule. Suitable (C2-Cs)olefin monomers include, e.g., ethylene, propene, 1-butene, 1-pentene, heptene.
Suitable vinyl aromatic monomers include, e.g., styrene and substituted styrenes having one or more alkyl, alkoxyl, hydroxyl or halo substituent group attached to the aromatic ring, including, e.g., -methyl styrene, p-methyl styrene, vinyl toluene, vinyl xylene, trimethyl styrene, butyl styrene, chlorostyrene, dichlorostyrene, bromostyrene, p-hydroxystyrene, methoxystyrene and vinyl-substituted condensed aromatic ring structures, such as, e.g., vinyl naphthalene, vinyl anthracene, as well as mixtures of vinyl aromatic monomers. As used herein, the term "monoethylenically unsaturated nitrile monomer" means an acyclic compound that includes a single nitrile group and a single site of ethylenic unsaturation per molecule and includes, e.g., acrylonitrile, methacrylonitrile, α- chloro acrylonitrile.
The elastomeric phase may, optionally, include a minor amount, e.g., up to 5 wt%, of repeating units derived from a polyethylenically unsaturated "crosslinking" monomer, e.g., butylene diacrylate, divinyl benzene, butene diol dimethacrylate, trimethylolpropane tri(meth)acrylate. As used herein, the term "polyethylenically unsaturated" means having two or more sites of ethylenic unsaturation per molecule. The elastomeric phase may, particularly in those embodiments wherein the elastomeric phase has repeating units derived from alkyl (meth)acrylate monomers, include a minor amount, e.g., up to 5 wt% of repeating units derived from a polyethylenically unsaturated "graftlinking" monomer. Suitable graftlinking monomers include those monomers having a first site of ethylenic unsaturation with a reactivity similar to that of the monoethylenically unsaturated monomers from which the respective substrate or superstrate is derived and a second site of ethylenic unsaturation with a relative reactivity that is substantially different from that of the monoethylenically unsaturated monomers from which the elastomeric phase is derived so that the first site reacts during synthesis of the elastomeric phase and the second site is available for later reaction under different reaction conditions, e.g., during synthesis of the rigid thermoplastic phase. Suitable -10-
graftlinking monomers include, e.g., allyl methacrylate, diallyl maleate, triallyl cyanurate.
In a preferred embodiment, the elastomeric phase comprises from 60 to 100 wt% repeating units derived from one or more conjugated diene monomers and from 0 to 40 wt% repeating units derived from one or more monomers selected from vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers, such as, for example, a styrene-butadiene copolymer, an acrylonitrile-butadiene copolymer or a styrene-butadiene- acrylonitrile copolymer. In an alternative preferred embodiment, the elastomeric phase comprises repeating units derived from one or more (Ci-Ci2)alkyl acrylate monomers. In a more highly preferred embodiment, the rubbery polymeric substrate comprises from 40 to 95 wt% repeating units derived from one or more (Cι-Ci2)alkyl acrylate monomers, more preferably from one or more monomers selected from ethyl acrylate, butyl acrylate and n-hexyl acrylate.
In a preferred embodiment, the elastomeric phase is made by aqueous emulsion polymerization in the presence of a free radical initiator, e.g., an azonitrile initiator, an organic peroxide initiator, a persulfate initiator or a redox initiator system, and, optionally, in the presence of a chain transfer agent, e.g., an alkyl mercaptan and coagulated to form particles of elastomeric phase material. In a preferred embodiment, the emulsion polymerized particles of elastomeric phase material have a weight average particle size of 50 to 800 ran, more preferably, of from 100 to 500 nm, as measured by light transmission. The size of emulsion polymerized elastomeric particles may optionally be increased by mechanical or chemical agglomeration of the emulsion polymerized particles, according to known techniques.
(b) Rigid Thermoplastic Phase -11-
The rigid thermoplastic resin phase comprises one or more thermoplastic polymers and exhibits a Tg of greater than 25°C, preferably greater than or equal to 90°C and even more preferably greater than or equal to 100°C. In a preferred embodiment, the rigid thermoplastic phase comprises a polymer or a mixture of two or more polymers each having repeating units derived from one or more monomers selected from the group consisting of ( l-Ci 2)cdkyl (meth)acrylate monomers, vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers. Suitable (Cι-Ci2)alkyl (meth)acrylate monomers, vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers are those set forth above in the description of the elastomeric phase.
