Source: https://patents.google.com/patent/DE60034840T2/en
Timestamp: 2020-02-17 12:15:49
Document Index: 85087729

Matched Legal Cases: ['Application No. 25633877', 'art 5', 'art 5', 'art 6', 'art 5', 'art 5', 'art 5', 'art 208', 'art 208', 'art 208', 'art 208', 'art 208', 'art 313', 'art 314', 'art 314', 'art 313', 'art 313', 'art 313', 'art 314', 'art 313', 'art 313']

DE60034840T2 - Photovoltaic module - Google Patents
DE60034840T2
DE60034840T2 DE60034840T DE60034840T DE60034840T2 DE 60034840 T2 DE60034840 T2 DE 60034840T2 DE 60034840 T DE60034840 T DE 60034840T DE 60034840 T DE60034840 T DE 60034840T DE 60034840 T2 DE60034840 T2 DE 60034840T2
DE60034840T
DE60034840D1 (en
DE60034840T3 (en
1999-03-23 Priority to JP7791099 priority Critical
1999-03-23 Priority to JP07791099A priority patent/JP4224161B2/en
2007-06-28 Publication of DE60034840D1 publication Critical patent/DE60034840D1/en
2007-09-20 Publication of DE60034840T2 publication Critical patent/DE60034840T2/en
2008-02-18 First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27524696&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60034840(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
2011-02-24 Publication of DE60034840T3 publication Critical patent/DE60034840T3/en
The The invention relates to a photovoltaic module with a semiconductor layer, formed on a glass substrate and by an encapsulating material is closed. Known photovoltaic modules are u. a. such of the crystal type using monocrystalline or polycrystalline Silicon are produced, and those of the amorphous type, which are under Use of amorphous silicon are made. In any case must be noted be that silicon easily chemically reacts and is fragile if it is a kinetic Load is suspended.
The Use of an encapsulation structure has been chosen to control the silicon to protect in the photovoltaic module and electrically isolating the semiconductor layer of the module. According to the proposed Encapsulation technique, the encapsulation structure, an encapsulating material normally made of EVA (ethylene-vinyl acetate copolymer) or EVAT (three-part copolymer with ethylene-vinyl acetate triallyl isocyanurate bridge). If an encapsulation of the semiconductor layer with an encapsulating material takes place, the substrate and the deposited on the substrate Encapsulating material usually combined using pressure and heat.
There the encapsulating material is heated under pressure, it contracts. Therefore, the encapsulating material is sized to be larger as the substrate, under the heat shrinkage To compensate for pressure. The extent of shrinkage of the encapsulating material by heat however, under pressure may function as a function of various factors involved in the heating / pressurizing process Factors vary. The end result can often be a perimeter of the Be encapsulating material that over its counterpart the substrate out to the outside protrudes.
If the photovoltaic module is used in a state in which the peripheral edge of the encapsulating material over the counterpart of the substrate out to the outside protrudes, may inadvertently create an external force on the section of the encapsulating material be over the end surface protruding from the substrate, and a repetitive exercise of a such power can finally damaging the circumference of the encapsulating material to at least partially to separate the encapsulating material from the substrate through a gap the rainwater can get into the semiconductor layer.
14 In the accompanying drawings, there is schematically illustrated a known thin film type photovoltaic module capable of improving the resistance of the photocells to environmental influences. The illustrated photovoltaic module is the same module as disclosed in Japanese Laid-Open Utility Model Application No. 25633877. Regarding 14 is a front surface glass cover 1 shown serving as a transparent substrate on the back surface of a plurality of photovoltaic thin-film cells 2 arranged and through the backside electrode 3 connected in series and / or in parallel. The backside electrode 3 is with an output connection wire 4 connected, which is usually made of metal foil. The backside electrode 3 is through a filling part 5 locked. In particular, the filling part becomes 5 normally formed by hot melt EVA, with the corresponding end of the output lead wire 4 is left standing. The back surface of the filling part 5 is with a back surface encapsulation material (weather resistant film) 6 coated, which has a three-layer structure, wherein a metal foil 6a from a pair of insulating films 6b is sandwiched. The backfill filling part 6 is provided with a through hole serving as the output terminal section Q for guiding the output terminal wire 4 serves to the outside. The output connection wire 4 is through the through hole to the back surface side of the Rückflächenkapselungsmaterials 6 drawn. The outgoing output lead wire 4 is at its front end at the terminal 7 fixed by solder or by a screw. An output line wire 8th is with the connection 7 connected. The connection section with the output connection wire 4 , the connection 7 and the output line wire 8th is in a junction box 9 added.
The exposed areas of the filling part 5 and the output terminal wire 4 of the output terminal section Q can be sealed with protective resin such as silicon resin. Accordingly, the surface of the connection 7 with protective resin, such as silicon resin.
15 In the accompanying drawings, there is schematically illustrated a known photovoltaic module of the crystal type 15 are a variety of photocells 11 of the crystal type on the back surface of a front surface glass coating 1 arranged and through connecting wires 12 connected. The photovoltaic cell located at one end of the module 11 is with an output connection wire 4 connected, which is usually made of metal foil. Otherwise, the module has according to 15 essentially the same configuration as the module according to 14 ,
None of the photovoltaic modules listed above are moisture resistant and water resistance satisfactory because the filling part 5 is exposed at the output terminal section Q of the atmosphere. When the output terminal section Q is protected by silicon resin or other protective material, it is satisfactory in neither moisture resistance nor water resistance since the section Q is practically exposed to the atmosphere. Consequently, in particular, when water in the interior of the junction box 9 penetrates, moisture through the output terminal section Q in the filling part 5 to thereby make the output terminal wire 4 and the backside electrode 3 to be corroded. This is a major disadvantage of known photovoltaic modules, especially with regard to environmental impact resistance. In fact, most malfunctions that occur in photovoltaic modules are a corroded back electrode 3 attributed to moisture that has penetrated from the outside in this. Document EP-A-0 969 521 describes a photovoltaic module encapsulated between resin layers.
in view of the preceding circumstances It is therefore the object of the present invention, a photovoltaic Module that can prevent its encapsulating material, which encapsulates the semiconductor layer is damaged and its circumference from Substrate is separated.