In a highly preferred embodiment, rigid thermoplastic phase comprises one or more vinyl aromatic polymers. Suitable vinyl aromatic polymers comprise at least 50 wt% repeating units derived from one or more vinyl aromatic monomers.
The rigid thermoplastic phase is made according to known processes, e.g., mass polymerization, emulsion polymerization, suspension polymerization or combinations thereof, wherein a at least a portion of the rigid thermoplastic phase is chemically bonded, i.e., "grafted" to the elastomeric phase via reaction with unsaturated sites present in the elastomeric phase. The unsaturated sites in the elastomeric phase are provided, e.g., by residual unsaturated sites in repeating units derived from a -12-
conjugated diene or by residual unsaturated sites in repeating units derived from a graftlinking monomer.
In an alternative preferred embodiment, at least a portion of the thermoplastic phase is made by a mass polymerization process, wherein particles of the material from which the elastomeric phase is to be formed are dispersed in a mixture of the monomers from which the rigid thermoplastic phase is to be formed and the monomers of the mixture are then polymerized to form the rubber modified thermoplastic resin.
The amount of grafting that takes place between the rigid thermoplastic phase and the elastomeric phase varies with the relative amount and composition of the elastomeric phase. In a preferred embodiment, from 10 to 90 wt%, preferably from 30 to 80 wt%, even more preferably 65 to 80 wt% of the rigid thermoplastic phase is chemically grafted to the elastomeric phase and from 10 to 90 wt%, preferably from 20 to 70 wt%, more preferably from 20 to 35 wt% of the rigid thermoplastic phase remains "free, i.e., non-grafted.
The rigid thermoplastic phase of the rubber modified thermoplastic resin may be formed: (i) solely by polymerization carried out in the presence of the elastomeric phase or (ii) by addition of one or more separately polymerized rigid thermoplastic polymers to a rigid thermoplastic polymer that has been polymerized in the presence of the elastomeric phase. In a preferred , less than 10 pbw, more preferably less than 5 pbw of separately polymerized rigid thermoplastic polymer is added per 100 pbw of the thermoplastic resin composition of the present invention. Most preferably no -13-
separately polymerized rigid thermoplastic polymer is added to the thermoplastic resin composition of the present invention.
Each of the polymers of the elastomeric phase and of the rigid thermoplastic resin phase of the rubber modified thermoplastic resin may, provided that the Tg limitation for the respective phase is satisfied, optionally include up to 10 wt% of third repeating units derived from one or more other copolymerizable monomers such as, e.g., monoethylenically unsaturated carboxylic acids such as, e.g., acrylic acid, methacrylic acid, itaconic acid, hydroxy(Cι-Ci2)a.kyl (meth)acrylate monomers such as, e.g., hydroxyethyl methacrylate; (C4-Ci2)cycloalkyl (meth)acrylate monomers such as e.g., cyclohexyl methacrylate; (meth)acrylamide monomers such as e.g., acrylamide and methacrylamide; maleimide monomers such as, e.g., N-alkyl maleimides, N-aryl maleimides, maleic anhydride, vinyl esters such as, e.g., vinyl acetate and vinyl propionate. As used herein, the term "(C4- Ci2)cy l°alkyl" means a cyclic alkyl substituent group having from 4 to 12 carbon atoms per group and the term "(meth)acrylamide" refers collectively to acrylamides and methacrylamides. -14-
Fluoropolvmer Additive
Suitable fluoropolymers and methods for making such fluoropolymers are known, see, e.g., U.S Patent Nos. 3,671,487, 3,723,373 and 3,383,092. Suitable fluoropolymers include homopolymers and copolymers that comprise repeating units derived from one or more fluorinated olefin monomers. The term "fluorinated olefin monomer" means an olefin monomer that includes at least one fluorine atom substituent. Suitable fluorinated olefin monomers include , e.g., fluoroethylenes such as, e.g., CF2=CF2, CHF=CF2, CH2=CF2, CH2=CHF, CC1F=CF2, CC12=CF2, CC1F=CC1F, CHF=CCl2, CH2=CC1F, and CCl2=CClF and fluoropropylenes such as, e.g., CF3CF=CF2, CF3CF=CHF, CF3CH=CF2, CF3CH=CH2, CF3CF=CHF, CHF2CH=CHF and CF3CH=CH2. In a preferred embodiment, the fluorinated olefin monomer is one or more of tetrafluoroethylene (CF2=CF2), chlorotrichloroethylene (CC1F=CF2), vinylidene fluoride (CH2=CF2) and hexafluoropropylene (CF2=CFCF3).
Suitable fluorinated olefin homopolymers include e.g., poly(tetra- fluoroethy lene), poly (hexafluoroethy lene) .
Suitable fluorinated olefin copolymers include copolymers comprising repeating units derived from two or more fluorinated olefin copolymers such as , e.g., poly(tetrafluoroethylene-hexafluoroethylene), and copolymers comprising repeating units derived from one or more fluorinated monomers and one or more non-fluorinated monoethylenically unsaturated monomers that are copolymerizable with the fluorinated monomers such as, e.g., poly(tetrafluoroethylene-ethylene-propylene) copolymers. Suitable non- fluorinated monoethylenically unsaturated monomers include e.g., olefin monomers such as, e.g., ethylene, propylene butene, acrylate monomers such as e.g., methyl methacrylate, butyl acrylate, vinyl ethers, such as, e.g., -15-
cyclohexyl vinyl ether, ethyl vinyl ether, n-butyl vinyl ether, vinyl esters such as, e.g., vinyl acetate, vinyl versatate.
In a highly preferred embodiment , the fluoropolymer is a poly(tetrafluoroethylene) homopolymer ("PTFE"). In a preferred embodiment, a fluoropolymer is added to the rubber modified thermoplastic resin in the form of a fluoropolymer additive that comprises particles of fluoropolymer encapsulated in a second polymer.
In a preferred embodiment, the fluoropolymer additive comprises from 30 to 70 wt%, more preferably 40 to 60 wt%, of the fluoropolymer and from 30 to 70 wt%, more preferably 40 to 60 wt%, of the second polymer.
In a preferred embodiment, the monoethylenically unsaturated monomers that are emulsion polymerized to form the second polymer -16-
comprise one or more monomers selected from vinyl aromatic monomers, monoethylenically unsaturated nitrile monomer and (C^-Ci2)alkyl (meth)acrylate monomers.
In a highly preferred embodiment, the second polymer comprises repeating units derived from styrene and acrylonitrile. More preferably, the second polymer comprises from 60 to 90 wt% repeating units derived from styrene and from 10 to 40 wt% repeating units derived from acrylonitrile.
A chain transfer agent such as, e.g., a (C -Cι3) alkyl mercaptan compound such as nonyl mercaptan, t-dodecyl mercaptan, may, optionally, be added to the reaction vessel during the polymerization reaction to reduce the molecular weight of the second polymer. In a preferred embodiment, no chain transfer agent is used.
In a preferred embodiment, the stabilized fluoropolymer dispersion is charged to a reaction vessel and heated with stirring. The initiator system and the one or more monoethylenically unsaturated monomers are then charged to the reaction vessel and heated to polymerize the monomers in the presence of the fluoropolymer particles of the dispersion to thereby form the second polymer. -17-
Suitable fluoropolymer additives and emulsion polymerization methods are disclosed in EP 0 739 914 Al.
In a preferred embodiment, the second polymer exhibits a weight average molecular weight ("Mw") of from 75 x 103 to 800 x 103, a number average molecular weight ("Mn") of from 30 x 103 to 200 x 103 and a polydispersity (M /Mn) of less than or equal to 6. Phosphorus-containing Flame Retardant Compound
Phosphorus-containing compounds suitable as the phosphorus- containing flame retardant compound of the present invention are known compounds including monophosphate esters such as, for example, triphenyl phosphate, tricresyl phosphate, tritolyl phosphate, diphenyl ' tricresylphosphate, phenyl bisdodecyl phosphate, ethyl diphenyl phosphate, as well as diphosphate esters and oligomeric phosphates such as, for example, resorcinol diphosphate, diphenyl hydrogen phosphate, bisphenol A diphosphate, 2-ethylhexyl hydrogen phosphate. Suitable oligomeric phosphate compounds are set forth in coassigned U.S. Patent Number 5,672,645, to Johannes C. Gossens et al for a "Polymer Mixture Having Aromatic Polycarbonate, Styrene Containing Copolymer and/ or Graft Copolymer and a Flame Retardant, Articles Formed Therefrom", the disclosure of which is hereby incorporated herein by reference.