According to the invention above described object by providing a photovoltaic Module according to claim 1 achieved. Further advantageous embodiments are set out in claim 2 and 3.
The The invention will become apparent from the following detailed description with the attached Better understandable drawings, these show the following:
1 is a schematic sectional view of an example of a photovoltaic module.
2 is a schematic sectional view of a second example of a photovoltaic module.
3 is a schematic sectional view of a third example of a photovoltaic module.
4 is a schematic sectional view of a fourth example of a photovoltaic module.
5 is a schematic sectional view of a fifth example of a photovoltaic module.
6 Fig. 12 is a schematic perspective view of a fifth example of the photovoltaic module showing the main encapsulant and the vapor barrier material disposed on the back surface of the module.
7 Fig. 12 is a schematic sectional view of a sixth example of a photovoltaic module illustrating a method of manufacturing a photovoltaic module.
8th Fig. 12 is a schematic sectional view of the sixth example of a photovoltaic module disposed in a vacuum laminating apparatus, illustrating the step of heat bonding in its manufacturing method.
9 Fig. 12 is a schematic sectional view of the sixth example of a photovoltaic module illustrating the laminate immediately before the clipping step in its manufacturing process.
10 Fig. 12 is a schematic sectional view of the sixth example of a photovoltaic module illustrating the laminate cut in the clipping step.
11 Fig. 10 is a schematic sectional view of an embodiment of a thin-film type photovoltaic module according to the present invention.
12 Fig. 13 is a schematic sectional view of another embodiment of a crystalline type photovoltaic module according to the present invention.
13 Fig. 10 is a schematic sectional view of another embodiment of a thin-film type photovoltaic module according to the present invention.
14 is a schematic sectional view of a known photovoltaic module.
15 Fig. 10 is a schematic sectional view of another known thin film type photovoltaic module.
1 illustrates an example of a photovoltaic module, denoted overall by the reference numeral 100 is designated. In 1 denotes the reference numeral 101 a glass substrate. Both the front surface and the back surface of the glass substrate 101 are chamfered along their edges to make chamfers (second chamfered surfaces) 101 to produce at a predetermined inclination angle.
Transparent conductive film strips 103 are on the back surface of the glass substrate 101 at regular intervals along the entire length of the glass substrate 101 formed in a predetermined direction, with a SiO 2 film between them 102 located. The SiO 2 film 102 and the transparent conductive film strips 103 Although in this embodiment, on the bevels 102 on the back surface of the substrate 101 but can be arranged from the bevels 102 be removed.
Semiconductor film strip 104 are on the transparent conductive film 103 trained at regular intervals. A back electrode layer 105 is on each strip of the semiconductor layer 104 applied to produce a multi-layered structure. Two adjacent semiconductor layer strips each 104 are through the transparent conductive film 103 and the back electrode layer 105 electrically connected in series.
The transparent conductive film strips 103 which are arranged at the opposite ends as viewed in a direction perpendicular to this predetermined direction, are connected to respective bus bars 106a . 106b provided with solder on them 107 are attached and act as external optical electrodes. One of the busbars or the busbar 106a acts as an anode while the other busbar 106a acts as a cathode.
The on the back surface of the glass substrate 101 formed semiconductor layer 104 is with an encapsulating material 108 coated. The encapsulating material 108 has a resin layer 109 of a resin material such as EVA or EVAT, and a resin film layer 110 on top of the resin layer 109 covered. Although not shown, each of the paired busbars 106a . 106b at its one end through the resin layer 109 and the resin film layer 110 led to the outside. Thus, the electrical output of the photovoltaic module via the busbars 106a . 106b be won.
The outer circumference of the encapsulating material 108 has an inclined surface (first inclined surface) 108a with a predetermined angle of inclination. The angle of inclination of the inclined surface 108a is the same as the inclination angle of the chamfers 101 of the glass substrate 101 , The bevels 101 are uniform with the inclined surface 108a
The encapsulating material 108 is with the glass substrate 101 united when the former is connected to the back surface of the latter by heat and under pressure. During the bonding process, the encapsulating material 108 change his profile because it contracts thermally. Therefore, the size of the encapsulating material becomes 108 chosen so that it can not be smaller than the size of the glass substrate 101 when the encapsulating material 108 thermally contracted. The inclined surface 108a of the encapsulating material 108 is formed out after the encapsulating material 108 with the glass substrate 101 has been connected or the encapsulating material 108 thermally contracted. With this sequence, the bevels can 101 of the glass substrate 101 reliable with the inclined surface 108a of the encapsulating material 108 to lock.
For a photovoltaic module 100 is thus effected in the manner described above, that the outer peripheral surface of the encapsulating material 108 has an inclined surface that has the same angle of inclination as the bevels 101 of the glass substrate 101 , and also the bevels 101 with the inclined surface 108a united.
As a result, the circumference of the encapsulating material stands 108 not over the circumference of the glass substrate 101 out to the outside. Consequently, the encapsulating material 108 protected against damage that may otherwise occur if an external force acts unintentionally on it. It also prevents it from the glass substrate 101 is separated to the accidental ingress of rainwater into the semiconductor layer 104 to effect.