In a preferred embodiment, the phosphorus-containing compound of the present invention is an oligomer compound according to the structural formula (IV): -18-
Rr (O) - O - X — O — P — (O) — ] — R a n
I b , <
(IV) wherein Ri, R2, R3 and R are each independently aryl, which may be optionally substituted with halo or alkyl, X is arylene, optionally substituted with halo or alkyl, a, b, c and d are each independently 0 or 1, and n is an integer of from 1 to 5.
As used herein, aryl means a monovalent radical containing one or more aromatic rings per radical, which may optionally be substituted on the one or more aromatic rings with one or more alkyl groups, each preferably (C -C6)alkyl and which, in the case wherein the radical contains two or more rings, may be fused rings.
As used herein, arylene means a divalent radical containing one or more aromatic rings per radical, which may optionally be substituted on the one or more aromatic rings with one or more alkyl groups, each preferably (C -Cβ)alkyl and which, in the case wherein the divalent radical contains two or more rings, the rings may be may be fused or may be joined by a non- aromatic linkages, such as for example, an alkylene, alkylidene, any of which may be substituted at one or more sites on the aromatic ring with a halo group or (C -C6)alkyl group. In a preferred embodiment, X is a residue derived from resorcinol or hydroquinone.
In a preferred embodiment, Rl, R2, R3 and R4 are each phenyl, a, b, c and d are each 1, X is phenylene and n is 2 or wherein the phosphate containing compound is a blend of phosphorus containing oligomers with n having an average value of from 1 to 2, more preferably from 1.2 to 1.7. -19-
(1) antioxidants, such as, e.g., organophosphites , e.g., tris(nonyl- phenyl)ρhosphite, (2,4,6-tri-tert-buty lphenyl)(2-buty 1-2-ethy 1-1,3- propanediol)phosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite or distearyl pentaerythritol diphosphite, as well as alkylated monophenols, polyphenols, alkylated reaction products of polyphenols with dienes, such as, e.g., butylated reaction products of para-cresol and dicyclopentadiene, alkylated hydroquinones, hydroxylated thiodiphenyl ethers, alkylidene-bisphenols, benzyl compounds, acylaminophenols, esters of beta-(3,5-di-tert-butyl-4- hydroxyphenol)-propionic acid with monohydric or polyhydric alcohols, esters of beta-(5-tert-butyl-4-hydroxy-3-methylphenyl)- propionic acid with monohydric or polyhydric alcohols, esters of beta-
(5-tert-butyl-4-hydroxy-3-methylphenyl) propionic acid with mono-or polyhydric alcohols, esters of thioalkyl or thioaryl compounds, such as, e.g., distearylthiopropionate, dilaurylthiopropionate, ditridecylthiodipropionate, amides of beta-(3,5-di-tert-butyl-4- hydroxyphenol)-propionic acid;
(2) UV absorbers and light stabilizers such as, e.g., (i) 2-(2'- hydroxyphenyl)-benzotriazoles, 2-Hydroxy-benzophenones; (ii) esters of substituted and unsubstituted benzoic acids, (iii) acrylates, (iv) nickel compounds; (3) metal deactivators, such as, e.g., N,N'-diphenyloxalic acid diamide,
3-salicy loy lamino-1 ,2,4-triazole;
(4) peroxide scavengers, such as, e.g., (Cιo-C.2θ)alkyl esters of β- thiodipropionic acid, mercapto benzimidazole; -20-
(6) basic co-stabilizers, such as, e.g., melamine, polyvinylpyrrolidone, triallyl cyanurate; urea derivatives, hydrazine derivatives; amines, polyamides, polyurethanes; (7) sterically hindered amines such as, e.g., triisopropanol amine or the reaction product of 2,4-dichloro-6-(4-morpholinyl)-l, 3, 5-triazine with a polymer of 1, 6-diamine, N, N'-Bis(-2, 2, 4, 6-tetramethyl-4- piperidenyl) hexane;
(9) fillers and reinforcing agents, such as, e.g., silicates, Ti02, glass fibers, carbon black, graphite, calcium carbonate, talc, mica;
(9) other additives such as, e.g., lubricants such as , e.g., pentaerythritol tetrastearate, EBS wax, silicone fluids, plasticizers, optical brighteners, pigments, dyes, colorants, flameproofing agents; anti-static agents; blowing agents;
(10) other flame retardant additives such as, for example, borate flame retardant compounds, in addition to the above described phosphorus- containing flame retardant additive. The thermoplastic resin composition of the present invention is made by combining and mixing the components of the composition of the present invention under conditions suitable for the formation of a blend of the components, such as for example, by melt mixing using, for example, a two- roll mill, a Banbury mixer or a single screw or twin-screw extruder, and, optionally, then reducing the composition so formed to particulate form, e.g., by pelletizing or grinding the composition. -21-
The components used in the thermoplastic resin compositions of Examples 1-2 of the present invention and of Comparative Examples C1-C3 were as follows: PC-1 Branched polycarbonate resin derived from bisphenol A, phosgene and having a weight average molecular weight of about 32,000 g/mol. PC-2: Linear polycarbonate resin derived from bisphenol A, phosgene and trimellitic trichlorite and having a weight average molecular weight of about 31,000 g/mol.