The encapsulating material 108 not only has the feature that its circumference does not exceed the circumference of the glass substrate 101 outwardly projecting, but another feature, namely that the bevels 101 of the glass substrate 101 with the inclined surface 108a of the encapsulating material 108 are united.
Thus, the chamfers extend 101 from the inclined surface 108a evenly and continuously, without creating a step at its border.
When an external force unintentionally on a peripheral portion of the encapsulating material 108 is thus reliably prevented that the latter is damaged along its circumference and separated from the glass substrate.
2 is a schematic sectional view of another photovoltaic module 120 , As in the first example described above, this second example shows a photovoltaic module 120 a glass substrate 101 on, that too bevels 101 which are formed by chamfering its outer circumference.
However, the outer peripheral surface of the encapsulating material 108 no inclined surface 108a but a vertical surface 108b leading to the flat surface of the glass substrate 101 is substantially vertical. The vertical surface 108b is on the back surface of the glass substrate 101 arranged so that they do not over the outer peripheral surface of the glass substrate 101 may extend outward. In this example, the vertical surface 108b arranged so that one of its edges is positionally aligned with the corresponding edges of the chamfers 101 matches.
Although in this arrangement, the vertical surface 108a of the encapsulating material 108 from the bevels 101 of the glass substrate 101 differs in angle and is therefore not combined with these is the encapsulating material 108 protected against any external force that may be inadvertently exerted thereon, since the encapsulating material 108 not over the outer circumference of the glass substrate 101 out to the outside, as in the first example.
In addition, the vertical surface 108b arranged so that one of its edges is positionally aligned with the corresponding edges of the chamfers 101 matches. Therefore, the encapsulating material extends 108 neither over the outer circumference of the glass substrate 101 out to the outside, still from the corresponding edges of the bevels 101 unlike the imaginary vertical surface 108c , in the 2 indicated by a dashed line. Thus, the encapsulating material 108 more reliably than in the first example, before the adverse effect of an external force that can be inadvertently exerted on its circumference.
3 is a schematic sectional view of the third example of a photovoltaic module 130 , The glass substrate 101 of the photovoltaic module 130 this example is not chamfered at its edge, and its outer peripheral surface is a vertical surface 101b , In contrast, the outer peripheral surface of the encapsulating material 108 as inclined surface 108a performed at a predetermined inclination angle and arranged so that they do not over the vertical surface 101b of the glass substrate 101 extends outwards. In this example, one of the edges is the inclined surface 108a arranged so that it is in position with the corresponding edge of the vertical surface 101b of the glass substrate 101 matches.
As the scope of encapsulation material 108 in this arrangement, not over the outer peripheral surface of the glass substrate 101 outwardly protruding, is the encapsulating material 108 against any external force that may be inadvertently exerted on it. As the outer peripheral surface of the encapsulating material 108 is not inclined, it is also exposed to an external force less.
In this example, the last end of the inclined surface 108a of the encapsulating material 108 relative to the vertical surface 101b of the glass substrate 101 be positioned inside.
4 is a schematic sectional view of the fourth example of a photovoltaic module 140 , The glass substrate 101 of the photovoltaic module 140 This example is not chamfered at its edge and has a vertical surface 101b , Also the outer peripheral surface of the encapsulation 108 is not bevelled and has a vertical surface 108b , Then the vertical surface 108b of the encapsulating material 108 with the vertical surface 101b of the glass substrate 101 united.
As the scope of encapsulation material 108 not over the circumference of the glass substrate 101 outwardly protrudes, in this arrangement, the encapsulating material 108 an external force that may be inadvertently exerted thereon is less exposed so that it is protected from damage and accidents that could separate it from the glass substrate.
In this fourth example, the vertical surface 108b of the encapsulating material 108 relative to the vertical surface 101b of the glass substrate 101 be positioned inside.
In view of the fact that the encapsulating material 108 thermally contract when it is with the glass substrate 101 is thermally connected under pressure, accordingly, the inclined surface 108a or the vertical surface 108b of the encapsulating material 108 The second to fourth examples are preferably formed after the encapsulating material 108b with the glass substrate 101 has been thermally bonded under pressure.
5 is a schematic sectional view of the fifth example of a photovoltaic module 200 , Note, however, that the arrangement of this example can be applied to each of the above-described first to fourth examples.
A transparent SiO 2 electrode layer is on a glass substrate 201 made of soda-lime glass measuring 92 cm (length) × 46 cm (width) × 4 mm (height). The transparent electrode layer 202 is along scribing lines 202a , which correspond to a plurality of unit cells, scribed and divided into strands with a width of about 10 mm. An amorphous silicon type semiconductor layer for photoelectric conversion 203 with pin connections is on the transparent electrode layer 202 educated.
The amorphous silicon type semiconductor layer for photoelectric conversion 203 is along the scribe lines 203a by the respective respective score lines 202a the transparent electrode layer 202 microns are shifted about 100 microns, scribed. The scribe lines 203a make so many connection openings between the transparent electrode layer 203 and a back electrode layer 204 ready on the semiconductor layer for photoelectric conversion 203 is formed by introducing ZnO and Ag into a multilayer structure. The back electrode layer 204 and the photoelectric conversion photoelectric conversion layer 203 , which is arranged on the front surface side relative to the former, are respectively by scribe lines 203a . 204a divided into strands, with the scribe lines 204a the back electrode layer 204 from the respective respective score lines 203a of the photoelectric conversion photoelectric conversion layer 203 μm are shifted to about 100 μm. Then, the plurality of unit cells (having a strand width of about 10 mm) are connected in series to produce an integrated module of photovoltaic thin film cells.
The photoelectric conversion semiconductor layer and the back electrode layer become along a line along the outer circumference of the glass substrate 201 pulled from the glass substrate 201 and separated from the latter by 5 mm to create an isolation / separation zone there around the photovoltaic cells along the entire circumference of the glass substrate 201 to be electrically separated from the outside. The portions of the photoelectric conversion semiconductor layer and the back electrode layer that are outward relative to the outermost strands are removed to produce about 3.5 mm wide wiring zones. The wiring zones become solder 205 applied to bus bar electrodes 206 to create. Thus, the busbar electrodes are 206 arranged parallel to the strands of photovoltaic cells. Then the busbar electrodes become 206 connected to the respective conductive bands (not shown).
Then, as in the perspective view in 6 It can be seen, a main encapsulation material 207 from an EVA web is placed on a central portion of the back surfaces of the photovoltaic cells, and polyisobutylene resin is applied thereto to form a vapor barrier member 208 which covers a surrounding area of the back surfaces of the photovoltaic cells. In particular, the material of the vapor barrier part 208 applied to a zone region having a width of less than 5 mm from the outer periphery of the glass substrate 201 has, so that the material of the vapor barrier part 208 not with the bus bar electrodes 206 and the back electrode layer 204 comes into contact in the power generation area. In addition, a back surface cover film becomes 209 vinyl fluoride resin / Al / vinyl fluoride resin on the encapsulating material with the main encapsulating material 207 and the vapor barrier part 208 overlaid, and the arrangement of films is sealed with a Vakuumlaminiervorrichtung. The vacuum laminator is operated at 150 ° C for 30 minutes for the thermosetting process. Under the conditions described above, the materials of the main encapsulant and the vapor barrier member are bridged and cured. As the polyisobutylene resin becomes mobile during this process, the lateral surfaces of the glass substrate become 201 also from the vapor barrier part 208 covered. The main encapsulation material 207 and the vapor barrier part 208 have a thickness of about 0.6 mm, while the back surface cover film 209 has a thickness of 110 microns.
In one experiment, the current-voltage characteristic of the thus-prepared photovoltaic module was detected by means of a solar simulator of 100 mW / cm 2 and 1.5 A to obtain an output power level of 32 W from the photovoltaic module. Then, the photovoltaic module was observed in a PCT (Pressure Cooker Test) conducted at 120 ° C under 2 atmospheres, and the appearance of the photovoltaic module was examined after the test and found that the back electrode remained completely unaffected and corrosion free was.
For purposes of comparison, a photovoltaic module was made exactly as in the previous example, except that only EVA was used as the encapsulating material to cover the entire back surfaces of the photovoltaic cells. The comparative sample was also observed by the solar simulator to obtain an output power level of 32W as in the fifth example. However, when the specimen was observed in a PCT (vapor pressure test) at 120 ° C under 2 atmospheres, and the appearance of the photovoltaic module after the test was examined, it was found that the back electrode is likely to have entered through the periphery due to the moisture , had been corroded. A thermoset encapsulant, such as EVA, has advantages in that it has a reflectivity similar to that of glass and can be made cheaply. However, EVA is not satisfactory in water resistance, moisture resistance and alkali resistance. Therefore, moisture can easily penetrate through the exposed EVA into conventional photovoltaic modules, so that the inside conductive tapes and the back electrode layer are corroded, and hence the long-term reliability of the module deteriorates.
As described above, the fifth example provides a photovoltaic module 200 an excellent advantage, namely long-term reliability due to the anticorrosive effect by using an encapsulating material with a Hauptkapselungsmaterial covering a central region of the back surfaces of the photovoltaic cells, and a vapor barrier part, which covers a peripheral region of the back surfaces of the photovoltaic cells, so that the penetration of any moisture, which tries to penetrate through the outer sides of the encapsulating material into the interior of the photovoltaic module in order to corrode the conductive bands and the back electrode layer inside, can be effectively prevented. In addition, such a photovoltaic module can be manufactured at low cost.
There the polyisoprene resin material of the vapor barrier only on a peripheral region the back surface of the mounted photovoltaic cells is applied, is also the Material application process effortlessly. Further In such an arrangement, the consumption of a relatively expensive Materials low, and thus can the cost of producing such a photovoltaic module kept low. Finally, the main encapsulating material and the vapor barrier can be made with the same thickness can the back surface of the photovoltaic module are made very flat.
A material having a vapor permeability of 1 g / m 2 · day at a film thickness of 100 μm is preferably used for the vapor barrier. The materials which can be used for the vapor barrier and satisfy the above-described requirement include polyisobutylene type resin materials, urethane type isobutylene resin materials, silicon type isobutylene resin materials, urethane type adhesive, acrylate type adhesive and epoxy type adhesive, wherein the use of a resin material of the polyisobutylene type is preferable from the standpoint of insulation effect and strength.
Various Known techniques can be used for hardening the above compounds are used. For example can be used for curing Resin materials of the polyisobutyl type are used a technique as disclosed in Japanese Patent Application Laid-Open No. 6-49365 for polymerization and curing A compound has been disclosed which includes: a Isobutylene-type polymer substance having C-C double bonds at the ends, one Harder with two or more than two hydrosol radicals and a catalyst and a technique for polymerizing a compound that is a polymeric substance isobutylene type with hydroxyl radicals at the ends, an isocyanate compound and a curing catalyst contains.
For the purpose of the present examples The compound also some other additives, such as a plasticizer for regulating the viscosity the one to be hardened Connection, be added. A vapor barrier part of one elastic hardened Material can be cured by curing a composition containing such substances formed become.