ABS: Emulsion polymerized acrylonitrile-butadiene-styrene (" ABS") graft copolymer comprising 50 pbw of a discontinuous elastomeric phase (butadiene) and 50 pbw of a rigid thermoplastic phase (copolymer of 75 pbw styrene and 25 pbw acrylonitrile);
TSAN: Additive made by copolymerizing styrene and acrylonitrile in the presence of an aqueous dispersion of PTFE (50 wt% PTFE, 50wt% styrene-acrylonitrile copolymer). RDP Resorcinol diphosphate (Rheofos RDP, from FMC Corporation, Ltd.).
TiO2 Titanium dioxide (RFC 5, Tioxide Europe).
The respective compositions were made by combining the above-listed components in the relative amounts (in pbw) set forth in TABLE I in a twin -22-
screw extruder. The compositions were then injection molded at 255°C into a 60°C mold to form samples for testing.
The samples were tested according to the following methods: melt volume rate was measured according to ISO 1133 at 260°C using a 5 kilogram weight, notched impact Izod performance was measured according to ISO 180, Vicat B temperature was measured according to ISO 306 tensile properties were measured according to ISO 527, flame retardant properties were measured according to UL 94 and CSTBNF P92505. The compositions were evaluated for compliance with DIN/ VDE 0472, Part 815, Test B which requires a fluorine content of less than or equal to 0.1 wt%.
Results of the testing are set forth in TABLES I for each of the compositions of Examples 1-2 and Comparative Examples C1-C3 and as melt viscosity ("MVR") expressed in milliliters per 10 minute ("ml/10 min"), notched Izod impact strength at room temperature ("RT"), 10°C and 0°C " expressed in kilojoules per square meter ("KJ/m2"), tensile strength and tensile modulus in Newtons per square millimeter ("N/mm2"), elongation at break as percent of original length (%), Vicat B temperature expressed in °C, UL 94 classification as V-0, V-l or V-2, total flame out time in seconds ("s"), number of flaming drips per 5 samples, and compliance with DIN/ VDE 0472 Part 815, Test B and CSTBNF P92505, expressed as a rating of "Pass" or "Fail".
The results of the testing are set forth below in TABLE I for reach of the compositions of Examples 1-2 and Comparative Examples C1-C3. -23-
Cl C2 C3 1 2
PC-1 84.25 84.15 83.95 84.05 —
PC-2 — — — — 84.05
ABS 6 6 6 6 6
RDP 9 9 9 9 9
TSAN — 0.1 0.3 0.2 0.2
Additives 0.4 0.4 0.4 0.4 0.4
Ti02 0.35 0.35 0.35 0.35 0.35
MVR at 260°C (ml/ 10 min) 9.8 9.2 8.1 8.4 16.7
RT 43.9 43.9 46.4 44.0 52.3
10° 17.6 18.4 18.8 17.9 45.5
0° 16.2 16.6 16.8 16.3 19.1
Tensile Modulus (N/mm2) 2611 2579 2631 2590 2640
Tensile Strength at yield (N/mm2) 64.9 64.5 64.4 64.6 64.0
Elongation at break (%) 46 72 66 74 107
Vicat B (°C) 111.4 112.4 112.6 112.8 111.4
UL 94 V-2 V-l V-0 V-0 V-0
Flame out time (s) 98 81 14 23 13
Flaming drips 5 0 0 0 0
DIN/ VDE 0472, Part 815, Test B Pass Pass Fail Pass Pass
NF P92505 Fail Fail Pass Pass Pass
The composition of the present invention meets the low fluorine content requirements of DIN/ VDE 0472 Part 815, Test B, yet unexpectedly provides high performance and good flame retardant properties.