7 is a schematic sectional view of the sixth example of a photovoltaic module 310 showing a main portion thereof to illustrate a photovoltaic module manufacturing method. 8th to 10 FIG. 12 are schematic sectional views of the sixth example of the photovoltaic module illustrating various steps of its manufacturing process. The method described below for this example can also be applied to the first to fourth examples of photovoltaic modules described above.
This in 7 shown photovoltaic module 310 has a photovoltaic sub-module, in turn, a plurality of photovoltaic cells 312 on a translucent (transparent) glass substrate 311 are integrally formed. It causes the sunlight through the glass substrate 311 enters the photovoltaic submodule. Each unit cell 312 has a transparent front electrode layer 312a , a non-monocrystalline silicon type photoelectric conversion unit 312b and a back electrode layer 312c on, one after the other on the glass substrate 311 are arranged in the order listed above.
The transparent front electrode layer 312a placed directly on the glass substrate 311 is formed, may be a layer of a transparent conductive oxide film, such as ITO film, SiO 2 film or a ZnO film. The transparent front electrode layer 312a may have a single-layer structure or a multi-layer structure and may be formed by a corresponding known technique such as vapor deposition, CVD method or sputtering method. Preferably, the surface of the transparent front electrode layer has a surface texture structure with microwave. Characterized in that the surface of the transparent front electrode layer 312 When such a texture structure is imparted, all the solar rays incident on the non-monocrystalline silicon type photoelectric conversion unit 312b hit and the cell 312 can be suppressed without contributing to the photoelectric conversion process.
Although not shown, it has the transparent front electrode layer 312a formed non-monocrystalline silicon type photoelectric conversion unit 312b a multi-layer structure obtained by sequentially depositing a p-type non-crystalline silicon semiconductor layer, a non-crystalline silicon thin film photoelectric conversion layer, and an n-type non-crystalline silicon semiconductor layer. The above-mentioned p-type semiconductor layer, the photoelectric conversion layer 342 and the n-type semiconductor layer can all be formed by plasma CVD methods. The p-type silicon semiconductor layer may be formed by using silicon, silicon carbide or a silicon alloy such as silicon-germanium doped with p-type conductivity-determining impurities such as boron atoms or aluminum atoms. Materials that can be used for the layer include silicon (silane, etc.), which is an intrinsic semiconductor, silicon carbide, and silicon alloys such as silicon germanium. In addition, a lightly doped p-type or n-type semiconductor material containing silicon and a trace of a conductivity-type impurity may also be used if it is sufficiently effective for photoelectric conversion. The photoelectric conversion layer is made to have a thickness between 0.1 and 10 μm when made of an amorphous material. The n-type silicon-containing semiconductor layer formed on the photoelectric conversion layer may be made of silicon, silicon carbide or a silicon alloy such as silicon germanium doped with n conductivity type impurities such as phosphorus atoms or nitrogen atoms.
Although on the photoelectric conversion unit 312b formed back electrode layer 312c is made of a metallic material, it is advantageous that the back electrode layer 312c not only works as an electrode, but also as a reflection layer for reflecting the light rays passing through the glass substrate 311 in the photoelectric conversion unit 312b enter and to the back electrode layer 312c get back into the photoelectric conversion unit 312b enter. Therefore, it is preferably made of a metallic material having a high reflectivity for light, such as silver or a silver alloy. The back electrode layer 312c can be formed by a known technique, such as vapor deposition or sputtering.
The transparent front electrode layer 312a The non-monocrystalline silicon type photoelectric conversion unit 312b and the back electrode layer 312c like so many thin layers with a large surface area on the glass substrate 311 formed and then normally by means of a laser process, in a plurality of unit cells 312 divided, wherein the unit cells 312 then electrically connected in series or in parallel to produce a one-piece structure.
As in 7 are shown, the transparent front electrode layer and the others on the glass substrate 311 formed silicon thin film layers normally by a sandblasting technique from its peripheral region 311 ent removed, so that the peripheral area 311 to the atmosphere is exposed to cells 312 to create. The exposed glass surface of the peripheral portion of the glass substrate 311 produces an improved adhesion relative to the encapsulating resin to be applied thereon, as described in more detail below.
The back surface of the photovoltaic submodule described above is then replaced by a protective film formed thereon 314 with an encapsulating resin layer (adhesive layer) interposed therebetween 313 protected and locked. The encapsulating resin can be easily hardened when softened and melted by heat, and can be used on the glass substrate 311 hermetically seal formed unit cells and cause the protective film 314 firmly connected to the photovoltaic submodule. Resinous materials which can be used as an encapsulating resin are usually thermoplastic resin materials such as EVA, EVAT, PVB (polyvinyl butyral) and PIB, of which EVA can preferably be used for the purpose of the invention in terms of adhesion to the glass substrate and cost ,
The listed above thermoplastic resin materials contain a hardener (bridging agent) for bridging and curing of the resin. Harder, preferably for the purpose of the invention can be used are u. a. organic Peroxide compounds such as 2,5-dimethylhexane-2,5-dihydroperoxide. One Bridging agent off an organic peroxide compound can radicals for bridging the Encapsulate resin when heated above 100 ° C.
The protective film 314 is used to protect the photovoltaic sub-module when it is placed outdoors, so that it is desirably very moisture resistant and waterproof and has a high insulating effect. Such a protective film 314 For example, an organic film layer of a fluororesin film such as polyvinyl fluoride film (e.g., Tedler-Film (trade name)) or Po have lyethylene terephthalate (PET) film, which are arranged on the side, with the encapsulating resin layer 313 is kept in contact. The organic film layer may have a single-layer structure or a multi-layer structure. As an alternative, the protective film layer 314 have a structure in which a metal foil such as aluminum foil may be sandwiched between a pair of organic films. Since a metal foil, such as aluminum foil, can improve the moisture resistance and water resistance of the protective film, it can effectively protect the photovoltaic sub-module against moisture that tries to penetrate from the back surface when the protective film 314 has such a structure. The organic films are preferably fluororesin films for the purpose of the invention.
The encapsulating resin layer 313 and the protective film 314 are along the circumference of the glass substrate 311 circumcised.
Now, the first to fourth kind of a manufacturing method of a photovoltaic module will be described below with reference to FIG 8th to 10 described. Briefly, a photovoltaic module is manufactured by sequentially applying an encapsulating resin sheet which can be easily cured when softened and melted by heat, and a protective film having an area larger than the surface of the glass substrate on the back surface of the photovoltaic sub-module. and performing a curing process after softening and melting the encapsulating resin to securely connect the protective film to the back surface of the photovoltaic sub-module. Then, in a corresponding manufacturing step, the photovoltaic module is subjected to a predetermined clipping process to produce a finished photovoltaic module.
Usually For example, the encapsulating resin sheet and the protective film together with the Photovoltaic sub-module in a Vakuumheißklebevorrichtung (a so-called Vacuum lamination device) to deliver the encapsulating resin soften and melt, and warmed and interconnected, while they are heated in vacuo.
Any known double vacuum type laminating apparatus may be used in the present invention. The vacuum laminator 330 , in the 8th as an example, has a lower chamber 332 and an upper chamber 331 which can be operated to be relative to the lower chamber 332 be opened and closed by a drive mechanism (not shown).
The upper chamber 331 is with a partition 331a whose circumference is airtight with the inner peripheral wall of the upper chamber 331 connected is. The upper chamber 331 is also on one of its side walls with an upper suction hole 331b provided with the interior, passing through the partition wall 331a limited and separated, is kept in touch. The upper suction hole 331b is connected to a suction pump (not shown). On the other hand, the lower chamber 332 inside with a table 332a for holding a lamination object, wherein the table 332a a heater 332c for heating the lamination object. In addition, the lower chamber 332 on one of its side walls with a lower suction hole 332b provided, which is connected to a suction pump (not shown).
If the photovoltaic submodule 320 with a glass substrate 311 and several cells 312 , which are in one piece on the glass substrate 311 are formed, is encapsulated, first the photovoltaic submodule 320 on the table 332a in the lower chamber 332 leveled, with the glass substrate 311 with the table 332a is kept in contact. Then, the encapsulating resin sheet becomes 313 ' on the back surface (the upper surface in 8th ) of the photovoltaic submodule 320 levels, and then the protective film 314 on the encapsulating resin sheet 313 ' placed to produce a laminate. Note that the encapsulating resin sheet 313 ' as large or slightly larger than the glass substrate 311 is and the protective film 314 is slightly larger than the glass substrate 311 ,
After that, the upper chamber 331 relative to the lower chamber 332 closed and both the interior of the upper chamber 331 as well as the lower chamber 332 evacuated to that in the encapsulation resin sheet 313 ' to remove contained gas. Then the internal pressure of the upper chamber 331 restored. As a result, it expands in the upper chamber 331 arranged partition 331a down from, as in 8th shown to the lamination object on the heater 332c heated table 332a is placed to press down. Then the lamination object is heated and placed between the table 332a and the partition 331a kept under pressure until the encapsulation resin sheet 313 ' softens and melts to subsequently produce a laminate in which the protective film 314 and the back surface of the photovoltaic sub-module 320 are firmly connected.
In this first mode of embodiment of the sixth example, the heating / bonding process continues until the encapsulating resin in the vacuum laminating apparatus is fully cured. That is, in this first mode, the heating / bonding process is performed at a temperature higher than that Curing temperature of the encapsulating resin and lower than the decomposition temperature of the encapsulating resin. For example, an EVA encapsulating resin material containing a normal organic peroxide compound may be heated / bonded at a temperature above about 120 ° C and below 170 ° C for about 5 to 120 minutes. After complete curing of the encapsulating resin, the produced laminate (photovoltaic module) is removed from the vacuum laminator 330 removed.
When removing the laminate product from the vacuum laminator 330 First, the internal pressure of the lower chamber 332 restored to cause the partition 331a which has been stretched down, contracted and resumes the original profile and the ceiling of the upper chamber 331 raising. Then the vacuum laminator 330 opened so that the laminate product can be taken out.
Now the circumcision process will be described. As stated above, the laminate product comprising the vacuum laminator has 330 has been taken out after the completion of the curing process of the encapsulating resin, a profile as in 9 shown, wherein the encapsulating resin partially over the circumference of the glass substrate 311 As the encapsulating resin became molten when heated under pressure. That is, it has a molten and extended part 313a that is under the corresponding extended part 314a the protective film is also located over a circumference of the glass base 311 extends beyond.
Therefore, the molten and expanded part becomes 313a of the encapsulating resin together with the corresponding extended part 314a of the protective film 314 subjected to a clipping process in a state in which the extended part 313a of the encapsulating resin is heated to a temperature above the softening point (and below the decomposition temperature) of the encapsulating resin. Although the specific temperature of the clipping process may vary depending on the particular encapsulating resin used, it is between 40 ° C and 150 ° C when the encapsulating resin is normal EVA. A normal cutting device, such as a cutter, can be used for the clipping process. Normally, the encapsulating resin and the protective film become 313 along the circumference of the glass substrate 311 cut off.