(b) a rubber modified graft copolymer comprising a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase,
(c) a phosphorus containing flame retardant compound, and
(d) a fluoropolymer, in an amount effective improve the flame retardant performance of the composition, provided that the fluorine content of the composition does not exceed 0.1 percent by weight fluorine.
2. The composition of claim 1, wherein the composition comprises from 60 to 95 parts by weight of the polycarbonate resin, from 1 to 15 parts by weight of the rubber modified graft copolymer, from 3 to 15 parts by weight of the phosphorus containing flame retardant compound and wherein the amount of fluoropolymer is effective to provide a fluorine content of from 0.038 to 0.1 parts by weight of the fluoropolymer, each based on 100 pbw of the composition
3. The composition of claim 1, wherein the aromatic polycarbonate resin comprises a linear aromatic polycarbonate resin.
4. The composition of claim 1, wherein the aromatic polycarbonate resin comprises a branched aromatic polycarbonate resin.
5. The composition of claim 1, wherein the elastomeric phase comprises a polybutadiene rubber or a poly(styrene-butadiene) rubber and the rigid thermoplastic phase comprises structural units derived from one or more monomers selected from vinyl aromatic monomers and a monoethylenically unsaturated nitrile monomers. -25-
6. The composition of claim 5, wherein rigid phase comprises a copolymer of derived from monomers selected from the group consisting of styrene, ╬▒-methyl styrene and acrylonitrile.
7. The composition of claim 1, wherein the phosphorus containing compound comprises a compound according to the structural formula:
RlΓÇö (O) ΓÇö P ΓÇö O ΓÇö X ΓÇö O ΓÇö P ΓÇö (O) ΓÇö ] ΓÇö R4 a I I d n
(┬░) (O)
I I c 2 R3 wherein Ri, R2, R3 and R are each independently aryl, which may be optionally substituted with halo or alkyl,
X is arylene, optionally substituted with halo or alkyl, a, b, c and d are each independently 0 or 1, and n is an integer of from 1 to 5.
8. The composition of claim 7, wherein, Ri, R2, R3 and R4 are each phenyl, a, b, c and d are each 1, X is phenylene.
9. The composition of claim 7, wherein n is 2
10. The composition of claim 7, wherein the phosphate containing compound is a blend of phosphorus containing oligomers with n having an average value of from 1 to 2.
11. The composition of claim 1, wherein the fluoropolymer is a tetrafluoroethylene polymer. -26-
12. The composition of claim 1, wherein the fluoropolymer is added to the composition in the form of an additive made by emulsion polymerization of one or more monoethylenically unsaturated monomers in the presence of an aqueous dispersion of the fluoropolymer to form a second polymer in the presence of the fluoropolymer.
13. The composition of claim 12, wherein the additive is made by emulsion polymerization of styrene and acrylonitrile in the presence of an aqueous dispersion of the fluoropolymer.
14. An article molded from the composition of claim 1.
PCT/US1999/007727 1998-05-01 1999-04-08 Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content WO1999057198A1 (en)
US7164098 true 1998-05-01 1998-05-01
US09/071,640 1998-05-01
EP19990915331 EP1076675A1 (en) 1998-05-01 1999-04-08 Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content
JP2000547163A JP2002513837A (en) 1998-05-01 1999-04-08 Low halogen content flame retardant polycarbonate / rubber modified graft copolymer resin blends
WO1999057198A1 true true WO1999057198A1 (en) 1999-11-11
ID=22102623
PCT/US1999/007727 WO1999057198A1 (en) 1998-05-01 1999-04-08 Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content
JP (1) JP2002513837A (en)
CN (1) CN1300308A (en)
EP (1) EP1076675A1 (en)
WO (1) WO1999057198A1 (en)
WO2007031201A1 (en) 2005-09-14 2007-03-22 Bayer Materialscience Ag A thermoplastic molding composition and articles thermoformed therefrom
EP0693495A1 (en) * 1994-07-22 1996-01-24 Bayer Ag Phosphoric acid esters having several phosphor atoms
EP0700969A1 (en) * 1994-09-05 1996-03-13 Cheil Industries Inc. Flameproof thermoplastic resin compositions
EP0700968A1 (en) * 1994-09-05 1996-03-13 Cheil Industries Inc. Flameproof thermoplastic resin compositions
CN1300308A (en) 2001-06-20 application
EP1076675A1 (en) 2001-02-21 application
JP2002513837A (en) 2002-05-14 application
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