During the clipping process, the entire laminate product can be heated above the softening point of the encapsulating resin. Alternatively, the clipping process may be performed while the laminate product is planarized on a hot plate with the glass substrate down and the laminate is heated above the softening point of the encapsulating resin. As still another alternative, the clipping process may be performed by means of a cutting device, such as a cutter, which is heated to heat the laminate above the softening point of the encapsulating resin. In this case, the extended part becomes 313a in turn brought into contact with a cutting device which is heated to a predetermined temperature, so that the extended part 313a is heated above the softening point of the encapsulating resin.
Preferably the clipping process becomes the completion of the hardening process of the Encapsulating resin performed, because the encapsulating resin after complete curing of the encapsulating resin easier to cut with a cutting device than before the completion of the curing process.
In this second mode of embodiment of the sixth example, the heating / bonding process in the vacuum laminating apparatus 330 completed while the encapsulating resin is cured, that is, after the start of the curing process of the encapsulating resin and before completion of the process. In other words, the laminate is removed from the vacuum laminator when the encapsulating resin sheet 313 ' has already begun to soften and melt to be cured by the heating / bonding process, but has not yet fully cured. Although the conditions under which the heating / bonding operation is performed may be appropriately selected depending on the curing characteristic of the encapsulating resin to be used, the operation is normally carried out at a temperature between 120 ° C and 130 ° C for about 5 to 10 minutes, when the encapsulating resin is normal EVA in an organic peroxide compound.
The laminate, that of the vacuum laminator 330 is removed, if the encapsulating resin is still not completely cured (the laminate may be referred to as a photovoltaic module intermediate, since the curing process is not yet completed), then it is placed in a normal reheater (not shown), such as a furnace and heated there to terminate the curing process of the encapsulating resin. Although the conditions under which the curing operation is carried out may be appropriately selected depending on the type of encapsulating resin to be used, the operation is normally carried out at a temperature of over 140 ° C (and unreacted) the decomposition temperature of the encapsulating resin) for 10 to 120 minutes when the encapsulating resin is normal EVA. Although the encapsulating resin can contract when cured in this heating process, the extent of contraction is small and negligible.
Then the clipping process takes place on the photovoltaic module after the completion of the curing process the encapsulating resin removed from the Nachwärmgerät and is terminated before the encapsulating resin drops below its softening point chilled is.
at the type of execution of the lamination process described above the lamination object does not take the vacuum laminator until completion the curing process of the encapsulating resin, so that gives an advantage, namely an improvement in productivity in the production of photovoltaic Modules.
In the third mode of embodiment of the sixth example, as in the second type described above, the heating / bonding process in the vacuum laminating apparatus 330 terminates while the encapsulating resin cures, that is, after the start of the curing process of the encapsulating resin and before the completion of the process. Subsequently, the obtained photovoltaic module intermediate product is removed from the vacuum laminator.
That of the vacuum laminator 330 taken laminate product has a profile, as in 9 shown, wherein the encapsulating resin partially over the circumference of the glass substrate 311 expands since the encapsulating resin became molten when it was heated under pressure. Therefore, it has an extended part 313a , Therefore, the molten and expanded part becomes 313a of the encapsulating resin together with the corresponding extended part 314a of the protective film 314 (please refer 10 ) subjected to a clipping process. Normally, a cutter may be used to stretch the extended portions along the circumference of the glass substrate 311 ' during the clipping process.
Then the workpiece, which is an in 10 has been introduced into a conventional Nachwärmgerät, such as a furnace, and heated there to terminate the curing process of the encapsulating resin. Although the conditions under which the curing operation takes place may be appropriately selected depending on the kind of the encapsulating resin to be used, the operation is normally carried out at a temperature higher than 140 ° C (and lower than the decomposition temperature of the encapsulating resin) for 10 to 120 minutes Encapsulating resin is normal EVA. Although the encapsulating resin can contract when cured in this heating process, the extent of contraction is small and negligible.
In the third kind described above, there is no risk that the extended part 313a during the Nachwärmprozesses to harden the encapsulating resin dissolves and the Nachwärmgerät contaminated when the workpiece is reheated in Nachwärmgerät, since all unnecessary parts of the encapsulating resin and the protective film are removed before the Nachwärmprozeß during trimming (see 9 ). In this way, a photovoltaic module 310 according to 7 produced.
In the method of manufacturing a photovoltaic module, as described above with respect to the sixth example, both the expanded portion 314a of the protective film as well as the extended part 313a the encapsulation resin are removed smoothly and efficiently in the clipping process, without even partially separating the protective film from the remaining part of the module and / or the glass substrate 311 , the protective film 314 and / or damaging the encapsulating resin because the encapsulating resin layer is not subjected to excessive stress during the clipping process. As a result, a laminate in which the end face of the encapsulating resin layer 313 and the protective film 314 with the end surface of the glass substrate 311 is flush, won, as in 10 finally shown a finished photovoltaic module product 310 to produce, as in 7 shown.
The Production costs of a photovoltaic module can be reduced Since it is no longer necessary, the heating / pressurizing process and the Process of Softening / melting and hardening of the encapsulating resin continuously in an expensive vacuum laminator perform. Furthermore may be the molten and expanded part of the encapsulating resin along with the redundant part the protective film in the trimming process easily removed Consequently, the productivity and the yield in the process of Increase production of photovoltaic modules.
11 is a schematic sectional view of an embodiment of a photovoltaic module according to the invention 400 , which is a thin-film type photovoltaic module. It should be noted, however, that the following description applies substantially to the first to fourth examples described above. In 11 are several photovoltaic thin-film cells 402 on the back surface of the front glass cover 401 that as transparent Substrate serves, arranged and through a back surface electrode 403 in series and / or in parallel. The back surface electrode 403 is in turn with an output lead wire 404 connected, which is usually made of metal foil.
The above listed back surface side components are through a filler layer 405 wrapped, wherein the output terminal wire 404 pulled out from there. The filler material is usually selected from EVA, PVB and silicon resin.
Then, the back surface of the filling material layer becomes 405 with back surface encapsulation materials 406 coated with a three-layer structure, which results from a metal foil 406a between a pair of insulating films 406b a highly moisture-resistant and water-resistant material, such as fluorine films or ET films, sandwiched. The gap between the two back surface encapsulation materials 406 is connected to an output terminal section Q for feeding out the outer lead wire 404 Mistake.
As shown above, has the back surface encapsulating material a three-layered structure by sandwiching a metal foil arises between a pair of insulating films, though it does alternatively may be made of a single insulating film. When the three-layered structure is used, the improved sandwiched between the insulating films arranged metal foil the moisture resistance and the water resistance of the Partly, so that it The photovoltaic cells can effectively protect against moisture.
The external connection wire 404 which is pulled out through the output terminal section Q is made to extend along the back surface of the photovoltaic module. In particular, one of the back surface encapsulating materials becomes 406 on the filler layer 405 and the EVA film, and the output lead wire pulled out 404 and the output terminal section Q are on the backside encapsulating material 406 applied. Then, the EVA film on the extension of the output terminal section 404 applied, and the other backside encapsulation material 406 is applied on the EVA film. The multi-layer structure of the back surface side is completed when the layers are normally treated in a hot melt process. The length along which the outer back surface encapsulation material 406 on the outside lead wire 404 is applied (which corresponds to the distance between the atmosphere and the Ausgangsanschlußteilstück), is preferably 100 mm or more. To be more specific, the longer, the better for the distance. The outside lead wire pulled outside 404 will then be at the terminal 406 fixed by solder or by a screw, and an output line wire 408 will with the connection 407 connected. The connection section of the module with the output connection wire 404 , the connection 407 and the output line wire 408 is in a junction box 409 accommodated.
As described above, the filling material layer is 405 the output terminal section Q of the above-described photovoltaic module 400 with the back surface encapsulation materials 406 covered and therefore not exposed to the atmosphere. Therefore, the filler layer 405 of the output terminal section Q is separated from the atmosphere by a distance longer than the counterpart of any known photovoltaic module, so that moisture is prevented from intruding inwardly. Thus, the outside lead wire 404 and the back surface electrode 403 effectively protected against corrosion to improve the weather resistance of the photovoltaic module. Due to the advantages described above, it is no longer necessary, the interior of the junction box 409 To close with protective resin, so that the efficiency of the production of the photovoltaic module is significantly increased.
12 Fig. 12 is a schematic sectional view of another embodiment of a photovoltaic module according to the invention which is of the crystal type. In 12 are the components that are in those 11 are denoted by the same reference numerals and will not be further described.
In 12 are several photovoltaic cells 411 on the back surface of the front glass cover 401 arranged and interconnected by connecting wires 412 connected. Each of the photovoltaic cells 411 , which are disposed at the opposite ends, is connected to an output lead wire 404 connected. Otherwise, the module has the same configuration as in 1 shown.
This in 12 illustrated photovoltaic module offers the advantages as above with respect to 11 described so that the back surface electrode 403 and the connecting wires are protected against corrosion to improve the weather resistance of the module.
13 Fig. 10 is a schematic sectional view of another embodiment of a photovoltaic module according to the invention, which is also of the thin film type. In 13 are the components that are in 11 are denoted by the same reference numerals and will not be further described.
In 13 is the arrangement of photovoltaic cells 402 , the back surface electrode 403 and the filler layer 405 on the back surface of the front glass cover 401 same as in 11 , In the photovoltaic module according to 13 are the back surface encapsulation materials 406 provided with a through hole in which the output terminal section Q is arranged. Then the output lead wire is 404 on the back surface side of a back surface encapsulating material 406 pulled out and through the filling material layer 405 extended. A third backfill encapsulation material 413 is on the other back surface encapsulation material 406 and the extension of the outer lead wire 404 applied, wherein the filling material layer 405 is arranged in between.
This in 13 illustrated photovoltaic module also offers the advantages as above based on 11 described so that the back surface electrode 403 and the connecting wires are protected against corrosion to improve the weather resistance of the module.
Photovoltaic module ( 400 ) with: a transparent substrate ( 401 ); photovoltaic cells ( 402 ) formed on the back surface of the transparent substrate ( 401 ) are formed; a stuffing part ( 405 ) for closing the photovoltaic cells ( 402 ); and a back surface encapsulating material ( 406 ) located on the back surface of the filling part ( 405 ) is arranged; characterized in that it further comprises: an output terminal wire ( 404 ) connected to the photovoltaic cells ( 402 ) connected is; the output terminal wire ( 404 ) from the interior of the filling part ( 405 ) through an output terminal section (Q) to the rear surface of the back surface encapsulating material (Q) 406 ), wherein the filling part ( 405 ) of the output terminal section (Q) is not directly exposed to the atmosphere.
Photovoltaic module according to Claim 1, characterized in that the output connection wire ( 404 ) along the back surface of the photovoltaic module ( 400 ) and an extension portion of the output lead wire (FIG. 404 ) with the back surface encapsulating material ( 406 ) is coated.
Photovoltaic module according to claim 2, characterized in that a first back surface encapsulating material layer ( 406 ), the output lead wire ( 404 ) and a second back surface encapsulating material layer ( 406 ) has a layer structure in the extension portion of the output lead wire (FIG. 404 ) form.
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